Microwave Spectra of Molecules of Astrophysical Interest.
XXV. Methylamine
V. Ilyushin
Institute of Radio Astronomy of NASU, Chervonopraporna 4, 61002 Kharkov, Ukraine
F. J. Lovasa…
Optical Technology Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8441
共Received 16 April 2007; revised manuscript received 5 June 2007; accepted 2 July 2007; published online 5 September 2007兲
The microwave spectrum of methylamine in its ground vibrational state is critically
reviewed and supplemented with spectral frequency calculations derived from rotationinternal rotation-inversion analysis. The review covers the frequency range from
1 to 500 GHz and includes the transitions with rotational quantum number J from 0 to
30. The calculated frequency with uncertainty at the 95% confidence limit along with the
lower state energy and line strength are presented. For J 艋 10 transitions and some J
⬎ 10 transitions exhibiting large hyperfine splittings, the quadrupole hyperfine structure is
also tabulated. © 2007 by the U.S. Secretary of Commerce on behalf of the United States.
All rights reserved.. 关DOI: 10.1063/1.2769382兴
Key words: hyperfine structure; interstellar molecule; large amplitude motion; methylamine; microwave
spectrum; radio astronomy; rotational transitions.
CONTENTS
1.
2.
3.
4.
5.
6.
List of Symbols. . . . . . . . . . . . . . . . . . . . . . . . . . .
Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Organization of Tables. . . . . . . . . . . . . . . . . . . . .
3.1. Molecular Parameters. . . . . . . . . . . . . . . . . .
3.2. Microwave Transitions. . . . . . . . . . . . . . . . .
Acknowledgments. . . . . . . . . . . . . . . . . . . . . . . . .
Methylamine Spectral Tables. . . . . . . . . . . . . . . .
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1141
1142
1142
1142
1143
1144
1144
1276
List of Tables
1.
2.
Molecular parameters of the ground torsional
state of methylamine CH3NH2. . . . . . . . . . . . . . . 1145
Microwave transitions of CH3NH2 in order of
frequency. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1145
1. List of Symbols
␣ ⫽ torsional angle of the methyl group
CH3
␥ ⫽ inversion angle of the amine group
NH2
A , B , C ⫽ rotational parameters A 艌 B 艌 C, B̄
= 0.5共B + C兲
a兲
Electronic mail: [email protected]
© 2007 by the U.S. Secretary of Commerce on behalf of the United States.
All rights reserved..
0047-2689/2007/36„3…/1141/136/$42.00
⌬J , ⌬JK , ⌬K , ␦J , ␦K ⫽ quartic
centrifugal
distortion
parameters
centrifugal
distortion
⌽J , ⌽JK , ⌽KJ , ⌽K , ␾K ⫽ sextic
parameters
␹xx , ␹yy , ␹zz ⫽ elements of quadrupole coupling
tensor, ␹+ = ␹zz, ␹− = ␹yy − ␹xx
␳ , ␳K ⫽ internal
rotation
interaction
parameters2
hnV , hnJ , hnK , qn , f n, ⫽ tunneling parameters that describe
etc., n = 2 , 3 , . . .
torsional tunneling motion 共odd n
= 3 , 5 , . . .兲 and inversion tunneling
motion 共even n = 2 , 4 , . . .兲1,2,9,14
␮ , ␮x , ␮y , ␮z ⫽ electric dipole moment and components of the dipole moment along
the molecular-fixed axis system
␮2S ⫽ the product of the square of the dipole moment 共␮2兲 and transition
line strength 共S兲
Wst ⫽ nuclear spin statistical weight
A1, A2, B1, B2, E1±1, ⫽ torsion-inversion-rotation symmeand E2±1
try species representing irreducible
representations of the permutationinversion group G12
J ⫽ rotational angular momentum
quantum number
Ka ⫽ projection of J along the principal
a axis in the limiting prolate symmetric top
F ⫽ total angular momentum quantum
number including the nuclear spin I
from the nitrogen atom
1141
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1142
V. ILYUSHIN AND F. J. LOVAS
Conversion factor ⫽ 1 cm−1 = 29 979.2458 MHz
2. Introduction
The present work is a part of a series of critical reviews on
molecules identified in interstellar molecular clouds. Predicted and observed transition frequencies, energy levels,
and line strengths for methylamine, CH3NH2, are provided
for the frequency range between 1 and 500 GHz and for the
range of quantum numbers 0 艋 J 艋 30 and 0 艋 Ka 艋 15. Also,
since some hyperfine splittings in the methylamine spectrum
can reach values up to 1 MHz, we decided to tabulate the
frequencies of quadrupole hyperfine components for the low
J transitions 共J 艋 10兲 and some J ⬎ 10 transitions exhibiting
large hyperfine splittings. The review is based on the recent
progress in measuring, assigning, and fitting of the rotational
spectrum of the ground vibrational state of methylamine,1
CH3NH2, a spectrum complicated by both internal rotation
of the methyl top and inversion of amino group. The phenomenological Hamiltonian used in the present work is
based on the group-theoretical high-barrier tunneling formalism developed for methylamine by Ohashi and Hougen.2 The
model in use includes 53 parameters whose values were determined from the fit of 850 far-infrared and 696 microwave
transitions in the ground state. In this fit almost all observed
spectral lines are reproduced to within their measurement
uncertainties and the overall weighted standard deviation of
0.8 is achieved.
3. Organization of Tables
In the following subsections we describe the molecular
constants employed in the analysis as well as a procedure for
the line strength calculation in the group-theoretical highbarrier tunneling formalism used for methylamine. Also we
discuss the format of Table 2 containing the microwave transitions of CH3NH2 in order of frequency and different limits
adopted for calculation of the transitions to keep this table at
reasonable length.
3.1. Molecular Parameters
The parameters of the rotation-internal rotation-inversion
Hamiltonian presented in Table 1 were obtained from a nonlinear least-squares fit of 850 far-infrared and 696 microwave
transitions in the ground vibrational state of methylamine
12
CH314NH2. The fit uses the group-theoretical high-barrier
tunneling formalism developed for methylamine by Ohashi
and Hougen.2 This formalism describes the large amplitude
vibrational motions in terms of tunneling frequencies and
tunneling paths between energetically equivalent molecular
frameworks separated by barriers hindering internal rotation
of the methyl top and inversion of the amino group. The
tunneling formalism proved to be most efficient in the case
when several large amplitude vibrations are present in a molecule. In addition to the rotation-internal rotation-inversion
Hamiltonian parameters, Table 1 contains the quadrupole
coupling constants for methylamine obtained from the non-
linear least-squares fit of 893 hyperfine components. Ilyushin
et al.1 describe in detail the analysis of the observed quadrupole hyperfine structure of the microwave transitions.
The global fit of the observed transitions to 53 parameters
of the rotation-internal rotation-inversion Hamiltonian in use
is slightly different from the previous fit described by Ilyushin et al.1 In the course of preparation of the current review, we have noticed that some of the old microwave
measurements3–8 summarized by Ohashi et al.9 and used by
Ilyushin et al.1 were rounded up to the megahertz digit 共following Ohashi et al.9 this group of measurements was used
by Ilyushin et al.1 with uncertainty of 1 MHz兲. In the current
fit we replaced these rounded frequencies by the original
unrounded measured values.3–8 In addition an inspection of
the tables with the old measurements3–8 gave us an opportunity to assign 24 new lines. Also we decided to assign an
uncertainty of 0.5 MHz for the group of measurements used
previously1 with uncertainty of 1 MHz since after the refit
described here, only a small fraction of transitions in this
group had observed minus calculated values larger than
0.5 MHz. The rms deviation for this group of data has reduced from 0.403 MHz in the study of Ilyushin et al.1 to
0.315 MHz in the current fit. All other groups of
measurements1,10,11 were weighted as described by Ilyushin
et al.1 共the weights in the fit were proportional to the reciprocals of the estimated uncertainties squared兲 and rms deviations for the other groups remained practically the same as in
the study of Ilyushin et al.1 共see Table 2 by Ilyushin et al.1兲.
The set of 53 parameters of the rotation-internal rotationinversion Hamiltonian used was the same as that by Ilyushin
et al.1 and the new parameter values obtained here differ
from those of Ilyushin et al.1 within statistical uncertainties.
The fitting program used by Ilyushin et al.1 共supplied by
Ohashi12兲 was modified to provide the line strength calculations for methylamine transitions. The total line strength of a
microwave transition between the level L⬘ containing 共2J⬘
+ 1兲M ⬘ components and the level L containing 共2J + 1兲M
components is calculated as
S共L⬘,L兲 =
1
兺 3兩具J⬘,Ka⬘,⌫⬘,M兩␮Z兩J,Ka,⌫,M典兩2 ,
␮2 M
共1兲
where ␮2 is the square of the electric dipole moment; ␮Z
= 兺g⌽Zg␮g is the instantaneous electric dipole moment component along the laboratory-fixed Z axis 共the ⌽Zg represent
direction cosines and ␮g the electric dipole moment component along the molecular-fixed g = x , y , z axis兲; 兩J , Ka , ⌫ , M典
and 兩J⬘ , Ka⬘ , ⌫⬘ , M典 are the wave functions that represent levels L⬘ and L. The overall torsion-inversion-rotation wave
function 兩J , Ka , ⌫ , M典 can be written as
a,⌫兩⌫共kJ兲典,
兩J,Ka,⌫,M典 = 兺 CJ,K
k
共2兲
k
where 兩⌫共kJ兲典 are torsion-inversion-rotation basis functions
used to set up the Hamiltonian matrix which are the combinations of 兩 twEt典 torsion-inversion wave functions and symmetric rotor basis functions 兩J , K , M典 关explicit expressions
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MICROWAVE SPECTRA OF METHYLAMINE
for the 兩⌫共kJ兲典 torsion-inversion-rotation basis functions can
a,⌫ are eigenbe found in the study by Ohashi et al.9兴; CJ,K
k
vector coefficients obtained after diagonalization of the
Hamiltonian matrix. In view of the large amplitude internal
rotation of the methyl top and inversion of amino group, the
electric dipole moment components along molecular-fixed
axes ␮g = ␮g共␣ , ␥兲 are considered as functions of the methyl
torsion angle ␣ and amino umbrella angle ␥. So, the line
strength can be expressed as
S共L⬘,L兲 =
1
兺3
␮2 M
冏兺 兺 兺
g
k⬘
k
J ,Ka⬘,⌫⬘ J,Ka,⌫
Ck
⬘
C k⬘
⫻具⌫⬘共k⬘J⬘兲兩␮g共␣, ␥兲⌽Zg兩⌫共kJ兲典
冏
2
,
共3兲
where 具⌫⬘共k⬘J⬘兲兩␮g⌽Zg兩⌫共kJ兲典 is a combination of the terms
of the 具J⬘ , K⬘ , M兩⌽Zg兩J , K , M典具 twEt 兩␮g共␣ , ␥兲兩 twEt典 type 共see
⬘
the study by Ohashi et al.9 for more details on the exact
expressions of the basis functions used to set up the Hamiltonian matrix兲. The expressions for the direction cosine matrix elements 具J⬘ , K⬘ , M兩⌽Zg兩J , K , M典 can be found
elsewhere13 and the dipole moment matrix elements
具 twEt 兩␮g共␣ , ␥兲兩 twEt典 are expressed as Fourier expansions as
⬘
usually done for all Hamiltonian terms in the grouptheoretical high-barrier tunneling formalism in use.1,2,9,14
The molecular-fixed components of the dipole moment
␮x , ␮y are of species E3m−p and that of ␮z is of species A1 in
m
the extended permutation-inversion group G12
used in the
2
present treatment. The Fourier series expression for the
␮x ± i␮y 共a combination of ␮x , ␮y components which is not
m 2
兲 bemixed by the generating operations of the group G12
comes
具 Eu+兩␮x ± i␮y兩 Et+典
tw
tw
冋冉
3m−1
= 具1储␮±储1典 + 2
兺 具1储␮±储1 + n典cos
n=1
t±
冊 册
3m − p 2␲
n
6m
2
+ ␦3m−p,even共− 1兲t+共3m−p兲/2具1储␮±储1 + 3m典,
共4兲
when subscripts on the symmetry species obey the selection
rules t = u ⫿ 共3m − p兲 modulo 6m and which is zero otherwise.
For the ␮z component we have
3m−1
具 twEu+兩␮z兩 twEt+典 = 具1储␮z储1典 + 2
冋
兺
n=1
⫻cos 共n − 1兲t
具1储␮z储1 + n典
册
2␲
+ 共− 1兲t具1储␮z储1 + 3m典,
6m
共5兲
when subscripts on the symmetry species obey the selection
rules u − t = 0 modulo 6m and which is zero otherwise.
In the terminology of Ohashi and Hougen,2 there are both
tunneling
and
nontunneling
contributions
to
具 twEt 兩␮g共␣ , ␥兲兩 twEt典 matrix elements. We do not have any
⬘
information on the tunneling contributions of dipole moment
matrix elements and therefore they were set to zero for in-
1143
tensity calculations in the present review. The choice of nontunneling contributions is suggested by the fact that in the
absence of Coriolis interactions, the ⌬Ka = 0 transitions are
caused by the ␮z component and ⌬Ka = ± 1 transitions are
caused by the ␮x ± i␮y component 共see discussion in Sec. 6 of
the study of Ohashi and Hougen2兲. Our calculations show
that mixing due to Coriolis interactions of ␮z and ␮x ± i␮y
contributions in methylamine is rather small, so that the situation essentially corresponds to the ordinary asymmetric rotor with nonzero ␮a and ␮c components where the ⌬Ka = 0
transitions occur due to the ␮a component and ⌬Ka = ± 1
transitions occur due to the ␮c component. Therefore we
took the nontunneling contribution of dipole moment matrix
elements to be 具1储␮z储1典 = ␮a and 具1储␮±储1典 = ␮c. This correspondence is also supported by the fact that the s term of the
Hamiltonian in use, which is responsible for the off-diagonal
contributions to the moment of inertia tensor due to the
internal-axis-method treatment of internal rotation in
methylamine,14 was not required by the final fit;1 thus, the
pure rotational part of the Hamiltonian corresponds to the
principal axis system of the molecule. For the corresponding
matrix element values in our calculations, we used
具1储␮z储1典 = −0.307 D, 具1储␮±储1典 = 1.258 D, and ␮2 = 1.677 D2
as obtained, respectively, for ␮a and ␮c via Stark effect measurements by Lide, Jr.15 and corrected by Takagi and
Kojima.7
3.2. Microwave Transitions
Table 2 contains the predicted and observed rotational
transitions for methylamine. For each spectral line, the first
eight columns contain the upper state and lower state quantum numbers in the form J, Ka, and ⌫, plus the total angular
momentum quantum number F = J + I, J + I − 1, J − I, where I
is the nuclear spin angular momentum quantum number for
the 14N nucleus, with I = 1. According to the adopted energy
level labeling scheme,9 each vibration-rotation-tunneling energy level is characterized by the usual quantum numbers J
and Ka and by an overall torsion-inversion-rotation symmetry species ⌫ corresponding to an irreducible representation
of the permutation-inversion group G12. The labels of the
irreducible representations of the point group C6␯, which is
isomorphic with G12, are used as the symbols for ⌫’s, i.e.,
A1, A2, B1, B2, E1, and E2. The symmetry labels of doubly
degenerate levels E1 and E2 have additional ±1 labels to
distinguish between two degenerate levels with the same J
and Ka 共see discussion by Ohashi et al.9兲. For the Ka = 0
levels where +1 and −1 labels have no meaning since there
are only one E1 and one E2 levels, it was arbitrarily chosen to
call all Ka = 0 E levels as +1 levels. In the case when a
measured line corresponds to the unresolved pair of the transitions J , Ka , A1 ← J⬘, Ka⬘ , A2 and J , Ka , A2 ← J⬘, Ka⬘ , A1 共or
J , Ka , B1 ← J⬘, Ka⬘ , B2 and J , Ka , B2 ← J⬘, Ka⬘ , B1兲 the labels ⌫
= A 共or B兲 appear in Table 2 to note that the average of the
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1144
V. ILYUSHIN AND F. J. LOVAS
two transition frequencies is considered. The labels ⌫ = A 共or
B兲 appear only for measured lines and, for completeness in
the current review, we give the calculated frequencies for the
unresolved transitions also.
The quantum numbers for a given transition are followed
by the observed frequency, when available, with experimentally estimated uncertainty 共type B, k = 1兲16 in parentheses in
megahertz. We present the hyperfine free rotational transition
frequencies which were used in the final fit of the rotationinternal rotation-inversion Hamiltonian parameters presented
in Table 1. In the next column the calculated transition frequencies with calculated uncertainties in parentheses are presented, which were computed using the molecular parameters from Table 1. The calculated uncertainties were
estimated from the variance-covariance matrix as described
by Kirchhoff17 and correspond approximately to 95% confidence interval 共i.e., type A, k = 2, representing twice the standard deviation兲.16 The next two columns represent the energy
of the lower state 共El兲 in cm−1 and the product ␮2S of the
square of the dipole moment 共␮2兲 and transition line strength
共S兲, calculated as discussed in the previous section 关see expression 共1兲兴. The ␮2S value for each transition is followed
by the nuclear spin statistical weight 共Wst兲 which equals 1 for
A1, A2, and E2 species and equals 3 for B1, B2, and E1
species. The last column gives the reference from which the
measurements included in Table 2 were obtained.
As was already mentioned, the hyperfine quadrupole splittings in methylamine spectrum can reach values up to
1 MHz and therefore we decided to tabulate the frequencies
of quadrupole hyperfine components for the low J transitions
共J 艋 10兲 and some J ⬎ 10 transitions exhibiting large hyperfine splittings. For J ⬎ 10 transitions the hyperfine components are presented only if the quadrupole splitting exceeds
an estimated linewidth observed for interstellar lines 共recalculated from km s−1 to megahertz for a given transition frequency兲. As a typical linewidth we took 3 km s−1 which is
equal to 共or less than兲 the linewidths observed in such
sources as Orion KL and Sgr B2 where methylamine lines
were detected.18,19 Also, to limit the size of Table 2, we have
presented only the most intense hyperfine quadrupole components for which the relative intensities exceeded 5% of the
total intensity of the rotation transition 共i.e., mainly with the
selection rule ⌬F = ⌬J兲. The expressions used for the relative
intensities of the quadrupole hyperfine components can be
found elsewhere.20 For the quadrupole components, the line
strength column contains the product of the ␮2S for a given
rotational transition and relative intensity of the quadrupole
component.
The rotational transitions in the ground vibrational state of
methylamine obeying the symmetry selection rules A1 ↔ A2,
B1 ↔ B2, E1 ↔ E1, and E2 ↔ E2 were calculated for the range
of rotational quantum numbers 0 艋 J 艋 30 and 0 艋 Ka 艋 15.
We have included in the calculation rotational transitions
with rotational selection rules ⌬J = 0 , ± 1 and ⌬Ka
= 0 , ± 1 , ± 2 , ± 3. In Table 2, those transitions which match
the frequency range requirement 共from 1 to 500 GHz兲 and
whose line strength exceeds the limit of 0.01 are included.
The transitions in Table 2 are sorted in order of frequency
with hyperfine quadrupole components following the corresponding rotational transition. As a convenience to the user,
an asterisk 共 *兲 follows the calculated uncertainty of the pure
rotational transition to distinguish more easily the calculated
frequencies of the rotational transitions from hyperfine quadrupole components 共also note that the upper state and lower
state quantum numbers in the case of rotational transitions do
not contain the total angular momentum quantum number F兲.
4. Acknowledgments
The authors are indebted to Dr. J. Hougen for helpful discussions and suggestions regarding intensity calculations in
the group-theoretical high-barrier tunneling formalism developed for methylamine and to Dr. N. Ohashi for providing his
fitting program for methylamine.
5. Methylamine Spectral Tables
The molecular parameters obtained from the global fit of
the rotational spectrum of methylamine in the ground vibrational state are given in Table 1. The calculated spectrum for
the ground vibrational state of methylamine is given in Table
2. References to the experimental data shown in Table 2 can
be found in Sec. 6.
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MICROWAVE SPECTRA OF METHYLAMINE
1145
TABLE 1. Molecular parameters of the ground torsional state of methylamine CH3NH2 关parameter values are given in megahertz except for ␳ and ␳K which
are unitless, statistical uncertainties are shown as one standard uncertainty 共type A, k = 1兲16 in units of the last digits兴
Rotationala
Inversionb
Torsionalc
B̄
22 169.366 36共30兲
h2V
−1 549.186 21共77兲
h3V
A − B̄
B−C
⌬J
⌬JK
⌬K
80 986.382 3共11兲
h4V
2.731 86共96兲
h5V
⌽J
⌽JK
⌽KJ
⌽K
␾K
877.877 17共53兲
0.039 451 0共18兲
0.170 986共15兲
0.701 044共24兲
0.001 756 73共17兲
−0.337 72共13兲
−0.000 000 048 5共16兲
0.000 002 442共50兲
−0.000 008 55共10兲
0.000 033 22共29兲
0.000 236 6共48兲
␳
␳K
0.649 760 23共13兲
−0.000 001 160 1共77兲
␹+
␹−
−2.413 6共12兲
6.064 6共24兲
␦J
␦K
h2J
h2K
h4K
h2JJ
h2KK
h2JK
h2JKK
q2
q4
q2J
q2K
q2JJ
q2KK
f2
f4
f 2J
f 2K
f 2KK
f 共2兲
2
r2
r2K
0.101 759共11兲
1.739 55共16兲
−0.004 778共37兲
−0.000 005 466共88兲
−0.000 901 6共63兲
−0.000 154 00共94兲
0.000 000 192 3共56兲
21.549 23共52兲
−0.030 71共20兲
−0.003 736 8共45兲
−0.019 676共43兲
0.000 002 098共62兲
0.000 010 23共54兲
−0.096 739共38兲
0.000 215 3共39兲
0.000 004 452共67兲
0.001 188共37兲
−0.000 001 600共47兲
−0.000 002 443共55兲
10.979共37兲
−0.720 6共73兲
−2 493.514 0共12兲
2.883 98共55兲
h3J
h5J
h3K
h5K
h3JJ
h3KK
h3JJK
f3
f 3J
f 3K
f 3JK
f 共2兲
3
共2兲
f 3J
−0.052 546共20兲
0.000 228 2共55兲
1.166 76共22兲
−0.002 667共73兲
−0.000 017 296共44兲
−0.000 299 5共42兲
−0.000 000 047 02共67兲
−0.173 439共24兲
−0.000 002 61共13兲
−0.000 135 9共32兲
−0.000 000 064 6共27兲
−0.000 003 021共89兲
0.000 000 002 20共13兲
a
These parameters do not involve tunneling motions.
These parameters arise from the NH2 inversion tunneling motion.
c
These parameters arise from the CH3 torsional tunneling motion.
b
TABLE 2. Microwave transitions of CH3NH2 in order of frequency
J⬘
K⬘a
⌫⬘
16
16
16
16
27
27
27
27
27
27
27
27
17
17
17
17
17
17
17
17
17
17
17
17
8
3
3
3
3
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
0
0
0
0
2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
F⬘
16
17
15
27
28
26
27
28
26
17
18
16
17
18
16
16
18
17
J⬙
K⬙a
⌫⬙
17
17
17
17
27
27
27
27
27
27
27
27
17
17
17
17
17
17
17
17
16
16
16
16
8
0
0
0
0
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
B1
B1
B1
B1
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
F⬙
17
18
16
27
28
26
27
28
26
17
18
16
17
16
15
17
16
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
1 111.760 共0.031兲*
1 111.066 共0.031兲
1 112.081 共0.031兲
1 112.138 共0.031兲
1 197.223 共0.031兲*
1 197.201 共0.031兲
1 197.233 共0.031兲
1 197.234 共0.031兲
1 222.140 共0.031兲*
1 222.118 共0.031兲
1 222.151 共0.031兲
1 222.152 共0.031兲
1 369.183 共0.014兲*
1 369.138 共0.014兲
1 369.204 共0.014兲
1 369.208 共0.014兲
1 398.049 共0.013兲*
1 398.002 共0.013兲
1 398.070 共0.013兲
1 398.074 共0.013兲
1 423.321 共0.033兲*
1 422.950 共0.033兲
1 423.006 共0.033兲
1 424.003 共0.033兲
1 449.601 共0.005兲*
El
共cm−1兲
␮ 2S
共D2兲
Wst
225.687
225.687
225.687
225.687
602.056
602.056
602.056
602.056
601.883
601.883
601.883
601.883
250.966
250.966
250.966
250.966
250.869
250.869
250.869
250.869
225.639
225.639
225.639
225.639
64.436
0.056
0.018
0.020
0.017
0.108
0.036
0.037
0.035
0.107
0.036
0.037
0.034
0.096
0.032
0.034
0.030
0.096
0.032
0.034
0.030
0.024
0.007
0.008
0.008
0.090
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1146
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
8
8
8
13
13
13
13
8
8
8
8
19
19
19
19
28
28
28
28
28
28
28
28
8
8
8
8
18
18
18
18
18
18
18
18
7
7
7
7
29
29
29
29
29
29
29
29
1
1
1
1
1
1
9
9
9
9
2
2
2
3
3
3
3
2
2
2
2
6
6
6
6
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
4
4
4
4
4
4
4
4
1
1
1
1
1
1
2
2
2
2
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
A1
A1
A1
A1
B1
B1
B1
B1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
A2
A2
A2
A2
A2
A2
A2
A2
A2
A2
8
9
7
8
8
8
12
12
12
12
8
8
8
8
20
20
20
20
28
28
28
28
28
28
28
28
9
9
9
9
18
18
18
18
18
18
18
18
7
7
7
7
29
29
29
29
29
29
29
29
2
2
2
2
2
2
9
9
9
9
2
2
2
4
4
4
4
2
2
2
2
5
5
5
5
4
4
4
4
4
4
4
4
2
2
2
2
3
3
3
3
3
3
3
3
2
2
2
2
4
4
4
4
4
4
4
4
0
0
0
0
0
0
2
2
2
2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
A2
A2
A2
A2
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
B1
B1
B1
B1
A1
A1
A1
A1
A1
A1
A1
A1
A1
A1
8
12
14
13
8
9
7
19
20
18
28
29
27
28
29
27
8
7
9
18
19
17
18
19
17
7
8
6
29
30
28
29
30
28
1
1
2
2
0
9
10
8
7
11
13
12
8
9
7
20
21
19
28
29
27
28
29
27
9
8
10
18
19
17
18
19
17
7
8
6
29
30
28
29
30
28
2
1
2
3
1
9
10
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
1 449.463 共0.005兲
1 449.659 共0.005兲
1 449.684 共0.005兲
1 458.564 共0.009兲*
1 458.527 共0.009兲
1 458.531 共0.009兲
1 458.632 共0.009兲
1 467.694 共0.005兲*
1 467.555 共0.005兲
1 467.753 共0.005兲
1 467.778 共0.005兲
1 580.521 共0.012兲*
1 580.470 共0.012兲
1 580.545 共0.012兲
1 580.547 共0.012兲
1 586.903 共0.042兲*
1 586.876 共0.042兲
1 586.915 共0.042兲
1 586.916 共0.042兲
1 619.633 共0.041兲*
1 619.606 共0.041兲
1 619.646 共0.041兲
1 619.647 共0.041兲
1 626.131 共0.009兲*
1 626.109 共0.009兲
1 626.140 共0.009兲
1 626.143 共0.009兲
1 909.138 共0.019兲*
1 909.082 共0.019兲
1 909.165 共0.019兲
1 909.169 共0.019兲
1 949.112 共0.018兲*
1 949.054 共0.018兲
1 949.139 共0.018兲
1 949.143 共0.018兲
1 954.821 共0.008兲*
1 954.768 共0.008兲
1 954.842 共0.008兲
1 954.853 共0.008兲
2 081.166 共0.054兲*
2 081.134 共0.054兲
2 081.181 共0.054兲
2 081.183 共0.054兲
2 123.670 共0.054兲*
2 123.637 共0.054兲
2 123.685 共0.054兲
2 123.687 共0.054兲
2 166.305 共0.008兲*
2 164.634 共0.008兲
2 165.857 共0.008兲
2 165.906 共0.008兲
2 166.692 共0.008兲
2 169.036 共0.008兲
2 272.403 共0.007兲*
2 272.231 共0.007兲
2 272.477 共0.007兲
2 272.504 共0.007兲
64.436
64.436
64.436
158.845
158.845
158.845
158.845
64.473
64.473
64.473
64.473
378.284
378.284
378.284
378.284
643.397
643.397
643.397
643.397
643.225
643.225
643.225
643.225
77.814
77.814
77.814
77.814
277.574
277.574
277.574
277.574
277.478
277.478
277.478
277.478
52.393
52.393
52.393
52.393
686.209
686.209
686.209
686.209
686.038
686.038
686.038
686.038
4.437
4.437
4.437
4.437
4.437
4.437
77.738
77.738
77.738
77.738
0.029
0.033
0.026
2.751
0.844
0.985
0.912
0.088
0.028
0.032
0.025
4.158
1.383
1.454
1.315
0.104
0.034
0.036
0.033
0.103
0.034
0.036
0.033
1.855
0.611
0.546
0.683
0.090
0.030
0.032
0.028
0.091
0.030
0.032
0.029
0.022
0.007
0.008
0.006
0.100
0.033
0.034
0.032
0.099
0.033
0.034
0.032
0.779
0.195
0.065
0.065
0.364
0.087
0.080
0.026
0.029
0.024
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1147
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
8
8
8
8
9
9
9
9
19
19
19
19
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
19
19
19
19
30
30
30
30
17
17
17
17
30
30
30
30
9
9
9
9
30
30
30
30
30
30
30
30
18
2
2
2
2
2
2
2
2
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
4
4
4
4
3
3
3
3
4
4
4
4
2
2
2
2
1
1
1
1
1
1
1
1
3
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B2
B2
B2
B2
A1
A1
A1
A1
A1
A1
A1
A1
B1
B1
B1
B1
B1
B1
B1
B1
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
F⬘
8
9
7
9
10
8
19
20
18
2
3
1
2
3
2
1
2
3
1
2
3
2
1
19
20
18
30
31
29
17
18
16
30
31
29
9
10
8
29
31
30
29
31
30
J⬙
K⬙a
⌫⬙
8
8
8
8
9
9
9
9
19
19
19
19
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
19
19
19
19
30
30
30
30
17
17
17
17
30
30
30
30
9
9
9
9
30
30
30
30
30
30
30
30
18
2
2
2
2
2
2
2
2
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
4
4
4
4
3
3
3
3
4
4
4
4
2
2
2
2
0
0
0
0
0
0
0
0
3
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B1
B1
B1
B1
A2
A2
A2
A2
A2
A2
A2
A2
B2
B2
B2
B2
B2
B2
B2
B2
A1
A1
A1
A1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
8
9
7
9
10
8
19
20
18
2
2
2
3
3
1
1
2
2
2
3
3
1
1
19
20
18
30
31
29
17
18
16
30
31
29
9
10
8
3 015.170 共0.500兲
29
31
30
29
31
30
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
2 299.900 共0.008兲*
2 299.804 共0.008兲
2 299.940 共0.008兲
2 299.958 共0.008兲
2 300.591 共0.007兲*
2 300.416 共0.007兲
2 300.666 共0.007兲
2 300.694 共0.007兲
2 612.776 共0.026兲*
2 612.706 共0.026兲
2 612.808 共0.026兲
2 612.814 共0.026兲
2 639.492 共0.002兲*
2 637.975 共0.002兲
2 638.562 共0.002兲
2 638.888 共0.002兲
2 639.338 共0.002兲
2 639.925 共0.002兲
2 640.095 共0.002兲
2 641.008 共0.002兲
2 644.074 共0.002兲*
2 642.557 共0.002兲
2 643.144 共0.002兲
2 643.470 共0.002兲
2 643.920 共0.002兲
2 644.507 共0.002兲
2 644.677 共0.002兲
2 645.590 共0.002兲
2 667.055 共0.025兲*
2 666.984 共0.025兲
2 667.088 共0.025兲
2 667.094 共0.025兲
2 702.214 共0.071兲*
2 702.175 共0.071兲
2 702.233 共0.071兲
2 702.235 共0.071兲
2 716.776 共0.015兲*
2 716.755 共0.015兲
2 716.786 共0.015兲
2 716.788 共0.015兲
2 756.813 共0.070兲*
2 756.773 共0.070兲
2 756.832 共0.070兲
2 756.834 共0.070兲
2 943.254 共0.008兲*
2 943.106 共0.008兲
2 943.317 共0.008兲
2 943.341 共0.008兲
3 014.962 共0.285兲*
3 014.933 共0.285兲
3 014.935 共0.285兲
3 015.018 共0.285兲
3 020.581 共0.156兲*
3 020.556 共0.156兲
3 020.559 共0.156兲
3 020.629 共0.156兲
3 029.884 共0.018兲*
64.223
64.223
64.223
64.223
77.775
77.775
77.775
77.775
305.658
305.658
305.658
305.658
7.408
7.408
7.408
7.408
7.408
7.408
7.408
7.408
7.249
7.249
7.249
7.249
7.249
7.249
7.249
7.249
305.563
305.563
305.563
305.563
730.490
730.490
730.490
730.490
250.776
250.776
250.776
250.776
730.321
730.321
730.321
730.321
77.529
77.529
77.529
77.529
681.003
681.003
681.003
681.003
681.090
681.090
681.090
681.090
277.390
0.039
0.013
0.014
0.011
0.078
0.025
0.028
0.023
0.085
0.028
0.030
0.027
0.078
0.018
0.004
0.004
0.004
0.032
0.004
0.012
0.080
0.018
0.004
0.004
0.004
0.033
0.004
0.012
0.086
0.029
0.030
0.027
0.096
0.032
0.033
0.031
0.026
0.008
0.009
0.008
0.096
0.032
0.033
0.031
0.052
0.017
0.019
0.015
79.151
25.490
27.220
26.327
79.339
25.551
27.285
26.390
0.038
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
Ref.
5
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1148
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
18
18
18
19
19
19
19
10
10
10
10
10
10
10
10
8
8
8
8
20
20
20
20
19
19
19
19
20
20
20
20
19
19
19
19
8
8
8
8
8
8
8
8
29
29
29
29
10
10
10
10
29
29
29
29
24
24
3
3
3
6
6
6
6
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
6
6
6
6
3
3
3
3
3
3
3
3
1
1
1
1
2
2
2
2
1
1
1
1
6
6
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
B1
B1
B1
B1
B1
B1
B1
B1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E2 − 1
E2 − 1
18
19
17
18
18
18
20
20
20
20
10
10
10
10
10
10
10
10
9
9
9
9
20
20
20
20
19
19
19
19
20
20
20
20
20
20
20
20
9
9
9
9
9
9
9
9
29
29
29
29
10
10
10
10
29
29
29
29
23
23
3
3
3
5
5
5
5
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
5
5
5
5
2
2
2
2
2
2
2
2
0
0
0
0
2
2
2
2
0
0
0
0
7
7
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
B2
B2
B2
B2
B2
B2
B2
B2
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E2 − 1
E2 − 1
18
19
17
19
20
18
10
11
9
10
11
9
8
7
9
20
21
19
19
20
18
20
21
19
19
20
18
8
9
7
8
7
9
28
30
29
10
11
9
28
30
29
23
Obs. Freq. 共unc.兲
共MHz兲
20
21
19
10
11
9
10
11
9
9
8
10
20
21
19
19
20
18
20
21
19
20
21
19
9
10
8
9
8
10
28
30
29
10
11
9
4 076.650 共0.500兲
28
30
29
22
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
3 029.849 共0.018兲
3 029.900 共0.018兲
3 029.903 共0.018兲
3 224.656 共0.012兲*
3 224.606 共0.012兲
3 224.680 共0.012兲
3 224.683 共0.012兲
3 397.541 共0.011兲*
3 397.331 共0.011兲
3 397.633 共0.011兲
3 397.663 共0.011兲
3 439.348 共0.011兲*
3 439.135 共0.011兲
3 439.440 共0.011兲
3 439.471 共0.011兲
3 482.673 共0.008兲*
3 482.654 共0.008兲
3 482.680 共0.008兲
3 482.684 共0.008兲
3 515.789 共0.034兲*
3 515.704 共0.034兲
3 515.828 共0.034兲
3 515.835 共0.034兲
3 527.441 共0.024兲*
3 527.389 共0.024兲
3 527.465 共0.024兲
3 527.469 共0.024兲
3 588.178 共0.033兲*
3 588.092 共0.033兲
3 588.219 共0.033兲
3 588.225 共0.033兲
3 691.665 共0.011兲*
3 691.615 共0.011兲
3 691.690 共0.011兲
3 691.692 共0.011兲
3 881.573 共0.010兲*
3 881.382 共0.010兲
3 881.658 共0.010兲
3 881.682 共0.010兲
3 913.781 共0.008兲*
3 913.752 共0.008兲
3 913.793 共0.008兲
3 913.796 共0.008兲
3 923.735 共0.138兲*
3 923.705 共0.138兲
3 923.708 共0.138兲
3 923.792 共0.138兲
3 963.165 共0.010兲*
3 962.965 共0.010兲
3 963.251 共0.010兲
3 963.280 共0.010兲
4 076.296 共0.250兲*
4 076.262 共0.250兲
4 076.265 共0.250兲
4 076.362 共0.250兲
4 098.057 共0.014兲*
4 098.036 共0.014兲
277.390
277.390
277.390
378.322
378.322
378.322
378.322
92.516
92.516
92.516
92.516
92.553
92.553
92.553
92.553
77.852
77.852
77.852
77.852
335.217
335.217
335.217
335.217
305.478
305.478
305.478
305.478
335.122
335.122
335.122
335.122
378.087
378.087
378.087
378.087
77.738
77.738
77.738
77.738
77.627
77.627
77.627
77.627
637.437
637.437
637.437
637.437
92.309
92.309
92.309
92.309
637.344
637.344
637.344
637.344
540.301
540.301
0.013
0.013
0.012
4.152
1.381
1.452
1.313
0.073
0.024
0.026
0.022
0.070
0.023
0.025
0.021
1.852
0.610
0.545
0.682
0.081
0.027
0.028
0.026
0.049
0.016
0.017
0.016
0.081
0.027
0.028
0.026
4.161
1.383
1.455
1.316
1.848
0.608
0.681
0.543
0.383
0.126
0.113
0.141
76.114
24.482
26.202
25.313
0.057
0.019
0.021
0.017
75.884
24.408
26.123
25.237
5.054
1.613
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
Ref.
5
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1149
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
24
24
20
20
20
20
8
8
8
8
2
2
2
2
2
2
17
17
17
17
29
21
21
21
21
9
9
9
9
30
21
21
21
21
19
19
19
19
19
19
19
19
11
11
11
11
11
11
11
11
28
28
28
28
6
6
6
6
6
3
3
3
3
3
3
3
3
0
0
0
0
0
0
0
0
0
0
4
3
3
3
3
2
2
2
2
4
3
3
3
3
6
6
6
6
6
6
6
6
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
A2
A2
A2
A2
B2
B2
B2
B2
B1
B1
B1
B1
A2
A2
A2
A2
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
25
24
23
23
20
20
20
20
9
9
9
9
1
1
1
1
1
1
16
16
16
16
29
21
21
21
21
8
8
8
8
30
21
21
21
21
20
20
20
20
20
20
20
20
11
11
11
11
11
11
11
11
28
28
28
28
5
5
5
7
7
3
3
3
3
2
2
2
2
1
1
1
1
1
1
3
3
3
3
4
3
3
3
3
3
3
3
3
4
3
3
3
3
5
5
5
5
5
5
5
5
2
2
2
2
2
2
2
2
0
0
0
0
2
2
2
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
B2
B2
B2
B2
A1
A1
A1
A1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
24
23
20
21
19
8
9
7
1
3
1
2
2
16
18
17
21
22
20
8
10
9
21
22
20
19
20
18
19
20
18
11
12
10
11
12
10
27
29
28
5
7
Obs. Freq. 共unc.兲
共MHz兲
20
21
19
9
10
8
0
2
1
2
1
15
17
16
21
22
20
4 660.420 共0.500兲
7
9
8
21
22
20
4 857.860 共0.500兲
20
21
19
4 859.880 共0.500兲
20
21
19
11
12
10
11
12
10
4 963.000 共0.500兲
27
29
28
4
6
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
4 098.037 共0.014兲
4 098.096 共0.014兲
4 260.624 共0.033兲*
4 260.553 共0.033兲
4 260.657 共0.033兲
4 260.662 共0.033兲
4 352.012 共0.008兲*
4 351.886 共0.008兲
4 352.068 共0.008兲
4 352.081 共0.008兲
4 364.348 共0.005兲*
4 362.872 共0.005兲
4 364.087 共0.005兲
4 364.169 共0.005兲
4 364.873 共0.005兲
4 365.392 共0.005兲
4 399.998 共0.034兲*
4 399.625 共0.034兲
4 399.682 共0.034兲
4 400.685 共0.034兲
4 511.546 共0.181兲*
4 658.491 共0.045兲*
4 658.389 共0.045兲
4 658.538 共0.045兲
4 658.545 共0.045兲
4 660.428 共0.008兲*
4 660.385 共0.008兲
4 660.391 共0.008兲
4 660.509 共0.008兲
4 750.888 共0.220兲*
4 753.437 共0.044兲*
4 753.334 共0.044兲
4 753.486 共0.044兲
4 753.493 共0.044兲
4 857.724 共0.010兲*
4 857.675 共0.010兲
4 857.748 共0.010兲
4 857.750 共0.010兲
4 859.736 共0.010兲*
4 859.687 共0.010兲
4 859.760 共0.010兲
4 859.762 共0.010兲
4 886.897 共0.016兲*
4 886.646 共0.016兲
4 887.008 共0.016兲
4 887.041 共0.016兲
4 946.415 共0.015兲*
4 946.161 共0.015兲
4 946.527 共0.015兲
4 946.560 共0.015兲
4 963.988 共0.121兲*
4 963.952 共0.121兲
4 963.956 共0.121兲
4 964.056 共0.121兲
5 195.433 共0.010兲*
5 194.828 共0.010兲
5 195.040 共0.010兲
540.301
540.301
335.042
335.042
335.042
335.042
77.409
77.409
77.409
77.409
4.592
4.592
4.592
4.592
4.592
4.592
225.443
225.443
225.443
225.443
686.283
366.251
366.251
366.251
366.251
77.554
77.554
77.554
77.554
730.570
366.156
366.156
366.156
366.156
378.111
378.111
378.111
378.111
378.111
378.111
378.111
378.111
108.769
108.769
108.769
108.769
108.806
108.806
108.806
108.806
595.218
595.218
595.218
595.218
33.427
33.427
33.427
1.753
1.682
0.058
0.019
0.020
0.018
0.033
0.011
0.012
0.010
0.456
0.051
0.213
0.038
0.038
0.114
0.032
0.010
0.011
0.010
0.021
0.077
0.025
0.027
0.024
1.822
0.536
0.671
0.600
0.030
0.077
0.026
0.027
0.024
4.162
1.384
1.455
1.316
4.162
1.384
1.455
1.316
0.066
0.022
0.024
0.020
0.063
0.021
0.023
0.019
72.870
23.408
25.112
24.230
1.256
0.343
0.483
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
Ref.
5
5
5
5
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1150
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
21
21
21
21
3
3
3
3
28
28
28
28
3
3
3
3
11
11
11
11
2
2
2
2
2
2
2
2
4
4
4
4
8
8
8
8
22
22
22
22
27
27
27
27
22
22
22
22
8
8
8
8
13
13
13
13
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
2
2
2
2
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
6
5
21
21
21
21
3
3
3
3
28
28
28
28
3
3
3
3
11
11
11
11
2
2
2
2
2
2
2
2
5
5
5
5
9
9
9
9
22
22
22
22
27
27
27
27
22
22
22
22
9
9
9
9
12
12
12
12
2
3
3
3
3
1
1
1
1
0
0
0
0
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
3
3
3
3
0
0
0
0
3
3
3
3
2
2
2
2
4
4
4
4
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
B1
B1
B1
B1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
5
21
22
20
3
4
2
27
29
28
3
4
2
11
12
10
2
3
1
2
3
2
1
3
5
4
8
9
7
22
23
21
26
28
27
22
23
21
8
7
9
12
14
13
Obs. Freq. 共unc.兲
共MHz兲
21
22
20
3
4
2
5 284.820 共0.500兲
27
29
28
3
4
2
11
12
10
2
2
2
3
3
1
1
4
6
5
5 766.680 共0.500兲
9
10
8
22
23
21
26
28
27
22
23
21
6 246.420 共0.500兲
9
8
10
6 269.810 共0.500兲
11
13
12
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
5 196.401 共0.010兲
5 275.530 共0.044兲*
5 275.438 共0.044兲
5 275.573 共0.044兲
5 275.580 共0.044兲
5 278.693 共0.004兲*
5 277.177 共0.004兲
5 279.199 共0.004兲
5 279.906 共0.004兲
5 284.656 共0.218兲*
5 284.615 共0.218兲
5 284.620 共0.218兲
5 284.734 共0.218兲
5 287.855 共0.004兲*
5 286.339 共0.004兲
5 288.360 共0.004兲
5 289.068 共0.004兲
5 416.292 共0.014兲*
5 416.041 共0.014兲
5 416.402 共0.014兲
5 416.435 共0.014兲
5 669.477 共0.008兲*
5 668.772 共0.008兲
5 668.837 共0.008兲
5 668.873 共0.008兲
5 669.613 共0.008兲
5 669.678 共0.008兲
5 670.080 共0.008兲
5 670.181 共0.008兲
5 681.341 共0.009兲*
5 681.078 共0.009兲
5 681.200 共0.009兲
5 681.719 共0.009兲
5 766.665 共0.008兲*
5 766.474 共0.008兲
5 766.750 共0.008兲
5 766.773 共0.008兲
6 085.787 共0.059兲*
6 085.666 共0.059兲
6 085.844 共0.059兲
6 085.852 共0.059兲
6 156.402 共0.107兲*
6 156.360 共0.107兲
6 156.364 共0.107兲
6 156.482 共0.107兲
6 208.400 共0.057兲*
6 208.277 共0.057兲
6 208.458 共0.057兲
6 208.466 共0.057兲
6 246.278 共0.009兲*
6 246.251 共0.009兲
6 246.291 共0.009兲
6 246.293 共0.009兲
6 269.689 共0.009兲*
6 269.652 共0.009兲
6 269.656 共0.009兲
6 269.759 共0.009兲
33.427
366.079
366.079
366.079
366.079
11.801
11.801
11.801
11.801
595.119
595.119
595.119
595.119
11.642
11.642
11.642
11.642
108.564
108.564
108.564
108.564
7.370
7.370
7.370
7.370
7.370
7.370
7.370
7.370
25.444
25.444
25.444
25.444
77.775
77.775
77.775
77.775
398.758
398.758
398.758
398.758
554.435
554.434
554.434
554.435
398.664
398.664
398.664
398.664
77.627
77.627
77.627
77.627
158.965
158.965
158.965
158.965
␮ 2S
共D2兲
Wst
0.407
0.063
0.021
0.022
0.020
0.054
0.015
0.022
0.011
72.613
23.325
25.024
24.145
0.056
0.016
0.023
0.012
0.058
0.019
0.021
0.017
0.017
0.004
0.001
0.001
0.001
0.007
0.001
0.0033
0.319
0.083
0.126
0.102
1.845
0.607
0.680
0.543
0.073
0.024
0.025
0.023
69.614
22.330
24.018
23.143
0.073
0.024
0.025
0.023
1.471
0.484
0.433
0.542
2.737
0.839
0.980
0.907
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
32
3
4
34
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Ref.
5
5
5
5
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1151
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
2
2
2
2
2
2
20
20
20
20
22
22
22
22
27
27
27
27
12
12
12
12
8
8
8
8
12
12
12
12
24
24
24
24
8
8
8
8
16
16
16
16
24
24
24
24
3
3
3
3
12
12
12
12
26
26
26
0
0
0
0
0
0
5
5
5
5
3
3
3
3
1
1
1
1
2
2
2
2
3
3
3
3
2
2
2
2
4
4
4
4
3
3
3
3
3
3
3
3
4
4
4
4
1
1
1
1
2
2
2
2
1
1
1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
F⬘
1
1
3
2
2
19
21
20
22
23
21
26
28
27
12
13
11
8
9
7
12
13
11
23
25
24
8
9
7
16
17
15
23
25
24
3
4
2
12
13
11
25
27
J⬙
K⬙a
⌫⬙
1
1
1
1
1
1
19
19
19
19
22
22
22
22
27
27
27
27
12
12
12
12
9
9
9
9
12
12
12
12
25
25
25
25
9
9
9
9
17
17
17
17
25
25
25
25
3
3
3
3
12
12
12
12
26
26
26
1
1
1
1
1
1
6
6
6
6
3
3
3
3
0
0
0
0
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
2
2
2
2
0
0
0
0
1
1
1
1
1
1
1
1
2
2
2
2
0
0
0
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
0
1
2
2
1
6 500.420 共0.500兲
18
20
19
22
23
21
6 655.040 共0.500兲
26
28
27
12
13
11
6 857.000 共0.500兲
9
10
8
12
13
11
24
26
25
9
10
8
17
18
16
24
26
25
3
4
2
12
13
11
7 515.560 共0.500兲
25
27
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
6 437.552 共0.005兲*
6 436.225 共0.005兲
6 437.298 共0.005兲
6 437.306 共0.005兲
6 438.093 共0.005兲
6 438.522 共0.005兲
6 500.045 共0.011兲*
6 500.018 共0.011兲
6 500.020 共0.011兲
6 500.096 共0.011兲
6 615.437 共0.058兲*
6 615.322 共0.058兲
6 615.491 共0.058兲
6 615.498 共0.058兲
6 654.772 共0.190兲*
6 654.724 共0.190兲
6 654.729 共0.190兲
6 654.863 共0.190兲
6 805.197 共0.022兲*
6 804.903 共0.022兲
6 805.328 共0.022兲
6 805.363 共0.022兲
6 857.035 共0.007兲*
6 856.859 共0.007兲
6 857.113 共0.007兲
6 857.134 共0.007兲
6 887.024 共0.021兲*
6 886.726 共0.021兲
6 887.156 共0.021兲
6 887.192 共0.021兲
6 889.573 共0.323兲*
6 889.470 共0.323兲
6 889.483 共0.323兲
6 889.766 共0.323兲
6 895.173 共0.012兲*
6 895.093 共0.012兲
6 895.210 共0.012兲
6 895.216 共0.012兲
7 018.732 共0.032兲*
7 018.046 共0.032兲
7 019.048 共0.032兲
7 019.104 共0.032兲
7 067.677 共0.234兲*
7 067.574 共0.234兲
7 067.587 共0.234兲
7 067.870 共0.234兲
7 278.907 共0.006兲*
7 277.809 共0.006兲
7 279.272 共0.006兲
7 279.784 共0.006兲
7 355.000 共0.019兲*
7 354.698 共0.019兲
7 355.133 共0.019兲
7 355.170 共0.019兲
7 516.246 共0.094兲*
7 516.196 共0.094兲
7 516.202 共0.094兲
4.626
4.626
4.626
4.626
4.626
4.626
378.016
378.016
378.016
378.016
398.590
398.590
398.590
398.590
554.329
554.329
554.329
554.329
126.496
126.496
126.496
126.496
77.529
77.529
77.529
77.529
126.533
126.533
126.533
126.533
486.473
486.473
486.473
486.473
77.710
77.710
77.710
77.710
225.590
225.590
225.590
225.590
486.533
486.533
486.533
486.533
11.780
11.780
11.780
11.780
126.293
126.293
126.293
126.293
515.086
515.086
515.086
0.418
0.046
0.035
0.195
0.035
0.104
4.164
1.317
1.456
1.385
0.065
0.022
0.023
0.021
69.337
22.241
23.922
23.051
0.061
0.020
0.022
0.019
1.470
0.484
0.541
0.432
0.058
0.019
0.021
0.018
0.064
0.021
0.022
0.021
0.034
0.011
0.012
0.010
0.045
0.015
0.016
0.014
0.036
0.011
0.012
0.012
0.029
0.008
0.012
0.006
0.055
0.018
0.020
0.017
66.351
21.251
22.920
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
Ref.
5
5
9
5
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1152
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
26
24
24
30
30
30
30
23
23
23
23
23
23
23
23
26
26
26
26
23
23
23
23
24
24
24
24
13
13
13
13
29
29
29
29
2
2
2
2
2
2
4
4
4
4
4
4
4
4
25
25
25
25
8
8
8
8
1
6
6
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
4
4
4
4
3
3
3
3
1
1
1
1
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
E2 − 1
B2
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
A2
A2
A2
A2
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
B1
B1
A1
A1
A1
A1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
26
26
23
23
30
30
30
30
23
23
23
23
23
23
23
23
26
26
26
26
23
23
23
23
25
25
25
25
12
12
12
12
29
29
29
29
1
1
1
1
1
1
4
4
4
4
4
4
4
4
25
25
25
25
9
9
9
9
0
7
7
0
0
0
0
3
3
3
3
3
3
3
3
0
0
0
0
3
3
3
3
1
1
1
1
4
4
4
4
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
2
2
2
2
E2 + 1
B1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B2
B2
A2
A2
A2
A2
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
26
29
31
30
23
24
22
23
24
22
25
27
26
23
24
22
23
25
24
12
14
13
28
30
29
1
3
2
1
2
4
5
3
4
5
3
24
26
25
8
9
7
Obs. Freq. 共unc.兲
共MHz兲
7 727.740 共0.500兲
29
31
30
23
24
22
23
24
22
8 201.650 共0.500兲
25
27
26
23
24
22
24
26
25
8 411.940 共0.500兲
11
13
12
8 684.290 共0.500兲
28
30
29
8 777.826 共0.020兲
0
2
2
1
1
4
5
3
4
5
3
9 057.850 共0.500兲
24
26
25
9
10
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
7 516.341 共0.094兲
7 547.826 共0.012兲*
7 548.022 共0.012兲*
7 727.463 共0.150兲*
7 727.436 共0.150兲
7 727.439 共0.150兲
7 727.514 共0.150兲
7 846.995 共0.076兲*
7 846.853 共0.076兲
7 847.061 共0.076兲
7 847.070 共0.076兲
8 003.037 共0.074兲*
8 002.892 共0.074兲
8 003.105 共0.074兲
8 003.114 共0.074兲
8 201.316 共0.164兲*
8 201.259 共0.164兲
8 201.265 共0.164兲
8 201.422 共0.164兲
8 324.676 共0.075兲*
8 324.537 共0.075兲
8 324.741 共0.075兲
8 324.750 共0.075兲
8 348.078 共0.316兲*
8 347.977 共0.316兲
8 347.989 共0.316兲
8 348.267 共0.316兲
8 411.969 共0.009兲*
8 411.932 共0.009兲
8 411.936 共0.009兲
8 412.039 共0.009兲
8 684.145 共0.132兲*
8 684.113 共0.132兲
8 684.116 共0.132兲
8 684.205 共0.132兲
8 777.827 共0.007兲*
8 775.096 共0.008兲
8 777.440 共0.007兲
8 778.226 共0.007兲
8 778.275 共0.007兲
8 779.498 共0.007兲
8 797.064 共0.006兲*
8 795.548 共0.006兲
8 797.615 共0.006兲
8 798.147 共0.006兲
8 812.331 共0.006兲*
8 810.815 共0.006兲
8 812.882 共0.006兲
8 813.414 共0.006兲
9 058.506 共0.083兲*
9 058.447 共0.083兲
9 058.454 共0.083兲
9 058.617 共0.083兲
9 189.533 共0.011兲*
9 189.357 共0.011兲
9 189.610 共0.011兲
9 189.632 共0.011兲
515.086
540.441
540.441
681.009
681.009
681.009
681.009
432.737
432.737
432.737
432.737
432.644
432.644
432.644
432.644
514.975
514.975
514.975
514.975
432.573
432.573
432.573
432.573
486.602
486.602
486.602
486.602
158.996
158.996
158.996
158.996
637.355
637.355
637.355
637.355
4.350
4.350
4.350
4.350
4.350
4.350
17.657
17.657
17.657
17.657
17.498
17.498
17.498
17.498
477.175
477.175
477.175
477.175
77.529
77.529
77.529
77.529
␮ 2S
共D2兲
Wst
22.054
5.046
5.046
79.403
25.571
27.307
26.411
0.070
0.023
0.024
0.022
0.070
0.023
0.024
0.022
66.060
21.158
22.820
21.957
0.0651
0.022
0.022
0.021
0.070
0.022
0.024
0.023
2.743
0.841
0.982
0.909
76.146
24.493
26.213
25.324
0.779
0.087
0.363
0.065
0.065
0.195
0.041
0.012
0.016
0.010
0.044
0.013
0.017
0.011
63.084
20.171
21.820
20.963
0.380
0.125
0.140
0.112
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
23
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
Ref.
3
3
3
3
10
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1153
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
13
13
13
13
13
13
13
13
2
2
2
2
2
2
24
24
24
24
24
24
24
28
28
28
28
13
13
13
13
25
25
25
25
24
24
24
24
11
11
11
11
4
4
4
4
24
24
24
24
26
26
26
4
4
4
4
26
2
2
2
2
2
2
2
2
0
0
0
0
0
0
6
6
6
4
4
4
4
1
1
1
1
2
2
2
2
1
1
1
1
3
3
3
3
2
2
2
2
1
1
1
1
3
3
3
3
8
8
8
2
2
2
2
8
A2
A2
A2
A2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
A1
A
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
F⬘
13
14
12
13
14
12
1
1
3
2
2
23
25
24
27
29
28
13
14
12
24
26
25
24
25
23
11
12
10
4
5
3
24
25
23
3
5
4
J⬙
K⬙a
⌫⬙
13
13
13
13
13
13
13
13
1
1
1
1
1
1
23
23
23
25
25
25
25
28
28
28
28
13
13
13
13
25
25
25
25
24
24
24
24
11
11
11
11
4
4
4
4
24
24
24
24
27
27
27
5
5
5
5
27
2
2
2
2
2
2
2
2
1
1
1
1
1
1
7
7
7
1
1
1
1
0
0
0
0
2
2
2
2
0
0
0
0
3
3
3
3
2
2
2
2
1
1
1
1
3
3
3
3
7
7
7
1
1
1
1
7
A1
A1
A1
A1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
A2
A
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
13
14
12
13
14
12
9 459.230 共0.020兲
0
1
2
2
1
9 706.100 共0.500兲
24
26
25
9 779.330 共0.500兲
27
29
28
13
14
12
9 938.950 共0.500兲
24
26
25
24
25
23
11
12
10
4
5
3
24
25
23
10 262.410 共0.500兲
4
6
5
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
9 218.586 共0.030兲*
9 218.246 共0.030兲
9 218.738 共0.030兲
9 218.776 共0.030兲
9 327.714 共0.029兲*
9 327.370 共0.029兲
9 327.868 共0.029兲
9 327.907 共0.029兲
9 459.246 共0.008兲*
9 458.292 共0.008兲
9 458.805 共0.008兲
9 459.037 共0.008兲
9 459.823 共0.008兲
9 460.028 共0.008兲
9 706.100 共0.013兲*
9 706.198 共0.013兲*
9 706.295 共0.013兲*
9 707.840 共0.222兲*
9 707.738 共0.222兲
9 707.750 共0.222兲
9 708.032 共0.222兲
9 779.108 共0.116兲*
9 779.071 共0.116兲
9 779.075 共0.116兲
9 779.180 共0.116兲
9 835.070 共0.026兲*
9 834.718 共0.026兲
9 835.227 共0.026兲
9 835.267 共0.026兲
9 938.377 共0.142兲*
9 938.311 共0.142兲
9 938.318 共0.142兲
9 938.500 共0.142兲
9 995.475 共0.097兲*
9 995.310 共0.097兲
9 995.553 共0.097兲
9 995.563 共0.097兲
10 028.566 共0.011兲*
10 028.436 共0.011兲
10 028.623 共0.011兲
10 028.640 共0.011兲
10 116.413 共0.005兲*
10 115.098 共0.005兲
10 116.892 共0.005兲
10 117.353 共0.005兲
10 191.328 共0.094兲*
10 191.159 共0.094兲
10 191.407 共0.094兲
10 191.418 共0.094兲
10 262.215 共0.023兲*
10 262.220 共0.023兲*
10 262.226 共0.023兲*
10 286.188 共0.009兲*
10 286.021 共0.009兲
10 286.103 共0.009兲
10 286.422 共0.009兲
10 362.904 共0.017兲*
145.697
145.697
145.697
145.697
145.734
145.734
145.734
145.734
4.422
4.422
4.422
4.422
4.422
4.422
540.469
540.469
540.469
486.594
486.594
486.594
486.594
595.135
595.135
595.135
595.135
145.494
145.494
145.494
145.494
477.056
477.056
477.056
477.056
468.189
468.189
468.189
468.189
108.469
108.469
108.469
108.469
17.647
17.648
17.647
17.647
468.096
468.096
468.096
468.096
690.966
690.966
690.966
25.426
25.426
25.426
25.426
690.781
0.057
0.019
0.020
0.017
0.053
0.017
0.019
0.016
0.322
0.036
0.027
0.150
0.027
0.081
5.040
10.081
5.040
0.036
0.012
0.012
0.012
72.885
23.412
25.117
24.235
0.052
0.017
0.018
0.016
62.783
20.075
21.716
20.863
0.066
0.022
0.023
0.021
0.017
0.006
0.006
0.005
0.031
0.009
0.012
0.008
0.066
0.022
0.023
0.021
5.559
11.118
5.559
0.785
0.204
0.309
0.251
5.568
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
3
Ref.
10
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1154
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
24
24
24
24
16
16
16
16
24
24
24
24
27
27
27
27
6
6
6
6
12
12
12
12
15
24
24
24
24
13
13
13
13
4
4
4
4
13
14
14
14
14
15
13
15
30
14
14
14
14
6
6
6
6
26
26
26
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
5
1
1
1
1
3
3
3
3
2
2
2
2
3
2
2
2
2
5
3
5
1
2
2
2
2
1
1
1
1
1
1
1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
B2
B2
B2
B2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
A1
A1
A1
A1
A2
A2
A1
A2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
F⬘
24
25
23
16
17
15
23
25
24
26
28
27
5
7
6
12
13
11
23
25
24
12
14
13
3
5
4
14
15
13
14
15
13
5
7
6
25
27
J⬙
K⬙a
⌫⬙
24
24
24
24
17
17
17
17
24
24
24
24
27
27
27
27
5
5
5
5
12
12
12
12
16
24
24
24
24
12
12
12
12
5
5
5
5
12
14
14
14
14
16
12
16
30
14
14
14
14
5
5
5
5
26
26
26
3
3
3
3
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
2
2
2
2
2
4
0
0
0
0
4
4
4
4
1
1
1
1
4
2
2
2
2
4
4
4
0
2
2
2
2
2
2
2
2
0
0
0
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
A1
A2
A1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
24
25
23
17
18
16
23
25
24
26
28
27
4
6
5
12
13
11
11 878.900 共0.500兲
23
25
24
11 961.290 共0.500兲
11
13
12
4
6
5
12 162.440 共0.500兲
14
15
13
12 238.840 共0.500兲
12 258.960 共0.500兲
12 306.860 共0.500兲
14
15
13
4
6
5
12 444.040 共0.500兲
25
27
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
10 451.107 共0.095兲*
10 450.943 共0.095兲
10 451.184 共0.095兲
10 451.194 共0.095兲
10 483.095 共0.037兲*
10 482.408 共0.037兲
10 483.412 共0.037兲
10 483.469 共0.037兲
10 797.255 共0.073兲*
10 797.186 共0.073兲
10 797.194 共0.073兲
10 797.385 共0.073兲
11 027.399 共0.102兲*
11 027.354 共0.102兲
11 027.359 共0.102兲
11 027.482 共0.102兲
11 081.648 共0.010兲*
11 081.043 共0.010兲
11 081.255 共0.010兲
11 082.617 共0.010兲
11 147.965 共0.014兲*
11 147.773 共0.014兲
11 148.050 共0.014兲
11 148.074 共0.014兲
11 269.410 共0.011兲*
11 878.813 共0.122兲*
11 878.737 共0.122兲
11 878.746 共0.122兲
11 878.956 共0.122兲
11 961.246 共0.008兲*
11 961.204 共0.008兲
11 961.209 共0.008兲
11 961.326 共0.008兲
12 029.973 共0.010兲*
12 029.808 共0.010兲
12 029.889 共0.010兲
12 030.205 共0.010兲
12 162.448 共0.009兲*
12 193.021 共0.040兲*
12 192.635 共0.040兲
12 193.196 共0.040兲
12 193.236 共0.040兲
12 238.901 共0.008兲*
12 251.348 共0.008兲*
12 258.623 共0.008兲*
12 306.002 共0.290兲*
12 334.687 共0.038兲*
12 334.296 共0.038兲
12 334.864 共0.038兲
12 334.905 共0.038兲
12 340.370 共0.008兲*
12 339.819 共0.008兲
12 340.012 共0.008兲
12 341.251 共0.008兲
12 444.234 共0.089兲*
12 444.182 共0.089兲
12 444.188 共0.089兲
468.027
468.027
468.027
468.027
225.516
225.516
225.516
225.516
440.700
440.700
440.700
440.700
554.350
554.350
554.350
554.350
33.390
33.390
33.390
33.390
126.210
126.210
126.210
126.210
244.734
440.575
440.575
440.575
440.575
158.802
158.802
158.802
158.802
25.426
25.426
25.426
25.426
158.689
166.370
166.370
166.370
166.370
244.540
158.802
244.540
680.842
166.406
166.407
166.406
166.406
33.224
33.224
33.224
33.224
515.001
515.001
515.001
0.064
0.021
0.022
0.020
0.070
0.023
0.025
0.022
59.817
19.092
20.720
19.873
69.618
22.331
24.019
23.145
1.256
0.342
0.483
0.407
0.024
0.008
0.009
0.007
3.270
59.510
18.994
20.613
19.770
2.747
0.842
0.983
0.910
0.196
0.051
0.077
0.063
2.741
0.053
0.017
0.019
0.016
3.274
2.748
3.274
79.087
0.048
0.016
0.017
0.015
0.914
0.249
0.352
0.296
66.347
21.250
22.919
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
Ref.
3
3
3
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1155
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
26
25
25
25
25
22
23
23
23
23
25
25
25
25
13
13
13
13
14
14
14
14
25
25
25
25
6
6
6
6
5
5
5
5
5
5
5
5
16
16
16
16
19
19
29
23
23
23
23
23
25
25
25
25
24
24
24
1
3
3
3
3
3
1
1
1
1
3
3
3
3
2
2
2
2
2
2
2
2
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
6
6
1
3
1
1
1
1
1
1
1
1
4
4
4
E1 − 1
B2
B2
B2
B2
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
B2
B2
B2
B2
A1
A1
A1
A1
A2
A1
A1
E1 − 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
26
26
25
25
25
25
22
23
23
23
23
25
25
25
25
13
13
13
13
14
14
14
14
25
25
25
25
5
5
5
5
5
5
5
5
5
5
5
5
17
17
17
17
20
20
29
23
23
23
23
23
25
25
25
25
25
25
25
0
3
3
3
3
3
0
0
0
0
3
3
3
3
2
2
2
2
2
2
2
2
3
3
3
3
2
2
2
2
1
1
1
1
1
1
1
1
0
0
0
0
5
5
0
3
0
0
0
0
0
0
0
0
1
1
1
E1 + 1
B1
B1
B1
B1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
A2
A2
A2
A2
A1
A2
A2
E1 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
26
25
26
24
22
24
23
25
26
24
13
14
12
14
15
13
25
26
24
5
7
6
5
6
4
5
6
4
16
17
15
22
24
23
24
26
25
23
25
Obs. Freq. 共unc.兲
共MHz兲
25
26
24
12 744.250 共0.500兲
22
24
23
25
26
24
13
14
12
14
15
13
25
26
24
13 176.170 共0.500兲
4
6
5
5
6
4
5
6
4
17
18
16
13 415.330 共0.500兲
13 416.570 共0.500兲
13 464.760 共0.500兲
14 033.540 共0.500兲
22
24
23
14 044.390 共0.500兲
24
26
25
24
26
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
12 444.333 共0.089兲
12 588.071 共0.122兲*
12 587.880 共0.122兲
12 588.161 共0.122兲
12 588.173 共0.122兲
12 618.224 共0.052兲*
12 744.881 共0.065兲*
12 744.801 共0.065兲
12 744.810 共0.065兲
12 745.032 共0.065兲
12 830.657 共0.118兲*
12 830.462 共0.118兲
12 830.749 共0.118兲
12 830.760 共0.118兲
12 863.799 共0.020兲*
12 863.538 共0.020兲
12 863.916 共0.020兲
12 863.945 共0.020兲
12 915.344 共0.034兲*
12 914.942 共0.034兲
12 915.525 共0.034兲
12 915.567 共0.034兲
13 046.770 共0.118兲*
13 046.578 共0.118兲
13 046.860 共0.118兲
13 046.871 共0.118兲
13 176.156 共0.007兲*
13 175.548 共0.007兲
13 175.762 共0.007兲
13 177.127 共0.007兲
13 193.898 共0.008兲*
13 192.383 共0.009兲
13 194.481 共0.008兲
13 194.909 共0.009兲
13 216.800 共0.008兲*
13 215.284 共0.008兲
13 217.383 共0.008兲
13 217.811 共0.008兲
13 373.268 共0.034兲*
13 372.585 共0.034兲
13 373.583 共0.034兲
13 373.640 共0.034兲
13 414.983 共0.010兲*
13 417.026 共0.010兲*
13 464.292 共0.253兲*
13 525.100 共0.070兲*
14 033.469 共0.106兲*
14 033.381 共0.106兲
14 033.391 共0.106兲
14 033.634 共0.106兲
14 044.520 共0.078兲*
14 044.459 共0.078兲
14 044.466 共0.078兲
14 044.635 共0.078兲
14 054.938 共0.204兲*
14 054.834 共0.204兲
14 054.847 共0.204兲
515.001
505.110
505.110
505.110
505.110
398.444
405.663
405.663
405.663
405.663
505.019
505.019
505.019
505.019
145.424
145.424
145.424
145.424
166.167
166.167
166.167
166.167
504.952
504.952
504.952
504.952
33.322
33.322
33.322
33.322
24.977
24.977
24.977
24.977
24.818
24.818
24.818
24.818
225.323
225.323
225.323
225.323
377.927
377.927
637.181
432.441
405.531
405.530
405.530
405.531
477.088
477.088
477.088
477.088
486.594
486.594
486.594
22.053
0.063
0.021
0.022
0.020
0.018
56.555
18.015
19.620
18.783
0.063
0.021
0.022
0.020
0.031
0.010
0.011
0.009
0.048
0.016
0.017
0.015
0.062
0.020
0.021
0.020
0.436
0.119
0.168
0.141
0.033
0.010
0.012
0.009
0.037
0.011
0.014
0.010
0.065
0.022
0.023
0.020
4.164
4.164
75.815
0.025
56.246
17.917
19.513
18.681
63.076
20.169
21.818
20.961
0.040
0.013
0.014
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
Ref.
3
6
3
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1156
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
24
6
6
6
6
5
5
5
5
24
24
4
4
4
4
28
24
24
24
24
22
22
22
22
24
24
24
24
26
26
14
14
14
14
26
26
26
26
15
15
15
15
24
24
24
24
8
8
8
8
15
15
15
15
26
26
26
4
1
1
1
1
1
1
1
1
6
6
2
2
2
2
1
3
3
3
3
1
1
1
1
4
4
4
4
8
8
2
2
2
2
3
3
3
3
2
2
2
2
1
1
1
1
3
3
3
3
2
2
2
2
3
3
3
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
A1
A1
A1
24
25
5
5
5
5
5
5
5
5
23
23
5
5
5
5
28
24
24
24
24
22
22
22
22
25
25
25
25
27
27
14
14
14
14
26
26
26
26
15
15
15
15
24
24
24
24
9
9
9
9
15
15
15
15
26
26
26
1
2
2
2
2
1
1
1
1
7
7
1
1
1
1
0
3
3
3
3
0
0
0
0
1
1
1
1
7
7
2
2
2
2
3
3
3
3
2
2
2
2
0
0
0
0
2
2
2
2
2
2
2
2
3
3
3
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
A2
A2
A2
25
5
7
6
5
6
4
3
5
4
24
25
23
21
23
22
23
25
24
14
15
13
26
27
25
15
16
14
23
25
24
8
9
7
15
16
14
26
27
Obs. Freq. 共unc.兲
共MHz兲
4
6
5
5
6
4
14 098.160 共0.500兲
14 215.990 共0.500兲
14 437.750 共0.500兲
4
6
5
14 771.220 共0.500兲
24
25
23
14 910.710 共0.500兲
21
23
22
24
26
25
14
15
13
26
27
25
15
16
14
15 842.140 共0.500兲
23
25
24
15 907.610 共0.500兲
9
10
8
15
16
14
26
27
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
14 055.132 共0.204兲
14 095.288 共0.008兲*
14 094.742 共0.008兲
14 094.933 共0.008兲
14 096.161 共0.008兲
14 095.646 共0.006兲*
14 094.230 共0.006兲
14 096.191 共0.006兲
14 096.590 共0.006兲
14 098.175 共0.012兲*
14 216.201 共0.014兲*
14 438.113 共0.008兲*
14 437.850 共0.008兲
14 437.972 共0.008兲
14 438.491 共0.008兲
14 770.940 共0.220兲*
14 867.159 共0.092兲*
14 867.047 共0.092兲
14 867.212 共0.092兲
14 867.219 共0.092兲
14 911.177 共0.057兲*
14 911.084 共0.057兲
14 911.096 共0.057兲
14 911.351 共0.057兲
14 983.323 共0.217兲*
14 983.218 共0.217兲
14 983.231 共0.217兲
14 983.519 共0.217兲
15 173.563 共0.014兲*
15 173.574 共0.014兲*
15 284.952 共0.028兲*
15 284.621 共0.028兲
15 285.102 共0.028兲
15 285.137 共0.028兲
15 684.318 共0.152兲*
15 684.100 共0.152兲
15 684.422 共0.152兲
15 684.434 共0.152兲
15 792.566 共0.053兲*
15 792.131 共0.053兲
15 792.763 共0.053兲
15 792.805 共0.053兲
15 842.216 共0.068兲*
15 842.145 共0.068兲
15 842.153 共0.068兲
15 842.350 共0.068兲
15 907.613 共0.008兲*
15 907.488 共0.008兲
15 907.669 共0.008兲
15 907.682 共0.008兲
15 972.063 共0.050兲*
15 971.623 共0.050兲
15 972.263 共0.050兲
15 972.305 共0.050兲
15 980.990 共0.146兲*
15 980.767 共0.146兲
15 981.095 共0.146兲
486.594
33.165
33.165
33.165
33.165
24.974
24.974
24.974
24.974
540.284
540.152
25.444
25.444
25.444
25.444
594.954
467.909
467.909
467.909
467.909
372.064
372.064
372.064
372.064
486.533
486.533
486.533
486.533
690.939
690.939
166.109
166.109
166.109
166.109
543.502
543.502
543.502
543.502
188.514
188.514
188.514
188.514
440.612
440.612
440.612
440.612
77.409
77.409
77.409
77.409
188.551
188.551
188.551
188.551
543.411
543.411
543.411
0.013
0.354
0.096
0.136
0.115
0.029
0.009
0.011
0.008
5.043
5.054
0.669
0.173
0.263
0.214
72.538
0.032
0.011
0.011
0.010
53.304
16.943
18.523
17.698
0.037
0.012
0.013
0.012
5.552
5.552
0.035
0.012
0.013
0.011
0.061
0.020
0.021
0.019
0.049
0.016
0.017
0.015
59.807
19.089
20.716
19.869
1.819
0.599
0.670
0.535
0.045
0.015
0.016
0.014
0.060
0.020
0.021
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
Ref.
