1. IDENTIFICATION
Product Name
Synonym
Product Use Description
Company
:
:
:
:
Emergency Contact
:
EcoRelease
Blend of Fatty Acid Methyl Esters, Form Oil, Mold Release Agent
Form/mold release coating
Chloronova d.b.a. EcoFeedstock
6964 Tradewinds Drive
Carlsbad, CA 92011
EcoFeedstock – 760-689-3046
2. HAZARDS IDENTIFICATION
Classifications
:
Pictograms
:
Signal Word
Hazard Statements
:
:
Aspiration Hazard – Category 2
Eye Irritation – Category 3
Warning
Combustible liquid. Heating may cause a fire.
May be harmful if swallowed and enters airways.
Harmful if inhaled. May cause an allergic skin reaction. Causes eye
irritation.
PRECAUTIONARY STATEMENTS
Prevention
:
Response
:
Do not handle until all safety precautions have been read and
understood.
Keep away from heat/sparks/open flames/hot surfaces –
No smoking.
Do not spray on an open flame or other ignition source.
Keep away from combustible materials.
Keep container tightly closed.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Use only outdoors or in a well-ventilated area.
Use personal protective equipment as required.
In case of fire: Use dry chemical, CO2, water spray or
fire fighting foam to extinguish.
If swallowed: Do NOT induce vomiting. Rinse mouth. Call a poison
center or doctor/physician if you feel unwell.
If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses if present and easy to do. Continue rinsing.
Storage
:
Disposal
:
If skin irritation occurs: Wash with soap and water.
If skin or eye irritation persists, get medical attention.
If inhaled: Remove victim to fresh air and keep at rest in a position
comfortable for breathing.
Get medical advice/attention if you feel unwell.
Store in a closed container. Protect from sunlight. Do not expose to
temperatures exceeding 50◦ C/122◦ F.
Dispose of contents/containers to approved disposal site in
accordance with local, regional, national, and/or international
regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
Methyl Soyate
Methyl Canolate
CAS No.
67784-80-9
67762-38-3
Mass %
20 - 80%
20 - 80%
LD50 (Albino Rats)
> 50 ml/kg
> 50 ml/kg
4. FIRST-AID MEASURES
Inhalation
:
Skin Contact
:
Eye contact
:
Ingestion
:
Immediately remove victim to fresh air. If victim has stopped
breathing, give artificial respiration, preferably by mouth to mouth.
Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water. Seek
medical advice if symptoms persist or develop.
Remove contact lenses. Rinse immediately with plenty of water, also
under the eyelids, for at least 15 minutes. Seek medical advice if
symptoms persist or develop.
Do not induce vomiting. Never give anything by mouth to an
unconscious person. Obtain medical attention.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing
media
:
Specific hazards during
fire fighting
:
Special protective equipm- :
SMALL FIRES: Any extinguisher suitable for Class B fires, dry
chemical, CO2, water spray or fire fighting foam. LARGE FIRES:
Water spray, fog or fire fighting foam. Water may be ineffective for
fighting the fire, but may be used to cool fire exposed containers.
Keep containers and surroundings cool with water spray.
Avoid using straight water steams. Water spray and foam (AF/ATC)
must be applied carefully to avoid frothing and from as far of a
distance as possible. Avoid excessive water spray application, as in
grease fires. Keep away from flames, hot surfaces, and other ignition
sources. No smoking. Keep surrounding area cool with water spray
from a distance and prevent further ignition of combustible material.
Keep run-off water out of sewers and water sources.
Firefighting activities that may result in potential exposure to high
ent for fire fighters
Unusual fire and explosion :
hazards
Further information
:
heat, smoke or toxic by-products of combustion should require
NIOSH/MSHA approved pressure demand self-contained breathing
apparatus with full face piece and full protective clothing.
Spontaneous combustion may occur in a closed container exposed
to elevated temperatures if material is absorbed in various fiber
matrices and oxygen is present (e.g oily rags) due to runaway
exothermic oxidation reactions. Store wiping rags in metal cans with
tightly fitting lids or submerged under water. Cool closed containers
exposed to fire with water spray. Hazardous combustion products
include carbon monoxide, carbon dioxide, aldehydes, ketones, and
other oxidized hydrocarbons.
This product has been determined to be a combustible liquid
per the OSHA Hazard Communication Standard and should be
handled accordingly. Can ignite under moderate heating. Vapors are
heavier than air and may accumulate in low lying areas. Vapors may
accumulate in confined spaces. For additional fire related
information, see NFPA 30 or the North American Emergency
Response Guide 128.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
:
Environmental
precautions
:
Methods for cleaning up
:
Isolate and evacuate area. Shut off source if it is safe to do so. Keep
all sources of ignition away from released material. All contaminated
surfaces will be slippery. Use impervious gloves when handling
contaminated material. Keep untrained personnel away from
contamination.
