Unit Packet 5 Ionic Compounds Cost: $1 Prosser Chemistry Name: ___________________ Period: _____ Introduction to Ionic Bonding 1. For the following elements, indicate the orbital notation in the diagram, write the abbreviated electron configuration, identify the element as a metal or a non-metal, indicate whether it will gain or lose electrons to form a stable octet, and identify how many electrons will be transferred in the process. Orbital Notation a. Short Electron Configuration Beryllium (Be) Bonding Habits Metal or Non-metal? Gain or Lose Electrons? # of Electrons: _____ b. Fluorine (F) Metal or Non-metal? Gain or Lose Electrons? # of Electrons: _____ c. Sulfur (S) Metal or Non-metal? Gain or Lose Electrons? # of Electrons: _____ 2. In general, do metals have a tendency to gain or to lose electrons? In general, do non-metals have a tendency to gain or to lose electrons? 3. Fill in the following charts for each element given. Lithium A. Electron configuration B. Number of electrons in the outer energy level C. Will the atom have a tendency to gain or lose electrons? D. How many electrons will be gained or lost? E. If the atom gains or loses the electrons as stated in D above, what will be the net charge on the newly formed ion? Potassium A. Electron configuration B. Number of electrons in the outer energy level Why do lithium and potassium form ions with the same charge? How do their positions on the periodic table relate to this issue? C. Will the atom have a tendency to gain or lose electrons? D. How many electrons will be gained or lost? E. If the atom gains or loses the electrons as stated in D above, what will be the net charge on the newly formed ion? 1 Calcium A. Electron configuration B. Number of electrons in the outer energy level C. Will the atom have a tendency to gain or lose electrons? D. How many electrons will be gained or lost? E. If the atom gains or loses the electrons as stated in D above, what will be the net charge on the newly formed ion? Magnesium A. Electron configuration B. Number of electrons in the outer energy level Why do calcium and magnesium form ions with the same charge? How do their positions on the periodic table relate to this issue? C. Will the atom have a tendency to gain or lose electrons? D. How many electrons will be gained or lost? E. If the atom gains or loses the electrons as stated in D above, what will be the net charge on the newly formed ion? 4. A neutral iron atom loses three electrons to form an ion. a. How many protons does the ion have? ____________ b. How many electrons does the ion have? ____________ c. What is the charge on the ion? ____________ 5. A neutral sulfur atom gains two electrons to form an ion. a. How many protons does the ion have? ____________ b. How many electrons does the ion have? ____________ c. What is the charge on the ion? ____________ d. Where do you think the two electrons came from? 6. Explain how ionic compounds are formed. 2 Forming Ionic Compounds 1. Normally a calcium atom has 20 protons and 20 electrons. How many protons and electrons does a +2 calcium ion have? 2. Normally a sulfur atom has 16 protons and 16 electrons. How many protons and electrons does a -2 sulfur ion have? 3. Predict the formula of the ionic compound which will be formed from each of the following pairs of ions. + 2S _________________ 3+ Cl _________________ Na Fe Ca 2+ O 2- _________________ 2+ Mg F _________________ + Cl _________________ 3+ NO3- _________________ K Fe Na Ca + 2+ 3+ Al SO4 Br O - 2- 2- _________________ _________________ _________________ 4. Predict the formula of the ionic compound which will be formed from each of the following pairs of atoms. (Use your periodic table.) a. K and S b. Ca and F c. Mg and O d. Li and N 3 5. Given the formula CaCO3, if the calcium ion has a +2 charge, what is the charge on the CO 3 ion? 6. Use the following ions to form 10 different compounds. You may use each ion more than once. Na+ S2- I- PO43- NH4+ Zn2+ Fe3+ SO42- a. __________________ b. ___________________ c. __________________ d. ___________________ e. __________________ f. ___________________ g. __________________ h. ___________________ i. __________________ j. ___________________ 4 Name ___________________________ Naming Ionic Compounds This activity will challenge your ability to recognize patterns and apply those patterns to new situations. It will also introduce you to the general rules for naming simple chemical compounds. You will need to use your periodic table and what you now know about how compounds are formed to help you. Part 1 Below are some chemical formulas and their names. NaCl CaCl2 K2 O Al2O3 sodium chloride calcium chloride potassium oxide aluminum oxide MgO Na2S Li3N magnesium oxide sodium sulfide lithium nitride 1. List any patterns you see among the formulas and their names. 2. The first element in each compound is what kind of element? __________________ 3. The second element in each compound is what kind of element? ________________ 4. What kind of bonding is holding these compounds together? __________________ 5. Fill in the blanks in the following rule for naming ionic compounds. Ionic compounds are formed between ions which have ________________ charges. When naming ionic compounds, the name of the ________________ ion goes first. The name of the _____________ ion goes second and it always ends in __________. 