3
3
3
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1157
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
26
26
26
26
26
27
22
22
22
22
15
15
15
15
15
25
25
25
25
17
21
21
21
21
4
4
4
4
5
5
5
5
23
23
23
23
26
2
2
2
2
2
2
6
6
6
6
15
15
15
15
6
6
6
6
28
21
3
3
3
3
3
1
1
1
1
1
2
2
2
2
5
3
3
3
3
4
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
1
1
1
1
2
2
2
2
1
1
1
1
7
1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 − 1
B1
25
26
26
26
26
26
27
22
22
22
22
15
15
15
15
16
25
25
25
25
16
21
21
21
21
5
5
5
5
5
5
5
5
23
23
23
23
26
1
1
1
1
1
1
6
6
6
6
15
15
15
15
6
6
6
6
27
21
3
3
3
3
3
0
0
0
0
0
2
2
2
2
4
3
3
3
3
5
0
0
0
0
1
1
1
1
1
1
1
1
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
8
0
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E1 − 1
B2
25
26
27
25
21
23
22
15
16
14
25
26
24
20
22
21
3
5
4
5
6
4
22
24
23
1
1
3
2
2
6
7
5
15
16
14
6
7
5
Obs. Freq. 共unc.兲
共MHz兲
26
27
25
16 240.640 共0.500兲
16 410.630 共0.500兲
21
23
22
15
16
14
25
26
24
16 947.650 共0.500兲
17 302.030 共0.500兲
20
22
21
17 475.860 共0.500兲
4
6
5
5
6
4
17 849.460 共0.500兲
22
24
23
17 887.200 共0.500兲
0
1
2
2
1
6
7
5
15
16
14
6
7
5
18 562.400 共0.500兲
19 013.550 共0.500兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
15 981.107 共0.146兲
16 167.350 共0.145兲*
16 167.130 共0.145兲
16 167.454 共0.145兲
16 167.467 共0.145兲
16 240.419 共0.190兲*
16 410.285 共0.091兲*
16 410.184 共0.091兲
16 410.196 共0.091兲
16 410.475 共0.091兲
16 654.974 共0.044兲*
16 654.522 共0.044兲
16 655.180 共0.044兲
16 655.224 共0.044兲
16 680.607 共0.010兲*
16 742.546 共0.118兲*
16 742.400 共0.118兲
16 742.615 共0.118兲
16 742.624 共0.118兲
16 947.493 共0.010兲*
17 302.333 共0.051兲*
17 302.225 共0.051兲
17 302.239 共0.051兲
17 302.533 共0.051兲
17 475.825 共0.010兲*
17 475.541 共0.010兲
17 475.672 共0.010兲
17 476.236 共0.010兲
17 741.081 共0.006兲*
17 739.955 共0.006兲
17 741.514 共0.006兲
17 741.832 共0.006兲
17 849.570 共0.059兲*
17 849.487 共0.059兲
17 849.497 共0.059兲
17 849.725 共0.059兲
17 887.062 共0.163兲*
18 348.552 共0.008兲*
18 347.449 共0.008兲
18 348.186 共0.008兲
18 348.328 共0.008兲
18 349.115 共0.008兲
18 349.410 共0.008兲
18 468.041 共0.011兲*
18 466.526 共0.011兲
18 468.648 共0.011兲
18 469.006 共0.011兲
18 483.926 共0.038兲*
18 483.526 共0.038兲
18 484.108 共0.038兲
18 484.146 共0.038兲
18 500.118 共0.011兲*
18 498.603 共0.011兲
18 500.724 共0.011兲
18 501.082 共0.011兲
18 562.473 共0.014兲*
19 013.343 共0.078兲*
543.411
543.346
543.346
543.346
543.346
554.161
371.925
371.925
371.925
371.925
188.312
188.312
188.312
188.312
244.703
504.847
504.847
504.847
504.847
268.991
339.905
339.905
339.905
339.905
25.417
25.417
25.417
25.417
24.834
24.834
24.834
24.834
405.573
405.573
405.573
405.573
514.804
4.229
4.229
4.229
4.229
4.229
4.229
33.759
33.760
33.759
33.759
188.262
188.262
188.262
188.262
33.601
33.601
33.601
33.601
731.333
339.759
0.019
0.059
0.020
0.021
0.019
69.258
52.998
16.846
18.416
17.596
0.045
0.015
0.016
0.014
3.265
0.038
0.013
0.013
0.012
3.643
50.072
15.878
17.431
16.619
0.988
0.256
0.389
0.316
0.019
0.006
0.007
0.005
56.544
18.012
19.616
18.780
65.975
0.360
0.040
0.030
0.168
0.030
0.090
0.027
0.009
0.010
0.007
0.038
0.012
0.013
0.012
0.032
0.010
0.012
0.009
5.935
49.775
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
Ref.
3
3
3
3
3
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1158
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
21
21
21
6
6
6
6
26
26
26
26
27
27
27
27
27
27
27
27
25
25
25
25
4
4
4
4
27
27
27
27
20
20
20
20
22
22
22
22
16
16
16
16
26
16
16
16
16
13
26
13
17
17
16
16
16
16
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
2
2
2
2
3
3
3
3
1
1
1
1
1
1
1
1
2
2
2
2
8
2
2
2
2
3
8
3
4
4
2
2
2
2
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
E2 − 1
B1
B1
B1
B1
B1
E2 + 1
B2
B1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
20
22
21
21
21
21
6
6
6
6
26
26
26
26
27
27
27
27
27
27
27
27
25
25
25
25
5
5
5
5
27
27
27
27
20
20
20
20
22
22
22
22
16
16
16
16
27
16
16
16
16
12
27
12
16
16
16
16
16
16
0
0
0
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
0
0
0
0
1
1
1
1
3
3
3
3
0
0
0
0
0
0
0
0
2
2
2
2
7
2
2
2
2
4
7
4
5
5
2
2
2
2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E2 − 1
B2
B2
B2
B2
B2
E2 + 1
B1
B2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
20
22
21
6
7
5
26
27
25
27
28
26
27
28
26
24
26
25
4
5
3
27
28
26
19
21
20
21
23
22
16
17
15
16
17
15
16
17
15
Obs. Freq. 共unc.兲
共MHz兲
6
7
5
26
27
25
27
28
26
27
28
26
19 724.620 共0.500兲
24
26
25
19 776.840 共0.500兲
5
6
4
27
28
26
19 919.560 共0.500兲
19
21
20
20 076.000 共0.500兲
21
23
22
16
17
15
16
17
15
20 547.170 共0.500兲
20 831.280 共0.500兲
21 019.170 共0.500兲
21 051.620 共0.500兲
16
17
15
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
19 013.227 共0.078兲
19 013.242 共0.078兲
19 013.560 共0.078兲
19 106.471 共0.007兲*
19 105.009 共0.007兲
19 107.055 共0.007兲
19 107.401 共0.007兲
19 235.757 共0.147兲*
19 235.574 共0.147兲
19 235.844 共0.147兲
19 235.854 共0.147兲
19 345.452 共0.188兲*
19 345.203 共0.188兲
19 345.569 共0.188兲
19 345.583 共0.188兲
19 703.833 共0.180兲*
19 703.581 共0.180兲
19 703.953 共0.180兲
19 703.967 共0.180兲
19 724.525 共0.138兲*
19 724.456 共0.138兲
19 724.463 共0.138兲
19 724.656 共0.138兲
19 776.987 共0.008兲*
19 775.949 共0.008兲
19 777.391 共0.008兲
19 777.668 共0.008兲
19 871.032 共0.176兲*
19 870.781 共0.176兲
19 871.151 共0.176兲
19 871.165 共0.176兲
19 919.873 共0.045兲*
19 919.750 共0.045兲
19 919.767 共0.045兲
19 920.101 共0.045兲
20 076.216 共0.052兲*
20 076.120 共0.052兲
20 076.132 共0.052兲
20 076.395 共0.052兲
20 077.687 共0.068兲*
20 077.204 共0.068兲
20 077.908 共0.068兲
20 077.952 共0.068兲
20 220.983 共0.015兲*
20 300.159 共0.064兲*
20 299.671 共0.064兲
20 300.383 共0.064兲
20 300.427 共0.064兲
20 547.315 共0.009兲*
20 749.224 共0.015兲*
20 831.223 共0.009兲*
21 019.071 共0.009兲*
21 051.545 共0.009兲*
21 110.614 共0.056兲*
21 110.112 共0.056兲
21 110.844 共0.056兲
21 110.890 共0.056兲
339.759
339.759
339.759
33.761
33.761
33.761
33.761
543.253
543.253
543.253
543.253
583.362
583.362
583.362
583.362
583.272
583.272
583.272
583.272
476.883
476.883
476.883
476.883
24.974
24.974
24.974
24.974
583.209
583.209
583.209
583.209
309.186
309.186
309.186
309.186
371.973
371.973
371.973
371.973
212.129
212.129
212.129
212.129
690.800
212.165
212.165
212.165
212.165
158.614
690.609
158.614
268.780
268.780
211.927
211.927
211.927
211.927
15.784
17.327
16.520
0.026
0.008
0.010
0.007
0.042
0.014
0.015
0.014
0.058
0.019
0.020
0.019
0.057
0.019
0.020
0.018
62.693
20.046
21.685
20.833
0.633
0.203
0.250
0.164
0.057
0.019
0.020
0.018
46.868
14.824
16.348
15.548
53.295
16.940
18.519
17.695
0.046
0.015
0.016
0.014
5.559
0.041
0.014
0.014
0.013
2.750
5.566
2.751
3.646
3.646
0.042
0.014
0.015
0.013
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
1
3
3
3
1
1
1
1
Ref.
3
3
3
3
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1159
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
15
24
24
24
24
20
20
20
20
6
6
6
6
6
6
6
6
24
22
27
27
27
27
16
16
16
16
21
21
21
21
17
19
19
19
19
4
4
4
4
15
15
6
6
6
6
28
28
28
28
28
11
11
23
23
23
23
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
7
3
3
3
3
2
2
2
2
1
1
1
1
4
1
1
1
1
2
2
2
2
5
5
1
1
1
1
7
3
3
3
3
4
4
1
1
1
1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B2
B1
B1
B1
B1
B1
E2 + 1
B1
B1
B1
B1
B2
B1
A1
A1
A1
A1
F⬘
23
25
24
19
21
20
5
7
6
6
7
5
27
28
26
16
17
15
20
22
21
18
20
19
3
5
4
6
7
5
28
29
27
22
24
23
J⬙
K⬙a
⌫⬙
16
24
24
24
24
20
20
20
20
5
5
5
5
6
6
6
6
23
23
27
27
27
27
16
16
16
16
21
21
21
21
16
19
19
19
19
5
5
5
5
16
16
5
5
5
5
27
28
28
28
28
12
12
23
23
23
23
4
0
0
0
0
0
0
0
0
2
2
2
2
1
1
1
1
7
6
3
3
3
3
2
2
2
2
0
0
0
0
5
0
0
0
0
1
1
1
1
4
4
2
2
2
2
8
3
3
3
3
3
3
0
0
0
0
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B2
B2
B2
B2
B2
E2 + 1
B2
B2
B2
B2
B1
B2
A2
A2
A2
A2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
21 712.650 共0.500兲
21 765.230 共0.500兲
23
25
24
21 842.310 共0.500兲
19
21
20
21 930.490 共0.500兲
4
6
5
6
7
5
27
28
26
16
17
15
22 528.020 共0.500兲
20
22
21
22 722.630 共0.500兲
22 759.360 共0.500兲
18
20
19
23 340.880 共0.500兲
4
6
5
23 409.160 共0.500兲
23 429.420 共0.500兲
23 449.910 共0.500兲
5
6
4
28
29
27
23 683.170 共0.500兲
23 861.400 共0.500兲
24 019.010 共0.500兲
22
24
23
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
21 712.659 共0.010兲*
21 765.132 共0.117兲*
21 765.052 共0.117兲
21 765.061 共0.117兲
21 765.283 共0.117兲
21 841.898 共0.068兲*
21 841.766 共0.068兲
21 841.784 共0.068兲
21 842.144 共0.068兲
21 930.443 共0.008兲*
21 929.835 共0.008兲
21 930.049 共0.008兲
21 931.413 共0.008兲
21 939.366 共0.007兲*
21 938.092 共0.007兲
21 939.875 共0.007兲
21 940.177 共0.007兲
22 080.797 共0.014兲*
22 221.211 共0.014兲*
22 415.503 共0.181兲*
22 415.281 共0.181兲
22 415.608 共0.181兲
22 415.620 共0.181兲
22 507.276 共0.050兲*
22 506.812 共0.050兲
22 507.487 共0.050兲
22 507.530 共0.050兲
22 528.182 共0.045兲*
22 528.072 共0.045兲
22 528.087 共0.045兲
22 528.387 共0.045兲
22 722.583 共0.010兲*
22 759.631 共0.040兲*
22 759.491 共0.040兲
22 759.511 共0.040兲
22 759.890 共0.040兲
23 340.882 共0.011兲*
23 340.598 共0.011兲
23 340.728 共0.011兲
23 341.292 共0.011兲
23 409.220 共0.009兲*
23 429.382 共0.009兲*
23 449.966 共0.011兲*
23 449.475 共0.011兲
23 450.158 共0.011兲
23 450.288 共0.011兲
23 526.985 共0.014兲*
23 633.208 共0.231兲*
23 632.929 共0.231兲
23 633.341 共0.231兲
23 633.356 共0.231兲
23 683.273 共0.008兲*
23 861.284 共0.008兲*
24 019.088 共0.098兲*
24 018.996 共0.098兲
24 019.007 共0.098兲
24 019.260 共0.098兲
244.584
440.399
440.399
440.399
440.399
309.034
309.034
309.034
309.034
33.030
33.030
33.030
33.030
33.635
33.635
33.635
33.635
540.109
505.418
583.125
583.125
583.125
583.125
211.884
211.884
211.884
211.884
339.813
339.813
339.813
339.813
268.953
279.909
279.909
279.909
279.909
25.259
25.259
25.259
25.259
244.355
244.354
33.435
33.435
33.435
33.435
731.121
624.688
624.688
624.688
624.688
140.083
140.077
405.352
405.352
405.352
405.352
3.267
59.416
18.964
20.581
19.740
46.584
14.734
16.249
15.454
0.822
0.224
0.316
0.266
0.021
0.007
0.008
0.006
5.049
4.679
0.045
0.015
0.016
0.014
0.038
0.013
0.013
0.012
50.065
15.876
17.429
16.616
3.639
43.703
13.782
15.276
14.491
0.989
0.256
0.390
0.317
3.273
3.273
1.401
0.454
0.539
0.382
5.937
0.056
0.018
0.019
0.018
2.379
2.379
56.150
17.886
19.479
18.649
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1160
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
28
28
28
28
28
18
18
18
18
28
28
28
28
7
7
7
7
7
7
7
7
19
19
19
19
7
7
7
7
17
17
17
17
20
20
20
20
17
17
17
17
26
18
18
18
18
17
17
17
17
28
28
28
28
22
22
22
7
3
3
3
3
0
0
0
0
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
2
2
2
2
8
1
1
1
1
2
2
2
2
3
3
3
3
1
1
1
E2 − 1
A1
A1
A1
A1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
F⬘
28
29
27
17
19
18
28
29
27
7
8
6
7
8
6
18
20
19
7
8
6
17
18
16
19
21
20
17
18
16
17
19
18
17
18
16
28
29
27
21
23
J⬙
K⬙a
⌫⬙
27
28
28
28
28
17
17
17
17
28
28
28
28
7
7
7
7
7
7
7
7
19
19
19
19
7
7
7
7
17
17
17
17
20
20
20
20
17
17
17
17
27
18
18
18
18
17
17
17
17
28
28
28
28
22
22
22
8
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
0
0
0
0
1
1
1
1
2
2
2
2
0
0
0
0
2
2
2
2
7
0
0
0
0
2
2
2
2
3
3
3
3
0
0
0
E2 − 1
A2
A2
A2
A2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
B1
B1
B1
B1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
28
29
27
16
18
17
28
29
27
7
8
6
7
8
6
24 889.540 共0.500兲
18
20
19
7
8
6
17
18
16
25 206.620 共0.500兲
19
21
20
17
18
16
25 810.650 共0.500兲
17
19
18
17
18
16
28
29
27
26 493.630 共0.500兲
21
23
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
24 037.230 共0.015兲*
24 061.005 共0.221兲*
24 060.721 共0.221兲
24 061.140 共0.221兲
24 061.155 共0.221兲
24 099.571 共0.040兲*
24 099.171 共0.040兲
24 099.229 共0.040兲
24 100.309 共0.040兲
24 217.049 共0.212兲*
24 216.766 共0.212兲
24 217.184 共0.212兲
24 217.198 共0.212兲
24 617.704 共0.014兲*
24 616.190 共0.014兲
24 618.328 共0.014兲
24 618.636 共0.014兲
24 660.518 共0.015兲*
24 659.003 共0.015兲
24 661.141 共0.015兲
24 661.450 共0.015兲
24 889.489 共0.059兲*
24 889.339 共0.059兲
24 889.361 共0.059兲
24 889.765 共0.059兲
25 080.129 共0.009兲*
25 078.645 共0.009兲
25 080.740 共0.009兲
25 081.042 共0.009兲
25 103.692 共0.087兲*
25 103.161 共0.087兲
25 103.936 共0.087兲
25 103.981 共0.087兲
25 206.857 共0.039兲*
25 206.731 共0.039兲
25 206.748 共0.039兲
25 207.090 共0.039兲
25 373.918 共0.082兲*
25 373.381 共0.082兲
25 374.165 共0.082兲
25 374.211 共0.082兲
25 725.908 共0.014兲*
25 810.850 共0.035兲*
25 810.692 共0.035兲
25 810.716 共0.035兲
25 811.142 共0.035兲
26 334.106 共0.070兲*
26 333.554 共0.070兲
26 334.360 共0.070兲
26 334.407 共0.070兲
26 337.839 共0.219兲*
26 337.578 共0.219兲
26 337.962 共0.219兲
26 337.976 共0.219兲
26 493.596 共0.081兲*
26 493.490 共0.081兲
26 493.503 共0.081兲
731.295
624.599
624.599
624.599
624.599
250.916
250.916
250.916
250.916
624.539
624.539
624.539
624.539
44.005
44.005
44.005
44.005
43.846
43.846
43.846
43.846
279.750
279.750
279.750
279.750
44.009
44.010
44.009
44.009
237.213
237.213
237.213
237.213
309.093
309.093
309.093
309.093
237.249
237.249
237.249
237.249
690.654
252.076
252.076
252.076
252.076
237.011
237.011
237.011
237.011
624.463
624.463
624.463
624.463
371.744
371.744
371.744
5.929
0.054
0.018
0.019
0.017
0.082
0.026
0.029
0.027
0.055
0.018
0.019
0.018
0.023
0.007
0.008
0.006
0.028
0.009
0.011
0.008
43.438
13.699
15.184
14.403
0.023
0.007
0.009
0.007
0.044
0.014
0.015
0.014
46.866
14.823
16.347
15.548
0.038
0.013
0.013
0.012
5.564
40.587
12.758
14.221
13.450
0.039
0.013
0.014
0.012
0.046
0.015
0.016
0.015
52.901
16.815
18.382
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
Ref.
3
3
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1161
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
22
18
18
18
18
7
7
7
7
17
17
17
17
15
17
4
4
4
4
19
19
19
19
18
18
18
18
10
10
10
10
4
4
4
4
29
29
29
29
17
17
17
17
28
28
29
29
29
29
21
21
21
21
29
29
29
29
1
0
0
0
0
1
1
1
1
2
2
2
2
5
4
2
2
2
2
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
3
3
3
3
1
1
1
1
7
7
3
3
3
3
1
1
1
1
3
3
3
3
A2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B1
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
22
22
17
17
17
17
7
7
7
7
17
17
17
17
16
16
5
5
5
5
19
19
19
19
18
18
18
18
9
9
9
9
5
5
5
5
29
29
29
29
17
17
17
17
27
27
29
29
29
29
21
21
21
21
29
29
29
29
0
3
3
3
3
1
1
1
1
2
2
2
2
4
5
1
1
1
1
0
0
0
0
0
0
0
0
3
3
3
3
1
1
1
1
3
3
3
3
0
0
0
0
8
8
3
3
3
3
0
0
0
0
3
3
3
3
A1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B2
A1
A1
A1
A1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
22
17
19
18
7
8
6
17
18
16
4
5
3
18
20
19
17
19
18
9
11
10
4
5
3
29
30
28
16
18
17
29
30
28
20
22
21
29
30
28
Obs. Freq. 共unc.兲
共MHz兲
16
18
17
7
8
6
17
18
16
27 504.750 共0.500兲
27 758.400 共0.500兲
5
6
4
28 107.750 共0.500兲
18
20
19
28 142.850 共0.500兲
17
19
18
8
10
9
28 533.900 共0.500兲
5
6
4
29
30
28
29 055.200 共0.500兲
16
18
17
29
30
28
29 191.470 共0.500兲
20
22
21
29
30
28
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
26 493.793 共0.081兲
26 947.496 共0.043兲*
26 947.094 共0.043兲
26 947.152 共0.043兲
26 948.238 共0.043兲
27 306.927 共0.008兲*
27 305.563 共0.008兲
27 307.489 共0.008兲
27 307.766 共0.008兲
27 387.721 共0.064兲*
27 387.199 共0.064兲
27 387.961 共0.064兲
27 388.006 共0.064兲
27 504.974 共0.010兲*
27 758.481 共0.010兲*
28 027.269 共0.008兲*
28 026.377 共0.008兲
28 027.617 共0.008兲
28 027.853 共0.008兲
28 107.994 共0.034兲*
28 107.851 共0.034兲
28 107.872 共0.034兲
28 108.258 共0.034兲
28 143.214 共0.051兲*
28 143.046 共0.051兲
28 143.071 共0.051兲
28 143.523 共0.051兲
28 513.369 共0.008兲*
28 513.313 共0.008兲
28 513.322 共0.008兲
28 513.473 共0.008兲
28 533.759 共0.007兲*
28 532.721 共0.007兲
28 534.163 共0.007兲
28 534.440 共0.007兲
28 608.480 共0.280兲*
28 608.168 共0.280兲
28 608.629 共0.280兲
28 608.645 共0.280兲
29 055.515 共0.031兲*
29 055.337 共0.031兲
29 055.365 共0.031兲
29 055.840 共0.031兲
29 098.539 共0.014兲*
29 098.558 共0.014兲*
29 113.250 共0.267兲*
29 112.933 共0.267兲
29 113.401 共0.267兲
29 113.417 共0.267兲
29 191.915 共0.067兲*
29 191.795 共0.067兲
29 191.811 共0.067兲
29 192.139 共0.067兲
29 264.097 共0.254兲*
29 263.780 共0.254兲
29 264.247 共0.254兲
29 264.263 共0.254兲
371.744
251.012
251.012
251.012
251.012
43.893
43.894
43.893
43.893
236.974
236.974
236.974
236.974
244.429
268.904
24.834
24.834
24.834
24.834
279.815
279.815
279.815
279.815
251.911
251.911
251.911
251.911
91.250
91.250
91.250
91.250
24.974
24.974
24.974
24.974
667.480
667.480
667.480
667.480
225.687
225.687
225.687
225.687
731.265
731.265
667.392
667.392
667.392
667.392
339.575
339.575
339.575
339.575
667.334
667.334
667.334
667.334
17.564
0.088
0.028
0.031
0.029
0.021
0.007
0.008
0.006
0.038
0.013
0.013
0.012
3.270
3.637
0.165
0.053
0.065
0.043
43.706
13.783
15.278
14.492
40.348
12.683
14.137
13.371
2.143
0.639
0.782
0.707
0.283
0.091
0.112
0.073
0.053
0.018
0.018
0.017
37.534
11.756
13.186
12.430
5.921
5.921
0.051
0.017
0.018
0.017
49.677
15.753
17.293
16.487
0.053
0.017
0.018
0.017
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
1
1
1
1
1
1
1
1
1
1
1
1
Ref.
3
3
3
3
4
3
3
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1162
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
6
6
6
6
4
4
4
4
22
22
18
18
18
18
4
4
4
4
18
18
18
18
21
21
29
29
29
29
18
18
18
18
18
18
18
18
17
17
17
17
8
8
8
8
8
8
8
8
8
8
8
8
20
20
20
20
17
1
1
1
1
2
2
2
2
7
7
0
0
0
0
2
2
2
2
2
2
2
2
5
5
3
3
3
3
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
4
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
A1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
B1
B1
B1
B1
A1
A1
A1
A1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A1
F⬘
6
7
5
4
5
3
17
19
18
4
5
3
18
19
17
29
30
28
17
19
18
18
19
17
16
18
17
8
9
7
8
9
7
8
9
7
19
21
20
J⬙
K⬙a
⌫⬙
5
5
5
5
5
5
5
5
23
23
17
17
17
17
5
5
5
5
18
18
18
18
20
20
29
29
29
29
18
18
18
18
18
18
18
18
17
17
17
17
8
8
8
8
8
8
8
8
8
8
8
8
20
20
20
20
16
2
2
2
2
1
1
1
1
6
6
3
3
3
3
1
1
1
1
2
2
2
2
6
6
3
3
3
3
0
0
0
0
2
2
2
2
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
5
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
A2
A2
A2
A2
A2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B2
B2
B2
B2
A2
A2
A2
A2
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
A2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
5
6
4
29 771.400 共0.500兲
5
6
4
16
18
17
30 565.900 共0.500兲
5
6
4
18
19
17
29
30
28
31 221.000 共0.500兲
17
19
18
18
19
17
31 583.640 共0.500兲
16
18
17
8
9
7
8
9
7
8
9
7
32 112.710 共0.500兲
19
21
20
32 155.000 共0.500兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
29 307.163 共0.010兲*
29 306.672 共0.010兲
29 307.355 共0.010兲
29 307.485 共0.010兲
29 771.054 共0.008兲*
29 770.160 共0.008兲
29 771.403 共0.008兲
29 771.640 共0.008兲
30 088.199 共0.014兲*
30 236.457 共0.011兲*
30 444.449 共0.040兲*
30 444.049 共0.040兲
30 444.107 共0.040兲
30 445.186 共0.040兲
30 565.730 共0.009兲*
30 564.661 共0.009兲
30 566.146 共0.009兲
30 566.431 共0.009兲
30 919.395 共0.110兲*
30 918.817 共0.110兲
30 919.662 共0.110兲
30 919.709 共0.110兲
30 993.856 共0.010兲*
30 997.166 共0.010兲*
31 050.689 共0.261兲*
31 050.389 共0.261兲
31 050.831 共0.261兲
31 050.847 共0.261兲
31 220.869 共0.029兲*
31 220.707 共0.029兲
31 220.731 共0.029兲
31 221.166 共0.029兲
31 241.590 共0.103兲*
31 241.006 共0.103兲
31 241.860 共0.103兲
31 241.907 共0.103兲
31 583.276 共0.045兲*
31 583.088 共0.045兲
31 583.118 共0.045兲
31 583.619 共0.045兲
31 640.247 共0.018兲*
31 638.734 共0.018兲
31 640.885 共0.018兲
31 641.156 共0.018兲
31 695.396 共0.018兲*
31 693.882 共0.018兲
31 696.033 共0.018兲
31 696.304 共0.018兲
31 977.468 共0.011兲*
31 975.973 共0.011兲
31 978.097 共0.011兲
31 978.365 共0.011兲
32 112.424 共0.054兲*
32 112.288 共0.054兲
32 112.307 共0.054兲
32 112.677 共0.054兲
32 154.912 共0.008兲*
33.398
33.398
33.398
33.398
24.834
24.834
24.834
24.834
505.199
505.326
250.964
250.964
250.964
250.964
24.977
24.977
24.977
24.977
263.765
263.765
263.765
263.765
407.913
407.913
667.265
667.265
667.265
667.265
251.980
251.980
251.980
251.980
263.801
263.801
263.801
263.801
225.516
225.516
225.516
225.516
55.712
55.712
55.712
55.712
55.553
55.553
55.553
55.553
55.719
55.719
55.719
55.719
308.847
308.847
308.847
308.847
268.594
1.398
0.453
0.538
0.381
0.759
0.243
0.299
0.197
4.683
4.674
0.058
0.018
0.020
0.019
0.914
0.292
0.360
0.237
0.041
0.014
0.014
0.013
4.537
4.537
0.046
0.015
0.016
0.015
40.599
12.762
14.225
13.454
0.035
0.012
0.012
0.011
37.326
11.690
13.112
12.361
0.019
0.006
0.007
0.006
0.026
0.008
0.009
0.007
0.020
0.007
0.007
0.006
46.488
14.703
16.215
15.422
3.648
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
Ref.
4
4
3
3
3
6
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1163
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
17
6
6
6
6
11
11
18
18
18
18
26
16
16
16
16
11
18
18
18
18
17
26
8
8
8
8
28
28
28
15
15
15
15
6
6
6
6
30
30
30
30
17
17
17
17
22
22
10
10
10
10
30
30
30
30
30
4
1
1
1
1
4
4
2
2
2
2
1
1
1
1
1
4
2
2
2
2
4
1
1
1
1
1
7
7
7
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
7
7
2
2
2
2
3
3
3
3
3
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E2 − 1
F⬘
6
7
5
18
19
17
15
17
16
18
19
17
8
9
7
15
16
14
6
7
5
30
31
29
16
18
17
9
11
10
30
31
29
J⬙
K⬙a
⌫⬙
16
5
5
5
5
12
12
18
18
18
18
25
16
16
16
16
12
18
18
18
18
16
25
8
8
8
8
27
27
27
16
16
16
16
5
5
5
5
30
30
30
30
17
17
17
17
23
23
9
9
9
9
30
30
30
30
30
5
2
2
2
2
3
3
2
2
2
2
4
0
0
0
0
3
2
2
2
2
5
4
1
1
1
1
8
8
8
0
0
0
0
2
2
2
2
3
3
3
3
0
0
0
0
6
6
3
3
3
3
3
3
3
3
3
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
A1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
32 187.000 共0.500兲
32 283.000 共0.500兲
5
6
4
18
19
17
32 467.760 共0.500兲
15
17
16
32 469.010 共0.500兲
18
19
17
33 152.000 共0.500兲
8
9
7
16
17
15
5
6
4
30
31
29
34 527.510 共0.500兲
16
18
17
8
10
9
30
31
29
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
32 186.678 共0.008兲*
32 282.626 共0.008兲*
32 282.136 共0.008兲
32 282.817 共0.008兲
32 282.948 共0.008兲
32 287.197 共0.008兲*
32 305.992 共0.009兲*
32 370.756 共0.086兲*
32 370.156 共0.086兲
32 371.033 共0.086兲
32 371.082 共0.086兲
32 403.107 共0.249兲*
32 468.016 共0.028兲*
32 467.819 共0.028兲
32 467.852 共0.028兲
32 468.377 共0.028兲
32 469.094 共0.008兲*
33 151.069 共0.080兲*
33 150.491 共0.080兲
33 151.336 共0.080兲
33 151.383 共0.080兲
33 152.078 共0.012兲*
33 284.571 共0.235兲*
33 760.994 共0.010兲*
33 759.577 共0.010兲
33 761.590 共0.010兲
33 761.844 共0.010兲
33 862.179 共0.017兲*
33 989.067 共0.022兲*
33 989.086 共0.022兲*
34 002.238 共0.029兲*
34 001.601 共0.029兲
34 002.531 共0.029兲
34 002.587 共0.029兲
34 279.736 共0.010兲*
34 279.343 共0.010兲
34 279.888 共0.010兲
34 279.996 共0.010兲
34 329.867 共0.337兲*
34 329.521 共0.337兲
34 330.032 共0.337兲
34 330.049 共0.337兲
34 527.671 共0.025兲*
34 527.490 共0.025兲
34 527.518 共0.025兲
34 528.002 共0.025兲
34 623.414 共0.014兲*
34 623.531 共0.014兲*
34 896.565 共0.011兲*
34 896.474 共0.011兲
34 896.492 共0.011兲
34 896.727 共0.011兲
34 918.773 共0.321兲*
34 918.422 共0.321兲
34 918.941 共0.321兲
34 918.958 共0.321兲
35 068.706 共0.301兲*
268.594
33.322
33.322
33.322
33.322
139.984
139.870
263.563
263.563
263.563
263.563
523.960
200.745
200.745
200.745
200.745
139.978
263.530
263.530
263.530
263.530
268.755
523.990
55.610
55.610
55.610
55.610
730.947
731.129
731.129
200.647
200.647
200.647
200.647
33.224
33.224
33.224
33.224
711.736
711.736
711.736
711.736
225.590
225.590
225.590
225.590
505.364
505.364
91.145
91.145
91.145
91.145
711.649
711.649
711.649
711.649
711.594
3.648
0.894
0.290
0.344
0.244
2.377
2.376
0.036
0.012
0.013
0.011
0.047
34.556
10.778
12.175
11.434
2.376
0.037
0.012
0.013
0.012
3.642
0.052
0.021
0.007
0.008
0.006
5.939
5.929
5.929
0.025
0.008
0.009
0.008
0.428
0.139
0.165
0.117
0.051
0.017
0.018
0.016
37.557
11.763
13.193
12.437
4.671
4.671
0.617
0.184
0.225
0.204
0.049
0.016
0.017
0.016
0.050
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
3
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
6
6
7
9
6
7
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1164
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
30
30
30
16
16
16
16
19
19
19
19
15
15
15
15
6
6
6
6
11
18
18
18
18
29
29
4
4
4
4
30
30
30
30
22
22
15
15
15
15
10
10
10
10
19
19
19
19
26
18
10
10
10
10
19
19
19
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
4
0
0
0
0
9
9
2
2
2
2
3
3
3
3
7
7
3
3
3
3
2
2
2
2
2
2
2
2
1
6
2
2
2
2
2
2
2
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
30
31
29
30
30
30
16
16
16
16
19
19
19
19
15
15
15
15
5
5
5
5
12
17
17
17
17
30
30
5
5
5
5
30
30
30
30
23
23
16
16
16
16
9
9
9
9
19
19
19
19
25
19
9
9
9
9
19
19
19
3
3
3
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
2
3
3
3
3
3
8
8
1
1
1
1
3
3
3
3
6
6
0
0
0
0
3
3
3
3
2
2
2
2
4
5
3
3
3
3
2
2
2
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
30
31
29
15
17
16
18
20
19
14
16
15
6
7
5
17
19
18
4
5
3
30
31
29
15
16
14
9
11
10
19
20
18
11
9
10
19
20
Obs. Freq. 共unc.兲
共MHz兲
35 182.730 共0.500兲
15
17
16
18
20
19
36 014.900 共0.500兲
14
16
15
5
6
4
16
18
17
36 452.100 共0.500兲
5
6
4
30
31
29
16
17
15
8
10
9
19
20
18
10
8
9
19
20
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
35 068.355 共0.301兲
35 068.874 共0.301兲
35 068.891 共0.301兲
35 182.874 共0.040兲*
35 182.667 共0.040兲
35 182.701 共0.040兲
35 183.253 共0.040兲
35 247.763 共0.043兲*
35 247.610 共0.043兲
35 247.632 共0.043兲
35 248.047 共0.043兲
36 015.206 共0.024兲*
36 014.987 共0.024兲
36 015.026 共0.024兲
36 015.602 共0.024兲
36 034.653 共0.009兲*
36 034.252 共0.009兲
36 034.809 共0.009兲
36 034.919 共0.009兲
36 066.769 共0.009兲*
36 234.540 共0.038兲*
36 234.134 共0.038兲
36 234.193 共0.038兲
36 235.290 共0.038兲
36 399.947 共0.033兲*
36 399.947 共0.033兲*
36 452.374 共0.009兲*
36 451.305 共0.010兲
36 452.791 共0.009兲
36 453.076 共0.010兲
36 597.062 共0.308兲*
36 596.723 共0.308兲
36 597.223 共0.308兲
36 597.240 共0.308兲
36 792.477 共0.013兲*
36 792.596 共0.013兲*
37 013.782 共0.028兲*
37 013.146 共0.028兲
37 014.074 共0.028兲
37 014.130 共0.028兲
37 233.653 共0.008兲*
37 233.562 共0.008兲
37 233.579 共0.008兲
37 233.816 共0.008兲
37 566.135 共0.138兲*
37 565.511 共0.138兲
37 566.424 共0.138兲
37 566.472 共0.138兲
37 608.482 共0.262兲*
37 854.756 共0.011兲*
37 878.842 共0.011兲*
37 878.830 共0.011兲
37 878.832 共0.011兲
37 878.866 共0.011兲
37 943.777 共0.129兲*
37 943.147 共0.129兲
37 944.069 共0.129兲
711.594
711.594
711.594
200.570
200.570
200.570
200.570
279.562
279.562
279.562
279.562
177.253
177.253
177.253
177.253
33.165
33.165
33.165
33.165
140.052
250.867
250.867
250.867
250.867
859.525
859.525
24.818
24.818
24.818
24.818
711.530
711.530
711.530
711.530
505.265
505.265
200.745
200.745
200.745
200.745
91.067
91.067
91.067
91.068
291.784
291.784
291.784
291.784
523.845
348.689
91.250
91.250
91.250
91.250
291.819
291.819
291.819
0.017
0.017
0.016
34.385
10.725
12.114
11.378
43.345
13.669
15.151
14.372
31.665
9.830
11.192
10.467
0.966
0.313
0.371
0.263
2.374
0.076
0.024
0.027
0.025
6.077
6.077
0.914
0.293
0.360
0.237
0.046
0.015
0.016
0.015
4.677
4.677
0.022
0.007
0.008
0.007
1.607
0.479
0.587
0.530
0.039
0.013
0.014
0.012
0.043
3.795
0.086
0.031
0.026
0.028
0.032
0.011
0.011
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
1
3
3
3
3
3
3
3
Ref.
7
7
4
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1165
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
19
16
16
16
16
11
10
10
10
10
18
18
18
18
10
10
10
10
15
15
15
15
18
18
18
18
26
19
19
19
19
15
15
15
15
21
21
9
9
9
9
9
9
9
9
14
14
14
14
9
9
9
9
19
19
19
19
2
1
1
1
1
4
2
2
2
2
1
1
1
1
2
2
2
2
1
1
1
1
0
0
0
0
1
2
2
2
2
3
3
3
3
5
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
A2
A2
A2
A2
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
18
19
16
16
16
16
12
9
9
9
9
18
18
18
18
9
9
9
9
15
15
15
15
17
17
17
17
25
19
19
19
19
16
16
16
16
20
20
9
9
9
9
9
9
9
9
14
14
14
14
9
9
9
9
19
19
19
19
2
0
0
0
0
3
3
3
3
3
0
0
0
0
3
3
3
3
0
0
0
0
3
3
3
3
4
2
2
2
2
0
0
0
0
6
6
1
1
1
1
1
1
1
1
0
0
0
0
1
1
1
1
2
2
2
2
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B1
A1
A1
A1
A1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
18
15
17
16
9
11
10
17
19
18
10
11
9
14
16
15
17
19
18
19
20
18
15
16
14
9
10
8
9
10
8
13
15
14
9
10
8
19
20
18
Obs. Freq. 共unc.兲
共MHz兲
38 002.870 共0.500兲
15
17
16
8
10
9
17
19
18
9
10
8
14
16
15
16
18
17
19
20
18
16
17
15
9
10
8
9
10
8
13
15
14
9
10
8
19
20
18
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
37 944.117 共0.129兲
38 003.250 共0.022兲*
38 003.049 共0.022兲
38 003.082 共0.022兲
38 003.617 共0.022兲
38 216.581 共0.009兲*
38 252.306 共0.009兲*
38 252.211 共0.009兲
38 252.229 共0.009兲
38 252.478 共0.009兲
38 584.163 共0.035兲*
38 583.991 共0.035兲
38 584.017 共0.035兲
38 584.479 共0.035兲
38 859.729 共0.010兲*
38 859.692 共0.010兲
38 859.743 共0.010兲
38 859.755 共0.010兲
38 908.496 共0.035兲*
38 908.268 共0.035兲
38 908.308 共0.035兲
38 908.911 共0.035兲
38 951.317 共0.042兲*
38 950.922 共0.042兲
38 950.979 共0.042兲
38 952.045 共0.042兲
38 968.581 共0.380兲*
39 258.199 共0.105兲*
39 257.552 共0.105兲
39 258.499 共0.105兲
39 258.548 共0.105兲
39 451.294 共0.027兲*
39 450.653 共0.027兲
39 451.589 共0.027兲
39 451.645 共0.027兲
39 518.315 共0.011兲*
39 521.575 共0.011兲*
39 531.930 共0.021兲*
39 530.417 共0.021兲
39 532.578 共0.021兲
39 532.819 共0.021兲
39 601.070 共0.022兲*
39 599.557 共0.022兲
39 601.718 共0.022兲
39 601.959 共0.022兲
39 656.850 共0.021兲*
39 656.610 共0.021兲
39 656.655 共0.021兲
39 657.281 共0.021兲
39 774.639 共0.013兲*
39 773.139 共0.013兲
39 775.281 共0.013兲
39 775.521 共0.013兲
39 818.495 共0.098兲*
39 817.866 共0.098兲
39 818.787 共0.098兲
39 818.835 共0.098兲
291.819
200.647
200.647
200.647
200.647
139.948
91.277
91.277
91.277
91.277
251.720
251.720
251.720
251.720
91.145
91.145
91.145
91.145
177.073
177.072
177.072
177.073
250.776
250.776
250.776
250.776
523.811
291.582
291.582
291.582
291.582
200.745
200.745
200.745
200.745
407.812
407.812
68.880
68.880
68.880
68.880
68.721
68.721
68.721
68.721
155.212
155.211
155.211
155.212
68.888
68.888
68.888
68.888
291.552
291.552
291.552
291.552
0.010
34.592
10.789
12.187
11.446
2.373
2.217
0.661
0.810
0.732
40.259
12.655
14.106
13.341
1.610
0.531
0.588
0.480
31.536
9.790
11.147
10.425
0.023
0.007
0.008
0.008
0.088
0.034
0.011
0.012
0.011
0.040
0.013
0.014
0.012
4.535
4.535
0.017
0.005
0.006
0.005
0.024
0.008
0.009
0.007
28.870
8.914
10.241
9.532
0.018
0.006
0.007
0.005
0.035
0.012
0.012
0.011
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
Ref.
7
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1166
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
7
7
7
7
10
10
10
10
10
10
10
10
22
26
26
21
6
6
6
6
21
10
10
10
10
9
9
9
9
3
3
3
3
15
15
15
15
10
10
10
10
18
18
18
18
17
17
17
17
14
14
14
14
21
11
13
13
3
3
3
3
2
2
2
2
2
2
2
2
7
1
1
5
1
1
1
1
5
2
2
2
2
1
1
1
1
0
0
0
0
1
1
1
1
2
2
2
2
0
0
0
0
1
1
1
1
1
1
1
1
5
4
1
1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
E2 − 1
E2 + 1
B1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B2
B2
B2
B2
E1 + 1
E1 + 1
E2 − 1
E2 − 1
F⬘
7
8
6
9
11
10
9
11
10
6
7
5
10
11
9
9
10
8
2
4
3
14
16
15
10
11
9
17
19
18
16
18
17
13
15
14
12
J⬙
K⬙a
⌫⬙
8
8
8
8
9
9
9
9
9
9
9
9
23
25
25
20
5
5
5
5
20
9
9
9
9
9
9
9
9
2
2
2
2
15
15
15
15
9
9
9
9
17
17
17
17
17
17
17
17
14
14
14
14
20
12
13
13
2
2
2
2
3
3
3
3
3
3
3
3
6
4
4
6
2
2
2
2
6
3
3
3
3
1
1
1
1
1
1
1
1
0
0
0
0
3
3
3
3
3
3
3
3
0
0
0
0
0
0
0
0
6
3
0
0
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E2 − 1
E2 + 1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B1
B1
B1
B1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
8
9
7
8
10
9
8
10
9
5
6
4
9
10
8
9
10
8
1
3
2
41 615.340 共0.500兲
14
16
15
41 658.420 共0.500兲
9
10
8
16
18
17
42 101.940 共0.500兲
16
18
17
42 720.940 共0.500兲
13
15
14
42 804.580 共0.500兲
43 040.720 共0.500兲
43 346.580 共0.500兲
12
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
39 948.261 共0.008兲*
39 948.117 共0.008兲
39 948.324 共0.008兲
39 948.343 共0.008兲
40 060.218 共0.007兲*
40 060.161 共0.007兲
40 060.170 共0.007兲
40 060.323 共0.007兲
40 134.536 共0.011兲*
40 134.440 共0.011兲
40 134.459 共0.011兲
40 134.707 共0.011兲
40 249.736 共0.014兲*
40 263.454 共0.276兲*
40 498.584 共0.388兲*
40 706.706 共0.011兲*
41 036.913 共0.009兲*
41 036.422 共0.009兲
41 037.105 共0.009兲
41 037.236 共0.009兲
41 165.885 共0.013兲*
41 196.817 共0.008兲*
41 196.781 共0.008兲
41 196.831 共0.008兲
41 196.842 共0.008兲
41 232.752 共0.012兲*
41 231.303 共0.012兲
41 233.372 共0.012兲
41 233.603 共0.012兲
41 263.780 共0.008兲*
41 262.825 共0.008兲
41 263.442 共0.008兲
41 264.860 共0.008兲
41 615.271 共0.019兲*
41 615.049 共0.019兲
41 615.088 共0.019兲
41 615.674 共0.019兲
41 658.481 共0.009兲*
41 658.443 共0.009兲
41 658.495 共0.009兲
41 658.506 共0.009兲
41 859.373 共0.041兲*
41 858.975 共0.041兲
41 859.032 共0.041兲
41 860.110 共0.041兲
42 101.038 共0.027兲*
42 100.847 共0.027兲
42 100.877 共0.027兲
42 101.389 共0.027兲
42 720.607 共0.031兲*
42 720.357 共0.031兲
42 720.404 共0.031兲
42 721.057 共0.031兲
42 804.395 共0.013兲*
43 040.424 共0.009兲*
43 346.435 共0.019兲*
43 346.175 共0.019兲
64.390
64.390
64.390
64.390
90.864
90.864
90.864
90.864
91.177
91.177
91.177
91.177
505.009
523.698
523.635
407.748
33.030
33.030
33.030
33.030
407.967
91.067
91.068
91.067
91.067
68.785
68.786
68.785
68.785
7.496
7.496
7.496
7.496
177.154
177.154
177.154
177.154
91.278
91.279
91.278
91.278
250.583
250.583
250.583
250.584
225.323
225.323
225.323
225.323
155.027
155.027
155.027
155.027
407.875
139.668
134.624
134.624
1.475
0.484
0.550
0.426
0.083
0.025
0.030
0.028
2.221
0.662
0.811
0.733
4.683
0.044
0.081
4.534
0.508
0.165
0.195
0.139
4.524
0.623
0.206
0.227
0.186
0.020
0.006
0.007
0.006
1.541
0.308
0.661
0.457
31.716
9.846
11.210
10.484
2.230
0.736
0.814
0.665
0.038
0.012
0.013
0.013
37.244
11.665
13.083
12.334
28.789
8.889
10.212
9.505
4.531
2.380
26.178
8.032
3
3
3
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
1
1
Ref.
6
6
6
6
6
6
6
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1167
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
13
13
10
10
10
10
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
29
20
20
20
20
14
14
14
14
15
15
15
15
20
20
20
20
29
29
29
16
16
16
16
18
14
7
7
7
7
29
7
7
7
7
1
1
2
2
2
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
2
2
2
2
1
1
1
1
3
3
3
3
2
2
2
2
9
9
9
1
1
1
1
6
3
1
1
1
1
9
3
3
3
3
E2 − 1
E2 − 1
A1
A1
A1
A1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
A2
A
A1
A2
A2
A2
A2
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 − 1
A2
A2
A2
A2
14
13
13
13
9
9
9
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
30
20
20
20
20
14
14
14
14
16
16
16
16
20
20
20
20
30
30
30
16
16
16
16
19
13
6
6
6
6
30
8
8
8
8
0
0
3
3
3
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
2
2
2
2
0
0
0
0
0
0
0
0
2
2
2
2
8
8
8
0
0
0
0
5
4
2
2
2
2
8
2
2
2
2
E2 + 1
E2 + 1
A2
A2
A2
A2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A1
A
A2
A1
A1
A1
A1
E1 + 1
E1 + 1
B2
B2
B2
B2
E1 − 1
A1
A1
A1
A1
14
13
10
11
9
0
2
1
0
2
1
0
2
1
0
2
1
20
21
19
13
15
14
15
16
14
20
21
19
15
17
16
6
8
7
7
8
6
Obs. Freq. 共unc.兲
共MHz兲
43 498.320 共0.500兲
9
10
8
44 338.070 共0.500兲
1
1
1
1
1
1
44 338.860 共0.500兲
1
1
1
44 338.860 共0.500兲
1
1
1
20
21
19
45 324.520 共0.500兲
13
15
14
16
17
15
20
21
19
45 759.260 共0.500兲
45 769.960 共0.500兲
15
17
16
45 957.660 共0.500兲
45 994.560 共0.500兲
5
7
6
46 544.840 共0.500兲
8
9
7
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
43 346.227 共0.019兲
43 346.900 共0.019兲
43 498.183 共0.010兲*
43 498.149 共0.010兲
43 498.196 共0.010兲
43 498.207 共0.010兲
44 337.938 共0.001兲*
44 336.732 共0.002兲
44 337.818 共0.001兲
44 338.542 共0.001兲
44 338.468 共0.001兲*
44 337.262 共0.002兲
44 338.348 共0.001兲
44 339.072 共0.001兲
44 338.755 共0.001兲*
44 337.548 共0.002兲
44 338.634 共0.001兲
44 339.358 共0.001兲
44 338.876 共0.001兲*
44 337.669 共0.002兲
44 338.756 共0.001兲
44 339.480 共0.001兲
45 027.956 共0.060兲*
45 077.158 共0.171兲*
45 076.491 共0.171兲
45 077.469 共0.171兲
45 077.518 共0.171兲
45 324.797 共0.016兲*
45 324.553 共0.016兲
45 324.599 共0.016兲
45 325.236 共0.016兲
45 438.942 共0.028兲*
45 438.307 共0.028兲
45 439.234 共0.028兲
45 439.289 共0.028兲
45 512.862 共0.160兲*
45 512.188 共0.160兲
45 513.175 共0.160兲
45 513.224 共0.160兲
45 759.185 共0.030兲*
45 759.186 共0.030兲*
45 759.186 共0.030兲*
45 770.937 共0.022兲*
45 770.726 共0.022兲
45 770.761 共0.022兲
45 771.322 共0.022兲
45 957.512 共0.012兲*
45 994.525 共0.009兲*
46 380.508 共0.011兲*
46 379.955 共0.011兲
46 380.127 共0.011兲
46 381.421 共0.011兲
46 410.195 共0.032兲*
46 544.555 共0.009兲*
46 544.465 共0.009兲
46 544.596 共0.009兲
46 544.605 共0.009兲
134.624
134.624
91.179
91.179
91.179
91.179
0.206
0.206
0.206
0.206
0.404
0.404
0.404
0.404
0.000
0.000
0.000
0.000
0.301
0.301
0.301
0.301
859.557
321.268
321.268
321.268
321.268
155.112
155.112
155.112
155.112
200.647
200.647
200.647
200.647
321.303
321.303
321.303
321.303
859.391
859.391
859.391
200.374
200.374
200.374
200.374
348.739
178.064
42.299
42.299
42.299
42.299
859.595
64.484
64.484
64.484
64.484
9.325
8.630
2.234
0.737
0.816
0.666
0.095
0.011
0.053
0.032
0.094
0.010
0.052
0.031
0.094
0.010
0.052
0.031
0.094
0.010
0.052
0.031
6.070
0.037
0.012
0.013
0.012
28.941
8.936
10.266
9.555
0.034
0.011
0.012
0.011
0.030
0.010
0.010
0.009
6.074
12.147
6.074
34.310
10.702
12.088
11.353
3.789
3.128
1.596
0.450
0.603
0.521
6.063
1.486
0.488
0.554
0.429
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
3
1
1
1
1
1
3
3
3
3
3
3
3
1
1
1
1
Ref.
6
7
7
7
6
6
6
6
6
6
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1168
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
13
13
13
13
20
20
20
20
12
12
12
12
20
20
20
20
29
18
7
7
7
7
18
10
10
10
10
3
3
3
3
14
7
7
7
7
25
7
7
7
7
15
15
15
15
13
13
13
13
18
18
10
10
10
10
15
15
1
1
1
1
2
2
2
2
1
1
1
1
2
2
2
2
9
6
3
3
3
3
6
1
1
1
1
0
0
0
0
3
3
3
3
3
6
3
3
3
3
3
3
3
3
1
1
1
1
6
6
2
2
2
2
1
1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 − 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B2
B2
B2
B2
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
F⬘
12
14
13
20
21
19
11
13
12
20
21
19
7
8
6
10
11
9
2
4
3
7
8
6
7
8
6
15
16
14
12
14
13
11
9
10
14
J⬙
K⬙a
⌫⬙
13
13
13
13
20
20
20
20
12
12
12
12
20
20
20
20
30
19
8
8
8
8
19
10
10
10
10
2
2
2
2
13
8
8
8
8
24
8
8
8
8
16
16
16
16
13
13
13
13
19
19
9
9
9
9
15
15
0
0
0
0
2
2
2
2
0
0
0
0
2
2
2
2
8
5
2
2
2
2
5
1
1
1
1
1
1
1
1
4
2
2
2
2
7
2
2
2
2
0
0
0
0
0
0
0
0
5
5
3
3
3
3
0
0
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 − 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
46 575.180 共0.500兲
12
14
13
20
21
19
47 032.080 共0.500兲
11
13
12
20
21
19
47 608.080 共0.500兲
8
9
7
10
11
9
48 385.200 共0.500兲
1
3
2
48 414.500 共0.500兲
8
9
7
8
9
7
16
17
15
49 087.192 共0.060兲
12
14
13
49 228.724 共0.020兲
49 229.937 共0.020兲
49 425.686 共0.020兲
10
8
9
49 559.857 共0.020兲
14
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
46 574.707 共0.028兲*
46 574.436 共0.028兲
46 574.490 共0.028兲
46 575.191 共0.028兲
47 025.804 共0.127兲*
47 025.113 共0.127兲
47 026.125 共0.127兲
47 026.176 共0.127兲
47 032.201 共0.016兲*
47 031.921 共0.016兲
47 031.981 共0.016兲
47 032.698 共0.016兲
47 406.587 共0.119兲*
47 405.910 共0.119兲
47 406.902 共0.119兲
47 406.952 共0.119兲
47 564.591 共0.035兲*
47 607.239 共0.012兲*
47 986.442 共0.010兲*
47 986.216 共0.010兲
47 986.540 共0.010兲
47 986.573 共0.010兲
48 082.405 共0.011兲*
48 372.496 共0.025兲*
48 370.986 共0.025兲
48 373.153 共0.025兲
48 373.371 共0.025兲
48 385.595 共0.005兲*
48 385.046 共0.005兲
48 385.373 共0.005兲
48 386.270 共0.005兲
48 409.398 共0.013兲*
48 413.933 共0.008兲*
48 413.845 共0.008兲
48 413.973 共0.008兲
48 413.981 共0.008兲
48 448.455 共0.014兲*
48 770.496 共0.008兲*
48 770.389 共0.008兲
48 770.543 共0.008兲
48 770.555 共0.008兲
48 897.660 共0.033兲*
48 897.026 共0.033兲
48 897.952 共0.033兲
48 898.007 共0.033兲
49 087.261 共0.014兲*
49 086.996 共0.014兲
49 087.049 共0.014兲
49 087.735 共0.014兲
49 228.693 共0.010兲*
49 229.903 共0.010兲*
49 425.691 共0.008兲*
49 425.678 共0.008兲
49 425.680 共0.008兲
49 425.715 共0.008兲
49 559.870 共0.017兲*
49 559.638 共0.017兲
134.437
134.437
134.437
134.437
321.066
321.066
321.066
321.066
115.494
115.494
115.494
115.494
321.039
321.039
321.039
321.039
859.383
348.777
64.436
64.436
64.436
64.436
348.542
83.350
83.350
83.350
83.350
7.559
7.559
7.559
7.559
178.183
64.522
64.522
64.522
64.522
575.721
64.300
64.300
64.300
64.300
200.570
200.570
200.570
200.570
134.524
134.524
134.524
134.524
348.566
348.566
90.864
90.864
90.864
90.864
176.875
176.875
26.151
8.024
9.315
8.621
0.031
0.010
0.011
0.010
23.594
7.185
8.444
7.764
0.034
0.011
0.012
0.011
6.078
3.785
1.482
0.486
0.552
0.428
3.792
0.022
0.007
0.008
0.007
1.128
0.226
0.483
0.334
0.028
1.484
0.487
0.553
0.429
5.428
0.186
0.061
0.069
0.054
0.054
0.018
0.019
0.017
26.273
8.061
9.358
8.662
3.792
3.792
2.148
0.784
0.641
0.709
31.469
9.769
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
6
6
6
7
9
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1169
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
15
15
10
10
10
10
7
7
7
7
12
12
12
12
3
3
3
3
11
11
11
11
14
21
7
7
7
7
7
7
7
7
15
15
15
15
25
25
3
3
3
3
3
3
3
3
7
7
7
7
12
12
12
12
14
7
7
1
1
1
1
1
1
3
3
3
3
1
1
1
1
0
0
0
0
1
1
1
1
3
5
3
3
3
3
3
3
3
3
3
3
3
3
6
6
2
2
2
2
0
0
0
0
1
1
1
1
1
1
1
1
3
3
3
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
16
15
15
15
10
10
10
10
8
8
8
8
12
12
12
12
2
2
2
2
11
11
11
11
13
20
8
8
8
8
8
8
8
8
16
16
16
16
24
24
4
4
4
4
2
2
2
2
6
6
6
6
12
12
12
12
13
8
8
0
0
1
1
1
1
2
2
2
2
0
0
0
0
1
1
1
1
0
0
0
0
4
6
2
2
2
2
2
2
2
2
0
0
0
0
7
7
1
1
1
1
1
1
1
1
2
2
2
2
0
0
0
0
4
2
2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B2
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
E2 + 1
16
15
10
11
9
7
8
6
11
13
12
2
4
3
10
12
11
7
8
6
7
8
6
15
16
14
2
4
3
2
4
3
6
8
7
11
13
12
7
Obs. Freq. 共unc.兲
共MHz兲
10
11
9
49 874.067 共0.020兲
8
9
7
50 423.400 共0.500兲
11
13
12
50 615.829 共0.020兲
1
3
2
50 658.152 共0.060兲
10
12
11
50 797.855 共0.020兲
50 859.798 共0.020兲
51 070.378 共0.020兲
8
9
7
51 098.272 共0.060兲
8
9
7
16
17
15
51 891.380 共0.020兲
51 891.699 共0.020兲
51 939.449 共0.060兲
3
5
4
52 202.361 共0.020兲
1
3
2
52 265.790 共0.020兲
5
7
6
52 853.692 共0.060兲
11
13
12
52 926.708 共0.060兲
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
49 559.678 共0.017兲
49 560.290 共0.017兲
49 671.231 共0.014兲*
49 669.765 共0.014兲
49 671.869 共0.014兲
49 672.080 共0.014兲
49 874.078 共0.008兲*
49 873.852 共0.008兲
49 874.176 共0.008兲
49 874.209 共0.008兲
50 422.652 共0.025兲*
50 422.360 共0.025兲
50 422.422 共0.025兲
50 423.170 共0.025兲
50 615.856 共0.005兲*
50 615.494 共0.005兲
50 615.687 共0.005兲
50 616.343 共0.005兲
50 658.217 共0.014兲*
50 657.917 共0.014兲
50 657.986 共0.014兲
50 658.741 共0.014兲
50 797.859 共0.009兲*
50 859.768 共0.011兲*
51 070.396 共0.008兲*
51 070.193 共0.008兲
51 070.484 共0.008兲
51 070.513 共0.008兲
51 098.340 共0.009兲*
51 098.234 共0.009兲
51 098.387 共0.009兲
51 098.399 共0.009兲
51 828.571 共0.029兲*
51 827.940 共0.029兲
51 828.861 共0.029兲
51 828.916 共0.029兲
51 891.398 共0.011兲*
51 891.717 共0.011兲*
51 939.453 共0.009兲*
51 939.363 共0.010兲
51 939.406 共0.009兲
51 939.581 共0.010兲
52 202.362 共0.008兲*
52 201.407 共0.008兲
52 202.024 共0.008兲
52 203.442 共0.008兲
52 265.796 共0.011兲*
52 265.243 共0.011兲
52 265.415 共0.011兲
52 266.710 共0.011兲
52 853.748 共0.012兲*
52 853.461 共0.012兲
52 853.522 共0.012兲
52 854.256 共0.012兲
52 926.729 共0.009兲*
53 398.239 共0.012兲*
53 398.037 共0.012兲
176.875
176.875
83.420
83.420
83.420
83.420
64.473
64.473
64.473
64.473
115.303
115.303
115.303
115.303
7.588
7.588
7.588
7.588
97.822
97.822
97.822
97.822
178.183
407.555
64.223
64.223
64.223
64.223
64.300
64.300
64.300
64.300
200.374
200.374
200.374
200.374
575.861
575.861
17.985
17.985
17.985
17.985
7.337
7.337
7.337
7.337
42.261
42.261
42.261
42.261
115.392
115.392
115.392
115.392
178.215
64.223
64.223
11.123
10.403
0.019
0.006
0.007
0.006
1.480
0.486
0.552
0.428
23.628
7.195
8.456
7.775
0.936
0.187
0.401
0.277
21.118
6.374
7.598
6.933
3.096
4.538
1.299
0.426
0.484
0.375
1.299
0.426
0.484
0.375
0.050
0.017
0.018
0.016
5.420
5.420
0.155
0.037
0.063
0.049
1.540
0.308
0.660
0.456
1.595
0.450
0.602
0.521
23.719
7.223
8.488
7.805
3.119
0.185
0.061
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
Ref.
1
6
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1170
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
7
7
14
14
14
14
21
21
21
21
7
7
7
7
21
21
21
21
25
25
3
3
3
3
10
10
10
10
11
11
11
11
7
7
7
7
25
25
25
23
23
29
7
7
7
7
14
21
21
21
21
21
21
21
21
3
3
3
3
1
1
1
1
2
2
2
2
1
1
1
1
2
2
2
2
6
6
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
8
8
8
4
4
9
1
1
1
1
5
2
2
2
2
2
2
2
2
2
2
E2 − 1
E2 − 1
A2
A2
A2
A2
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
A1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A1
E1 + 1
B2
E2 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
8
6
8
8
14
14
14
14
21
21
21
21
6
6
6
6
21
21
21
21
24
24
2
2
2
2
10
10
10
10
11
11
11
11
6
6
6
6
26
26
26
24
24
30
6
6
6
6
15
21
21
21
21
21
21
21
21
4
4
2
2
0
0
0
0
2
2
2
2
2
2
2
2
2
2
2
2
7
7
1
1
1
1
0
0
0
0
0
0
0
0
2
2
2
2
7
7
7
1
1
8
2
2
2
2
4
2
2
2
2
2
2
2
2
1
1
E2 + 1
E2 + 1
A1
A1
A1
A1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
A2
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
E1 + 1
B1
E2 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
9
7
13
15
14
21
22
20
6
8
7
21
22
20
3
4
2
9
11
10
10
12
11
6
8
7
6
8
7
21
22
20
21
22
20
3
Obs. Freq. 共unc.兲
共MHz兲
53 428.030 共0.020兲
13
15
14
21
22
20
53 768.278 共0.020兲
5
7
6
21
22
20
54 055.300 共0.500兲
2
3
1
54 165.810 共0.500兲
9
11
10
10
12
11
5
7
6
54 519.149 共0.060兲
54 595.755 共0.060兲
55 547.366 共0.060兲
55 573.349 共0.060兲
5
7
6
55 676.551 共0.020兲
21
22
20
21
22
20
56 040.931 共0.060兲
4
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
53 398.327 共0.012兲
53 398.356 共0.012兲
53 428.037 共0.014兲*
53 427.784 共0.014兲
53 427.832 共0.014兲
53 428.493 共0.014兲
53 477.403 共0.211兲*
53 476.693 共0.211兲
53 477.734 共0.211兲
53 477.783 共0.211兲
53 768.267 共0.009兲*
53 767.726 共0.009兲
53 767.895 共0.009兲
53 769.158 共0.009兲
53 972.839 共0.197兲*
53 972.123 共0.197兲
53 973.172 共0.197兲
53 973.222 共0.197兲
54 037.621 共0.013兲*
54 037.938 共0.013兲*
54 055.072 共0.007兲*
54 055.042 共0.007兲
54 055.051 共0.007兲
54 055.227 共0.007兲
54 165.263 共0.012兲*
54 164.946 共0.012兲
54 165.025 共0.012兲
54 165.812 共0.012兲
54 214.140 共0.021兲*
54 213.826 共0.021兲
54 213.898 共0.021兲
54 214.689 共0.021兲
54 322.317 共0.008兲*
54 321.746 共0.008兲
54 321.925 共0.008兲
54 323.258 共0.008兲
54 519.108 共0.026兲*
54 519.115 共0.026兲*
54 595.701 共0.016兲*
54 865.083 共0.268兲*
54 972.672 共0.199兲*
55 547.408 共0.031兲*
55 573.374 共0.009兲*
55 572.849 共0.009兲
55 573.012 共0.009兲
55 574.242 共0.009兲
55 676.527 共0.011兲*
55 694.565 共0.152兲*
55 693.833 共0.152兲
55 694.906 共0.152兲
55 694.958 共0.152兲
55 926.793 共0.144兲*
55 926.072 共0.144兲
55 927.130 共0.144兲
55 927.180 共0.144兲
56 040.953 共0.010兲*
56 040.874 共0.010兲
64.223
64.223
154.829
154.829
154.829
154.829
352.217
352.217
352.217
352.217
42.100
42.100
42.100
42.100
352.250
352.250
352.250
352.250
575.888
575.888
7.370
7.370
7.370
7.370
81.613
81.613
81.613
81.613
97.630
97.630
97.630
97.630
42.197
42.197
42.197
42.197
651.138
651.138
650.953
449.415
449.480
859.212
42.040
42.040
42.040
42.040
221.084
352.014
352.015
352.014
352.014
351.990
351.990
351.990
351.990
17.984
17.984
0.069
0.053
28.731
8.871
10.192
9.486
0.036
0.012
0.012
0.011
0.961
0.271
0.363
0.314
0.028
0.009
0.010
0.009
5.413
5.413
0.412
0.122
0.176
0.082
18.745
5.597
6.787
6.135
21.221
6.405
7.635
6.967
0.581
0.164
0.219
0.190
5.192
5.192
5.200
0.050
0.029
6.081
0.646
0.182
0.244
0.211
2.902
0.029
0.010
0.010
0.009
0.032
0.011
0.011
0.010
0.535
0.167
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
3
3
1
3
1
1
1
1
3
1
1
1
1
3
3
3
3
1
1
Ref.
1
1
7
7
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1171
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
3
3
23
14
11
11
11
11
14
14
14
14
13
13
13
13
9
9
9
9
23
3
3
3
3
18
18
10
10
10
10
11
11
11
11
25
25
11
11
11
11
14
25
25
25
10
10
10
10
7
7
7
7
19
19
19
19
2
2
4
3
1
1
1
1
5
3
5
3
1
1
1
1
1
1
1
1
4
2
2
2
2
6
6
1
1
1
1
1
1
1
1
6
6
1
1
1
1
3
8
8
8
1
1
1
1
3
3
3
3
0
0
0
0
E2 + 1
E2 + 1
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
E2 + 1
A2
A1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A2
B2
B2
B2
B2
B2
B2
B2
B2
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
B2
B
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
4
2
4
4
24
13
11
11
11
11
15
13
15
13
13
13
13
13
9
9
9
9
24
4
4
4
4
19
19
10
10
10
10
11
11
11
11
24
24
11
11
11
11
13
26
26
26
10
10
10
10
8
8
8
8
18
18
18
18
1
1
1
4
0
0
0
0
4
4
4
4
0
0
0
0
0
0
0
0
1
1
1
1
1
5
5
0
0
0
0
1
1
1
1
7
7
1
1
1
1
4
7
7
7
0
0
0
0
2
2
2
2
3
3
3
3
E2 + 1
E2 + 1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
E2 + 1
A1
A2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A1
B1
B1
B1
B1
B1
B1
B1
B1
E1 + 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
B1
B
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
5
3
10
12
11
12
14
13
8
10
9
3
4
2
9
11
10
11
12
10
11
12
10
9
11
10
7
8
6
18
20
19
Obs. Freq. 共unc.兲
共MHz兲
56 401.131 共0.060兲
56 572.382 共0.060兲
10
12
11
56 647.584 共0.020兲
56 658.684 共0.060兲
56 659.440 共0.020兲
56 847.816 共0.020兲
57 330.891 共0.020兲
12
14
13
57 491.217 共0.020兲
8
10
9
4
5
3
57 898.300 共0.500兲
9
11
10
11
12
10
58 432.951 共0.020兲
58 520.201 共0.060兲
11
12
10
59 450.789 共0.020兲
60 189.952 共0.020兲
9
11
10
60 356.184 共0.060兲
8
9
7
17
19
18
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
56 040.981 共0.010兲
56 041.010 共0.010兲
56 258.490 共0.262兲*
56 401.149 共0.009兲*
56 572.426 共0.011兲*
56 572.118 共0.011兲
56 572.189 共0.011兲
56 572.965 共0.011兲
56 647.585 共0.009兲*
56 658.725 共0.009兲*
56 659.449 共0.009兲*
56 847.819 共0.009兲*
57 330.896 共0.012兲*
57 330.621 共0.012兲
57 330.676 共0.012兲
57 331.385 共0.012兲
57 491.252 共0.010兲*
57 490.920 共0.010兲
57 491.010 共0.010兲
57 491.817 共0.010兲
57 599.225 共0.189兲*
57 785.034 共0.011兲*
57 784.955 共0.011兲
57 785.063 共0.011兲
57 785.092 共0.011兲
57 816.149 共0.011兲*
57 817.378 共0.011兲*
57 898.220 共0.019兲*
57 897.885 共0.019兲
57 897.968 共0.019兲
57 898.797 共0.019兲
58 002.967 共0.030兲*
58 001.459 共0.030兲
58 003.631 共0.030兲
58 003.829 共0.030兲
58 432.953 共0.012兲*
58 520.244 共0.015兲*
59 038.669 共0.017兲*
59 037.192 共0.017兲
59 039.318 共0.017兲
59 039.512 共0.017兲
59 047.185 共0.008兲*
59 450.784 共0.015兲*
59 450.788 共0.015兲*
59 450.791 共0.015兲*
60 189.983 共0.009兲*
60 189.654 共0.009兲
60 189.736 共0.009兲
60 190.550 共0.009兲
60 356.209 共0.008兲*
60 356.043 共0.008兲
60 356.281 共0.008兲
60 356.304 共0.008兲
60 516.391 共0.049兲*
60 515.963 共0.049兲
60 516.022 共0.049兲
60 517.185 共0.049兲
17.984
17.984
449.547
178.021
97.721
97.720
97.720
97.721
220.890
177.908
220.890
178.021
134.237
134.237
134.237
134.237
66.868
66.868
66.868
66.868
449.542
17.984
17.984
17.984
17.984
348.381
348.381
81.418
81.418
81.418
81.418
99.438
99.438
99.438
99.438
575.704
575.573
99.512
99.512
99.512
99.512
177.908
651.111
651.111
651.111
81.511
81.511
81.511
81.511
64.095
64.095
64.095
64.095
277.543
277.543
277.543
277.543
0.218
0.127
0.055
3.124
21.282
6.424
7.657
6.987
2.906
3.101
2.906
3.125
26.102
8.009
9.298
8.605
16.464
4.850
6.005
5.367
0.029
0.067
0.021
0.027
0.016
3.794
3.794
18.930
5.652
6.854
6.196
0.021
0.007
0.007
0.006
5.416
5.428
0.018
0.006
0.006
0.005
0.028
5.186
10.372
5.186
18.959
5.661
6.864
6.205
1.474
0.484
0.549
0.426
0.100
0.031
0.035
0.033
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
Ref.
