Table S1. Basic Aerosol characteristics for various regions of the troposphere. Unless otherwise specified, results are from the Hal simulations.
GMD
nm; Dry
GMD
nm; Wet
pH
Na+
nmol m-3
Log(EFBr)
Log(EFCl)
NSS-SO4
nmol m-3
NoHal
NSS-SO4
nmol m-3
Fine
Accum
Coarse
Fine
Accum
Coarse
Fine
Accum
Coarse
Fine
Accum
Coarse
Bulk
Fine
Accum
Coarse
Fine
Accum
Coarse
Fine
Accum
Coarse
Bulk
Fine
Accum
Coarse
Bulk
Med.
48.2
1.1x102
1.0x103
70.9
1.6x102
1.8x103
1.10
1.34
2.81
1.0x10-4
2.9
90.3
93.2
5.2
1.1
-0.8
4.6
1.4
-0.6
0.47
4.7
0.23
5.5
0.48
5.3
0.22
6.1
SFC
Min
20.3
78.8
1.0x103
23.7
83.3
1.3x103
-0.79
-0.55
0.19
0.0
0.2
2.4
2.6
3.6
-0.8
-2.1
3.0
-0.2
-2.4
0.04
0.44
0.02
0.51
0.070
0.60
0.010
0.68
Max
52.8
3.7x102
3.8x103
92.4
4.4x102
4.0x103
3.07
4.26
5.28
2.7x10-3
19.7
7.0x102
7.2x102
7.5
2.4
0.0
7.0
1.6
-0.1
31.2
120
17.8
134
29.3
134
16.3
149
Med.
47.6
1.1x102
1.0x103
74.2
1.6x102
2.0x103
1.00
1.17
2.69
1.0x10-4
2.3
67.1
69.5
5.3
1.1
-0.7
4.6
1.4
-0.6
0.55
4.1
0.20
4.9
0.53
4.7
0.20
5.5
PBL
Min
21.5
82.5
1.0x103
25.0
90.7
1.3x103
-0.70
-0.53
0.19
0.0
0.2
2.5
2.7
3.8
-0.5
-2.1
3.3
0.3
-2.3
0.05
0.49
0.02
0.57
0.073
0.68
0.011
0.78
Max
52.8
3.3x102
3.4x103
95.6
4.2x102
3.5x103
3.08
4.14
5.58
1.9x10-3
14.2
4.8x102
4.9x102
7.6
2.3
0.0
7.0
1.6
-0.2
20.9
91.3
13.2
104
19.8
101
10.3
109
Med.
32.1
1.1x102
1.1x103
38.3
1.3x102
1.4x103
-0.36
-0.20
0.26
0.0
0.3
6.6
6.9
6.2
1.7
-0.4
5.1
1.4
-0.5
0.19
1.4
0.04
1.8
0.20
1.5
0.037
1.8
FT
Min
25.1
89.1
1.0x103
27.8
9.7x101
1.1x103
-0.79
-0.46
-0.21
0.0
0.1
1.2
1.3
5.6
1.5
-0.7
4.5
1.2
-0.8
0.08
0.44
0.01
0.53
0.084
0.52
0.0056
0.62
Max
40.9
2.0x102
1.4x103
55.3
2.7x102
1.6x103
0.00
0.22
0.83
1.0x10-4
1.0
21.1
22.1
7.4
2.0
0.0
6.3
1.5
-0.4
1.7
8.8
0.43
10.3
1.8
9.7
0.43
11.5
Table S2. Aerosol composition for various regions of the atmosphere. Unless otherwise specified, results are from the Hal simulations. Double
dashes indicate a value is undefined.
GMD
nm; Dry
GMD
nm; Wet
pH
Na+
nmol m-3
Log(EFBr)
Log(EFCl)
NSS-SO4
nmol m-3
NoHal
NSS-SO4
nmol m-3
Fine
Accum.
Coarse
Fine
Accum.
Coarse
Fine
Accum.
Coarse
Fine
Accum.
Coarse
Bulk
Fine
Accum.
Coarse
Fine
Accum.
Coarse
Fine
Accum.
Coarse
Bulk
Fine
Accum.
Coarse
Bulk
Med.
