Announcements • Toxins End of Unit Assessment Retakes – After School Today • Last day for any retakes is THIS Friday • Notebooks due by Monday June 1st – NBs turned in Friday will get 5% EC in NB grade • If you did not complete google forms(2), you must do so or you may not get higher than a D on your NB. Calorimetry • The measurement of heat-related constants, such as specific heat. Calorimeter: A device used to measure the heat absorbed or released in a chemical or physical change. Specific Heat of Brass Lab • cbrass = __ _Qbrass__ _ mbrass ×∆Tbrass cbrass : specific heat of brass Qbrass : amount of heat transferred (J) mbrass : mass of brass object (g) ∆Tbrass : change in temperature of brass (oC or K) • Object must be submerged in calorimeter water • You MUST know exactly how much water is in the calorimeter (styrofoam cup) • 3 trials should be with same amounts of water in calorimeter • ONLY thing you are measuring the mass of is the brass object. – DO NOT weigh the water in the calorimeter to find the mass. Styrofoam cup calorimeter • Hot metal placed in cold water. • Heat transfers from hot metal to cold water. • Temperature of each will eventually reach thermal equilibrium – When two objects in contact with one another reach the same temperature. • Amount of heat lost by metal is = amount of heat gained by water. – Qmetal = -Qwater ∆TH2O = T2 – T1 ∆Tbrass = T2 – 100oC Calculations • Amount of heat lost by brass is = amount of heat gained by water. Qbrass = -QH2O Step 1: Solving for Qwater Find out how much heat the water absorbed from brass. QH2O= mH2O×cH2O×∆TH2O Step 2: Qbrass. Amount of heat lost by the brass = amount of heat gained by the water. Qbrass = -QH2O Step 3: cbrass. Determine the specific heat of brass. cbrass = __ _Qbrass__ _ mbrass ×∆Tbrass Measured in lab cH2O = 4.18 J/g*oC For %Error Accepted Value for Specific Heat of brass: 0.380 J/goC Procedure 1. Boil ~200mL in a 400mL beaker (1/two groups) 2. Get a brass object from Ms. Yow. Record object # @ top of page. Find the mass of brass object (mbrass) 3. Lower brass object into water with tongs. Be careful not to drop it and crack the beaker. 4. Add 50-100 mL of cold water into styrofoam cup. 1mL of water = 1g of water. (mwater = volume of water in styrofoam cup) 1. Need to know exactly how much water and water needs to cover brass object in cup. Procedure 5. Record initial temperature (T1) of water in styrofoam cup 6. When brass object has been in boiling water for ~3 minutes, quickly and carefully move it into the styrofoam cup (calorimeter) with tongs. 7. Without moving the thermometer too much, and also not touching the thermometer to the brass, record the highest temperature the water reaches (T2). 8. Do 2 more trials starting with new cold water. Conclusion (NB pg. 174) Attach Calculations to NB pg. 175 Attach Lab handout to NB pg. 175 Summary /Conclusion on NB pg. 174 (on it’s own page), Write a summary of the lab and your calculations. (guiding questions provided on next slide) Give 2-3 reasons why your experimental value for the specific heat of brass was not the same as the accepted value. Some questions to address in your summary/conclusion. 1. What is calorimetry? What is a calorimeter and how did we utilize calorimetry in this lab? 2. Why do we use the ending temperature of the water as the ending temperature of the brass? 3. Why can we assume the starting temperature of the brass is 100? 4. How do you convert from Qwater into Qbrass? 5. What are 2-3 sources of error that probably happened in your lab? Do not just list anything that could have happened to someone doing the lab – they need to be things that probably happened in YOUR lab. 6. Why is Q of water a positive value? Does that make it endothermic or exothermic? 7. Why is Q of brass a negative value? Does that make it endothermic or exothermic? 8. Did the size and shape of the brass make a difference in the specific heat value? Why or why not? 9. How would your data change if we had put the brass in the freezer and put hot water into the calorimeter? How would the math change? How would your answer change?
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