1
1
1
1
1
1
1
1
7
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1172
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
8
8
8
8
3
3
3
3
14
12
12
12
12
18
9
9
9
9
23
3
3
3
3
3
3
3
3
22
22
22
22
29
23
7
7
7
7
19
19
19
19
7
7
7
7
22
22
22
22
9
9
9
9
3
3
3
3
1
1
1
1
2
2
2
2
5
1
1
1
1
4
1
1
1
1
4
2
2
2
2
0
0
0
0
2
2
2
2
7
4
1
1
1
1
0
0
0
0
1
1
1
1
2
2
2
2
1
1
1
1
2
2
2
2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A2
A2
A2
A2
E2 + 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
F⬘
7
9
8
2
4
3
11
13
12
8
10
9
3
4
2
4
2
3
22
23
21
6
8
7
18
20
19
6
8
7
22
23
21
8
10
9
2
4
3
J⬙
K⬙a
⌫⬙
8
8
8
8
4
4
4
4
15
12
12
12
12
17
9
9
9
9
24
4
4
4
4
2
2
2
2
22
22
22
22
28
24
6
6
6
6
18
18
18
18
7
7
7
7
22
22
22
22
9
9
9
9
4
4
4
4
0
0
0
0
1
1
1
1
4
0
0
0
0
5
0
0
0
0
1
1
1
1
1
1
1
1
1
2
2
2
2
8
1
2
2
2
2
3
3
3
3
0
0
0
0
2
2
2
2
0
0
0
0
1
1
1
1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A1
A1
A1
A1
E2 + 1
B2
B2
B2
B2
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
E1 − 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
60 570.849 共0.020兲
7
9
8
60 699.167 共0.060兲
3
5
4
61 103.863 共0.020兲
61 220.476 共0.020兲
11
13
12
61 421.867 共0.020兲
61 424.722 共0.060兲
8
10
9
62 055.870 共0.020兲
4
5
3
62 783.284 共0.020兲
3
1
2
22
23
21
62 848.953 共0.020兲
63 079.501 共0.020兲
5
7
6
17
19
18
63 334.425 共0.020兲
6
8
7
22
23
21
63 652.855 共0.020兲
8
10
9
63 909.185 共0.020兲
3
5
4
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
60 570.881 共0.009兲*
60 570.538 共0.009兲
60 570.640 共0.009兲
60 571.452 共0.009兲
60 699.160 共0.008兲*
60 699.069 共0.008兲
60 699.113 共0.008兲
60 699.288 共0.008兲
61 103.862 共0.010兲*
61 220.474 共0.011兲*
61 220.179 共0.011兲
61 220.242 共0.011兲
61 220.996 共0.011兲
61 421.831 共0.011兲*
61 424.731 共0.016兲*
61 424.376 共0.016兲
61 424.473 共0.016兲
61 425.335 共0.016兲
61 974.046 共0.177兲*
62 055.866 共0.008兲*
62 054.678 共0.008兲
62 056.298 共0.008兲
62 056.716 共0.008兲
62 783.275 共0.008兲*
62 783.200 共0.008兲
62 783.241 共0.008兲
62 783.433 共0.008兲
62 783.614 共0.259兲*
62 782.865 共0.259兲
62 783.964 共0.259兲
62 784.014 共0.259兲
62 848.985 共0.017兲*
62 941.602 共0.188兲*
63 079.479 共0.009兲*
63 078.910 共0.009兲
63 079.088 共0.009兲
63 080.417 共0.009兲
63 321.747 共0.051兲*
63 321.317 共0.051兲
63 321.376 共0.051兲
63 322.545 共0.051兲
63 334.439 共0.008兲*
63 334.093 共0.008兲
63 334.208 共0.008兲
63 335.001 共0.008兲
63 339.482 共0.242兲*
63 338.728 共0.242兲
63 339.835 共0.242兲
63 63 339.885 共0.242兲
63 652.874 共0.008兲*
63 652.526 共0.008兲
63 652.620 共0.008兲
63 653.466 共0.008兲
63 909.207 共0.009兲*
63 909.053 共0.009兲
63 909.127 共0.009兲
63 909.426 共0.009兲
53.590
53.590
53.590
53.590
17.985
17.985
17.985
17.985
221.053
115.102
115.102
115.102
115.102
294.111
66.672
66.672
66.672
66.672
449.542
17.647
17.648
17.647
17.647
7.182
7.182
7.182
7.183
384.628
384.628
384.628
384.628
772.620
449.480
41.905
41.905
41.905
41.905
277.638
277.638
277.638
277.638
41.781
41.781
41.781
41.781
384.661
384.661
384.661
384.661
66.765
66.765
66.765
66.765
17.950
17.950
17.950
17.950
14.260
4.129
5.247
4.622
0.451
0.107
0.184
0.141
2.899
23.588
7.183
8.441
7.762
4.020
16.752
4.935
6.110
5.461
0.030
0.438
0.137
0.178
0.104
0.603
0.258
0.121
0.179
0.034
0.011
0.012
0.011
6.308
0.028
1.016
0.287
0.384
0.332
0.108
0.034
0.038
0.036
12.109
3.427
4.503
3.894
0.026
0.008
0.009
0.008
16.746
4.933
6.108
5.459
0.607
0.145
0.247
0.190
1
1
1
1
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1173
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
25
8
8
8
8
14
25
11
11
11
11
22
22
22
22
22
22
22
22
14
18
18
6
6
6
6
14
25
21
19
19
19
19
8
8
8
8
18
5
5
5
5
29
7
7
7
7
14
14
10
10
29
12
12
12
12
10
8
1
1
1
1
3
8
1
1
1
1
2
2
2
2
2
2
2
2
3
4
4
1
1
1
1
5
6
7
0
0
0
0
1
1
1
1
4
1
1
1
1
7
1
1
1
1
5
5
4
4
7
1
1
1
1
1
E2 − 1
B2
B2
B2
B2
B2
E2 + 1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B2
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
B1
B1
B1
B1
B1
B2
B1
B2
E2 − 1
B1
B1
B1
B1
A2
F⬘
7
9
8
10
12
11
22
23
21
22
23
21
5
7
6
18
20
19
7
9
8
4
6
5
6
8
7
12
13
11
J⬙
K⬙a
⌫⬙
26
8
8
8
8
13
26
11
11
11
11
22
22
22
22
22
22
22
22
13
17
17
6
6
6
6
15
24
22
18
18
18
18
8
8
8
8
17
5
5
5
5
28
7
7
7
7
15
15
11
11
28
12
12
12
12
10
7
0
0
0
0
4
7
0
0
0
0
2
2
2
2
2
2
2
2
4
5
5
0
0
0
0
4
7
6
3
3
3
3
0
0
0
0
5
0
0
0
0
8
0
0
0
0
4
4
3
3
8
1
1
1
1
0
E2 − 1
B1
B1
B1
B1
B1
E2 + 1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B2
B1
B2
B1
E2 − 1
B2
B2
B2
B2
A1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
64 483.522 共0.020兲
64 745.572 共0.020兲
7
9
8
64 962.730 共0.020兲
65 030.522 共0.020兲
65 046.842 共0.020兲
10
12
11
22
23
21
22
23
21
65 399.830 共0.060兲
65 485.041 共0.020兲
65 535.921 共0.020兲
65 706.558 共0.020兲
5
7
6
66 130.499 共0.020兲
66 381.212 共0.020兲
66 525.087 共0.020兲
17
19
18
66 908.168 共0.020兲
7
9
8
67 177.766 共0.020兲
67 609.018 共0.020兲
4
6
5
67 798.137 共0.020兲
67 815.760 共0.020兲
6
8
7
67 849.747 共0.020兲
67 861.880 共0.020兲
68 154.398 共0.020兲
68 261.483 共0.020兲
12
13
11
68 759.556 共0.020兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
64 483.493 共0.016兲*
64 745.574 共0.013兲*
64 745.199 共0.013兲
64 745.311 共0.013兲
64 746.199 共0.013兲
64 962.757 共0.010兲*
65 030.519 共0.016兲*
65 046.834 共0.010兲*
65 046.518 共0.010兲
65 046.591 共0.010兲
65 047.387 共0.010兲
65 277.366 共0.181兲*
65 276.595 共0.181兲
65 277.727 共0.181兲
65 277.778 共0.181兲
65 384.994 共0.172兲*
65 384.232 共0.172兲
65 385.350 共0.172兲
65 385.401 共0.172兲
65 399.896 共0.010兲*
65 485.054 共0.009兲*
65 535.920 共0.009兲*
65 706.567 共0.007兲*
65 706.231 共0.007兲
65 706.355 共0.007兲
65 707.095 共0.007兲
66 130.530 共0.010兲*
66 381.243 共0.014兲*
66 525.091 共0.014兲*
66 884.546 共0.050兲*
66 884.120 共0.050兲
66 884.179 共0.050兲
66 885.336 共0.050兲
66 908.171 共0.007兲*
66 907.804 共0.007兲
66 907.914 共0.007兲
66 908.782 共0.007兲
67 177.763 共0.011兲*
67 609.017 共0.006兲*
67 608.713 共0.006兲
67 608.841 共0.006兲
67 609.472 共0.006兲
67 798.134 共0.016兲*
67 815.760 共0.011兲*
67 815.366 共0.011兲
67 815.496 共0.011兲
67 816.402 共0.011兲
67 849.764 共0.009兲*
67 861.893 共0.009兲*
68 154.380 共0.008兲*
68 261.478 共0.008兲*
68 291.347 共0.019兲*
68 483.777 共0.035兲*
68 482.272 共0.035兲
68 484.445 共0.035兲
68 484.627 共0.035兲
68 759.547 共0.010兲*
650.971
53.393
53.393
53.393
53.393
177.834
650.780
97.427
97.427
97.427
97.427
384.425
384.425
384.425
384.425
384.403
384.403
384.403
384.403
177.834
293.900
293.900
31.443
31.443
31.443
31.443
220.934
575.529
471.462
277.584
277.584
277.584
277.584
53.487
53.487
53.487
53.487
294.073
22.579
22.579
22.579
22.579
772.409
41.584
41.584
41.584
41.584
220.704
220.704
122.336
122.332
772.582
116.985
116.985
116.985
116.985
81.215
5.192
14.681
4.250
5.402
4.759
3.128
5.199
21.190
6.396
7.624
6.957
0.027
0.009
0.009
0.009
0.031
0.010
0.011
0.010
3.129
4.024
4.024
9.986
2.738
3.762
3.172
2.901
5.423
4.312
0.074
0.023
0.026
0.025
14.635
4.237
5.385
4.744
4.016
7.876
2.062
3.016
2.453
6.311
12.709
3.597
4.726
4.086
2.905
2.905
2.015
2.015
6.302
0.020
0.006
0.007
0.006
18.907
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
1
1
1
1
3
1
1
3
3
3
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1174
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
4
4
4
4
3
3
3
3
3
3
3
3
7
7
7
7
25
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
7
7
7
7
6
6
6
6
3
3
3
3
3
3
3
3
14
18
9
9
9
9
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
8
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
5
4
1
1
1
1
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
A1
A1
A1
A1
9
11
10
10
10
10
4
4
4
4
4
4
4
4
3
3
3
3
7
7
7
7
26
2
2
2
2
2
2
2
2
1
1
1
1
1
2
1
6
6
6
6
6
6
6
6
4
4
4
4
4
4
4
4
15
17
9
9
9
9
0
0
0
0
0
0
0
1
1
1
1
0
0
0
0
0
0
0
0
7
0
0
0
0
0
0
0
0
0
0
0
0
0
10
0
2
2
2
2
0
0
0
0
1
1
1
1
1
1
1
1
4
5
0
0
0
0
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 − 1
A2
A2
A2
A2
9
11
10
3
5
4
2
4
3
2
4
3
6
8
7
1
3
2
3
1
2
2
1
2
1
0
1
7
8
6
5
7
6
3
4
2
3
4
2
8
10
9
Obs. Freq. 共unc.兲
共MHz兲
68 978.320 共0.020兲
3
5
4
69 781.149 共0.020兲
3
5
4
69 809.476 共0.020兲
2
4
3
69 903.701 共0.020兲
6
8
7
70 016.487 共0.020兲
70 199.117 共0.020兲
2
2
2
3
1
3
1
70 320.133 共0.020兲
1
1
2
1
2
0
70 550.223 共0.060兲
6
7
5
70 594.240 共0.020兲
5
7
6
70 815.577 共0.020兲
4
5
3
4
5
3
71 938.245 共0.060兲
72 215.664 共0.020兲
72 309.090 共0.020兲
8
10
9
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
68 759.210 共0.010兲
68 759.294 共0.010兲
68 760.128 共0.010兲
68 978.318 共0.007兲*
68 978.083 共0.007兲
68 978.199 共0.007兲
68 978.648 共0.007兲
69 781.117 共0.010兲*
69 780.963 共0.010兲
69 781.037 共0.010兲
69 781.336 共0.010兲
69 809.475 共0.007兲*
69 809.365 共0.007兲
69 809.429 共0.007兲
69 809.614 共0.007兲
69 903.704 共0.006兲*
69 903.320 共0.006兲
69 903.447 共0.006兲
69 904.327 共0.006兲
70 016.463 共0.016兲*
70 199.113 共0.008兲*
70 198.035 共0.008兲
70 198.368 共0.008兲
70 198.967 共0.008兲
70 199.154 共0.008兲
70 199.259 共0.008兲
70 199.754 共0.008兲
70 200.190 共0.008兲
70 320.128 共0.008兲*
70 319.279 共0.008兲
70 319.574 共0.008兲
70 320.003 共0.008兲
70 320.017 共0.008兲
70 320.298 共0.008兲
70 321.089 共0.008兲
70 550.275 共0.012兲*
70 549.753 共0.012兲
70 550.486 共0.012兲
70 550.604 共0.012兲
70 594.237 共0.009兲*
70 593.822 共0.009兲
70 593.976 共0.009兲
70 594.889 共0.009兲
70 815.573 共0.007兲*
70 814.385 共0.007兲
70 816.004 共0.007兲
70 816.422 共0.007兲
70 815.585 共0.008兲*
70 814.604 共0.008兲
70 815.941 共0.008兲
70 816.286 共0.008兲
71 938.290 共0.011兲*
72 215.661 共0.012兲*
72 309.083 共0.009兲*
72 308.727 共0.009兲
72 308.824 共0.009兲
72 309.690 共0.009兲
81.215
81.215
81.215
15.190
15.190
15.190
15.190
17.792
17.792
17.792
17.792
9.277
9.277
9.277
9.277
41.678
41.678
41.678
41.678
650.825
4.841
4.841
4.841
4.841
4.841
4.841
4.841
4.841
1.883
1.883
1.883
1.883
1.883
1.883
1.883
42.315
42.315
42.315
42.315
31.246
31.246
31.246
31.246
17.647
17.648
17.647
17.647
17.491
17.491
17.491
17.491
220.779
294.024
66.468
66.468
66.468
66.468
5.645
6.845
6.188
5.818
1.414
2.276
1.750
0.608
0.145
0.248
0.190
3.946
0.835
1.585
1.105
12.612
3.569
4.690
4.055
5.197
2.420
0.121
0.125
0.560
1.004
0.363
0.125
0.121
1.274
0.106
0.177
0.177
0.142
0.531
0.142
1.843
0.602
0.696
0.520
10.827
2.969
4.079
3.439
0.141
0.044
0.058
0.034
0.057
0.018
0.023
0.014
2.903
4.013
16.736
4.930
6.104
5.455
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1175
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
19
19
19
19
3
3
3
3
6
6
6
6
3
3
3
3
11
23
23
23
23
5
5
5
5
14
14
14
14
29
29
29
23
23
23
23
21
21
5
5
5
5
4
4
4
4
22
22
19
19
19
19
8
8
8
8
23
0
0
0
0
2
2
2
2
1
1
1
1
2
2
2
2
2
2
2
2
2
1
1
1
1
3
3
3
3
7
7
7
2
2
2
2
7
7
1
1
1
1
1
1
1
1
5
5
0
0
0
0
1
1
1
1
2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
E1 − 1
A2
A2
A2
A2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B
B2
B2
B2
B2
B2
E1 − 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
A2
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E2 − 1
F⬘
18
20
19
3
4
2
5
7
6
3
4
2
23
24
22
4
6
5
14
15
13
23
24
22
4
6
5
3
5
4
18
20
19
7
9
8
J⬙
K⬙a
⌫⬙
18
18
18
18
4
4
4
4
6
6
6
6
4
4
4
4
10
23
23
23
23
5
5
5
5
15
15
15
15
28
28
28
23
23
23
23
22
22
5
5
5
5
4
4
4
4
21
21
18
18
18
18
8
8
8
8
23
3
3
3
3
1
1
1
1
0
0
0
0
1
1
1
1
3
2
2
2
2
0
0
0
0
0
0
0
0
8
8
8
2
2
2
2
6
6
0
0
0
0
0
0
0
0
6
6
3
3
3
3
0
0
0
0
2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
E1 − 1
A1
A1
A1
A1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B
B1
B1
B1
B1
B1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
17
19
18
72 559.640 共0.020兲
4
5
3
72 586.989 共0.020兲
5
7
6
72 671.575 共0.020兲
4
5
3
72 856.148 共0.020兲
23
24
22
73 044.481 共0.020兲
4
6
5
15
16
14
73 365.624 共0.020兲
23
24
22
74 393.483 共0.060兲
74 571.274 共0.020兲
74 901.949 共0.020兲
4
6
5
75 134.870 共0.020兲
3
5
4
75 416.594 共0.020兲
75 421.836 共0.020兲
17
19
18
75 648.053 共0.020兲
7
9
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
72 506.470 共0.048兲*
72 506.034 共0.048兲
72 506.095 共0.048兲
72 507.277 共0.048兲
72 559.666 共0.008兲*
72 558.685 共0.008兲
72 560.022 共0.008兲
72 560.368 共0.008兲
72 586.983 共0.006兲*
72 586.587 共0.006兲
72 586.734 共0.006兲
72 587.606 共0.006兲
72 671.596 共0.009兲*
72 670.319 共0.009兲
72 672.060 共0.009兲
72 672.508 共0.009兲
72 856.155 共0.009兲*
73 004.732 共0.316兲*
73 003.948 共0.316兲
73 005.100 共0.316兲
73 005.151 共0.316兲
73 044.473 共0.008兲*
73 044.038 共0.008兲
73 044.222 共0.008兲
73 045.126 共0.008兲
73 287.441 共0.026兲*
73 286.851 共0.026兲
73 287.711 共0.026兲
73 287.765 共0.026兲
73 365.598 共0.017兲*
73 365.613 共0.017兲*
73 365.628 共0.017兲*
73 620.776 共0.296兲*
73 619.986 共0.296兲
73 621.147 共0.296兲
73 621.198 共0.296兲
74 393.392 共0.014兲*
74 571.284 共0.012兲*
74 901.933 共0.006兲*
74 901.533 共0.006兲
74 901.702 共0.006兲
74 902.535 共0.006兲
75 134.858 共0.007兲*
75 134.403 共0.007兲
75 134.626 共0.007兲
75 135.496 共0.007兲
75 416.615 共0.011兲*
75 421.854 共0.011兲*
75 536.354 共0.055兲*
75 535.937 共0.055兲
75 535.995 共0.055兲
75 537.126 共0.055兲
75 648.042 共0.008兲*
75 647.665 共0.008兲
75 647.777 共0.008兲
75 648.669 共0.008兲
75 779.521 共0.215兲*
277.491
277.491
277.491
277.491
17.491
17.491
17.491
17.491
31.340
31.340
31.340
31.340
17.657
17.657
17.657
17.657
106.038
418.500
418.500
418.500
418.500
22.381
22.381
22.381
22.381
177.154
177.154
177.154
177.154
772.552
772.552
772.552
418.532
418.532
418.532
418.532
471.243
471.370
22.476
22.476
22.476
22.476
14.992
14.992
14.992
14.992
438.924
438.924
277.390
277.390
277.390
277.390
53.188
53.188
53.188
53.188
418.298
0.100
0.032
0.035
0.033
0.526
0.165
0.214
0.125
10.658
2.923
4.016
3.386
0.577
0.180
0.235
0.137
2.425
0.033
0.011
0.011
0.010
9.024
2.363
3.456
2.811
0.019
0.006
0.007
0.006
6.293
12.586
6.293
0.024
0.008
0.008
0.008
4.316
4.308
8.742
2.289
3.348
2.723
7.290
1.772
2.851
2.193
4.915
4.915
0.021
0.007
0.007
0.007
14.670
4.247
5.398
4.755
0.025
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1176
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
23
23
23
23
23
23
23
14
14
14
14
7
7
7
7
18
18
10
10
4
4
4
4
30
3
3
3
3
10
18
29
2
2
2
2
2
2
2
2
3
3
3
3
29
29
19
19
19
19
3
3
3
3
14
14
14
14
2
2
2
2
2
2
2
3
3
3
3
1
1
1
1
4
4
4
4
1
1
1
1
2
1
1
1
1
4
4
7
1
1
1
1
1
1
1
1
1
1
1
1
7
7
0
0
0
0
2
2
2
2
3
3
3
3
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A2
A1
E2 + 1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
A2
E1 − 1
E1 + 1
B2
B2
B2
B2
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
23
24
22
23
23
23
23
23
23
23
15
15
15
15
6
6
6
6
17
17
11
11
4
4
4
4
30
3
3
3
3
11
17
28
2
2
2
2
2
2
2
2
3
3
3
3
28
28
18
18
18
18
4
4
4
4
15
15
15
15
2
2
2
2
2
2
2
0
0
0
0
2
2
2
2
5
5
3
3
0
0
0
0
1
0
0
0
0
3
5
8
0
0
0
0
0
0
0
0
0
0
0
0
8
8
3
3
3
3
1
1
1
1
0
0
0
0
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A1
A2
E2 + 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A1
E1 − 1
E1 + 1
B1
B1
B1
B1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
23
24
22
23
24
22
14
15
13
7
8
6
3
5
4
2
4
3
1
3
1
3
2
2
2
2
4
3
18
20
19
3
4
2
14
15
13
Obs. Freq. 共unc.兲
共MHz兲
23
24
22
15
16
14
76 398.872 共0.020兲
6
7
5
76 582.554 共0.020兲
76 632.307 共0.020兲
76 748.210 共0.020兲
76 779.047 共0.020兲
76 782.324 共0.020兲
3
5
4
76 834.434 共0.020兲
76 838.943 共0.020兲
2
4
3
76 888.483 共0.020兲
77 590.081 共0.060兲
78 079.451 共0.060兲
78 135.517 共0.020兲
2
2
1
3
2
3
1
78 146.195 共0.020兲
2
4
3
78 234.879 共0.020兲
17
19
18
78 558.347 共0.020兲
4
5
3
15
16
14
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
75 778.715 共0.215兲
75 779.899 共0.215兲
75 779.951 共0.215兲
75 781.392 共0.205兲*
75 780.593 共0.205兲
75 781.767 共0.205兲
75 781.818 共0.205兲
76 313.733 共0.025兲*
76 313.143 共0.025兲
76 314.002 共0.025兲
76 314.056 共0.025兲
76 398.848 共0.011兲*
76 398.325 共0.011兲
76 399.058 共0.011兲
76 399.177 共0.011兲
76 582.545 共0.009兲*
76 632.303 共0.009兲*
76 748.196 共0.009兲*
76 779.030 共0.009兲*
76 782.307 共0.006兲*
76 781.924 共0.006兲
76 782.112 共0.006兲
76 782.844 共0.006兲
76 834.447 共0.022兲*
76 838.932 共0.007兲*
76 838.460 共0.007兲
76 838.735 共0.007兲
76 839.521 共0.007兲
76 888.467 共0.009兲*
77 590.133 共0.014兲*
78 079.501 共0.020兲*
78 135.504 共0.007兲*
78 133.832 共0.008兲
78 134.589 共0.007兲
78 135.055 共0.008兲
78 135.376 共0.007兲
78 135.952 共0.008兲
78 136.738 共0.007兲
78 137.175 共0.008兲
78 146.174 共0.006兲*
78 145.870 共0.006兲
78 146.047 共0.006兲
78 146.553 共0.006兲
78 234.845 共0.025兲*
78 234.875 共0.025兲*
78 325.919 共0.053兲*
78 325.496 共0.053兲
78 325.554 共0.053兲
78 326.704 共0.053兲
78 558.334 共0.010兲*
78 557.057 共0.010兲
78 558.799 共0.010兲
78 559.247 共0.010兲
78 702.193 共0.024兲*
78 701.601 共0.024兲
78 702.463 共0.024兲
78 702.517 共0.024兲
418.298
418.298
418.298
418.276
418.276
418.276
418.276
177.253
177.253
177.253
177.253
42.277
42.277
42.277
42.277
293.714
293.714
122.124
122.236
15.086
15.086
15.086
15.086
693.605
9.079
9.079
9.079
9.079
122.233
293.875
772.236
4.643
4.643
4.643
4.643
4.643
4.643
4.643
4.643
9.173
9.173
9.173
9.173
772.417
772.417
277.202
277.202
277.202
277.202
17.498
17.498
17.498
17.498
177.253
177.253
177.253
177.253
␮ 2S
共D2兲
0.008
0.009
0.008
0.029
0.010
0.010
0.009
0.019
0.006
0.007
0.006
1.838
0.600
0.694
0.518
4.026
4.026
2.014
2.013
6.816
1.657
2.666
2.051
44.437
5.611
1.188
2.254
1.572
2.013
4.019
6.314
3.976
0.199
0.206
0.5963
1.649
0.920
0.206
0.199
4.841
1.024
1.945
1.356
6.302
6.302
0.043
0.014
0.015
0.014
0.577
0.180
0.235
0.137
0.028
0.009
0.010
0.009
Wst
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
1
3
3
3
3
3
2
3
3
3
3
3
3
3
3
1
1
3
3
3
3
3
3
3
3
1
1
1
1
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1177
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
7
7
7
7
30
11
2
2
2
2
2
2
2
2
21
21
1
1
1
1
1
1
1
27
1
1
1
1
1
1
1
7
7
7
7
13
13
13
13
27
10
28
28
7
7
7
7
21
21
11
6
6
6
6
11
17
1
1
1
1
1
2
2
1
1
1
1
1
1
1
1
7
7
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
4
9
9
1
1
1
1
7
7
2
1
1
1
1
2
6
1
A1
A1
A1
A1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A1
B1
B1
B1
B1
B1
B1
B1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E1 + 1
E1 − 1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B1
E2 + 1
A2
A2
A2
A2
B1
E2 − 1
E2 + 1
F⬘
6
8
7
1
3
1
3
2
2
2
0
2
1
2
1
1
1
2
0
1
2
1
7
8
6
13
14
12
7
8
6
5
7
6
J⬙
K⬙a
⌫⬙
7
7
7
7
30
10
2
2
2
2
2
2
2
2
22
22
1
1
1
1
1
1
1
26
1
1
1
1
1
1
1
6
6
6
6
13
13
13
13
26
11
29
29
6
6
6
6
22
22
10
6
6
6
6
10
18
1
0
0
0
0
1
3
0
0
0
0
0
0
0
0
6
6
0
0
0
0
0
0
0
4
0
0
0
0
0
0
0
2
2
2
2
1
1
1
1
4
3
8
8
2
2
2
2
6
6
3
0
0
0
0
3
5
0
A2
A2
A2
A2
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
B2
B2
B2
B2
B2
B2
B2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 − 1
E1 − 1
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
E2 + 1
A1
A1
A1
A1
B2
E2 − 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
78 732.165 共0.020兲
6
8
7
78 738.008 共0.020兲
78 842.944 共0.020兲
78 928.748 共0.020兲
2
2
1
3
2
3
1
78 951.788 共0.060兲
78 951.880 共0.060兲
79 008.707 共0.020兲
1
1
1
2
2
0
79 210.324 共0.020兲
1
1
1
2
2
0
79 402.422 共0.020兲
6
7
5
13
14
12
80 515.475 共0.020兲
80 569.830 共0.020兲
81 075.254 共0.060兲
6
7
5
81 130.443 共0.060兲
81 130.540 共0.060兲
81 184.544 共0.020兲
81 521.084 共0.020兲
5
7
6
82 164.199 共0.020兲
82 205.447 共0.060兲
82 231.156 共0.020兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
78 732.155 共0.008兲*
78 731.759 共0.008兲
78 731.890 共0.008兲
78 732.799 共0.008兲
78 738.002 共0.020兲*
78 842.929 共0.011兲*
78 928.726 共0.007兲*
78 927.460 共0.007兲
78 927.927 共0.007兲
78 928.683 共0.007兲
78 928.713 共0.007兲
78 928.768 共0.007兲
78 929.554 共0.007兲
78 929.991 共0.007兲
78 951.775 共0.015兲*
78 951.844 共0.015兲*
79 008.693 共0.008兲*
79 007.177 共0.008兲
79 007.998 共0.008兲
79 008.546 共0.008兲
79 008.722 共0.008兲
79 009.270 共0.008兲
79 010.356 共0.008兲
79 128.372 共0.285兲*
79 210.297 共0.008兲*
79 209.523 共0.008兲
79 209.728 共0.008兲
79 210.036 共0.008兲
79 210.247 共0.008兲
79 210.452 共0.008兲
79 211.333 共0.008兲
79 402.446 共0.008兲*
79 401.903 共0.008兲
79 402.665 共0.008兲
79 402.788 共0.008兲
79 803.866 共0.041兲*
79 802.366 共0.041兲
79 804.538 共0.041兲
79 804.706 共0.041兲
79 953.529 共0.271兲*
80 515.479 共0.010兲*
80 569.826 共0.024兲*
80 569.826 共0.024兲*
81 075.194 共0.010兲*
81 074.722 共0.010兲
81 075.384 共0.010兲
81 075.493 共0.010兲
81 130.458 共0.015兲*
81 130.527 共0.015兲*
81 184.551 共0.009兲*
81 521.078 共0.008兲*
81 520.662 共0.008兲
81 520.816 共0.008兲
81 521.731 共0.008兲
82 164.188 共0.011兲*
82 205.497 共0.012兲*
82 231.128 共0.005兲*
41.378
41.378
41.378
41.378
693.555
105.934
4.737
4.737
4.737
4.737
4.737
4.737
4.737
4.737
471.408
471.408
1.685
1.685
1.685
1.685
1.685
1.685
1.685
562.361
1.780
1.780
1.780
1.780
1.780
1.780
1.779
42.197
42.197
42.197
42.197
135.990
135.990
135.990
135.990
562.391
122.306
815.306
815.306
42.100
42.100
42.100
42.100
471.308
471.308
105.856
31.040
31.040
31.040
31.040
106.066
320.619
1.883
12.703
3.595
4.724
4.084
44.359
0.858
2.914
0.146
0.151
0.437
1.209
0.675
0.151
0.146
4.306
4.306
2.373
0.264
0.330
0.198
0.989
0.330
0.264
0.060
1.392
0.116
0.193
0.155
0.193
0.580
0.155
1.145
0.374
0.433
0.323
0.019
0.006
0.007
0.006
0.067
2.011
5.712
5.712
0.799
0.261
0.302
0.225
4.310
4.310
1.745
10.824
2.968
4.078
3.438
2.596
3.430
1.099
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
3
3
3
3
3
3
3
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
1
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1178
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
1
1
1
1
1
1
2
2
2
2
2
2
2
2
30
10
3
3
3
3
7
7
7
7
11
4
4
4
4
29
22
22
5
5
5
5
11
24
24
24
24
4
4
4
4
11
27
1
1
1
1
1
1
1
11
6
6
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
4
1
1
1
1
1
1
1
1
2
1
1
1
1
2
5
5
1
1
1
1
2
2
2
2
2
0
0
0
0
2
1
1
1
1
1
1
1
1
2
3
3
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
B2
B1
A1
A1
A1
A1
A1
A1
A1
A1
A1
A1
A1
A1
A1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
1
2
1
0
2
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
30
11
3
3
3
3
6
6
6
6
10
4
4
4
4
29
21
21
5
5
5
5
10
24
24
24
24
3
3
3
3
10
26
1
1
1
1
1
1
1
10
7
7
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
3
0
0
0
0
2
2
2
2
3
0
0
0
0
1
6
6
0
0
0
0
3
2
2
2
2
1
1
1
1
3
4
0
0
0
0
0
0
0
3
2
2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B1
B2
A2
A2
A2
A2
A2
A2
A2
A2
A2
A2
A2
A2
A2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
1
1
2
1
2
0
1
3
2
3
2
1
2
3
4
2
7
8
6
4
5
3
4
6
5
24
25
23
3
5
4
1
2
1
2
0
1
6
Obs. Freq. 共unc.兲
共MHz兲
82 366.552 共0.020兲
2
2
2
3
3
1
1
82 543.175 共0.020兲
82 669.877 共0.020兲
82 805.234 共0.020兲
3
4
2
82 880.328 共0.020兲
6
7
5
82 884.703 共0.020兲
83 752.981 共0.020兲
4
5
3
83 978.920 共0.100兲
4
6
5
24
25
23
84 215.034 共0.020兲
2
4
3
84 259.281 共0.060兲
84 305.236 共0.060兲
1
1
2
2
1
0
84 391.627 共0.020兲
84 454.889 共0.020兲
7
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
82 230.167 共0.005兲
82 230.597 共0.005兲
82 230.891 共0.005兲
82 231.240 共0.005兲
82 231.321 共0.005兲
82 231.978 共0.005兲
82 366.532 共0.005兲*
82 365.782 共0.005兲
82 365.881 共0.005兲
82 366.057 共0.005兲
82 366.667 共0.005兲
82 366.844 共0.005兲
82 367.006 共0.005兲
82 367.281 共0.005兲
82 543.155 共0.023兲*
82 669.881 共0.010兲*
82 805.207 共0.005兲*
82 804.731 共0.005兲
82 805.366 共0.005兲
82 805.589 共0.005兲
82 880.302 共0.009兲*
82 879.806 共0.009兲
82 880.501 共0.009兲
82 880.615 共0.009兲
82 884.721 共0.011兲*
83 752.950 共0.004兲*
83 752.378 共0.004兲
83 753.158 共0.004兲
83 753.359 共0.004兲
83 895.407 共0.018兲*
83 905.444 共0.012兲*
83 910.605 共0.012兲*
83 978.941 共0.007兲*
83 978.505 共0.007兲
83 978.690 共0.007兲
83 979.595 共0.007兲
84 043.256 共0.013兲*
84 142.458 共0.385兲*
84 141.640 共0.385兲
84 142.843 共0.385兲
84 142.893 共0.385兲
84 215.036 共0.009兲*
84 214.337 共0.009兲
84 214.703 共0.009兲
84 215.978 共0.009兲
84 259.221 共0.011兲*
84 266.228 共0.310兲*
84 305.195 共0.005兲*
84 304.159 共0.005兲
84 304.678 共0.005兲
84 304.883 共0.005兲
84 305.402 共0.005兲
84 305.456 共0.005兲
84 305.969 共0.005兲
84 391.631 共0.008兲*
84 454.892 共0.009兲*
84 454.667 共0.009兲
1.883
1.883
1.883
1.883
1.883
1.883
4.841
4.841
4.841
4.841
4.841
4.841
4.841
4.841
693.631
122.202
9.277
9.277
9.277
9.277
42.040
42.040
42.040
42.040
106.038
15.190
15.190
15.190
15.190
649.313
438.823
438.823
22.176
22.176
22.176
22.176
105.966
453.832
453.832
453.832
453.832
11.977
11.977
11.977
11.977
105.934
562.247
1.780
1.780
1.780
1.780
1.780
1.780
1.779
105.654
52.553
52.553
0.092
0.153
0.153
0.122
0.458
0.122
1.558
0.078
0.081
0.361
0.646
0.081
0.234
0.078
44.341
2.012
1.669
0.467
0.670
0.353
1.040
0.339
0.393
0.293
0.189
1.479
0.445
0.578
0.359
41.607
4.912
4.912
9.024
2.363
3.456
2.811
2.601
0.032
0.010
0.011
0.010
2.281
0.543
0.929
0.713
1.753
0.050
0.982
0.082
0.136
0.136
0.409
0.109
0.109
0.184
1.127
0.368
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
Ref.
1
1
1
1
1
1
1
8
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1179
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
6
21
2
2
2
2
2
2
2
2
14
14
14
14
24
24
24
24
22
5
5
5
5
3
3
3
3
22
27
29
4
4
4
4
30
11
4
4
4
4
27
11
8
8
8
8
24
24
24
24
22
24
24
24
24
27
3
3
7
1
1
1
1
1
1
1
1
3
3
3
3
2
2
2
2
5
1
1
1
1
1
1
1
1
5
1
2
1
1
1
1
2
2
1
1
1
1
1
2
1
1
1
1
2
2
2
2
5
2
2
2
2
1
E1 + 1
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
A2
E2 + 1
A2
A2
A2
A2
B2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
7
5
7
7
22
2
2
2
2
2
2
2
2
15
15
15
15
24
24
24
24
21
5
5
5
5
3
3
43
3
21
26
29
4
4
4
4
30
10
4
4
4
4
26
10
7
7
7
7
24
24
24
24
21
24
24
24
24
26
2
2
6
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
2
6
0
0
0
0
0
0
0
0
6
4
1
0
0
0
0
1
3
0
0
0
0
4
3
2
2
2
2
2
2
2
2
6
2
2
2
2
4
E1 + 1
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
A1
E2 + 1
A1
A1
A1
A1
B1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
8
6
2
3
1
2
3
2
1
14
15
13
24
25
23
5
6
4
3
2
3
5
4
4
5
3
7
9
8
24
25
23
24
25
23
Obs. Freq. 共unc.兲
共MHz兲
84 595.534 共0.060兲
84 598.235 共0.060兲
2
2
2
3
3
1
1
15
16
14
24
25
23
85 113.805 共0.020兲
85 350.128 共0.020兲
5
6
4
85 425.111 共0.020兲
3
4
2
85 565.597 共0.020兲
85 902.717 共0.020兲
86 074.728 共0.020兲
3
5
4
86 476.180 共0.020兲
86 600.879 共0.020兲
86 898.735 共0.020兲
4
5
3
87 049.052 共0.020兲
87 098.137 共0.020兲
6
8
7
24
25
23
87 198.478 共0.020兲
24
25
23
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
84 454.987 共0.009兲
84 455.027 共0.009兲
84 595.479 共0.015兲*
84 598.202 共0.005兲*
84 597.540 共0.005兲
84 597.605 共0.005兲
84 597.641 共0.005兲
84 598.326 共0.005兲
84 598.391 共0.005兲
84 598.763 共0.005兲
84 598.864 共0.005兲
84 747.088 共0.025兲*
84 746.501 共0.025兲
84 747.357 共0.025兲
84 747.411 共0.025兲
84 817.512 共0.360兲*
84 816.690 共0.360兲
84 817.900 共0.360兲
84 817.950 共0.360兲
85 113.777 共0.013兲*
85 350.098 共0.005兲*
85 349.428 共0.005兲
85 350.355 共0.005兲
85 350.545 共0.005兲
85 425.080 共0.005兲*
85 424.362 共0.005兲
85 425.319 共0.005兲
85 425.654 共0.005兲
85 565.573 共0.014兲*
85 598.310 共0.455兲*
85 902.706 共0.016兲*
86 074.729 共0.007兲*
86 074.273 共0.007兲
86 074.497 共0.007兲
86 075.367 共0.007兲
86 476.162 共0.025兲*
86 600.842 共0.009兲*
86 898.720 共0.005兲*
86 897.941 共0.005兲
86 899.004 共0.005兲
86 899.277 共0.005兲
86 935.275 共0.326兲*
87 049.054 共0.011兲*
87 098.139 共0.012兲*
87 097.618 共0.012兲
87 097.764 共0.012兲
87 099.019 共0.012兲
87 110.686 共0.242兲*
87 109.854 共0.242兲
87 111.078 共0.242兲
87 111.129 共0.242兲
87 198.461 共0.014兲*
87 199.457 共0.254兲*
87 198.619 共0.254兲
87 199.852 共0.254兲
87 199.903 共0.254兲
87 206.114 共0.465兲*
52.553
52.553
471.052
4.737
4.737
4.737
4.737
4.737
4.737
4.737
4.737
177.154
177.154
177.154
177.154
453.863
453.863
453.863
453.863
438.759
22.579
22.579
22.579
22.579
9.173
9.173
9.173
9.173
438.978
562.217
649.261
14.786
14.786
14.786
14.786
693.524
105.856
15.086
15.086
15.086
15.086
562.101
106.068
52.648
52.647
52.647
52.648
453.609
453.609
453.609
453.609
438.886
453.629
453.629
453.629
453.629
562.042
0.426
0.318
4.316
1.065
0.246
0.055
0.053
0.055
0.442
0.053
0.160
0.025
0.008
0.009
0.008
0.022
0.007
0.008
0.007
4.912
1.162
0.362
0.445
0.304
0.775
0.217
0.311
0.164
4.900
0.110
41.538
7.290
1.772
2.851
2.193
44.161
0.869
0.481
0.145
0.188
0.117
0.052
2.617
1.929
0.557
0.719
0.633
0.028
0.009
0.010
0.009
4.908
0.024
0.008
0.008
0.008
0.100
3
3
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
3
1
3
3
3
3
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1180
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
10
6
6
6
6
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
7
7
7
7
14
14
14
14
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
4
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
B2
B2
B2
B2
B2
B2
A2
A2
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
F⬘
6
7
5
2
4
3
1
3
1
2
2
1
3
1
2
2
7
8
6
14
15
13
1
1
3
2
2
1
1
3
2
2
1
3
2
1
2
1
3
2
1
2
1
3
2
J⬙
K⬙a
⌫⬙
11
6
6
6
6
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
6
6
6
6
15
15
15
15
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
B1
B1
B1
B1
B1
B1
A1
A1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
87 507.283 共0.020兲
87 645.969 共0.020兲
6
7
5
87 782.492 共0.020兲
2
4
3
87 794.718 共0.020兲
1
2
0
1
2
87 795.014 共0.020兲
1
2
0
1
2
88 159.591 共0.020兲
6
7
5
15
16
14
88 387.978 共0.020兲
0
1
2
2
1
88 547.670 共0.020兲
0
1
2
2
1
88 667.913 共0.020兲
1
2
1
0
2
88 668.660 共0.060兲
1
2
1
0
2
88 669.583 共0.060兲
1
2
1
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
87 507.267 共0.010兲*
87 645.932 共0.005兲*
87 645.187 共0.005兲
87 646.231 共0.005兲
87 646.407 共0.005兲
87 782.494 共0.008兲*
87 782.022 共0.008兲
87 782.297 共0.008兲
87 783.084 共0.008兲
87 794.717 共0.002兲*
87 793.201 共0.003兲
87 794.505 共0.002兲
87 794.570 共0.003兲
87 795.320 共0.002兲
87 795.868 共0.002兲
87 795.016 共0.002兲*
87 793.500 共0.003兲
87 794.805 共0.002兲
87 794.869 共0.003兲
87 795.620 共0.002兲
87 796.167 共0.002兲
88 159.608 共0.009兲*
88 159.062 共0.009兲
88 159.828 共0.009兲
88 159.952 共0.009兲
88 219.789 共0.030兲*
88 219.205 共0.030兲
88 220.057 共0.030兲
88 220.110 共0.030兲
88 387.971 共0.002兲*
88 386.975 共0.003兲
88 387.488 共0.002兲
88 387.750 共0.002兲
88 388.591 共0.002兲
88 388.796 共0.002兲
88 547.665 共0.002兲*
88 546.708 共0.003兲
88 547.445 共0.002兲
88 547.483 共0.002兲
88 548.082 共0.002兲
88 548.377 共0.002兲
88 667.906 共0.003兲*
88 666.692 共0.003兲
88 667.852 共0.003兲
88 667.914 共0.003兲
88 668.502 共0.003兲
88 668.638 共0.003兲
88 668.681 共0.002兲*
88 667.466 共0.003兲
88 668.627 共0.002兲
88 668.689 共0.002兲
88 669.276 共0.003兲
88 669.413 共0.003兲
88 669.543 共0.002兲*
88 668.328 共0.003兲
88 669.489 共0.002兲
88 669.551 共0.002兲
121.922
31.443
31.443
31.443
31.443
8.873
8.873
8.873
8.873
4.321
4.321
4.321
4.321
4.321
4.321
4.480
4.480
4.480
4.480
4.480
4.480
41.905
41.905
41.905
41.905
177.073
177.073
177.072
177.072
4.422
4.422
4.422
4.422
4.422
4.422
4.229
4.229
4.229
4.229
4.229
4.229
1.685
1.685
1.685
1.685
1.685
1.685
1.883
1.883
1.883
1.883
1.883
1.883
1.780
1.780
1.780
1.780
2.016
0.864
0.274
0.325
0.237
5.613
1.188
2.255
1.572
0.141
0.012
0.066
0.016
0.035
0.012
0.141
0.012
0.066
0.016
0.035
0.012
0.701
0.229
0.265
0.198
0.041
0.014
0.014
0.013
0.138
0.015
0.012
0.064
0.012
0.035
0.140
0.016
0.012
0.066
0.012
0.035
0.189
0.016
0.088
0.047
0.021
0.016
0.189
0.016
0.088
0.047
0.021
0.016
0.188
0.016
0.088
0.047
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1181
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
2
2
2
2
2
2
2
2
2
2
2
2
2
2
11
2
2
2
2
2
2
5
5
5
5
2
2
2
2
2
2
2
2
28
2
2
2
2
2
2
2
2
2
2
2
2
29
1
1
1
1
1
1
1
28
28
17
0
0
0
0
0
0
0
0
1
1
1
1
1
1
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
9
1
1
1
1
1
1
1
1
1
1
1
1
2
1
1
1
1
1
1
1
9
9
6
E1 + 1
E1 + 1
A1
A1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A2
A2
A2
A2
E2 − 1
A1
A1
A1
A1
A1
A1
B1
B1
B1
B1
B1
B1
A1
A1
A1
A1
A1
A1
A1
A1
A2
A1
E1 + 1
1
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
10
1
1
1
1
1
1
5
5
5
5
2
2
2
2
2
2
2
2
29
1
1
1
1
1
1
1
1
1
1
1
1
29
1
1
1
1
1
1
1
29
29
18
0
0
0
0
0
0
0
0
1
1
1
1
1
1
3
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
8
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
8
8
5
E1 + 1
E1 + 1
A2
A2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
A1
A1
A1
A1
E2 − 1
A2
A2
A2
A2
A2
A2
B2
B2
B2
B2
B2
B2
A2
A2
A2
A2
A2
A2
A2
A2
A1
A2
E1 + 1
0
2
1
3
2
1
2
1
3
2
1
2
1
2
3
2
1
5
6
4
1
3
1
3
2
2
2
1
2
3
2
1
1
2
3
2
1
0
2
1
2
1
1
Obs. Freq. 共unc.兲
共MHz兲
1
2
1
0
2
88 804.093 共0.020兲
0
2
2
1
1
88 867.230 共0.020兲
88 962.557 共0.020兲
0
2
2
1
1
88 997.581 共0.020兲
5
6
4
89 081.457 共0.020兲
2
2
1
3
2
3
1
89 554.651 共0.020兲
0
2
2
1
1
89 557.402 共0.020兲
0
2
2
1
1
89 753.910 共0.020兲
89 956.068 共0.020兲
1
1
1
2
2
0
89 975.505 共0.020兲
90 327.712 共0.020兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
88 670.138 共0.003兲
88 670.275 共0.003兲
88 669.626 共0.002兲*
88 668.411 共0.003兲
88 669.572 共0.002兲
88 669.634 共0.002兲
88 670.221 共0.003兲
88 670.358 共0.003兲
88 804.084 共0.002兲*
88 803.231 共0.003兲
88 803.973 共0.002兲
88 804.150 共0.002兲
88 804.304 共0.002兲
88 804.579 共0.002兲
88 867.270 共0.012兲*
88 962.550 共0.002兲*
88 961.736 共0.003兲
88 962.413 共0.003兲
88 962.478 共0.003兲
88 962.932 共0.003兲
88 963.033 共0.003兲
88 997.579 共0.006兲*
88 996.765 共0.006兲
88 997.893 共0.006兲
88 998.123 共0.006兲
89 081.463 共0.008兲*
89 079.791 共0.008兲
89 080.548 共0.008兲
89 081.014 共0.008兲
89 081.334 共0.008兲
89 081.911 共0.008兲
89 082.697 共0.008兲
89 083.134 共0.008兲
89 243.473 共0.054兲*
89 554.649 共0.003兲*
89 552.986 共0.003兲
89 553.981 共0.003兲
89 554.567 共0.003兲
89 555.252 共0.003兲
89 556.165 共0.003兲
89 557.404 共0.003兲*
89 555.741 共0.003兲
89 556.736 共0.003兲
89 557.323 共0.003兲
89 558.008 共0.003兲
89 558.920 共0.003兲
89 753.902 共0.017兲*
89 956.072 共0.008兲*
89 954.556 共0.008兲
89 955.378 共0.008兲
89 955.925 共0.008兲
89 956.102 共0.008兲
89 956.649 共0.008兲
89 957.735 共0.008兲
89 975.495 共0.022兲*
89 975.495 共0.022兲*
90 327.707 共0.013兲*
1.779
1.780
1.479
1.479
1.479
1.479
1.479
1.479
4.626
4.626
4.626
4.626
4.626
4.626
105.968
4.592
4.592
4.592
4.592
4.592
4.592
22.476
22.476
22.476
22.476
4.437
4.437
4.437
4.437
4.437
4.437
4.437
4.437
815.337
4.509
4.509
4.509
4.509
4.509
4.509
4.350
4.350
4.350
4.350
4.350
4.350
649.335
1.479
1.479
1.479
1.479
1.479
1.479
1.479
815.171
815.171
320.668
0.021
0.016
0.188
0.016
0.088
0.047
0.021
0.016
0.141
0.016
0.066
0.012
0.012
0.035
2.623
0.138
0.015
0.011
0.064
0.034
0.011
0.296
0.092
0.113
0.078
3.978
0.199
0.206
0.597
1.650
0.921
0.206
0.199
5.706
0.141
0.016
0.012
0.066
0.035
0.012
0.141
0.016
0.012
0.066
0.035
0.012
41.517
2.374
0.264
0.330
0.198
0.989
0.330
0.264
5.709
5.709
3.425
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1182
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
15
28
7
7
7
7
14
28
6
6
6
6
6
6
6
6
28
4
4
4
4
14
14
14
14
17
6
6
6
6
17
26
15
8
8
8
8
6
6
6
6
28
6
6
6
6
17
17
29
6
6
6
6
8
8
8
8
3
9
1
1
1
1
3
2
3
3
3
3
1
1
1
1
9
0
0
0
0
1
1
1
1
6
3
3
3
3
6
6
3
1
1
1
1
3
3
3
3
2
3
3
3
3
6
6
2
3
3
3
3
1
1
1
1
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 − 1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E2 + 1
A2
A2
A2
A2
E1 − 1
E2 − 1
E2 + 1
A2
A2
A2
A2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
F⬘
7
8
6
6
7
5
6
7
5
3
5
4
14
15
13
6
7
5
7
9
8
6
7
5
6
7
5
6
7
5
8
9
7
J⬙
K⬙a
⌫⬙
14
29
7
7
7
7
15
28
7
7
7
7
6
6
6
6
29
3
3
3
3
14
14
14
14
18
7
7
7
7
18
25
14
7
7
7
7
7
7
7
7
28
7
7
7
7
18
18
29
7
7
7
7
8
8
8
8
4
8
0
0
0
0
0
1
2
2
2
2
0
0
0
0
8
1
1
1
1
1
1
1
1
5
2
2
2
2
5
7
4
2
2
2
2
2
2
2
2
1
2
2
2
2
5
5
1
2
2
2
2
0
0
0
0
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 + 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E2 + 1
A1
A1
A1
A1
E1 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B2
B2
B2
B2
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
90 572.000 共0.060兲
90 628.677 共0.020兲
90 641.405 共0.020兲
7
8
6
91 201.254 共0.020兲
91 294.624 共0.020兲
7
8
6
91 693.436 共0.020兲
6
7
5
91 749.815 共0.020兲
91 848.357 共0.020兲
2
4
3
14
15
13
91 982.964 共0.020兲
92 162.820 共0.020兲
7
8
6
92 466.434 共0.060兲
92 802.074 共0.020兲
92 942.993 共0.060兲
92 981.791 共0.020兲
6
8
7
93 173.484 共0.020兲
7
8
6
93 307.489 共0.020兲
7
8
6
93 592.611 共0.020兲
93 593.318 共0.020兲
93 882.912 共0.020兲
94 052.685 共0.020兲
7
8
6
94 331.915 共0.020兲
8
9
7
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
90 572.086 共0.010兲*
90 628.656 共0.023兲*
90 641.366 共0.006兲*
90 640.564 共0.006兲
90 641.696 共0.006兲
90 641.859 共0.006兲
91 188.938 共0.026兲*
91 201.265 共0.015兲*
91 294.630 共0.010兲*
91 294.451 共0.010兲
91 294.707 共0.010兲
91 294.737 共0.010兲
91 693.454 共0.007兲*
91 692.615 共0.007兲
91 693.789 共0.007兲
91 693.988 共0.007兲
91 749.829 共0.028兲*
91 848.379 共0.006兲*
91 847.846 共0.006兲
91 848.114 共0.006兲
91 849.113 共0.006兲
91 949.457 共0.049兲*
91 947.962 共0.049兲
91 950.132 共0.049兲
91 950.287 共0.049兲
91 982.952 共0.013兲*
92 162.842 共0.010兲*
92 162.557 共0.010兲
⬙92 162.962 共0.010兲
92 163.014 共0.010兲
92 466.488 共0.013兲*
92 802.075 共0.015兲*
92 943.059 共0.014兲*
92 981.820 共0.012兲*
92 981.299 共0.012兲
92 981.445 共0.012兲
92 982.700 共0.012兲
93 173.491 共0.009兲*
93 173.313 共0.009兲
93 173.567 共0.009兲
93 173.596 共0.009兲
93 307.480 共0.013兲*
93 423.699 共0.009兲*
93 423.495 共0.009兲
93 423.785 共0.009兲
93 423.820 共0.009兲
93 592.597 共0.011兲*
93 593.305 共0.011兲*
93 882.923 共0.018兲*
94 052.694 共0.009兲*
94 052.409 共0.009兲
94 052.814 共0.009兲
94 052.866 共0.009兲
94 331.875 共0.007兲*
94 331.029 共0.007兲
94 332.231 共0.007兲
94 332.382 共0.007兲
198.760
815.375
41.781
41.781
41.781
41.781
176.875
606.463
52.639
52.639
52.639
52.639
31.340
31.340
31.340
31.340
815.163
12.023
12.023
12.023
12.023
156.452
156.452
156.452
156.452
320.707
52.610
52.610
52.610
52.610
320.471
612.611
198.880
52.610
52.610
52.610
52.610
52.677
52.677
52.677
52.677
606.408
52.458
52.458
52.458
52.458
320.496
320.496
649.223
52.648
52.648
52.647
52.647
53.590
53.590
53.590
53.590
3.510
5.699
0.634
0.204
0.236
0.180
0.038
38.890
1.129
0.369
0.427
0.319
0.190
0.060
0.072
0.052
5.712
1.963
0.467
0.800
0.613
0.018
0.006
0.006
0.006
3.421
1.128
0.368
0.426
0.318
3.427
5.806
0.068
1.927
0.557
0.718
0.632
1.128
0.368
0.426
0.318
38.830
0.066
0.022
0.025
0.019
3.428
3.428
41.348
1.127
0.368
0.426
0.318
0.471
0.153
0.173
0.136
3
3
1
1
1
1
1
3
1
1
1
1
3
3
3
3
1
3
3
3
3
3
3
3
3
1
1
1
1
1
3
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1183
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
11
4
4
4
4
8
8
8
8
8
8
8
8
7
7
7
7
4
4
4
4
22
6
6
6
6
15
6
6
6
6
20
20
20
20
25
25
25
25
26
26
8
8
8
8
25
25
25
25
28
15
2
2
2
2
6
6
2
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
5
3
3
3
3
3
3
3
3
3
0
0
0
0
2
2
2
2
6
6
1
1
1
1
2
2
2
2
2
3
2
2
2
2
3
3
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
B2
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
F⬘
3
5
4
7
9
8
7
9
8
7
8
6
3
5
4
6
7
5
6
7
5
19
21
20
25
26
24
7
9
8
25
26
24
2
3
1
6
J⬙
K⬙a
⌫⬙
10
3
3
3
3
7
7
7
7
7
7
7
7
7
7
7
7
3
3
3
3
21
7
7
7
7
14
7
7
7
7
19
19
19
19
25
25
25
25
25
25
7
7
7
7
25
25
25
25
28
14
3
3
3
3
7
7
3
1
1
1
1
2
2
2
2
2
2
2
2
0
0
0
0
1
1
1
1
6
2
2
2
2
4
2
2
2
2
3
3
3
3
2
2
2
2
7
7
2
2
2
2
2
2
2
2
1
4
1
1
1
1
2
2
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
B1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
A1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
94 420.185 共0.020兲
94 466.126 共0.020兲
2
4
3
94 495.959 共0.020兲
6
8
7
94 890.070 共0.020兲
6
8
7
94 983.799 共0.020兲
7
8
6
95 145.314 共0.020兲
2
4
3
95 225.389 共0.020兲
95 378.504 共0.020兲
7
8
6
95 380.575 共0.020兲
95 746.899 共0.060兲
7
8
6
18
20
19
25
26
24
96 238.837 共0.020兲
96 239.346 共0.020兲
96 450.749 共0.020兲
6
8
7
25
26
24
97 202.843 共0.020兲
97 484.743 共0.060兲
97 663.377 共0.060兲
3
4
2
7
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
94 420.198 共0.008兲*
94 466.155 共0.006兲*
94 465.815 共0.006兲
94 465.971 共0.006兲
94 466.648 共0.006兲
94 495.966 共0.010兲*
94 495.423 共0.010兲
94 495.577 共0.010兲
94 496.880 共0.010兲
94 890.051 共0.009兲*
94 889.498 共0.009兲
94 889.655 共0.009兲
94 890.983 共0.009兲
94 983.832 共0.008兲*
94 982.972 共0.008兲
94 984.187 共0.008兲
94 984.362 共0.008兲
95 145.307 共0.008兲*
95 144.608 共0.008兲
95 144.973 共0.008兲
95 146.249 共0.008兲
95 225.365 共0.012兲*
95 378.519 共0.009兲*
95 378.263 共0.009兲
95 378.627 共0.009兲
95 378.673 共0.009兲
95 380.571 共0.010兲*
95 746.970 共0.009兲*
95 746.767 共0.009兲
95 747.056 共0.009兲
95 747.091 共0.009兲
95 807.828 共0.062兲*
95 807.371 共0.062兲
95 807.432 共0.062兲
95 808.679 共0.062兲
96 191.896 共0.465兲*
96 191.048 共0.465兲
96 192.295 共0.465兲
96 192.345 共0.465兲
96 238.838 共0.012兲*
96 239.347 共0.012兲*
96 450.786 共0.010兲*
96 450.276 共0.010兲
96 450.419 共0.010兲
96 451.648 共0.010兲
96 923.956 共0.437兲*
96 923.104 共0.437兲
96 924.359 共0.437兲
96 924.409 共0.437兲
97 202.849 共0.013兲*
97 484.761 共0.010兲*
97 663.360 共0.010兲*
97 662.846 共0.011兲
97 663.502 共0.010兲
97 663.893 共0.011兲
97 701.791 共0.013兲*
97 701.535 共0.013兲
105.654
12.039
12.039
12.039
12.039
52.458
52.458
52.458
52.458
52.553
52.553
52.553
52.553
41.678
41.678
41.678
41.678
11.818
11.818
11.818
11.818
438.567
52.393
52.393
52.393
52.393
198.880
52.458
52.458
52.458
52.458
305.651
305.651
305.651
305.652
490.622
490.622
490.622
490.622
612.751
612.751
52.393
52.393
52.393
52.393
490.652
490.652
490.652
490.652
606.481
198.911
12.023
12.023
12.023
12.023
52.393
52.393
2.434
1.599
0.381
0.652
0.500
0.879
0.254
0.328
0.288
0.699
0.202
0.261
0.229
0.128
0.041
0.048
0.036
2.279
0.543
0.928
0.712
4.916
1.063
0.347
0.402
0.300
3.439
1.063
0.347
0.402
0.300
0.119
0.038
0.042
0.040
0.030
0.010
0.011
0.010
5.796
5.796
1.061
0.307
0.395
0.348
0.020
0.007
0.007
0.006
38.809
3.498
0.042
0.013
0.018
0.008
0.066
0.021
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
1
1
1
1
3
3
3
3
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1184
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
6
26
26
20
20
20
20
27
9
9
9
9
24
24
24
8
8
8
8
4
4
4
4
25
25
25
25
25
25
25
25
28
13
15
27
13
13
15
2
2
2
2
15
28
17
17
20
20
20
20
26
26
22
22
9
9
3
3
6
6
0
0
0
0
2
1
1
1
1
8
8
8
1
1
1
1
0
0
0
0
2
2
2
2
2
2
2
2
9
5
3
2
5
5
3
2
2
2
2
3
2
6
6
0
0
0
0
6
6
4
4
1
1
E2 − 1
E2 − 1
A2
A1
B1
B1
B1
B1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 − 1
A1
E2 + 1
A2
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
B2
A2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
B1
E2 + 1
E1 + 1
E1 + 1
7
5
7
7
25
25
19
19
19
19
27
9
9
9
9
25
25
25
8
8
8
8
3
3
3
3
25
25
25
25
25
25
25
25
29
14
14
27
14
14
14
3
3
3
3
14
28
18
18
19
19
19
19
25
25
23
23
9
9
2
2
7
7
3
3
3
3
1
0
0
0
0
7
7
7
0
0
0
0
1
1
1
1
2
2
2
2
2
2
2
2
8
4
4
1
4
4
4
1
1
1
1
4
1
5
5
3
3
3
3
7
7
1
1
0
0
E2 + 1
E2 + 1
A1
A2
B2
B2
B2
B2
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 − 1
A2
E2 + 1
A1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
B1
A1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 − 1
B2
E2 + 1
E1 + 1
E1 + 1
8
6
19
21
20
9
10
8
8
9
7
4
5
3
25
26
24
25
26
24
2
3
1
19
21
20
9
Obs. Freq. 共unc.兲
共MHz兲
98 371.631 共0.020兲
98 372.136 共0.020兲
18
20
19
98 707.320 共0.020兲
98 724.040 共0.020兲
9
10
8
98 781.680 共0.060兲
98 836.155 共0.020兲
98 885.575 共0.060兲
8
9
7
99 127.254 共0.020兲
3
4
2
25
26
24
25
26
24
99 775.934 共0.020兲
100 071.284 共0.020兲
100 848.225 共0.060兲
100 907.749 共0.020兲
101 042.110 共0.020兲
101 048.990 共0.020兲
3
4
2
102 207.753 共0.020兲
102 208.469 共0.020兲
18
20
19
102 768.256 共0.020兲
102 824.442 共0.020兲
103 427.422 共0.060兲
9
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
97 701.898 共0.013兲
97 701.944 共0.013兲
98 371.656 共0.013兲*
98 372.162 共0.013兲*
98 571.635 共0.063兲*
98 571.176 共0.063兲
98 571.237 共0.063兲
98 572.489 共0.063兲
98 707.349 共0.013兲*
98 724.003 共0.008兲*
98 723.120 共0.008兲
98 724.382 共0.008兲
98 724.523 共0.008兲
98 781.643 共0.029兲*
98 781.647 共0.029兲*
98 836.137 共0.017兲*
98 885.639 共0.009兲*
98 884.756 共0.009兲
98 886.011 共0.009兲
98 886.169 共0.009兲
99 127.285 共0.007兲*
99 126.922 共0.007兲
99 127.387 共0.007兲
99 127.630 共0.007兲
99 362.412 共0.286兲*
99 361.550 共0.286兲
99 362.819 共0.286兲
99 362.870 共0.286兲
99 529.446 共0.299兲*
99 528.579 共0.299兲
99 529.856 共0.299兲
99 529.907 共0.299兲
99 775.957 共0.022兲*
100 071.274 共0.011兲*
100 848.247 共0.011兲*
100 907.737 共0.012兲*
101 042.106 共0.010兲*
101 048.991 共0.010兲*
101 181.754 共0.010兲*
101 236.885 共0.011兲*
101 236.130 共0.011兲
101 237.108 共0.011兲
101 237.611 共0.011兲
101 515.371 共0.010兲*
101 515.410 共0.015兲*
102 207.748 共0.012兲*
102 208.467 共0.012兲*
102 237.124 共0.064兲*
102 236.670 共0.064兲
102 236.731 共0.064兲
102 237.967 共0.064兲
102 768.268 共0.013兲*
102 824.419 共0.018兲*
103 337.304 共0.222兲*
103 366.508 共0.170兲*
103 427.513 共0.010兲*
103 426.605 共0.010兲
52.393
52.393
612.779
612.779
305.746
305.746
305.746
305.746
565.058
66.868
66.868
66.868
66.868
612.779
612.779
612.593
53.487
53.487
53.487
53.487
11.780
11.780
11.780
11.780
490.400
490.401
490.400
490.400
490.419
490.419
490.419
490.419
814.991
198.911
198.717
565.000
198.717
198.717
198.605
12.039
12.039
12.039
12.039
198.717
606.364
320.310
320.310
305.682
305.682
305.682
305.682
612.593
612.464
413.815
413.885
66.765
66.765
0.025
0.018
5.788
5.788
0.128
0.041
0.045
0.043
36.291
0.357
0.116
0.130
0.105
4.828
4.828
4.836
0.090
0.029
0.033
0.026
0.314
0.098
0.128
0.075
0.027
0.009
0.009
0.009
0.022
0.007
0.008
0.007
5.715
2.541
3.506
36.243
2.544
2.544
3.444
0.252
0.075
0.108
0.050
3.508
38.652
3.429
3.429
0.092
0.029
0.032
0.031
5.792
5.805
0.039
0.023
0.066
0.021
1
1
1
1
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
1
1
1
1
1
1
1
1
1
1
3
1
1
3
3
3
3
3
3
3
1
3
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1185
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
9
9
15
8
8
8
8
24
24
24
10
10
10
10
22
6
6
6
6
27
15
15
15
15
2
2
2
2
13
19
22
26
2
2
2
2
30
4
4
4
4
20
20
20
20
10
10
10
10
26
24
26
26
26
26
24
27
1
1
3
1
1
1
1
8
8
8
1
1
1
1
4
3
3
3
3
2
1
1
1
1
2
2
2
2
5
4
4
2
2
2
2
2
7
0
0
0
0
0
0
0
0
1
1
1
1
2
8
2
2
2
2
8
2
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 − 1
A1
A1
A1
A1
E2 + 1
B1
10
8
9
9
14
7
7
7
7
25
25
25
10
10
10
10
23
7
7
7
7
27
15
15
15
15
3
3
3
3
14
18
23
26
3
3
3
3
29
3
3
3
3
19
19
19
19
10
10
10
10
26
25
26
26
26
26
25
27
0
0
4
2
2
2
2
7
7
7
0
0
0
0
1
2
2
2
2
1
1
1
1
1
1
1
1
1
4
5
1
1
1
1
1
1
8
1
1
1
1
3
3
3
3
0
0
0
0
1
7
2
2
2
2
7
1
E1 + 1
E1 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 − 1
A2
A2
A2
A2
E2 + 1
B2
10
8
7
9
8
10
11
9
6
7
5
15
16
14
2
3
1
2
3
1
4
5
3
19
21
20
10
11
9
26
27
25
Obs. Freq. 共unc.兲
共MHz兲
103 668.387 共0.020兲
6
8
7
103 733.125 共0.020兲
103 836.510 共0.020兲
10
11
9
104 800.135 共0.020兲
7
8
6
104 845.170 共0.020兲
15
16
14
104 942.283 共0.020兲
3
4
2
105 513.362 共0.020兲
105 921.006 共0.020兲
106 365.818 共0.020兲
106 425.151 共0.020兲
3
4
2
107 133.956 共0.020兲
107 461.880 共0.020兲
3
4
2
18
20
19
108 644.848 共0.060兲
10
11
9
108 655.985 共0.020兲
108 750.455 共0.020兲
26
27
25
109 316.904 共0.020兲
109 328.324 共0.020兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
103 427.902 共0.010兲
103 428.047 共0.010兲
103 619.266 共0.009兲*
103 668.361 共0.010兲*
103 667.815 共0.010兲
103 667.969 共0.010兲
103 669.284 共0.010兲
103 733.126 共0.016兲*
103 733.128 共0.016兲*
103 733.130 共0.016兲*
103 836.495 共0.009兲*
103 835.576 共0.009兲
103 836.894 共0.009兲
103 837.026 共0.009兲
104 671.934 共0.217兲*
104 800.165 共0.009兲*
104 799.930 共0.009兲
104 800.264 共0.009兲
104 800.305 共0.009兲
104 845.176 共0.012兲*
104 903.674 共0.060兲*
104 902.186 共0.060兲
104 904.350 共0.060兲
104 904.495 共0.060兲
104 942.266 共0.008兲*
104 940.655 共0.008兲
104 942.775 共0.008兲
104 943.677 共0.008兲
105 513.346 共0.012兲*
105 920.972 共0.011兲*
105 981.834 共0.162兲*
106 365.824 共0.012兲*
106 425.145 共0.009兲*
106 424.631 共0.009兲
106 425.288 共0.009兲
106 425.678 共0.009兲
107 133.969 共0.023兲*
107 461.887 共0.008兲*
107 461.765 共0.008兲
107 461.908 共0.008兲
107 462.039 共0.008兲
107 626.876 共0.061兲*
107 626.410 共0.061兲
107 626.472 共0.061兲
107 627.741 共0.061兲
108 644.937 共0.012兲*
108 644.003 共0.012兲
108 645.343 共0.012兲
108 645.478 共0.012兲
108 655.974 共0.011兲*
108 750.466 共0.018兲*
109 142.201 共0.561兲*
109 141.326 共0.561兲
109 142.615 共0.561兲
109 142.664 共0.561兲
109 316.897 共0.018兲*
109 328.352 共0.013兲*
66.765
66.765
198.605
52.261
52.261
52.261
52.261
612.751
612.751
612.751
81.613
81.613
81.613
81.613
413.951
52.261
52.261
52.261
52.261
565.072
178.370
178.370
178.370
178.370
11.780
11.780
11.780
11.780
198.880
320.707
413.948
525.100
12.023
12.023
12.023
12.023
815.375
11.605
11.605
11.605
11.605
305.596
305.596
305.596
305.596
81.511
81.511
81.511
81.511
525.041
612.611
528.868
528.868
528.868
528.868
612.420
564.951
0.024
0.019
0.069
1.230
0.355
0.458
0.404
4.823
9.646
4.823
0.276
0.090
0.100
0.082
0.043
1.126
0.368
0.425
0.318
36.222
0.017
0.006
0.006
0.005
0.221
0.065
0.095
0.044
2.538
4.402
0.023
33.815
0.223
0.066
0.096
0.045
6.684
0.676
0.211
0.275
0.161
0.127
0.040
0.045
0.042
0.049
0.016
0.018
0.015
33.780
4.829
0.029
0.010
0.010
0.009
4.834
36.077
3
3
1
3
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
1
3
3
3
3
3
3
3
3
1
1
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1186
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
15
11
11
11
11
26
26
26
26
2
2
2
2
19
15
19
22
13
26
20
22
19
30
13
13
26
26
26
26
30
9
9
9
9
26
9
9
9
9
26
26
26
26
2
2
2
2
20
20
20
20
25
24
11
11
11
11
3
1
1
1
1
2
2
2
2
2
2
2
2
4
3
4
4
5
6
7
4
4
7
5
5
2
2
2
2
7
4
4
4
4
2
4
4
4
4
2
2
2
2
2
2
2
2
0
0
0
0
2
8
1
1
1
1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
A1
A1
A1
A1
B1
B2
B2
E1 − 1
E1 + 1
E2 + 1
E2 + 1
E2 − 1
E1 + 1
E2 + 1
B2
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
B2
B2
B2
B2
A2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
F⬘
11
12
10
26
27
25
2
3
1
26
27
25
9
10
8
9
10
8
26
27
25
2
3
1
19
21
20
11
12
10
J⬙
K⬙a
⌫⬙
14
11
11
11
11
26
26
26
26
3
3
3
3
18
14
18
23
14
25
21
23
18
29
14
14
26
26
26
26
29
10
10
10
10
26
10
10
10
10
26
26
26
26
3
3
3
3
19
19
19
19
25
25
11
11
11
11
4
0
0
0
0
2
2
2
2
1
1
1
1
5
4
5
1
4
7
6
1
5
8
4
4
2
2
2
2
8
3
3
3
3
1
3
3
3
3
2
2
2
2
1
1
1
1
3
3
3
3
1
7
0
0
0
0
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
A2
A2
A2
A2
B2
B1
B1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E2 + 1
B1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
B1
B1
B1
B1
A1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
109 382.495 共0.020兲
109 696.905 共0.020兲
11
12
10
26
27
25
109 959.690 共0.020兲
3
4
2
109 970.045 共0.020兲
110 035.334 共0.060兲
110 047.779 共0.020兲
110 533.343 共0.060兲
110 680.455 共0.020兲
110 831.081 共0.020兲
111 655.647 共0.020兲
112 064.286 共0.020兲
112 273.032 共0.020兲
112 280.072 共0.020兲
26
27
25
112 541.583 共0.020兲
112 591.184 共0.020兲
10
11
9
112 633.261 共0.020兲
112 652.518 共0.020兲
10
11
9
26
27
25
113 704.058 共0.020兲
3
4
2
18
20
19
114 126.905 共0.020兲
114 309.465 共0.020兲
114 576.909 共0.060兲
11
12
10
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
109 382.524 共0.012兲*
109 696.885 共0.010兲*
109 695.933 共0.010兲
109 697.304 共0.010兲
109 697.429 共0.010兲
109 928.507 共0.528兲*
109 927.627 共0.528兲
109 928.923 共0.528兲
109 928.973 共0.528兲
109 959.713 共0.009兲*
109 959.405 共0.010兲
109 959.787 共0.009兲
109 960.082 共0.010兲
109 970.078 共0.010兲*
110 035.425 共0.011兲*
110 047.790 共0.010兲*
110 384.680 共0.153兲*
110 533.406 共0.012兲*
110 680.484 共0.017兲*
110 831.101 共0.016兲*
111 384.664 共0.164兲*
111 655.638 共0.012兲*
112 064.281 共0.024兲*
112 273.044 共0.011兲*
112 280.082 共0.011兲*
112 521.357 共0.336兲*
112 520.467 共0.336兲
112 521.777 共0.336兲
112 521.827 共0.336兲
112 541.607 共0.026兲*
112 591.176 共0.010兲*
112 591.021 共0.010兲
112 591.246 共0.010兲
112 591.264 共0.010兲
112 633.269 共0.012兲*
112 652.517 共0.010兲*
112 652.355 共0.010兲
112 652.588 共0.010兲
112 652.607 共0.010兲
112 756.294 共0.352兲*
112 755.400 共0.352兲
112 756.717 共0.352兲
112 756.767 共0.352兲
113 704.052 共0.007兲*
113 702.440 共0.007兲
113 704.560 共0.007兲
113 705.462 共0.007兲
113 761.670 共0.069兲*
113 761.223 共0.069兲
113 761.282 共0.069兲
113 762.502 共0.069兲
114 126.906 共0.012兲*
114 309.459 共0.018兲*
114 577.035 共0.013兲*
114 576.072 共0.013兲
114 577.458 共0.013兲
114 577.585 共0.013兲
198.530
97.822
97.822
97.822
97.822
528.898
528.898
528.898
528.898
11.977
11.977
11.977
11.977
320.496
198.530
320.496
413.948
198.760
612.420
438.978
413.885
320.668
815.163
198.530
198.530
528.648
528.648
528.648
528.648
815.337
106.068
106.068
106.068
106.068
525.111
106.066
106.066
106.066
106.066
528.665
528.665
528.665
528.665
11.780
11.780
11.780
11.780
305.298
305.298
305.298
305.298
486.594
612.464
97.721
97.721
97.720
97.720
3.511
0.218
0.072
0.078
0.066
0.019
0.006
0.007
0.006
0.267
0.079
0.114
0.053
4.407
3.513
4.407
0.023
2.540
5.799
3.950
0.022
4.397
6.688
2.543
2.543
0.026
0.009
0.009
0.008
6.677
1.660
0.548
0.606
0.495
33.760
1.660
0.548
0.606
0.495
0.021
0.007
0.007
0.007
0.039
0.012
0.017
0.008
0.047
0.015
0.016
0.016
31.463
4.832
0.038
0.012
0.014
0.011
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
1
3
1
3
3
3
3
3
3
1
3
3
3
3
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1187
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
12
12
12
12
13
25
19
12
26
30
30
30
8
8
8
8
16
16
16
16
20
13
20
23
23
25
19
19
2
2
2
2
9
9
9
9
9
9
9
9
12
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
5
2
4
2
2
7
7
7
1
1
1
1
1
1
1
1
7
3
7
5
5
2
4
4
2
2
2
2
4
4
4
4
4
4
4
4
1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 − 1
B2
B2
B
B1
B1
B1
B1
B1
B1
B1
B1
B1
E1 − 1
E2 − 1
E1 + 1
A1
A2
A1
A1
A2
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 + 1
F⬘
1
2
0
2
3
2
3
1
2
3
1
12
13
11
8
9
7
16
17
15
2
3
1
9
10
8
9
10
8
J⬙
K⬙a
⌫⬙
0
0
0
0
3
3
3
1
3
3
3
3
3
3
3
3
12
12
12
12
14
25
18
11
26
29
29
29
7
7
7
7
16
16
16
16
21
14
21
22
22
25
18
18
3
3
3
3
10
10
10
10
10
10
10
10
12
0
0
0
0
1
1
1
3
1
1
1
1
1
1
1
1
0
0
0
0
4
1
5
3
1
8
8
8
2
2
2
2
1
1
1
1
6
0
6
6
6
1
5
5
1
1
1
1
3
3
3
3
3
3
3
3
0
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 − 1
B1
B1
B
B2
B2
B2
B2
B2
B2
B2
B2
B2
E1 − 1
E2 + 1
E1 + 1
A2
A1
A2
A2
A1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
114 658.603 共0.020兲
1
1
1
115 231.444 共0.020兲
3
4
A1
2
115 837.305 共0.020兲
3
4
2
115 978.857 共0.020兲
3
4
2
116 337.625 共0.020兲
12
13
11
116 354.911 共0.060兲
116 503.007 共0.020兲
116 693.415 共0.020兲
117 058.097 共0.020兲
117 273.926 共0.020兲
117 627.723 共0.020兲
117 911.252 共0.060兲
7
8
6
16
17
15
118 699.842 共0.060兲
118 906.594 共0.020兲
119 852.650 共0.020兲
119 860.775 共0.020兲
120 517.957 共0.020兲
121 025.597 共0.020兲
121 101.618 共0.020兲
121 118.122 共0.020兲
3
4
2
121 167.133 共0.020兲
10
11
9
121 233.632 共0.020兲
10
11
9
121 263.923 共0.060兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
114 658.597 共0.008兲*
114 658.351 共0.008兲
114 658.646 共0.008兲
114 659.088 共0.008兲
115 231.470 共0.009兲*
115 229.653 共0.009兲
115 232.047 共0.009兲
115 233.044 共0.009兲
115 837.272 共0.010兲*
115 836.964 共0.010兲
115 837.346 共0.010兲
115 837.641 共0.010兲
115 978.884 共0.009兲*
115 977.513 共0.009兲
115 979.311 共0.009兲
115 980.101 共0.009兲
116 337.606 共0.012兲*
116 336.621 共0.012兲
116 338.044 共0.012兲
116 338.163 共0.012兲
116 354.973 共0.012兲*
116 503.000 共0.011兲*
116 693.407 共0.014兲*
117 058.109 共0.010兲*
117 273.953 共0.013兲*
117 627.684 共0.025兲*
117 627.709 共0.025兲*
117 627.733 共0.025兲*
117 911.310 共0.014兲*
117 910.784 共0.014兲
117 911.528 共0.014兲
117 911.632 共0.014兲
118 646.171 共0.074兲*
118 644.691 共0.074兲
118 646.848 共0.074兲
118 646.983 共0.074兲
118 699.762 共0.016兲*
118 782.989 共0.022兲*
118 906.597 共0.014兲*
119 852.664 共0.012兲*
119 860.785 共0.012兲*
120 517.962 共0.013兲*
121 025.583 共0.010兲*
121 101.606 共0.010兲*
121 118.103 共0.010兲*
121 116.287 共0.010兲
121 118.680 共0.010兲
121 119.677 共0.010兲
121 167.124 共0.010兲*
121 166.967 共0.010兲
121 167.194 共0.010兲
121 167.213 共0.010兲
121 233.606 共0.010兲*
121 233.451 共0.010兲
121 233.675 共0.010兲
121 233.693 共0.010兲
121 264.058 共0.014兲*
0.404
0.404
0.404
0.404
11.801
11.801
11.801
11.801
11.818
11.818
11.818
11.818
11.605
11.605
11.605
11.605
115.494
115.494
115.494
115.494
198.605
486.533
320.619
122.306
524.986
815.306
815.306
815.306
52.677
52.677
52.677
52.677
201.743
201.743
201.743
201.743
438.759
155.212
438.886
471.408
471.408
486.602
320.310
320.310
11.642
11.642
11.642
11.642
105.856
105.856
105.856
105.856
105.968
105.968
105.968
105.968
115.392
0.733
0.244
0.407
0.081
0.258
0.077
0.111
0.052
0.267
0.079
0.114
0.053
0.250
0.074
0.107
0.050
0.176
0.058
0.063
0.054
2.542
31.443
4.393
2.645
33.629
6.667
13.335
6.667
2.316
0.760
0.863
0.669
0.017
0.006
0.006
0.005
3.953
0.019
3.946
5.297
5.297
31.425
4.409
4.409
0.258
0.077
0.111
0.052
1.660
0.548
0.606
0.495
1.659
0.547
0.606
0.495
0.030
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1188
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
12
12
12
9
9
9
9
24
19
30
30
30
30
12
27
27
27
27
20
20
20
1
1
1
1
8
8
8
8
13
13
13
13
27
27
27
27
1
1
1
1
24
27
27
13
9
9
9
9
12
28
25
20
20
20
28
12
1
1
1
4
4
4
4
2
4
7
7
7
7
2
2
2
2
2
7
7
7
1
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
2
9
9
3
4
4
4
4
2
1
2
7
7
7
1
2
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 + 1
A2
A
A1
E2 + 1
A2
A2
A2
A2
A1
A
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B2
B2
B2
B2
E2 + 1
B1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
B1
B1
B
B2
E1 + 1
B2
12
13
11
12
12
12
10
10
10
10
24
18
29
29
29
29
11
27
27
27
27
21
21
21
0
0
0
0
7
7
7
7
13
13
13
13
27
27
27
27
0
0
0
0
24
28
28
14
10
10
10
10
11
27
25
21
21
21
27
11
0
0
0
3
3
3
3
1
5
8
8
8
8
3
2
2
2
2
6
6
6
0
0
0
0
2
2
2
2
0
0
0
0
2
2
2
2
0
0
0
0
1
8
8
0
3
3
3
3
3
4
1
6
6
6
4
3
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E1 + 1
E1 − 1
E1 + 1
A1
A
A2
E2 − 1
A1
A1
A1
A1
A2
A
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B1
B1
B1
B1
E2 + 1
B2
B1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 − 1
B2
B2
B
B1
E1 − 1
B1
12
13
11
9
10
8
27
28
26
1
2
0
8
9
7
13
14
12
27
28
26
1
2
0
9
10
8
Obs. Freq. 共unc.兲
共MHz兲
121 296.313 共0.020兲
10
11
9
121 940.015 共0.020兲
122 047.125 共0.060兲
122 289.027 共0.020兲
122 475.304 共0.060兲
122 633.590 共0.020兲
27
28
26
123 279.331 共0.020兲
123 549.225 共0.060兲
1
1
1
123 750.792 共0.020兲
7
8
6
123 792.456 共0.020兲
13
14
12
27
28
26
124 228.031 共0.020兲
1
1
1
124 399.128 共0.020兲