35.3
1.1x102
1.1x103
45.7
1.3x102
1.5x103
-0.08
0.08
0.80
0.0
0.8
19.3
20.1
6.1
1.6
-0.5
5.1
1.4
-0.5
0.29
2.0
0.07
2.4
0.31
2.1
0.07
2.5
NH CBL
Min
26.0
88.7
1.0x103
29.2
98.8
1.2x103
-0.71
-0.40
-0.11
0.0
0.1
1.5
1.6
5.5
1.4
-0.8
4.4
1.2
-0.9
0.08
0.46
0.01
0.55
0.084
0.56
7x10-2
0.66
Max
43.2
2.1x102
1.8x103
61.3
3.0x102
1.9x103
0.54
1.03
1.70
5.0x10-4
3.7
1.2x102
1.2x102
7.4
2.1
-0.1
6.5
1.5
-0.4
5.30
24.3
3.12
28.0
5.6
27.2
2.3
29.3
Med.
38.6
1.0x102
1.0x103
53.2
1.3x102
1.7x103
0.09
0.26
1.21
1.x10-4
0.67
13.5
14.1
5.2
1.2
-0.8
4.5
1.1
-0.8
1.36
8.2
0.39
10.0
1.2
7.7
0.34
9.5
SH CBL
Min
0.1
0.1
1.1
0.1
0.2
2.6
-0.79
-0.55
0.0
0.0
0.0
0.03
0.03
1.4
-2.9
-1.2
-1.9
-3.5
0.0
0.0
0.0
0.0
4x10-3
1.2x10-2
0
1.6x10-2
Max
52.7
3.7x102
3.82103
79.9
3.8x102
4.0x103
2.35
2.23
4.44
1.4x10-3
4.9
1.5x102
1.6x102
7.5
2.2
-0.1
6.8
1.6
-0.3
15.41
120.2
14.3
133.7
15.2
134
12.3
149
Med.
46.2
94.9
1.0x103
58.1
1.2x102
1.6x103
0.04
0.51
1.55
0.0
1.0
22.7
23.8
4.6
1.6
-0.6
3.8
1.5
-0.7
0.09
0.65
0.02
0.77
0.14
0.79
0.015
0.95
NH MBL
Min
0.1
0.1
1.1
0.1
0.2
2.1
-0.61
-0.08
0.0
0.0
0.0
0.1
0.1
1.5
-2.0
-3.7
0.9
-1.5
-3.5
0.0
0.0
0.0
0.0
3x10-3
1.5x10-2
0
1.8x10-2
Max
52.7
2.3x102
3.2x103
81.2
2.4x102
3.4x103
2.27
2.25
4.43
1.1x10-3
7.1
1.9x102
2.0x102
7.3
2.4
0.0
6.5
1.6
-0.3
21.43
60.9
2.5
65.5
22.6
69.0
2.8
76.0
Med.
44.8
1.1x102
1.0x103
62.9
1.4x102
1.6x103
0.77
1.09
2.01
0
2.8
91
94
4.7
0.1
-1.6
4.7
1.2
-0.6
0.76
6.5
0.35
7.8
0.72
6.6
0.32
7.8
SH MBL
Min
0.0
0.0
0.0
0.0
0.0
0.0
-0.44
0.0
0.0
0.0
0.0
0.0
0.0
-1.0
---1.7
--0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Max
52.8
2.2x102
1.8x103
91.3
2.9x102
2.3x103
2.34
2.79
4.33
2.6x10-3
11.56
4.7x102
4.8x102
7.3
1.7
-0.2
6.9
1.6
-0.1
31.19
75.7
16.5
104.9
29.3
80.1
16.3
90.6
Table S3. Simulated mixing ratios for various gases across specified regions of the atmosphere from the Hal simulation. Units are in pmol mol-1
unless specified otherwise.