6. Try naming the following compounds. NaBr CaF2 BaO Al2S3 7. Now try to write the formulas for the following compounds. potassium chloride calcium bromide sodium sulfide 5 Naming Ionic Compounds (Part 2) Below are some more compounds and their names. FeCl2 FeCl3 Cu2O CuO iron (II) chloride iron (III) chloride copper (I) oxide copper (II) oxide PbO PbO2 lead (II) oxide lead (IV) oxide The patterns for naming these compounds is a little more difficult to see at first. 1. The first element in each compound is a ________________________________. 2. What do you know about the charge of the first elements in these compounds? 3. How are the first elements in these compounds different from the first elements in the compounds in part 1? 4. What type of bonding is holding these compounds together? _______________ 5. How are the names of these compounds different from the names of the ionic compounds in part 1? 6. Remembering that the total charge must equal zero in an ionic compound, what do you think the roman numerals in the names of these compounds stand for? 7. How will you know when to use roman numerals in the name of an ionic compound? 8. Try to name these compounds. FeBr3 NiS CoCl2 9. Now try to write the formulas for the following compounds. copper (I) chloride iron (III) oxide 6 Introduction to Polyatomic Ions Fill in the symbols for the following polyatomic ions: sulfate __________ nitrate ___________ phosphate ___________ hydroxide ________ carbonate ________ bicarbonate __________ ammonium _______ acetate __________ Fill in the blanks in the following table: CATION Ca2+ ANION FORMULA NAME ClMgCO3 ammonium sulfate Fe3+ NO3NaHCO3 tin (IV) oxide SnCl4 manganese (III) oxide Pb2+ S2BaSO4 lead (II) hydroxide AlPO4 K+ ClAgNO3 sodium carbonate Al3+ O2HgO calcium sulfate 7 Naming Ionic Compounds Worksheet 1. Name each of the following ionic compounds. a. MgI2 ________________________________ b. Na2S ________________________________ c. CaBr2 ________________________________ 3. Name the following ionic compounds whose metals do not have a fixed charge. a. CuCl2 ________________________________ b. CoS ________________________________ c. Cu2S ________________________________ 4. Name the following compounds that contain polyatomic ions. a. Na2CO3 ________________________________ b. Mg(NO3)2 ________________________________ c. Cu3PO4 ________________________________ 5. Write the formulas for the following compounds that contain polyatomic ions. a. sodium carbonate ____________________ b. calcium carbonate ____________________ c. iron (II) phosphate ____________________ 6. Write the formulas for the following compounds. a. calcium chloride ____________________ b. magnesium oxide ____________________ c. iron (II) bromide ____________________ d. iron (III) nitrate ____________________ e. iron (III) nitride ____________________ f. lead (IV) oxide ____________________ g. aluminum sulfide ____________________ h. cobalt (III) chloride ____________________ i. cobalt (III) carbonate ____________________ j. aluminum fluoride ____________________ k. lithium sulfate ____________________ 8 l. manganese (II) phosphide ____________________ m. magnesium hydroxide ____________________ 7. Name each of the following compounds. a. MgI2 ________________________________ b. CoS ________________________________ c. Cu2S ________________________________ d. CaO ________________________________ e. AlCl3 ________________________________ f. MnO2 ________________________________ g. BaF2 ________________________________ h. Na2SO4 ________________________________ i. FeCO3 ________________________________ j. Ca3P2 ________________________________ k. MnO2 ________________________________ l. Al2(SO4)3 ________________________________ m. HgO ________________________________ 9 Moles and Formulas 1. Give the name of each of the following compounds. Then calculate the molecular mass for each compound. Name Molecular Mass NH4Cl CaSO4 Fe(OH)3 Fe2(SO4)3 Sr(NO3)2 AlCl3 -4 2. What is the mass of 3.57 x 10 mol of N2O5? 3. How many moles are in 194 g of NH3? 32 4. What is the mass of 8.75 x 10 molecules of C6H8O6? 5. Aspartame is the chemical name for Nutrasweet. Its molecular formula is C 14H18N2O5. a. Find the molecular mass of Nutrasweet. b. If you used 1.50 g of Nutrasweet in a glass of tea, how many moles did you use? 10 Moles and Formulas (Part 2) 1. What is a mole? 2. What is the mass of 1 mole of carbon dioxide - CO2? ___________________ 3. What is the mass of 1 mole of barium nitrate - Ba(NO3)2? ___________________ 4. Give the name of each compound and calculate how many moles are present in each of the following samples. a. 2.0 x 10-3 g of SnO2 name: b. 62.8 g of BaCl2 name: 5. Give the name of each compound and calculate the mass of each of the following samples. a. 5.0 mol of Li2CO3 name: b. 0.054 mol Co(NO3)2 name: 6. Give the formula and find the number of molecules present in the following sample. 0.0908 g of nickel (II) chloride formula: 11
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