124 751.988 共0.020兲
124 939.240 共0.020兲
10
11
9
124 980.103 共0.020兲
125 303.098 共0.020兲
125 466.548 共0.020兲
125 949.095 共0.020兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
121 263.066 共0.014兲
121 264.499 共0.014兲
121 264.618 共0.014兲
121 296.286 共0.010兲*
121 296.125 共0.010兲
121 296.357 共0.010兲
121 296.376 共0.010兲
121 940.010 共0.012兲*
122 047.180 共0.016兲*
122 289.044 共0.027兲*
122 475.218 共0.037兲*
122 475.242 共0.037兲*
122 475.267 共0.037兲*
122 633.608 共0.012兲*
122 977.173 共0.674兲*
122 976.274 共0.674兲
122 977.599 共0.674兲
122 977.648 共0.674兲
123 279.311 共0.017兲*
123 279.331 共0.017兲*
123 279.351 共0.017兲*
123 549.174 共0.008兲*
123 549.003 共0.008兲
123 549.208 共0.008兲
123 549.516 共0.008兲
123 750.768 共0.013兲*
123 750.241 共0.013兲
123 750.986 共0.013兲
123 751.090 共0.013兲
123 792.467 共0.015兲*
123 791.449 共0.015兲
123 792.924 共0.015兲
123 793.038 共0.015兲
123 814.286 共0.636兲*
123 813.383 共0.636兲
123 814.714 共0.636兲
123 814.764 共0.636兲
124 228.018 共0.008兲*
124 226.958 共0.008兲
124 228.230 共0.008兲
124 230.137 共0.008兲
124 399.123 共0.012兲*
124 752.019 共0.022兲*
124 752.019 共0.022兲*
124 870.500 共0.023兲*
124 939.252 共0.011兲*
124 939.094 共0.011兲
124 939.322 共0.011兲
124 939.340 共0.011兲
124 980.126 共0.011兲*
125 101.525 共0.326兲*
125 303.110 共0.013兲*
125 466.531 共0.017兲*
125 466.551 共0.017兲*
125 466.571 共0.017兲*
125 858.439 共0.312兲*
125 949.084 共0.013兲*
115.392
115.392
115.392
105.966
105.966
105.966
105.966
449.542
320.471
814.991
815.171
815.171
815.171
122.202
568.569
568.569
568.569
568.569
438.924
438.924
438.924
0.301
0.301
0.301
0.301
52.639
52.639
52.639
52.639
134.624
134.624
134.624
134.624
568.598
568.598
568.598
568.598
0.206
0.206
0.206
0.206
449.480
772.552
772.552
155.112
106.038
106.038
106.038
106.038
122.124
602.235
486.473
438.823
438.823
438.823
602.265
122.332
0.010
0.011
0.009
1.659
0.547
0.606
0.495
29.234
4.401
6.690
6.677
13.354
6.677
1.080
0.029
0.010
0.010
0.009
3.944
7.889
3.944
0.655
0.218
0.364
0.073
2.308
0.757
0.860
0.667
0.144
0.048
0.051
0.044
0.018
0.006
0.006
0.006
1.582
0.527
0.879
0.176
29.233
5.350
5.350
0.018
1.657
0.547
0.605
0.494
1.909
0.077
31.308
3.948
7.896
3.948
0.088
2.979
3
3
3
1
1
1
1
3
3
3
1
3
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
3
3
3
3
3
3
3
1
1
3
3
3
3
3
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1189
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
16
27
27
27
27
1
1
1
1
5
5
5
5
27
27
27
27
8
8
8
8
9
9
9
9
9
9
9
9
12
12
8
8
8
8
23
23
13
24
12
1
1
1
1
13
13
13
13
5
5
5
5
20
23
23
21
21
6
2
2
2
2
1
1
1
1
0
0
0
0
2
2
2
2
1
1
1
1
4
4
4
4
1
1
1
1
2
2
1
1
1
1
5
5
3
2
2
1
1
1
1
1
1
1
1
3
3
3
3
7
5
2
0
0
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
A2
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B2
B2
A2
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E1 − 1
A2
A2
F⬘
27
28
26
1
2
0
4
6
5
27
28
26
8
9
7
9
10
8
8
10
9
8
9
7
1
2
0
13
14
12
5
6
4
20
J⬙
K⬙a
⌫⬙
17
27
27
27
27
0
0
0
0
4
4
4
4
27
27
27
27
7
7
7
7
10
10
10
10
8
8
8
8
11
11
7
7
7
7
22
22
14
24
11
0
0
0
0
13
13
13
13
6
6
6
6
21
22
23
20
20
5
2
2
2
2
0
0
0
0
1
1
1
1
2
2
2
2
2
2
2
2
3
3
3
3
2
2
2
2
3
3
2
2
2
2
6
6
0
1
3
0
0
0
0
0
0
0
0
2
2
2
2
6
6
1
3
3
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
A1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B1
B1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E1 + 1
A1
A1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
126 552.891 共0.060兲
27
28
26
126 569.624 共0.020兲
1
1
1
126 664.485 共0.020兲
3
5
4
27
28
26
126 867.494 共0.020兲
7
8
6
127 096.777 共0.020兲
10
11
9
127 343.598 共0.020兲
7
9
8
127 824.784 共0.060兲
128 206.031 共0.060兲
128 257.005 共0.060兲
7
8
6
128 302.937 共0.020兲
128 310.937 共0.020兲
128 449.722 共0.020兲
128 579.230 共0.020兲
128 644.116 共0.060兲
1
1
1
13
14
12
128 896.395 共0.020兲
6
7
5
128 939.733 共0.060兲
129 530.714 共0.020兲
129 754.766 共0.020兲
19
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
126 552.954 共0.015兲*
126 567.954 共0.394兲*
126 567.041 共0.394兲
126 568.387 共0.394兲
126 568.437 共0.394兲
126 569.597 共0.005兲*
126 569.239 共0.006兲
126 569.668 共0.005兲
126 570.312 共0.006兲
126 664.492 共0.010兲*
126 663.882 共0.010兲
126 664.152 共0.010兲
126 665.390 共0.010兲
126 861.936 共0.413兲*
126 861.019 共0.413兲
126 862.370 共0.413兲
126 862.420 共0.413兲
126 867.519 共0.008兲*
126 866.956 共0.008兲
126 867.752 共0.008兲
126 867.863 共0.008兲
127 096.783 共0.011兲*
127 096.626 共0.011兲
127 096.854 共0.011兲
127 096.872 共0.011兲
127 343.597 共0.014兲*
127 343.098 共0.014兲
127 343.225 共0.014兲
127 344.456 共0.014兲
127 824.720 共0.016兲*
128 206.074 共0.012兲*
128 256.959 共0.010兲*
128 256.457 共0.010兲
128 257.167 共0.010兲
128 257.267 共0.010兲
128 302.910 共0.014兲*
128 310.911 共0.014兲*
128 369.694 共0.028兲*
128 449.724 共0.013兲*
128 579.200 共0.009兲*
128 644.071 共0.006兲*
128 643.639 共0.006兲
128 644.158 共0.006兲
128 644.936 共0.006兲
128 745.104 共0.017兲*
128 744.082 共0.017兲
128 745.563 共0.017兲
128 745.677 共0.017兲
128 896.395 共0.010兲*
128 896.049 共0.010兲
128 896.535 共0.010兲
128 896.614 共0.010兲
128 939.674 共0.017兲*
129 530.712 共0.015兲*
129 754.758 共0.013兲*
129 908.712 共0.077兲*
129 908.225 共0.077兲
294.024
568.350
568.350
568.350
568.350
0.404
0.404
0.404
0.404
17.950
17.950
17.950
17.950
568.366
568.366
568.366
568.366
52.553
52.553
52.553
52.553
105.934
105.934
105.934
105.934
64.473
64.473
64.473
64.473
122.233
122.306
52.458
52.458
52.458
52.458
471.308
471.308
155.027
449.547
121.922
0.301
0.301
0.301
0.301
134.524
134.524
134.524
134.524
42.197
42.197
42.197
42.197
438.567
471.243
413.948
335.242
335.242
3.070
0.025
0.008
0.009
0.008
0.850
0.283
0.472
0.094
2.992
0.776
1.179
0.957
0.020
0.007
0.007
0.006
1.442
0.473
0.537
0.417
1.658
0.547
0.605
0.495
2.253
0.663
0.830
0.742
2.985
0.360
1.345
0.441
0.501
0.389
5.293
5.293
0.030
29.217
0.350
0.928
0.309
0.515
0.103
0.024
0.008
0.008
0.007
0.789
0.256
0.303
0.215
3.953
5.293
27.126
0.139
0.044
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
3
1
1
1
1
3
3
3
1
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1190
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
21
21
23
12
28
8
8
8
8
13
28
23
3
3
3
3
3
3
3
3
9
9
9
9
14
14
14
14
3
3
3
3
23
12
3
3
3
3
21
21
21
21
12
28
3
3
3
3
3
3
3
3
3
3
3
3
3
0
0
5
2
1
1
1
1
1
3
1
5
1
1
1
1
1
1
1
1
4
4
4
4
1
1
1
1
1
1
1
1
2
2
1
1
1
1
0
0
0
0
2
1
0
0
0
0
0
0
0
0
0
0
0
0
0
A2
A2
E2 + 1
E2 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B1
E2 + 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
22
21
20
20
22
11
27
7
7
7
7
14
27
22
2
2
2
2
2
2
2
2
10
10
10
10
14
14
14
14
2
2
2
2
23
11
2
2
2
2
20
20
20
20
11
27
2
2
2
2
2
2
2
2
2
2
2
2
2
3
3
6
3
4
2
2
2
2
0
4
6
1
1
1
1
1
1
1
1
3
3
3
3
0
0
0
0
1
1
1
1
1
3
1
1
1
1
3
3
3
3
3
4
0
0
0
0
0
0
0
0
0
0
0
0
0
A1
A1
E2 + 1
E2 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A2
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B2
E2 + 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
21
20
8
9
7
4
2
3
4
2
3
9
10
8
14
15
13
2
4
3
2
4
3
20
22
21
4
3
2
4
3
2
4
3
2
Obs. Freq. 共unc.兲
共MHz兲
129 975.755 共0.060兲
129 988.659 共0.060兲
130 211.807 共0.020兲
7
8
6
131 603.057 共0.060兲
131 685.374 共0.020兲
3
1
2
131 685.749 共0.020兲
3
1
2
131 946.690 共0.020兲
10
11
9
132 093.519 共0.060兲
14
15
13
132 201.245 共0.020兲
1
3
2
132 295.205 共0.020兲
132 335.172 共0.060兲
132 592.754 共0.020兲
1
3
2
19
21
20
132 728.525 共0.020兲
132 981.947 共0.020兲
3
2
1
132 982.380 共0.020兲
3
2
1
132 983.805 共0.020兲
3
2
1
132 984.724 共0.020兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
129 908.288 共0.077兲
129 909.619 共0.077兲
129 975.698 共0.016兲*
129 988.608 共0.014兲*
130 184.247 共0.367兲*
130 211.780 共0.009兲*
130 211.225 共0.009兲
130 212.009 共0.009兲
130 212.120 共0.009兲
131 373.827 共0.024兲*
131 446.503 共0.542兲*
131 603.009 共0.016兲*
131 685.367 共0.003兲*
131 685.266 共0.003兲
131 685.457 共0.003兲
131 685.521 共0.003兲
131 685.766 共0.003兲*
131 685.664 共0.003兲
131 685.855 共0.003兲
131 685.919 共0.003兲
131 946.681 共0.010兲*
131 946.525 共0.010兲
131 946.751 共0.010兲
131 946.769 共0.010兲
132 093.564 共0.020兲*
132 092.514 共0.020兲
132 094.039 共0.020兲
132 094.148 共0.020兲
132 201.246 共0.004兲*
132 201.096 共0.004兲
132 201.098 共0.004兲
132 201.595 共0.004兲
132 295.210 共0.012兲*
132 335.126 共0.012兲*
132 592.750 共0.003兲*
132 592.606 共0.003兲
132 592.629 共0.003兲
132 593.047 共0.003兲
132 633.421 共0.077兲*
132 632.933 共0.077兲
132 632.995 共0.077兲
132 634.331 共0.077兲
132 728.522 共0.013兲*
132 863.615 共0.385兲*
132 981.939 共0.004兲*
132 981.906 共0.004兲
132 981.951 共0.004兲
132 982.052 共0.004兲
132 982.388 共0.004兲*
132 982.354 共0.004兲
132 982.400 共0.004兲
132 982.500 共0.004兲
132 983.798 共0.004兲*
132 983.764 共0.004兲
132 983.810 共0.004兲
132 983.910 共0.004兲
132 984.734 共0.004兲*
335.242
335.242
471.462
122.202
602.121
52.393
52.393
52.393
52.393
154.829
602.096
471.370
7.249
7.249
7.249
7.249
7.408
7.408
7.408
7.408
105.654
105.654
105.654
105.654
155.212
155.212
155.211
155.211
7.370
7.370
7.370
7.370
413.885
122.124
7.182
7.182
7.182
7.183
335.335
335.335
335.335
335.335
122.336
601.976
4.643
4.643
4.643
4.643
4.841
4.841
4.841
4.841
4.737
4.737
4.737
4.737
4.437
0.048
0.046
5.279
1.923
0.057
0.972
0.319
0.362
0.281
0.027
0.135
5.288
0.251
0.108
0.050
0.074
0.251
0.108
0.050
0.075
1.660
0.548
0.606
0.495
0.120
0.040
0.043
0.037
0.245
0.049
0.105
0.073
27.148
1.097
0.249
0.050
0.107
0.074
0.149
0.047
0.052
0.050
3.012
0.061
0.284
0.122
0.084
0.057
0.283
0.121
0.084
0.057
0.282
0.121
0.084
0.056
0.282
1
1
1
1
3
1
1
1
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
1
3
3
3
3
1
1
1
1
3
3
3
3
1
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1191
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
28
9
9
9
9
24
3
3
3
3
27
3
3
3
3
27
27
3
3
3
3
3
0
0
0
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
2
1
1
1
1
9
1
1
1
1
9
9
1
1
1
1
1
A2
A2
A2
B1
B1
B1
B1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
B2
B2
B2
B2
B1
A1
A1
A1
A1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
A2
A2
A2
A2
B2
4
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
27
8
8
8
8
24
2
2
2
2
28
2
2
2
2
28
28
2
2
2
2
2
0
0
0
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
4
2
2
2
2
1
1
1
1
1
8
1
1
1
1
8
8
1
1
1
1
1
A1
A1
A1
B2
B2
B2
B2
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
B1
B1
B1
B1
B2
A2
A2
A2
A2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
A1
A1
A1
A1
B1
3
2
1
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
8
10
9
4
3
2
3
4
2
2
4
3
Obs. Freq. 共unc.兲
共MHz兲
133 008.250 共0.020兲
1
3
2
133 008.592 共0.020兲
1
3
2
1
3
2
133 021.099 共0.020兲
1
3
2
133 023.194 共0.020兲
1
3
2
1
3
2
1
3
2
133 036.340 共0.020兲
1
3
2
133 224.733 共0.060兲
7
9
8
133 366.566 共0.020兲
133 421.065 共0.020兲
3
2
1
133 810.677 共0.020兲
2
3
1
134 202.258 共0.020兲
134 324.933 共0.060兲
1
3
2
134 329.075 共0.060兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
132 984.701 共0.004兲
132 984.746 共0.004兲
132 984.847 共0.004兲
133 008.251 共0.003兲*
133 007.648 共0.003兲
133 008.079 共0.003兲
133 008.855 共0.003兲
133 008.584 共0.003兲*
133 007.981 共0.003兲
133 008.412 共0.003兲
133 009.188 共0.003兲
133 020.988 共0.003兲*
133 020.389 共0.003兲
133 020.818 共0.003兲
133 021.585 共0.003兲
133 021.113 共0.003兲*
133 020.514 共0.003兲
133 020.943 共0.003兲
133 021.711 共0.003兲
133 023.173 共0.003兲*
133 022.574 共0.003兲
133 023.003 共0.003兲
133 023.770 共0.003兲
133 023.192 共0.003兲*
133 022.593 共0.003兲
133 023.022 共0.003兲
133 023.789 共0.003兲
133 036.323 共0.003兲*
133 035.728 共0.003兲
133 036.155 共0.003兲
133 036.915 共0.003兲
133 036.341 共0.003兲*
133 035.746 共0.003兲
133 036.173 共0.003兲
133 036.932 共0.003兲
133 138.083 共0.554兲*
133 224.788 共0.014兲*
133 224.288 共0.014兲
133 224.416 共0.014兲
133 225.648 共0.014兲
133 366.570 共0.014兲*
133 421.063 共0.004兲*
133 421.054 共0.004兲
133 421.074 共0.004兲
133 421.083 共0.004兲
133 467.129 共0.053兲*
133 810.676 共0.004兲*
133 810.633 共0.004兲
133 810.692 共0.004兲
133 810.700 共0.004兲
134 202.245 共0.021兲*
134 202.245 共0.021兲*
134 324.967 共0.004兲*
134 324.753 共0.004兲
134 324.938 共0.004兲
134 325.121 共0.004兲
134 329.149 共0.004兲*
4.437
4.437
4.437
15.682
15.682
15.682
15.682
15.644
15.644
15.644
15.644
15.474
15.474
15.474
15.474
15.573
15.573
15.573
15.573
15.416
15.416
15.416
15.416
15.280
15.280
15.280
15.280
15.645
15.645
15.645
15.645
15.682
15.682
15.682
15.682
601.923
64.436
64.436
64.436
64.436
449.415
7.588
7.588
7.588
7.588
772.582
7.559
7.559
7.559
7.559
772.417
772.417
7.496
7.496
7.496
7.496
7.337
0.121
0.083
0.056
0.157
0.031
0.067
0.047
0.157
0.031
0.067
0.047
0.157
0.031
0.067
0.047
0.157
0.031
0.067
0.047
0.157
0.031
0.067
0.046
0.157
0.031
0.067
0.046
0.157
0.031
0.067
0.047
0.157
0.031
0.067
0.047
0.123
2.251
0.662
0.829
0.741
29.114
0.249
0.107
0.074
0.050
5.344
0.245
0.072
0.105
0.049
5.347
5.347
0.252
0.050
0.108
0.075
0.251
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
1
1
3
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1192
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
3
3
3
9
9
9
9
12
5
5
5
5
16
9
9
9
9
27
1
1
1
1
16
8
8
8
8
5
5
5
5
27
16
23
5
5
5
5
21
21
21
21
9
9
9
9
16
14
14
14
14
27
16
22
5
5
5
1
1
1
1
1
1
1
2
0
0
0
0
6
1
1
1
1
9
1
1
1
1
3
1
1
1
1
3
3
3
3
9
6
2
3
3
3
3
0
0
0
0
1
1
1
1
6
1
1
1
1
6
3
2
0
0
0
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E2 + 1
E2 + 1
A1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 + 1
E1 − 1
B2
B2
B2
2
4
3
2
2
2
8
8
8
8
11
4
4
4
4
17
8
8
8
8
28
0
0
0
0
15
7
7
7
7
6
6
6
6
28
17
23
6
6
6
6
20
20
20
20
8
8
8
8
17
14
14
14
14
26
15
22
4
4
4
1
1
1
2
2
2
2
3
1
1
1
1
5
2
2
2
2
8
0
0
0
0
4
2
2
2
2
2
2
2
2
8
5
1
2
2
2
2
3
3
3
3
2
2
2
2
5
0
0
0
0
7
4
1
1
1
1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
A1
A1
A1
A1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
E2 + 1
E2 + 1
A2
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E1 + 1
B1
B1
B1
1
3
2
8
10
9
4
6
5
8
10
9
1
2
0
8
9
7
5
6
4
5
6
4
20
22
21
8
10
9
14
15
13
4
6
Obs. Freq. 共unc.兲
共MHz兲
134 478.242 共0.060兲
7
9
8
134 519.943 共0.060兲
134 631.679 共0.020兲
3
5
4
134 692.125 共0.020兲
134 845.659 共0.020兲
7
9
8
134 855.819 共0.020兲
135 174.683 共0.020兲
1
1
1
135 195.028 共0.060兲
135 645.809 共0.020兲
7
8
6
135 911.458 共0.020兲
6
7
5
135 945.260 共0.060兲
136 352.798 共0.020兲
136 379.713 共0.020兲
136 395.070 共0.020兲
6
7
5
19
21
20
136 778.150 共0.060兲
7
9
8
136 844.762 共0.020兲
14
15
13
137 159.620 共0.020兲
137 500.832 共0.020兲
137 521.827 共0.060兲
137 583.312 共0.020兲
3
5
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
134 328.935 共0.004兲
134 329.119 共0.004兲
134 329.302 共0.004兲
134 478.295 共0.010兲*
134 477.742 共0.010兲
134 477.885 共0.010兲
134 479.244 共0.010兲
134 520.004 共0.014兲*
134 631.684 共0.006兲*
134 631.144 共0.006兲
134 631.379 共0.006兲
134 632.484 共0.006兲
134 692.134 共0.016兲*
134 845.631 共0.010兲*
134 845.085 共0.010兲
134 845.226 共0.010兲
134 846.569 共0.010兲
134 855.853 共0.021兲*
135 174.686 共0.009兲*
135 173.626 共0.009兲
135 174.898 共0.009兲
135 176.805 共0.009兲
135 195.126 共0.011兲*
135 645.829 共0.009兲*
135 645.257 共0.010兲
135 646.066 共0.009兲
135 646.180 共0.009兲
135 911.469 共0.010兲*
135 911.159 共0.010兲
135 911.594 共0.010兲
135 911.666 共0.010兲
135 945.323 共0.028兲*
136 352.790 共0.016兲*
136 379.710 共0.014兲*
136 395.093 共0.010兲*
136 394.703 共0.010兲
136 395.249 共0.010兲
136 395.339 共0.010兲
136 437.186 共0.082兲*
136 436.706 共0.082兲
136 436.767 共0.082兲
136 438.084 共0.082兲
136 778.195 共0.011兲*
136 777.699 共0.011兲
136 777.826 共0.011兲
136 779.047 共0.011兲
136 844.802 共0.016兲*
137 055.904 共0.020兲*
137 054.852 共0.020兲
137 056.380 共0.020兲
137 056.489 共0.020兲
137 159.586 共0.018兲*
137 500.823 共0.015兲*
137 521.807 共0.013兲*
137 583.292 共0.010兲*
137 582.682 共0.010兲
137 582.951 共0.010兲
7.337
7.337
7.337
64.300
64.300
64.300
64.300
122.236
17.985
17.985
17.985
17.985
294.073
64.390
64.390
64.390
64.390
772.620
0.000
0.000
0.000
0.000
220.934
52.261
52.261
52.261
52.261
42.277
42.277
42.277
42.277
772.409
294.111
413.951
42.261
42.261
42.261
42.261
335.262
335.262
335.262
335.262
64.223
64.223
64.223
64.223
293.875
155.112
155.112
155.112
155.112
650.971
221.053
379.815
17.792
17.792
17.792
0.050
0.108
0.074
0.693
0.204
0.255
0.228
3.021
2.787
0.723
1.098
0.892
3.066
0.776
0.228
0.286
0.256
5.339
1.583
0.528
0.879
0.176
3.896
0.880
0.289
0.328
0.254
0.789
0.256
0.303
0.215
5.350
3.063
27.134
0.788
0.255
0.303
0.215
0.113
0.036
0.039
0.038
1.570
0.462
0.578
0.517
3.067
0.019
0.006
0.007
0.006
6.186
0.152
25.132
2.988
0.775
1.177
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
3
3
3
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1193
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
5
28
28
28
28
5
5
5
5
5
5
5
5
16
16
5
5
5
5
23
12
5
5
5
5
16
22
5
5
5
5
27
27
15
15
15
15
23
28
28
28
28
21
21
21
21
28
28
28
28
16
27
27
23
23
23
9
0
2
2
2
2
0
0
0
0
3
3
3
3
6
6
3
3
3
3
5
2
3
3
3
3
3
2
3
3
3
3
6
6
1
1
1
1
2
2
2
2
2
0
0
0
0
2
2
2
2
3
6
6
8
8
8
1
B2
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B2
B1
B1
B1
B1
E2 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
A1
A2
A2
A1
E1 + 1
E1 − 1
5
4
28
28
28
28
4
4
4
4
6
6
6
6
17
17
6
6
6
6
22
11
6
6
6
6
15
22
6
6
6
6
26
26
15
15
15
15
23
28
28
28
28
20
20
20
20
28
28
28
28
15
26
26
24
24
24
8
1
2
2
2
2
1
1
1
1
2
2
2
2
5
5
2
2
2
2
6
3
2
2
2
2
4
1
2
2
2
2
7
7
0
0
0
0
1
2
2
2
2
3
3
3
3
2
2
2
2
4
7
7
7
7
7
2
B1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B1
B2
B2
B2
B2
E2 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
A2
A1
A1
A2
E1 + 1
E1 − 1
4
28
29
27
4
6
5
5
6
4
5
6
4
5
6
4
5
6
4
15
16
14
28
29
27
20
22
21
28
29
27
Obs. Freq. 共unc.兲
共MHz兲
28
29
27
137 774.448 共0.020兲
3
5
4
137 797.085 共0.020兲
6
7
5
137 950.573 共0.020兲
137 950.972 共0.020兲
138 286.823 共0.020兲
6
7
5
139 597.898 共0.020兲
139 727.142 共0.020兲
139 740.707 共0.020兲
6
7
5
140 035.916 共0.020兲
140 143.567 共0.020兲
140 254.496 共0.060兲
6
7
5
140 590.951 共0.020兲
140 591.747 共0.020兲
141 268.464 共0.060兲
15
16
14
141 415.960 共0.020兲
28
29
27
19
21
20
28
29
27
142 095.145 共0.020兲
142 708.906 共0.020兲
142 709.698 共0.020兲
143 049.856 共0.060兲
143 084.119 共0.020兲
143 691.447 共0.020兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
137 584.190 共0.010兲
137 675.746 共0.807兲*
137 674.826 共0.807兲
137 676.183 共0.807兲
137 676.232 共0.807兲
137 774.487 共0.006兲*
137 774.095 共0.006兲
137 774.258 共0.006兲
137 775.081 共0.006兲
137 797.088 共0.010兲*
137 796.778 共0.010兲
137 797.212 共0.010兲
137 797.283 共0.010兲
137 950.581 共0.013兲*
137 950.982 共0.013兲*
138 286.831 共0.009兲*
138 286.441 共0.009兲
138 286.987 共0.009兲
138 287.077 共0.009兲
139 597.877 共0.015兲*
139 727.165 共0.010兲*
139 740.713 共0.010兲*
139 740.353 共0.010兲
139 740.858 共0.010兲
139 740.940 共0.010兲
140 035.904 共0.011兲*
140 143.577 共0.012兲*
140 254.570 共0.010兲*
140 254.234 共0.010兲
140 254.705 共0.010兲
140 254.782 共0.010兲
140 590.920 共0.015兲*
140 591.716 共0.015兲*
141 268.536 共0.027兲*
141 267.454 共0.027兲
141 269.028 共0.027兲
141 269.133 共0.027兲
141 415.946 共0.014兲*
141 478.620 共0.460兲*
141 477.686 共0.460兲
141 479.063 共0.460兲
141 479.112 共0.460兲
141 526.282 共0.077兲*
141 525.787 共0.077兲
141 525.850 共0.077兲
141 527.206 共0.077兲
141 823.905 共0.483兲*
141 822.968 共0.483兲
141 824.350 共0.483兲
141 824.399 共0.483兲
142 095.153 共0.012兲*
142 708.887 共0.015兲*
142 709.679 共0.015兲*
143 049.836 共0.031兲*
143 049.839 共0.031兲*
143 084.104 共0.020兲*
143 691.412 共0.010兲*
17.792
609.723
609.723
609.723
609.723
17.984
17.984
17.984
17.984
42.315
42.315
42.315
42.315
293.900
293.900
42.299
42.299
42.299
42.299
471.052
121.922
42.040
42.040
42.040
42.040
221.053
379.751
42.100
42.100
42.100
42.100
651.111
651.111
177.253
177.253
177.253
177.253
413.815
609.505
609.505
609.505
609.505
335.184
335.184
335.184
335.184
609.520
609.521
609.520
609.520
221.084
651.138
651.138
575.888
575.888
575.704
64.095
0.956
0.028
0.009
0.010
0.009
2.377
0.616
0.937
0.761
0.788
0.255
0.303
0.215
3.068
3.068
0.788
0.255
0.303
0.215
5.298
2.661
0.773
0.250
0.297
0.211
3.743
25.183
0.773
0.250
0.297
0.211
6.175
6.175
0.101
0.033
0.036
0.031
27.043
0.024
0.008
0.008
0.008
0.155
0.049
0.054
0.052
0.019
0.006
0.006
0.006
3.881
6.166
6.166
4.468
4.468
4.474
1.476
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
3
1
1
1
1
1
1
1
1
1
1
3
3
1
1
1
1
3
3
3
3
3
1
1
1
1
1
1
1
1
3
1
1
1
1
3
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1194
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
9
9
9
27
22
12
5
5
5
5
21
16
12
12
16
16
16
16
27
27
21
29
29
29
29
23
23
23
21
16
29
29
29
29
5
5
5
5
22
12
29
29
29
29
20
16
16
16
16
21
21
21
5
5
5
5
20
1
1
1
9
2
5
0
0
0
0
2
3
5
5
3
3
6
6
6
6
2
4
4
4
4
8
8
8
0
3
4
4
4
4
3
3
3
3
2
5
4
4
4
4
4
1
1
1
1
2
4
4
0
0
0
0
2
E1 − 1
E1 − 1
E1 − 1
E1 + 1
A2
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
A2
A1
A2
E2 + 1
A1
A1
A2
E1 + 1
E1 − 1
E2 + 1
B1
B1
B1
B1
B2
B
B1
E1 + 1
E2 − 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E2 + 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
8
10
9
8
8
8
28
22
13
4
4
4
4
21
15
13
13
15
15
17
17
26
26
21
30
30
30
30
24
24
24
20
15
30
30
30
30
6
6
6
6
22
13
30
30
30
30
19
16
16
16
16
21
22
22
4
4
4
4
20
2
2
2
8
1
4
1
1
1
1
1
4
4
4
4
4
5
5
7
7
1
1
1
1
1
7
7
7
3
4
1
1
1
1
2
2
2
2
1
4
1
1
1
1
5
0
0
0
0
1
1
1
1
1
1
1
1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
A1
A2
A1
E2 + 1
A2
A2
A1
E1 + 1
E1 − 1
E2 + 1
B2
B2
B2
B2
B1
B
B2
E1 + 1
E2 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E2 + 1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
7
9
8
5
6
4
29
30
28
29
30
28
5
6
4
29
30
28
16
17
15
5
6
4
Obs. Freq. 共unc.兲
共MHz兲
144 012.297 共0.020兲
144 260.676 共0.020兲
144 455.453 共0.020兲
144 748.091 共0.020兲
4
5
3
145 193.469 共0.020兲
145 299.029 共0.060兲
145 424.820 共0.020兲
145 428.657 共0.020兲
145 726.063 共0.020兲
146 269.263 共0.020兲
146 591.065 共0.020兲
146 591.470 共0.020兲
147 104.529 共0.020兲
147 129.374 共0.060兲
147 898.677 共0.020兲
30
31
29
148 020.578 共0.020兲
148 261.176 共0.020兲
30
31
29
149 223.890 共0.020兲
6
7
5
149 404.611 共0.020兲
30
31
29
16
17
15
4
5
3
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
143 690.879 共0.010兲
143 691.017 共0.010兲
143 692.327 共0.010兲
144 012.311 共0.022兲*
144 260.662 共0.015兲*
144 455.459 共0.013兲*
144 748.097 共0.007兲*
144 747.581 共0.007兲
144 748.271 共0.007兲
144 748.497 共0.007兲
145 193.442 共0.014兲*
145 299.065 共0.012兲*
145 424.835 共0.012兲*
145 428.667 共0.012兲*
145 726.089 共0.011兲*
146 269.281 共0.012兲*
146 591.069 共0.014兲*
146 591.477 共0.014兲*
147 104.560 共0.017兲*
147 129.275 共0.022兲*
147 898.694 共0.013兲*
147 938.665 共0.671兲*
147 937.469 共0.671兲
147 939.235 共0.671兲
147 939.293 共0.671兲
148 020.575 共0.018兲*
148 020.576 共0.018兲*
148 020.578 共0.018兲*
148 142.663 共0.091兲*
148 261.170 共0.010兲*
148 586.667 共0.669兲*
148 585.471 共0.669兲
148 587.236 共0.669兲
148 587.295 共0.669兲
149 223.921 共0.010兲*
149 223.571 共0.010兲
149 224.062 共0.010兲
149 224.142 共0.010兲
149 404.578 共0.015兲*
149 910.934 共0.014兲*
150 380.346 共0.679兲*
150 379.141 共0.679兲
150 380.921 共0.679兲
150 380.980 共0.679兲
150 448.043 共0.013兲*
151 338.165 共0.036兲*
151 337.054 共0.036兲
151 338.673 共0.036兲
151 338.775 共0.036兲
152 047.614 共0.016兲*
152 165.937 共0.146兲*
152 219.049 共0.184兲*
152 549.119 共0.008兲*
152 548.811 共0.008兲
152 549.217 共0.008兲
152 549.371 共0.008兲
152 723.932 共0.014兲*
64.095
64.095
64.095
772.236
379.816
178.215
17.647
17.648
17.647
17.647
347.147
220.890
178.021
178.021
220.779
220.890
293.714
293.714
650.953
650.825
347.081
681.104
681.104
681.103
681.103
575.861
575.861
575.861
334.871
220.779
681.252
681.253
681.252
681.252
41.905
41.905
41.905
41.905
379.677
178.183
681.267
681.267
681.267
681.267
348.777
200.745
200.745
200.745
200.745
347.145
379.751
379.677
17.491
17.491
17.491
17.491
315.945
0.434
0.544
0.486
5.353
25.172
2.187
0.196
0.063
0.077
0.051
23.247
3.893
2.189
2.189
3.749
3.896
3.069
3.069
6.171
6.186
23.333
0.019
0.006
0.007
0.006
4.463
8.927
4.463
0.049
0.153
0.022
0.007
0.008
0.007
0.788
0.255
0.303
0.215
25.093
2.185
0.018
0.006
0.006
0.006
4.788
0.087
0.029
0.030
0.027
23.326
0.017
0.030
0.604
0.193
0.238
0.157
21.459
3
3
3
3
1
3
3
3
3
3
3
1
1
1
1
1
1
1
3
3
1
3
3
3
3
3
1
3
3
1
1
1
1
1
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
3
1
1
1
1
3
Ref.
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1195
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
23
29
21
23
16
20
20
16
21
12
27
19
20
20
12
12
8
8
8
8
8
8
8
8
29
21
29
23
2
2
2
2
2
2
21
20
19
12
13
20
17
17
17
17
22
19
19
19
24
24
20
22
9
9
9
9
20
8
2
4
8
3
4
4
3
4
5
6
7
2
4
5
5
4
4
4
4
4
4
4
4
2
2
2
8
1
1
1
1
1
1
4
2
2
5
2
4
1
1
1
1
0
2
7
7
5
5
2
0
1
1
1
1
4
E2 − 1
A2
A2
E2 + 1
B2
B2
B1
B1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B1
B2
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
B1
E2 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
A2
E1 − 1
E2 + 1
E1 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E2 + 1
E1 − 1
E1 + 1
A2
A1
B2
B1
B2
B2
B2
B2
A2
F⬘
8
9
7
8
9
7
1
2
3
2
1
17
18
16
9
10
8
J⬙
K⬙a
⌫⬙
24
29
22
24
15
19
19
15
22
13
26
20
20
19
13
13
9
9
9
9
9
9
9
9
29
21
29
24
1
1
1
1
1
1
22
20
19
13
12
19
17
17
17
17
21
19
20
20
23
23
20
21
8
8
8
8
19
7
2
1
7
4
5
5
4
1
4
7
6
1
5
4
4
3
3
3
3
3
3
3
3
2
1
2
7
0
0
0
0
0
0
1
1
1
4
3
5
0
0
0
0
3
1
6
6
6
6
1
3
2
2
2
2
5
E2 − 1
A1
A1
E2 + 1
B1
B1
B2
B2
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B2
B1
B2
B2
B2
B2
B1
B1
B1
B1
E1 − 1
B2
E2 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A1
E1 + 1
E2 + 1
E1 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E2 + 1
E1 − 1
E1 + 1
A1
A2
B1
B2
B1
B1
B1
B1
A1
F⬙
9
10
8
9
10
8
1
1
2
2
0
17
18
16
8
9
7
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
153 022.029 共0.022兲*
153 212.369 共0.962兲*
153 500.996 共0.180兲*
153 608.325 共0.022兲*
153 803.005 共0.014兲*
154 475.512 共0.012兲*
154 591.616 共0.012兲*
154 752.560 共0.013兲*
154 773.130 共0.140兲*
154 923.464 共0.014兲*
154 978.932 共0.022兲*
155 139.454 共0.019兲*
155 517.698 共0.013兲*
156 159.130 共0.014兲*
156 681.635 共0.013兲*
156 685.553 共0.013兲*
157 001.220 共0.011兲*
157 001.013 共0.011兲
157 001.310 共0.011兲
157 001.339 共0.011兲
157 034.312 共0.011兲*
157 034.102 共0.011兲
157 034.404 共0.011兲
157 034.434 共0.011兲
157 225.982 共0.538兲*
157 288.190 共0.016兲*
157 615.671 共0.564兲*
158 605.124 共0.022兲*
158 867.794 共0.009兲*
158 866.724 共0.009兲
158 867.656 共0.009兲
158 867.781 共0.009兲
158 868.380 共0.009兲
158 868.534 共0.009兲
159 202.052 共0.133兲*
159 698.409 共0.018兲*
160 069.630 共0.015兲*
160 757.327 共0.014兲*
161 058.043 共0.012兲*
161 194.432 共0.016兲*
162 314.378 共0.050兲*
162 313.240 共0.050兲
162 314.901 共0.050兲
162 314.999 共0.050兲
162 757.789 共0.097兲*
162 960.701 共0.014兲*
163 007.636 共0.019兲*
163 242.638 共0.017兲*
164 303.480 共0.015兲*
164 315.828 共0.015兲*
165 025.383 共0.017兲*
165 447.305 共0.096兲*
165 476.973 共0.016兲*
165 476.459 共0.016兲
165 477.190 共0.016兲
165 477.279 共0.016兲
165 485.190 共0.011兲*
575.721
652.329
379.816
575.529
220.704
348.566
348.566
220.704
379.815
178.064
650.780
407.967
315.879
348.739
177.834
177.834
91.278
91.279
91.278
91.278
91.277
91.277
91.277
91.277
652.112
347.004
652.126
575.573
1.883
1.883
1.883
1.883
1.883
1.883
379.815
315.941
286.213
177.908
140.052
348.689
225.687
225.687
225.687
225.687
366.315
286.146
407.748
407.875
505.364
505.364
315.798
366.406
64.522
64.522
64.522
64.522
348.381
4.468
0.027
0.033
4.473
3.900
4.794
4.794
3.903
0.018
2.186
6.179
3.592
21.594
4.782
2.189
2.189
1.316
0.433
0.485
0.387
1.316
0.433
0.485
0.387
0.023
23.259
0.018
4.471
0.929
0.077
0.232
0.434
0.077
0.103
0.017
21.591
19.758
2.187
2.800
4.778
0.075
0.025
0.026
0.023
0.158
19.958
3.594
3.588
5.682
5.682
21.533
0.170
2.823
0.929
1.040
0.830
4.797
1
1
1
1
3
3
3
3
3
3
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
1
1
1
1
1
1
3
1
3
1
3
1
1
1
1
1
1
1
3
3
1
1
3
3
3
3
3
3
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1196
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
8
8
8
8
20
8
8
8
8
8
8
8
8
13
20
10
10
10
10
19
18
2
2
2
2
2
2
19
19
6
6
6
6
13
26
26
12
8
8
8
8
22
2
2
2
2
2
2
30
13
19
19
18
29
15
29
2
4
4
4
4
4
4
4
4
4
4
4
4
4
2
4
1
1
1
1
2
2
1
1
1
1
1
1
7
7
0
0
0
0
2
9
9
3
4
4
4
4
0
1
1
1
1
1
1
2
2
7
7
2
1
6
1
1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A1
A2
A2
A2
A2
E2 + 1
E1 − 1
B2
B2
B2
B2
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A1
A1
A1
A1
A1
E2 + 1
B1
B2
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
B1
B1
B1
B1
B1
B1
A1
B1
B2
B1
E2 + 1
E2 + 1
E2 − 1
E1 + 1
E2 + 1
F⬘
8
9
7
8
9
7
8
9
7
9
11
10
1
3
2
1
2
5
7
6
8
9
7
2
2
1
3
1
J⬙
K⬙a
⌫⬙
9
9
9
9
19
9
9
9
9
9
9
9
9
12
19
9
9
9
9
19
18
1
1
1
1
1
1
20
20
5
5
5
5
12
27
27
13
9
9
9
9
21
1
1
1
1
1
1
30
12
20
20
18
28
16
28
1
3
3
3
3
5
3
3
3
3
3
3
3
3
3
5
2
2
2
2
1
1
0
0
0
0
0
0
6
6
1
1
1
1
3
8
8
0
3
3
3
3
3
0
0
0
0
0
0
2
3
6
6
1
4
5
4
0
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
E1 − 1
B1
B1
B1
B1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
A2
A2
A2
A2
E2 + 1
B2
B1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
B2
B2
A2
B2
B1
B2
E2 + 1
E2 − 1
E2 − 1
E1 − 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
9
10
8
9
10
8
9
10
8
8
10
9
1
2
1
0
2
4
6
5
9
10
8
169 447.508 共0.100兲
1
2
1
2
0
171 035.274 共0.100兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
165 566.241 共0.012兲*
165 566.034 共0.012兲
165 566.331 共0.012兲
165 566.360 共0.012兲
165 598.775 共0.012兲*
165 658.813 共0.011兲*
165 658.607 共0.011兲
165 658.903 共0.011兲
165 658.932 共0.011兲
165 692.628 共0.011兲*
165 692.419 共0.011兲
165 692.720 共0.011兲
165 692.749 共0.011兲
166 248.905 共0.015兲*
166 525.902 共0.019兲*
167 112.266 共0.017兲*
167 111.782 共0.017兲
167 111.895 共0.017兲
167 113.112 共0.017兲
167 174.043 共0.019兲*
167 188.848 共0.015兲*
167 598.269 共0.008兲*
167 597.011 共0.008兲
167 598.202 共0.008兲
167 598.319 共0.008兲
167 598.822 共0.008兲
167 599.043 共0.008兲
167 606.488 共0.021兲*
167 606.510 共0.021兲*
168 584.383 共0.012兲*
168 583.814 共0.012兲
168 584.032 共0.012兲
168 585.269 共0.012兲
168 602.044 共0.014兲*
168 946.166 共0.027兲*
168 946.167 共0.027兲*
169 265.226 共0.026兲*
169 342.494 共0.012兲*
169 342.287 共0.012兲
169 342.585 共0.012兲
169 342.614 共0.012兲
169 416.850 共0.103兲*
169 447.484 共0.009兲*
169 446.424 共0.009兲
169 447.148 共0.009兲
169 447.337 共0.009兲
169 447.735 共0.009兲
169 449.147 共0.009兲
169 557.266 共1.144兲*
169 586.021 共0.017兲*
169 801.248 共0.022兲*
169 801.270 共0.022兲*
170 190.943 共0.014兲*
170 230.481 共0.372兲*
170 897.816 共0.018兲*
170 903.491 共0.359兲*
171 035.212 共0.006兲*
91.067
91.068
91.067
91.067
348.381
91.179
91.179
91.179
91.179
91.177
91.177
91.177
91.177
139.948
348.542
77.775
77.775
77.775
77.775
286.208
257.953
1.780
1.780
1.780
1.780
1.779
1.780
407.913
407.913
25.417
25.417
25.417
25.417
139.870
731.265
731.265
134.437
91.250
91.250
91.250
91.250
366.322
1.685
1.685
1.685
1.685
1.685
1.685
696.384
140.077
407.812
407.812
257.886
643.582
268.904
643.613
1.883
1.316
0.433
0.485
0.387
4.797
1.315
0.433
0.484
0.387
1.315
0.433
0.484
0.387
1.267
4.786
2.566
0.765
0.937
0.847
19.958
18.127
0.636
0.053
0.297
0.159
0.071
0.053
3.587
3.587
3.668
1.000
1.411
1.189
2.110
4.991
4.991
0.021
1.314
0.433
0.484
0.386
0.137
2.373
0.593
0.198
0.198
1.108
0.264
0.026
3.365
3.590
3.590
18.419
0.098
2.715
0.113
1.444
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
1
3
3
3
3
3
3
3
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
3
1
1
1
3
1
Ref.
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1197
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
2
2
2
2
2
9
9
9
9
13
8
8
8
8
28
28
28
28
12
13
19
24
24
28
28
28
28
10
10
10
10
2
2
2
2
2
2
19
4
4
4
4
10
10
10
10
30
13
24
17
10
10
10
10
22
18
18
1
1
1
1
1
1
1
1
1
2
4
4
4
4
4
4
4
4
3
2
2
5
5
4
4
4
4
1
1
1
1
1
1
1
1
1
1
7
3
3
3
3
1
1
1
1
2
2
5
2
1
1
1
1
0
1
1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
A1
E1 − 1
B1
B2
B1
A2
A2
A2
A2
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
1
2
3
2
1
1
1
1
1
1
8
8
8
8
12
9
9
9
9
29
29
29
29
13
12
19
23
23
29
29
29
29
9
9
9
9
1
1
1
1
1
1
20
5
5
5
5
9
9
9
9
30
12
23
17
9
9
9
9
21
18
18
0
0
0
0
0
2
2
2
2
3
3
3
3
3
1
1
1
1
0
3
1
6
6
1
1
1
1
2
2
2
2
0
0
0
0
0
0
6
2
2
2
2
2
2
2
2
2
3
6
1
2
2
2
2
3
0
0
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
A2
E1 + 1
B2
B1
B2
A1
A1
A1
A1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 + 1
E2 + 1
1
1
2
2
0
9
10
8
8
9
7
28
29
27
28
29
27
9
11
10
2
1
2
3
1
4
5
3
9
11
10
9
11
10
18
Obs. Freq. 共unc.兲
共MHz兲
8
9
7
9
10
8
29
30
28
29
30
28
8
10
9
173 267.798 共0.100兲
1
1
2
2
0
5
6
4
8
10
9
8
10
9
18
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
171 034.472 共0.006兲
171 034.746 共0.006兲
171 035.294 共0.006兲
171 035.470 共0.006兲
171 036.282 共0.006兲
171 307.117 共0.014兲*
171 306.602 共0.014兲
171 307.334 共0.014兲
171 307.424 共0.014兲
171 457.999 共0.019兲*
171 502.399 共0.013兲*
171 502.191 共0.013兲
171 502.489 共0.013兲
171 502.519 共0.013兲
172 229.136 共0.576兲*
172 227.955 共0.576兲
172 229.698 共0.576兲
172 229.757 共0.576兲
172 300.585 共0.022兲*
172 561.491 共0.012兲*
172 577.937 共0.018兲*
172 712.030 共0.017兲*
172 724.195 共0.017兲*
172 900.101 共0.574兲*
172 898.920 共0.574兲
172 900.663 共0.574兲
172 900.723 共0.574兲
172 989.866 共0.016兲*
172 989.381 共0.016兲
172 989.494 共0.016兲
172 990.712 共0.016兲
173 267.745 共0.006兲*
173 267.091 共0.006兲
173 267.192 共0.006兲
173 267.815 共0.006兲
173 267.880 共0.006兲
173 269.003 共0.006兲
173 282.767 共0.021兲*
173 296.472 共0.012兲*
173 295.917 共0.012兲
173 296.681 共0.012兲
173 296.853 共0.012兲
173 654.079 共0.012兲*
173 653.509 共0.012兲
173 653.646 共0.012兲
173 655.068 共0.012兲
173 779.029 共0.627兲*
173 921.842 共0.014兲*
173 958.770 共0.019兲*
174 041.549 共0.016兲*
174 135.785 共0.011兲*
174 135.236 共0.011兲
174 135.367 共0.011兲
174 136.741 共0.011兲
174 144.057 共0.098兲*
174 198.713 共0.067兲*
174 197.552 共0.067兲
1.883
1.883
1.883
1.883
1.883
64.484
64.484
64.484
64.484
139.978
91.145
91.145
91.145
91.145
637.480
637.480
637.480
637.480
134.237
139.668
286.062
505.265
505.265
637.630
637.630
637.630
637.630
77.738
77.738
77.738
77.738
1.780
1.780
1.780
1.780
1.780
1.779
407.555
33.322
33.322
33.322
33.322
77.627
77.627
77.627
77.627
696.168
140.052
505.199
231.168
77.710
77.710
77.710
77.710
366.255
252.076
252.076
0.120
0.361
0.674
0.120
0.160
2.811
0.925
1.036
0.827
3.373
1.315
0.433
0.484
0.387
0.018
0.006
0.006
0.006
0.019
0.585
19.910
5.678
5.678
0.020
0.007
0.007
0.006
2.563
0.764
0.936
0.846
1.739
0.435
0.145
0.145
0.811
0.193
3.594
0.473
0.151
0.186
0.123
0.487
0.145
0.178
0.161
0.023
0.604
5.677
16.548
0.797
0.238
0.291
0.263
0.182
0.065
0.022
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1198
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
18
18
24
18
9
9
9
9
29
4
4
4
4
4
4
4
4
9
9
9
9
4
4
4
4
24
13
8
8
8
8
29
4
4
4
4
10
10
10
10
6
6
6
6
17
4
4
4
4
4
4
4
4
4
4
4
4
1
1
5
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
2
4
4
4
4
1
1
1
1
1
1
1
1
1
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
E2 + 1
E2 + 1
E2 + 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
19
17
18
18
23
18
8
8
8
8
28
3
3
3
3
3
3
3
3
8
8
8
8
3
3
3
3
23
12
9
9
9
9
28
3
3
3
3
9
9
9
9
5
5
5
5
17
3
3
3
3
3
3
3
3
3
3
3
3
0
0
6
1
2
2
2
2
4
1
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
6
3
3
3
3
3
4
1
1
1
1
2
2
2
2
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
E2 + 1
E2 + 1
E2 + 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
19
17
9
10
8
5
3
4
5
3
4
9
10
8
5
3
4
8
9
7
5
3
4
9
11
10
5
7
6
5
4
3
5
4
3
5
4
3
Obs. Freq. 共unc.兲
共MHz兲
8
9
7
4
2
3
4
2
3
8
9
7
4
2
3
9
10
8
4
2
3
8
10
9
4
6
5
177 271.444 共0.100兲
4
3
2
177 272.161 共0.100兲
4
3
2
177 273.525 共0.100兲
4
3
2
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
174 199.249 共0.067兲
174 199.344 共0.067兲
174 397.654 共0.018兲*
174 438.850 共0.020兲*
174 620.270 共0.009兲*
174 619.707 共0.009兲
174 620.508 共0.009兲
174 620.606 共0.009兲
175 286.105 共0.433兲*
175 568.020 共0.004兲*
175 567.960 共0.004兲
175 568.078 共0.004兲
175 568.084 共0.004兲
175 568.458 共0.004兲*
175 568.398 共0.004兲
175 568.516 共0.004兲
175 568.522 共0.004兲
175 711.047 共0.011兲*
175 710.547 共0.011兲
175 711.258 共0.011兲
175 711.345 共0.011兲
175 909.592 共0.005兲*
175 909.499 共0.005兲
175 909.554 共0.005兲
175 909.766 共0.005兲
176 019.472 共0.019兲*
176 083.975 共0.018兲*
176 363.085 共0.012兲*
176 362.879 共0.012兲
176 363.175 共0.012兲
176 363.204 共0.012兲
176 418.253 共0.642兲*
176 440.205 共0.004兲*
176 440.107 共0.004兲
176 440.122 共0.004兲
176 440.413 共0.004兲
176 597.333 共0.012兲*
176 596.850 共0.012兲
176 596.963 共0.012兲
176 598.174 共0.012兲
176 749.056 共0.007兲*
176 748.517 共0.008兲
176 748.723 共0.008兲
176 749.896 共0.008兲
177 174.771 共0.014兲*
177 271.362 共0.005兲*
177 271.337 共0.005兲
177 271.379 共0.005兲
177 271.404 共0.005兲
177 272.094 共0.005兲*
177 272.069 共0.005兲
177 272.110 共0.005兲
177 272.136 共0.005兲
177 273.459 共0.005兲*
177 273.434 共0.005兲
177 273.475 共0.005兲
177 273.500 共0.005兲
252.076
252.076
505.418
257.947
64.390
64.390
64.390
64.390
643.466
11.642
11.642
11.642
11.642
11.801
11.801
11.801
11.801
64.300
64.300
64.300
64.300
11.780
11.780
11.780
11.780
505.326
139.948
90.864
90.864
90.864
90.864
643.450
11.605
11.605
11.605
11.605
77.529
77.529
77.529
77.529
25.444
25.444
25.444
25.444
231.101
9.277
9.277
9.277
9.277
9.079
9.079
9.079
9.079
9.173
9.173
9.173
9.173
0.023
0.020
5.661
18.422
1.810
0.596
0.667
0.532
0.061
0.353
0.144
0.084
0.110
0.354
0.144
0.084
0.111
2.052
0.675
0.756
0.603
0.349
0.142
0.083
0.109
5.672
2.134
1.316
0.433
0.485
0.387
0.163
0.349
0.142
0.083
0.109
2.088
0.623
0.762
0.689
3.534
0.964
1.359
1.145
16.969
0.378
0.154
0.118
0.090
0.378
0.154
0.118
0.090
0.376
0.153
0.118
0.090
1
1
1
1
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
Ref.
11
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1199
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
0
0
0
0
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
A1
A1
A1
A1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
F⬘
5
4
3
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
J⬙
K⬙a
⌫⬙
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
0
0
0
0
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
A2
A2
A2
A2
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
177 276.280 共0.100兲
4
3
2
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
2
4
3
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
177 276.223 共0.005兲*
177 276.198 共0.005兲
177 276.239 共0.005兲
177 276.265 共0.005兲
177 334.136 共0.004兲*
177 333.962 共0.004兲
177 334.047 共0.004兲
177 334.379 共0.004兲
177 334.631 共0.004兲*
177 334.457 共0.004兲
177 334.542 共0.004兲
177 334.874 共0.004兲
177 344.712 共0.004兲*
177 344.262 共0.004兲
177 344.539 共0.004兲
177 345.251 共0.004兲
177 346.311 共0.004兲*
177 345.861 共0.004兲
177 346.138 共0.004兲
177 346.850 共0.004兲
177 346.527 共0.004兲*
177 346.077 共0.004兲
177 346.354 共0.004兲
177 347.066 共0.004兲
177 346.547 共0.004兲*
177 346.097 共0.004兲
177 346.374 共0.004兲
177 347.086 共0.004兲
177 347.987 共0.004兲*
177 347.537 共0.004兲
177 347.814 共0.004兲
177 348.526 共0.004兲
177 348.086 共0.004兲*
177 347.636 共0.004兲
177 347.913 共0.004兲
177 348.625 共0.004兲
177 348.237 共0.004兲*
177 347.787 共0.004兲
177 348.064 共0.004兲
177 348.777 共0.004兲
177 348.458 共0.004兲*
177 348.008 共0.004兲
177 348.285 共0.004兲
177 348.997 共0.004兲
177 368.216 共0.004兲*
177 368.048 共0.004兲
177 368.131 共0.004兲
177 368.451 共0.004兲
177 369.524 共0.004兲*
177 369.356 共0.004兲
177 369.439 共0.004兲
177 369.758 共0.004兲
177 369.820 共0.004兲*
177 369.651 共0.004兲
177 369.735 共0.004兲
177 370.056 共0.004兲
177 371.151 共0.004兲*
8.873
8.873
8.873
8.873
20.119
20.119
20.119
20.119
20.081
20.081
20.081
20.081
33.391
33.391
33.391
33.391
33.601
33.601
33.601
33.601
33.601
33.601
33.601
33.601
33.573
33.573
33.573
33.573
33.468
33.468
33.468
33.468
33.187
33.187
33.187
33.187
33.501
33.501
33.501
33.501
33.501
33.501
33.501
33.501
20.010
20.010
20.010
20.010
19.911
19.911
19.911
19.911
19.853
19.853
19.853
19.853
19.717
0.376
0.153
0.117
0.089
0.283
0.067
0.115
0.088
0.283
0.067
0.115
0.088
0.165
0.039
0.067
0.052
0.165
0.039
0.067
0.052
0.165
0.039
0.067
0.052
0.165
0.039
0.067
0.052
0.165
0.039
0.067
0.052
0.165
0.039
0.067
0.052
0.165
0.039
0.067
0.052
0.165
0.039
0.067
0.052
0.283
0.067
0.115
0.088
0.283
0.067
0.115
0.088
0.282
0.067
0.115
0.088
0.282
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1200
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
4
4
4
4
4
4
4
4
4
4
4
26
29
9
9
9
9
29
4
4
4
4
13
26
26
13
4
4
4
4
15
4
4
4
4
26
4
4
4
4
6
6
6
6
17
18
26
2
2
2
2
2
2
6
6
6
6
2
2
2
2
2
2
2
2
2
2
2
9
1
1
1
1
1
1
1
1
1
1
2
9
9
2
1
1
1
1
6
1
1
1
1
9
1
1
1
1
0
0
0
0
3
2
9
1
1
1
1
1
1
0
0
0
0
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
B1
B1
B1
B1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
A1
A2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E1 − 1
B1
B1
B1
B1
B1
B1
B1
B1
E1 + 1
B2
E2 + 1
A1
A1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
3
5
4
3
3
3
3
3
3
3
3
3
3
3
27
28
8
8
8
8
28
3
3
3
3
12
27
27
12
3
3
3
3
16
3
3
3
3
27
3
3
3
3
5
5
5
5
16
18
27
1
1
1
1
1
1
5
5
5
5
2
2
2
2
2
2
2
2
2
2
2
8
4
2
2
2
2
4
1
1
1
1
3
8
8
3
1
1
1
1
5
1
1
1
1
8
1
1
1
1
1
1
1
1
4
1
8
0
0
0
0
0
0
1
1
1
1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
B2
B2
B2
B2
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E1 − 1
B2
B2
B2
B2
B2
B2
B2
B2
E1 + 1
B1
E2 + 1
A2
A2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
2
4
3
3
5
4
3
5
4
9
10
8
4
5
3
4
5
3
3
5
4
3
5
4
5
7
6
2
2
1
3
1
5
7
6
2
4
3
2
4
3
8
9
7
3
4
2
3
4
2
2
4
3
2
4
3
4
6
5
1
2
1
2
0
4
6
5
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
177 370.982 共0.004兲
177 371.066 共0.004兲
177 371.386 共0.004兲
177 403.949 共0.004兲*
177 403.785 共0.004兲
177 403.867 共0.004兲
177 404.177 共0.004兲
177 404.330 共0.004兲*
177 404.166 共0.004兲
177 404.248 共0.004兲
177 404.557 共0.004兲
177 698.831 共0.054兲*
177 967.640 共0.454兲*
178 010.946 共0.009兲*
178 010.351 共0.009兲
178 011.198 共0.009兲
178 011.303 共0.009兲
178 199.016 共0.655兲*
178 219.105 共0.005兲*
178 219.026 共0.005兲
178 219.129 共0.005兲
178 219.174 共0.005兲
178 437.114 共0.016兲*
178 439.102 共0.027兲*
178 439.102 共0.027兲*
178 734.682 共0.016兲*
178 747.099 共0.005兲*
178 747.054 共0.005兲
178 747.118 共0.005兲
178 747.123 共0.005兲
179 051.725 共0.019兲*
179 086.829 共0.005兲*
179 086.757 共0.005兲
179 086.814 共0.005兲
179 086.893 共0.005兲
179 091.627 共0.025兲*
179 092.496 共0.005兲*
179 092.424 共0.005兲
179 092.482 共0.005兲
179 092.560 共0.005兲
179 488.052 共0.012兲*
179 487.481 共0.012兲
179 487.700 共0.012兲
179 488.939 共0.012兲
179 865.917 共0.012兲*
179 910.977 共0.019兲*
180 150.874 共0.034兲*
180 390.580 共0.009兲*
180 389.520 共0.009兲
180 390.244 共0.009兲
180 390.433 共0.009兲
180 390.831 共0.009兲
180 392.243 共0.009兲
180 392.476 共0.007兲*
180 392.034 共0.007兲
180 392.198 共0.007兲
180 393.171 共0.007兲
19.717
19.717
19.717
20.082
20.082
20.082
20.082
20.120
20.120
20.120
20.120
731.295
643.324
64.223
64.223
64.223
64.223
643.279
12.039
12.039
12.039
12.039
139.870
731.129
731.129
140.083
12.023
12.023
12.023
12.023
268.953
11.977
11.977
11.977
11.977
731.333
11.818
11.818
11.818
11.818
25.259
25.259
25.259
25.259
244.584
257.799
731.121
1.479
1.479
1.479
1.479
1.479
1.479
25.426
25.426
25.426
25.426
0.067
0.115
0.088
0.283
0.067
0.115
0.088
0.283
0.067
0.115
0.088
4.986
0.070
0.779
0.256
0.287
0.229
0.149
0.349
0.109
0.142
0.083
1.293
4.988
4.988
3.417
0.348
0.109
0.142
0.083
2.712
0.354
0.084
0.144
0.111
4.981
0.353
0.084
0.144
0.110
3.662
0.999
1.409
1.187
4.281
18.382
4.991
2.374
0.594
0.198
0.198
1.108
0.264
3.181
0.868
1.224
1.031
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
3
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1201
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
4
4
4
4
13
16
4
4
4
4
15
15
22
17
28
17
15
15
4
4
4
4
4
4
4
4
10
10
10
10
9
9
9
9
16
24
4
4
4
4
4
4
4
4
17
28
28
13
17
15
19
17
28
28
22
22
22
3
3
3
3
2
2
3
3
3
3
6
6
0
2
6
3
6
6
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
2
5
3
3
3
3
3
3
3
3
3
6
6
2
3
2
1
2
6
6
8
8
8
A1
A1
A1
A1
A2
E1 − 1
A2
A2
A2
A2
E2 + 1
E1 − 1
E1 + 1
A1
E2 − 1
E2 + 1
B2
B1
B1
B1
B1
B1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B1
E1 + 1
E1 − 1
E1 − 1
E2 + 1
B1
A2
A1
A1
A2
E1 + 1
F⬘
4
5
3
4
5
3
4
5
3
4
5
3
9
11
10
9
10
8
4
5
3
4
5
3
J⬙
K⬙a
⌫⬙
5
5
5
5
12
16
5
5
5
5
16
16
21
17
27
16
16
16
5
5
5
5
5
5
5
5
9
9
9
9
8
8
8
8
16
23
5
5
5
5
5
5
5
5
16
27
27
12
16
15
19
17
27
27
23
23
23
2
2
2
2
3
1
2
2
2
2
5
5
3
1
7
4
5
5
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
6
2
2
2
2
2
2
2
2
4
7
7
3
4
1
0
1
7
7
7
7
7
A2
A2
A2
A2
A1
E1 + 1
A1
A1
A1
A1
E2 + 1
E1 − 1
E1 + 1
A2
E2 − 1
E2 − 1
B1
B2
B2
B2
B2
B2
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
E1 + 1
E1 − 1
E1 + 1
E2 + 1
B2
A1
A2
A2
A1
E1 + 1
F⬙
5
6
4
5
6
4
5
6
4
5
6
4
8
10
9
8
9
7
5
6
4
5
6
4
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
180 426.925 共0.011兲*
180 426.396 共0.011兲
180 427.124 共0.011兲
180 427.288 共0.011兲
180 493.669 共0.018兲*
180 589.048 共0.016兲*
180 669.194 共0.011兲*
180 668.609 共0.011兲
180 669.414 共0.011兲
180 669.594 共0.011兲
180 717.651 共0.019兲*
181 218.144 共0.019兲*
181 460.449 共0.118兲*
181 460.553 共0.020兲*
181 521.718 共0.025兲*
182 071.953 共0.017兲*
182 303.671 共0.016兲*
182 303.891 共0.016兲*
182 317.154 共0.010兲*
182 316.625 共0.010兲
182 317.352 共0.010兲
182 317.516 共0.010兲
182 562.487 共0.010兲*
182 561.902 共0.010兲
182 562.707 共0.010兲
182 562.887 共0.010兲
183 148.225 共0.011兲*
183 147.702 共0.011兲
183 147.826 共0.011兲
183 149.136 共0.011兲
183 466.051 共0.010兲*
183 465.466 共0.010兲
183 466.298 共0.010兲
183 466.400 共0.010兲
183 881.486 共0.014兲*
183 978.440 共0.019兲*
184 118.965 共0.012兲*
184 118.405 共0.012兲
184 119.176 共0.012兲
184 119.349 共0.012兲
184 679.146 共0.011兲*
184 678.595 共0.011兲
184 679.353 共0.011兲
184 679.524 共0.011兲
184 788.729 共0.013兲*
184 948.472 共0.024兲*
184 949.697 共0.024兲*
185 425.290 共0.013兲*
186 769.707 共0.014兲*
186 794.123 共0.016兲*
186 981.325 共0.089兲*
186 993.002 共0.020兲*
187 050.047 共0.022兲*
187 051.267 共0.022兲*
187 323.671 共0.035兲*
187 323.672 共0.035兲*
187 339.468 共0.025兲*
33.398
33.398
33.398
33.398
139.984
205.860
33.390
33.390
33.390
33.390
268.991
268.755
365.920
231.160
690.800
244.703
268.780
268.780
33.435
33.435
33.435
33.435
33.427
33.427
33.427
33.427
77.409
77.409
77.409
77.409
64.095
64.095
64.095
64.095
205.793
505.009
33.165
33.165
33.165
33.165
33.224
33.224
33.224
33.224
244.703
690.939
690.939
139.668
244.734
182.031
279.909
231.011
690.966
690.966
540.469
540.469
540.284
0.473
0.151
0.186
0.123
3.428
14.995
0.473
0.151
0.186
0.123
2.710
2.714
0.047
16.976
6.570
0.305
2.714
2.714
0.472
0.151
0.186
0.122
0.472
0.151
0.186
0.122
1.767
0.527
0.645
0.583
1.024
0.337
0.377
0.301
15.600
5.683
0.470
0.150
0.185
0.122
0.470
0.150
0.185
0.122
3.983
6.557
6.557
2.826
4.264
13.442
0.057
16.943
6.547
6.547
4.112
4.112
4.117
1
1
1
1
1
3
1
1
1
1
1
3
3
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
1
3
1
1
1
1
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1202
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
16
26
11
17
11
11
17
15
6
6
6
6
15
15
17
28
28
22
22
14
17
4
4
4
4
16
23
11
15
21
14
23
22
22
29
13
6
6
6
6
27
17
21
21
28
11
18
17
19
20
15
18
20
21
14
11
11
2
9
5
3
5
5
3
2
0
0
0
0
6
6
3
6
6
8
8
2
3
3
3
3
3
2
0
5
2
4
2
0
8
8
10
2
0
0
0
0
4
3
4
4
6
5
7
3
2
2
2
2
1
4
2
5
5
A2
E1 + 1
E1 − 1
A1
A2
A1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
A2
E1 − 1
E1 + 1
B1
B2
E1 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
A2
E2 − 1
A1
E2 + 1
E2 + 1
B2
E2 − 1
E2 + 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
B1
B1
B2
E2 + 1
E1 + 1
E2 + 1
B2
E1 + 1
E1 + 1
B1
E1 + 1
E2 + 1
E1 + 1
A2
B2
B1
F⬘
6
7
5
4
5
3
6
7
5
J⬙
K⬙a
⌫⬙
16
27
12
16
12
12
16
15
5
5
5
5
16
16
16
27
27
23
23
14
16
5
5
5
5
16
22
12
15
20
14
22
23
23
30
13
5
5
5
5
28
16
20
20
27
12
19
16
19
20
15
18
20
20
14
12
12
1
8
4
4
4
4
4
1
1
1
1
1
5
5
4
7
7
7
7
1
4
2
2
2
2
1
3
4
1
5
1
3
7
7
9
1
1
1
1
1
1
4
5
5
7
4
6
4
1
1
1
1
0
5
1
4
4
A1
E1 + 1
E1 − 1
A2
A1
A2
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A2
A1
E1 − 1
E1 + 1
B2
B1
E1 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
A1
E2 − 1
A2
E2 + 1
E2 + 1
B1
E2 − 1
E2 + 1
E1 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
B2
B2
B1
E2 + 1
E1 + 1
E2 + 1
B1
E1 + 1
E1 + 1
B2
E1 + 1
E2 + 1
E1 + 1
A1
B1
B2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
5
6
4
5
6
4
5
6
4
200 294.510 共0.060兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
188 210.220 共0.021兲*
188 256.359 共0.030兲*
188 830.715 共0.016兲*
189 748.896 共0.014兲*
189 797.822 共0.014兲*
189 799.855 共0.014兲*
190 280.580 共0.012兲*
190 283.041 共0.014兲*
190 844.702 共0.007兲*
190 844.126 共0.007兲
190 844.913 共0.007兲
190 845.107 共0.007兲
190 967.278 共0.017兲*
190 967.501 共0.017兲*
191 127.106 共0.015兲*
191 435.414 共0.029兲*
191 442.323 共0.024兲*
192 313.089 共0.023兲*
192 313.091 共0.023兲*
192 622.389 共0.016兲*
192 997.356 共0.012兲*
193 623.457 共0.011兲*
193 622.901 共0.011兲
193 623.666 共0.011兲
193 623.838 共0.011兲
193 795.822 共0.021兲*
194 297.280 共0.121兲*
194 298.321 共0.016兲*
194 662.131 共0.021兲*
195 006.356 共0.015兲*
196 353.593 共0.013兲*
196 956.921 共0.119兲*
197 298.273 共0.028兲*
197 904.739 共0.029兲*
197 950.147 共0.090兲*
198 046.158 共0.016兲*
198 133.557 共0.008兲*
198 133.126 共0.008兲
198 133.712 共0.008兲
198 133.865 共0.008兲
198 161.371 共0.489兲*
198 219.371 共0.017兲*
199 002.524 共0.015兲*
199 172.516 共0.015兲*
199 277.046 共0.031兲*
199 302.686 共0.016兲*
199 450.313 共0.023兲*
199 568.277 共0.016兲*
199 888.126 共0.100兲*
200 130.519 共0.120兲*
200 294.423 共0.021兲*
200 339.917 共0.083兲*
200 640.556 共0.117兲*
200 691.291 共0.017兲*
200 793.602 共0.021兲*
201 077.784 共0.015兲*
201 079.863 共0.015兲*
205.851
730.947
158.996
244.540
158.802
158.802
244.429
181.965
24.974
24.974
24.974
24.974
268.594
268.594
244.540
690.654
690.781
540.441
540.441
159.683
244.429
33.030
33.030
33.030
33.030
205.701
398.871
158.965
182.021
378.322
159.618
398.961
540.301
540.109
905.353
138.818
24.834
24.834
24.834
24.834
595.446
244.354
378.111
378.111
690.609
158.845
378.429
244.355
286.213
315.945
181.870
257.953
309.186
378.284
159.672
158.614
158.614
15.611
4.993
1.841
4.286
1.843
1.843
3.990
14.306
0.119
0.039
0.046
0.033
2.715
2.715
4.290
6.570
6.552
4.107
4.107
11.863
0.307
0.473
0.151
0.186
0.123
15.584
0.176
1.839
14.322
5.178
13.078
0.190
4.112
4.116
5.503
10.247
0.469
0.152
0.181
0.128
0.019
4.294
5.185
5.185
6.562
1.840
3.238
4.299
0.244
0.182
14.300
0.332
0.050
5.170
13.100
1.842
1.842
1
3
3
1
1
1
1
1
3
3
3
3
1
1
1
3
3
3
3
3
1
3
3
3
3
3
1
1
1
1
1
3
1
1
3
3
1
1
1
1
1
3
3
3
1
3
1
3
3
3
3
3
1
3
1
3
3
Ref.
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1203
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
23
21
7
7
7
7
7
7
7
7
20
17
13
20
3
3
3
3
22
22
12
16
14
29
29
11
15
29
23
23
21
11
14
13
18
12
18
11
14
25
25
24
14
7
7
7
7
7
7
7
7
21
7
7
7
7
7
0
2
4
4
4
4
4
4
4
4
4
2
2
4
1
1
1
1
8
2
2
2
2
10
10
5
2
10
0
2
4
1
2
2
7
2
7
2
2
5
5
2
2
0
0
0
0
4
4
4
4
4
4
4
4
4
4
E1 + 1
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
B1
E1 + 1
E2 + 1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E1 − 1
E1 + 1
E1 − 1
A1
A2
E2 + 1
E1 + 1
E2 − 1
E2 + 1
E1 + 1
E2 − 1
B1
B2
A1
E1 − 1
E2 + 1
E1 + 1
E1 − 1
E1 + 1
A1
A2
E1 + 1
E2 + 1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A2
A2
A2
A2
A1
F⬘
7
8
6
7
8
6
4
2
3
6
8
7
7
8
6
7
8
6
J⬙
K⬙a
⌫⬙
22
21
8
8
8
8
8
8
8
8
21
17
13
21
2
2
2
2
23
22
12
16
13
30
30
12
15
30
22
23
20
10
14
13
19
12
19
11
14
24
24
24
13
6
6
6
6
8
8
8
8
20
8
8
8
8
8
3
1
3
3
3
3
3
3
3
3
1
1
1
1
0
0
0
0
7
1
1
1
3
9
9
4
1
9
3
1
5
2
1
1
6
1
6
1
1
6
6
1
3
1
1
1
1
3
3
3
3
5
3
3
3
3
3
E1 − 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
B2
E1 + 1
E2 + 1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
A2
A1
E2 + 1
E1 + 1
E2 − 1
E2 − 1
E1 + 1
E2 − 1
B2
B1
A2
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
E1 + 1
E2 − 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A1
A1
A1
A1
A2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
8
9
7
8
9
7
3
1
2
207 405.161 共0.060兲
5
7
6
8
9
7
8
9
7
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
201 103.974 共0.129兲*
201 120.235 共0.144兲*
201 390.724 共0.013兲*
201 390.445 共0.013兲
201 390.842 共0.013兲
201 390.890 共0.013兲
201 407.296 共0.013兲*
201 407.015 共0.013兲
201 407.415 共0.013兲
201 407.464 共0.013兲
201 427.226 共0.153兲*
201 429.270 共0.068兲*
202 068.859 共0.013兲*
202 662.247 共0.149兲*
202 791.863 共0.009兲*
202 791.784 共0.009兲
202 791.865 共0.009兲
202 792.014 共0.009兲
202 903.649 共0.028兲*
202 906.800 共0.171兲*
203 050.982 共0.016兲*
203 096.324 共0.055兲*
204 807.794 共0.015兲*
205 110.933 共0.071兲*
205 110.933 共0.071兲*
205 147.457 共0.017兲*
205 278.048 共0.044兲*
205 291.212 共0.066兲*
205 426.622 共0.122兲*
205 536.150 共0.203兲*
205 721.725 共0.019兲*
206 399.779 共0.020兲*
206 466.776 共0.020兲*
206 584.764 共0.020兲*
207 317.291 共0.024兲*
207 405.217 共0.012兲*
207 579.603 共0.022兲*
207 641.431 共0.015兲*
207 907.342 共0.035兲*
208 770.585 共0.021兲*
208 789.031 共0.021兲*
209 050.696 共0.241兲*
209 664.168 共0.018兲*
209 942.420 共0.015兲*
209 941.868 共0.015兲
209 942.055 共0.015兲
209 943.309 共0.015兲
209 949.032 共0.013兲*
209 948.754 共0.013兲
209 949.151 共0.013兲
209 949.199 共0.013兲
209 962.331 共0.014兲*
210 061.153 共0.013兲*
210 060.875 共0.013兲
210 061.271 共0.013兲
210 061.319 共0.013兲
210 078.088 共0.013兲*
398.865
347.147
77.968
77.968
77.968
77.968
77.968
77.968
77.968
77.968
347.004
231.168
138.754
347.145
4.841
4.841
4.841
4.841
540.152
379.815
119.437
205.860
159.277
905.127
905.127
158.689
182.031
905.270
398.810
413.948
378.233
92.553
159.519
138.806
378.210
119.374
378.336
101.542
159.683
540.792
540.792
449.542
159.174
34.376
34.376
34.376
34.376
77.758
77.758
77.758
77.758
377.927
77.868
77.868
77.868
77.868
77.868
0.162
0.138
0.986
0.323
0.367
0.285
0.986
0.323
0.367
0.285
0.022
0.459
11.908
0.025
0.938
0.402
0.188
0.278
4.115
0.106
8.625
0.641
2.901
5.510
5.510
1.841
0.899
5.499
0.206
0.083
5.166
2.867
13.083
11.940
3.241
10.785
3.236
7.072
1.253
6.070
6.070
0.066
1.406
4.303
1.214
1.625
1.405
0.986
0.323
0.367
0.285
5.188
0.985
0.323
0.367
0.285
0.985
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
1
1
1
3
1
1
3
1
3
3
1
3
1
3
3
3
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Ref.
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1204
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
7
7
7
21
29
13
21
3
3
3
3
10
10
10
10
18
18
11
12
14
11
13
11
29
11
14
25
25
10
10
10
10
25
23
7
7
7
7
18
18
12
30
29
29
12
14
30
3
3
3
3
21
14
9
9
9
9
4
4
4
4
10
2
4
1
1
1
1
2
2
2
2
7
7
1
2
2
1
2
2
10
1
2
9
9
1
1
1
1
2
0
4
4
4
4
7
7
2
1
10
10
2
2
1
1
1
1
1
1
6
2
2
2
2
A1
A1
A1
A2
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A2
E2 − 1
A2
E2 + 1
A1
B1
E2 + 1
E2 + 1
E1 − 1
B2
B2
B1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B2
E1 + 1
E2 + 1
B1
B2
E2 − 1
A2
E1 + 1
B2
B2
B2
B2
E2 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
7
8
6
8
8
8
20
30
13
20
2
2
2
2
10
10
10
10
19
19
10
12
13
10
13
11
30
10
13
26
26
9
9
9
9
25
22
8
8
8
8
19
19
12
29
30
30
12
13
29
2
2
2
2
21
15
9
9
9
9
3
3
3
5
9
1
5
0
0
0
0
1
1
1
1
6
6
2
1
3
2
1
1
9
2
3
8
8
2
2
2
2
1
3
3
3
3
3
6
6
1
4
9
9
1
3
4
0
0
0
0
0
5
1
1
1
1
A2
A2
A2
A1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
E2 − 1
A1
E2 + 1
A2
B2
E2 + 1
E2 + 1
E1 + 1
B1
B1
B2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B1
E1 + 1
E2 − 1
B2
B1
E2 + 1
A1
E1 − 1
B1
B1
B1
B1
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
8
9
7
2
4
3
9
11
10
10
11
9
7
8
6
3
4
2
8
10
9
Obs. Freq. 共unc.兲
共MHz兲
1
3
2
9
11
10
212 018.341 共0.060兲
9
10
8
8
9
7
2
3
1
8
10
9
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
210 077.807 共0.013兲
210 078.206 共0.013兲
210 078.255 共0.013兲
210 128.643 共0.014兲*
210 298.016 共0.070兲*
210 909.957 共0.027兲*
211 029.308 共0.022兲*
211 129.971 共0.008兲*
211 129.780 共0.008兲
211 129.811 共0.008兲
211 130.363 共0.008兲
211 839.029 共0.014兲*
211 838.675 共0.014兲
211 838.763 共0.014兲
211 839.639 共0.014兲
211 933.711 共0.026兲*
211 933.722 共0.026兲*
211 964.699 共0.013兲*
212 018.335 共0.019兲*
212 028.958 共0.018兲*
212 272.455 共0.020兲*
212 293.620 共0.020兲*
212 338.485 共0.011兲*
212 456.445 共0.111兲*
212 685.476 共0.013兲*
213 053.137 共0.022兲*
213 151.895 共0.036兲*
213 151.895 共0.036兲*
213 184.172 共0.018兲*
213 183.682 共0.018兲
213 184.382 共0.018兲
213 184.459 共0.018兲
213 489.319 共0.284兲*
213 722.198 共0.152兲*
213 729.052 共0.014兲*
213 728.772 共0.014兲
213 729.170 共0.014兲
213 729.218 共0.014兲
214 135.095 共0.027兲*
214 135.107 共0.027兲*
214 198.947 共0.021兲*
214 422.303 共0.423兲*
214 587.691 共0.060兲*
214 587.691 共0.060兲*
214 760.217 共0.026兲*
214 921.289 共0.024兲*
214 990.901 共0.413兲*
215 108.726 共0.009兲*
215 107.812 共0.009兲
215 109.002 共0.009兲
215 109.580 共0.009兲
215 143.053 共0.150兲*
215 240.692 共0.022兲*
215 670.049 共0.012兲*
215 669.694 共0.012兲
215 669.790 共0.012兲
215 670.654 共0.012兲
77.868
77.868
77.868
377.927
905.276
138.818
378.087
4.737
4.737
4.737
4.737
85.135
85.135
85.135
85.135
378.374
378.374
92.442
119.424
159.095
92.516
138.652
101.481
905.181
92.513
159.300
691.446
691.446
77.852
77.852
77.852
77.852
486.594
398.444
77.940
77.940
77.940
77.940
378.273
378.273
119.437
686.402
904.950
904.950
119.374
159.201
686.434
4.643
4.643
4.643
4.643
339.905
245.259
70.215
70.215
70.215
70.215
0.323
0.367
0.285
5.189
5.499
1.704
5.175
0.436
0.087
0.187
0.129
5.677
1.695
2.055
1.858
3.235
3.235
0.324
10.834
2.363
2.863
11.927
9.693
5.504
0.754
3.754
4.635
4.635
3.364
1.110
1.228
1.003
0.054
0.043
0.985
0.323
0.367
0.284
3.237
3.237
2.217
0.123
5.511
5.511
0.025
3.764
0.146
3.156
0.935
1.353
0.631
0.045
2.368
4.494
1.324
1.639
1.465
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
3
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
1
1
3
3
3
3
3
1
1
3
3
3
3
Ref.