-1
O3 (nmol mol )
OH
HO2
CH3O2
NO
NO2
PAN
Br
Br2
BrO
BrCl
BrNO2
BrNO3
HBr
HOBr
Brt
Cl (cm-3)
Cl2
ClO
ClNO2
ClNO3
HCl
HOCl
Cl*
SO2
DMS
Median
11.0
6.5x10-3
2.0
1.2
3.0
23.0
22.0
0.2
3.3
1.4
3.2
0.02
0.89
1.6
0.54
18.0
6.4x103
1.5
0.14
0.38
0.16
2.0x102
0.4
22.0
29.0
32
Surface
Min
0.99
2.0x10-4
0.17
0.08
0.11
0.20
0.13
2.0x10-4
0.059
0.0026
0.004
1.0x10-4
0.018
0.091
0.011
0.98
22
0.0001
0.0011
1.0x10-4
1.0x10-4
0.47
6.0x10-4
0.029
0.32
3.1x10-3
Max
52.0
0.094
10.0
8.3
1.1x104
1.4x104
5.8x102
2.6
10.0
6.1
16.0
3.3
9.1
13.0
3.8
43.0
8.4x104
35.0
6.0
3.7x102
7.8
2.5z103
37.0
4.1x102
1.3x105
6.8x102
Median
13.0
0.0071
2.3
1.5
2.5
18.0
22.0
0.23
3.3
1.6
3.6
0.019
0.74
1.6.0
0.68
19.0
7.3x103
1.8
0.27
0.29
0.18
1.8x102
0.63
21.0
26
14
PBL
Min
0.99
2.0x10-4
0.17
0.08
0.079
0.2
0.065
2.0x10-4
0.026
0.0026
0.004
0.0
0.018
0.085
0.011
0.98
22
1.00x10-4
0.0011
1.0x10-4
1.0x10-4
0.47
5.0x10-4
0.029
0.09
2.0x10-3
Max
59.0
0.11
12.0
8.3
1.1x104
1.4x104
5.8x102
3.1
10.0
6.3
16.0
3.3
9.1
13.0
3.8
44.0
8.6x104
60.0
7.2
3.7x102
7.8
2.6x103
37.0
4.1x102
1.3x105
6.8x102
Median
46.0
0.027
2.9
0.57
10.0
20.0
1.5x102
0.033
0.2
0.23
0.046
0.0058
0.23
0.71
0.29
2.5
170
0.045
0.025
0.024
0.16
5.4
0.05
0.56
3.3
0.13
FT
Min
1.9
4.0x10-4
0.53
0.049
0.29
0.22
2.1
2.0x10-4
0.0
8.0x10-4
0.0
0.0
6.0x10-4
0.022
0.0021
0.038
0.7
0.0
0.0
0.0
1.0x10-4
3.6x10-2
1.0x10-4
4.0x10-4
0.38
1.3x10-7
Max
6.0x102
0.14
13
5.7
1.1x102
4.6x102
5.7x102
1.9
7.2
4.3
10
1.2
5.7
11.0
2.9
32.0
4.5x104
28.0
10.0
67.0
5.3
1.7x103
19.0
1.0x102
1.0x104
59
Table S4. Simulated mixing ratios for various gases across specified regions of the atmosphere from the Hal simulation. Units are in pmol mol-1
unless specified otherwise.
-1
O3 (nmol mol )
OH
HO2
CH3O2
NO
NO2
PAN
Br
Br2
BrO
BrCl
BrNO2
BrNO3
HBr
HOBr
Brt
Cl (cm-3)
Cl2
ClO
ClNO2
ClNO3
HCl
HOCl
Cl*
SO2
DMS
Median
15.0
0.01
2.1
0.75
35.0
2.9x102
1.3x102
0.036
1.6
0.18
2.9
0.28
3.0
1.6
0.27
13
6.1x103
2.7
0.086
27.0
0.9
140
0.58
39.0
1.3x102
1.2
NH CBL
Min
0.011
0.0
0.0011
0.0007
0.0053
0.031
0.025
1.0x10-4
0.002
8.0x10-4
0.0049
0.0
0.0016
5.0x10-4
4.0x10-4
0.021
3.7
0.002
2.0x10-4
6.0x10-4
4.0x10-4
0.018
1.0x10-4
0.055
0.047
1.8x10-4
Max
48.0
0.09
9.7
7.0
1.0x104
1.4x104
5.8x102
0.8
8.1
3.4
11.0
3.2
7.9
13.0
2.3
35.0
3.4x104
19.0
1.9
3.0x102
6.1
1.8x103
17.0
3.3x102
4.6x104
71
Median
3.8
8.0x10-4
0.73
0.17
1.2
0.47
22.0
0.075
3.0
0.61
0.017
0.0032
0.034
0.24
0.18
7.9
120
0.002
0.0059
0.051
0.0027
5.6
0.0065
0.085
3.4
16
SH CBL
Min
0.0063
0.0
0.0014
0.0004
0.0024
0.0013
0.013
1.0x10-4
0.0032
0.0011
1.0x10-4
0.0
1.0x10-4
3.0x10-4
3.0x10-4
0.016
0.43
0.0
0.0
1.0x10-4
0.0
0.014
0.0
2.0x10-4
5.2x10-3
1.6x10-2
Max
35.0
0.052
10.0
6.9
1.2x103
5.3x103
3.7x102
1.0
5.1