Discharge into the environment must be avoided. If the product
contaminates rivers and lakes or drains, inform respective
authorities.
Contain and collect spillage with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite) and
place in container for disposal according to local / national
regulations.
7. HANDLING AND STORAGE
Precautions for safe
handling
:
Comply with all applicable EPA, OSHA, NFPA and consistent state
and local requirements. Use appropriate grounding and bonding
practices. Do not expose to heat, open flames, strong oxidizers or
other sources of ignition. Do not cut, drill, grind, or weld on empty
Conditions for safe stor- :
age, incl. incompatibilities
containers since they may contain explosive residues. Keep used
rags under water and away from heat (see section V)
Store in moisture-free tanks with scheduled water drainage.
Corrosion and microbial growth are promoted by the presence of
water. Product decomposition can be avoided by preventing
temperature extremes and air during storage. Contact with copper
alloys, lead, tin, and zinc may result in increased sediments that can
plug filters.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure guidelines
:
Engineering controls
:
OSHA, OSHA-Z1, ACGIH, and NIOSH have not yet established
exposure limits for the aforementioned components.
Use adequate ventilation to minimize gas and vapor concentrations
of this product, particularly in confined spaces. Use only intrinsically
safe electrical equipment approved for use in classified areas. An
emergency eye wash station and safety shower should be located
near the work station.
PERSONAL PROTECTIVE EQUIPMENT
Eye protection
:
Respiratory protection
:
Skin and body protection
:
Hand protection
:
Work/hygiene practices
:
Safety glasses equipped with side shields are recommended as
minimum protection in industrial settings. Chemical goggles should
be worn during transfer operations or when there is a likelihood of
misting, splashing or spraying of this material.
A breathing apparatus is needed when aerosol or mist is formed.
Observe respirator assigned protection factors (APFs) criteria cited
in OSHA 190.134. Self-contained breathing apparatus should be
used for fire fighting.
Material is sometimes encountered at elevated temperatures.
Thermal burns are possible. Wear long-sleeved
fire-retardant garments while working with flammable and
combustible liquids. Additional chemical-resistant protective gear
may be required if splashing or spraying conditions exist. This may
include an apron, arm covers, impervious gloves, boots and
additional facial protection.
Use chemical resistant gloves such as neoprene, nitrile, or PVA to
prevent prolonged or repeated skin contact.
Handle in accordance with good industrial hygiene and safety
practice. Wash contaminated clothing and skin regularly with soap
and water.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odor
Odor threshhold
:
:
:
Amber to light yellow.
Mild.
No data available.
pH
:
Melting point/freezing point:
Initial boiling point
:
and range
Flash point
:
Evaporation rate
:
U.E.L.
:
L.E.L.
:
Vapor pressure
:
Vapor density (air = 1)
:
Relative density
:
(water = 1)
Density
:
Solubility (in water)
:
Partition coefficient
:
(n-octanol/water)
Auto-ignition temperature :
Decomposition
:
temperature
V.O.C.
:
Kinematic viscosity
:
Conductivity
:
Non-aqueous; no data available.
-10 to -15◦ C.
340◦ C @ 1 atm, 85% volume recovered at 360◦ C.
≥ 130 ◦ C.
Negligible.
10 volume %.
0.3 volume %.
10 mmHg @ 205◦ C.
No data available.
.880 @ 20◦ C.
7.0-7.5 lbf/gal @ 20◦ C.
Negligible.
No data available.
375-450◦ C.
≥ 270◦ C.
49 g/l.
4.0-10.0 cST @ 40◦ C.
No data available.
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
:
:
:
Vapors may form explosive mixture with air. Prone to oxidation.
Stable at the specified storage conditions.
Hazardous polymerization will not occur.
:
:
Heat, highly oxidizing environments.
Avoid contact with strong oxidizing agents such as strong acids,
alkalis, chlorine and other halogens, dichromates or
permanganates, which can cause fire or explosion.
In case of fire, combustion products (e.g., oxides of carbon, sulfur
and nitrogen, fumes or vapors, soot and smoke) and/or dangerously
low oxygen levels can result.
Hazardous decomposition :
products
11. TOXICOLOGICAL INFORMATION
Chemical Name
Methyl Soyate
Methyl Canolate
CAS No.
67784-80-9
67762-38-3
LC50
No data available
No data available
LD50 Oral
> 50 ml/kg
> 50 ml/kg
LD50 Dermal
> 5000 mg/kg
No data available
No components are listed by IARC, NTP, ACGIH, or OSHA HCS 2012 as carcinogenic.
ROUTES OF ENTRY/EXPOSURE
Skin contact
:
Prolonged or repeated contact is not likely to cause significant skin
Eye contact
:
Ingestion
:
Inhalation
:
irritation. Material is sometimes encountered at elevated
temperatures. Thermal burns are possible.