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1205
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
3
3
3
3
7
7
7
7
11
14
10
10
10
10
11
25
25
18
11
3
3
3
3
11
12
7
7
7
7
25
3
3
3
3
25
26
10
10
10
10
8
8
8
8
5
5
5
5
5
5
5
5
30
5
5
5
5
1
1
1
1
4
4
4
4
1
2
2
2
2
2
2
5
5
7
2
3
3
3
3
2
2
0
0
0
0
5
1
1
1
1
5
2
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
B1
B2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E1 + 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
A1
A1
A1
A1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
F⬘
3
4
2
7
8
6
9
11
10
3
4
2
6
8
7
3
4
2
10
11
9
7
9
8
6
5
4
6
5
4
6
4
5
J⬙
K⬙a
⌫⬙
2
2
2
2
8
8
8
8
10
13
10
10
10
10
11
24
24
19
11
4
4
4
4
11
12
6
6
6
6
24
2
2
2
2
24
26
9
9
9
9
8
8
8
8
4
4
4
4
4
4
4
4
29
4
4
4
4
0
0
0
0
3
3
3
3
2
3
1
1
1
1
1
6
6
6
1
2
2
2
2
1
1
1
1
1
1
6
0
0
0
0
6
1
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
4
1
1
1
1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
B2
B1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E1 + 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
2
3
1
8
9
7
216 842.416 共0.060兲
9
11
10
217 079.400 共0.060兲
4
5
3
5
7
6
218 408.868 共0.100兲
2
3
1
9
10
8
7
9
8
5
4
3
5
4
3
5
3
4
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
215 787.595 共0.007兲*
215 787.131 共0.007兲
215 787.721 共0.007兲
215 788.089 共0.007兲
215 890.887 共0.014兲*
215 890.607 共0.014兲
215 891.005 共0.014兲
215 891.053 共0.014兲
215 927.863 共0.015兲*
216 290.465 共0.015兲*
216 842.498 共0.011兲*
216 842.121 共0.011兲
216 842.215 共0.011兲
216 843.150 共0.011兲
217 079.373 共0.017兲*
217 134.164 共0.022兲*
217 152.337 共0.023兲*
217 625.145 共0.027兲*
217 669.997 共0.016兲*
217 670.157 共0.013兲*
217 669.176 共0.013兲
217 670.491 共0.013兲
217 670.923 共0.013兲
217 754.777 共0.021兲*
217 758.226 共0.019兲*
218 220.928 共0.009兲*
218 220.391 共0.009兲
218 220.573 共0.009兲
218 221.796 共0.009兲
218 399.312 共0.025兲*
218 408.878 共0.007兲*
218 408.172 共0.007兲
218 409.084 共0.007兲
218 409.564 共0.007兲
218 832.943 共0.022兲*
218 887.180 共0.335兲*
219 005.088 共0.017兲*
219 004.596 共0.017兲
219 005.299 共0.017兲
219 005.376 共0.017兲
219 151.222 共0.011兲*
219 150.864 共0.011兲
219 150.970 共0.011兲
219 151.818 共0.011兲
219 440.096 共0.005兲*
219 440.056 共0.005兲
219 440.131 共0.005兲
219 440.133 共0.005兲
219 440.497 共0.005兲*
219 440.457 共0.005兲
219 440.532 共0.005兲
219 440.534 共0.005兲
219 502.447 共0.510兲*
219 650.030 共0.005兲*
219 649.973 共0.005兲
219 650.030 共0.005兲
219 650.116 共0.005兲
4.841
4.841
4.841
4.841
77.835
77.835
77.835
77.835
92.309
158.894
85.076
85.076
85.076
85.076
101.528
540.693
540.693
378.016
101.542
25.926
25.926
25.926
25.926
101.481
119.270
34.399
34.399
34.399
34.399
540.627
4.737
4.737
4.737
4.737
540.845
525.100
77.814
77.814
77.814
77.814
56.785
56.785
56.785
56.785
17.498
17.498
17.498
17.498
17.657
17.657
17.657
17.657
686.283
17.647
17.647
17.647
17.648
2.218
0.657
0.951
0.444
0.985
0.323
0.367
0.285
2.550
0.876
8.607
2.570
3.116
2.817
9.778
6.066
6.066
3.241
2.711
0.197
0.062
0.080
0.047
0.057
10.825
4.206
1.186
1.589
1.374
6.065
2.721
0.806
1.166
0.544
6.047
0.044
3.348
1.105
1.222
0.999
3.519
1.019
1.295
1.141
0.452
0.178
0.145
0.117
0.453
0.178
0.145
0.117
0.062
0.450
0.177
0.117
0.144
1
1
1
1
1
1
1
1
1
3
1
1
1
1
1
3
3
1
3
3
3
3
3
1
3
3
3
3
3
3
3
3
3
3
1
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
Ref.
1
1
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1206
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
18
14
5
5
5
5
30
25
7
7
7
7
10
10
10
10
7
7
7
7
9
9
9
9
10
10
10
10
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
3
2
1
1
1
1
1
5
4
4
4
4
2
2
2
2
0
0
0
0
2
2
2
2
2
2
2
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
2
2
2
2
2
4
4
4
4
4
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
B1
B1
B1
B1
A1
A1
A1
A1
A1
A1
A1
A1
A2
F⬘
6
4
5
7
8
6
9
11
10
6
8
7
8
10
9
9
11
10
6
4
5
6
4
5
6
4
5
6
4
5
4
6
5
4
6
5
4
6
5
J⬙
K⬙a
⌫⬙
17
13
4
4
4
4
29
24
8
8
8
8
10
10
10
10
6
6
6
6
9
9
9
9
10
10
10
10
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
1
1
1
1
4
6
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
2
2
2
2
2
4
4
4
4
4
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
B2
B2
B2
B2
A2
A2
A2
A2
A2
A2
A2
A2
A1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
5
3
4
8
9
7
9
11
10
220 826.728 共0.060兲
5
7
6
220 888.349 共0.060兲
8
10
9
221 204.485 共0.060兲
9
11
10
221 527.452 共0.060兲
5
3
4
221 530.466 共0.060兲
5
3
4
5
3
4
221 536.290 共0.060兲
5
3
4
3
5
4
3
5
4
3
5
4
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
220 082.856 共0.021兲*
220 092.746 共0.018兲*
220 158.136 共0.005兲*
220 158.059 共0.005兲
220 158.084 共0.005兲
220 158.283 共0.005兲
220 419.557 共0.755兲*
220 449.395 共0.024兲*
220 760.509 共0.013兲*
220 760.230 共0.013兲
220 760.627 共0.013兲
220 760.675 共0.013兲
220 805.663 共0.017兲*
220 805.401 共0.017兲
220 805.466 共0.017兲
220 806.115 共0.017兲
220 826.704 共0.015兲*
220 826.152 共0.015兲
220 826.339 共0.015兲
220 827.596 共0.015兲
220 888.443 共0.010兲*
220 888.072 共0.010兲
220 888.173 共0.010兲
220 889.072 共0.010兲
221 204.501 共0.013兲*
221 204.194 共0.013兲
221 204.271 共0.013兲
221 205.032 共0.013兲
221 527.438 共0.005兲*
221 527.416 共0.005兲
221 527.454 共0.005兲
221 527.458 共0.005兲
221 530.404 共0.005兲*
221 530.383 共0.005兲
221 530.421 共0.005兲
221 530.425 共0.005兲
221 530.481 共0.006兲*
221 530.460 共0.006兲
221 530.498 共0.006兲
221 530.501 共0.006兲
221 536.285 共0.006兲*
221 536.264 共0.006兲
221 536.302 共0.006兲
221 536.305 共0.006兲
221 651.281 共0.005兲*
221 651.210 共0.005兲
221 651.229 共0.005兲
221 651.405 共0.005兲
221 651.982 共0.005兲*
221 651.911 共0.005兲
221 651.929 共0.005兲
221 652.106 共0.005兲
221 660.320 共0.007兲*
221 659.960 共0.007兲
221 660.153 共0.007兲
221 660.799 共0.007兲
221 660.321 共0.007兲*
269.861
159.277
17.491
17.491
17.491
17.491
686.278
540.754
77.554
77.554
77.554
77.554
85.076
85.076
85.076
85.076
34.218
34.218
34.218
34.218
70.161
70.161
70.161
70.161
85.135
85.135
85.135
85.135
15.190
15.190
15.190
15.190
15.086
15.086
15.086
15.086
14.992
14.992
14.992
14.992
14.786
14.786
14.786
14.786
26.034
26.034
26.034
26.034
25.996
25.996
25.996
25.996
58.258
58.258
58.258
58.258
58.258
0.032
0.907
0.448
0.176
0.116
0.143
0.195
6.059
0.986
0.323
0.367
0.285
0.125
0.037
0.045
0.041
4.295
1.211
1.623
1.403
7.496
2.208
2.734
2.444
3.089
0.922
1.118
1.011
0.472
0.186
0.122
0.151
0.470
0.185
0.122
0.150
0.473
0.186
0.123
0.151
0.470
0.185
0.122
0.150
0.396
0.103
0.156
0.127
0.396
0.103
0.156
0.127
0.170
0.044
0.067
0.054
0.170
3
3
1
1
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
Ref.
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1207
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
4
6
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
3
5
4
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
5
4
3
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
221 659.961 共0.007兲
221 660.154 共0.007兲
221 660.801 共0.007兲
221 661.202 共0.007兲*
221 660.842 共0.007兲
221 661.036 共0.007兲
221 661.682 共0.007兲
221 663.274 共0.006兲*
221 662.914 共0.006兲
221 663.108 共0.006兲
221 663.754 共0.006兲
221 664.120 共0.006兲*
221 663.760 共0.006兲
221 663.953 共0.006兲
221 664.600 共0.007兲
221 664.314 共0.007兲*
221 663.954 共0.007兲
221 664.147 共0.007兲
221 664.794 共0.007兲
221 664.315 共0.007兲*
221 663.955 共0.007兲
221 664.149 共0.007兲
221 664.795 共0.007兲
221 664.347 共0.006兲*
221 663.987 共0.006兲
221 664.180 共0.006兲
221 664.827 共0.006兲
221 680.497 共0.006兲*
221 680.308 共0.006兲
221 680.398 共0.006兲
221 680.765 共0.006兲
221 681.852 共0.005兲*
221 681.663 共0.005兲
221 681.753 共0.005兲
221 682.120 共0.005兲
221 682.530 共0.005兲*
221 682.341 共0.005兲
221 682.432 共0.005兲
221 682.798 共0.005兲
221 682.607 共0.005兲*
221 682.418 共0.005兲
221 682.509 共0.005兲
221 682.875 共0.005兲
221 684.363 共0.005兲*
221 684.174 共0.005兲
221 684.264 共0.005兲
221 684.631 共0.005兲
221 684.367 共0.006兲*
221 684.178 共0.006兲
221 684.269 共0.006兲
221 684.635 共0.006兲
221 684.864 共0.006兲*
221 684.675 共0.006兲
221 684.766 共0.006兲
221 685.132 共0.006兲
221 685.139 共0.006兲*
221 684.950 共0.006兲
58.258
58.258
58.258
58.301
58.301
58.301
58.301
58.452
58.452
58.452
58.452
58.143
58.143
58.143
58.143
58.069
58.069
58.069
58.069
58.069
58.069
58.069
58.069
58.419
58.419
58.419
58.419
39.307
39.307
39.307
39.307
39.517
39.517
39.517
39.517
39.488
39.488
39.488
39.488
39.517
39.517
39.517
39.517
39.384
39.384
39.384
39.384
39.416
39.416
39.416
39.416
39.102
39.102
39.102
39.102
39.416
39.416
0.044
0.067
0.054
0.170
0.044
0.067
0.054
0.170
0.044
0.067
0.054
0.170
0.044
0.067
0.054
0.170
0.044
0.067
0.054
0.170
0.044
0.067
0.054
0.170
0.044
0.067
0.054
0.302
0.078
0.119
0.097
0.302
0.078
0.119
0.097
0.302
0.078
0.119
0.097
0.302
0.078
0.119
0.097
0.301
0.078
0.119
0.096
0.302
0.078
0.119
0.096
0.301
0.078
0.119
0.096
0.302
0.078
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1208
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
10
10
10
10
5
5
5
5
5
5
5
5
25
11
30
7
7
7
7
7
7
7
7
30
14
10
10
10
10
25
25
11
5
5
5
5
10
10
10
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
9
1
1
0
0
0
0
2
2
2
2
1
2
1
1
1
1
9
9
2
1
1
1
1
1
1
1
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
A2
A2
A2
A2
B2
B2
B2
B2
E2 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
6
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
10
10
10
10
4
4
4
4
4
4
4
4
26
10
29
6
6
6
6
7
7
7
7
29
13
9
9
9
9
26
26
11
4
4
4
4
9
9
9
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
2
2
2
2
2
2
2
2
8
2
4
1
1
1
1
1
1
1
1
4
3
2
2
2
2
8
8
1
1
1
1
1
2
2
2
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A1
A1
A1
A1
B1
B1
B1
B1
E2 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
5
4
4
6
5
4
6
5
4
6
5
4
6
5
9
11
10
4
6
5
4
6
5
6
8
7
6
8
7
10
11
9
5
6
4
10
11
Obs. Freq. 共unc.兲
共MHz兲
221 717.585 共0.060兲
3
5
4
221 721.773 共0.060兲
3
5
4
221 724.239 共0.060兲
3
5
4
221 728.698 共0.060兲
3
5
4
221 755.055 共0.060兲
9
11
10
221 790.469 共0.060兲
3
5
4
221 791.536 共0.060兲
3
5
4
5
7
6
6
8
7
9
10
8
222 846.216 共0.060兲
223 124.584 共0.060兲
4
5
3
9
10
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
221 685.041 共0.006兲
221 685.407 共0.006兲
221 717.567 共0.005兲*
221 717.500 共0.005兲
221 717.518 共0.005兲
221 717.684 共0.005兲
221 721.771 共0.005兲*
221 721.706 共0.005兲
221 721.723 共0.005兲
221 721.884 共0.005兲
221 724.256 共0.005兲*
221 724.191 共0.005兲
221 724.207 共0.005兲
221 724.370 共0.005兲
221 728.700 共0.005兲*
221 728.637 共0.005兲
221 728.653 共0.005兲
221 728.810 共0.005兲
221 755.043 共0.016兲*
221 754.646 共0.016兲
221 754.745 共0.016兲
221 755.728 共0.016兲
221 790.514 共0.005兲*
221 790.455 共0.005兲
221 790.470 共0.005兲
221 790.618 共0.005兲
221 791.559 共0.005兲*
221 791.499 共0.005兲
221 791.514 共0.005兲
221 791.662 共0.005兲
221 938.460 共0.058兲*
222 050.948 共0.013兲*
222 172.247 共0.534兲*
222 263.031 共0.008兲*
222 262.553 共0.008兲
222 262.713 共0.008兲
222 263.806 共0.008兲
222 282.224 共0.010兲*
222 281.866 共0.010兲
222 281.984 共0.010兲
222 282.807 共0.010兲
222 294.068 共0.771兲*
222 579.512 共0.022兲*
222 590.740 共0.009兲*
222 590.193 共0.009兲
222 590.975 共0.009兲
222 591.060 共0.009兲
222 685.715 共0.036兲*
222 685.715 共0.036兲*
222 846.153 共0.018兲*
223 124.585 共0.005兲*
223 124.508 共0.005兲
223 124.613 共0.005兲
223 124.640 共0.005兲
223 325.310 共0.011兲*
223 324.833 共0.011兲
223 325.515 共0.011兲
39.416
39.416
25.769
25.769
25.769
25.769
25.926
25.926
25.926
25.926
25.634
25.634
25.634
25.634
25.827
25.827
25.827
25.827
85.119
85.119
85.119
85.119
26.000
26.000
26.000
26.000
26.037
26.037
26.037
26.037
691.474
92.201
686.144
34.367
34.367
34.367
34.367
44.846
44.846
44.846
44.846
686.109
159.174
77.710
77.710
77.710
77.710
691.309
691.309
101.373
17.984
17.984
17.984
17.984
77.627
77.627
77.627
0.119
0.096
0.395
0.102
0.156
0.126
0.396
0.103
0.156
0.127
0.395
0.102
0.156
0.127
0.396
0.103
0.156
0.127
8.764
2.617
3.173
2.868
0.396
0.103
0.156
0.127
0.396
0.103
0.156
0.127
4.631
2.109
0.077
3.937
1.110
1.487
1.285
2.713
0.768
1.009
0.872
0.179
2.402
2.274
0.750
0.830
0.678
4.633
4.633
9.771
0.448
0.143
0.177
0.116
2.831
0.934
1.033
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
3
1
1
1
1
1
3
3
3
3
3
1
3
3
3
3
1
1
3
1
1
1
1
1
1
1
Ref.
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1209
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
25
14
5
5
5
5
9
9
9
9
5
5
5
5
5
5
5
5
26
25
8
8
8
8
24
18
9
9
9
9
3
3
3
3
14
3
3
3
3
6
6
6
6
14
14
27
14
29
9
9
9
9
3
3
3
3
1
9
6
1
1
1
1
2
2
2
2
1
1
1
1
1
1
1
1
4
9
2
2
2
2
0
3
2
2
2
2
3
3
3
3
2
3
3
3
3
2
2
2
2
6
2
2
6
6
2
2
2
2
1
1
1
1
E2 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E2 − 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
B1
E1 + 1
E1 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
9
9
26
15
4
4
4
4
9
9
9
9
4
4
4
4
4
4
4
4
27
26
8
8
8
8
23
17
9
9
9
9
4
4
4
4
13
4
4
4
4
6
6
6
6
15
13
27
15
28
9
9
9
9
2
2
2
2
2
8
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
8
1
1
1
1
3
4
1
1
1
1
2
2
2
2
3
2
2
2
2
1
1
1
1
5
3
1
5
7
1
1
1
1
0
0
0
0
E2 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
B1
B1
B1
B1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E2 + 1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B2
E1 + 1
E1 − 1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
8
5
4
6
8
10
9
4
6
5
4
6
5
7
9
8
8
10
9
3
4
2
3
4
2
5
7
6
8
10
9
3
4
2
Obs. Freq. 共unc.兲
共MHz兲
223 629.272 共0.060兲
4
3
5
8
10
9
3
5
4
3
5
4
7
9
8
8
10
9
4
5
3
4
5
3
5
7
6
226 034.398 共0.060兲
8
10
9
2
3
1
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
223 325.590 共0.011兲
223 335.793 共0.033兲*
223 407.315 共0.024兲*
223 629.263 共0.005兲*
223 629.248 共0.005兲
223 629.267 共0.005兲
223 629.272 共0.005兲
223 831.697 共0.014兲*
223 831.413 共0.014兲
223 831.490 共0.014兲
223 832.179 共0.014兲
223 837.331 共0.006兲*
223 837.297 共0.006兲
223 837.323 共0.006兲
223 837.367 共0.006兲
223 844.565 共0.006兲*
223 844.530 共0.006兲
223 844.557 共0.006兲
223 844.600 共0.006兲
224 358.140 共0.414兲*
224 366.260 共0.043兲*
224 447.558 共0.010兲*
224 447.201 共0.010兲
224 447.308 共0.010兲
224 448.152 共0.010兲
224 472.366 共0.150兲*
224 583.841 共0.014兲*
224 682.489 共0.011兲*
224 682.160 共0.011兲
224 682.249 共0.011兲
224 683.049 共0.011兲
224 868.981 共0.012兲*
224 868.017 共0.012兲
224 869.309 共0.012兲
224 869.735 共0.012兲
224 944.302 共0.020兲*
224 972.938 共0.012兲*
224 971.938 共0.012兲
224 973.279 共0.012兲
224 973.717 共0.012兲
225 045.153 共0.010兲*
225 044.801 共0.010兲
225 044.932 共0.010兲
225 045.706 共0.010兲
225 078.337 共0.023兲*
225 101.833 共0.021兲*
225 275.303 共0.394兲*
225 587.224 共0.023兲*
225 889.259 共0.037兲*
226 034.388 共0.014兲*
226 033.989 共0.014兲
226 034.097 共0.014兲
226 035.067 共0.014兲
226 045.921 共0.010兲*
226 045.007 共0.010兲
226 046.197 共0.010兲
226 046.775 共0.010兲
77.627
691.512
245.308
17.985
17.985
17.985
17.985
70.161
70.161
70.161
70.161
17.950
17.950
17.950
17.950
17.792
17.792
17.792
17.792
554.703
691.301
56.736
56.736
56.736
56.736
432.911
269.711
70.215
70.215
70.215
70.215
26.000
26.000
26.000
26.000
159.095
25.996
25.996
25.996
25.996
34.399
34.399
34.399
34.399
245.347
159.309
565.058
245.110
732.096
70.199
70.199
70.199
70.199
4.437
4.437
4.437
4.437
0.844
4.626
2.365
0.450
0.144
0.117
0.177
0.255
0.075
0.093
0.083
0.453
0.117
0.178
0.145
0.452
0.117
0.178
0.145
0.017
4.635
6.352
1.839
2.337
2.059
0.193
4.664
3.293
0.970
1.201
1.073
0.197
0.061
0.080
0.047
1.442
0.197
0.061
0.080
0.047
2.024
0.555
0.763
0.643
2.363
3.832
0.037
2.366
6.956
7.787
2.294
2.840
2.538
3.157
0.936
1.353
0.631
1
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
3
3
3
3
1
3
3
3
1
1
1
1
1
1
1
1
1
Ref.
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1210
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
10
10
10
10
18
14
14
8
8
8
8
3
3
3
3
14
3
3
3
3
24
5
5
5
5
7
7
7
7
10
10
10
10
8
8
8
8
25
3
3
3
3
3
3
3
3
4
4
4
4
29
29
7
7
7
7
18
1
1
1
1
3
6
6
2
2
2
2
3
3
3
3
2
3
3
3
3
0
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
5
3
3
3
3
3
3
3
3
2
2
2
2
6
6
2
2
2
2
3
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
A1
B1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
F⬘
10
11
9
7
9
8
3
4
2
3
4
2
4
6
5
6
8
7
9
11
10
7
9
8
3
4
2
3
4
2
3
5
4
6
8
7
J⬙
K⬙a
⌫⬙
9
9
9
9
17
15
15
8
8
8
8
4
4
4
4
13
4
4
4
4
23
5
5
5
5
7
7
7
7
10
10
10
10
8
8
8
8
24
4
4
4
4
4
4
4
4
4
4
4
4
28
28
7
7
7
7
17
2
2
2
2
4
5
5
1
1
1
1
2
2
2
2
3
2
2
2
2
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
2
2
2
2
2
2
2
2
1
1
1
1
7
7
1
1
1
1
4
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
B2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
A2
B2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
9
10
8
7
9
8
4
5
3
4
5
3
4
6
5
227 497.882 共0.060兲
6
8
7
227 545.040 共0.100兲
9
11
10
227 997.008 共0.060兲
7
9
8
4
5
3
4
5
3
3
5
4
6
8
7
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
226 268.564 共0.010兲*
226 267.939 共0.010兲
226 268.832 共0.010兲
226 268.930 共0.010兲
226 640.429 共0.019兲*
226 652.785 共0.020兲*
226 652.900 共0.020兲*
226 747.458 共0.012兲*
226 747.159 共0.012兲
226 747.248 共0.012兲
226 747.956 共0.012兲
226 762.186 共0.011兲*
226 761.222 共0.011兲
226 762.513 共0.011兲
226 762.939 共0.011兲
226 822.170 共0.023兲*
226 867.457 共0.011兲*
226 866.457 共0.011兲
226 867.798 共0.011兲
226 868.236 共0.011兲
227 108.765 共0.147兲*
227 405.596 共0.010兲*
227 405.269 共0.010兲
227 405.407 共0.010兲
227 406.088 共0.010兲
227 497.908 共0.010兲*
227 497.574 共0.010兲
227 497.684 共0.010兲
227 498.452 共0.010兲
227 545.018 共0.016兲*
227 544.620 共0.016兲
227 544.719 共0.016兲
227 545.704 共0.016兲
227 997.003 共0.010兲*
227 996.658 共0.010兲
227 996.761 共0.010兲
227 997.577 共0.010兲
228 368.290 共0.026兲*
228 491.820 共0.013兲*
228 490.838 共0.013兲
228 492.155 共0.013兲
228 492.587 共0.013兲
229 059.859 共0.012兲*
229 058.879 共0.013兲
229 060.193 共0.012兲
229 060.624 共0.012兲
229 310.604 共0.011兲*
229 310.345 共0.011兲
229 310.472 共0.011兲
229 310.967 共0.011兲
229 312.378 共0.038兲*
229 314.235 共0.038兲*
229 452.729 共0.011兲*
229 452.427 共0.011兲
229 452.527 共0.011兲
229 453.220 共0.011兲
229 670.312 共0.017兲*
77.529
77.529
77.529
77.529
269.830
245.136
245.136
56.736
56.736
56.736
56.736
26.037
26.037
26.037
26.037
159.211
26.034
26.034
26.034
26.034
432.999
25.444
25.444
25.444
25.444
44.804
44.804
44.804
44.804
84.963
84.963
84.963
84.963
56.785
56.785
56.785
56.785
540.437
25.769
25.769
25.769
25.769
25.827
25.827
25.827
25.827
17.985
17.985
17.985
17.985
732.236
732.236
44.804
44.804
44.804
44.804
269.830
0.550
0.182
0.201
0.164
0.548
2.367
2.367
0.450
0.130
0.166
0.146
0.197
0.061
0.0803
0.047
3.847
0.197
0.061
0.080
0.047
0.208
1.410
0.369
0.540
0.439
5.251
1.486
1.953
1.689
8.759
2.615
3.171
2.867
3.320
0.961
1.222
1.076
6.072
0.197
0.061
0.080
0.047
0.197
0.061
0.080
0.047
0.848
0.206
0.332
0.255
6.942
6.942
0.628
0.178
0.234
0.202
4.138
1
1
1
1
1
3
3
1
1
1
1
3
3
3
3
1
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
Ref.
1
11
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1211
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
8
8
8
8
6
6
6
6
22
3
3
3
3
7
7
7
7
29
29
24
2
2
2
2
2
2
2
2
18
14
21
21
21
10
10
10
10
6
6
6
6
9
9
9
9
5
5
5
5
25
28
10
7
7
7
7
4
2
2
2
2
2
2
2
2
1
2
2
2
2
2
2
2
2
6
6
0
2
2
2
2
2
2
2
2
3
2
8
8
8
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
9
2
5
2
2
2
2
2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
A2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 − 1
A1
A1
A1
A1
E2 + 1
F⬘
7
9
8
5
7
6
2
4
3
6
8
7
2
2
2
3
3
1
1
10
11
9
5
7
6
8
10
9
4
6
5
6
8
7
J⬙
K⬙a
⌫⬙
8
8
8
8
6
6
6
6
22
3
3
3
3
7
7
7
7
28
28
23
2
2
2
2
2
2
2
2
17
13
22
22
22
9
9
9
9
6
6
6
6
9
9
9
9
5
5
5
5
26
28
11
7
7
7
7
4
1
1
1
1
1
1
1
1
0
1
1
1
1
1
1
1
1
7
7
3
1
1
1
1
1
1
1
1
4
3
7
7
7
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
8
1
4
1
1
1
1
1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
E1 + 1
A1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 − 1
A2
A2
A2
A2
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
229 908.118 共0.060兲
7
9
8
230 024.073 共0.060兲
5
7
6
2
4
3
231 060.560 共0.060兲
6
8
7
1
3
2
3
2
1
2
9
10
8
5
7
6
231 844.292 共0.100兲
8
10
9
232 003.712 共0.060兲
4
6
5
233 368.424 共0.060兲
6
8
7
233 410.781 共0.100兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
229 908.120 共0.013兲*
229 907.720 共0.013兲
229 907.839 共0.013兲
229 908.788 共0.013兲
230 024.095 共0.010兲*
230 023.797 共0.010兲
230 023.908 共0.010兲
230 024.564 共0.010兲
230 444.387 共0.191兲*
230 686.552 共0.011兲*
230 686.485 共0.011兲
230 686.524 共0.011兲
230 686.635 共0.011兲
231 060.535 共0.009兲*
231 060.182 共0.009兲
231 060.299 共0.009兲
231 061.107 共0.009兲
231 395.924 共0.034兲*
231 397.773 共0.034兲*
231 423.151 共0.158兲*
231 474.035 共0.012兲*
231 473.377 共0.012兲
231 473.413 共0.012兲
231 473.478 共0.012兲
231 474.195 共0.012兲
231 474.260 共0.012兲
231 474.592 共0.012兲
231 474.694 共0.012兲
231 524.229 共0.017兲*
231 575.418 共0.017兲*
231 602.063 共0.032兲*
231 603.100 共0.040兲*
231 603.101 共0.040兲*
231 603.180 共0.011兲*
231 602.588 共0.011兲
231 603.434 共0.011兲
231 603.526 共0.011兲
231 829.203 共0.011兲*
231 828.920 共0.011兲
231 829.025 共0.011兲
231 829.649 共0.011兲
231 844.267 共0.015兲*
231 843.867 共0.015兲
231 843.976 共0.015兲
231 844.946 共0.015兲
232 003.755 共0.010兲*
232 003.522 共0.010兲
232 003.621 共0.010兲
232 004.106 共0.010兲
232 507.967 共0.041兲*
232 679.885 共0.462兲*
233 198.502 共0.019兲*
233 368.423 共0.012兲*
233 368.024 共0.012兲
233 368.156 共0.012兲
233 369.072 共0.012兲
233 410.773 共0.011兲*
56.767
56.767
56.767
56.767
34.367
34.367
34.367
34.367
372.064
12.023
12.023
12.023
12.023
44.846
44.846
44.846
44.846
732.263
732.263
432.892
7.559
7.559
7.559
7.559
7.559
7.559
7.559
7.559
269.861
158.894
506.335
506.519
506.519
77.409
77.409
77.409
77.409
34.367
34.367
34.367
34.367
70.042
70.042
70.042
70.042
25.426
25.426
25.426
25.426
691.126
606.463
141.255
44.826
44.826
44.826
44.826
17.984
6.842
1.981
2.518
2.218
4.319
1.184
1.627
1.372
0.040
0.371
0.078
0.149
0.104
3.204
0.907
1.191
1.030
6.931
6.931
0.188
0.078
0.004
0.004
0.018
0.032
0.004
0.012
0.004
4.643
2.942
3.764
3.759
3.759
1.107
0.365
0.404
0.330
0.657
0.180
0.247
0.209
7.784
2.293
2.839
2.537
3.580
0.937
1.371
1.115
4.637
0.031
1.505
5.922
1.676
2.202
1.904
2.923
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
1
1
1
1
1
1
1
1
11
1
1
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1212
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
4
4
4
5
5
5
5
6
6
6
6
10
10
18
3
3
3
3
2
2
2
2
2
2
2
2
18
4
4
4
4
24
14
14
8
8
8
8
29
29
3
3
3
3
18
18
5
5
5
5
6
6
6
6
21
21
2
2
2
2
2
2
2
2
2
2
2
2
5
5
3
2
2
2
2
2
2
2
2
2
2
2
2
3
2
2
2
2
0
6
6
2
2
2
2
6
6
2
2
2
2
3
3
2
2
2
2
2
2
2
2
8
8
2
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
A1
A2
B2
B2
B2
B2
E1 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B1
E1 − 1
3
5
4
4
4
4
5
5
5
5
6
6
6
6
11
11
17
3
3
3
3
2
2
2
2
2
2
2
2
17
4
4
4
4
23
15
15
8
8
8
8
28
28
3
3
3
3
17
17
5
5
5
5
6
6
6
6
22
22
2
1
1
1
1
1
1
1
1
1
1
1
4
4
4
1
1
1
1
1
1
1
1
1
1
1
1
4
1
1
1
1
3
5
5
1
1
1
1
7
7
1
1
1
1
4
4
1
1
1
1
1
1
1
1
7
7
1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
A2
A1
B1
B1
B1
B1
E1 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B2
E1 − 1
3
5
4
4
6
5
5
7
6
3
4
2
2
2
2
3
3
1
1
3
5
4
7
9
8
3
4
2
4
6
5
5
7
6
Obs. Freq. 共unc.兲
共MHz兲
4
6
5
233 802.311 共0.060兲
5
7
6
234 260.005 共0.100兲
3
4
2
234 657.910 共0.060兲
2
3
1
2
3
2
1
3
5
4
235 735.037 共0.100兲
7
9
8
3
4
2
236 159.846 共0.100兲
4
6
5
236 408.788 共0.060兲
5
7
6
237 143.530 共0.100兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
233 410.661 共0.011兲
233 410.716 共0.011兲
233 410.930 共0.011兲
233 758.673 共0.011兲*
233 758.445 共0.011兲
233 758.542 共0.011兲
233 759.015 共0.011兲
233 802.315 共0.009兲*
233 801.965 共0.009兲
233 802.095 共0.009兲
233 802.864 共0.009兲
234 162.840 共0.016兲*
234 163.857 共0.016兲*
234 191.682 共0.017兲*
234 260.058 共0.012兲*
234 259.900 共0.012兲
234 260.111 共0.012兲
234 260.184 共0.012兲
234 657.948 共0.012兲*
234 657.203 共0.012兲
234 657.380 共0.012兲
234 657.478 共0.012兲
234 657.985 共0.012兲
234 658.161 共0.012兲
234 658.419 共0.012兲
234 658.693 共0.012兲
234 828.775 共0.014兲*
235 154.558 共0.011兲*
235 154.448 共0.011兲
235 154.502 共0.011兲
235 154.713 共0.011兲
235 324.765 共0.151兲*
235 337.423 共0.021兲*
235 337.540 共0.021兲*
235 734.966 共0.014兲*
235 734.566 共0.014兲
235 734.685 共0.014兲
235 735.635 共0.014兲
235 743.501 共0.041兲*
235 782.105 共0.035兲*
236 004.139 共0.012兲*
236 003.981 共0.012兲
236 004.192 共0.012兲
236 004.266 共0.012兲
236 025.213 共0.014兲*
236 108.805 共0.018兲*
236 159.884 共0.009兲*
236 159.556 共0.009兲
236 159.695 共0.009兲
236 160.375 共0.009兲
236 408.779 共0.011兲*
236 408.384 共0.011兲
236 408.531 共0.011兲
236 409.398 共0.011兲
236 610.593 共0.029兲*
236 610.594 共0.029兲*
237 143.512 共0.010兲*
17.984
17.984
17.984
25.426
25.426
25.426
25.426
34.399
34.399
34.399
34.399
141.061
141.061
269.666
12.039
12.039
12.039
12.039
7.588
7.588
7.588
7.588
7.588
7.588
7.588
7.588
269.556
17.984
17.984
17.984
17.984
432.850
244.949
244.949
56.610
56.610
56.610
56.610
731.952
732.077
12.039
12.039
12.039
12.039
269.711
269.667
25.444
25.444
25.444
25.444
34.376
34.376
34.376
34.376
506.492
506.492
7.370
0.711
1.143
0.879
0.506
0.132
0.194
0.158
2.989
0.820
1.126
0.949
1.506
1.506
4.682
2.199
0.616
0.883
0.465
1.294
0.300
0.067
0.065
0.067
0.537
0.065
0.194
4.145
0.276
0.067
0.108
0.083
0.228
2.367
2.367
6.840
1.980
2.517
2.217
6.956
6.937
0.096
0.027
0.039
0.020
0.033
4.689
2.710
0.710
1.038
0.844
5.020
1.377
1.892
1.595
3.756
3.756
1.230
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
3
1
3
3
3
3
1
1
1
1
3
3
3
Ref.
1
11
1
11
11
1
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1213
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
2
2
2
2
2
2
2
7
7
7
7
18
3
3
3
3
3
3
3
3
4
4
4
4
10
5
5
5
5
7
7
7
7
4
4
4
4
3
3
3
3
22
2
2
2
2
2
2
2
2
29
4
4
4
4
5
5
2
2
2
2
2
2
2
0
0
0
0
3
2
2
2
2
3
3
3
3
2
2
2
2
5
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
4
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A1
A1
A1
A1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
2
3
2
1
2
3
1
2
2
2
2
2
2
2
6
6
6
6
17
3
3
3
3
4
4
4
4
4
4
4
4
11
5
5
5
5
7
7
7
7
4
4
4
4
3
3
3
3
21
2
2
2
2
2
2
2
2
29
4
4
4
4
5
5
1
1
1
1
1
1
1
1
1
1
1
4
1
1
1
1
2
2
2
2
1
1
1
1
4
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E1 − 1
E1 − 1
2
2
3
2
1
3
1
7
8
6
3
4
2
3
4
2
3
5
4
4
6
5
6
8
7
4
5
3
2
4
3
2
2
2
3
3
1
1
3
5
4
5
Obs. Freq. 共unc.兲
共MHz兲
6
7
5
237 965.522 共0.100兲
3
4
2
4
5
3
238 067.520 共0.100兲
3
5
4
239 023.740 共0.100兲
4
6
5
239 209.628 共0.100兲
6
8
7
239 427.041 共0.100兲
4
5
3
239 446.290 共0.100兲
2
4
3
240 235.858 共0.100兲
1
3
2
3
2
1
2
3
5
4
5
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
237 142.250 共0.010兲
237 143.032 共0.010兲
237 143.091 共0.010兲
237 143.466 共0.010兲
237 143.558 共0.010兲
237 143.872 共0.010兲
237 144.773 共0.010兲
237 327.399 共0.008兲*
237 326.805 共0.008兲
237 327.628 共0.008兲
237 327.792 共0.008兲
237 858.659 共0.015兲*
237 965.458 共0.010兲*
237 964.444 共0.010兲
237 965.797 共0.010兲
237 966.270 共0.010兲
238 001.166 共0.012兲*
238 000.184 共0.012兲
238 001.500 共0.012兲
238 001.932 共0.012兲
238 067.376 共0.009兲*
238 067.117 共0.009兲
238 067.244 共0.009兲
238 067.739 共0.009兲
238 677.024 共0.019兲*
239 023.813 共0.010兲*
239 023.433 共0.010兲
239 023.594 共0.010兲
239 024.384 共0.010兲
239 209.612 共0.012兲*
239 209.213 共0.012兲
239 209.345 共0.012兲
239 210.262 共0.012兲
239 427.017 共0.009兲*
239 426.064 共0.009兲
239 427.364 共0.009兲
239 427.698 共0.009兲
239 446.259 共0.010兲*
239 446.192 共0.010兲
239 446.231 共0.010兲
239 446.342 共0.010兲
239 599.365 共0.020兲*
240 235.821 共0.011兲*
240 235.163 共0.011兲
240 235.199 共0.011兲
240 235.264 共0.011兲
240 235.980 共0.011兲
240 236.045 共0.011兲
240 236.378 共0.011兲
240 236.479 共0.011兲
241 121.389 共0.541兲*
241 209.163 共0.010兲*
241 208.819 共0.010兲
241 208.988 共0.010兲
241 209.645 共0.010兲
241 501.242 共0.010兲*
241 500.318 共0.010兲
7.370
7.370
7.370
7.370
7.370
7.370
7.370
33.761
33.761
33.761
33.761
269.556
11.780
11.780
11.780
11.780
25.634
25.634
25.634
25.634
17.985
17.985
17.985
17.985
141.223
25.417
25.417
25.417
25.417
44.668
44.668
44.668
44.668
17.647
17.648
17.647
17.647
12.023
12.023
12.023
12.023
409.340
7.559
7.559
7.559
7.559
7.559
7.559
7.559
7.559
649.313
17.950
17.950
17.950
17.950
24.974
24.974
0.285
0.064
0.064
0.061
0.061
0.510
0.184
0.075
0.024
0.028
0.021
0.551
1.908
0.534
0.767
0.404
0.197
0.062
0.080
0.047
2.377
0.578
0.930
0.715
1.504
4.129
1.081
1.581
1.286
5.921
1.675
2.202
1.904
2.299
0.692
0.899
0.559
1.937
0.410
0.778
0.542
5.571
1.235
0.062
0.064
0.286
0.512
0.064
0.185
0.062
0.026
3.235
0.786
1.265
0.973
2.554
0.795
3
3
3
3
3
3
3
3
3
3
3
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
Ref.
11
11
11
11
11
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1214
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
5
5
21
29
28
21
6
6
6
6
18
3
3
3
3
22
29
10
17
22
6
6
6
6
7
7
7
7
2
2
2
2
2
2
2
2
18
5
5
5
5
24
12
22
10
10
29
6
6
6
6
6
6
6
6
2
2
2
2
8
5
10
8
2
2
2
2
3
2
2
2
2
4
6
5
7
4
2
2
2
2
0
0
0
0
2
2
2
2
2
2
2
2
3
2
2
2
2
0
1
4
5
5
5
4
4
4
4
4
4
4
4
2
2
E1 − 1
E1 − 1
E2 − 1
A2
E1 − 1
E2 + 1
B2
B2
B2
B2
B2
A1
A1
A1
A1
B2
E2 + 1
E1 + 1
E2 + 1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A2
A2
A2
A2
B1
B1
B1
B1
B1
E1 + 1
B2
E1 + 1
B1
B2
B2
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
E1 + 1
6
4
5
5
22
30
29
22
6
6
6
6
17
3
3
3
3
21
28
11
18
21
6
6
6
6
6
6
6
6
2
2
2
2
2
2
2
2
17
5
5
5
5
23
11
21
11
11
30
7
7
7
7
7
7
7
7
2
2
1
1
7
2
9
7
1
1
1
1
4
1
1
1
1
5
7
4
6
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
4
1
1
1
1
3
2
5
4
4
2
3
3
3
3
3
3
3
3
1
1
E1 − 1
E1 − 1
E2 − 1
A1
E1 − 1
E2 + 1
B1
B1
B1
B1
B1
A2
A2
A2
A2
B1
E2 + 1
E1 + 1
E2 + 1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A1
A1
A1
A1
B2
B2
B2
B2
B2
E1 + 1
B1
E1 + 1
B2
B1
B1
B2
B2
B2
B2
B1
B1
B1
B1
E1 − 1
E1 − 1
6
4
5
7
6
2
4
3
6
7
5
7
8
6
2
2
2
3
1
3
1
4
6
5
6
7
5
6
7
5
2
5
7
6
2
4
3
6
7
5
6
7
5
1
3
2
3
1
2
2
4
6
5
7
8
6
7
8
6
2
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
241 501.598 共0.010兲
241 501.859 共0.010兲
241 579.251 共0.034兲*
241 992.689 共0.606兲*
242 112.893 共0.089兲*
242 206.047 共0.037兲*
242 261.957 共0.011兲*
242 261.562 共0.012兲
242 261.709 共0.012兲
242 262.577 共0.012兲
242 625.458 共0.020兲*
242 961.361 共0.010兲*
242 961.119 共0.010兲
242 961.260 共0.010兲
242 961.664 共0.010兲
243 552.009 共0.020兲*
243 575.344 共0.045兲*
243 672.858 共0.019兲*
243 763.795 共0.028兲*
243 796.367 共0.020兲*
244 151.624 共0.010兲*
244 150.715 共0.010兲
244 151.987 共0.010兲
244 152.202 共0.010兲
244 202.397 共0.009兲*
244 201.897 共0.009兲
244 202.588 共0.009兲
244 202.729 共0.009兲
244 277.744 共0.011兲*
244 276.684 共0.011兲
244 277.010 共0.011兲
244 277.597 共0.011兲
244 277.786 共0.011兲
244 277.891 共0.011兲
244 278.373 共0.011兲
244 278.804 共0.011兲
244 501.902 共0.019兲*
244 886.856 共0.011兲*
244 886.475 共0.011兲
244 886.636 共0.011兲
244 887.426 共0.011兲
244 948.250 共0.193兲*
245 202.161 共0.026兲*
245 255.221 共0.021兲*
245 463.442 共0.018兲*
245 464.483 共0.018兲*
245 530.120 共0.571兲*
245 764.729 共0.016兲*
245 764.340 共0.016兲
245 764.888 共0.016兲
245 764.970 共0.016兲
245 772.271 共0.016兲*
245 771.881 共0.016兲
245 772.430 共0.016兲
245 772.513 共0.016兲
245 905.297 共0.009兲*
245 904.036 共0.009兲
24.974
24.974
506.351
702.040
861.143
506.159
34.218
34.218
34.218
34.218
269.481
11.977
11.977
11.977
11.977
409.130
731.906
141.104
350.365
409.130
33.761
33.761
33.761
33.761
33.635
33.635
33.635
33.635
7.496
7.496
7.496
7.496
7.496
7.496
7.496
7.496
269.482
25.259
25.259
25.259
25.259
432.441
108.806
409.302
140.873
140.873
702.096
66.137
66.137
66.137
66.137
66.137
66.137
66.137
66.137
7.370
7.370
0.978
0.669
3.759
0.029
5.149
3.763
5.020
1.376
1.891
1.594
4.692
2.317
0.490
0.931
0.649
5.580
6.947
1.504
2.891
5.580
2.725
0.866
1.027
0.747
0.340
0.111
0.129
0.096
1.319
0.066
0.068
0.305
0.547
0.198
0.068
0.066
4.699
4.129
1.081
1.581
1.286
0.036
3.154
5.560
1.506
1.506
0.031
0.675
0.220
0.255
0.190
0.675
0.220
0.255
0.190
0.073
0.017
3
3
1
1
3
1
3
3
3
3
3
1
1
1
1
3
1
3
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1215
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
2
2
2
2
2
2
4
4
4
4
23
3
3
3
3
2
2
2
2
2
2
2
2
4
4
4
4
21
3
3
3
3
7
7
7
7
4
4
4
4
4
4
4
4
15
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
8
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
A1
A1
A1
A1
B2
B2
B2
B2
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
3
2
1
2
3
1
2
2
2
2
2
2
3
3
3
3
23
3
3
3
3
2
2
2
2
2
2
2
2
4
4
4
4
22
3
3
3
3
7
7
7
7
4
4
4
4
4
4
4
4
14
3
3
3
3
2
2
2
2
2
2
2
2
1
1
1
1
1
1
0
0
0
0
0
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
7
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
A2
A2
A2
A2
B1
B1
B1
B1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
2
3
2
1
3
1
3
5
4
3
4
2
2
3
1
2
2
3
1
3
5
4
3
4
2
7
8
6
4
5
3
4
5
3
3
4
2
2
2
3
2
1
3
1
2
4
3
3
4
2
2
2
2
3
1
3
1
3
5
4
3
4
2
7
8
6
4
5
3
4
5
3
3
4
2
2
3
2
1
2
3
1
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
245 904.817 共0.009兲
245 904.877 共0.009兲
245 905.251 共0.009兲
245 905.344 共0.009兲
245 905.658 共0.009兲
245 906.559 共0.009兲
246 249.681 共0.009兲*
246 249.487 共0.009兲
246 249.536 共0.009兲
246 250.026 共0.009兲
246 490.084 共0.239兲*
246 725.165 共0.008兲*
246 724.151 共0.008兲
246 725.503 共0.008兲
246 725.976 共0.008兲
246 924.172 共0.011兲*
246 922.501 共0.011兲
246 923.287 共0.011兲
246 923.723 共0.011兲
246 923.863 共0.011兲
246 924.620 共0.011兲
246 924.649 共0.011兲
246 925.843 共0.011兲
247 080.140 共0.011兲*
247 079.795 共0.011兲
247 079.964 共0.011兲
247 080.622 共0.011兲
247 205.184 共0.035兲*
247 255.790 共0.009兲*
247 255.017 共0.009兲
247 256.048 共0.009兲
247 256.408 共0.009兲
247 362.353 共0.011兲*
247 361.451 共0.011兲
247 362.724 共0.011兲
247 362.907 共0.011兲
248 183.789 共0.008兲*
248 182.837 共0.008兲
248 184.136 共0.008兲
248 184.470 共0.008兲
248 185.405 共0.009兲*
248 184.660 共0.009兲
248 185.676 共0.009兲
248 185.937 共0.009兲
248 273.693 共0.020兲*
248 274.729 共0.010兲*
248 273.496 共0.010兲
248 275.140 共0.010兲
248 275.716 共0.010兲
248 571.634 共0.010兲*
248 570.560 共0.010兲
248 571.159 共0.010兲
248 571.341 共0.010兲
248 571.492 共0.010兲
248 571.775 共0.010兲
248 571.941 共0.010兲
248 572.707 共0.010兲
7.370
7.370
7.370
7.370
7.370
7.370
9.277
9.277
9.277
9.277
405.663
11.780
11.780
11.780
11.780
7.408
7.408
7.408
7.408
7.408
7.408
7.408
7.408
17.792
17.792
17.792
17.792
506.203
11.605
11.605
11.605
11.605
44.009
44.010
44.009
44.009
17.647
17.648
17.647
17.647
17.491
17.491
17.491
17.491
179.981
11.801
11.801
11.801
11.801
7.182
7.183
7.182
7.183
7.182
7.183
7.182
7.182
0.004
0.004
0.004
0.004
0.030
0.011
0.795
0.189
0.324
0.248
0.036
0.343
0.096
0.138
0.073
1.298
0.300
0.067
0.065
0.067
0.065
0.538
0.195
3.235
0.786
1.265
0.973
3.762
0.081
0.023
0.033
0.017
2.807
0.902
1.044
0.794
0.772
0.232
0.302
0.188
0.229
0.069
0.090
0.056
2.967
2.245
0.629
0.902
0.475
1.292
0.299
0.067
0.067
0.065
0.065
0.536
0.194
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1216
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
3
3
3
3
3
3
3
3
28
28
12
28
10
5
5
5
5
4
4
4
4
4
4
4
4
2
2
2
2
2
2
2
2
5
5
5
5
22
12
30
8
8
8
8
12
8
8
8
8
5
5
5
5
17
17
6
6
2
2
2
2
2
2
2
2
10
10
1
10
5
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
4
1
2
0
0
0
0
1
2
2
2
2
2
2
2
2
7
7
2
2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B2
B2
B2
B2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E1 + 1
A1
A1
A1
A1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E2 + 1
E2 + 1
F⬘
2
4
3
3
4
2
5
6
4
4
5
3
4
5
3
2
2
2
3
1
3
1
5
6
4
7
9
8
8
9
7
5
6
4
6
J⬙
K⬙a
⌫⬙
3
3
3
3
3
3
3
3
29
29
11
29
11
5
5
5
5
4
4
4
4
4
4
4
4
2
2
2
2
2
2
2
2
5
5
5
5
21
11
30
7
7
7
7
11
8
8
8
8
5
5
5
5
18
18
6
6
1
1
1
1
1
1
1
1
9
9
2
9
4
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
2
1
1
1
1
1
2
1
1
1
1
1
1
1
1
6
6
1
1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A2
E2 − 1
E2 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B1
B1
B1
B1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E2 − 1
E2 − 1
F⬙
2
4
3
3
4
2
5
6
4
4
5
3
4
5
3
1
3
2
3
1
2
2
5
6
4
6
8
7
8
9
7
5
6
4
6
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
248 838.500 共0.011兲*
248 838.257 共0.011兲
248 838.399 共0.011兲
248 838.803 共0.011兲
248 999.871 共0.010兲*
248 999.098 共0.010兲
249 000.129 共0.010兲
249 000.490 共0.010兲
249 258.957 共0.072兲*
249 258.957 共0.072兲*
249 355.670 共0.015兲*
249 487.692 共0.064兲*
249 527.261 共0.019兲*
249 744.836 共0.009兲*
249 744.061 共0.009兲
249 745.135 共0.009兲
249 745.353 共0.009兲
249 929.190 共0.009兲*
249 928.443 共0.009兲
249 929.462 共0.009兲
249 929.723 共0.009兲
250 110.220 共0.010兲*
250 109.151 共0.010兲
250 110.609 共0.010兲
250 110.985 共0.010兲
250 159.397 共0.011兲*
250 158.337 共0.011兲
250 158.663 共0.011兲
250 159.250 共0.011兲
250 159.439 共0.011兲
250 159.544 共0.011兲
250 160.026 共0.011兲
250 160.457 共0.011兲
250 255.530 共0.009兲*
250 254.605 共0.009兲
250 255.885 共0.009兲
250 256.146 共0.009兲
250 278.619 共0.022兲*
250 398.508 共0.015兲*
250 613.476 共0.632兲*
250 702.202 共0.018兲*
250 701.658 共0.018兲
250 701.823 共0.018兲
250 703.104 共0.018兲
251 068.343 共0.025兲*
251 128.689 共0.012兲*
251 127.791 共0.012兲
251 129.068 共0.012兲
251 129.228 共0.012兲
251 499.754 共0.009兲*
251 498.970 共0.009兲
251 500.056 共0.009兲
251 500.277 共0.009兲
251 628.951 共0.029兲*
251 917.639 共0.027兲*
251 963.461 共0.010兲*
251 962.656 共0.010兲
11.818
11.818
11.818
11.818
11.605
11.605
11.605
11.605
860.917
860.917
108.745
861.059
140.948
24.834
24.834
24.834
24.834
17.491
17.491
17.491
17.491
17.657
17.657
17.657
17.657
7.337
7.337
7.337
7.337
7.337
7.337
7.337
7.337
24.974
24.974
24.974
24.974
409.252
108.803
693.605
44.826
44.826
44.826
44.826
108.769
55.719
55.719
55.719
55.719
24.834
24.834
24.834
24.834
350.145
350.272
33.635
33.635
2.317
0.490
0.931
0.649
2.182
0.611
0.877
0.462
5.155
5.155
0.215
5.145
1.505
0.405
0.126
0.155
0.106
2.865
0.862
1.121
0.696
3.067
0.923
1.200
0.746
1.319
0.066
0.068
0.305
0.547
0.198
0.068
0.066
1.251
0.390
0.479
0.327
5.558
0.653
0.023
4.891
1.413
1.822
1.605
3.149
2.776
0.900
1.022
0.804
3.430
1.068
1.314
0.898
2.892
2.888
0.498
0.158
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1217
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
6
19
5
5
5
5
2
2
2
2
2
2
2
2
15
6
6
6
6
25
26
26
6
6
6
6
4
4
4
4
3
3
3
3
6
6
6
6
6
6
6
6
6
6
6
6
22
28
22
12
7
7
7
7
15
6
2
2
4
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
0
5
5
2
2
2
2
1
1
1
1
2
2
2
2
4
4
4
4
4
4
4
4
4
4
4
4
4
10
4
1
2
2
2
2
2
2
E2 + 1
E2 + 1
A2
A2
A2
A2
A2
B1
B1
B1
B1
B1
B1
B1
B1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A2
A2
A2
A2
A2
E1 + 1
A1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
7
5
6
6
20
5
5
5
5
2
2
2
2
2
2
2
2
14
6
6
6
6
24
25
25
6
6
6
6
3
3
3
3
3
3
3
3
7
7
7
7
7
7
7
7
7
7
7
7
21
29
21
11
7
7
7
7
14
6
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
3
6
6
1
1
1
1
0
0
0
0
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
5
9
5
2
1
1
1
1
3
1
E2 − 1
E2 − 1
A1
A1
A1
A1
A1
B2
B2
B2
B2
B2
B2
B2
B2
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
A1
A1
A1
A1
E1 + 1
A2
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
A2
7
5
5
6
4
2
3
1
2
2
3
1
6
7
5
6
7
5
3
5
4
3
4
2
6
7
5
6
7
5
6
7
5
7
8
6
5
6
4
2
2
2
3
1
3
1
6
7
5
6
7
5
2
4
3
3
4
2
7
8
6
7
8
6
7
8
6
7
8
6
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
251 963.783 共0.010兲
251 963.974 共0.010兲
252 076.738 共0.125兲*
252 460.238 共0.010兲*
252 459.237 共0.010兲
252 460.623 共0.010兲
252 460.905 共0.010兲
252 810.495 共0.011兲*
252 808.823 共0.011兲
252 809.609 共0.011兲
252 810.046 共0.011兲
252 810.186 共0.011兲
252 810.943 共0.011兲
252 810.972 共0.011兲
252 812.166 共0.011兲
252 849.385 共0.023兲*
252 908.786 共0.009兲*
252 907.873 共0.009兲
252 909.150 共0.009兲
252 909.366 共0.009兲
253 230.758 共0.184兲*
253 255.533 共0.030兲*
253 282.642 共0.030兲*
253 768.569 共0.010兲*
253 767.740 共0.010兲
253 768.900 共0.010兲
253 769.096 共0.010兲
254 055.766 共0.008兲*
254 055.424 共0.008兲
254 055.546 共0.008兲
254 056.319 共0.008兲
254 161.468 共0.011兲*
254 160.235 共0.011兲
254 161.879 共0.011兲
254 162.455 共0.011兲
254 318.755 共0.015兲*
254 318.366 共0.015兲
254 318.913 共0.015兲
254 318.996 共0.015兲
254 445.917 共0.015兲*
254 445.529 共0.015兲
254 446.076 共0.015兲
254 446.158 共0.015兲
254 453.624 共0.015兲*
254 453.234 共0.015兲
254 453.783 共0.015兲
254 453.866 共0.015兲
254 457.696 共0.019兲*
254 483.646 共0.071兲*
254 696.778 共0.019兲*
254 771.962 共0.020兲*
254 804.835 共0.010兲*
254 804.015 共0.010兲
254 805.173 共0.010兲
254 805.340 共0.010兲
255 237.845 共0.023兲*
255 361.473 共0.011兲*
33.635
33.635
315.941
24.977
24.977
24.977
24.977
7.249
7.249
7.249
7.249
7.249
7.249
7.249
7.249
179.878
33.761
33.761
33.761
33.761
468.436
577.691
577.691
33.635
33.635
33.635
33.635
9.173
9.173
9.173
9.173
11.642
11.642
11.642
11.642
65.927
65.927
65.927
65.927
66.037
66.037
66.037
66.037
66.037
66.037
66.037
66.037
408.946
861.065
408.947
108.564
43.893
43.894
43.893
43.893
179.798
33.759
0.188
0.137
0.018
3.809
1.187
1.459
0.997
1.298
0.300
0.067
0.065
0.067
0.065
0.538
0.195
1.479
1.740
0.553
0.655
0.477
0.207
6.461
6.461
3.999
1.270
1.507
1.096
0.259
0.062
0.106
0.081
2.244
0.628
0.902
0.475
0.675
0.221
0.255
0.190
0.675
0.220
0.255
0.190
0.675
0.220
0.255
0.190
5.584
5.145
5.584
2.944
0.437
0.141
0.163
0.124
2.683
4.480
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1218
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
6
6
9
9
9
9
22
25
4
4
4
4
7
7
7
7
17
17
15
28
7
7
7
7
24
24
6
6
6
6
15
8
8
8
8
5
5
5
5
17
17
28
28
7
7
7
7
8
8
8
8
13
15
8
8
8
2
2
2
2
2
2
2
4
0
2
2
2
2
2
2
2
2
7
7
2
10
2
2
2
2
9
9
4
4
4
4
2
2
2
2
2
2
2
2
2
7
7
10
10
2
2
2
2
0
0
0
0
6
2
2
2
2
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
B1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B2
B1
B2
B1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
6
7
5
6
6
6
9
9
9
9
21
24
4
4
4
4
7
7
7
7
18
18
14
29
7
7
7
7
25
25
7
7
7
7
14
8
8
8
8
5
5
5
5
18
18
29
29
7
7
7
7
7
7
7
7
14
14
8
8
8
1
1
1
1
1
1
1
5
3
1
1
1
1
1
1
1
1
6
6
3
9
1
1
1
1
8
8
3
3
3
3
3
1
1
1
1
1
1
1
1
6
6
9
9
1
1
1
1
1
1
1
1
5
3
1
1
1
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A2
B2
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B1
B2
B1
B2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
6
7
5
9
10
8
4
5
3
7
8
6
7
8
6
6
7
5
8
9
7
5
6
4
7
8
6
7
9
8
8
9
9
10
8
4
5
3
7
8
6
7
8
6
7
8
6
8
9
7
5
6
4
7
8
6
6
8
7
8
9
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
255 360.498 共0.011兲
255 361.863 共0.011兲
255 362.093 共0.011兲
255 444.688 共0.013兲*
255 443.792 共0.013兲
255 445.072 共0.013兲
255 445.215 共0.013兲
255 560.830 共0.025兲*
255 851.705 共0.180兲*
255 997.778 共0.011兲*
255 996.708 共0.011兲
255 998.167 共0.011兲
255 998.542 共0.011兲
256 140.663 共0.010兲*
256 139.752 共0.010兲
256 141.038 共0.010兲
256 141.224 共0.010兲
256 261.325 共0.032兲*
256 261.331 共0.032兲*
256 327.873 共0.028兲*
256 654.921 共0.107兲*
256 759.656 共0.011兲*
256 758.783 共0.011兲
256 760.016 共0.011兲
256 760.193 共0.011兲
257 368.810 共0.047兲*
257 368.810 共0.047兲*
258 102.274 共0.015兲*
258 101.885 共0.015兲
258 102.433 共0.015兲
258 102.516 共0.015兲
258 192.108 共0.030兲*
258 208.552 共0.011兲*
258 207.729 共0.011兲
258 208.898 共0.011兲
258 209.045 共0.011兲
258 349.241 共0.011兲*
258 348.239 共0.011兲
258 349.626 共0.011兲
258 349.908 共0.011兲
258 468.501 共0.034兲*
258 468.508 共0.034兲*
258 782.233 共0.064兲*
258 782.233 共0.064兲*
258 857.426 共0.012兲*
258 856.454 共0.012兲
258 857.827 共0.012兲
258 858.025 共0.012兲
259 042.415 共0.010兲*
259 041.876 共0.010兲
259 042.040 共0.010兲
259 043.308 共0.010兲
259 582.107 共0.026兲*
259 733.340 共0.020兲*
259 974.470 共0.012兲*
259 973.550 共0.012兲
259 974.858 共0.012兲
33.760
33.759
33.759
68.888
68.888
68.888
68.888
409.106
468.522
17.498
17.498
17.498
17.498
44.009
44.010
44.009
44.009
350.310
350.310
180.000
860.969
43.893
43.894
43.893
43.893
653.094
653.094
66.109
66.109
66.109
66.109
179.902
55.610
55.610
55.610
55.610
24.818
24.818
24.818
24.818
350.208
350.208
860.739
860.739
44.005
44.005
44.005
44.005
44.846
44.846
44.846
44.846
223.091
179.598
55.719
55.719
55.719
1.423
1.688
1.229
2.612
0.851
0.953
0.769
5.567
0.224
3.065
0.922
1.199
0.745
2.243
0.721
0.834
0.635
2.887
2.887
4.144
5.150
4.643
1.493
1.726
1.314
4.283
4.283
0.675
0.220
0.255
0.190
4.157
0.274
0.089
0.101
0.079
3.804
1.185
1.457
0.996
2.890
2.890
5.156
5.156
5.080
1.633
1.889
1.438
4.812
1.390
1.793
1.579
2.028
1.204
2.781
0.901
1.023
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
3
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1219
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
8
6
6
6
6
10
10
10
10
25
12
8
8
8
8
11
4
4
4
4
4
4
4
4
6
6
6
6
8
8
8
8
26
26
17
9
9
9
9
26
8
8
8
8
24
26
6
6
6
6
6
6
6
6
8
8
8
2
4
4
4
4
2
2
2
2
0
1
2
2
2
2
1
1
1
1
1
1
1
1
1
2
2
2
2
0
0
0
0
5
5
7
2
2
2
2
5
2
2
2
2
1
5
1
1
1
1
1
1
1
1
0
0
0
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B1
B1
B1
B1
B1
B1
B1
B1
B2
B1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
A1
A1
A1
A1
E2 + 1
E2 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
7
8
7
7
7
7
10
10
10
10
24
11
8
8
8
8
10
3
3
3
3
3
3
3
3
6
6
6
6
7
7
7
7
25
25
18
9
9
9
9
25
8
8
8
8
24
25
5
5
5
5
5
5
5
5
7
7
7
1
3
3
3
3
1
1
1
1
3
2
1
1
1
1
2
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
6
6
6
1
1
1
1
6
1
1
1
1
0
6
1
1
1
1
1
1
1
1
1
1
1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B2
B2
B2
B2
B2
B2
B2
B2
B1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
A2
A2
A2
A2
E2 + 1
E2 + 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
7
6
7
5
10
11
9
8
9
7
4
5
3
4
5
3
6
7
5
7
9
8
9
10
8
8
9
7
7
6
5
7
6
5
7
9
Obs. Freq. 共unc.兲
共MHz兲
7
8
6
260 293.904 共0.060兲
10
11
9
8
9
7
260 963.336 共0.060兲
3
4
2
261 219.290 共0.060兲
3
4
2
261 252.887 共0.060兲
6
7
5
261 562.197 共0.060兲
6
8
7
9
10
8
8
9
7
6
5
4
6
5
4
6
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
259 975.023 共0.012兲
260 265.737 共0.016兲*
260 265.348 共0.016兲
260 265.896 共0.016兲
260 265.978 共0.016兲
260 293.983 共0.014兲*
260 293.092 共0.015兲
260 294.371 共0.014兲
260 294.499 共0.014兲
260 299.617 共0.192兲*
260 427.074 共0.016兲*
260 508.452 共0.012兲*
260 507.533 共0.012兲
260 508.838 共0.012兲
260 509.003 共0.012兲
260 963.398 共0.021兲*
261 024.312 共0.007兲*
261 023.757 共0.007兲
261 024.495 共0.007兲
261 024.763 共0.007兲
261 219.283 共0.010兲*
261 218.420 共0.010兲
261 219.577 共0.010兲
261 219.952 共0.010兲
261 252.825 共0.011兲*
261 251.850 共0.011兲
261 253.216 共0.011兲
261 253.446 共0.011兲
261 562.178 共0.018兲*
261 561.632 共0.018兲
261 561.798 共0.018兲
261 563.082 共0.018兲
261 570.705 共0.031兲*
261 597.415 共0.031兲*
261 967.145 共0.033兲*
262 121.194 共0.012兲*
262 120.376 共0.012兲
262 121.545 共0.012兲
262 121.676 共0.012兲
262 853.801 共0.034兲*
262 997.969 共0.014兲*
262 996.985 共0.014兲
262 998.383 共0.014兲
262 998.559 共0.014兲
263 216.992 共0.295兲*
263 283.183 共0.028兲*
263 299.089 共0.006兲*
263 299.059 共0.006兲
263 299.112 共0.006兲
263 299.114 共0.006兲
263 299.359 共0.006兲*
263 299.330 共0.006兲
263 299.383 共0.006兲
263 299.385 共0.006兲
263 377.814 共0.009兲*
263 377.312 共0.009兲
263 377.463 共0.009兲
55.719
66.004
66.004
66.004
66.004
83.518
83.518
83.518
83.518
468.405
108.469
55.610
55.610
55.610
55.610
92.668
9.277
9.277
9.277
9.277
9.079
9.079
9.079
9.079
33.601
33.601
33.601
33.601
44.668
44.668
44.668
44.668
577.592
577.592
349.952
68.785
68.786
68.785
68.785
577.525
55.712
55.712
55.712
55.712
440.700
577.743
24.818
24.818
24.818
24.818
24.977
24.977
24.977
24.977
44.804
44.804
44.804
0.805
0.675
0.220
0.255
0.190
2.308
0.755
0.836
0.689
0.212
2.495
5.309
1.721
1.953
1.537
3.943
3.128
0.978
1.275
0.745
3.924
1.226
1.599
0.934
4.472
1.420
1.685
1.226
4.881
1.410
1.818
1.602
6.457
6.457
2.892
0.124
0.040
0.045
0.037
6.456
5.605
1.817
2.062
1.623
0.032
6.435
0.549
0.211
0.178
0.150
0.550
0.212
0.178
0.150
4.613
1.333
1.719
3
1
1
1
1
3
3
3
3
3
3
1
1
1
1
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
3
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
Ref.
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1220
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
8
6
6
6
6
25
6
6
6
6
4
4
4
4
9
9
9
9
7
7
7
7
19
26
9
9
9
9
6
6
6
6
11
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
0
1
1
1
1
0
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
3
5
2
2
2
2
4
4
4
4
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
2
2
2
2
2
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
B2
B2
B2
B2
A2
A2
A2
A2
8
7
5
5
5
5
24
5
5
5
5
3
3
3
3
9
9
9
9
7
7
7
7
18
25
9
9
9
9
7
7
7
7
11
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
1
1
1
1
1
3
1
1
1
1
0
0
0
0
1
1
1
1
1
1
1
1
4
6
1
1
1
1
3
3
3
3
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
2
2
2
2
2
2
2
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E1 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
B1
B1
B1
B1
A1
A1
A1
A1
7
7
5
6
7
5
6
4
5
3
9
10
8
7
8
6
9
10
8
6
7
5
7
5
6
7
5
6
7
5
6
7
5
6
5
7
6
5
7
6
Obs. Freq. 共unc.兲
共MHz兲
6
4
5
263 840.097 共0.060兲
6
4
5
3
4
2
9
10
8
264 752.377 共0.060兲
7
8
6
265 064.393 共0.060兲
9
10
8
7
8
6
265 645.945 共0.060兲
265 742.552 共0.060兲
6
4
5
265 746.624 共0.060兲
6
4
5
265 749.321 共0.060兲
6
4
5
265 757.212 共0.060兲
6
4
5
265 957.488 共0.060兲
4
6
5
265 958.426 共0.060兲
4
6
5
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
263 378.648 共0.009兲
263 431.685 共0.006兲*
263 431.647 共0.006兲
263 431.694 共0.006兲
263 431.732 共0.006兲
263 791.670 共0.185兲*
263 840.124 共0.006兲*
263 840.068 共0.006兲
263 840.096 共0.006兲
263 840.221 共0.006兲
264 172.179 共0.008兲*
264 171.416 共0.008兲
264 172.437 共0.008兲
264 172.777 共0.008兲
264 457.128 共0.014兲*
264 456.187 共0.014兲
264 457.531 共0.014兲
264 457.681 共0.014兲
264 752.355 共0.012兲*
264 751.382 共0.012兲
264 752.755 共0.012兲
264 752.953 共0.012兲
264 855.705 共0.025兲*
264 894.433 共0.032兲*
265 064.448 共0.014兲*
265 063.482 共0.014兲
265 064.862 共0.014兲
265 065.017 共0.014兲
265 142.551 共0.015兲*
265 142.163 共0.015兲
265 142.710 共0.015兲
265 142.792 共0.015兲
265 646.040 共0.016兲*
265 742.574 共0.006兲*
265 742.554 共0.006兲
265 742.578 共0.006兲
265 742.599 共0.006兲
265 746.636 共0.006兲*
265 746.616 共0.006兲
265 746.640 共0.006兲
265 746.660 共0.006兲
265 749.325 共0.007兲*
265 749.305 共0.007兲
265 749.330 共0.007兲
265 749.349 共0.007兲
265 757.223 共0.006兲*
265 757.203 共0.006兲
265 757.228 共0.006兲
265 757.247 共0.006兲
265 957.508 共0.006兲*
265 957.472 共0.006兲
265 957.473 共0.006兲
265 957.580 共0.006兲
265 958.468 共0.006兲*
265 958.433 共0.006兲
265 958.433 共0.006兲
265 958.541 共0.006兲
44.804
24.974
24.974
24.974
24.974
468.376
24.834
24.834
24.834
24.834
9.173
9.173
9.173
9.173
68.888
68.888
68.888
68.888
43.846
43.846
43.846
43.846
296.463
577.653
68.785
68.786
68.785
68.785
65.723
65.723
65.723
65.723
99.608
22.579
22.579
22.579
22.579
22.476
22.476
22.476
22.476
22.381
22.381
22.381
22.381
22.176
22.176
22.176
22.176
33.427
33.427
33.427
33.427
33.390
33.390
33.390
33.390
1.514
0.549
0.211
0.150
0.178
0.247
0.546
0.210
0.149
0.177
3.665
1.145
1.493
0.873
3.370
1.099
1.229
0.993
5.067
1.629
1.884
1.434
0.064
6.449
5.877
1.916
2.144
1.731
0.675
0.221
0.255
0.191
1.895
0.566
0.218
0.154
0.184
0.564
0.217
0.154
0.183
0.567
0.218
0.155
0.184
0.564
0.217
0.154
0.183
0.503
0.137
0.193
0.163
0.503
0.137
0.193
0.163
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
Ref.
1
1
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1221
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
A
A
A
A
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
F⬘
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
J⬙
K⬙a
⌫⬙
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
A
A
A
A
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
4
6
5
4
6
5
4
6
5
4
6
5
4
6
5
265 967.066 共0.060兲
4
6
5
4
6
5
4
6
5
4
6
5
265 986.927 共0.060兲
4
6
5
4
6
5
265 988.006 共0.060兲
4
6
5
265 990.310 共0.060兲
4
6
5
4
6
5
265 991.761 共0.060兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
265 962.622 共0.011兲*
265 962.322 共0.011兲
265 962.465 共0.011兲
265 963.051 共0.011兲
265 962.622 共0.011兲*
265 962.322 共0.011兲
265 962.465 共0.011兲
265 963.051 共0.011兲
265 963.744 共0.010兲*
265 963.444 共0.010兲
265 963.587 共0.010兲
265 964.172 共0.010兲
265 966.624 共0.010兲*
265 966.324 共0.010兲
265 966.467 共0.010兲
265 967.052 共0.010兲
265 966.983 共0.010兲*
265 966.683 共0.010兲
265 966.825 共0.010兲
265 967.411 共0.010兲
265 967.016 共0.011兲*
265 966.716 共0.011兲
265 966.859 共0.011兲
265 967.444 共0.011兲
265 967.016 共0.011兲*
265 966.716 共0.011兲
265 966.859 共0.011兲
265 967.444 共0.011兲
265 967.779 共0.010兲*
265 967.479 共0.010兲
265 967.622 共0.010兲
265 968.208 共0.010兲
265 986.986 共0.008兲*
265 986.801 共0.008兲
265 986.882 共0.008兲
265 987.259 共0.008兲
265 986.988 共0.008兲*
265 986.803 共0.008兲
265 986.885 共0.008兲
265 987.262 共0.008兲
265 986.991 共0.008兲*
265 986.806 共0.008兲
265 986.888 共0.008兲
265 987.265 共0.008兲
265 988.079 共0.008兲*
265 987.894 共0.008兲
265 987.976 共0.008兲
265 988.353 共0.008兲
265 990.312 共0.008兲*
265 990.127 共0.008兲
265 990.208 共0.008兲
265 990.585 共0.008兲
265 991.618 共0.008兲*
265 991.433 共0.008兲
265 991.515 共0.008兲
265 991.892 共0.008兲
265 991.657 共0.008兲*
89.922
89.922
89.922
89.922
89.922
89.922
89.922
89.922
90.046
90.046
90.046
90.046
90.131
90.131
90.131
90.131
90.092
90.092
90.092
90.092
89.732
89.732
89.732
89.732
89.732
89.732
89.732
89.732
89.894
89.894
89.894
89.894
65.652
65.652
65.652
65.652
65.652
65.652
65.652
65.652
65.652
65.652
65.652
65.652
65.695
65.695
65.695
65.695
65.846
65.846
65.846
65.845
65.813
65.813
65.813
65.813
65.537
0.173
0.047
0.066
0.056
0.173
0.047
0.066
0.056
0.173
0.047
0.066
0.056
0.173
0.047
0.066
0.056
0.173
0.047
0.066
0.056
0.173
0.047
0.067
0.056
0.173
0.047
0.067
0.056
0.173
0.047
0.067
0.056
0.314
0.086
0.121
0.102
0.628
0.171
0.242
0.204
0.314
0.086
0.121
0.102
0.314
0.086
0.121
0.102
0.314
0.086
0.121
0.102
0.314
0.086
0.121
0.102
0.314
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
Ref.