2.4
6.7
2.6
4.1
4.9
1.0
19.0
1.6x104
17.0
1.0
2.5x102
2.1
1.3x103
8.0
2.7x102
1.3x105
2.2x102
Median
14.0
0.011
2.2
2.2
3.0
33.0
15.0
0.083
2.0
0.91
5.5
0.026
1.2
1.4
0.75
17.0
1.3x104
3.9
0.44
2.7
0.27
430
0.73
27.0
28
18
NH MBL
Min
0.0
0.0
0.0
0.0
0.0
0.0
1.0x10-4
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0029
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Max
47.0
0.077
8.9
8.3
3.6x103
7.8x103
3.7x102
0.78
10.0
4.7
16
3.2
9.1
6.7
3.8
43.0
8.4x104
35.0
6.0
2.9x102
7.8
2.5x103
37.0
3.4x102
3.6x104
3.0x102
Median
4.0
0.0022
1.1
1.3
0.74
3.4
8.0
0.4
3.4
2.3
1.3
0.0026
0.36
1.7
0.91
18.0
5.1x103
0.23
0.11
0.024
0.019
1.5x102
0.18
2.8
12
69
SH MBL
Min
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Max
36
0.048
8.3
7.2
2.9x102
1.4x103
2.1x102
2.6
8.0
6.1
11.0
1.3
5.0
5.2
3.7
34
5.5x104
35.0
4.2
79.0
1.2
1.8x103
33.0
1.1x102
6.5x104
5.1x102
Table S5. Simulated mixing ratios for various gases across specified regions of the atmosphere from the NoHal simulation. Units are in pmol mol-1
unless specified otherwise.
-1
O3 (nmol mol )
OH
HO2
CH3O2
NO
NO2
PAN
SO2
DMS
Median
34.0
0.01
2.3
2.0
3.8
30.0
45.0
31
1.1x102
Surface
Min
18.0
0.001
0.19
0.14
0.42
0.98
0.21
0.35
6.1x10-2
Max
64.0
0.10
11.0
9.2
6.0x103
1.7x104
6.7x102
1.3x105
1.1x103
Median
37.0
0.012
2.8
2.0
3.8
25.0
45.0
28
55
PBL
Min
18.0
0.001
0.19
0.14
0.39
0.98
0.16
0.12
2.9x10-3
Max
69.0
0.11
12.0
9.2
6.0x103
1.7x104
6.7x102
1.3x105
1.1x103
Median
67.0
0.034
2.7
0.53
12.0
24.0
1.8x102
3.6
1.2
FT
Min
27.0
0.002
0.44
0.043
0.72
1.4
2.3
0.31
0.0
Max
5.9x102
0.16
13.0
6.5
92.0
4.0x102
6.5x102
9.6x103
1.1x103
Table S6. Simulated mixing ratios for various gases across specified regions of the atmosphere from the NoHal simulation. Units are in pmol mol-1
unless specified otherwise
-1
O3 (nmol mol )
OH
HO2
CH3O2
NO
NO2
PAN
SO2
DMS
Median
37
0.98
2.1
0.83
22
2.6x102
2.0x102
1.4x102
2.2
NH CBL
Min
0.43
0.0
0.14
6.x10-4
0.42
0.35
0.55
0.046
3.0x10-4
Max
Median
64
30
0.94
0.22
9.8
1.0
8.0
0.41
3
6.x10
0.96
1.6x104
1.6
2
6.7x10
45
4
4.6x10
3.8
2
1.0x10 1.7x102
SH CBL
Min
0.35
0.0
0.21
0.11
0.18
0.39
0.26
5.2x10-2
0.02
Max
Median
41
36
0.51
0.17
11
2.0
8.4
2.3
540
4.2
5.2x103
53
2
3.9x10
30
5
1.3x10
28
2
5.2x10
28
NH MBL
Min
0.0
0.0
0.0
0.0
0.0
0.0
2.x10-4
0.0
0.0
Max
Median
59
28
0.83
0.8
8.9
2.3
9.2
2.9
3
1.7x10
1.5
8.x103
14
2
4.5x10
20
4
3.8x10
13
2
3.5x10 2.0x102
SH MBL
Min
0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Max
48
0.56
8.3
8.4
140
1.4x103
2.3x102
6.2x104
9.3x102
Figure S1. ANN zonal-median Brt (pmol mol-1).
Figure S2. ANN HCl (pmol mol-1) for the PBL.
Figure S3. Zonal-median ANN O3 (nmol mol-1) for (a) Hal, (b) NoHal, and (c) Hal versus NoHal percent deviation. .