Chemistry 12 Unit 5 ACIDS AND BASES SUMMARY NOTES ARRENHIUS THEORY ACID – releases H+ v4.2 BASE – releases OH- BRONSTED-LOWRY THEORY ACID – proton donor BASE – proton acceptor Conjugate pairs differ by one proton (H+) Amphiprotic – can act as an acid or a base (usually negative and have an easily removable hydrogen.) NEUTRALIZATION – Acid + Base Salt + Water ACIDS -taste sour -conduct electricity -turn litmus RED -produce H2(g) when reacting with certain metals (ex. Mg) -neutralized by bases BASES -taste bitter -conduct electricity -turn litmus BLUE -feel slippery -neutralized by acids Both acids and bases conduct electricity, the amount that it conducts depends on the number of ions in solution. More ions = more conductive. (Strong acid/base will have a higher conductivity that weak acids and bases of the same concentration) STRONG ACIDS/BASES – Ionize 100% (not at equilibrium) WEAK ACIDS/BASES – less than 100% ionized (at equilibrium – use ICE chart to solve) Ka/b = [products] [reactants] STRONGER ACIDS AND BASES WILL REACT TO PRODUCE THEIR WEAKER CONJUGATES SELF-IONIZATION OF WATER 2H2O(l) + 59kJ H3O+(aq) + OH-(aq) Kw = [H3O+][OH-] pKw = pH + pOH Kw = 1.00 x 10-14 @ 25oC pH = -log[H3O+] pOH = -log[OH-] [H3O+] = antilog(-pH) [OH-] = antilog(-pOH) pH + pOH = pKw (which is 14.00 @ 25oC) (If temp changes, Kw changes) @25oC pH < 7 = ACIDIC pH = 7 = NEUTRAL pH > 7 = BASIC
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