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1222
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
5
7
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
4
6
5
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
7
5
6
7
5
6
7
Obs. Freq. 共unc.兲
共MHz兲
4
6
5
4
6
5
266 015.981 共0.060兲
4
6
5
266 016.495 共0.060兲
4
6
5
4
6
5
266 018.409 共0.060兲
4
6
5
4
6
5
4
6
5
266 021.467 共0.060兲
4
6
5
4
6
5
266 058.732 共0.060兲
4
6
5
266 082.055 共0.060兲
6
4
5
266 084.933 共0.060兲
6
4
5
266 108.951 共0.060兲
6
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
265 991.472 共0.008兲
265 991.553 共0.008兲
265 991.930 共0.008兲
265 991.879 共0.008兲*
265 991.694 共0.008兲
265 991.775 共0.008兲
265 992.152 共0.008兲
265 991.885 共0.008兲*
265 991.700 共0.008兲
265 991.781 共0.008兲
265 992.158 共0.008兲
266 016.016 共0.007兲*
266 015.921 共0.007兲
266 015.955 共0.007兲
266 016.168 共0.007兲
266 016.502 共0.007兲*
266 016.407 共0.007兲
266 016.440 共0.007兲
266 016.654 共0.007兲
266 018.076 共0.007兲*
266 017.981 共0.007兲
266 018.014 共0.007兲
266 018.227 共0.007兲
266 018.515 共0.007兲*
266 018.421 共0.007兲
266 018.454 共0.007兲
266 018.667 共0.007兲
266 019.673 共0.007兲*
266 019.578 共0.007兲
266 019.612 共0.007兲
266 019.825 共0.007兲
266 020.323 共0.007兲*
266 020.228 共0.007兲
266 020.262 共0.007兲
266 020.475 共0.007兲
266 021.477 共0.007兲*
266 021.382 共0.007兲
266 021.416 共0.007兲
266 021.628 共0.007兲
266 021.731 共0.007兲*
266 021.636 共0.007兲
266 021.669 共0.007兲
266 021.882 共0.007兲
266 058.749 共0.006兲*
266 058.716 共0.006兲
266 058.716 共0.006兲
266 058.817 共0.006兲
266 082.066 共0.006兲*
266 082.036 共0.006兲
266 082.037 共0.006兲
266 082.128 共0.006兲
266 084.941 共0.006兲*
266 084.912 共0.006兲
266 084.914 共0.006兲
266 085.000 共0.006兲
266 108.939 共0.006兲*
266 108.912 共0.006兲
65.537
65.537
65.537
65.462
65.462
65.462
65.462
65.462
65.462
65.462
65.462
46.701
46.701
46.701
46.701
46.911
46.911
46.911
46.911
46.883
46.883
46.883
46.883
46.911
46.911
46.911
46.911
46.811
46.811
46.811
46.811
46.778
46.778
46.778
46.778
46.497
46.497
46.497
46.497
46.811
46.811
46.811
46.811
33.165
33.165
33.165
33.165
33.030
33.030
33.030
33.030
33.322
33.322
33.322
33.322
33.224
33.224
0.086
0.121
0.102
0.314
0.086
0.121
0.102
0.314
0.086
0.121
0.102
0.424
0.116
0.163
0.138
0.424
0.116
0.163
0.137
0.424
0.116
0.163
0.138
0.424
0.116
0.163
0.1373
0.424
0.116
0.163
0.137
0.424
0.116
0.163
0.137
0.424
0.116
0.163
0.137
0.424
0.116
0.163
0.137
0.500
0.136
0.192
0.162
0.502
0.193
0.137
0.163
0.503
0.193
0.137
0.163
0.501
0.193
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
6
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
Ref.
1
1
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1223
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
6
24
6
6
6
6
6
6
6
6
10
10
10
10
15
11
24
24
24
13
9
9
9
9
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
24
8
8
8
8
19
13
15
10
10
10
10
13
30
10
10
2
2
9
2
2
2
2
2
2
2
2
2
2
2
2
2
1
9
9
9
6
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
9
2
2
2
2
3
6
2
2
2
2
2
6
6
2
2
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A2
A1
A2
E1 − 1
E1 + 1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
E2 + 1
B1
B1
B1
B1
E1 + 1
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
5
6
5
5
25
5
5
5
5
5
5
5
5
10
10
10
10
14
10
25
25
25
14
9
9
9
9
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
25
8
8
8
8
18
14
14
10
10
10
10
14
29
10
10
2
2
8
2
2
2
2
2
2
2
2
1
1
1
1
3
2
8
8
8
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
8
1
1
1
1
4
5
3
1
1
1
1
5
7
1
1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
A1
A2
A1
E1 − 1
E1 + 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
E2 + 1
B2
B2
B2
B2
E1 + 1
E2 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
4
5
7
5
6
7
5
6
10
11
9
9
10
8
6
7
5
5
6
7
5
7
6
5
7
6
8
9
7
10
11
9
10
Obs. Freq. 共unc.兲
共MHz兲
266 200.594 共0.060兲
6
4
5
266 202.659 共0.060兲
6
4
5
10
11
9
266 775.502 共0.060兲
9
10
8
5
6
4
4
5
6
4
6
5
4
6
5
8
9
7
10
11
9
270 476.893 共0.060兲
10
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
266 108.915 共0.006兲
266 108.992 共0.006兲3
266 185.873 共0.064兲*
266 200.595 共0.006兲*
266 200.570 共0.006兲
266 200.573 共0.006兲
266 200.644 共0.006兲
266 202.673 共0.006兲*
266 202.649 共0.006兲
266 202.652 共0.006兲
266 202.722 共0.006兲
266 513.729 共0.014兲*
266 512.915 共0.014兲
266 514.083 共0.014兲
266 514.201 共0.014兲
266 757.618 共0.024兲*
266 775.423 共0.019兲*
266 941.716 共0.047兲*
266 941.716 共0.047兲*
267 588.147 共0.042兲*
267 759.645 共0.028兲*
267 838.721 共0.016兲*
267 837.715 共0.016兲
267 839.152 共0.016兲
267 839.312 共0.016兲
268 038.409 共0.006兲*
268 038.358 共0.006兲
268 038.429 共0.006兲
268 038.441 共0.006兲
268 442.510 共0.006兲*
268 442.505 共0.006兲
268 442.510 共0.006兲
268 442.512 共0.006兲
268 573.503 共0.006兲*
268 573.481 共0.006兲
268 573.496 共0.006兲
268 573.526 共0.006兲
268 582.407 共0.006兲*
268 582.386 共0.006兲
268 582.400 共0.006兲
268 582.430 共0.006兲
268 591.237 共0.054兲*
268 898.057 共0.014兲*
268 897.072 共0.014兲
268 898.472 共0.014兲
268 898.648 共0.014兲
269 343.626 共0.017兲*
269 435.561 共0.027兲*
269 504.359 共0.027兲*
269 659.456 共0.016兲*
269 658.485 共0.016兲
269 659.878 共0.016兲
269 660.018 共0.016兲
269 952.665 共0.028兲*
270 263.058 共0.054兲*
270 476.894 共0.017兲*
270 475.880 共0.017兲
33.224
3.224
653.122
33.398
33.398
33.398
33.398
33.435
33.435
33.435
33.435
83.420
83.420
83.420
83.420
179.981
92.630
652.957
652.957
653.160
223.140
68.880
68.880
68.880
68.880
25.426
25.426
25.426
25.426
25.444
25.444
25.444
25.444
25.417
25.417
25.417
25.417
25.259
25.259
25.259
25.259
652.949
55.553
55.553
55.553
55.553
296.314
223.178
179.878
83.518
83.518
83.518
83.518
222.942
774.860
83.420
83.420
0.137
0.162
4.279
0.503
0.193
0.137
0.163
0.503
0.193
0.137
0.163
0.041
0.013
0.015
0.012
1.254
3.921
4.281
4.281
4.275
2.026
6.051
1.973
2.207
1.782
0.546
0.177
0.210
0.149
0.549
0.150
0.178
0.211
0.551
0.150
0.212
0.178
0.549
0.150
0.211
0.178
4.283
5.586
1.811
2.056
1.617
5.035
2.025
2.744
4.011
1.313
1.452
1.198
2.027
7.346
6.291
2.059
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
1
1
1
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
3
3
3
3
3
1
1
3
3
3
3
3
1
1
1
Ref.
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1224
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
11
13
13
11
19
12
15
15
4
4
4
4
26
10
10
10
10
15
30
30
9
9
9
9
19
11
25
11
30
30
20
20
20
19
24
11
9
9
9
9
13
15
9
9
9
9
9
9
9
9
19
19
10
10
10
2
2
1
6
6
1
3
2
2
2
1
1
1
1
5
2
2
2
2
2
6
6
2
2
2
2
3
1
0
2
6
6
8
8
8
3
9
2
5
5
5
5
2
2
5
5
5
5
5
5
5
5
3
3
2
2
2
E2 − 1
E2 − 1
E1 + 1
B2
B1
E2 + 1
E2 + 1
E1 − 1
B2
E2 − 1
A1
A1
A1
A1
E2 − 1
A1
A1
A1
A1
A2
B2
B1
B2
B2
B2
B2
E2 − 1
E2 + 1
E1 + 1
E1 + 1
A2
A1
E1 + 1
A1
A2
E1 − 1
E1 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
A1
E2 + 1
B1
B1
B1
11
9
10
10
10
14
14
10
18
12
14
14
3
3
3
3
25
10
10
10
10
14
29
29
9
9
9
9
18
10
24
11
29
29
21
21
21
18
25
11
10
10
10
10
13
14
10
10
10
10
10
10
10
10
18
18
10
10
10
1
1
2
5
5
2
4
1
3
3
0
0
0
0
6
1
1
1
1
3
7
7
1
1
1
1
4
2
3
1
7
7
7
7
7
4
8
1
4
4
4
4
1
3
4
4
4
4
4
4
4
4
4
4
1
1
1
E2 − 1
E2 − 1
E1 + 1
B1
B2
E2 − 1
E2 − 1
E1 − 1
B1
E2 + 1
A2
A2
A2
A2
E2 − 1
A2
A2
A2
A2
A1
B1
B2
B1
B1
B1
B1
E2 − 1
E2 + 1
E1 + 1
E1 − 1
A1
A2
E1 + 1
A2
A1
E1 − 1
E1 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
A2
E2 + 1
B2
B2
B2
11
9
4
5
3
10
11
9
9
10
8
9
10
8
9
10
8
9
10
8
10
11
Obs. Freq. 共unc.兲
共MHz兲
271 003.355 共0.060兲
3
4
2
273 440.216 共0.060兲
10
11
9
273 745.850 共0.060兲
9
10
8
10
11
9
10
11
9
10
11
9
10
11
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
270 477.335 共0.017兲
270 477.481 共0.017兲
270 690.085 共0.010兲*
270 998.730 共0.024兲*
270 998.788 共0.024兲*
271 003.368 共0.013兲*
271 187.891 共0.022兲*
271 461.292 共0.017兲*
271 858.866 共0.026兲*
271 892.819 共0.026兲*
272 148.016 共0.011兲*
272 147.154 共0.011兲
272 148.310 共0.011兲
272 148.685 共0.011兲
272 768.757 共0.035兲*
273 440.209 共0.018兲*
273 439.174 共0.018兲
273 440.659 共0.018兲
273 440.808 共0.018兲
273 534.159 共0.028兲*
273 683.571 共0.059兲*
273 686.343 共0.059兲*
273 745.927 共0.016兲*
273 744.920 共0.016兲
273 746.359 共0.016兲
273 746.520 共0.016兲
274 715.332 共0.022兲*
274 966.532 共0.011兲*
275 166.776 共0.242兲*
275 674.606 共0.018兲*
275 747.357 共0.051兲*
275 750.117 共0.051兲*
275 871.697 共0.040兲*
275 888.043 共0.046兲*
275 888.043 共0.046兲*
276 380.251 共0.021兲*
276 766.978 共0.054兲*
276 793.445 共0.020兲*
277 560.111 共0.023兲*
277 559.879 共0.023兲
277 560.213 共0.023兲
277 560.245 共0.023兲
277 704.001 共0.021兲*
278 217.266 共0.022兲*
278 521.409 共0.019兲*
278 521.177 共0.019兲
278 521.510 共0.019兲
278 521.542 共0.019兲
278 521.884 共0.019兲*
278 521.653 共0.019兲
278 521.985 共0.019兲
278 522.017 共0.019兲
278 619.919 共0.020兲*
279 351.877 共0.016兲*
279 356.862 共0.018兲*
279 355.825 共0.018兲
279 357.313 共0.018兲
83.420
83.420
92.513
222.967
222.967
92.442
296.432
117.155
180.015
179.798
8.873
8.873
8.873
8.873
577.337
83.509
83.509
83.509
83.509
179.917
774.999
774.999
68.721
68.721
68.721
68.721
296.432
92.309
467.909
99.608
775.026
775.026
473.858
474.042
474.042
296.463
652.774
99.512
124.992
124.992
124.992
124.992
136.161
179.598
124.797
124.797
124.797
124.797
124.797
124.797
124.797
124.797
296.269
296.160
83.350
83.350
83.350
2.278
1.878
2.859
2.027
2.027
3.605
0.875
1.441
4.257
1.529
3.926
1.227
1.599
0.935
6.464
6.414
2.099
2.322
1.915
4.277
7.330
7.330
6.025
1.964
2.198
1.775
4.213
0.365
0.028
4.671
7.318
7.318
3.416
3.412
3.412
5.011
4.285
6.564
1.182
0.390
0.431
0.352
1.023
3.027
1.182
0.390
0.432
0.353
1.182
0.390
0.432
0.353
5.083
4.219
6.379
2.088
2.310
1
1
3
3
3
1
1
3
3
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
1
3
3
1
1
3
1
1
3
3
1
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
3
3
3
Ref.
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1225
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
13
13
11
30
11
30
26
25
19
20
20
19
12
19
9
9
9
9
26
13
12
8
8
8
8
23
14
13
11
20
27
20
30
19
13
12
26
30
30
9
9
9
9
30
16
23
23
30
5
5
5
5
13
19
9
9
2
6
6
2
6
1
6
0
1
3
8
8
3
2
3
5
5
5
5
0
1
2
0
0
0
0
4
2
1
2
8
10
8
3
3
1
2
0
3
6
5
5
5
5
3
7
4
4
3
1
1
1
1
1
3
5
5
B1
A2
A1
A2
E1 − 1
E1 + 1
E1 + 1
A1
E2 + 1
E1 − 1
B1
B2
A2
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E1 − 1
E2 − 1
B2
E2 − 1
E1 − 1
E2 + 1
E1 + 1
B1
E1 − 1
A1
E1 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
E2 + 1
B1
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
B2
B2
B2
9
10
14
14
11
29
10
29
25
25
18
21
21
18
12
18
10
10
10
10
25
12
12
7
7
7
7
22
14
12
11
21
28
21
30
18
12
12
25
30
29
10
10
10
10
30
17
22
22
30
4
4
4
4
12
18
10
10
1
5
5
1
7
2
7
3
0
4
7
7
4
1
4
4
4
4
4
3
2
1
1
1
1
1
5
1
2
1
7
9
7
2
4
2
1
3
2
7
4
4
4
4
2
6
5
5
2
0
0
0
0
2
4
4
4
B2
A1
A2
A1
E1 − 1
E1 − 1
E1 + 1
A2
E2 + 1
E1 + 1
B2
B1
A1
E1 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E1 − 1
E2 − 1
B1
E2 − 1
E1 − 1
E2 + 1
E1 + 1
B2
E1 + 1
A2
E1 − 1
E2 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
E2 + 1
B2
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
B1
B1
B1
9
9
10
8
8
9
7
9
10
8
4
6
5
9
Obs. Freq. 共unc.兲
共MHz兲
10
11
9
283 515.960 共0.060兲
284 065.688 共0.060兲
7
8
6
285 795.489 共0.060兲
287 185.230 共0.060兲
10
11
9
3
5
4
10
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
279 357.462 共0.018兲
279 702.440 共0.025兲*
279 702.498 共0.025兲*
279 866.780 共0.020兲*
280 054.257 共0.058兲*
280 055.557 共0.012兲*
280 124.509 共0.051兲*
280 522.414 共0.225兲*
280 554.893 共0.361兲*
280 868.172 共0.018兲*
280 912.980 共0.037兲*
280 912.980 共0.037兲*
281 236.808 共0.023兲*
282 609.257 共0.022兲*
282 879.318 共0.020兲*
283 048.390 共0.022兲*
283 048.159 共0.022兲
283 048.492 共0.022兲
283 048.524 共0.022兲
283 136.654 共0.218兲*
283 515.979 共0.033兲*
284 065.621 共0.023兲*
284 122.543 共0.010兲*
284 121.953 共0.010兲
284 122.779 共0.010兲
284 122.918 共0.010兲
284 230.598 共0.027兲*
284 353.497 共0.026兲*
285 770.558 共0.017兲*
285 795.535 共0.020兲*
285 864.980 共0.043兲*
286 289.194 共0.096兲*
286 512.124 共0.047兲*
286 769.309 共0.248兲*
287 013.679 共0.023兲*
287 165.866 共0.017兲*
287 185.255 共0.022兲*
287 664.634 共0.231兲*
287 847.596 共0.259兲*
287 874.396 共0.064兲*
288 035.577 共0.022兲*
288 035.345 共0.022兲
288 035.678 共0.022兲
288 035.710 共0.022兲
288 078.730 共0.404兲*
288 079.971 共0.035兲*
288 124.505 共0.027兲*
288 469.912 共0.027兲*
289 000.109 共0.354兲*
289 136.454 共0.009兲*
289 136.167 共0.009兲
289 136.258 共0.009兲
289 136.931 共0.009兲
289 373.852 共0.032兲*
289 575.187 共0.023兲*
289 840.296 共0.021兲*
289 840.065 共0.021兲
83.350
222.780
222.780
99.597
774.717
92.201
774.840
505.447
477.175
296.314
474.014
474.014
296.270
117.155
296.160
124.960
124.960
124.960
124.960
505.530
126.533
117.062
44.009
44.010
44.009
44.009
441.833
156.624
126.538
99.438
473.874
818.398
473.681
701.965
296.085
126.582
117.144
505.406
701.992
774.670
124.840
124.840
124.840
124.840
702.040
323.775
441.622
441.622
702.096
15.190
15.190
15.190
15.190
126.496
296.086
124.609
124.609
1.905
2.028
2.028
6.689
7.345
1.109
7.324
0.219
0.029
0.065
3.409
3.409
5.093
5.282
0.881
1.181
0.390
0.431
0.352
0.237
3.427
6.722
0.049
0.016
0.018
0.014
5.967
0.689
0.147
6.645
3.412
4.798
3.415
23.861
5.095
0.517
6.877
0.233
24.225
7.336
1.181
0.390
0.431
0.352
24.419
2.549
5.979
5.980
24.488
0.600
0.156
0.236
0.192
3.420
5.106
1.182
0.390
3
1
1
1
3
3
3
1
1
3
3
3
1
3
1
1
1
1
1
3
3
1
3
3
3
3
1
3
1
3
1
3
1
3
3
3
1
3
1
1
3
3
3
3
1
1
3
3
3
1
1
1
1
1
3
3
3
Ref.
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1226
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
9
9
9
9
9
9
23
5
5
5
5
5
5
5
5
13
8
8
8
8
26
9
9
9
9
15
16
20
13
13
12
27
27
27
9
9
9
9
23
13
16
16
28
16
5
5
5
5
29
27
27
16
29
13
29
26
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
2
0
0
0
0
0
0
0
0
0
2
2
8
2
1
2
10
10
10
5
5
5
5
4
2
2
7
5
7
1
1
1
1
3
5
5
2
3
1
3
1
4
B2
B2
B1
B1
B1
B1
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
B1
A1
A2
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
A2
E2 + 1
E1 − 1
A1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
A1
A2
E2 + 1
E2 + 1
E1 − 1
A1
E2 + 1
E2 + 1
10
8
10
10
10
10
10
10
22
6
6
6
6
6
6
6
6
13
7
7
7
7
25
8
8
8
8
15
15
21
13
12
12
28
28
28
10
10
10
10
22
13
15
17
29
17
4
4
4
4
29
26
26
15
29
12
29
26
6
4
4
4
4
4
4
5
3
3
3
3
3
3
3
3
1
1
1
1
1
3
1
1
1
1
1
3
7
1
2
1
9
9
9
4
4
4
4
5
1
3
6
2
6
0
0
0
0
2
6
6
3
2
2
2
0
3
B1
B1
B2
B2
B2
B2
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 + 1
B2
A2
A1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
A1
E2 − 1
E1 − 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
E2 + 1
E2 − 1
E1 − 1
A2
E2 + 1
E2 + 1
11
9
9
10
8
5
6
4
5
6
4
8
9
7
8
10
9
9
10
8
4
6
5
Obs. Freq. 共unc.兲
共MHz兲
10
11
9
6
7
5
6
7
5
7
8
6
7
9
8
293 128.948 共0.060兲
10
11
9
295 463.400 共0.060兲
3
5
4
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
289 840.397 共0.021兲
289 840.429 共0.021兲
289 840.782 共0.021兲*
289 840.551 共0.021兲
289 840.883 共0.021兲
289 840.915 共0.021兲
289 853.935 共0.028兲*
290 127.257 共0.018兲*
290 126.688 共0.018兲
290 127.479 共0.018兲
290 127.631 共0.018兲
290 130.277 共0.018兲*
290 129.707 共0.018兲
290 130.499 共0.018兲
290 130.651 共0.018兲
290 567.800 共0.025兲*
290 684.741 共0.011兲*
290 684.212 共0.011兲
290 684.952 共0.011兲
290 685.078 共0.011兲
290 781.966 共0.224兲*
290 823.825 共0.021兲*
290 823.281 共0.021兲
290 823.431 共0.021兲
290 824.746 共0.021兲
291 405.509 共0.035兲*
291 430.126 共0.026兲*
291 509.841 共0.044兲*
292 349.961 共0.027兲*
293 125.558 共0.027兲*
293 129.026 共0.023兲*
293 421.315 共0.080兲*
293 421.315 共0.080兲*
293 696.744 共0.071兲*
293 898.439 共0.022兲*
293 898.207 共0.022兲
293 898.540 共0.022兲
293 898.572 共0.022兲
294 868.887 共0.026兲*
295 463.358 共0.024兲*
295 768.357 共0.029兲*
295 942.787 共0.036兲*
296 142.661 共0.519兲*
296 256.846 共0.033兲*
296 432.338 共0.009兲*
296 431.954 共0.009兲
296 432.085 共0.009兲
296 432.959 共0.009兲
297 060.763 共0.214兲*
297 759.895 共0.042兲*
297 799.139 共0.042兲*
298 205.869 共0.028兲*
298 309.970 共0.222兲*
298 313.831 共0.022兲*
298 372.370 共0.347兲*
298 428.284 共0.436兲*
298 678.312 共0.017兲*
124.609
124.609
124.609
124.609
124.609
124.609
441.795
55.785
55.785
55.785
55.785
55.785
55.785
55.785
55.785
136.161
43.893
43.894
43.893
43.893
505.387
56.767
56.767
56.767
56.767
178.542
202.163
473.724
136.070
126.293
116.985
818.172
818.172
818.314
124.684
124.684
124.684
124.684
441.744
136.149
202.061
323.555
657.439
323.681
15.086
15.086
15.086
15.086
657.356
616.060
616.060
201.980
657.383
126.210
657.439
515.086
55.574
0.432
0.353
1.182
0.390
0.432
0.353
5.952
0.394
0.128
0.151
0.107
0.394
0.128
0.151
0.107
5.768
0.242
0.079
0.090
0.070
0.261
5.428
1.597
2.000
1.787
0.450
3.008
3.414
6.781
3.283
6.822
4.803
4.803
4.795
1.182
0.390
0.431
0.352
5.952
6.976
1.470
2.551
0.023
2.547
0.153
0.040
0.060
0.049
22.537
6.856
6.856
3.087
23.027
2.902
23.224
0.027
0.394
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
3
3
3
1
1
3
1
1
1
1
1
1
1
1
1
1
3
1
3
3
3
3
3
3
1
1
1
1
3
1
1
1
Ref.
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1227
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
5
5
5
27
5
5
5
5
5
5
5
5
16
23
9
9
9
9
23
29
16
14
28
23
16
16
27
16
13
23
23
9
9
9
9
14
5
5
5
5
16
16
16
27
27
9
9
9
9
12
26
5
5
5
5
14
27
4
4
4
10
4
4
4
4
4
4
4
4
2
4
0
0
0
0
4
3
2
2
5
4
7
7
10
2
2
9
9
0
0
0
0
2
4
4
4
4
7
7
2
10
10
0
0
0
0
6
0
4
4
4
4
2
5
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
B1
B2
E1 + 1
B1
E1 − 1
A1
A2
E2 + 1
A2
B2
B2
B1
B2
B2
B2
B2
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B2
E1 − 1
B1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
B1
5
6
4
6
6
6
28
6
6
6
6
6
6
6
6
16
22
8
8
8
8
22
29
15
14
29
22
17
17
28
15
13
24
24
8
8
8
8
14
6
6
6
6
17
17
15
28
28
8
8
8
8
13
25
6
6
6
6
14
26
3
3
3
9
3
3
3
3
3
3
3
3
1
5
1
1
1
1
5
2
3
1
2
5
6
6
9
3
1
8
8
1
1
1
1
1
3
3
3
3
6
6
3
9
9
1
1
1
1
5
3
3
3
3
3
1
6
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
B2
B1
E1 − 1
B2
E1 − 1
A2
A1
E2 + 1
A1
B1
B1
B2
B1
B1
B1
B1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B1
E1 + 1
B2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
B2
6
7
5
5
6
4
5
6
4
8
10
9
8
10
9
5
6
4
8
10
9
5
6
4
Obs. Freq. 共unc.兲
共MHz兲
6
7
5
6
7
5
7
9
8
7
9
8
6
7
5
7
9
8
6
7
5
304 768.006 共0.060兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
298 677.743 共0.017兲
298 678.534 共0.017兲
298 678.685 共0.017兲
298 680.735 共0.082兲*
298 817.340 共0.017兲*
298 816.772 共0.017兲
298 817.562 共0.017兲
298 817.713 共0.017兲
298 820.426 共0.017兲*
298 819.857 共0.017兲
298 820.648 共0.017兲
298 820.799 共0.017兲
298 865.819 共0.047兲*
298 971.625 共0.026兲*
299 189.760 共0.012兲*
299 189.217 共0.012兲
299 189.367 共0.012兲
299 190.679 共0.012兲
299 309.598 共0.025兲*
299 313.549 共0.304兲*
299 387.174 共0.036兲*
299 638.450 共0.030兲*
299 716.458 共0.491兲*
300 124.496 共0.030兲*
300 589.620 共0.038兲*
300 589.624 共0.038兲*
300 863.579 共0.112兲*
301 247.502 共0.038兲*
301 425.201 共0.025兲*
301 596.505 共0.059兲*
301 596.505 共0.059兲*
301 653.833 共0.022兲*
301 653.287 共0.022兲
301 653.438 共0.022兲
301 654.757 共0.022兲
301 705.652 共0.031兲*
302 465.058 共0.017兲*
302 464.489 共0.017兲
302 465.280 共0.017兲
302 465.431 共0.017兲
302 801.831 共0.041兲*
302 801.834 共0.041兲*
302 866.830 共0.026兲*
302 988.856 共0.077兲*
302 988.856 共0.077兲*
303 734.501 共0.010兲*
303 733.981 共0.010兲
303 734.124 共0.010兲
303 735.383 共0.010兲
303 922.504 共0.030兲*
304 407.180 共0.298兲*
304 629.905 共0.017兲*
304 629.336 共0.017兲
304 630.127 共0.017兲
304 630.278 共0.017兲
304 767.960 共0.026兲*
306 023.059 共0.043兲*
55.574
55.574
55.574
818.319
55.684
55.684
55.684
55.684
55.684
55.684
55.684
55.684
201.915
441.440
56.785
56.785
56.785
56.785
441.440
657.496
202.179
156.624
657.496
441.598
323.720
323.720
818.223
202.081
135.990
616.212
616.212
56.610
56.610
56.610
56.610
156.534
55.756
55.756
55.756
55.756
323.618
323.618
201.781
817.993
817.993
56.736
56.736
56.736
56.736
202.399
504.847
55.652
55.652
55.652
55.652
156.611
615.962
0.128
0.151
0.107
4.795
0.394
0.128
0.151
0.107
0.394
0.128
0.151
0.107
0.288
5.983
5.353
1.574
1.972
1.762
5.984
23.286
4.535
6.084
0.025
5.960
2.547
2.547
4.799
4.550
6.910
3.935
3.935
5.415
1.593
1.995
1.783
6.752
0.393
0.127
0.151
0.107
2.548
2.548
1.558
4.804
4.804
5.207
1.531
1.918
1.714
1.698
0.020
0.394
0.128
0.151
0.107
6.991
6.851
1
1
1
3
1
1
1
1
1
1
1
1
3
1
3
3
3
3
1
3
3
3
3
3
1
1
1
1
3
3
3
39
3
3
3
1
3
3
3
3
3
3
3
3
3
1
1
1
1
1
3
1
1
1
1
1
3
Ref.
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1228
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
27
27
16
17
5
5
5
5
28
7
7
7
7
7
7
7
7
7
7
7
7
27
7
7
7
7
27
5
5
5
5
28
28
12
27
28
27
5
5
5
5
20
15
7
7
7
7
7
7
7
7
7
7
7
7
7
7
5
0
7
2
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
5
1
1
1
1
5
1
1
1
1
3
3
1
0
3
5
4
4
4
4
3
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
B2
A2
E2 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
B2
B2
B2
B2
A2
E2 + 1
B1
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
F⬘
5
6
4
8
6
7
8
6
7
8
6
7
8
6
7
5
6
4
5
6
4
8
6
7
8
6
7
8
6
7
8
J⬙
K⬙a
⌫⬙
26
26
17
17
4
4
4
4
28
6
6
6
6
6
6
6
6
6
6
6
6
26
6
6
6
6
26
4
4
4
4
28
28
11
26
28
26
6
6
6
6
19
15
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
3
6
1
0
0
0
0
2
1
1
1
1
1
1
1
1
1
1
1
1
6
1
1
1
1
6
0
0
0
0
2
2
2
3
2
6
3
3
3
3
4
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
B1
A1
E2 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
B1
B1
B1
B1
A1
E2 − 1
B2
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
4
5
3
7
5
6
7
5
6
7
5
6
7
5
6
307 791.746 共0.060兲
4
5
3
308 739.484 共0.060兲
6
7
5
309 908.988 共0.060兲
7
5
6
309 914.410 共0.060兲
7
5
6
309 921.089 共0.060兲
7
5
6
309 931.604 共0.060兲
7
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
306 061.728 共0.043兲*
306 299.517 共0.273兲*
306 309.042 共0.040兲*
306 743.215 共0.063兲*
306 877.535 共0.008兲*
306 876.886 共0.008兲
306 877.772 共0.008兲
306 877.999 共0.008兲
306 946.945 共0.183兲*
307 142.583 共0.007兲*
307 142.560 共0.007兲
307 142.600 共0.007兲
307 142.600 共0.007兲
307 142.616 共0.007兲*
307 142.594 共0.007兲
307 142.634 共0.007兲
307 142.634 共0.007兲
307 231.103 共0.007兲*
307 231.075 共0.007兲
307 231.112 共0.007兲
307 231.132 共0.007兲
307 323.807 共0.048兲*
307 536.836 共0.007兲*
307 536.796 共0.007兲
307 536.823 共0.007兲
307 536.899 共0.007兲
307 750.115 共0.037兲*
307 791.754 共0.012兲*
307 790.911 共0.012兲
307 792.065 共0.012兲
307 792.347 共0.012兲
308 290.051 共0.298兲*
308 409.328 共0.191兲*
308 739.522 共0.025兲*
308 916.506 共0.264兲*
309 259.391 共0.261兲*
309 356.365 共0.044兲*
309 512.362 共0.016兲*
309 511.794 共0.016兲
309 512.584 共0.016兲
309 512.735 共0.016兲
309 661.580 共0.029兲*
309 889.435 共0.035兲*
309 908.963 共0.007兲*
309 908.943 共0.007兲
309 908.960 共0.007兲
309 908.992 共0.007兲
309 914.382 共0.007兲*
309 914.362 共0.007兲
309 914.379 共0.007兲
309 914.411 共0.007兲
309 921.059 共0.007兲*
309 921.040 共0.007兲
309 921.056 共0.007兲
309 921.087 共0.007兲
309 931.539 共0.007兲*
309 931.519 共0.007兲
615.962
543.944
323.361
226.742
15.190
15.190
15.190
15.190
614.224
33.601
33.601
33.601
33.601
33.759
33.759
33.759
33.760
33.761
33.761
33.761
33.761
615.894
33.635
33.635
33.635
33.635
616.112
14.992
14.992
14.992
14.992
614.316
614.251
108.971
544.025
614.372
616.021
55.371
55.371
55.371
55.371
324.542
178.542
31.443
31.443
31.443
31.443
31.340
31.340
31.340
31.340
31.246
31.246
31.246
31.246
31.040
31.040
6.851
0.227
2.551
0.184
4.068
1.302
1.603
1.055
21.232
0.646
0.244
0.182
0.211
0.647
0.244
0.182
0.211
0.646
0.244
0.182
0.211
6.850
0.644
0.243
0.182
0.210
6.827
4.671
1.495
1.840
1.211
22.104
21.901
4.559
0.246
22.160
6.842
0.394
0.128
0.151
0.107
0.121
6.226
0.661
0.250
0.186
0.216
0.658
0.249
0.186
0.215
0.662
0.250
0.187
0.216
0.658
0.248
3
1
1
3
1
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
1
1
1
3
3
3
3
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
Ref.
1
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1229
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
0
0
6
6
6
6
2
2
2
2
6
6
6
6
6
6
6
6
6
6
6
6
2
2
2
2
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
6
7
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
0
0
6
6
6
6
2
2
2
2
6
6
6
6
6
6
6
6
6
6
6
6
2
2
2
2
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
A1
A1
A1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
5
6
6
8
7
8
6
7
6
8
7
6
8
7
6
8
7
8
6
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
5
7
6
7
5
6
5
7
6
5
7
6
5
7
6
7
5
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
309 931.536 共0.007兲
309 931.566 共0.007兲
310 248.275 共0.017兲*
310 248.017 共0.017兲
310 248.127 共0.017兲
310 248.660 共0.017兲
310 250.638 共0.007兲*
310 250.613 共0.007兲
310 250.618 共0.007兲
310 250.686 共0.007兲
310 251.643 共0.016兲*
310 251.386 共0.016兲
310 251.496 共0.016兲
310 252.029 共0.016兲
310 251.774 共0.017兲*
310 251.517 共0.017兲
310 251.627 共0.017兲
310 252.160 共0.017兲
310 251.774 共0.017兲*
310 251.517 共0.017兲
310 251.627 共0.017兲
310 252.160 共0.017兲
310 251.924 共0.007兲*
310 251.899 共0.007兲
310 251.903 共0.007兲
310 251.972 共0.007兲
310 253.846 共0.017兲*
310 253.589 共0.017兲
310 253.698 共0.017兲
310 254.231 共0.017兲
310 253.995 共0.017兲*
310 253.738 共0.017兲
310 253.848 共0.017兲
310 254.381 共0.017兲
310 253.995 共0.017兲*
310 253.738 共0.017兲
310 253.848 共0.017兲
310 254.381 共0.017兲
310 254.992 共0.017兲*
310 254.735 共0.017兲
310 254.844 共0.017兲
310 255.377 共0.017兲
310 279.636 共0.013兲*
310 279.461 共0.013兲
310 279.531 共0.013兲
310 279.903 共0.013兲
310 279.636 共0.013兲*
310 279.461 共0.013兲
310 279.531 共0.013兲
310 279.903 共0.013兲
310 280.743 共0.013兲*
310 280.569 共0.013兲
310 280.639 共0.013兲
310 281.010 共0.013兲
310 284.084 共0.013兲*
310 283.909 共0.013兲
310 283.979 共0.013兲
31.040
31.040
128.477
128.477
128.477
128.477
42.299
42.299
42.299
42.299
128.696
128.696
128.696
128.696
128.640
128.640
128.640
128.640
128.640
128.640
128.640
128.640
42.261
42.261
42.261
42.261
128.279
128.279
128.279
128.279
128.536
128.536
128.536
128.536
128.536
128.536
128.536
128.536
128.600
128.600
128.600
128.600
98.794
98.794
98.794
98.794
98.794
98.794
98.794
98.794
98.917
98.917
98.917
98.917
99.003
99.003
99.003
0.185
0.215
0.175
0.049
0.066
0.057
0.606
0.229
0.171
0.198
0.175
0.049
0.066
0.057
0.175
0.049
0.066
0.057
0.175
0.049
0.066
0.057
0.606
0.229
0.171
0.1981
0.176
0.050
0.066
0.057
0.175
0.049
0.066
0.057
0.175
0.049
0.066
0.057
0.175
0.049
0.066
0.057
0.323
0.091
0.122
0.105
0.323
0.091
0.122
0.105
0.323
0.091
0.122
0.105
0.323
0.091
0.122
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
7
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
37
3
3
3
3
3
3
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1230
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
7
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
6
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
310 284.351 共0.013兲
310 284.535 共0.012兲*
310 284.361 共0.012兲
310 284.431 共0.012兲
310 284.803 共0.012兲
310 284.846 共0.013兲*
310 284.671 共0.013兲
310 284.741 共0.013兲
310 285.113 共0.013兲
310 284.846 共0.013兲*
310 284.671 共0.013兲
310 284.741 共0.013兲
310 285.113 共0.013兲
310 285.504 共0.013兲*
310 285.329 共0.013兲
310 285.399 共0.013兲
310 285.771 共0.013兲
310 310.701 共0.010兲*
310 310.594 共0.010兲
310 310.632 共0.010兲
310 310.870 共0.010兲
310 310.720 共0.010兲*
310 310.613 共0.010兲
310 310.651 共0.010兲
310 310.890 共0.010兲
310 312.027 共0.010兲*
310 311.921 共0.010兲
310 311.958 共0.010兲
310 312.197 共0.010兲
310 314.281 共0.009兲*
310 314.175 共0.009兲
310 314.212 共0.009兲
310 314.451 共0.009兲
310 315.832 共0.010兲*
310 315.726 共0.010兲
310 315.763 共0.010兲
310 316.002 共0.010兲
310 316.306 共0.010兲*
310 316.199 共0.010兲
310 316.237 共0.010兲
310 316.476 共0.010兲
310 316.546 共0.010兲*
310 316.440 共0.010兲
310 316.477 共0.010兲
310 316.716 共0.010兲
310 316.566 共0.010兲*
310 316.459 共0.010兲
310 316.497 共0.010兲
310 316.735 共0.010兲
310 349.885 共0.008兲*
310 349.832 共0.008兲
310 349.844 共0.008兲
310 349.978 共0.008兲
310 351.214 共0.008兲*
310 351.161 共0.008兲
310 351.174 共0.008兲
310 351.307 共0.008兲
99.003
98.964
98.964
98.964
98.964
98.604
98.604
98.604
98.604
98.604
98.604
98.604
98.604
98.766
98.766
98.766
98.766
74.524
74.524
74.524
74.524
74.524
74.524
74.524
74.524
74.567
74.567
74.567
74.567
74.718
74.718
74.718
74.718
74.686
74.686
74.686
74.686
74.410
74.410
74.410
74.410
74.335
74.335
74.335
74.335
74.335
74.335
74.335
74.335
55.785
55.785
55.785
55.785
55.574
55.574
55.574
55.574
0.1061
0.323
0.091
0.122
0.106
0.324
0.091
0.122
0.106
0.324
0.091
0.122
0.1061
0.324
0.091
0.122
0.106
0.444
0.125
0.168
0.145
0.444
0.125
0.168
0.145
0.444
0.125
0.168
0.145
0.444
0.125
0.168
0.145
0.444
0.125
0.168
0.145
0.444
0.125
0.168
0.145
0.444
0.125
0.168
0.1453
0.444
0.125
0.168
0.145
0.539
0.152
0.204
0.176
0.539
0.152
0.204
0.1761
7
3
3
3
3
1
1
1
1
1
1
1
7
3
37
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
7
3
3
3
3
3
3
3
3
1
1
1
7
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1231
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
23
7
7
7
7
7
7
7
7
7
7
7
7
5
5
5
5
7
7
7
7
7
7
7
7
14
23
23
23
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
9
2
2
2
2
2
2
2
2
2
2
2
2
1
1
1
1
2
2
2
2
2
2
2
2
2
9
9
9
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
B1
A2
A1
E1 − 1
F⬘
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
8
6
7
8
6
7
8
6
7
8
6
7
5
6
4
8
6
7
8
6
7
J⬙
K⬙a
⌫⬙
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
24
6
6
6
6
6
6
6
6
6
6
6
6
4
4
4
4
6
6
6
6
6
6
6
6
14
24
24
24
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
8
2
2
2
2
2
2
2
2
2
2
2
2
0
0
0
0
2
2
2
2
2
2
2
2
1
8
8
8
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
B2
A1
A2
E1 − 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
5
7
6
310 378.150 共0.060兲
7
5
6
310 441.820 共0.060兲
7
5
6
7
5
6
7
5
6
4
5
3
310 638.549 共0.060兲
7
5
6
310 642.098 共0.060兲
7
5
6
310 750.839 共0.060兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
310 353.095 共0.008兲*
310 353.042 共0.008兲
310 353.054 共0.008兲
310 353.188 共0.008兲
310 353.788 共0.008兲*
310 353.734 共0.008兲
310 353.747 共0.008兲
310 353.881 共0.008兲
310 354.413 共0.008兲*
310 354.360 共0.008兲
310 354.373 共0.008兲
310 354.506 共0.008兲
310 355.787 共0.008兲*
310 355.734 共0.008兲
310 355.746 共0.008兲
310 355.880 共0.008兲
310 357.890 共0.008兲*
310 357.838 共0.008兲
310 357.850 共0.008兲
310 357.983 共0.008兲
310 358.415 共0.008兲*
310 358.362 共0.008兲
310 358.374 共0.008兲
310 358.507 共0.008兲
310 378.210 共0.007兲*
310 378.185 共0.007兲
310 378.189 共0.007兲
310 378.258 共0.007兲
310 440.904 共0.072兲*
310 441.832 共0.007兲*
310 441.812 共0.007兲
310 441.818 共0.007兲
310 441.868 共0.007兲
310 462.980 共0.007兲*
310 462.963 共0.007兲
310 462.970 共0.007兲
310 463.011 共0.007兲
310 527.923 共0.007兲*
310 527.911 共0.007兲
310 527.920 共0.007兲
310 527.942 共0.007兲
310 527.984 共0.009兲*
310 527.190 共0.009兲
310 528.275 共0.009兲
310 528.543 共0.009兲
310 638.570 共0.007兲*
310 638.557 共0.007兲
310 638.565 共0.007兲
310 638.590 共0.007兲
310 642.112 共0.007兲*
310 642.100 共0.007兲
310 642.107 共0.007兲
310 642.132 共0.007兲
310 750.920 共0.028兲*
311 206.720 共0.060兲*
311 206.720 共0.060兲*
311 848.459 共0.053兲*
55.756
55.756
55.756
55.756
55.684
55.684
55.684
55.684
55.785
55.785
55.785
55.785
55.652
55.652
55.652
55.652
55.371
55.371
55.371
55.371
55.684
55.684
55.684
55.684
42.040
42.040
42.040
42.040
616.239
41.905
41.905
41.905
41.905
42.197
42.197
42.197
42.197
42.100
42.100
42.100
42.100
15.086
15.086
15.086
15.086
42.277
42.277
42.277
42.277
42.315
42.315
42.315
42.315
156.452
616.074
616.074
616.277
0.539
0.152
0.204
0.176
0.538
0.152
0.203
0.176
0.539
0.152
0.204
0.176
0.538
0.152
0.203
0.176
0.538
0.152
0.203
0.176
0.538
0.152
0.203
0.176
0.599
0.226
0.169
0.196
3.932
0.605
0.228
0.171
0.197
0.606
0.229
0.171
0.198
0.600
0.227
0.169
0.196
4.516
1.445
1.779
1.171
0.606
0.229
0.171
0.198
0.606
0.229
0.171
0.198
6.913
3.933
3.933
3.928
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
3
Ref.
1
1
1
1
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1232
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
12
15
23
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
27
12
16
20
12
12
18
15
12
12
20
27
27
27
16
27
27
27
12
5
5
5
5
27
12
16
16
20
19
19
19
2
2
2
2
2
2
16
6
2
9
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
6
2
3
6
1
2
2
6
6
3
0
3
1
2
5
3
3
1
1
1
1
1
3
1
2
2
3
8
8
8
2
2
2
2
2
2
2
E1 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
E1 + 1
E2 + 1
E1 + 1
E1 + 1
E1 − 1
A1
E1 − 1
A2
B1
B2
E2 + 1
E2 + 1
E1 + 1
E2 + 1
E2 − 1
E2 − 1
A1
E2 + 1
E2 + 1
A2
A2
A2
A2
B1
E1 + 1
B1
E2 − 1
E2 − 1
E1 + 1
A2
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
F⬘
7
8
6
6
8
7
6
8
7
6
8
7
5
6
4
2
1
2
3
1
J⬙
K⬙a
⌫⬙
13
15
24
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
26
13
15
19
13
11
18
15
13
13
19
26
27
27
15
26
27
27
11
4
4
4
4
27
11
15
15
19
20
20
20
1
1
1
1
1
1
15
5
1
8
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
5
3
4
5
2
1
1
5
5
4
3
2
0
3
6
2
2
2
0
0
0
0
2
2
3
3
4
7
7
7
1
1
1
1
1
1
3
E1 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
E1 − 1
E2 + 1
E1 − 1
E1 + 1
E1 − 1
A2
E1 − 1
A1
B2
B1
E2 − 1
E2 − 1
E1 + 1
E2 + 1
E2 − 1
E2 − 1
A2
E2 − 1
E2 − 1
A1
A1
A1
A1
B2
E1 + 1
B2
E2 + 1
E2 − 1
E1 + 1
A1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
6
7
5
313 204.773 共0.060兲
5
7
6
5
7
6
5
7
6
4
5
3
2
0
1
2
1
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
312 109.362 共0.033兲*
312 191.346 共0.036兲*
312 825.538 共0.066兲*
312 904.397 共0.007兲*
312 904.370 共0.007兲
312 904.409 共0.007兲
312 904.412 共0.007兲
313 204.761 共0.007兲*
313 204.753 共0.007兲
313 204.760 共0.007兲
313 204.768 共0.007兲
313 292.279 共0.007兲*
313 292.264 共0.007兲
313 292.274 共0.007兲
313 292.298 共0.007兲
313 302.982 共0.007兲*
313 302.967 共0.007兲
313 302.977 共0.007兲
313 303.000 共0.007兲
313 459.474 共0.276兲*
313 789.939 共0.031兲*
313 937.402 共0.030兲*
314 133.232 共0.020兲*
314 315.004 共0.033兲*
314 543.168 共0.023兲*
315 045.248 共0.083兲*
315 163.227 共0.029兲*
315 342.215 共0.029兲*
315 342.242 共0.029兲*
315 697.393 共0.026兲*
316 251.551 共0.269兲*
316 382.365 共0.157兲*
316 758.281 共0.523兲*
316 878.972 共0.033兲*
317 181.277 共0.049兲*
317 794.500 共0.256兲*
318 106.900 共0.163兲*
318 661.075 共0.016兲*
318 709.124 共0.012兲*
318 708.282 共0.012兲
318 709.435 共0.012兲
318 709.716 共0.012兲
318 799.634 共0.224兲*
318 808.818 共0.011兲*
319 027.367 共0.032兲*
319 316.483 共0.033兲*
319 958.016 共0.029兲*
320 148.149 共0.050兲*
320 178.387 共0.055兲*
320 178.387 共0.055兲*
320 436.586 共0.014兲*
320 435.892 共0.014兲
320 436.329 共0.014兲
320 436.410 共0.014兲
320 436.673 共0.014兲
320 437.626 共0.014兲
320 651.153 共0.035兲*
202.447
178.454
616.066
34.367
34.367
34.367
34.367
34.399
34.399
34.399
34.399
34.376
34.376
34.376
34.376
34.218
34.218
34.218
34.218
543.895
202.486
202.163
324.393
202.249
108.932
253.021
178.528
202.275
202.275
324.511
543.885
572.572
554.435
202.061
615.707
572.671
572.598
108.745
14.786
14.786
14.786
14.786
572.728
108.803
202.201
201.980
324.511
442.852
443.036
443.036
4.592
4.592
4.592
4.592
4.592
4.592
202.103
1.696
6.645
3.935
0.644
0.210
0.243
0.182
0.646
0.182
0.244
0.211
0.647
0.183
0.245
0.211
0.645
0.182
0.244
0.211
0.249
1.695
1.634
5.386
1.697
4.530
0.117
6.927
1.697
1.697
1.257
0.272
19.921
0.024
3.183
6.859
21.054
20.837
4.359
4.674
1.496
1.841
1.212
21.104
3.570
4.696
1.532
4.238
3.072
3.069
3.069
0.018
0.002
0.002
0.005
0.008
0.002
4.720
3
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
1
3
3
3
1
3
1
3
3
1
1
3
1
1
1
1
1
1
1
1
1
1
3
3
3
1
1
3
1
1
3
3
3
3
3
3
1
Ref.
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1233
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
23
14
15
14
20
16
8
8
8
8
8
8
8
8
8
8
8
8
14
30
20
30
2
2
2
2
2
2
19
20
16
12
12
12
19
19
26
16
2
2
2
2
2
2
20
20
16
26
14
26
8
8
8
8
29
26
20
9
1
2
1
3
2
5
5
5
5
5
5
5
5
5
5
5
5
1
3
3
3
2
2
2
2
2
2
2
3
2
6
6
1
8
8
3
2
2
2
2
2
2
2
3
3
2
3
1
3
5
5
5
5
3
3
3
E1 + 1
E2 − 1
B2
B2
E1 − 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E2 − 1
A2
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E2 + 1
E2 − 1
A1
A2
E2 + 1
B2
B1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A2
A2
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
E2 − 1
F⬘
8
9
7
8
9
7
8
9
7
2
2
1
3
1
2
2
3
1
1
8
9
7
J⬙
K⬙a
⌫⬙
24
13
15
13
19
16
9
9
9
9
9
9
9
9
9
9
9
9
13
30
19
30
1
1
1
1
1
1
19
19
16
13
13
11
20
20
26
15
1
1
1
1
1
1
19
19
16
26
13
26
9
9
9
9
29
26
19
8
2
1
2
4
1
4
4
4
4
4
4
4
4
4
4
4
4
2
2
4
2
1
1
1
1
1
1
1
4
1
5
5
2
7
7
2
3
1
1
1
1
1
1
4
4
1
2
2
2
4
4
4
4
2
2
4
E1 + 1
E2 − 1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 + 1
E2 − 1
A1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E2 + 1
E2 − 1
A2
A1
E2 + 1
B1
B2
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
A2
A2
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
9
10
8
9
10
8
9
10
8
2
1
0
2
1
2
1
2
0
1
326 708.830 共0.060兲
9
10
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
321 033.209 共0.068兲*
321 149.234 共0.020兲*
321 170.160 共0.031兲*
321 338.491 共0.043兲*
321 367.056 共0.027兲*
321 373.094 共0.041兲*
321 916.667 共0.026兲*
321 916.367 共0.026兲
321 916.796 共0.026兲
321 916.844 共0.026兲
322 874.824 共0.022兲*
322 874.524 共0.022兲
322 874.952 共0.022兲
322 875.000 共0.022兲
322 875.028 共0.022兲*
322 874.728 共0.022兲
322 875.156 共0.022兲
322 875.204 共0.022兲
322 881.287 共0.020兲*
322 916.303 共0.301兲*
323 024.579 共0.024兲*
323 366.371 共0.297兲*
323 462.032 共0.014兲*
323 461.353 共0.014兲
323 461.782 共0.014兲
323 461.925 共0.014兲
323 462.134 共0.014兲
323 462.998 共0.014兲
323 776.520 共0.108兲*
323 832.507 共0.020兲*
323 862.249 共0.042兲*
324 063.155 共0.030兲*
324 063.183 共0.030兲*
324 077.367 共0.012兲*
325 220.113 共0.046兲*
325 220.113 共0.046兲*
325 324.606 共0.133兲*
325 374.106 共0.029兲*
325 531.483 共0.011兲*
325 530.841 共0.011兲
325 531.047 共0.011兲
325 531.623 共0.011兲
325 531.749 共0.011兲
325 532.262 共0.011兲
325 838.709 共0.023兲*
326 536.013 共0.029兲*
326 708.787 共0.032兲*
326 850.896 共0.219兲*
327 185.995 共0.041兲*
327 365.768 共0.139兲*
327 413.595 共0.025兲*
327 413.295 共0.025兲
327 413.723 共0.025兲
327 413.772 共0.025兲
327 574.067 共0.254兲*
327 898.659 共0.192兲*
328 093.131 共0.026兲*
615.890
145.822
178.370
145.734
324.542
201.915
110.206
110.206
110.206
110.206
110.012
110.012
110.012
110.012
110.012
110.012
110.012
110.012
145.853
701.992
324.347
701.965
4.626
4.626
4.626
4.626
4.626
4.626
280.752
324.240
201.828
202.087
202.087
108.564
443.009
443.009
532.401
201.781
4.422
4.422
4.422
4.422
4.422
4.422
324.393
324.350
201.901
532.509
145.697
532.426
110.174
110.174
110.174
110.174
657.383
532.564
324.240
3.937
0.104
6.837
3.685
5.359
6.221
0.875
0.288
0.322
0.257
0.875
0.288
0.322
0.257
0.875
0.288
0.322
0.257
0.378
0.019
5.488
0.343
2.377
0.198
0.594
0.264
1.109
0.198
0.074
4.243
6.470
1.697
1.697
0.239
3.067
3.067
18.581
3.093
2.362
0.197
0.591
1.102
0.262
0.197
0.124
5.502
6.791
20.065
3.677
19.824
0.874
0.288
0.322
0.257
0.029
20.110
1.266
3
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
1
1
3
1
1
1
1
1
1
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
3
1
Ref.
1
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1234
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
29
12
24
2
2
2
2
2
2
19
10
10
10
10
26
28
19
14
9
9
9
9
20
6
6
6
6
8
8
8
8
15
28
24
16
20
28
24
28
25
2
2
2
2
2
2
17
8
8
8
8
8
8
8
8
17
2
3
1
4
2
2
2
2
2
2
8
0
0
0
0
10
0
8
1
0
0
0
0
3
1
1
1
1
5
5
5
5
7
3
4
2
2
0
4
3
3
2
2
2
2
2
2
2
5
5
5
5
5
5
5
5
2
2
E1 − 1
E1 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A1
A1
A1
A1
E1 − 1
A1
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 − 1
B2
B1
E1 − 1
B1
B1
E1 − 1
E1 + 1
A1
A1
A1
A1
A1
A1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 − 1
E1 + 1
F⬘
2
1
2
3
1
9
11
10
9
10
8
5
7
6
8
9
7
1
2
3
2
1
8
9
7
8
9
7
J⬙
K⬙a
⌫⬙
29
11
23
1
1
1
1
1
1
20
9
9
9
9
27
27
20
13
8
8
8
8
19
5
5
5
5
9
9
9
9
16
28
23
16
20
27
23
28
25
1
1
1
1
1
1
17
9
9
9
9
9
9
9
9
16
1
2
2
5
1
1
1
1
1
1
7
1
1
1
1
9
3
7
2
1
1
1
1
4
0
0
0
0
4
4
4
4
6
2
5
1
1
3
5
2
2
1
1
1
1
1
1
1
4
4
4
4
4
4
4
4
3
1
E1 + 1
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
A2
A2
A2
A2
E1 − 1
A2
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 − 1
B1
B2
E1 − 1
B2
B2
E1 + 1
E1 + 1
A2
A2
A2
A2
A2
A2
E1 − 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 − 1
E1 − 1
F⬙
2
0
1
2
1
8
10
9
8
9
7
4
6
5
9
10
8
0
2
2
1
1
9
10
8
9
10
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
328 111.452 共0.251兲*
328 837.384 共0.014兲*
328 903.531 共0.036兲*
329 198.371 共0.013兲*
329 197.677 共0.013兲
329 198.114 共0.013兲
329 198.196 共0.013兲
329 198.458 共0.013兲
329 199.411 共0.013兲
330 155.440 共0.052兲*
330 264.707 共0.025兲*
330 264.159 共0.025兲
330 264.297 共0.025兲
330 265.651 共0.025兲
330 478.574 共0.108兲*
330 516.719 共0.328兲*
330 822.820 共0.058兲*
330 984.304 共0.036兲*
331 167.228 共0.011兲*
331 166.652 共0.011兲
331 167.464 共0.011兲
331 167.582 共0.011兲
331 374.945 共0.028兲*
331 449.141 共0.010兲*
331 448.809 共0.010兲
331 448.909 共0.010兲
331 449.694 共0.010兲
332 392.245 共0.025兲*
332 391.945 共0.025兲
332 392.373 共0.025兲
332 392.421 共0.025兲
332 398.865 共0.041兲*
332 626.377 共0.213兲*
332 720.112 共0.037兲*
332 742.153 共0.035兲*
332 938.358 共0.139兲*
333 146.350 共0.317兲*
333 200.881 共0.037兲*
333 284.784 共0.211兲*
333 736.923 共0.113兲*
333 839.329 共0.012兲*
333 837.821 共0.012兲
333 838.506 共0.012兲
333 839.292 共0.012兲
333 839.778 共0.012兲
333 841.000 共0.012兲
334 130.937 共0.049兲*
334 209.791 共0.024兲*
334 209.491 共0.024兲
334 209.919 共0.024兲
334 209.967 共0.024兲
334 210.000 共0.024兲*
334 209.700 共0.024兲
334 210.128 共0.024兲
334 210.176 共0.024兲
334 252.154 共0.033兲*
334 293.269 共0.010兲*
657.356
108.469
475.798
4.592
4.592
4.592
4.592
4.592
4.592
442.868
70.199
70.199
70.199
70.199
777.119
583.929
442.675
145.494
55.719
55.719
55.719
55.719
324.164
22.579
22.579
22.579
22.579
110.055
110.055
110.055
110.055
298.660
614.251
475.588
201.743
309.934
584.007
475.588
614.224
493.715
4.509
4.509
4.509
4.509
4.509
4.509
226.742
109.823
109.823
109.823
109.823
109.823
109.823
109.823
109.823
225.824
4.422
0.482
1.021
6.366
2.363
0.197
0.263
0.591
1.103
0.197
3.069
5.910
1.763
2.157
1.950
4.451
0.232
3.072
3.581
0.033
0.011
0.012
0.010
5.502
0.428
0.117
0.165
0.139
0.875
0.288
0.322
0.257
2.215
0.042
6.382
6.690
0.047
0.252
6.383
0.678
17.200
2.386
0.265
0.199
1.114
0.597
0.199
6.100
0.875
0.288
0.322
0.257
0.875
0.288
0.322
0.257
3.027
0.017
3
3
1
3
3
3
3
3
3
1
1
1
1
1
3
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
3
3
3
3
3
3
3
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1235
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
2
2
2
2
2
4
4
4
4
4
4
4
4
24
2
2
2
2
2
2
20
25
28
14
19
25
25
17
2
2
2
2
2
2
9
9
9
9
26
26
28
26
27
8
8
8
8
6
6
6
6
17
10
10
10
10
27
2
2
2
2
2
4
4
4
4
4
4
4
4
4
2
2
2
2
2
2
3
3
1
1
8
3
3
2
2
2
2
2
2
2
0
0
0
0
10
10
0
10
3
5
5
5
5
1
1
1
1
2
0
0
0
0
3
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
A2
A2
A2
A2
A2
A2
B1
A1
E2 + 1
E1 − 1
E1 − 1
E2 + 1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A1
E1 + 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
2
2
3
1
1
1
1
1
1
1
5
5
5
5
5
5
5
5
23
1
1
1
1
1
1
19
25
28
13
20
25
25
17
1
1
1
1
1
1
8
8
8
8
27
27
27
27
27
9
9
9
9
5
5
5
5
16
9
9
9
9
27
1
1
1
1
1
3
3
3
3
3
3
3
3
5
1
1
1
1
1
1
4
2
0
2
7
2
2
1
1
1
1
1
1
1
1
1
1
1
9
9
3
9
2
4
4
4
4
0
0
0
0
3
1
1
1
1
2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
A1
A1
A1
A1
A1
A1
B2
A2
E2 + 1
E1 − 1
E1 − 1
E2 − 1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A2
E1 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
2
1
2
0
1
4
5
3
4
5
3
2
2
1
3
1
2
2
1
3
1
9
10
8
8
9
7
5
7
6
9
11
10
5
6
4
5
6
4
1
2
1
2
0
2
1
0
2
1
8
9
7
9
10
8
4
6
5
8
10
9
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
334 292.627 共0.010兲
334 292.832 共0.010兲
334 293.408 共0.010兲
334 293.534 共0.010兲
334 294.047 共0.010兲
334 481.458 共0.020兲*
334 480.560 共0.020兲
334 481.785 共0.020兲
334 482.096 共0.020兲
334 482.465 共0.020兲*
334 481.567 共0.020兲
334 482.792 共0.020兲
334 483.103 共0.020兲
334 490.127 共0.037兲*
334 712.252 共0.012兲*
334 711.192 共0.012兲
334 711.740 共0.012兲
334 712.399 共0.012兲
334 712.515 共0.012兲
334 713.768 共0.012兲
334 812.311 共0.029兲*
335 427.203 共0.187兲*
335 464.560 共0.622兲*
335 745.086 共0.030兲*
335 817.694 共0.054兲*
336 151.066 共0.119兲*
336 523.557 共0.165兲*
336 767.741 共0.051兲*
337 119.299 共0.011兲*
337 118.642 共0.011兲
337 118.937 共0.011兲
337 119.415 共0.011兲
337 119.423 共0.011兲
337 120.152 共0.011兲
337 495.495 共0.013兲*
337 494.960 共0.013兲
337 495.714 共0.013兲
337 495.825 共0.013兲
337 597.504 共0.092兲*
337 597.504 共0.092兲*
337 636.254 共0.326兲*
337 917.876 共0.083兲*
337 977.932 共0.178兲*
338 262.488 共0.025兲*
338 262.189 共0.025兲
338 262.616 共0.025兲
338 262.665 共0.025兲
338 333.619 共0.009兲*
338 333.227 共0.009兲
338 333.350 共0.009兲
338 334.266 共0.009兲
338 377.389 共0.037兲*
338 628.292 共0.014兲*
338 627.742 共0.014兲
338 627.881 共0.014兲
338 629.239 共0.014兲
338 797.868 共0.176兲*
4.422
4.422
4.422
4.422
4.422
46.911
46.911
46.911
46.911
46.911
46.911
46.911
46.911
475.760
4.480
4.480
4.480
4.480
4.480
4.480
324.167
493.830
595.218
145.424
442.718
493.739
493.885
226.656
4.229
4.229
4.229
4.229
4.229
4.229
55.610
55.610
55.610
55.610
776.893
776.893
583.873
777.034
572.598
109.898
109.898
109.898
109.898
22.476
22.476
22.476
22.476
225.724
70.215
70.215
70.215
70.215
572.572
0.001
0.004
0.008
0.002
0.001
0.157
0.050
0.062
0.041
0.157
0.050
0.062
0.041
6.342
2.374
0.593
0.198
0.198
1.108
0.264
5.518
19.130
0.022
3.296
3.071
18.848
19.172
6.236
2.377
0.198
0.594
0.264
1.109
0.198
0.172
0.057
0.063
0.051
4.456
4.456
0.260
4.448
0.063
0.875
0.288
0.322
0.257
0.095
0.026
0.036
0.031
1.365
5.830
1.739
2.129
1.924
0.948
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
3
1
1
3
3
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
3
3
3
3
1
3
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1236
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
24
17
24
2
2
2
2
2
2
28
15
24
15
2
2
2
2
2
2
17
10
10
10
10
24
17
28
28
21
26
4
4
4
4
4
4
4
4
4
4
4
4
10
10
10
10
24
24
26
24
17
24
26
24
24
15
15
4
2
4
2
2
2
2
2
2
0
7
4
7
2
2
2
2
2
2
2
0
0
0
0
3
2
5
5
2
10
4
4
4
4
4
4
4
4
4
4
4
4
0
0
0
0
3
4
3
4
2
3
3
3
4
7
7
E1 − 1
A2
E2 − 1
B1
B1
B1
B1
B1
B1
E2 + 1
E1 − 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B2
B2
E2 + 1
B1
B1
B1
B1
E1 + 1
B1
A2
A1
E1 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
E2 − 1
A1
A1
E2 + 1
E1 − 1
B2
E1 − 1
A2
A1
F⬘
1
2
3
2
1
2
2
1
3
1
9
11
10
4
5
3
4
5
3
4
5
3
9
11
10
J⬙
K⬙a
⌫⬙
23
17
23
1
1
1
1
1
1
27
16
23
16
1
1
1
1
1
1
16
9
9
9
9
24
16
27
27
21
27
5
5
5
5
5
5
5
5
5
5
5
5
9
9
9
9
24
23
26
23
16
24
26
24
23
16
16
5
1
5
1
1
1
1
1
1
3
6
5
6
1
1
1
1
1
1
3
1
1
1
1
2
3
6
6
1
9
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
2
5
2
5
3
2
2
2
5
6
6
E1 + 1
A1
E2 − 1
B2
B2
B2
B2
B2
B2
E2 − 1
E1 − 1
E1 − 1
E1 + 1
B1
B1
B1
B1
B1
B1
E2 + 1
B2
B2
B2
B2
E1 + 1
B2
A1
A2
E1 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
E2 − 1
A2
A2
E2 − 1
E1 + 1
B1
E1 − 1
A1
A2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
339 458.081 共0.100兲
0
2
2
1
1
1
2
1
2
0
8
10
9
5
6
4
5
6
4
5
6
4
8
10
9
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
338 837.225 共0.028兲*
339 458.030 共0.037兲*
339 496.904 共0.032兲*
339 723.825 共0.012兲*
339 722.317 共0.012兲
339 723.002 共0.012兲
339 723.788 共0.012兲
339 724.274 共0.012兲
339 725.496 共0.012兲
340 157.920 共0.320兲*
340 258.920 共0.043兲*
340 378.100 共0.045兲*
340 597.276 共0.040兲*
340 598.188 共0.012兲*
340 597.128 共0.012兲
340 597.675 共0.012兲
340 598.335 共0.012兲
340 598.451 共0.012兲
340 599.704 共0.012兲
340 912.470 共0.035兲*
341 058.314 共0.026兲*
341 057.764 共0.026兲
341 057.902 共0.026兲
341 059.261 共0.026兲
341 591.576 共0.096兲*
342 207.701 共0.047兲*
342 285.233 共0.059兲*
342 341.253 共0.059兲*
342 529.002 共0.175兲*
342 888.950 共0.097兲*
343 030.208 共0.019兲*
343 029.311 共0.019兲
343 030.535 共0.019兲
343 030.846 共0.019兲
343 178.750 共0.019兲*
343 177.853 共0.019兲
343 179.077 共0.019兲
343 179.388 共0.019兲
343 179.779 共0.019兲*
343 178.882 共0.019兲
343 180.107 共0.019兲
343 180.418 共0.019兲
343 320.512 共0.012兲*
343 319.976 共0.012兲
343 320.111 共0.012兲
343 321.435 共0.012兲
343 494.628 共0.160兲*
343 504.028 共0.036兲*
343 533.119 共0.148兲*
343 974.484 共0.035兲*
344 064.247 共0.048兲*
344 430.297 共0.101兲*
344 560.363 共0.146兲*
344 644.580 共0.141兲*
344 725.197 共0.037兲*
344 918.827 共0.045兲*
344 918.829 共0.045兲*
475.760
226.728
475.708
4.350
4.350
4.350
4.350
4.350
4.350
583.872
298.440
475.564
298.566
4.321
4.321
4.321
4.321
4.321
4.321
225.639
70.042
70.042
70.042
70.042
456.515
225.834
655.898
655.898
340.564
777.039
46.701
46.701
46.701
46.701
46.811
46.811
46.811
46.811
46.811
46.811
46.811
46.811
70.161
70.161
70.161
70.161
456.639
475.406
532.426
475.406
225.736
456.538
532.401
456.692
475.564
298.604
298.604
0.019
6.593
6.348
2.387
0.265
0.199
1.114
0.597
0.199
0.278
2.216
0.019
2.213
2.374
0.593
0.198
0.198
1.108
0.264
3.586
5.892
1.757
2.151
1.944
15.790
4.925
7.254
7.254
0.030
4.448
0.157
0.050
0.062
0.041
0.157
0.050
0.062
0.041
0.157
0.050
0.062
0.041
5.720
1.706
2.088
1.888
18.244
6.387
0.096
6.388
4.943
17.893
1.309
18.282
6.351
2.213
2.213
3
1
1
3
3
3
3
3
3
1
3
3
3
3
3
3
3
3
3
1
3
3
3
3
3
3
1
1
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
1
1
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1237
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
26
17
17
22
22
4
4
4
4
15
15
26
26
18
11
23
4
4
4
4
25
27
25
28
28
15
18
8
8
8
8
8
8
8
8
23
8
8
8
8
8
8
8
8
28
23
28
23
22
29
6
6
6
6
18
27
28
10
2
2
9
9
4
4
4
4
7
7
10
10
2
6
3
4
4
4
4
3
5
3
5
5
7
2
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
1
1
5
3
5
3
2
0
1
1
1
1
2
5
5
E2 + 1
B2
E1 − 1
B1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B1
B2
B1
E1 + 1
E2 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
E1 − 1
B2
B1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 + 1
E2 + 1
B1
E1 − 1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
B2
E1 + 1
F⬘
4
5
3
4
5
3
9
7
8
9
7
8
9
7
8
9
7
8
6
7
5
J⬙
K⬙a
⌫⬙
27
17
16
23
23
5
5
5
5
16
16
27
27
18
12
23
5
5
5
5
25
28
25
27
27
16
18
7
7
7
7
7
7
7
7
23
7
7
7
7
7
7
7
7
27
23
27
23
22
28
5
5
5
5
18
28
27
9
1
3
8
8
3
3
3
3
6
6
9
9
1
5
2
3
3
3
3
2
2
2
6
6
6
1
1
1
1
1
1
1
1
1
2
1
1
1
1
1
1
1
1
6
2
6
2
1
3
0
0
0
0
1
2
6
E2 + 1
B1
E1 + 1
B2
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B2
B1
B2
E1 − 1
E2 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
E1 + 1
B1
B2
E2 − 1
E2 − 1
A1
A1
A1
A1
B1
B1
B1
B1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 − 1
E2 + 1
B2
E1 − 1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
B1
E1 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
345 519.675 共0.100兲
5
6
4
5
6
4
8
6
7
8
6
7
8
6
7
8
6
7
353 388.593 共0.100兲
5
6
4
353 456.680 共0.100兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
345 082.164 共0.122兲*
345 519.697 共0.040兲*
345 670.884 共0.033兲*
345 834.551 共0.073兲*
345 834.551 共0.073兲*
346 819.859 共0.018兲*
346 818.962 共0.018兲
346 820.186 共0.018兲
346 820.497 共0.018兲
347 135.389 共0.049兲*
347 135.391 共0.049兲*
347 207.118 共0.094兲*
347 207.118 共0.094兲*
348 196.317 共0.060兲*
348 262.248 共0.035兲*
348 872.526 共0.081兲*
348 985.881 共0.019兲*
348 984.984 共0.019兲
348 986.209 共0.019兲
348 986.520 共0.019兲
349 197.836 共0.123兲*
350 090.497 共0.447兲*
350 479.469 共0.120兲*
350 492.626 共0.059兲*
350 547.829 共0.059兲*
350 651.061 共0.047兲*
350 949.562 共0.062兲*
350 967.947 共0.008兲*
350 967.928 共0.008兲
350 967.959 共0.008兲
350 967.962 共0.008兲
350 968.269 共0.008兲*
350 968.250 共0.008兲
350 968.281 共0.008兲
350 968.284 共0.008兲
351 028.213 共0.136兲*
351 030.714 共0.008兲*
351 030.693 共0.008兲
351 030.722 共0.008兲
351 030.735 共0.008兲
351 255.622 共0.008兲*
351 255.592 共0.008兲
351 255.616 共0.008兲
351 255.664 共0.008兲
351 811.008 共0.065兲*
352 173.804 共0.086兲*
352 235.613 共0.051兲*
352 235.731 共0.121兲*
352 543.946 共0.218兲*
353 131.680 共0.392兲*
353 388.506 共0.009兲*
353 387.786 共0.009兲
353 388.785 共0.009兲
353 388.985 共0.009兲
353 456.680 共0.045兲*
353 706.088 共0.424兲*
353 837.095 共0.060兲*
776.943
226.570
225.443
580.799
580.799
46.883
46.883
46.883
46.883
298.502
298.502
776.714
776.714
253.021
183.184
420.804
46.778
46.778
46.778
46.778
493.739
614.316
493.715
655.801
655.801
298.245
252.936
44.005
44.005
44.005
44.005
43.846
43.846
43.846
43.846
420.935
44.009
44.009
44.009
44.010
43.893
43.893
43.893
43.894
655.732
420.825
655.949
420.988
372.643
625.402
22.579
22.579
22.579
22.579
253.007
614.372
655.860
4.452
6.482
1.934
3.592
3.592
0.157
0.050
0.062
0.041
2.214
2.214
4.456
4.456
5.894
1.378
14.392
0.157
0.050
0.062
0.041
0.146
0.019
1.765
7.248
7.248
2.216
5.957
0.743
0.277
0.215
0.244
0.742
0.276
0.214
0.243
17.399
0.742
0.276
0.214
0.243
0.740
0.276
0.214
0.243
7.247
16.934
7.221
17.434
0.019
0.234
4.956
1.606
1.906
1.352
6.343
0.020
7.238
1
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
1
1
1
1
1
1
3
3
3
1
1
1
1
1
1
3
3
3
3
1
3
3
3
3
1
1
1
1
3
1
1
3
3
1
1
1
1
1
1
3
3
Ref.
11
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1238
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
4
4
4
4
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
29
21
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
4
4
4
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
3
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
2
2
2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
B2
B2
B2
F⬘
4
5
3
9
7
8
9
7
8
9
7
8
9
7
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
9
7
J⬙
K⬙a
⌫⬙
5
5
5
5
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
29
20
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
3
3
3
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
2
2
2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
B1
B1
B1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
5
6
4
354 019.214 共0.100兲
8
6
7
354 026.284 共0.100兲
8
6
7
354 038.469 共0.100兲
8
6
7
354 052.026 共0.100兲
8
6
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
8
6
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
353 872.637 共0.018兲*
353 871.740 共0.018兲
353 872.964 共0.018兲
353 873.275 共0.018兲
354 019.180 共0.008兲*
354 019.160 共0.008兲
354 019.171 共0.008兲
354 019.213 共0.008兲
354 026.247 共0.008兲*
354 026.226 共0.008兲
354 026.238 共0.008兲
354 026.279 共0.008兲
354 038.456 共0.008兲*
354 038.436 共0.008兲
354 038.448 共0.008兲
354 038.487 共0.008兲
354 052.061 共0.008兲*
354 052.041 共0.008兲
354 052.053 共0.008兲
354 052.092 共0.008兲
354 467.302 共0.733兲*
354 479.887 共0.035兲*
354 515.681 共0.025兲*
354 515.456 共0.025兲
354 515.543 共0.025兲
354 516.031 共0.025兲
354 517.040 共0.026兲*
354 516.815 共0.026兲
354 516.902 共0.026兲
354 517.390 共0.026兲
354 520.452 共0.025兲*
354 520.227 共0.025兲
354 520.314 共0.025兲
354 520.802 共0.025兲
354 520.452 共0.025兲*
354 520.227 共0.025兲
354 520.314 共0.025兲
354 520.802 共0.025兲
354 521.296 共0.026兲*
354 521.071 共0.026兲
354 521.157 共0.026兲
354 521.646 共0.026兲
354 521.847 共0.026兲*
354 521.622 共0.026兲
354 521.709 共0.026兲
354 522.197 共0.026兲
354 522.361 共0.025兲*
354 522.136 共0.025兲
354 522.222 共0.025兲
354 522.711 共0.025兲
354 522.361 共0.025兲*
354 522.136 共0.025兲
354 522.222 共0.025兲
354 522.711 共0.025兲
354 528.501 共0.008兲*
354 528.483 共0.008兲
354 528.488 共0.008兲
46.497
46.497
46.497
46.497
41.781
41.781
41.781
41.781
41.678
41.678
41.678
41.678
41.584
41.584
41.584
41.584
41.378
41.378
41.378
41.378
637.437
354.096
173.971
173.971
173.971
173.970
173.984
173.984
173.984
173.984
174.151
174.151
174.151
174.151
174.151
174.151
174.151
174.151
173.831
173.831
173.831
173.831
173.788
173.788
173.788
173.788
174.122
174.122
174.122
174.122
174.122
174.122
174.122
174.122
52.648
52.647
52.647
0.157
0.050
0.062
0.041
0.755
0.281
0.218
0.248
0.752
0.280
0.217
0.247
0.756
0.282
0.218
0.248
0.752
0.280
0.217
0.247
0.021
0.215
0.176
0.051
0.066
0.058
0.176
0.051
0.066
0.058
0.177
0.051
0.066
0.058
0.177
0.051
0.066
0.058
0.177
0.051
0.066
0.058
0.178
0.051
0.066
0.058
0.177
0.051
0.066
0.058
0.177
0.051
0.066
0.058
0.707
0.263
0.204
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
Ref.