May cause irritation. Irrigate eyes with water for at least 15 to 20
minutes. Seek medical attention if symptoms persist.
No hazards anticipated from ingestion incidental to industrial
exposure.
Negligible unless heated to produce vapors. Vapors or finely misted
materials may irritate the mucous membranes and cause irritation,
dizziness, and nausea. Remove to fresh air.
12. ECOLOGICAL INFORMATION
Toxicity
:
Persistence/degradability :
Bioaccumulative potential :
Other information
:
No data available for toxic effects on fish, aquatic invertebrates, and
algae.
If released to soil and water, this product is expected to biodegrade
under both aerobic and anaerobic conditions.
This product does not concentrate or accumulate in the food chain.
Keep out of sewers, drainage areas, and waterways. Report spills
and releases, as applicable, under Federal and State regulations.
13. DISPOSAL CONSIDERATIONS
This material, if discarded as produced, is not listed by the RCRA as hazardous waste. However, it
should be fully characterized prior to disposal (40 CFR 260-271). Use which results in chemical or
physical change or contamination may subject it to regulation as a hazardous waste. Along with
properly characterizing all waste materials, consult state and local regulations regarding the proper
disposal of this material.
Container rinsate could be considered a RCRA hazardous waste and must be disposed of with
care and in full compliance with federal, state and local regulations. Larger empty containers, such
as drums, should be returned to the distributor or to a qualified drum reconditioner. To assure
proper disposal of smaller empty containers, consult with state and local regulations and disposal
authorities.
14. TRANSPORT INFORMATION
United States Department :
of Transportation (US DOT)
Shipping Description: This material is not regulated as a hazardous
material or dangerous goods by DOT regulations.
Shipping Name: Fatty Acid Ester (National Motor Freight
Classification).
Transportation of
:
Dangerous Goods (TDG)
Canada
ID Number: 144920 (National Motor Freight Classification).
Shipping Classification: 65 (National Motor Freight Classification).
Reportable Quantity: None established for this material.
MARPOL III Status: Not a DOT Marine Pollutant per 49 CFR 171.8.
International Maritime
:
Organization International
Maritime Dangerous Goods
Code (IMO/IMDG)
Shipping Description: This material is not regulated as a hazardous
material or dangerous goods for transportation.
MARPOL III Status: Not a DOT Marine Pollutant per 49 CFR 171.8.
European Agreements
Concerning the
International Carriage by
Rail (RID) and by Road
(ADR)
:
Shipping Name: This material is not regulated as a hazardous
material or dangerous goods for transportation.
International Civil Aviation :
Organization / International
Air Transport Association
(ICAO/IATA)
Shipping Name: This material is not regulated as a hazardous
material or dangerous goods for transportation.
15. REGULATORY INFORMATION
UNITED STATES FEDERAL REGULATORY INFORMATION
EPA TSCA Inventory
:
This product and/or its components are listed on the Toxic
Substances Control Act (TSCA Inventory).
EPA SARA 302/304
Emergency Planning
and Notification
substance.
:
This material contains the following chemicals subject to reporting
under the Superfund Amendments and Reauthorization Act of
1986 (SARA): Product is not listed as an extremely hazardous
EPA SARA 311/312
(Title III Hazard
Categories)
:
Acute Health: No.
Chronic Health: No.
Fire Hazard: No.
Pressure Hazard: No.
Reactive Hazard: No.
EPA SARA Toxic
:
Chemical Notification
and Release Reporting
(40 CFR 372) and CERCLA
Reportable Quantities
(40 CFR 302.4)
EPA CWA and OPA
:
None.
This product does not contain any substances regulated as
pollutants pursuant to the Clean Water Act (CWA).
This product is considered an oil and is subject to federal oil spill
reporting requirements.
CANADIAN REGULATORY INFORMATION
DSL/NDSL Inventory
:
Workplace Hazardous
:
Materials Information
System (WHMIS) Hazard
Class
This product and/or its constituents are listed either on the Domestic
Substances List (DSL), the Non Domestic Substances List (NDSL)
or are exempt.
This product is not regulated by the WHMIS
EUROPEAN UNION REGULATORY INFORMATION
Labeling
:
Product is not dangerous as defined by the European Union
Dangerous Substances / Preparations Directives
CALIFORNIA PROPOSITION 65:
The following statement is made in order to comply with the California Safe Drinking Water and
Toxic Enforcement Act of 1986. This product contains no chemicals known to the state of California
to cause cancer.
16. OTHER INFORMATION
This safety data sheet relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any other process. Such information
was compiled to the best of the companys knowledge and believed accurate and reliable as of the
date indicated. However, no representation, warranty, or guarantee of any kind, express or implied,
is made to its accuracy, reliability or completeness and we assume no responsibility for any loss,
damage or expense, direct or consequential, arising out of use. It is the users responsibility to
satisfy themselves to the suitability and completeness of such information for his own particular use.
Last revised 8/2014.
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