11
11
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1239
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
2
2
2
2
2
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B2
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
8
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
2
2
2
2
2
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
B1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
7
9
7
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
8
6
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
354 528.536 共0.008兲
354 530.188 共0.008兲*
354 530.169 共0.008兲
354 530.175 共0.008兲
354 530.222 共0.008兲
354 554.186 共0.020兲*
354 554.023 共0.020兲
354 554.083 共0.020兲
354 554.443 共0.020兲
354 557.826 共0.019兲*
354 557.663 共0.019兲
354 557.723 共0.019兲
354 558.083 共0.019兲
354 558.117 共0.020兲*
354 557.954 共0.020兲
354 558.014 共0.020兲
354 558.374 共0.020兲
354 558.117 共0.020兲*
354 557.954 共0.020兲
354 558.014 共0.020兲
354 558.374 共0.020兲
354 560.625 共0.020兲*
354 560.462 共0.020兲
354 560.522 共0.020兲
354 560.881 共0.020兲
354 560.718 共0.020兲*
354 560.556 共0.020兲
354 560.616 共0.020兲
354 560.975 共0.020兲
354 560.718 共0.020兲*
354 560.556 共0.020兲
354 560.616 共0.020兲
354 560.975 共0.020兲
354 561.660 共0.020兲*
354 561.497 共0.020兲
354 561.557 共0.020兲
354 561.916 共0.020兲
354 591.988 共0.015兲*
354 591.879 共0.015兲
354 591.916 共0.015兲
354 592.166 共0.015兲
354 591.988 共0.015兲*
354 591.878 共0.015兲
354 591.915 共0.015兲
354 592.166 共0.015兲
354 592.988 共0.015兲*
354 592.878 共0.015兲
354 592.915 共0.015兲
354 593.166 共0.015兲
354 596.780 共0.015兲*
354 596.670 共0.015兲
354 596.707 共0.015兲
354 596.958 共0.015兲
354 597.340 共0.015兲*
354 597.230 共0.015兲
354 597.267 共0.015兲
354 597.517 共0.015兲
52.648
52.610
52.610
52.610
52.610
138.826
138.826
138.826
138.826
139.045
139.045
139.045
139.045
138.989
138.989
138.989
138.988
138.989
138.989
138.989
138.988
138.628
138.628
138.628
138.628
138.885
138.885
138.885
138.885
138.885
138.885
138.885
138.885
138.949
138.949
138.949
138.949
109.143
109.143
109.143
109.143
109.143
109.143
109.143
109.143
109.267
109.267
109.267
109.267
109.353
109.353
109.353
109.353
109.314
109.314
109.314
109.314
0.232
0.707
0.263
0.204
0.232
0.329
0.095
0.123
0.108
0.329
0.095
0.123
0.108
0.329
0.095
0.123
0.108
0.329
0.095
0.123
0.108
0.331
0.096
0.123
0.109
0.330
0.095
0.123
0.108
0.330
0.095
0.123
0.108
0.330
0.095
0.123
0.108
0.459
0.133
0.171
0.151
0.459
0.133
0.171
0.151
0.459
0.133
0.171
0.151
0.459
0.133
0.171
0.151
0.460
0.133
0.171
0.151
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1240
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
2
2
2
2
3
3
3
3
3
3
3
3
3
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
F⬘
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
9
7
8
7
9
8
7
9
8
J⬙
K⬙a
⌫⬙
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
2
2
2
2
3
3
3
3
3
3
3
3
3
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
F⬙
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
8
6
7
6
8
7
6
8
7
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
354 598.053 共0.015兲*
354 597.943 共0.015兲
354 597.980 共0.015兲
354 598.231 共0.015兲
354 598.053 共0.015兲*
354 597.943 共0.015兲
354 597.980 共0.015兲
354 598.231 共0.015兲
354 598.498 共0.015兲*
354 598.388 共0.015兲
354 598.425 共0.015兲
354 598.675 共0.015兲
354 630.965 共0.012兲*
354 630.899 共0.012兲
354 630.917 共0.012兲
354 631.078 共0.012兲
354 631.018 共0.012兲*
354 630.951 共0.012兲
354 630.970 共0.012兲
354 631.130 共0.012兲
354 632.555 共0.012兲*
354 632.489 共0.012兲
354 632.507 共0.012兲
354 632.667 共0.012兲
354 634.669 共0.011兲*
354 634.603 共0.011兲
354 634.621 共0.011兲
354 634.781 共0.011兲
354 636.477 共0.012兲*
354 636.410 共0.012兲
354 636.429 共0.012兲
354 636.589 共0.012兲
354 637.583 共0.012兲*
354 637.517 共0.012兲
354 637.535 共0.012兲
354 637.695 共0.012兲
354 637.826 共0.012兲*
354 637.759 共0.012兲
354 637.778 共0.012兲
354 637.938 共0.012兲
354 637.879 共0.012兲*
354 637.813 共0.012兲
354 637.831 共0.012兲
354 637.992 共0.012兲
354 659.338 共0.008兲*
354 659.317 共0.008兲
354 659.321 共0.008兲
354 659.378 共0.008兲
354 681.521 共0.009兲*
354 681.489 共0.009兲
354 681.492 共0.009兲
354 681.582 共0.009兲
354 686.028 共0.010兲*
354 685.996 共0.010兲
354 686.000 共0.010兲
354 686.088 共0.010兲
354 686.237 共0.009兲*
108.954
108.954
108.954
108.954
108.954
108.954
108.954
108.954
109.116
109.116
109.116
109.116
84.875
84.875
84.875
84.875
84.875
84.875
84.875
84.875
84.918
84.918
84.918
84.918
85.069
85.069
85.069
85.069
85.037
85.037
85.037
85.037
84.761
84.761
84.761
84.761
84.686
84.686
84.686
84.686
84.686
84.686
84.686
84.686
52.393
52.393
52.393
52.393
66.137
66.137
66.137
66.137
65.927
65.927
65.927
65.927
66.037
0.460
0.133
0.171
0.151
0.460
0.133
0.171
0.151
0.460
0.133
0.171
0.151
0.565
0.163
0.211
0.185
0.565
0.163
0.211
0.185
0.565
0.163
0.211
0.186
0.565
0.163
0.211
0.186
0.566
0.163
0.211
0.186
0.566
0.163
0.211
0.186
0.566
0.163
0.211
0.186
0.566
0.163
0.211
0.186
0.696
0.259
0.201
0.228
0.648
0.187
0.241
0.213
0.648
0.187
0.242
0.213
0.648
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1241
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
22
8
8
8
8
6
6
6
6
8
8
8
8
24
8
8
8
8
8
8
8
8
8
8
8
8
15
22
22
22
29
22
13
11
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
9
2
2
2
2
1
1
1
1
2
2
2
2
3
2
2
2
2
2
2
2
2
2
2
2
2
1
9
9
3
0
9
1
6
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B1
B1
B1
B1
E2 − 1
A1
A2
E1 + 1
B2
E1 − 1
B2
E1 + 1
7
9
8
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
23
7
7
7
7
5
5
5
5
7
7
7
7
24
7
7
7
7
7
7
7
7
7
7
7
7
14
23
23
22
28
23
12
12
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
8
2
2
2
2
0
0
0
0
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
8
8
2
3
8
2
5
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
E2 − 1
A2
A1
E1 + 1
B1
E1 − 1
B1
E1 + 1
6
8
7
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
9
7
8
6
7
5
9
7
8
8
9
7
9
8
7
9
8
7
Obs. Freq. 共unc.兲
共MHz兲
6
8
7
6
8
7
6
8
7
6
8
7
6
8
7
8
6
7
354 843.731 共0.100兲
5
6
4
8
6
7
7
8
6
8
7
6
8
7
6
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
Ref.
354 686.205 共0.009兲
354 686.209 共0.009兲
354 686.298 共0.009兲
354 687.504 共0.009兲*
354 687.472 共0.009兲
354 687.476 共0.009兲
354 687.564 共0.009兲
354 690.570 共0.009兲*
354 690.539 共0.009兲
354 690.542 共0.009兲
354 690.630 共0.009兲
354 690.682 共0.009兲*
354 690.650 共0.009兲
354 690.654 共0.009兲
354 690.743 共0.009兲
354 694.070 共0.010兲*
354 694.038 共0.010兲
354 694.042 共0.010兲
354 694.130 共0.010兲
354 695.483 共0.009兲*
354 695.452 共0.009兲
354 695.455 共0.009兲
354 695.543 共0.009兲
354 703.359 共0.082兲*
354 797.051 共0.008兲*
354 797.037 共0.008兲
354 797.043 共0.008兲
354 797.075 共0.008兲
354 843.680 共0.014兲*
354 842.840 共0.014兲
354 844.006 共0.014兲
354 844.234 共0.014兲
354 864.522 共0.008兲*
354 864.513 共0.008兲
354 864.521 共0.008兲
354 864.533 共0.008兲
354 881.404 共0.102兲*
355 004.417 共0.009兲*
355 004.413 共0.009兲
355 004.415 共0.009兲
355 004.426 共0.009兲
355 108.490 共0.008兲*
355 108.485 共0.008兲
355 108.493 共0.008兲
355 108.494 共0.008兲
355 113.971 共0.008兲*
355 113.967 共0.008兲
355 113.974 共0.008兲
355 113.975 共0.008兲
355 429.832 共0.025兲*
355 480.324 共0.074兲*
355 480.324 共0.074兲*
355 575.513 共0.068兲*
355 783.976 共0.378兲*
356 116.475 共0.065兲*
356 432.821 共0.031兲*
356 457.017 共0.038兲*
66.037
66.037
66.037
66.109
66.109
66.109
66.109
66.137
66.137
66.137
66.137
66.004
66.004
66.004
66.004
65.723
65.723
65.723
65.723
66.037
66.037
66.037
66.037
580.825
52.261
52.261
52.261
52.261
22.381
22.381
22.381
22.381
52.553
52.553
52.553
52.553
456.538
52.458
52.458
52.458
52.458
52.639
52.639
52.639
52.639
52.677
52.677
52.677
52.677
166.598
580.660
580.660
386.584
625.476
580.864
126.763
183.232
0.187
0.241
0.213
0.648
0.187
0.242
0.213
0.648
0.187
0.241
0.213
0.648
0.187
0.241
0.213
0.647
0.187
0.241
0.212
0.648
0.187
0.241
0.213
3.589
0.705
0.263
0.204
0.231
5.390
1.747
2.073
1.470
0.707
0.263
0.204
0.232
0.224
0.698
0.229
0.260
0.202
0.707
0.263
0.232
0.204
0.707
0.263
0.232
0.204
0.076
3.590
3.590
13.067
0.254
3.586
5.213
1.378
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
3
3
3
3
3
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1242
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
24
22
6
6
6
6
15
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
22
11
15
11
21
22
22
18
11
11
21
29
23
28
17
21
29
13
23
29
29
19
21
18
18
18
3
3
3
3
15
17
22
21
3
9
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
6
1
6
3
3
3
2
6
6
3
0
3
5
2
3
11
1
3
0
11
2
3
8
8
8
2
2
2
2
1
2
9
3
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
A2
E2 + 1
B1
E1 − 1
E1 + 1
B2
E2 + 1
B1
B2
B1
E2 + 1
E1 + 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E2 − 1
A2
E1 − 1
E2 + 1
E1 + 1
E1 + 1
A1
E1 + 1
A1
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
E2 − 1
E1 + 1
E2 − 1
F⬘
6
7
5
8
7
9
7
9
8
7
9
8
7
9
8
2
4
3
J⬙
K⬙a
⌫⬙
24
23
5
5
5
5
14
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
22
12
14
12
20
22
22
18
12
12
20
28
23
27
16
21
30
12
23
28
30
19
21
19
19
19
2
2
2
2
14
16
23
20
2
8
0
0
0
0
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
5
2
5
4
2
2
1
5
5
4
3
2
6
3
2
10
2
2
3
10
1
2
7
7
7
1
1
1
1
2
3
8
4
E1 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
A1
E2 + 1
B2
E1 − 1
E1 + 1
B1
E2 − 1
B2
B1
B2
E2 − 1
E1 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E2 − 1
A1
E1 + 1
E2 − 1
E1 + 1
E1 − 1
A2
E1 + 1
A2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
E2 − 1
E1 + 1
E2 − 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
357 440.091 共0.100兲
5
6
4
7
6
8
6
8
7
6
8
7
357 990.485 共0.008兲
6
8
7
359 547.640 共0.100兲
1
3
2
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
356 458.735 共0.098兲*
357 068.872 共0.079兲*
357 440.089 共0.010兲*
357 439.275 共0.010兲
357 440.405 共0.010兲
357 440.627 共0.010兲
357 455.035 共0.024兲*
357 709.688 共0.008兲*
357 709.677 共0.008兲
357 709.694 共0.008兲
357 709.694 共0.008兲
357 928.053 共0.008兲*
357 928.045 共0.008兲
357 928.051 共0.008兲
357 928.063 共0.008兲
357 990.490 共0.008兲*
357 990.478 共0.008兲
44.826
357 990.506 共0.008兲
358 003.147 共0.008兲*
358 003.135 共0.008兲
358 003.142 共0.008兲
358 003.163 共0.008兲
358 007.535 共0.116兲*
358 141.999 共0.035兲*
358 667.789 共0.056兲*
358 674.692 共0.038兲*
358 931.872 共0.026兲*
359 275.470 共0.104兲*
359 355.434 共0.072兲*
359 547.730 共0.049兲*
359 683.844 共0.034兲*
359 683.856 共0.034兲*
360 154.910 共0.031兲*
360 156.335 共0.384兲*
360 498.480 共0.084兲*
361 607.383 共0.067兲*
361 639.875 共0.038兲*
361 704.739 共0.057兲*
361 914.813 共0.150兲*
362 228.663 共0.029兲*
362 397.626 共0.080兲*
362 460.851 共0.378兲*
362 779.449 共0.221兲*
363 595.016 共0.074兲*
364 417.475 共0.099兲*
364 431.171 共0.060兲*
364 473.988 共0.064兲*
364 473.988 共0.064兲*
364 497.227 共0.014兲*
364 497.185 共0.014兲
364 497.217 共0.014兲
364 497.267 共0.014兲
364 502.620 共0.053兲*
364 711.495 共0.040兲*
365 306.456 共0.084兲*
365 430.440 共0.039兲*
456.515
580.653
22.476
22.476
22.476
22.476
166.618
44.804
44.804
44.804
44.804
44.846
44.846
44.846
44.846
44.826
44.826
0.277
44.826
44.668
44.668
44.668
44.668
386.722
183.271
166.406
183.034
353.948
386.774
386.603
252.849
183.060
183.060
354.066
625.342
420.825
655.546
225.824
353.855
956.319
126.723
420.804
625.346
956.492
280.752
354.001
413.320
413.503
413.503
7.559
7.559
7.559
7.559
166.370
225.724
580.476
354.066
2.299
3.592
5.292
1.715
2.035
1.443
0.261
0.740
0.243
0.214
0.276
0.742
0.214
0.277
0.244
0.744
0.215
1
0.244
0.741
0.214
0.276
0.243
16.590
1.377
3.927
1.378
5.703
16.621
15.939
6.224
1.378
1.378
1.654
0.266
0.349
7.257
2.046
11.880
4.971
5.176
2.864
0.281
4.965
5.629
15.808
2.735
2.733
2.733
0.155
0.031
0.066
0.046
3.918
3.734
3.593
4.253
Wst
3
1
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
3
3
3
3
1
1
3
3
3
3
1
3
3
3
1
3
1
1
3
3
1
1
3
1
3
3
1
3
1
1
3
3
3
3
1
1
3
1
Ref.
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1243
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
6
6
6
6
21
21
22
13
7
7
7
7
19
21
17
13
7
7
7
7
7
7
7
7
29
17
20
21
3
3
3
3
17
22
21
15
11
11
19
11
3
3
3
3
18
18
3
3
3
3
20
21
21
20
29
7
7
1
1
1
1
3
3
3
1
5
5
5
5
2
3
2
1
5
5
5
5
5
5
5
5
11
2
3
3
2
2
2
2
2
3
3
1
6
6
2
0
2
2
2
2
8
8
2
2
2
2
3
3
3
3
11
5
5
A1
A1
A1
A1
B1
E2 + 1
E2 − 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E1 − 1
B2
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E2 + 1
E2 − 1
E1 + 1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 − 1
E2 + 1
E2 − 1
A2
A1
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
E1 − 1
E2 − 1
B2
E1 − 1
E2 − 1
E2 − 1
F⬘
6
7
5
7
8
6
7
8
6
7
8
6
3
4
2
3
4
2
3
4
2
7
J⬙
K⬙a
⌫⬙
5
5
5
5
21
21
22
12
8
8
8
8
19
20
16
12
8
8
8
8
8
8
8
8
30
16
20
20
2
2
2
2
16
22
20
14
12
12
19
10
2
2
2
2
19
19
2
2
2
2
20
20
21
20
30
8
8
0
0
0
0
2
2
2
2
4
4
4
4
1
4
3
2
4
4
4
4
4
4
4
4
10
3
2
4
1
1
1
1
3
2
4
2
5
5
1
1
1
1
1
1
7
7
1
1
1
1
2
4
2
2
10
4
4
A2
A2
A2
A2
B2
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E1 − 1
B1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E2 + 1
E2 + 1
E1 + 1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 + 1
E2 + 1
E2 + 1
A1
A2
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
E1 + 1
E2 − 1
B1
E1 − 1
E2 − 1
E2 − 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
5
6
4
8
9
7
8
9
7
8
9
7
2
3
1
368 741.745 共0.100兲
2
3
1
2
3
1
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
365 746.342 共0.014兲*
365 745.503 共0.014兲
365 746.667 共0.014兲
365 746.896 共0.014兲
365 747.497 共0.089兲*
365 953.506 共0.061兲*
365 970.871 共0.070兲*
366 216.591 共0.019兲*
366 269.130 共0.029兲*
366 268.730 共0.029兲
366 269.296 共0.029兲
366 269.373 共0.029兲
366 440.594 共0.076兲*
366 523.486 共0.035兲*
366 619.878 共0.039兲*
366 823.709 共0.014兲*
367 224.171 共0.025兲*
367 223.771 共0.025兲
367 224.337 共0.025兲
367 224.414 共0.025兲
367 224.249 共0.025兲*
367 223.850 共0.025兲
367 224.416 共0.025兲
367 224.492 共0.025兲
367 245.428 共0.149兲*
367 246.576 共0.041兲*
367 267.871 共0.048兲*
367 395.066 共0.030兲*
367 681.122 共0.014兲*
367 680.974 共0.014兲
367 681.164 共0.014兲
367 681.267 共0.014兲
368 185.801 共0.043兲*
368 193.738 共0.066兲*
368 256.255 共0.025兲*
368 345.175 共0.048兲*
368 420.287 共0.034兲*
368 420.299 共0.034兲*
368 741.703 共0.057兲*
368 980.664 共0.030兲*
369 425.203 共0.014兲*
369 425.055 共0.014兲
369 425.246 共0.014兲
369 425.349 共0.014兲
369 531.823 共0.056兲*
369 531.823 共0.056兲*
370 166.704 共0.012兲*
370 166.040 共0.012兲
370 166.894 共0.012兲
370 167.366 共0.012兲
370 249.006 共0.084兲*
370 975.471 共0.030兲*
371 229.036 共0.058兲*
371 641.566 共0.076兲*
371 653.996 共0.153兲*
371 773.645 共0.028兲*
371 773.245 共0.028兲
22.176
22.176
22.176
22.176
354.051
353.872
386.603
126.538
96.898
96.898
96.898
96.898
280.668
354.096
225.866
126.582
96.704
96.704
96.704
96.704
96.704
96.704
96.704
96.704
956.469
225.639
322.620
353.901
7.588
7.588
7.588
7.588
225.769
386.584
353.795
166.167
182.872
182.872
280.737
85.119
7.588
7.588
7.588
7.588
413.476
413.476
7.370
7.370
7.370
7.370
322.772
353.948
353.872
322.821
956.158
96.866
96.866
5.394
1.748
2.075
1.471
15.837
14.866
0.544
5.106
0.590
0.194
0.220
0.171
5.644
5.674
5.149
4.388
0.591
0.194
0.220
0.171
0.591
0.194
0.220
0.171
4.961
1.439
10.873
5.896
2.624
0.777
1.124
0.525
5.179
3.389
4.256
3.849
1.378
1.378
6.054
6.332
0.041
0.012
0.017
0.008
2.731
2.731
2.505
0.742
1.073
0.501
15.049
0.220
0.847
15.076
4.971
0.590
0.194
1
1
1
1
3
1
1
1
3
3
3
3
1
3
3
3
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
1
3
1
3
3
1
1
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1244
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
7
7
20
21
29
29
19
15
17
7
7
7
7
3
3
3
3
21
13
25
30
21
30
18
25
19
18
19
21
20
18
14
18
7
7
7
7
30
19
11
3
3
3
3
25
19
29
29
13
25
10
10
10
10
7
7
7
5
5
3
3
11
11
3
1
2
1
1
1
1
2
2
2
2
3
1
4
1
3
0
8
10
2
8
3
3
3
2
7
3
5
5
5
5
0
3
0
2
2
2
2
4
3
11
11
1
4
0
0
0
0
5
5
5
E2 − 1
E2 − 1
E2 + 1
A2
B1
B2
E1 + 1
E1 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
A1
E2 − 1
E1 − 1
B2
E2 + 1
A1
B1
E2 − 1
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
E1 + 1
A2
A2
A2
A2
B1
E2 + 1
A1
A2
E1 + 1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
8
6
8
8
20
20
30
30
19
14
16
6
6
6
6
2
2
2
2
20
12
24
30
21
29
19
26
19
19
19
20
20
17
15
18
8
8
8
8
29
19
10
2
2
2
2
24
19
30
30
12
24
9
9
9
9
8
8
8
4
4
2
4
10
10
2
2
3
0
0
0
0
1
1
1
1
4
2
5
0
2
3
7
9
1
7
2
4
2
3
6
2
4
4
4
4
3
2
1
1
1
1
1
5
2
10
10
2
5
1
1
1
1
4
4
4
E2 − 1
E2 − 1
E2 − 1
A1
B2
B1
E1 + 1
E1 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A2
E2 − 1
E1 − 1
B1
E2 + 1
A2
B2
E2 − 1
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
E1 + 1
A1
A1
A1
A1
B2
E2 − 1
A2
A1
E1 − 1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
B1
B1
9
7
6
8
7
2
4
3
7
8
6
2
4
3
10
11
9
7
8
Obs. Freq. 共unc.兲
共MHz兲
373 243.386 共0.100兲
5
7
6
1
3
2
374 862.255 共0.100兲
8
9
7
1
3
2
9
10
8
8
9
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
371 773.811 共0.028兲
371 773.888 共0.028兲
371 952.326 共0.051兲*
372 033.683 共0.038兲*
372 159.583 共0.172兲*
372 159.583 共0.172兲*
372 272.213 共0.040兲*
372 739.987 共0.041兲*
373 058.605 共0.036兲*
373 243.402 共0.010兲*
373 243.053 共0.010兲
373 243.151 共0.010兲
373 243.993 共0.010兲
373 256.934 共0.013兲*
373 256.892 共0.013兲
373 256.923 共0.013兲
373 256.974 共0.013兲
373 531.785 共0.034兲*
373 571.590 共0.015兲*
373 621.382 共0.050兲*
373 689.064 共0.858兲*
373 748.338 共0.054兲*
374 105.854 共0.466兲*
374 450.575 共0.061兲*
374 680.547 共0.123兲*
374 862.281 共0.061兲*
375 137.951 共0.069兲*
375 499.898 共0.071兲*
375 698.621 共0.035兲*
376 212.949 共0.048兲*
376 710.565 共0.043兲*
376 720.454 共0.049兲*
376 723.491 共0.034兲*
376 744.076 共0.028兲*
376 743.677 共0.028兲
376 744.242 共0.028兲
376 744.319 共0.028兲
376 790.650 共0.449兲*
376 954.229 共0.065兲*
377 317.551 共0.016兲*
377 321.003 共0.012兲*
377 320.563 共0.012兲
377 320.880 共0.012兲
377 321.440 共0.012兲
377 338.401 共0.052兲*
377 344.479 共0.043兲*
377 458.139 共0.188兲*
377 458.139 共0.188兲*
377 971.674 共0.015兲*
377 998.119 共0.051兲*
378 402.930 共0.013兲*
378 402.378 共0.013兲
378 403.162 共0.013兲
378 403.263 共0.013兲
378 573.152 共0.027兲*
378 572.753 共0.027兲
378 573.318 共0.027兲
96.866
96.866
322.635
353.905
956.310
956.310
292.880
166.109
225.443
31.443
31.443
31.443
31.443
7.559
7.559
7.559
7.559
353.795
126.293
511.235
681.090
353.855
668.363
413.335
737.306
280.581
413.142
293.037
353.719
322.635
250.964
275.019
264.636
96.747
96.747
96.747
96.747
668.435
293.085
85.135
7.496
7.496
7.496
7.496
511.026
292.891
956.172
956.172
126.210
511.026
68.888
68.888
68.888
68.888
96.515
96.516
96.515
0.220
0.170
13.670
5.917
4.967
4.967
10.061
3.653
3.142
0.302
0.085
0.114
0.098
2.514
0.503
1.078
0.745
1.668
0.160
6.764
0.019
3.806
0.232
2.733
4.108
5.926
2.735
14.306
5.912
1.294
3.017
1.889
9.440
0.590
0.194
0.220
0.170
0.253
14.331
6.243
2.679
0.536
1.148
0.794
6.788
12.324
4.971
4.971
0.866
6.790
0.023
0.007
0.008
0.007
0.590
0.194
0.220
1
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
3
1
1
3
3
1
1
3
1
3
1
3
3
3
3
3
3
3
3
1
1
1
1
3
1
1
1
3
3
3
3
3
3
3
3
3
Ref.
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1245
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
7
7
7
7
7
3
3
3
3
20
25
11
7
7
7
7
3
3
3
3
3
3
3
3
18
18
21
20
18
17
19
30
3
3
3
3
18
25
25
11
18
25
7
7
7
7
30
3
3
3
3
20
18
25
19
16
25
5
5
5
5
5
2
2
2
2
3
4
0
1
1
1
1
2
2
2
2
2
2
2
2
8
3
3
2
2
3
3
0
2
2
2
2
3
10
10
0
3
10
5
5
5
5
0
2
2
2
2
2
2
4
3
3
4
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 + 1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
E1 − 1
A2
B2
E1 + 1
E2 + 1
E1 + 1
E2 − 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
A1
A2
E2 + 1
E2 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E2 − 1
E2 + 1
E1 − 1
E1 − 1
E1 + 1
E2 − 1
6
8
8
8
8
8
2
2
2
2
20
24
10
6
6
6
6
2
2
2
2
2
2
2
2
19
18
20
20
17
17
19
29
2
2
2
2
18
26
26
10
18
26
8
8
8
8
29
2
2
2
2
20
17
24
19
16
24
4
4
4
4
4
1
1
1
1
2
5
1
0
0
0
0
1
1
1
1
1
1
1
1
7
2
4
1
3
2
2
3
1
1
1
1
2
9
9
1
2
9
4
4
4
4
3
1
1
1
1
1
3
5
2
2
5
B1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
E1 − 1
A1
B1
E1 − 1
E2 − 1
E1 + 1
E2 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
A2
A1
E2 + 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
B1
B1
B1
B1
E2 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
7
7
8
6
3
4
2
6
8
7
3
4
2
3
4
2
3
4
2
7
8
6
2
4
3
Obs. Freq. 共unc.兲
共MHz兲
8
9
7
2
3
1
379 817.800 共0.100兲
5
7
6
2
3
1
2
3
1
2
3
1
8
9
7
1
3
2
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
378 573.395 共0.027兲
378 573.232 共0.027兲*
378 572.833 共0.027兲
378 573.399 共0.027兲
378 573.475 共0.027兲
378 926.411 共0.011兲*
378 925.746 共0.011兲
378 926.601 共0.011兲
378 927.073 共0.011兲
378 973.347 共0.045兲*
379 165.792 共0.050兲*
379 730.657 共0.030兲*
379 818.086 共0.010兲*
379 817.699 共0.010兲
379 817.809 共0.010兲
379 818.738 共0.010兲
379 848.540 共0.011兲*
379 848.064 共0.011兲
379 848.677 共0.011兲
379 849.015 共0.011兲
379 925.820 共0.012兲*
379 924.760 共0.012兲
379 926.122 共0.012兲
379 926.879 共0.012兲
380 128.776 共0.065兲*
380 175.276 共0.060兲*
380 239.791 共0.037兲*
380 344.945 共0.092兲*
380 624.196 共0.048兲*
380 626.734 共0.029兲*
380 871.920 共0.041兲*
380 988.206 共0.449兲*
381 592.622 共0.012兲*
381 592.145 共0.012兲
381 592.758 共0.012兲
381 593.096 共0.012兲
381 689.440 共0.055兲*
381 787.011 共0.108兲*
381 787.011 共0.108兲*
382 112.145 共0.015兲*
382 133.597 共0.036兲*
382 150.584 共0.099兲*
382 620.711 共0.028兲*
382 620.311 共0.028兲
382 620.877 共0.028兲
382 620.954 共0.028兲
383 123.346 共0.443兲*
383 202.762 共0.013兲*
383 202.322 共0.013兲
383 202.638 共0.013兲
383 203.198 共0.013兲
383 264.185 共0.094兲*
383 340.973 共0.043兲*
383 489.703 共0.038兲*
383 796.759 共0.038兲*
383 988.051 共0.025兲*
384 167.891 共0.039兲*
96.515
96.515
96.515
96.515
96.515
7.370
7.370
7.370
7.370
322.620
511.198
84.963
31.340
31.340
31.340
31.340
7.182
7.183
7.182
7.182
7.408
7.408
7.408
7.408
413.185
264.797
353.723
309.934
250.867
237.887
292.891
668.301
7.182
7.183
7.182
7.182
264.843
737.081
737.081
85.076
264.643
737.222
96.590
96.590
96.590
96.590
668.310
7.337
7.337
7.337
7.337
309.850
250.776
511.198
292.880
212.635
511.146
0.171
0.590
0.194
0.220
0.171
0.145
0.043
0.062
0.029
4.064
6.726
6.310
0.061
0.017
0.023
0.020
0.035
0.010
0.015
0.007
2.638
0.781
1.130
0.528
2.734
13.575
5.936
5.324
1.170
8.989
1.908
0.267
2.620
0.776
1.123
0.524
13.597
4.112
4.112
6.157
10.855
4.105
0.590
0.194
0.220
0.171
0.280
2.680
0.536
1.148
0.794
5.309
4.174
0.039
4.144
8.686
6.744
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
1
3
3
1
3
1
3
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
3
3
3
1
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1246
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
17
10
10
10
10
14
18
14
25
18
20
3
3
3
3
17
17
18
15
29
29
25
16
25
18
18
16
25
17
14
14
14
25
25
16
16
21
21
16
15
13
25
25
14
14
20
17
12
16
15
10
15
11
14
10
10
10
3
0
0
0
0
7
2
7
4
3
2
2
2
2
2
3
3
2
3
5
5
10
3
4
2
3
1
4
3
3
7
7
10
4
3
3
9
9
1
3
3
10
10
7
7
2
3
3
3
3
6
3
3
3
3
3
3
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
B2
E1 + 1
E1 + 1
E2 − 1
A1
B1
B1
B1
B1
B1
E2 + 1
A2
E1 + 1
A1
A2
E1 + 1
A2
A1
E1 − 1
E1 − 1
E2 − 1
A2
E2 − 1
E1 + 1
A1
A2
E2 + 1
E1 − 1
B2
E2 + 1
B2
B1
E1 − 1
A1
E1 + 1
B1
B2
B1
B2
B1
E1 − 1
E1 + 1
E2 − 1
B1
E2 − 1
E2 + 1
E1 + 1
A2
E1 + 1
E1 + 1
E1 + 1
F⬘
10
11
9
3
4
2
9
11
J⬙
K⬙a
⌫⬙
17
9
9
9
9
15
17
15
24
18
20
2
2
2
2
17
17
17
15
28
28
26
16
24
17
18
15
24
17
14
15
15
26
24
16
16
22
22
15
15
13
26
26
15
15
20
17
12
16
15
11
15
11
14
10
10
10
2
1
1
1
1
6
3
6
5
2
1
1
1
1
1
2
2
3
2
6
6
9
2
5
3
2
2
5
2
2
6
6
9
5
2
2
8
8
2
2
2
9
9
6
6
1
2
2
2
2
5
2
2
2
2
2
2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
B1
E1 + 1
E1 − 1
E2 − 1
A2
B2
B2
B2
B2
B2
E2 − 1
A1
E1 + 1
A2
A1
E1 + 1
A1
A2
E1 + 1
E1 + 1
E2 − 1
A1
E2 − 1
E1 + 1
A2
A1
E2 + 1
E1 − 1
B1
E2 − 1
B1
B2
E1 + 1
A2
E1 + 1
B2
B1
B2
B1
B2
E1 + 1
E1 + 1
E2 − 1
B2
E2 − 1
E2 − 1
E1 + 1
A1
E1 + 1
E1 + 1
E1 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
9
10
8
385 340.661 共0.100兲
2
3
1
391 489.690 共0.100兲
9
11
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
384 287.907 共0.051兲*
384 553.263 共0.015兲*
384 552.738 共0.015兲
384 553.483 共0.015兲
384 553.580 共0.015兲
384 577.419 共0.050兲*
384 766.032 共0.060兲*
384 938.936 共0.047兲*
385 045.193 共0.061兲*
385 163.481 共0.034兲*
385 340.630 共0.074兲*
385 811.722 共0.013兲*
385 810.662 共0.013兲
385 812.025 共0.013兲
385 812.782 共0.013兲
385 858.893 共0.047兲*
386 335.991 共0.031兲*
386 619.067 共0.061兲*
386 816.619 共0.022兲*
386 833.078 共0.080兲*
386 912.006 共0.080兲*
387 107.941 共0.114兲*
387 858.160 共0.043兲*
388 054.293 共0.050兲*
388 125.490 共0.042兲*
388 164.864 共0.032兲*
388 551.665 共0.031兲*
388 699.913 共0.047兲*
389 052.768 共0.030兲*
389 127.204 共0.020兲*
389 249.118 共0.052兲*
389 249.119 共0.052兲*
389 310.401 共0.136兲*
389 369.104 共0.047兲*
389 482.036 共0.040兲*
389 979.131 共0.026兲*
390 082.506 共0.087兲*
390 082.506 共0.087兲*
390 817.630 共0.029兲*
390 913.592 共0.036兲*
390 944.319 共0.018兲*
391 436.567 共0.114兲*
391 436.567 共0.114兲*
391 469.418 共0.056兲*
391 469.419 共0.056兲*
391 489.836 共0.078兲*
392 041.658 共0.028兲*
392 308.376 共0.017兲*
392 514.212 共0.026兲*
392 585.698 共0.034兲*
392 601.623 共0.040兲*
393 097.431 共0.022兲*
393 280.600 共0.016兲*
393 488.153 共0.031兲*
393 939.884 共0.014兲*
393 939.882 共0.014兲
393 939.883 共0.014兲
238.051
68.785
68.786
68.785
68.785
274.800
250.966
274.925
511.002
264.643
309.918
7.249
7.249
7.249
7.249
238.095
237.889
250.869
188.879
697.206
697.206
737.227
212.799
510.845
250.583
264.636
188.868
510.845
237.889
166.618
274.964
274.964
737.130
511.002
212.842
212.631
546.856
546.856
188.879
189.041
145.853
736.901
736.901
274.861
274.861
309.762
237.887
126.582
212.631
189.083
165.446
188.868
108.803
166.777
92.513
92.513
92.513
12.849
0.124
0.041
0.045
0.037
1.890
5.314
1.888
0.039
2.656
5.736
2.638
0.782
1.130
0.528
12.870
9.358
5.334
8.500
7.655
7.655
4.105
12.125
6.794
2.337
4.044
0.058
6.796
3.439
8.388
1.888
1.888
4.108
6.737
12.144
7.950
3.253
3.253
0.173
11.400
8.287
4.112
4.112
1.889
1.889
5.603
3.778
8.119
4.132
11.417
1.074
6.710
7.812
10.669
7.338
2.191
2.657
1
1
1
1
1
3
3
3
3
1
1
3
3
3
3
3
1
1
3
1
1
3
1
1
3
3
1
1
1
3
1
1
1
3
3
1
3
3
3
1
3
3
3
3
3
3
3
3
1
3
1
1
3
1
3
3
3
Ref.
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1247
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
9
9
9
9
8
8
8
8
9
9
9
9
9
9
9
9
7
7
7
7
9
9
9
9
6
6
6
6
29
5
5
5
5
9
9
9
9
14
4
4
4
4
3
3
3
3
29
14
16
16
15
13
14
29
29
12
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
5
3
3
3
3
1
1
1
1
7
3
3
3
3
3
3
3
3
5
3
3
1
3
3
3
5
5
3
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
E1 − 1
B2
E2 − 1
A1
E2 + 1
E1 − 1
E2 + 1
A2
10
10
9
9
9
9
8
8
8
8
8
8
8
8
8
8
8
8
7
7
7
7
8
8
8
8
6
6
6
6
28
5
5
5
5
8
8
8
8
15
4
4
4
4
3
3
3
3
28
14
16
15
15
13
14
28
28
12
2
2
2
2
2
2
2
2
2
1
1
1
1
1
1
1
1
2
2
2
2
1
1
1
1
2
2
2
2
6
2
2
2
2
1
1
1
1
6
2
2
2
2
2
2
2
2
6
2
2
2
2
2
2
6
6
2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
E1 + 1
B1
E2 − 1
A2
E2 − 1
E1 − 1
E2 + 1
A1
10
9
10
8
8
9
7
10
8
9
10
8
9
7
8
6
10
8
9
6
7
5
5
6
4
10
8
9
4
5
3
3
4
2
9
10
8
8
9
7
9
7
8
9
7
8
7
8
6
9
7
8
6
7
5
5
6
4
9
7
8
4
5
3
3
4
2
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
393 939.887 共0.014兲
394 369.550 共0.013兲*
394 369.510 共0.013兲
394 369.568 共0.013兲
394 369.574 共0.013兲
394 642.331 共0.012兲*
394 642.247 共0.012兲
394 642.366 共0.012兲
394 642.381 共0.012兲
394 773.156 共0.009兲*
394 773.140 共0.009兲
394 773.164 共0.009兲
394 773.169 共0.009兲
394 773.960 共0.009兲*
394 773.944 共0.009兲
394 773.968 共0.009兲
394 773.973 共0.009兲
394 812.783 共0.012兲*
394 812.650 共0.012兲
394 812.837 共0.012兲
394 812.864 共0.012兲
394 820.102 共0.009兲*
394 820.084 共0.009兲
394 820.108 共0.009兲
394 820.119 共0.009兲
394 917.872 共0.012兲*
394 917.677 共0.012兲
394 917.950 共0.012兲
394 917.997 共0.012兲
394 980.776 共0.079兲*
394 981.336 共0.013兲*
394 981.049 共0.013兲
394 981.447 共0.013兲
394 981.528 共0.013兲
394 986.747 共0.009兲*
394 986.724 共0.009兲
394 986.745 共0.009兲
394 986.777 共0.009兲
394 993.369 共0.055兲*
395 018.243 共0.014兲*
395 017.801 共0.014兲
395 018.404 共0.014兲
395 018.559 共0.014兲
395 038.374 共0.015兲*
395 037.627 共0.015兲
395 038.622 共0.015兲
395 038.971 共0.015兲
395 058.560 共0.079兲*
395 203.326 共0.028兲*
395 406.781 共0.025兲*
395 502.941 共0.071兲*
395 534.942 共0.023兲*
395 621.059 共0.026兲*
395 728.358 共0.019兲*
396 317.194 共0.088兲*
396 741.709 共0.069兲*
397 355.428 共0.022兲*
92.513
77.710
77.710
77.710
77.710
64.390
64.390
64.390
64.390
55.712
55.712
55.712
55.712
55.553
55.553
55.553
55.553
52.553
52.553
52.553
52.553
55.719
55.719
55.719
55.719
42.197
42.197
42.197
42.197
697.109
33.322
33.322
33.322
33.322
55.610
55.610
55.610
55.610
274.604
25.926
25.926
25.926
25.926
20.010
20.010
20.010
20.010
697.109
166.818
212.635
188.551
188.868
146.004
166.598
697.040
697.256
126.723
2.402
6.716
2.189
2.450
1.978
5.989
1.941
2.204
1.734
0.838
0.309
0.247
0.276
0.837
0.308
0.246
0.276
5.191
1.669
1.931
1.469
0.838
0.309
0.246
0.276
4.342
1.379
1.636
1.191
7.648
3.442
1.072
1.318
0.901
0.836
0.308
0.246
0.275
1.890
2.470
0.743
0.966
0.600
1.375
0.385
0.552
0.291
7.648
10.684
3.365
4.154
4.656
9.931
5.646
7.647
7.617
9.182
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
3
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1248
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
13
13
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
14
15
29
21
11
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
3
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
3
5
2
3
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
2
2
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 − 1
E1 − 1
E1 + 1
E1 + 1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
B1
B1
F⬘
10
8
9
10
8
9
10
8
9
10
8
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
10
J⬙
K⬙a
⌫⬙
13
13
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
14
15
28
21
11
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
2
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
2
6
1
2
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
2
2
B2
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 − 1
E1 + 1
E1 + 1
E1 − 1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
B2
B2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
398 066.418 共0.100兲
9
7
8
398 075.422 共0.100兲
9
7
8
398 094.797 共0.100兲
9
7
8
398 112.100 共0.100兲
9
7
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
9
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
397 373.872 共0.024兲*
397 910.584 共0.016兲*
398 066.376 共0.009兲*
398 066.354 共0.009兲
398 066.363 共0.009兲
398 066.412 共0.009兲
398 075.399 共0.009兲*
398 075.377 共0.009兲
398 075.386 共0.009兲
398 075.435 共0.009兲
398 094.802 共0.009兲*
398 094.782 共0.009兲
398 094.790 共0.009兲
398 094.837 共0.009兲
398 112.114 共0.009兲*
398 112.093 共0.009兲
398 112.102 共0.009兲
398 112.148 共0.009兲
398 116.818 共0.020兲*
398 253.322 共0.022兲*
398 338.668 共0.082兲*
398 455.795 共0.115兲*
398 736.783 共0.018兲*
398 760.141 共0.038兲*
398 759.941 共0.038兲
398 760.011 共0.038兲
398 760.461 共0.038兲
398 762.004 共0.037兲*
398 761.804 共0.037兲
398 761.874 共0.037兲
398 762.324 共0.037兲
398 762.004 共0.037兲*
398 761.804 共0.037兲
398 761.874 共0.037兲
398 762.324 共0.037兲
398 766.277 共0.038兲*
398 766.077 共0.038兲
398 766.148 共0.038兲
398 766.597 共0.038兲
398 766.391 共0.038兲*
398 766.190 共0.038兲
398 766.261 共0.038兲
398 766.711 共0.038兲
398 766.564 共0.037兲*
398 766.364 共0.037兲
398 766.435 共0.037兲
398 766.884 共0.037兲
398 767.967 共0.038兲*
398 767.767 共0.038兲
398 767.837 共0.038兲
398 768.287 共0.038兲
398 767.967 共0.038兲*
398 767.767 共0.038兲
398 767.837 共0.038兲
398 768.287 共0.038兲
398 788.934 共0.009兲*
398 788.919 共0.009兲
146.045
145.822
53.590
53.590
53.590
53.590
53.487
53.487
53.487
53.487
53.393
53.393
53.393
53.393
53.188
53.188
53.188
53.188
166.598
188.879
697.167
340.564
108.932
226.218
226.218
226.218
226.218
226.364
226.364
226.364
226.364
226.364
226.364
226.364
226.364
226.036
226.036
226.036
226.036
226.425
226.425
226.425
226.425
226.386
226.386
226.386
226.386
226.221
226.221
226.221
226.221
226.221
226.221
226.221
226.221
64.473
64.473
9.943
4.723
0.849
0.313
0.250
0.280
0.847
0.312
0.249
0.279
0.850
0.313
0.250
0.280
0.846
0.312
0.249
0.278
4.996
2.834
7.637
4.998
8.422
0.177
0.052
0.065
0.058
0.177
0.052
0.065
0.058
0.177
0.052
0.065
0.058
0.179
0.053
0.066
0.059
0.178
0.052
0.065
0.059
0.178
0.052
0.066
0.059
0.179
0.053
0.066
0.059
0.179
0.053
0.066
0.059
0.807
0.297
3
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
Ref.
11
11
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1249
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
2
2
2
2
2
2
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
B1
B1
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
8
9
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
2
2
2
2
2
2
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
B2
B2
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
7
8
10
8
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
7
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
398 788.924 共0.009兲
398 788.960 共0.009兲
398 791.106 共0.009兲*
398 791.091 共0.009兲
398 791.096 共0.009兲
398 791.132 共0.009兲
398 809.125 共0.029兲*
398 808.974 共0.029兲
398 809.025 共0.029兲
398 809.370 共0.029兲
398 810.766 共0.030兲*
398 810.615 共0.030兲
398 810.666 共0.030兲
398 811.011 共0.030兲
398 814.418 共0.029兲*
398 814.267 共0.029兲
398 814.318 共0.029兲
398 814.663 共0.029兲
398 814.418 共0.029兲*
398 814.267 共0.029兲
398 814.318 共0.029兲
398 814.663 共0.029兲
398 815.629 共0.029兲*
398 815.477 共0.029兲
398 815.529 共0.029兲
398 815.873 共0.029兲
398 816.107 共0.030兲*
398 815.955 共0.030兲
398 816.006 共0.030兲
398 816.351 共0.030兲
398 816.533 共0.029兲*
398 816.381 共0.029兲
398 816.432 共0.029兲
398 816.777 共0.029兲
398 816.533 共0.029兲*
398 816.381 共0.029兲
398 816.432 共0.029兲
398 816.777 共0.029兲
398 853.985 共0.023兲*
398 853.876 共0.023兲
398 853.911 共0.023兲
398 854.164 共0.023兲
398 857.811 共0.023兲*
398 857.702 共0.023兲
398 857.737 共0.023兲
398 857.991 共0.023兲
398 858.319 共0.023兲*
398 858.210 共0.023兲
398 858.244 共0.023兲
398 858.498 共0.023兲
398 858.319 共0.023兲*
398 858.210 共0.023兲
398 858.244 共0.023兲
398 858.498 共0.023兲
398 861.319 共0.023兲*
398 861.210 共0.023兲
398 861.245 共0.023兲
64.473
64.473
64.436
64.436
64.436
64.436
185.796
185.796
185.796
185.796
185.810
185.810
185.810
185.810
185.977
185.977
185.977
185.977
185.977
185.977
185.977
185.977
185.657
185.657
185.657
185.656
185.614
185.614
185.614
185.614
185.948
185.948
185.948
185.948
185.948
185.948
185.948
185.948
150.653
150.653
150.653
150.653
150.871
150.871
150.871
150.871
150.815
150.815
150.815
150.815
150.815
150.815
150.815
150.815
150.455
150.455
150.455
0.237
0.266
0.806
0.297
0.237
0.265
0.334
0.098
0.123
0.110
0.334
0.098
0.123
0.110
0.335
0.098
0.123
0.110
0.335
0.098
0.123
0.110
0.336
0.099
0.124
0.111
0.337
0.099
0.124
0.111
0.335
0.099
0.124
0.110
0.335
0.099
0.124
0.110
0.470
0.138
0.173
0.155
0.471
0.138
0.173
0.155
0.471
0.138
0.173
0.155
0.471
0.138
0.173
0.155
0.473
0.139
0.174
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1250
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
2
2
2
2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
E2 − 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
A2
A2
A2
A2
9
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
2
2
2
2
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
4
4
4
4
4
4
4
4
E2 − 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
A1
A1
A1
A1
8
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
10
8
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
9
7
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
398 861.498 共0.023兲
398 861.326 共0.023兲*
398 861.217 共0.023兲
398 861.252 共0.023兲
398 861.506 共0.023兲
398 861.326 共0.023兲*
398 861.217 共0.023兲
398 861.252 共0.023兲
398 861.506 共0.023兲
398 862.133 共0.023兲*
398 862.024 共0.023兲
398 862.059 共0.023兲
398 862.313 共0.023兲
398 899.011 共0.018兲*
398 898.938 共0.018兲
398 898.958 共0.018兲
398 899.135 共0.018兲
398 899.012 共0.018兲*
398 898.938 共0.018兲
398 898.959 共0.018兲
398 899.135 共0.018兲
398 899.389 共0.009兲*
398 899.371 共0.009兲
398 899.375 共0.009兲
398 899.423 共0.009兲
398 899.797 共0.018兲*
398 899.724 共0.018兲
398 899.744 共0.018兲
398 899.921 共0.018兲
398 904.030 共0.018兲*
398 903.957 共0.018兲
398 903.978 共0.018兲
398 904.154 共0.018兲
398 904.715 共0.018兲*
398 904.642 共0.018兲
398 904.662 共0.018兲
398 904.839 共0.018兲
398 905.974 共0.018兲*
398 905.901 共0.018兲
398 905.922 共0.018兲
398 906.098 共0.018兲
398 905.975 共0.018兲*
398 905.902 共0.018兲
398 905.922 共0.018兲
398 906.099 共0.018兲
398 906.083 共0.018兲*
398 906.010 共0.018兲
398 906.030 共0.018兲
398 906.207 共0.018兲
398 947.275 共0.014兲*
398 947.231 共0.014兲
398 947.240 共0.014兲
398 947.353 共0.014兲
398 947.401 共0.014兲*
398 947.357 共0.014兲
398 947.366 共0.014兲
398 947.478 共0.014兲
150.455
150.712
150.712
150.712
150.712
150.712
150.712
150.712
150.712
150.776
150.776
150.776
150.776
120.971
120.971
120.971
120.971
120.971
120.971
120.971
120.971
64.223
64.223
64.223
64.223
121.095
121.095
121.095
121.095
121.181
121.181
121.181
121.181
121.142
121.142
121.142
121.142
120.782
120.782
120.782
120.782
120.782
120.782
120.782
120.782
120.944
120.944
120.944
120.944
96.704
96.704
96.704
96.704
96.704
96.704
96.704
96.704
0.156
0.472
0.139
0.174
0.155
0.472
0.139
0.174
0.155
0.472
0.139
0.174
0.155
0.586
0.172
0.216
0.193
0.586
0.172
0.216
0.193
0.796
0.293
0.234
0.262
0.586
0.172
0.216
0.193
0.586
0.172
0.216
0.193
0.587
0.173
0.216
0.193
0.587
0.173
0.216
0.193
0.587
0.173
0.216
0.193
0.587
0.173
0.216
0.193
0.680
0.200
0.251
0.224
0.680
0.200
0.251
0.224
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1251
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
21
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
9
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
F⬘
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
10
8
9
10
8
9
10
8
9
10
8
9
10
8
9
10
8
9
10
8
9
10
8
9
J⬙
K⬙a
⌫⬙
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
22
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
8
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
F⬙
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
7
9
8
9
7
8
9
7
8
9
7
8
9
7
8
9
7
8
9
7
8
9
7
8
9
7
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
398 949.171 共0.014兲*
398 949.128 共0.014兲
398 949.136 共0.014兲
398 949.249 共0.014兲
398 950.960 共0.014兲*
398 950.916 共0.014兲
398 950.925 共0.014兲
398 951.038 共0.014兲
398 953.038 共0.014兲*
398 952.994 共0.014兲
398 953.003 共0.014兲
398 953.116 共0.014兲
398 955.003 共0.014兲*
398 954.959 共0.014兲
398 954.968 共0.014兲
398 955.081 共0.014兲
398 955.221 共0.014兲*
398 955.178 共0.014兲
398 955.186 共0.014兲
398 955.299 共0.014兲
398 955.350 共0.014兲*
398 955.306 共0.014兲
398 955.315 共0.014兲
398 955.427 共0.014兲
398 973.023 共0.094兲*
399 010.809 共0.011兲*
399 010.789 共0.011兲
399 010.789 共0.011兲
399 010.851 共0.011兲
399 016.424 共0.011兲*
399 016.404 共0.011兲
399 016.404 共0.011兲
399 016.466 共0.011兲
399 020.375 共0.011兲*
399 020.355 共0.011兲
399 020.355 共0.011兲
399 020.415 共0.011兲
399 021.226 共0.011兲*
399 021.206 共0.011兲
399 021.206 共0.011兲
399 021.267 共0.011兲
399 024.965 共0.011兲*
399 024.945 共0.011兲
399 024.945 共0.011兲
399 025.005 共0.011兲
399 027.383 共0.011兲*
399 027.363 共0.011兲
399 027.364 共0.011兲
399 027.423 共0.011兲
399 029.979 共0.011兲*
399 029.959 共0.011兲
399 029.959 共0.011兲
399 030.019 共0.011兲
399 033.358 共0.011兲*
399 033.338 共0.011兲
399 033.339 共0.011兲
399 033.398 共0.011兲
96.747
96.747
96.747
96.747
96.898
96.898
96.898
96.898
96.866
96.866
96.866
96.866
96.590
96.590
96.590
96.590
96.515
96.515
96.515
96.515
96.515
96.515
96.515
96.516
546.882
77.968
77.968
77.968
77.968
77.868
77.868
77.868
77.868
77.758
77.758
77.758
77.758
77.940
77.940
77.940
77.940
77.835
77.835
77.835
77.835
77.968
77.968
77.968
77.968
77.554
77.554
77.554
77.554
77.868
77.868
77.868
77.868
0.681
0.200
0.251
0.224
0.681
0.200
0.251
0.224
0.681
0.200
0.251
0.224
0.681
0.200
0.251
0.224
0.681
0.200
0.251
0.224
0.681
0.200
0.251
0.224
3.251
0.754
0.278
0.222
0.248
0.754
0.278
0.222
0.248
0.755
0.278
0.222
0.248
0.754
0.278
0.222
0.248
0.754
0.278
0.222
0.248
0.754
0.278
0.222
0.248
0.753
0.278
0.222
0.248
0.754
0.278
0.222
0.248
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1252
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
9
9
9
9
12
22
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
12
21
21
10
10
10
10
13
21
11
7
7
7
7
14
9
9
9
9
10
11
8
8
8
8
21
16
21
7
7
7
7
10
10
10
2
2
2
2
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
9
9
3
3
3
3
3
9
3
1
1
1
1
3
3
3
3
3
6
3
3
3
3
3
9
1
2
3
3
3
3
3
3
3
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
E2 + 1
A2
A1
A2
A2
A2
A2
E2 − 1
E1 − 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
A1
A1
A1
A1
E1 + 1
E2 + 1
A2
A2
A2
A2
E2 + 1
A2
E2 − 1
A1
A1
A1
A1
B2
B2
B2
F⬘
10
8
9
9
10
8
9
10
8
9
10
8
9
10
8
9
11
10
7
8
6
8
10
9
8
9
7
7
8
6
9
11
J⬙
K⬙a
⌫⬙
8
8
8
8
12
21
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
12
22
22
10
10
10
10
13
22
11
6
6
6
6
14
9
9
9
9
11
11
8
8
8
8
22
15
21
7
7
7
7
10
10
10
2
2
2
2
2
4
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
8
8
2
2
2
2
2
8
2
0
0
0
0
2
2
2
2
2
5
2
2
2
2
2
8
2
1
2
2
2
2
2
2
2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B1
B1
B1
B1
E2 − 1
A1
A2
A1
A1
A1
A1
E2 − 1
E1 − 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A2
A2
A2
A2
E1 + 1
E2 − 1
A1
A1
A1
A1
E2 + 1
A1
E2 − 1
A2
A2
A2
A2
B1
B1
B1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
9
7
8
8
9
7
8
9
7
8
9
7
8
9
7
9
11
10
400 550.464 共0.100兲
6
7
5
8
10
9
8
9
7
7
8
6
9
11
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
399 136.100 共0.010兲*
399 136.088 共0.010兲
399 136.094 共0.010兲
399 136.119 共0.010兲
399 140.420 共0.020兲*
399 280.262 共0.042兲*
399 302.759 共0.010兲*
399 302.756 共0.010兲
399 302.757 共0.010兲
399 302.766 共0.010兲
399 542.743 共0.011兲*
399 542.726 共0.011兲
399 542.748 共0.011兲
399 542.758 共0.011兲
399 613.907 共0.010兲*
399 613.899 共0.010兲
399 613.908 共0.010兲
399 613.917 共0.010兲
399 621.830 共0.010兲*
399 621.822 共0.010兲
399 621.831 共0.010兲
399 621.840 共0.010兲
399 683.406 共0.014兲*
399 762.110 共0.089兲*
399 762.110 共0.089兲*
399 811.540 共0.016兲*
399 811.501 共0.016兲
399 811.511 共0.016兲
399 811.608 共0.016兲
400 275.374 共0.018兲*
400 391.918 共0.078兲*
400 548.664 共0.017兲*
400 550.329 共0.010兲*
400 549.557 共0.010兲
400 550.640 共0.010兲
400 550.819 共0.010兲
400 586.852 共0.021兲*
400 625.595 共0.014兲*
400 625.582 共0.014兲
400 625.586 共0.014兲
400 625.617 共0.014兲
400 803.069 共0.043兲*
401 086.166 共0.013兲*
401 223.078 共0.013兲*
401 223.051 共0.013兲
401 223.090 共0.013兲
401 223.095 共0.013兲
401 320.928 共0.093兲*
401 322.559 共0.068兲*
401 433.979 共0.118兲*
401 645.331 共0.012兲*
401 645.246 共0.012兲
401 645.366 共0.012兲
401 645.383 共0.012兲
401 645.363 共0.015兲*
401 645.323 共0.015兲
401 645.333 共0.015兲
64.095
64.095
64.095
64.095
126.763
385.126
64.390
64.390
64.390
64.390
64.300
64.300
64.300
64.300
64.484
64.484
64.484
64.484
64.522
64.522
64.522
64.522
126.538
546.717
546.717
92.630
92.630
92.630
92.630
145.822
546.921
108.971
31.443
31.443
31.443
31.443
166.618
77.814
77.814
77.814
77.814
165.493
108.745
64.484
64.484
64.484
64.484
546.710
188.514
340.482
52.639
52.639
52.639
52.639
92.668
92.668
92.668
0.803
0.296
0.236
0.265
9.193
0.360
0.805
0.265
0.297
0.237
0.797
0.262
0.294
0.234
0.806
0.265
0.297
0.237
0.807
0.266
0.297
0.237
3.885
3.252
3.252
7.647
2.283
2.769
2.503
5.188
3.248
8.431
5.765
1.882
2.178
1.626
2.222
6.857
2.020
2.501
2.235
1.073
3.079
6.047
1.960
2.225
1.751
3.253
4.143
4.963
5.214
1.676
1.939
1.475
7.654
2.285
2.771
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
1
1
1
1
3
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1253
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
6
6
6
6
12
5
5
5
5
10
10
10
10
4
4
4
4
3
3
3
3
3
3
3
3
4
4
4
4
5
5
5
5
7
7
7
7
6
6
6
6
13
9
9
9
9
9
9
9
9
10
7
7
7
7
9
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
1
1
1
1
3
3
3
3
6
3
3
3
3
1
B2
A2
A2
A2
A2
E2 − 1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A1
A1
A1
A1
A2
A2
A2
A2
A1
A1
A1
A1
A2
A2
A2
A2
B2
B2
B2
B2
A1
A1
A1
A1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
E2 + 1
A2
A2
A2
A2
E1 + 1
10
10
6
6
6
6
12
5
5
5
5
10
10
10
10
4
4
4
4
3
3
3
3
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
6
6
6
6
13
8
8
8
8
9
9
9
9
11
7
7
7
7
8
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
0
0
0
0
2
2
2
2
2
1
1
1
1
2
2
2
2
5
2
2
2
2
1
B1
A1
A1
A1
A1
E2 − 1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
A1
A1
A1
A1
A2
A2
A2
A2
A1
A1
A1
A1
B1
B1
B1
B1
A2
A2
A2
A2
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
E2 + 1
A1
A1
A1
A1
E1 + 1
10
6
7
5
5
6
4
9
11
10
4
5
3
3
4
2
3
4
2
4
5
3
5
6
4
7
8
6
6
7
5
9
8
10
8
10
9
7
8
6
Obs. Freq. 共unc.兲
共MHz兲
6
7
5
5
6
4
9
11
10
4
5
3
3
4
2
3
4
2
4
5
3
5
6
4
402 397.378 共0.100兲
6
7
5
6
7
5
8
7
9
8
10
9
7
8
6
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
401 645.434 共0.015兲
401 930.113 共0.012兲*
401 929.955 共0.012兲
401 930.176 共0.012兲
401 930.214 共0.012兲
402 036.545 共0.016兲*
402 111.035 共0.013兲*
402 110.774 共0.013兲
402 111.135 共0.013兲
402 111.209 共0.013兲
402 157.302 共0.012兲*
402 157.265 共0.012兲
402 157.274 共0.012兲
402 157.366 共0.012兲
402 217.182 共0.013兲*
402 216.756 共0.013兲
402 217.336 共0.013兲
402 217.485 共0.013兲
402 272.894 共0.014兲*
402 272.157 共0.014兲
402 273.139 共0.014兲
402 273.483 共0.014兲
402 307.606 共0.014兲*
402 306.849 共0.014兲
402 307.858 共0.014兲
402 308.211 共0.014兲
402 321.433 共0.013兲*
402 320.972 共0.013兲
402 321.601 共0.013兲
402 321.762 共0.013兲
402 354.590 共0.013兲*
402 354.274 共0.013兲
402 354.712 共0.013兲
402 354.802 共0.013兲
402 397.337 共0.016兲*
402 396.492 共0.016兲
402 397.677 共0.016兲
402 397.872 共0.016兲
402 417.853 共0.012兲*
402 417.615 共0.012兲
402 417.948 共0.012兲
402 418.005 共0.012兲
402 426.990 共0.019兲*
402 458.504 共0.009兲*
402 458.503 共0.009兲
402 458.504 共0.009兲
402 458.506 共0.009兲
402 476.883 共0.013兲*
402 476.869 共0.013兲
402 476.873 共0.013兲
402 476.908 共0.013兲
402 492.173 共0.039兲*
402 524.344 共0.013兲*
402 524.151 共0.013兲
402 524.424 共0.013兲
402 524.463 共0.013兲
402 617.272 共0.009兲*
92.668
42.277
42.277
42.277
42.277
126.538
33.398
33.398
33.398
33.398
92.442
92.442
92.442
92.442
26.000
26.000
26.000
26.000
20.082
20.082
20.082
20.082
20.081
20.081
20.081
20.081
25.996
25.996
25.996
25.996
33.390
33.390
33.390
33.390
31.246
31.246
31.246
31.246
42.261
42.261
42.261
42.261
145.853
56.736
56.736
56.736
56.736
77.852
77.852
77.852
77.852
165.532
52.610
52.610
52.610
52.610
56.785
2.505
4.351
1.382
1.639
1.193
5.283
3.445
1.073
1.319
0.902
2.272
0.678
0.823
0.744
2.471
0.743
0.967
0.601
1.375
0.385
0.553
0.291
1.375
0.385
0.553
0.291
2.471
0.743
0.966
0.601
3.443
1.072
1.319
0.901
6.076
1.984
2.296
1.714
4.347
1.381
1.638
1.192
1.591
0.836
0.275
0.246
0.308
6.862
2.021
2.503
2.237
1.072
5.206
1.674
1.936
1.473
0.838
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
1
1
1
1
3
3
3
3
1
1
1
1
1
3
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1254
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
9
9
9
9
9
9
9
9
9
9
9
8
8
8
8
9
9
9
9
9
9
9
9
10
8
8
8
8
21
10
10
10
10
10
10
10
10
11
9
9
9
9
11
12
8
8
8
8
8
8
8
8
7
7
7
7
22
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
6
3
3
3
3
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
A1
A1
A1
A1
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
B2
B2
B2
B2
A2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
E1 + 1
8
10
9
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
9
9
9
9
9
9
9
9
11
8
8
8
8
21
10
10
10
10
10
10
10
10
11
9
9
9
9
11
12
8
8
8
8
8
8
8
8
7
7
7
7
21
1
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
5
2
2
2
2
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
4
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
B1
B1
B1
B1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
B2
B2
B2
E1 + 1
7
9
8
8
10
9
8
10
9
8
9
7
9
10
8
8
10
9
8
9
7
10
11
9
10
11
9
9
10
8
8
9
7
8
9
7
7
8
6
7
9
8
7
9
8
8
9
7
9
10
8
8
10
9
8
9
7
10
11
9
10
11
9
9
10
8
8
9
7
8
9
7
7
8
6
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
402 617.264 共0.009兲
402 617.268 共0.009兲
402 617.284 共0.009兲
402 664.838 共0.009兲*
402 664.827 共0.009兲
402 664.833 共0.009兲
402 664.853 共0.009兲
402 679.634 共0.009兲*
402 679.623 共0.009兲
402 679.628 共0.009兲
402 679.648 共0.009兲
402 689.640 共0.014兲*
402 689.472 共0.014兲
402 689.710 共0.014兲
402 689.740 共0.014兲
402 931.892 共0.016兲*
402 931.738 共0.016兲
402 931.958 共0.016兲
402 931.982 共0.016兲
402 934.155 共0.011兲*
402 934.148 共0.011兲
402 934.150 共0.011兲
402 934.167 共0.011兲
403 032.097 共0.042兲*
403 087.904 共0.012兲*
403 087.879 共0.012兲
403 087.915 共0.012兲
403 087.920 共0.012兲
403 271.288 共0.096兲*
403 271.966 共0.019兲*
403 271.817 共0.019兲
403 272.030 共0.019兲
403 272.052 共0.019兲
403 305.357 共0.016兲*
403 305.280 共0.016兲
403 305.390 共0.016兲
403 305.401 共0.016兲
403 309.166 共0.019兲*
403 381.990 共0.013兲*
403 381.905 共0.013兲
403 382.027 共0.013兲
403 382.040 共0.013兲
403 432.684 共0.015兲*
403 456.341 共0.024兲*
403 456.524 共0.011兲*
403 456.478 共0.011兲
403 456.543 共0.011兲
403 456.551 共0.011兲
403 488.112 共0.012兲*
403 488.006 共0.012兲
403 488.156 共0.012兲
403 488.175 共0.012兲
403 520.355 共0.012兲*
403 520.271 共0.012兲
403 520.389 共0.012兲
403 520.406 共0.012兲
403 709.184 共0.034兲*
56.785
56.785
56.785
56.767
56.767
56.767
56.767
56.610
56.610
56.610
56.610
64.436
64.436
64.436
64.436
77.738
77.738
77.738
77.738
77.627
77.627
77.627
77.627
165.295
64.522
64.522
64.522
64.522
340.549
92.516
92.516
92.516
92.516
92.201
92.201
92.201
92.201
108.469
77.409
77.409
77.409
77.409
108.745
126.210
64.300
64.300
64.300
64.300
64.095
64.095
64.095
64.095
52.677
52.677
52.677
52.677
384.978
0.247
0.309
0.276
0.839
0.247
0.309
0.276
0.836
0.246
0.308
0.275
6.031
1.955
2.219
1.746
6.829
2.226
2.491
2.011
1.475
0.434
0.538
0.481
1.073
6.051
1.961
2.226
1.752
5.400
7.600
2.488
2.752
2.269
0.272
0.089
0.099
0.081
0.554
0.117
0.038
0.043
0.034
5.332
0.982
0.778
0.252
0.286
0.225
0.043
0.014
0.016
0.013
5.216
1.677
1.940
1.476
5.973
3
3
3
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
1
3
1
1
1
1
3
3
3
3
3
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1255
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
11
7
7
7
7
13
12
6
6
6
6
6
6
6
6
14
5
5
5
5
10
10
5
5
5
5
4
4
4
4
3
3
3
3
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
12
7
7
7
7
14
10
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
3
3
6
6
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 − 1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B1
B1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
B2
B2
B2
B2
B1
B1
B1
B1
B2
B2
B2
B2
B1
B1
B1
B1
A1
B2
B2
B2
B2
E1 + 1
E2 − 1
F⬘
7
8
6
6
7
5
6
7
5
5
6
4
5
6
4
4
5
3
3
4
2
3
4
2
4
5
3
5
6
4
6
7
5
7
8
6
J⬙
K⬙a
⌫⬙
11
7
7
7
7
13
12
6
6
6
6
6
6
6
6
13
5
5
5
5
11
11
5
5
5
5
4
4
4
4
3
3
3
3
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
12
7
7
7
7
14
10
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
B2
B2
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
B2
B2
B2
B2
B1
B1
B1
B1
B2
B2
B2
B2
B1
B1
B1
B1
B2
B2
B2
B2
A2
B1
B1
B1
B1
E1 − 1
E2 − 1
F⬙
7
8
6
6
7
5
6
7
5
5
6
4
5
6
4
4
5
3
3
4
2
3
4
2
4
5
3
5
6
4
6
7
5
7
8
6
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
403 733.594 共0.024兲*
403 774.913 共0.011兲*
403 774.803 共0.011兲
403 774.958 共0.011兲
403 774.981 共0.011兲
403 808.118 共0.030兲*
403 811.824 共0.019兲*
403 812.582 共0.012兲*
403 812.425 共0.012兲
403 812.645 共0.012兲
403 812.682 共0.012兲
403 951.622 共0.011兲*
403 951.437 共0.011兲
403 951.696 共0.011兲
403 951.739 共0.011兲
403 960.233 共0.038兲*
403 998.754 共0.012兲*
403 998.493 共0.012兲
403 998.854 共0.012兲
403 998.927 共0.012兲
404 024.124 共0.039兲*
404 024.129 共0.039兲*
404 044.544 共0.011兲*
404 044.261 共0.011兲
404 044.653 共0.011兲
404 044.733 共0.011兲
404 108.460 共0.013兲*
404 108.036 共0.013兲
404 108.615 共0.013兲
404 108.764 共0.013兲
404 166.479 共0.013兲*
404 165.743 共0.013兲
404 166.725 共0.013兲
404 167.069 共0.013兲
404 201.629 共0.013兲*
404 200.872 共0.013兲
404 201.881 共0.013兲
404 202.234 共0.013兲
404 214.020 共0.013兲*
404 213.559 共0.013兲
404 214.187 共0.013兲
404 214.349 共0.013兲
404 245.346 共0.012兲*
404 245.029 共0.012兲
404 245.468 共0.012兲
404 245.557 共0.012兲
404 306.354 共0.012兲*
404 306.115 共0.012兲
404 306.449 共0.012兲
404 306.505 共0.012兲
404 343.542 共0.029兲*
404 410.129 共0.012兲*
404 409.936 共0.012兲
404 410.208 共0.012兲
404 410.248 共0.012兲
404 412.157 共0.037兲*
404 498.924 共0.014兲*
108.769
52.458
52.458
52.458
52.458
145.424
126.582
42.315
42.315
42.315
42.315
42.100
42.100
42.100
42.100
146.045
33.435
33.435
33.435
33.435
165.322
165.322
33.224
33.224
33.224
33.224
26.037
26.037
26.037
26.037
20.120
20.120
20.120
20.120
20.119
20.119
20.119
20.119
26.034
26.034
26.034
26.034
33.427
33.427
33.427
33.427
42.299
42.299
42.299
42.299
126.496
52.648
52.648
52.647
52.647
166.109
92.442
8.346
0.310
0.100
0.115
0.088
1.528
1.018
4.352
1.382
1.640
1.193
0.090
0.029
0.034
0.025
5.901
3.446
1.073
1.320
0.902
1.073
1.073
0.019
0.006
0.007
0.005
2.472
0.744
0.967
0.601
1.375
0.385
0.553
0.291
1.375
0.385
0.553
0.291
2.471
0.743
0.967
0.601
3.444
1.073
1.319
0.902
4.349
1.381
1.638
1.193
9.065
5.209
1.675
1.937
1.474
2.121
5.367
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
3
3
3
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1256
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
22
8
8
8
8
11
9
9
9
9
7
7
7
7
13
10
10
10
10
16
9
9
9
9
15
10
10
10
10
11
7
7
7
7
8
8
8
8
6
6
6
6
8
8
8
8
5
5
5
5
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
E2 − 1
E2 − 1
E2 − 1
E2 + 1
B1
B1
B1
B1
E1 − 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
9
11
10
10
10
10
21
8
8
8
8
11
9
9
9
9
6
6
6
6
13
10
10
10
10
15
9
9
9
9
15
10
10
10
10
11
7
7
7
7
8
8
8
8
6
6
6
6
8
8
8
8
5
5
5
5
4
4
4
4
2
2
2
4
2
2
2
2
2
2
2
2
2
0
0
0
0
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E1 + 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
B2
B2
B2
B2
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
9
11
10
8
9
7
9
10
8
7
8
6
10
11
9
8
10
9
9
11
10
7
8
6
8
9
7
6
7
5
8
9
7
5
6
4
4
5
3
8
9
7
9
10
8
6
7
5
10
11
9
8
10
9
9
11
10
7
8
6
8
9
7
6
7
5
8
9
7
5
6
4
4
5
3
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
404 498.886 共0.014兲
404 498.895 共0.014兲
404 498.989 共0.014兲
404 548.051 共0.038兲*
404 572.198 共0.013兲*
404 572.030 共0.013兲
404 572.268 共0.013兲
404 572.298 共0.013兲
404 801.691 共0.018兲*
404 810.647 共0.015兲*
404 810.494 共0.015兲
404 810.713 共0.015兲
404 810.738 共0.015兲
404 898.214 共0.011兲*
404 897.382 共0.011兲
404 898.549 共0.011兲
404 898.741 共0.011兲
405 131.784 共0.035兲*
405 146.260 共0.018兲*
405 146.112 共0.018兲
405 146.325 共0.018兲
405 146.346 共0.018兲
405 206.639 共0.063兲*
405 271.243 共0.013兲*
405 271.236 共0.013兲
405 271.238 共0.013兲
405 271.256 共0.013兲
405 300.544 共0.046兲*
405 475.361 共0.017兲*
405 475.358 共0.017兲
405 475.359 共0.017兲
405 475.365 共0.017兲
405 602.664 共0.022兲*
405 729.734 共0.012兲*
405 729.571 共0.012兲
405 729.801 共0.012兲
405 729.834 共0.012兲
405 756.424 共0.012兲*
405 756.281 共0.012兲
405 756.484 共0.012兲
405 756.509 共0.012兲
405 756.729 共0.012兲*
405 756.521 共0.012兲
405 756.813 共0.012兲
405 756.862 共0.012兲
405 789.022 共0.012兲*
405 788.976 共0.012兲
405 789.041 共0.012兲
405 789.049 共0.012兲
405 799.462 共0.013兲*
405 799.170 共0.013兲
405 799.574 共0.013兲
405 799.656 共0.013兲
405 836.532 共0.014兲*
405 836.089 共0.014兲
405 836.694 共0.014兲
405 836.849 共0.014兲
92.442
92.442
92.442
385.095
64.473
64.473
64.473
64.473
108.803
77.775
77.775
77.775
77.775
31.340
31.340
31.340
31.340
145.697
92.553
92.553
92.553
92.553
188.312
77.627
77.627
77.627
77.627
188.262
92.513
92.513
92.513
92.513
108.806
52.393
52.393
52.393
52.393
64.223
64.223
64.223
64.223
42.040
42.040
42.040
42.040
64.300
64.300
64.300
64.300
33.165
33.165
33.165
33.165
25.769
25.769
25.769
25.769
1.603
1.943
1.757
2.036
6.036
1.957
2.221
1.748
0.573
6.836
2.228
2.493
2.014
6.008
1.962
2.270
1.694
9.756
7.610
2.491
2.755
2.272
4.092
5.376
1.584
1.961
1.752
2.683
0.281
0.084
0.102
0.092
8.359
4.897
1.575
1.821
1.386
5.257
1.704
1.934
1.522
4.257
1.352
1.604
1.167
5.264
1.706
1.937
1.524
3.425
1.067
1.312
0.897
2.468
0.743
0.965
0.600
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
1
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1257
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
3
3
3
3
9
9
9
9
9
9
9
9
29
28
7
7
7
7
10
10
10
10
14
8
8
8
8
12
6
6
6
6
5
5
5
5
4
4
4
4
3
3
3
3
16
11
12
28
13
12
15
13
14
17
7
7
7
3
3
3
3
3
3
3
3
3
3
3
3
5
11
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
0
11
3
3
3
3
3
3
3
3
3
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E2 + 1
A1
E1 + 1
B2
E2 + 1
A2
E2 + 1
B1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
F⬘
3
4
2
9
10
8
9
10
8
7
8
6
10
11
9
8
9
7
6
7
5
5
6
4
4
5
3
3
4
2
7
8
J⬙
K⬙a
⌫⬙
3
3
3
3
9
9
9
9
9
9
9
9
28
29
7
7
7
7
10
10
10
10
14
8
8
8
8
12
6
6
6
6
5
5
5
5
4
4
4
4
3
3
3
3
16
11
11
29
13
12
15
13
14
17
7
7
7
2
2
2
2
2
2
2
2
2
2
2
2
6
10
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
10
2
2
2
2
2
2
2
2
2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 + 1
A2
E1 + 1
B1
E2 + 1
A1
E2 + 1
B2
E1 − 1
E2 + 1
E2 + 1
E2 + 1
F⬙
3
4
2
9
10
8
9
10
8
7
8
6
10
11
9
8
9
7
6
7
5
5
6
4
4
5
3
3
4
2
7
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
405 861.640 共0.015兲*
405 860.894 共0.015兲
405 861.889 共0.015兲
405 862.238 共0.015兲
405 877.409 共0.014兲*
405 877.273 共0.014兲
405 877.467 共0.014兲
405 877.489 共0.014兲
405 916.399 共0.016兲*
405 916.360 共0.016兲
405 916.416 共0.016兲
405 916.422 共0.016兲
406 048.703 共0.091兲*
406 049.772 共0.164兲*
406 102.757 共0.012兲*
406 102.647 共0.012兲
406 102.802 共0.012兲
406 102.824 共0.012兲
406 120.467 共0.017兲*
406 120.331 共0.017兲
406 120.526 共0.017兲
406 120.545 共0.017兲
406 131.689 共0.043兲*
406 197.932 共0.016兲*
406 197.849 共0.016兲
406 197.967 共0.016兲
406 197.982 共0.016兲
406 206.498 共0.027兲*
406 274.893 共0.012兲*
406 274.709 共0.012兲
406 274.967 共0.012兲
406 275.010 共0.012兲
406 363.509 共0.013兲*
406 363.226 共0.013兲
406 363.617 共0.013兲
406 363.697 共0.013兲
406 407.846 共0.014兲*
406 407.405 共0.014兲
406 408.006 共0.014兲
406 408.161 共0.014兲
406 429.383 共0.015兲*
406 428.637 共0.015兲
406 429.632 共0.015兲
406 429.980 共0.015兲
406 495.326 共0.056兲*
406 502.457 共0.021兲*
406 927.242 共0.034兲*
406 946.942 共0.227兲*
406 987.578 共0.033兲*
407 038.405 共0.026兲*
407 380.194 共0.053兲*
407 745.654 共0.032兲*
407 979.082 共0.041兲*
408 014.455 共0.067兲*
408 057.577 共0.015兲*
408 057.415 共0.015兲
408 057.644 共0.015兲
19.853
19.853
19.853
19.853
77.529
77.529
77.529
77.529
77.710
77.710
77.710
77.710
696.854
912.118
52.458
52.458
52.458
52.458
92.309
92.309
92.309
92.309
166.370
64.390
64.390
64.390
64.390
126.533
42.100
42.100
42.100
42.100
33.224
33.224
33.224
33.224
25.827
25.827
25.827
25.827
19.911
19.911
19.911
19.911
211.884
108.564
101.528
912.290
145.734
126.293
188.514
145.494
166.406
236.974
52.393
52.393
52.393
1.375
0.385
0.552
0.291
5.362
1.748
1.956
1.579
0.120
0.039
0.044
0.035
7.658
4.627
4.901
1.576
1.823
1.387
5.344
1.749
1.935
1.595
10.416
0.045
0.014
0.016
0.013
9.083
4.259
1.353
1.605
1.168
3.425
1.067
1.312
0.897
2.469
0.743
0.966
0.600
1.375
0.385
0.553
0.291
3.154
5.294
6.692
4.622
9.779
5.227
11.040
5.109
10.444
3.493
0.308
0.099
0.115
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
3
3
1
1
1
3
3
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1258
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
7
4
4
4
4
6
6
6
6
8
8
8
8
5
5
5
5
9
9
9
9
10
10
10
10
14
17
17
17
11
16
15
16
12
21
21
14
15
18
18
13
6
6
6
6
16
17
14
16
22
28
29
6
6
6
6
6
3
2
2
2
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
8
8
8
3
3
3
1
3
2
9
1
3
2
3
3
5
5
5
5
3
3
3
3
3
11
5
5
5
5
5
5
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E1 + 1
A2
A1
E2 − 1
A1
B2
E1 − 1
E2 − 1
B2
E1 + 1
A1
E2 + 1
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
A2
E2 − 1
E2 + 1
E2 − 1
E2 + 1
A1
A1
A1
A1
A1
A2
6
7
3
3
3
3
6
6
6
6
8
8
8
8
5
5
5
5
9
9
9
9
10
10
10
10
14
18
18
18
11
16
15
15
12
21
22
13
15
17
18
13
7
7
7
7
16
17
14
16
21
29
30
7
7
7
7
7
2
1
1
1
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
7
7
7
2
2
2
2
2
1
8
2
2
3
2
2
4
4
4
4
2
2
2
2
4
10
2
4
4
4
4
4
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
A1
A2
E2 + 1
A2
B1
E1 − 1
E2 + 1
B1
E1 + 1
A2
E2 + 1
E1 − 1
E1 − 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
A1
E2 + 1
E2 + 1
E2 − 1
E2 + 1
A2
A2
A2
A2
A2
A1
6
3
5
4
6
7
5
8
9
7
5
6
4
9
10
8
10
11
9
6
7
5
6
7
5
2
4
3
6
7
5
8
9
7
5
6
4
9
10
8
10
11
9
7
8
6
7
8
6
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
408 057.677 共0.015兲
408 057.703 共0.014兲*
408 057.468 共0.014兲
408 057.590 共0.014兲
408 058.021 共0.014兲
408 080.001 共0.015兲*
408 079.793 共0.015兲
408 080.084 共0.015兲
408 080.133 共0.015兲
408 088.922 共0.016兲*
408 088.780 共0.016兲
408 088.981 共0.016兲
408 089.007 共0.016兲
408 118.426 共0.016兲*
408 118.135 共0.016兲
408 118.538 共0.016兲
408 118.621 共0.016兲
408 214.497 共0.017兲*
408 214.362 共0.017兲
408 214.555 共0.017兲
408 214.577 共0.017兲
408 462.088 共0.019兲*
408 461.953 共0.019兲
408 462.147 共0.019兲
408 462.166 共0.019兲
408 643.702 共0.039兲*
408 720.484 共0.071兲*
408 774.667 共0.075兲*
408 774.667 共0.075兲*
408 848.975 共0.022兲*
408 917.985 共0.064兲*
409 217.727 共0.050兲*
409 301.556 共0.055兲*
409 391.544 共0.027兲*
409 447.116 共0.100兲*
409 586.487 共0.100兲*
409 748.746 共0.036兲*
409 752.405 共0.047兲*
409 861.634 共0.046兲*
409 874.561 共0.079兲*
410 110.444 共0.032兲*
410 618.295 共0.032兲*
410 617.741 共0.032兲
410 618.518 共0.032兲
410 618.646 共0.032兲
410 743.936 共0.061兲*
410 789.647 共0.078兲*
411 032.162 共0.039兲*
411 089.745 共0.056兲*
411 163.488 共0.051兲*
411 432.566 共0.160兲*
411 469.796 共0.875兲*
411 570.343 共0.027兲*
411 569.788 共0.027兲
411 570.565 共0.027兲
411 570.694 共0.027兲
411 570.369 共0.027兲*
52.393
12.023
12.023
12.023
12.023
42.040
42.040
42.040
42.040
64.223
64.223
64.223
64.223
33.165
33.165
33.165
33.165
77.529
77.529
77.529
77.529
92.309
92.309
92.309
92.309
166.167
385.260
385.444
385.444
108.564
212.129
188.551
188.262
126.293
340.393
546.533
146.004
188.312
250.964
263.530
145.494
85.069
85.069
85.069
85.069
212.165
237.213
166.167
211.927
385.095
912.267
696.384
84.875
84.875
84.875
84.875
84.875
0.087
0.471
0.112
0.192
0.147
0.089
0.028
0.034
0.025
0.774
0.251
0.285
0.224
0.018
0.006
0.007
0.005
1.465
0.478
0.534
0.432
2.254
0.738
0.816
0.673
4.891
2.405
2.403
2.403
3.047
11.626
11.076
3.965
3.832
5.263
3.254
5.855
4.524
2.499
3.676
4.639
0.337
0.110
0.127
0.095
11.669
12.169
5.514
3.977
4.288
4.618
0.017
0.337
0.110
0.127
0.095
0.337
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
3
3
1
3
3
1
1
3
3
1
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1259
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
6
6
6
4
4
4
4
22
22
19
15
17
22
17
10
10
18
18
7
7
7
7
4
4
4
4
14
16
17
17
18
8
8
8
8
14
18
20
11
18
10
10
10
10
9
9
9
9
12
8
8
8
8
7
7
7
7
5
5
5
2
2
2
2
3
3
3
3
3
3
3
6
6
2
3
1
1
1
1
2
2
2
2
1
3
8
8
3
1
1
1
1
1
2
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
E1 − 1
E1 + 1
E2 − 1
B2
E2 + 1
E2 + 1
A1
A2
E2 − 1
A1
A2
A2
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 − 1
B2
B1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
B1
E1 + 1
E1 − 1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
6
7
5
7
7
7
3
3
3
3
21
21
19
15
17
21
17
11
11
17
18
6
6
6
6
3
3
3
3
13
16
18
18
18
7
7
7
7
13
17
20
11
18
10
10
10
10
9
9
9
9
12
8
8
8
8
7
7
7
7
4
4
4
1
1
1
1
4
4
2
2
2
4
2
5
5
3
2
0
0
0
0
1
1
1
1
2
2
7
7
2
0
0
0
0
2
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 − 1
E1 − 1
E2 + 1
B1
E2 + 1
E2 + 1
A2
A1
E2 − 1
A2
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 + 1
B1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B2
E1 − 1
E1 − 1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
7
8
6
3
5
4
7
8
6
3
5
4
7
9
8
10
11
9
9
10
8
8
9
7
7
8
6
2
4
3
6
7
5
2
4
3
6
8
7
10
11
9
9
10
8
8
9
7
7
8
6
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
411 569.814 共0.027兲
411 570.591 共0.027兲
411 570.720 共0.027兲
411 629.878 共0.014兲*
411 629.835 共0.014兲
411 629.845 共0.014兲
411 629.956 共0.014兲
411 719.182 共0.038兲*
411 898.486 共0.048兲*
412 090.708 共0.093兲*
412 189.917 共0.048兲*
412 601.994 共0.075兲*
412 610.440 共0.033兲*
412 670.097 共0.066兲*
412 774.447 共0.039兲*
412 774.452 共0.039兲*
412 994.952 共0.047兲*
413 043.784 共0.096兲*
413 281.398 共0.016兲*
413 280.554 共0.016兲
413 281.738 共0.016兲
413 281.932 共0.016兲
413 373.663 共0.014兲*
413 373.622 共0.014兲
413 373.631 共0.014兲
413 373.739 共0.014兲
413 585.949 共0.024兲*
413 624.826 共0.058兲*
413 847.911 共0.067兲*
413 847.911 共0.067兲*
414 504.353 共0.077兲*
414 590.061 共0.012兲*
414 589.709 共0.012兲
414 589.800 共0.012兲
414 590.665 共0.012兲
414 612.395 共0.018兲*
414 638.439 共0.047兲*
414 674.458 共0.109兲*
414 830.257 共0.020兲*
414 840.169 共0.093兲*
414 840.833 共0.017兲*
414 840.758 共0.017兲
414 840.866 共0.017兲
414 840.877 共0.017兲
414 928.839 共0.014兲*
414 928.755 共0.014兲
414 928.875 共0.014兲
414 928.888 共0.014兲
414 959.789 共0.025兲*
415 043.713 共0.013兲*
415 043.608 共0.013兲
415 043.757 共0.013兲
415 043.776 共0.013兲
415 153.260 共0.012兲*
415 153.118 共0.012兲
415 153.318 共0.012兲
415 153.347 共0.012兲
84.875
84.875
84.875
12.039
12.039
12.039
12.039
384.930
385.126
291.552
188.312
237.249
384.826
237.011
165.133
165.133
250.867
263.765
31.040
31.040
31.040
31.040
12.039
12.039
12.039
12.039
145.822
211.927
385.416
385.416
263.563
41.781
41.781
41.781
41.781
145.853
251.012
321.039
108.469
263.801
92.201
92.201
92.201
92.201
77.409
77.409
77.409
77.409
126.210
64.095
64.095
64.095
64.095
52.261
52.261
52.261
52.261
0.110
0.127
0.095
2.850
0.679
1.161
0.891
6.309
5.943
3.690
6.504
12.221
4.287
3.270
1.074
1.074
4.398
12.663
6.082
1.986
2.298
1.715
0.182
0.043
0.074
0.057
5.859
7.634
2.401
2.401
2.489
0.214
0.062
0.080
0.070
5.270
5.619
3.528
7.803
12.725
7.337
2.401
2.657
2.191
6.719
2.190
2.451
1.979
8.094
5.992
1.942
2.205
1.735
5.195
1.670
1.932
1.470
1
1
1
1
1
1
1
1
3
3
1
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1260
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
12
6
6
6
6
13
5
5
5
5
4
4
4
4
4
4
4
4
3
3
3
3
17
18
19
28
14
29
6
6
6
6
18
28
28
22
19
15
4
4
4
4
19
18
12
21
22
16
22
26
17
19
24
20
20
22
17
0
3
3
3
3
3
3
3
3
3
2
2
2
2
3
3
3
3
3
3
3
3
3
2
3
11
3
5
5
5
5
5
2
11
11
3
3
3
2
2
2
2
3
3
0
3
3
3
2
4
8
2
10
3
3
3
3
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
A2
E1 − 1
E1 − 1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
B2
B1
E1 − 1
E2 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
E2 − 1
B1
E1 + 1
A1
E1 − 1
E1 + 1
E2 + 1
E2 − 1
E1 − 1
E1 − 1
A1
E2 + 1
E2 − 1
E1 − 1
F⬘
6
7
5
5
6
4
4
5
3
4
5
3
3
4
2
6
7
5
3
5
4
J⬙
K⬙a
⌫⬙
11
6
6
6
6
13
5
5
5
5
3
3
3
3
4
4
4
4
3
3
3
3
17
17
19
29
14
30
7
7
7
7
17
29
29
21
19
15
3
3
3
3
19
18
11
21
21
16
22
25
18
18
25
20
20
21
17
1
2
2
2
2
2
2
2
2
2
1
1
1
1
2
2
2
2
2
2
2
2
2
3
2
10
2
2
4
4
4
4
3
10
10
4
2
2
1
1
1
1
2
2
1
2
4
2
1
5
7
3
9
2
2
4
2
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
A1
E1 − 1
E1 − 1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
B1
B2
E1 + 1
E2 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
E2 + 1
B2
E1 − 1
A2
E1 − 1
E1 − 1
E2 + 1
E2 − 1
E1 − 1
E1 − 1
A2
E2 + 1
E2 + 1
E1 − 1
F⬙
6
7
5
5
6
4
3
4
2
4
5
3
3
4
2
7
8
6
2
4
3
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
415 214.757 共0.019兲*
415 241.997 共0.012兲*
415 241.798 共0.012兲
415 242.076 共0.012兲
415 242.123 共0.012兲
415 290.789 共0.030兲*
415 305.987 共0.012兲*
415 305.699 共0.012兲
415 306.098 共0.012兲
415 306.179 共0.012兲
415 336.609 共0.012兲*
415 335.830 共0.012兲
415 336.862 共0.012兲
415 337.252 共0.012兲
415 347.713 共0.013兲*
415 347.271 共0.013兲
415 347.874 共0.013兲
415 348.029 共0.013兲
415 372.317 共0.014兲*
415 371.570 共0.014兲
415 372.565 共0.014兲
415 372.914 共0.014兲
415 386.874 共0.070兲*
415 711.729 共0.050兲*
415 733.089 共0.117兲*
415 833.937 共0.170兲*
415 871.804 共0.037兲*
415 971.560 共0.876兲*
416 129.378 共0.030兲*
416 128.824 共0.030兲
416 129.601 共0.030兲
416 129.730 共0.030兲
416 140.414 共0.053兲*
416 317.360 共0.186兲*
416 317.360 共0.186兲*
416 327.408 共0.040兲*
416 602.678 共0.089兲*
416 737.248 共0.045兲*
416 814.475 共0.013兲*
416 814.240 共0.013兲
416 814.362 共0.013兲
416 814.793 共0.013兲
417 510.782 共0.115兲*
417 534.237 共0.086兲*
417 625.661 共0.035兲*
417 631.533 共0.126兲*
417 759.215 共0.049兲*
417 914.056 共0.055兲*
417 928.940 共0.144兲*
418 386.770 共0.068兲*
418 750.289 共0.071兲*
418 769.061 共0.055兲*
418 894.612 共0.140兲*
418 914.342 共0.143兲*
418 978.130 共0.104兲*
419 225.877 共0.044兲*
419 429.380 共0.067兲*
101.542
41.905
41.905
41.905
41.905
145.424
33.030
33.030
33.030
33.030
11.780
11.780
11.780
11.780
25.634
25.634
25.634
25.634
19.717
19.717
19.717
19.717
237.011
250.776
291.784
911.956
166.109
696.409
85.037
85.037
85.037
85.037
250.916
912.108
912.108
384.978
291.582
188.262
12.023
12.023
12.023
12.023
291.819
263.563
101.373
351.990
384.936
211.884
372.643
548.145
385.276
277.584
698.962
321.268
321.066
384.826
236.974
6.590
4.345
1.380
1.637
1.191
8.235
3.443
1.072
1.319
0.901
2.541
0.794
1.035
0.605
2.471
0.743
0.966
0.601
1.375
0.385
0.553
0.291
8.881
1.250
13.104
4.627
8.296
0.019
0.337
0.110
0.127
0.095
5.656
4.624
4.624
0.369
1.756
8.351
2.576
0.613
1.049
0.805
13.178
10.153
6.665
3.203
6.338
8.457
4.663
7.160
2.403
2.968
3.768
13.486
1.166
2.055
8.651
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
3
3
3
1
1
1
1
1
3
3
3
1
3
3
3
3
3
3
1
3
3
1
3
3
1
1
3
3
1
1
1
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1261
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
17
22
12
19
4
4
4
4
17
20
8
8
8
8
22
22
13
26
6
6
6
6
18
18
28
28
21
26
19
22
21
26
17
6
6
6
6
6
6
6
6
20
14
19
26
4
4
4
4
21
17
4
4
4
4
22
23
8
3
0
3
2
2
2
2
1
3
1
1
1
1
2
3
7
4
5
5
5
5
2
3
11
11
3
4
2
2
3
4
1
5
5
5
5
5
5
5
5
3
1
3
4
2
2
2
2
3
8
2
2
2
2
3
3
E2 + 1
B2
E2 + 1
E2 − 1
A1
A1
A1
A1
E2 − 1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E1 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
A2
A1
E2 + 1
B2
E2 + 1
A1
A2
B1
E1 − 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
E2 + 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
F⬘
3
5
4
7
9
8
6
7
5
6
7
5
6
7
5
4
5
3
4
5
3
J⬙
K⬙a
⌫⬙
18
21
11
19
3
3
3
3
16
20
7
7
7
7
22
22
14
25
7
7
7
7
17
18
29
29
21
25
18
22
21
25
16
7
7
7
7
7
7
7
7
20
13
19
25
3
3
3
3
21
18
3
3
3
3
22
23
7
4
1
2
1
1
1
1
2
2
0
0
0
0
1
2
6
5
4
4
4
4
3
2
10
10
2
5
3
1
2
5
2
4
4
4
4
4
4
4
4
2
2
2
5
1
1
1
1
2
7
1
1
1
1
2
2
E2 + 1
B1
E2 + 1
E2 + 1
A2
A2
A2
A2
E2 − 1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 − 1
E2 + 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
A1
A2
E2 + 1
B1
E2 − 1
A2
A1
B2
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E1 − 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E1 − 1
F⬙
2
4
3
6
8
7
7
8
6
7
8
6
7
8
6
3
4
2
3
4
2
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
419 457.307 共0.081兲*
419 972.496 共0.043兲*
420 078.246 共0.018兲*
420 130.119 共0.104兲*
420 399.985 共0.013兲*
420 399.595 共0.013兲
420 399.809 共0.013兲
420 400.496 共0.013兲
420 457.966 共0.039兲*
420 670.216 共0.141兲*
420 934.418 共0.011兲*
420 934.042 共0.011兲
420 934.140 共0.011兲
420 935.062 共0.011兲
420 954.152 共0.147兲*
420 960.507 共0.146兲*
421 044.671 共0.057兲*
421 081.392 共0.084兲*
421 092.096 共0.030兲*
421 091.542 共0.030兲
421 092.318 共0.030兲
421 092.447 共0.030兲
421 276.559 共0.045兲*
421 315.933 共0.080兲*
421 641.181 共0.203兲*
421 641.181 共0.203兲*
421 648.070 共0.121兲*
421 978.317 共0.070兲*
422 448.496 共0.062兲*
422 541.894 共0.124兲*
422 648.315 共0.176兲*
422 871.725 共0.068兲*
422 915.719 共0.037兲*
422 931.395 共0.029兲*
422 930.841 共0.029兲
422 931.618 共0.029兲
422 931.747 共0.029兲
422 931.422 共0.029兲*
422 930.868 共0.029兲
422 931.645 共0.029兲
422 931.773 共0.029兲
423 238.754 共0.126兲*
423 421.019 共0.018兲*
423 615.255 共0.097兲*
423 881.634 共0.067兲*
424 093.382 共0.011兲*
424 092.603 共0.011兲
424 093.635 共0.011兲
424 094.024 共0.011兲
424 378.826 共0.175兲*
424 443.078 共0.077兲*
424 625.610 共0.012兲*
424 625.073 共0.012兲
424 625.782 共0.012兲
424 626.059 共0.012兲
424 632.800 共0.141兲*
424 653.918 共0.168兲*
385.082
384.749
101.481
291.582
11.977
11.977
11.977
11.977
212.631
321.303
41.678
41.678
41.678
41.678
372.561
384.403
252.854
548.055
84.918
84.918
84.918
84.918
250.583
263.530
911.969
911.969
352.014
547.936
277.491
372.628
352.217
547.936
212.635
84.686
84.686
84.686
84.686
84.686
84.686
84.686
84.686
321.066
145.494
291.552
548.108
11.780
11.780
11.780
11.780
352.250
385.125
11.605
11.605
11.605
11.605
384.425
418.276
2.405
6.327
6.520
11.322
3.056
0.728
1.245
0.955
0.045
13.572
0.041
0.012
0.015
0.014
4.615
2.747
1.574
0.026
0.337
0.110
0.127
0.095
3.168
8.951
4.627
4.627
0.743
7.198
0.918
5.056
13.803
7.201
0.113
0.337
0.110
0.127
0.095
0.337
0.110
0.127
0.095
12.291
0.110
9.367
7.095
0.436
0.136
0.178
0.104
13.904
2.404
0.159
0.050
0.065
0.038
0.464
2.219
1
3
1
1
1
1
1
1
1
3
3
3
3
3
1
3
1
1
3
3
3
3
3
3
1
1
1
3
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1262
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
19
4
4
4
4
22
24
24
26
4
4
4
4
4
4
4
4
20
24
21
6
6
6
6
22
19
14
23
26
22
24
22
26
19
13
13
21
26
19
22
24
30
4
4
4
4
30
24
11
17
23
26
25
26
24
22
13
2
2
2
2
2
3
10
10
4
2
2
2
2
2
2
2
2
3
10
3
5
5
5
5
3
2
1
3
4
3
3
2
4
2
7
7
3
4
2
3
10
5
2
2
2
2
5
3
0
1
3
4
3
4
10
3
7
E2 + 1
A2
A2
A2
A2
B1
A2
A1
E2 − 1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
B1
E1 + 1
E2 + 1
E1 − 1
B1
E1 + 1
B1
E2 − 1
A1
E1 − 1
E1 + 1
E1 − 1
E1 + 1
E1 − 1
E2 − 1
E1 + 1
A2
B2
B2
B2
B2
A1
E2 + 1
E2 + 1
B1
A2
A2
E1 + 1
A1
E2 + 1
E1 − 1
A1
F⬘
4
5
3
3
5
4
4
5
3
6
7
5
4
5
3
J⬙
K⬙a
⌫⬙
18
3
3
3
3
21
25
25
25
3
3
3
3
3
3
3
3
20
25
21
7
7
7
7
22
18
13
23
25
22
24
22
25
18
14
14
21
25
18
22
25
29
3
3
3
3
29
24
10
16
23
25
25
25
25
22
14
3
1
1
1
1
4
9
9
5
1
1
1
1
1
1
1
1
2
9
2
4
4
4
4
2
3
2
2
5
2
2
1
5
3
6
6
2
5
3
2
9
6
1
1
1
1
6
2
1
2
2
5
2
5
9
2
6
E2 + 1
A1
A1
A1
A1
B2
A1
A2
E2 + 1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
B2
E1 − 1
E2 + 1
E1 + 1
B2
E1 − 1
B2
E2 − 1
A2
E1 − 1
E1 + 1
E1 − 1
E1 − 1
E1 + 1
E2 + 1
E1 + 1
A1
B1
B1
B1
B1
A2
E2 + 1
E2 − 1
B2
A1
A1
E1 − 1
A2
E2 + 1
E1 − 1
A2
F⬙
3
4
2
2
4
3
3
4
2
7
8
6
3
4
2
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
425 478.380 共0.053兲*
425 574.685 共0.013兲*
425 573.715 共0.013兲
425 575.001 共0.013兲
425 575.481 共0.013兲
425 886.267 共0.048兲*
425 989.309 共0.125兲*
425 989.309 共0.125兲*
426 193.674 共0.048兲*
426 277.943 共0.013兲*
426 277.553 共0.013兲
426 277.767 共0.013兲
426 278.453 共0.013兲
426 369.395 共0.012兲*
426 368.856 共0.012兲
426 369.568 共0.012兲
426 369.846 共0.012兲
426 379.935 共0.117兲*
426 394.352 共0.116兲*
426 923.600 共0.153兲*
426 974.210 共0.030兲*
426 973.656 共0.030兲
426 974.433 共0.030兲
426 974.561 共0.030兲
426 999.548 共0.217兲*
427 038.878 共0.077兲*
427 476.193 共0.018兲*
427 953.325 共0.164兲*
428 194.333 共0.050兲*
428 700.739 共0.216兲*
428 702.262 共0.193兲*
428 741.227 共0.128兲*
428 888.295 共0.050兲*
428 888.834 共0.077兲*
428 898.302 共0.057兲*
429 281.783 共0.055兲*
429 675.132 共0.141兲*
429 751.602 共0.083兲*
430 210.433 共0.052兲*
431 248.237 共0.183兲*
431 337.336 共0.133兲*
431 404.899 共0.107兲*
431 460.490 共0.013兲*
431 459.521 共0.013兲
431 460.806 共0.013兲
431 461.287 共0.013兲
431 514.754 共0.107兲*
431 629.754 共0.193兲*
431 783.376 共0.017兲*
431 844.117 共0.091兲*
432 035.982 共0.267兲*
432 621.197 共0.068兲*
433 099.336 共0.223兲*
433 495.592 共0.063兲*
433 547.996 共0.153兲*
433 578.731 共0.171兲*
433 580.609 共0.059兲*
277.390
11.801
11.801
11.801
11.801
384.755
698.737
698.737
548.145
11.818
11.818
11.818
11.818
11.605
11.605
11.605
11.605
321.039
698.877
352.014
84.761
84.761
84.761
84.761
384.628
277.574
145.424
418.298
548.108
384.661
453.609
372.472
548.055
277.478
252.635
252.760
351.990
547.912
277.202
384.425
698.882
739.981
11.642
11.642
11.642
11.642
739.981
453.629
83.420
212.165
418.500
547.756
490.400
547.757
698.785
384.403
252.799
4.816
2.963
0.926
1.207
0.706
6.360
3.772
3.772
0.026
3.058
0.728
1.246
0.956
2.833
0.885
1.154
0.675
9.899
3.766
13.027
0.337
0.110
0.127
0.095
14.052
5.700
0.682
0.287
0.078
14.167
1.688
4.917
7.138
5.723
1.574
1.573
10.529
0.078
2.778
13.550
3.766
8.059
2.963
0.926
1.207
0.706
8.059
0.177
0.091
4.365
14.226
7.205
1.215
7.208
3.769
11.220
1.573
1
1
1
1
1
3
1
1
1
3
3
3
3
1
1
1
1
3
1
1
1
1
1
1
1
3
3
1
3
3
3
3
1
1
3
3
3
3
3
1
3
1
3
3
3
3
1
1
1
3
1
1
3
1
1
3
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1263
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
13
23
26
20
20
24
24
25
13
13
23
9
9
9
9
17
24
26
23
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
23
13
24
30
30
26
30
30
17
23
10
10
10
10
10
10
10
10
24
10
10
10
7
3
4
9
9
10
10
3
7
7
3
6
6
6
6
1
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
7
3
5
5
3
5
5
1
2
0
0
0
0
0
0
0
0
3
0
0
0
A2
B2
E1 − 1
B1
B2
B2
B1
E2 + 1
B1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
E1 + 1
E1 − 1
A2
A2
A2
A2
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E2 − 1
B1
B2
B1
E2 + 1
E1 − 1
E2 + 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
B1
B1
B1
F⬘
9
10
8
11
9
10
11
9
10
11
9
10
11
9
10
11
9
10
11
9
10
11
9
J⬙
K⬙a
⌫⬙
14
23
25
21
21
25
25
25
14
14
23
10
10
10
10
16
24
26
23
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
23
14
24
29
29
26
29
29
16
23
9
9
9
9
9
9
9
9
24
9
9
9
6
2
5
8
8
9
9
2
6
6
2
5
5
5
5
2
2
2
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
2
6
6
2
6
6
2
1
0
0
0
0
0
0
0
0
2
0
0
0
A1
B1
E1 − 1
B2
B1
B1
B2
E2 + 1
B2
B1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
E1 − 1
E1 − 1
A1
A1
A1
A1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E2 − 1
B2
B1
B2
E2 + 1
E1 − 1
E2 + 1
E2 + 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B2
B2
B2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
10
11
9
10
8
9
10
8
9
10
8
9
10
8
9
442 044.358 共0.100兲
10
8
9
442 055.811 共0.100兲
10
8
9
442 084.152 共0.100兲
10
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
433 580.609 共0.059兲*
433 703.502 共0.266兲*
434 064.301 共0.059兲*
434 339.909 共0.102兲*
434 339.909 共0.102兲*
435 676.732 共0.136兲*
435 676.732 共0.136兲*
435 680.512 共0.226兲*
435 804.101 共0.064兲*
435 804.101 共0.064兲*
436 278.001 共0.219兲*
436 940.832 共0.045兲*
436 940.524 共0.045兲
436 940.965 共0.045兲
436 941.011 共0.045兲
437 645.755 共0.087兲*
437 828.414 共0.327兲*
437 845.963 共0.258兲*
438 179.018 共0.207兲*
438 556.184 共0.011兲*
438 556.169 共0.011兲
438 556.189 共0.011兲
438 556.197 共0.011兲
438 557.603 共0.011兲*
438 557.589 共0.011兲
438 557.608 共0.011兲
438 557.616 共0.011兲
438 592.913 共0.011兲*
438 592.898 共0.011兲
438 592.917 共0.011兲
438 592.928 共0.011兲
438 718.527 共0.011兲*
438 718.508 共0.011兲
438 718.526 共0.011兲
438 718.550 共0.011兲
438 757.658 共0.179兲*
439 336.076 共0.063兲*
439 457.568 共0.328兲*
439 488.819 共0.105兲*
439 597.090 共0.105兲*
440 122.063 共0.265兲*
440 844.259 共0.118兲*
441 270.613 共0.094兲*
441 568.581 共0.081兲*
441 819.934 共0.183兲*
442 044.515 共0.011兲*
442 044.493 共0.011兲
442 044.499 共0.011兲
442 044.555 共0.011兲
442 055.805 共0.011兲*
442 055.782 共0.011兲
442 055.789 共0.011兲
442 055.844 共0.011兲
442 080.861 共0.261兲*
442 084.115 共0.011兲*
442 084.093 共0.011兲
442 084.100 共0.011兲
252.799
418.532
547.912
514.384
514.384
698.556
698.556
490.419
252.696
252.696
418.298
149.185
149.185
149.185
149.185
212.129
453.832
528.648
418.276
68.880
68.880
68.880
68.880
68.721
68.721
68.721
68.721
68.888
68.888
68.888
68.888
68.785
68.785
68.785
68.786
406.169
252.439
453.863
739.885
739.885
528.665
739.815
740.031
211.927
406.088
66.868
66.868
66.868
66.868
66.765
66.765
66.765
66.765
453.629
66.672
66.672
66.672
1.573
14.357
7.108
2.920
2.920
3.772
3.772
0.109
1.573
1.573
13.897
0.787
0.260
0.287
0.235
4.353
14.322
0.835
11.908
0.934
0.341
0.278
0.308
0.932
0.340
0.278
0.308
0.933
0.341
0.278
0.308
0.932
0.340
0.278
0.308
4.329
1.574
14.470
8.052
8.052
0.068
8.050
8.016
4.313
4.273
0.943
0.344
0.281
0.311
0.941
0.343
0.281
0.310
14.098
0.944
0.345
0.282
1
3
3
3
3
3
3
1
3
3
1
1
1
1
1
1
1
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
1
3
3
3
1
3
1
1
1
1
1
1
1
3
3
3
3
1
3
3
3
Ref.
11
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1264
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
10
10
30
27
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
0
0
0
0
0
5
3
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
2
2
2
2
2
2
2
2
8
8
8
8
8
8
8
8
8
8
B1
A1
A1
A1
A1
E1 + 1
E1 + 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
10
9
9
9
9
9
29
27
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
0
0
0
0
0
6
2
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
2
2
2
2
2
2
2
2
8
8
8
8
8
8
8
8
8
8
B2
A2
A2
A2
A2
E1 + 1
E1 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
9
11
9
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
11
9
10
11
9
10
9
11
10
9
11
10
9
Obs. Freq. 共unc.兲
共MHz兲
442 105.756 共0.100兲
10
8
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
10
8
9
10
8
9
8
10
9
8
10
9
8
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
442 084.153 共0.011兲
442 105.720 共0.011兲*
442 105.699 共0.011兲
442 105.705 共0.011兲
442 105.758 共0.011兲
442 863.285 共0.110兲*
442 950.319 共0.300兲*
442 978.948 共0.054兲*
442 978.768 共0.054兲
442 978.826 共0.054兲
442 979.242 共0.054兲
442 978.948 共0.054兲*
442 978.768 共0.054兲
442 978.826 共0.054兲
442 979.242 共0.054兲
442 983.878 共0.054兲*
442 983.697 共0.054兲
442 983.756 共0.054兲
442 984.172 共0.054兲
442 984.037 共0.055兲*
442 983.856 共0.055兲
442 983.915 共0.055兲
442 984.331 共0.055兲
442 986.475 共0.054兲*
442 986.294 共0.054兲
442 986.353 共0.054兲
442 986.769 共0.054兲
442 986.475 共0.054兲*
442 986.294 共0.054兲
442 986.353 共0.054兲
442 986.769 共0.054兲
442 986.703 共0.054兲*
442 986.523 共0.054兲
442 986.581 共0.054兲
442 986.998 共0.054兲
442 988.736 共0.054兲*
442 988.556 共0.054兲
442 988.614 共0.054兲
442 989.030 共0.054兲
443 029.780 共0.011兲*
443 029.768 共0.011兲
443 029.773 共0.011兲
443 029.802 共0.011兲
443 032.533 共0.011兲*
443 032.521 共0.011兲
443 032.526 共0.011兲
443 032.555 共0.011兲
443 039.701 共0.043兲*
443 039.560 共0.043兲
443 039.605 共0.043兲
443 039.934 共0.043兲
443 041.565 共0.042兲*
443 041.424 共0.042兲
443 041.468 共0.042兲
443 041.797 共0.042兲
443 041.565 共0.042兲*
443 041.424 共0.042兲
66.672
66.468
66.468
66.468
66.468
739.942
568.350
285.376
285.376
285.376
285.375
285.376
285.376
285.376
285.375
285.598
285.598
285.598
285.598
285.516
285.516
285.516
285.516
285.187
285.187
285.187
285.187
285.187
285.187
285.187
285.187
285.415
285.415
285.415
285.415
285.509
285.509
285.509
285.509
77.775
77.775
77.775
77.775
77.738
77.738
77.738
77.738
239.520
239.520
239.520
239.520
239.666
239.666
239.666
239.666
239.666
239.666
0.312
0.940
0.343
0.280
0.310
8.039
0.553
0.177
0.053
0.065
0.059
0.177
0.053
0.065
0.059
0.178
0.053
0.065
0.059
0.178
0.053
0.065
0.059
0.181
0.054
0.066
0.060
0.181
0.054
0.066
0.060
0.180
0.054
0.066
0.059
0.180
0.054
0.066
0.059
0.905
0.330
0.270
0.299
0.904
0.330
0.270
0.298
0.337
0.101
0.123
0.111
0.338
0.101
0.123
0.111
0.338
0.101
3
1
1
1
1
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1265
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
2
2
2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
11
10
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
8
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
2
2
2
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
10
9
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
11
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
10
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
443 041.468 共0.042兲
443 041.797 共0.042兲
443 046.497 共0.043兲*
443 046.356 共0.043兲
443 046.400 共0.043兲
443 046.729 共0.043兲
443 046.590 共0.043兲*
443 046.449 共0.043兲
443 046.493 共0.043兲
443 046.822 共0.043兲
443 046.753 共0.042兲*
443 046.612 共0.042兲
443 046.656 共0.042兲
443 046.985 共0.042兲
443 048.198 共0.043兲*
443 048.057 共0.043兲
443 048.102 共0.043兲
443 048.431 共0.043兲
443 048.198 共0.043兲*
443 048.057 共0.043兲
443 048.102 共0.043兲
443 048.431 共0.043兲
443 095.147 共0.034兲*
443 095.041 共0.034兲
443 095.073 共0.034兲
443 095.325 共0.034兲
443 097.109 共0.034兲*
443 097.003 共0.034兲
443 097.034 共0.034兲
443 097.287 共0.034兲
443 100.935 共0.033兲*
443 100.829 共0.033兲
443 100.860 共0.033兲
443 101.113 共0.033兲
443 100.935 共0.033兲*
443 100.829 共0.033兲
443 100.860 共0.033兲
443 101.113 共0.033兲
443 102.605 共0.034兲*
443 102.499 共0.034兲
443 102.530 共0.034兲
443 102.783 共0.034兲
443 102.959 共0.034兲*
443 102.852 共0.034兲
443 102.884 共0.034兲
443 103.136 共0.034兲
443 103.244 共0.034兲*
443 103.137 共0.034兲
443 103.169 共0.034兲
443 103.422 共0.034兲
443 103.244 共0.034兲*
443 103.137 共0.034兲
443 103.169 共0.034兲
443 103.422 共0.034兲
443 111.062 共0.011兲*
443 111.047 共0.011兲
443 111.051 共0.011兲
239.666
239.666
239.726
239.727
239.727
239.726
239.337
239.337
239.337
239.337
239.687
239.687
239.687
239.687
239.522
239.522
239.522
239.522
239.522
239.522
239.522
239.522
199.099
199.099
199.099
199.099
199.113
199.113
199.113
199.113
199.280
199.280
199.280
199.280
199.280
199.280
199.280
199.280
198.960
198.960
198.960
198.960
198.917
198.917
198.917
198.917
199.251
199.251
199.251
199.251
199.251
199.251
199.251
199.251
77.529
77.529
77.529
0.123
0.111
0.339
0.101
0.124
0.112
0.342
0.102
0.125
0.113
0.340
0.101
0.124
0.112
0.341
0.102
0.124
0.113
0.341
0.102
0.124
0.113
0.479
0.143
0.175
0.158
0.479
0.143
0.175
0.158
0.480
0.143
0.175
0.159
0.480
0.143
0.175
0.159
0.482
0.144
0.176
0.159
0.483
0.144
0.176
0.159
0.481
0.143
0.176
0.159
0.481
0.143
0.176
0.159
0.897
0.328
0.268
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1266
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
10
10
10
10
10
10
23
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
2
6
6
6
6
6
6
6
6
2
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A2
A2
A2
A2
A2
A1
A1
A1
A1
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
10
9
9
9
9
9
9
9
9
9
23
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
2
6
6
6
6
6
6
6
6
1
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
5
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A1
A2
A2
A2
A2
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
9
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
443 111.090 共0.011兲
443 146.905 共0.027兲*
443 146.828 共0.027兲
443 146.849 共0.027兲
443 147.035 共0.027兲
443 150.822 共0.026兲*
443 150.746 共0.026兲
443 150.766 共0.026兲
443 150.952 共0.026兲
443 151.444 共0.159兲*
443 151.610 共0.027兲*
443 151.534 共0.027兲
443 151.554 共0.027兲
443 151.740 共0.027兲
443 151.610 共0.027兲*
443 151.534 共0.027兲
443 151.554 共0.027兲
443 151.740 共0.027兲
443 155.052 共0.027兲*
443 154.975 共0.027兲
443 154.996 共0.027兲
443 155.182 共0.027兲
443 155.052 共0.027兲*
443 154.975 共0.027兲
443 154.996 共0.027兲
443 155.182 共0.027兲
443 155.166 共0.027兲*
443 155.089 共0.027兲
443 155.110 共0.027兲
443 155.296 共0.027兲
443 155.635 共0.027兲*
443 155.559 共0.027兲
443 155.579 共0.027兲
443 155.765 共0.027兲
443 200.035 共0.021兲*
443 199.984 共0.021兲
443 199.995 共0.021兲
443 200.124 共0.021兲
443 200.036 共0.021兲*
443 199.985 共0.021兲
443 199.996 共0.021兲
443 200.125 共0.021兲
443 200.487 共0.021兲*
443 200.436 共0.021兲
443 200.448 共0.021兲
443 200.577 共0.021兲
443 205.150 共0.021兲*
443 205.099 共0.021兲
443 205.111 共0.021兲
443 205.240 共0.021兲
443 205.979 共0.021兲*
443 205.928 共0.021兲
443 205.940 共0.021兲
443 206.069 共0.021兲
443 207.579 共0.021兲*
443 207.528 共0.021兲
443 207.540 共0.021兲
77.529
163.957
163.957
163.957
163.957
164.176
164.176
164.176
164.176
406.153
164.120
164.120
164.120
164.120
164.120
164.120
164.120
164.120
164.016
164.016
164.016
164.016
164.016
164.016
164.016
164.016
163.759
163.759
163.759
163.759
164.081
164.081
164.081
164.081
134.277
134.277
134.277
134.277
134.277
134.277
134.277
134.277
134.401
134.401
134.401
134.401
134.487
134.487
134.487
134.487
134.448
134.448
134.448
134.448
134.250
134.250
134.250
0.296
0.601
0.179
0.220
0.198
0.602
0.180
0.220
0.199
4.714
0.602
0.180
0.220
0.199
0.602
0.180
0.220
0.199
0.604
0.180
0.221
0.199
0.604
0.180
0.221
0.199
0.605
0.180
0.221
0.200
0.604
0.180
0.221
0.199
0.706
0.211
0.258
0.233
0.706
0.211
0.258
0.233
0.706
0.211
0.258
0.233
0.707
0.211
0.258
0.233
0.707
0.211
0.258
0.233
0.708
0.211
0.258
1
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1267
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
5
5
5
5
5
5
5
5
5
9
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
E1 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E2 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
B2
B2
B2
B2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
10
9
9
9
9
9
9
9
9
9
21
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
5
5
5
5
5
5
5
5
5
8
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
E1 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E2 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
B1
B1
B1
B1
A1
A1
A1
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
9
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
9
11
10
11
9
10
11
9
10
11
9
10
11
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
8
10
9
10
8
9
10
8
9
10
8
9
10
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
443 207.669 共0.021兲
443 207.946 共0.021兲*
443 207.895 共0.021兲
443 207.906 共0.021兲
443 208.035 共0.021兲
443 207.947 共0.021兲*
443 207.896 共0.021兲
443 207.907 共0.021兲
443 208.036 共0.021兲
443 249.650 共0.108兲*
443 259.118 共0.017兲*
443 259.088 共0.017兲
443 259.092 共0.017兲
443 259.173 共0.017兲
443 259.390 共0.017兲*
443 259.360 共0.017兲
443 259.364 共0.017兲
443 259.445 共0.017兲
443 261.383 共0.017兲*
443 261.353 共0.017兲
443 261.357 共0.017兲
443 261.439 共0.017兲
443 262.639 共0.016兲*
443 262.609 共0.016兲
443 262.613 共0.016兲
443 262.694 共0.016兲
443 265.002 共0.016兲*
443 264.972 共0.016兲
443 264.976 共0.016兲
443 265.057 共0.016兲
443 268.080 共0.017兲*
443 268.050 共0.017兲
443 268.054 共0.017兲
443 268.136 共0.017兲
443 268.228 共0.017兲*
443 268.199 共0.017兲
443 268.203 共0.017兲
443 268.284 共0.017兲
443 268.507 共0.017兲*
443 268.477 共0.017兲
443 268.481 共0.017兲
443 268.562 共0.017兲
443 337.017 共0.013兲*
443 337.002 共0.013兲
443 337.004 共0.013兲
443 337.046 共0.013兲
443 343.617 共0.013兲*
443 343.602 共0.013兲
443 343.604 共0.013兲
443 343.646 共0.013兲
443 354.120 共0.014兲*
443 354.105 共0.014兲
443 354.107 共0.014兲
443 354.147 共0.014兲
443 354.203 共0.013兲*
443 354.188 共0.013兲
443 354.190 共0.013兲
134.250
134.088
134.088
134.088
134.088
134.088
134.088
134.088
134.088
514.410
110.012
110.012
110.012
110.012
110.012
110.012
110.012
110.012
110.055
110.055
110.055
110.055
110.206
110.206
110.206
110.206
110.174
110.174
110.174
110.174
109.898
109.898
109.898
109.898
109.823
109.823
109.823
109.823
109.823
109.823
109.823
109.823
91.277
91.277
91.277
91.277
91.177
91.177
91.177
91.177
91.067
91.067
91.067
91.068
91.250
91.250
91.250
0.234
0.708
0.211
0.258
0.234
0.708
0.211
0.258
0.234
2.918
0.791
0.236
0.289
0.261
0.791
0.236
0.289
0.261
0.792
0.236
0.289
0.261
0.792
0.236
0.289
0.261
0.792
0.236
0.289
0.261
0.792
0.236
0.289
0.261
0.792
0.236
0.289
0.261
0.792
0.236
0.289
0.261
0.858
0.313
0.256
0.283
0.857
0.313
0.256
0.283
0.858
0.313
0.256
0.283
0.858
0.313
0.256
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1268
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
24
10
10
10
10
23
20
20
13
10
10
10
10
10
10
10
10
10
10
10
10
25
20
27
9
9
9
9
17
20
25
9
9
9
9
10
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
3
2
2
2
2
3
9
9
0
2
2
2
2
2
2
2
2
2
2
2
2
3
9
3
6
6
6
6
1
9
3
6
6
6
6
1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B1
B1
B1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B1
B1
B1
B1
A2
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
10
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
24
9
9
9
9
22
21
21
12
9
9
9
9
9
9
9
9
9
9
9
9
25
21
27
10
10
10
10
16
21
25
10
10
10
10
9
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
3
2
2
2
2
2
2
2
2
2
4
8
8
1
2
2
2
2
2
2
2
2
2
2
2
2
2
8
2
5
5
5
5
2
8
2
5
5
5
5
1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B2
B2
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
A2
A1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B2
B2
B2
B2
A1
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
E2 + 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
9
11
9
10
11
9
10
11
9
10
11
9
10
11
9
10
10
11
9
10
11
9
10
11
9
10
11
9
9
10
8
9
10
8
10
8
9
10
8
9
10
8
9
10
8
9
10
8
9
9
10
8
9
10
8
9
10
8
9
10
8
10
11
9
10
11
9
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
443 354.231 共0.013兲
443 358.653 共0.013兲*
443 358.639 共0.013兲
443 358.641 共0.013兲
443 358.681 共0.013兲
443 365.393 共0.014兲*
443 365.379 共0.014兲
443 365.381 共0.014兲
443 365.420 共0.014兲
443 365.575 共0.014兲*
443 365.560 共0.014兲
443 365.562 共0.014兲
443 365.602 共0.014兲
443 372.607 共0.014兲*
443 372.593 共0.014兲
443 372.596 共0.014兲
443 372.634 共0.014兲
443 442.208 共0.011兲*
443 442.197 共0.011兲
443 442.201 共0.011兲
443 442.228 共0.011兲
443 569.422 共0.249兲*
443 795.241 共0.012兲*
443 795.225 共0.012兲
443 795.245 共0.012兲
443 795.255 共0.012兲
444 023.996 共0.051兲*
444 051.640 共0.105兲*
444 051.640 共0.105兲*
444 061.292 共0.040兲*
444 130.973 共0.013兲*
444 130.948 共0.013兲
444 130.981 共0.013兲
444 130.990 共0.013兲
444 157.672 共0.012兲*
444 157.656 共0.012兲
444 157.677 共0.012兲
444 157.685 共0.012兲
444 168.537 共0.012兲*
444 168.520 共0.012兲
444 168.542 共0.012兲
444 168.550 共0.012兲
444 449.755 共0.401兲*
444 674.487 共0.093兲*
444 968.835 共0.311兲*
445 147.883 共0.048兲*
445 147.575 共0.048兲
445 148.016 共0.048兲
445 148.062 共0.048兲
445 422.995 共0.073兲*
445 581.369 共0.107兲*
446 035.585 共0.403兲*
446 840.804 共0.043兲*
446 840.497 共0.043兲
446 840.937 共0.043兲
446 840.984 共0.043兲
447 157.007 共0.011兲*
91.250
91.145
91.145
91.145
91.145
91.278
91.278
91.278
91.279
90.864
90.864
90.864
90.864
91.179
91.179
91.179
91.179
77.409
77.409
77.409
77.409
453.609
77.710
77.710
77.710
77.710
417.630
514.245
514.245
119.424
77.627
77.627
77.627
77.627
77.814
77.814
77.814
77.814
77.852
77.852
77.852
77.852
490.622
514.449
568.366
149.232
149.232
149.232
149.232
211.884
514.238
490.652
149.271
149.271
149.271
149.271
70.161
0.283
0.857
0.313
0.256
0.283
0.858
0.313
0.256
0.283
0.857
0.313
0.256
0.283
0.857
0.313
0.256
0.283
0.900
0.329
0.268
0.297
12.521
0.902
0.298
0.329
0.269
0.561
2.919
2.919
6.990
0.898
0.296
0.328
0.268
0.904
0.298
0.330
0.270
0.905
0.299
0.330
0.270
14.337
2.916
0.042
0.787
0.260
0.287
0.235
4.233
2.920
14.503
0.786
0.259
0.287
0.234
0.932
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
3
3
3
3
1
3
1
3
3
3
3
3
1
3
1
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1269
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
9
9
9
9
8
8
8
8
9
9
9
9
9
9
9
9
28
23
25
23
23
25
27
28
8
8
8
8
30
5
5
5
5
18
27
15
26
13
8
8
8
8
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
6
6
6
1
1
1
1
6
6
6
6
6
6
6
6
3
3
3
3
2
3
11
3
1
1
1
1
5
2
2
2
2
1
11
1
3
0
1
1
1
1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A1
A1
A1
B1
B1
B1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E1 + 1
E2 − 1
E2 + 1
B2
E1 − 1
E2 − 1
E2 + 1
B1
B1
B1
B1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 − 1
E1 + 1
B2
A1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
9
11
10
9
9
9
9
9
9
9
9
9
9
9
9
9
9
9
10
10
10
10
7
7
7
7
10
10
10
10
10
10
10
10
28
22
25
22
23
25
28
28
7
7
7
7
29
4
4
4
4
17
28
14
26
12
7
7
7
7
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
5
5
5
0
0
0
0
5
5
5
5
5
5
5
5
2
4
2
4
1
2
10
2
0
0
0
0
6
1
1
1
1
2
10
2
2
1
0
0
0
0
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A2
A2
A2
B2
B2
B2
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
B1
B1
B1
B2
B2
B2
B2
E1 − 1
E1 + 1
E2 + 1
E2 − 1
B1
E1 − 1
E2 − 1
E2 + 1
B2
B2
B2
B2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 − 1
E1 + 1
B1
A2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
8
10
9
9
11
10
9
11
10
9
11
10
9
10
8
8
9
7
9
10
8
9
10
8
8
9
7
4
6
5
8
9
7
Obs. Freq. 共unc.兲
共MHz兲
8
10
9
8
10
9
8
10
9
10
11
9
448 351.229 共0.100兲
7
8
6
10
11
9
10
11
9
450 479.471 共0.100兲
7
8
6
3
5
4
7
8
6
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
447 157.003 共0.011兲
447 157.005 共0.011兲
447 157.011 共0.011兲
447 273.229 共0.011兲*
447 273.220 共0.011兲
447 273.224 共0.011兲
447 273.242 共0.011兲
447 311.879 共0.011兲*
447 311.869 共0.011兲
447 311.873 共0.011兲
447 311.894 共0.011兲
447 329.029 共0.011兲*
447 329.020 共0.011兲
447 329.024 共0.011兲
447 329.044 共0.011兲
447 387.499 共0.047兲*
447 387.192 共0.047兲
447 387.632 共0.047兲
447 387.678 共0.047兲
448 351.055 共0.011兲*
448 350.242 共0.011兲
448 351.390 共0.011兲
448 351.553 共0.011兲
448 363.464 共0.043兲*
448 363.157 共0.043兲
448 363.597 共0.043兲
448 363.643 共0.043兲
448 363.466 共0.043兲*
448 363.159 共0.043兲
448 363.599 共0.043兲
448 363.645 共0.043兲
448 425.565 共0.350兲*
448 426.842 共0.044兲*
448 727.282 共0.309兲*
448 863.872 共0.048兲*
449 370.094 共0.163兲*
449 841.882 共0.298兲*
450 200.977 共0.184兲*
450 233.233 共0.365兲*
450 479.425 共0.019兲*
450 478.568 共0.019兲
450 479.780 共0.019兲
450 479.951 共0.019兲
450 506.951 共0.120兲*
451 034.860 共0.014兲*
451 034.535 共0.014兲
451 034.679 共0.014兲
451 035.336 共0.014兲
451 098.158 共0.049兲*
451 127.866 共0.242兲*
451 236.776 共0.048兲*
451 974.087 共0.489兲*
452 277.552 共0.024兲*
452 911.886 共0.013兲*
452 911.035 共0.013兲
452 912.237 共0.013兲
452 912.407 共0.013兲
70.161
70.161
70.161
70.215
70.215
70.215
70.215
70.199
70.199
70.199
70.199
70.042
70.042
70.042
70.042
149.034
149.034
149.034
149.034
41.781
41.781
41.781
41.781
149.061
149.061
149.061
149.061
149.061
149.061
149.061
149.061
609.505
417.483
490.419
417.600
405.999
490.400
869.381
609.520
41.584
41.584
41.584
41.584
739.631
17.985
17.985
17.985
17.985
237.889
869.553
166.818
528.868
119.437
41.678
41.678
41.678
41.678
0.278
0.340
0.307
0.934
0.279
0.341
0.308
0.935
0.279
0.341
0.309
0.931
0.278
0.340
0.307
0.787
0.260
0.287
0.235
6.492
2.130
2.419
1.876
0.787
0.260
0.287
0.235
0.787
0.260
0.287
0.235
0.355
6.189
14.176
2.384
4.573
12.995
4.287
0.026
6.722
2.206
2.504
1.942
8.061
0.853
0.221
0.336
0.273
0.036
4.282
6.620
14.270
6.871
6.669
2.188
2.484
1.927
1
1
1
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
3
3
3
3
3
3
1
1
3
3
1
1
3
3
3
3
1
3
3
3
3
1
3
3
1
3
3
3
3
3
Ref.
11
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1270
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
16
16
16
26
18
20
29
13
5
5
5
5
5
5
5
5
9
9
9
9
27
5
5
5
5
5
5
5
5
23
26
23
5
5
5
5
15
26
9
9
9
9
9
9
9
9
13
23
23
16
16
19
5
5
5
5
27
8
8
8
3
1
9
3
0
5
5
5
5
2
2
2
2
1
1
1
1
11
5
5
5
5
5
5
5
5
3
3
3
2
2
2
2
1
3
6
6
6
6
6
6
6
6
0
3
3
8
8
2
2
2
2
2
11
E1 + 1
A1
A2
B1
E1 − 1
E1 + 1
E1 + 1
B2
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
A2
A2
A2
A2
A1
A1
A1
A1
A1
E2 − 1
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
E1 − 1
A2
A2
A2
A2
A1
A1
A1
A1
E2 + 1
E2 − 1
E1 − 1
B1
B2
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
F⬘
5
6
4
4
6
5
8
10
9
5
6
4
5
6
4
4
6
5
9
10
8
9
10
8
4
6
5
J⬙
K⬙a
⌫⬙
17
17
17
26
17
21
29
12
6
6
6
6
4
4
4
4
8
8
8
8
28
6
6
6
6
6
6
6
6
22
26
22
4
4
4
4
14
26
10
10
10
10
10
10
10
10
12
22
22
17
17
18
4
4
4
4
28
7
7
7
2
2
8
2
1
4
4
4
4
1
1
1
1
0
0
0
0
10
4
4
4
4
4
4
4
4
4
2
4
1
1
1
1
2
2
5
5
5
5
5
5
5
5
1
4
4
7
7
3
1
1
1
1
10
E1 + 1
A2
A1
B2
E1 + 1
E1 + 1
E1 − 1
B1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
A1
A1
A1
A2
A2
A2
A2
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
A1
E1 − 1
A1
A1
A1
A1
A2
A2
A2
A2
E2 + 1
E2 − 1
E1 − 1
B2
B1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 − 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
6
7
5
3
5
4
455 557.635 共0.100兲
7
9
8
6
7
5
6
7
5
3
5
4
10
11
9
10
11
9
3
5
4
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
453 015.784 共0.082兲*
453 080.216 共0.087兲*
453 080.216 共0.087兲*
453 511.485 共0.493兲*
453 706.976 共0.046兲*
453 873.050 共0.116兲*
454 286.746 共0.410兲*
454 699.498 共0.041兲*
454 964.797 共0.035兲*
454 963.984 共0.035兲
454 965.108 共0.035兲
454 965.342 共0.035兲
455 128.341 共0.014兲*
455 128.162 共0.014兲
455 128.234 共0.014兲
455 128.614 共0.014兲
455 557.627 共0.014兲*
455 557.282 共0.014兲
455 557.364 共0.014兲
455 558.229 共0.014兲
455 632.960 共0.178兲*
455 914.046 共0.030兲*
455 913.233 共0.030兲
455 914.357 共0.030兲
455 914.591 共0.030兲
455 914.053 共0.030兲*
455 913.241 共0.030兲
455 914.365 共0.030兲
455 914.598 共0.030兲
455 983.135 共0.048兲*
456 289.413 共0.366兲*
456 882.028 共0.043兲*
456 883.258 共0.014兲*
456 883.085 共0.014兲
456 883.155 共0.014兲
456 883.523 共0.014兲
457 018.130 共0.046兲*
457 081.720 共0.356兲*
457 126.140 共0.044兲*
457 125.833 共0.044兲
457 126.273 共0.044兲
457 126.319 共0.044兲
457 126.142 共0.044兲*
457 125.835 共0.044兲
457 126.275 共0.044兲
457 126.321 共0.044兲
457 184.340 共0.023兲*
457 188.548 共0.066兲*
457 549.096 共0.064兲*
458 168.144 共0.078兲*
458 168.144 共0.078兲*
458 587.556 共0.056兲*
459 789.147 共0.013兲*
459 788.823 共0.013兲
459 788.967 共0.013兲
459 789.623 共0.013兲
460 028.283 共0.192兲*
358.675
358.858
358.858
528.898
237.887
514.060
652.112
119.270
74.718
74.718
74.718
74.718
17.984
17.984
17.984
17.984
53.590
53.590
53.590
53.590
869.530
74.524
74.524
74.524
74.524
74.524
74.524
74.524
74.524
417.434
528.665
417.333
17.984
17.984
17.984
17.984
166.777
528.648
148.872
148.872
148.872
148.872
148.872
148.872
148.872
148.872
119.374
417.600
417.630
358.830
358.830
277.584
17.985
17.985
17.985
17.985
869.219
2.083
2.081
2.081
14.454
0.073
2.921
0.223
6.958
0.131
0.042
0.050
0.036
2.926
0.759
1.153
0.936
0.154
0.045
0.057
0.051
4.279
0.131
0.043
0.050
0.036
0.131
0.043
0.050
0.036
6.724
14.146
4.355
0.530
0.137
0.209
0.170
6.565
13.295
0.787
0.260
0.287
0.235
0.787
0.260
0.287
0.235
6.811
4.360
6.161
2.080
2.080
3.008
2.626
0.681
1.035
0.840
4.287
3
1
1
3
3
3
3
3
3
3
3
3
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
3
1
1
1
1
1
1
1
1
1
1
3
3
3
3
3
3
3
3
3
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1271
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
20
27
5
5
5
5
27
27
30
15
24
5
5
5
5
8
8
8
8
19
9
9
9
9
23
27
15
16
19
5
5
5
5
23
27
23
16
20
24
23
19
19
27
24
23
27
12
5
5
5
5
27
27
27
27
5
5
2
3
5
5
5
5
11
11
3
1
2
2
2
2
2
1
1
1
1
2
1
1
1
1
3
3
1
8
2
2
2
2
2
10
4
3
8
2
2
3
2
2
3
2
3
3
7
5
5
5
5
11
11
4
4
5
5
E1 − 1
A2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
B2
E1 + 1
E2 + 1
E1 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A1
A1
A1
A1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B2
E1 + 1
E2 − 1
B2
A2
A2
A2
A2
E1 − 1
E2 + 1
A2
E2 + 1
E2 + 1
E2 − 1
B1
A2
E2 − 1
E2 − 1
A1
E2 − 1
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
A2
E2 + 1
B1
B2
B2
F⬘
5
6
4
5
6
4
8
9
7
8
10
9
4
6
5
5
6
4
5
J⬙
K⬙a
⌫⬙
19
27
6
6
6
6
28
28
30
14
24
4
4
4
4
7
7
7
7
18
8
8
8
8
22
27
14
17
18
4
4
4
4
24
26
22
17
19
24
22
18
18
27
24
22
27
13
6
6
6
6
28
28
26
26
6
6
3
2
4
4
4
4
10
10
2
2
1
1
1
1
1
0
0
0
0
3
0
0
0
0
4
2
2
7
3
1
1
1
1
9
5
4
7
3
1
4
3
3
2
1
4
2
6
4
4
4
4
10
10
5
5
4
4
E1 − 1
A1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
B1
E1 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
A2
A2
A2
E2 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B1
E1 + 1
E2 − 1
B1
A1
A1
A1
A1
E1 − 1
E2 + 1
A1
E2 + 1
E2 − 1
E2 − 1
B2
A1
E2 + 1
E2 + 1
A2
E2 + 1
E1 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A2
A1
E2 − 1
B2
B1
B1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
6
7
5
4
5
3
461 340.579 共0.100兲
7
8
6
7
9
8
3
5
4
6
7
5
6
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
460 382.338 共0.070兲*
460 475.506 共0.595兲*
460 481.467 共0.033兲*
460 480.654 共0.033兲
460 481.778 共0.033兲
460 482.012 共0.033兲
460 489.086 共0.208兲*
460 489.086 共0.208兲*
460 548.339 共0.480兲*
460 683.162 共0.031兲*
460 927.592 共0.221兲*
461 151.273 共0.013兲*
461 150.434 共0.013兲
461 151.571 共0.013兲
461 151.888 共0.013兲
461 340.350 共0.019兲*
461 339.494 共0.019兲
461 340.704 共0.019兲
461 340.874 共0.019兲
461 706.695 共0.054兲*
461 728.273 共0.012兲*
461 727.912 共0.012兲
461 727.998 共0.012兲
461 728.901 共0.012兲
461 951.941 共0.053兲*
461 959.372 共0.601兲*
462 066.422 共0.024兲*
463 054.452 共0.082兲*
463 073.517 共0.057兲*
463 103.671 共0.013兲*
463 103.293 共0.013兲
463 103.464 共0.013兲
463 104.221 共0.013兲
463 120.257 共0.158兲*
463 201.197 共0.090兲*
463 743.758 共0.064兲*
463 780.644 共0.094兲*
463 785.129 共0.079兲*
464 018.318 共0.226兲*
464 182.791 共0.055兲*
464 505.857 共0.064兲*
464 736.578 共0.062兲*
464 839.868 共0.431兲*
465 090.306 共0.202兲*
465 206.704 共0.056兲*
465 365.822 共0.422兲*
465 371.400 共0.064兲*
465 437.140 共0.033兲*
465 436.327 共0.033兲
465 437.451 共0.033兲
465 437.685 共0.033兲
465 836.513 共0.226兲*
465 836.513 共0.226兲*
465 904.270 共0.113兲*
466 638.083 共0.094兲*
467 285.339 共0.032兲*
467 284.526 共0.032兲
305.682
568.569
74.686
74.686
74.686
74.686
869.371
869.371
696.168
166.598
441.140
17.647
17.648
17.647
17.647
41.378
41.378
41.378
41.378
277.491
53.487
53.487
53.487
53.487
417.483
568.598
166.618
358.690
277.638
17.950
17.950
17.950
17.950
662.086
586.525
417.442
358.496
305.596
441.060
417.254
277.543
277.390
568.366
441.125
417.333
568.350
232.166
74.567
74.567
74.567
74.567
869.232
869.232
586.435
586.317
74.335
74.335
2.866
14.121
0.131
0.042
0.050
0.036
4.284
4.284
0.137
6.626
4.004
2.547
0.815
1.003
0.660
6.730
2.208
2.507
1.944
5.146
0.029
0.009
0.011
0.010
0.576
14.322
6.171
2.081
6.109
3.483
0.903
1.372
1.115
3.434
7.548
6.765
2.082
0.662
3.944
6.746
6.154
0.998
14.018
4.378
2.411
13.414
1.271
0.131
0.042
0.050
0.036
4.287
4.287
0.051
7.612
0.131
0.042
3
1
1
1
1
1
3
3
3
1
3
3
3
3
3
1
1
1
1
1
3
3
3
3
3
3
3
1
3
1
1
1
1
3
1
1
1
1
1
3
1
1
1
1
1
3
1
3
3
3
3
1
1
1
3
3
3
Ref.
11
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1272
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
F⬘
J⬙
K⬙a
⌫⬙
F⬙
5
5
5
5
5
5
20
18
27
27
16
5
5
5
5
20
5
5
5
5
5
5
5
5
28
19
23
23
23
20
27
24
5
5
5
5
28
5
5
5
5
5
5
5
5
23
20
27
12
18
15
12
27
28
27
28
23
5
5
5
5
5
5
2
1
4
4
8
2
2
2
2
2
2
2
2
2
2
2
2
2
3
2
10
10
10
2
4
2
5
5
5
5
3
2
2
2
2
2
2
2
2
3
2
4
7
1
1
7
4
3
4
3
10
B2
B2
B1
B1
B1
B1
E2 + 1
B2
B2
E1 + 1
E1 − 1
B2
B2
B2
B2
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
A1
E1 + 1
A1
A2
E2 − 1
A2
E2 − 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A1
A1
A1
A1
B2
E1 − 1
E1 − 1
E1 − 1
A2
E2 + 1
E1 + 1
E2 − 1
E2 − 1
E1 + 1
E1 − 1
E1 + 1
6
4
6
6
6
6
6
6
19
17
26
26
17
4
4
4
4
19
4
4
4
4
4
4
4
4
28
18
24
24
24
19
26
24
6
6
6
6
28
4
4
4
4
4
4
4
4
22
19
26
13
17
14
13
26
28
26
28
24
4
4
4
4
4
4
3
2
5
5
7
1
1
1
1
3
1
1
1
1
1
1
1
1
2
3
9
9
9
3
5
1
4
4
4
4
2
1
1
1
1
1
1
1
1
4
3
5
6
2
2
6
5
2
5
2
9
B1
B1
B2
B2
B2
B2
E2 + 1
B1
B1
E1 + 1
E1 − 1
B1
B1
B1
B1
B1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
A2
E1 + 1
A2
A1
E2 − 1
A1
E2 + 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
B2
E2 − 1
E2 − 1
E2 − 1
E2 − 1
A2
A2
A2
A2
B1
E1 + 1
E1 + 1
E1 − 1
A1
E2 + 1
E1 + 1
E2 − 1
E2 + 1
E1 − 1
E1 − 1
E1 + 1
7
5
5
6
4
4
6
5
5
6
4
5
6
4
5
6
4
5
6
4
5
6
4
6
7
5
3
5
4
4
5
3
4
5
3
6
7
5
4
5
3
4
5
3
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
467 285.650 共0.032兲
467 285.883 共0.032兲
467 285.346 共0.032兲*
467 284.533 共0.032兲
467 285.657 共0.032兲
467 285.891 共0.032兲
467 312.569 共0.064兲*
467 692.704 共0.114兲*
467 833.192 共0.089兲*
468 636.239 共0.088兲*
468 760.553 共0.088兲*
468 977.006 共0.014兲*
468 976.628 共0.014兲
468 976.799 共0.014兲
468 977.555 共0.014兲
469 003.284 共0.098兲*
469 902.972 共0.012兲*
469 902.344 共0.012兲
469 903.193 共0.012兲
469 903.437 共0.012兲
469 905.560 共0.012兲*
469 904.720 共0.012兲
469 905.858 共0.012兲
469 906.176 共0.012兲
470 026.802 共0.720兲*
470 028.929 共0.056兲*
470 203.859 共0.144兲*
470 203.859 共0.144兲*
470 648.650 共0.135兲*
470 850.780 共0.097兲*
470 963.287 共0.065兲*
471 323.085 共0.206兲*
471 323.892 共0.033兲*
471 323.079 共0.033兲
471 324.203 共0.033兲
471 324.437 共0.033兲
471 452.227 共0.729兲*
471 657.890 共0.013兲*
471 657.253 共0.013兲
471 658.114 共0.013兲
471 658.361 共0.013兲
471 658.208 共0.013兲*
471 657.298 共0.013兲
471 658.532 共0.013兲
471 658.876 共0.013兲
471 782.145 共0.062兲*
471 906.884 共0.063兲*
472 962.046 共0.067兲*
473 221.535 共0.064兲*
473 473.380 共0.110兲*
473 598.506 共0.022兲*
473 625.730 共0.062兲*
473 666.361 共0.063兲*
474 450.282 共0.506兲*
474 495.855 共0.111兲*
474 763.404 共0.497兲*
475 576.747 共0.153兲*
74.335
74.335
74.335
74.335
74.335
74.335
305.478
237.249
586.318
586.489
358.539
17.792
17.792
17.792
17.792
305.658
17.491
17.491
17.491
17.491
17.647
17.648
17.647
17.647
609.723
277.202
661.861
661.861
662.001
305.563
586.525
440.971
74.410
74.410
74.410
74.410
609.751
17.491
17.491
17.491
17.491
17.657
17.657
17.657
17.657
417.262
305.298
586.489
231.946
237.213
166.167
232.071
586.435
609.520
586.293
609.505
662.006
0.050
0.036
0.131
0.042
0.050
0.036
5.459
4.561
7.616
7.435
2.082
3.486
0.904
1.373
1.116
6.081
0.462
0.148
0.182
0.120
0.776
0.248
0.306
0.201
13.891
3.159
3.437
3.437
3.432
6.108
0.051
4.238
0.131
0.042
0.050
0.036
14.110
2.885
0.923
1.137
0.748
3.310
1.059
1.304
0.858
6.791
3.268
0.149
1.271
4.547
0.077
1.270
7.524
13.801
0.148
13.370
3.432
3
3
3
3
3
3
1
3
3
3
3
3
3
3
3
3
1
1
1
1
3
3
3
3
1
3
1
1
1
1
1
3
1
1
1
1
3
1
1
1
1
1
1
1
1
3
3
3
3
1
1
3
1
1
3
3
3
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1273
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
27
15
18
5
5
5
5
23
12
12
27
19
19
27
12
23
23
12
12
14
19
29
18
8
8
8
8
29
11
11
11
11
19
12
25
29
29
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
4
1
1
2
2
2
2
10
7
7
4
9
9
4
0
10
10
7
7
0
1
3
1
6
6
6
6
3
1
1
1
1
1
7
2
3
3
0
0
0
0
10
10
10
10
10
10
10
10
9
9
9
9
2
9
9
9
A1
E1 + 1
E2 − 1
B1
B1
B1
B1
E2 + 1
A2
A1
A2
B2
B1
E1 − 1
E2 + 1
B1
B2
B2
B1
A1
E2 − 1
A2
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B2
A1
B1
E1 − 1
E2 − 1
E1 − 1
E2 − 1
E1 + 1
E2 − 1
E1 − 1
E2 + 1
E1 + 1
B2
A2
E2 − 1
B1
B2
E1 + 1
A1
A2
E1 − 1
E2 + 1
A2
A1
E1 − 1
E1 + 1
B1
B2
B1
E2 + 1
F⬘
5
6
4
8
9
7
J⬙
K⬙a
⌫⬙
26
14
17
4
4
4
4
24
13
13
26
20
20
26
11
24
24
13
13
13
18
29
17
9
9
9
9
29
10
10
10
10
18
13
25
29
29
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
5
2
2
1
1
1
1
9
6
6
5
8
8
5
1
9
9
6
6
1
2
2
2
5
5
5
5
2
1
1
1
1
2
6
1
2
2
0
0
0
0
10
10
10
10
10
10
10
10
9
9
9
9
2
9
9
9
A2
E1 − 1
E2 + 1
B2
B2
B2
B2
E2 + 1
A1
A2
A1
B1
B2
E1 − 1
E2 − 1
B2
B1
B1
B2
A2
E2 − 1
A1
E1 − 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
B1
A2
B2
E1 − 1
E2 − 1
E1 + 1
E2 − 1
E1 − 1
E2 + 1
E1 − 1
E2 + 1
E1 + 1
B1
A1
E2 − 1
B2
B1
E1 + 1
A2
A1
E1 − 1
E2 + 1
A1
A2
E1 − 1
E1 + 1
B2
B1
B2
E2 + 1
F⬙
4
5
3
9
10
8
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
477 202.807 共0.090兲*
477 351.374 共0.021兲*
477 432.264 共0.102兲*
477 543.752 共0.014兲*
477 542.841 共0.014兲
477 544.075 共0.014兲
477 544.419 共0.014兲
477 794.635 共0.172兲*
477 913.356 共0.065兲*
477 913.356 共0.065兲*
478 372.601 共0.084兲*
478 606.282 共0.118兲*
478 606.282 共0.118兲*
478 821.663 共0.076兲*
479 116.914 共0.020兲*
479 927.135 共0.159兲*
479 927.135 共0.159兲*
480 139.558 共0.072兲*
480 139.558 共0.072兲*
480 342.722 共0.047兲*
480 429.582 共0.062兲*
480 697.988 共0.868兲*
481 094.697 共0.094兲*
481 280.000 共0.049兲*
481 279.603 共0.049兲
481 280.168 共0.049兲
481 280.238 共0.049兲
482 060.468 共0.879兲*
482 315.123 共0.013兲*
482 317.293 共0.013兲*
482 344.931 共0.013兲*
482 441.593 共0.013兲*
483 157.404 共0.059兲*
483 679.238 共0.071兲*
484 417.335 共0.271兲*
485 189.738 共0.593兲*
485 337.434 共0.584兲*
485 948.640 共0.013兲*
485 962.488 共0.013兲*
486 001.373 共0.013兲*
486 027.836 共0.013兲*
487 171.092 共0.077兲*
487 172.875 共0.078兲*
487 172.875 共0.078兲*
487 177.555 共0.076兲*
487 178.119 共0.076兲*
487 178.119 共0.076兲*
487 179.222 共0.077兲*
487 180.440 共0.078兲*
487 242.808 共0.061兲*
487 242.808 共0.061兲*
487 248.080 共0.060兲*
487 248.430 共0.061兲*
487 248.899 共0.013兲*
487 251.137 共0.060兲*
487 251.137 共0.060兲*
487 251.443 共0.060兲*
586.139
166.109
237.011
17.498
17.498
17.498
17.498
661.908
232.110
232.110
586.140
483.384
483.384
586.293
99.512
661.679
661.679
232.007
232.007
138.806
264.643
652.329
236.974
134.401
134.401
134.401
134.401
652.355
83.509
83.350
83.518
83.420
264.636
231.750
477.556
652.126
652.112
81.613
81.511
81.418
81.215
351.451
351.436
351.436
351.616
351.290
351.290
351.279
351.590
300.152
300.152
300.374
300.292
92.553
299.963
299.963
300.192
7.620
0.510
4.515
3.310
1.059
1.304
0.858
3.435
1.270
1.270
7.624
2.594
2.594
7.450
0.067
3.438
3.438
1.270
1.270
7.226
0.029
13.585
4.466
0.525
0.173
0.193
0.154
13.820
1.029
1.027
1.028
1.027
0.047
1.271
3.693
13.502
13.185
1.037
1.035
1.038
1.034
0.178
0.178
0.178
0.180
0.182
0.182
0.182
0.180
0.340
0.340
0.341
0.341
1.003
0.346
0.346
0.345
1
3
1
3
3
3
3
1
1
1
1
3
3
3
1
3
3
3
3
1
1
1
3
1
1
1
1
3
1
3
3
1
3
1
3
1
3
1
3
3
1
1
3
3
3
1
1
3
1
1
1
3
3
3
3
3
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1274
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
25
19
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
25
19
19
2
9
2
8
8
8
8
8
8
8
8
7
7
7
7
7
7
7
7
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
2
9
4
4
4
4
4
4
4
4
3
3
3
3
3
2
3
3
3
2
9
9
A1
E2 − 1
E2 + 1
E2 + 1
B2
B1
E1 − 1
E2 − 1
E1 + 1
A2
A1
E1 + 1
E2 − 1
A1
A2
E1 − 1
E2 + 1
B1
B2
E1 − 1
E2 + 1
A1
A2
B1
B2
E1 + 1
E2 − 1
E2 − 1
B1
B2
E2 + 1
E1 + 1
E1 − 1
A1
A2
E2 − 1
E2 − 1
A1
A2
E1 + 1
E1 − 1
E2 − 1
E2 + 1
B1
B2
B1
A1
E1 − 1
E2 + 1
E2 − 1
E1 − 1
E1 + 1
B2
A2
A2
A2
A1
F⬘
J⬙
K⬙a
⌫⬙
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
25
20
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
25
20
20
2
9
2
8
8
8
8
8
8
8
8
7
7
7
7
7
7
7
7
6
6
6
6
6
6
6
6
5
5
5
5
5
5
5
5
1
8
4
4
4
4
4
4
4
4
3
3
3
3
3
2
3
3
3
1
8
8
A2
E2 − 1
E2 + 1
E2 + 1
B1
B2
E1 − 1
E2 − 1
E1 + 1
A1
A2
E1 + 1
E2 − 1
A2
A1
E1 − 1
E2 + 1
B2
B1
E1 − 1
E2 + 1
A2
A1
B2
B1
E1 + 1
E2 − 1
E2 − 1
B2
B1
E2 + 1
E1 + 1
E1 − 1
A2
A1
E2 − 1
E2 − 1
A2
A1
E1 + 1
E1 − 1
E2 − 1
E2 + 1
B2
B1
B2
A2
E1 − 1
E2 + 1
E2 − 1
E1 − 1
E1 + 1
B1
A1
A1
A1
A2
F⬙
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
487 252.338 共0.013兲*
487 253.393 共0.061兲*
487 305.017 共0.013兲*
487 310.692 共0.049兲*
487 312.490 共0.048兲*
487 312.490 共0.048兲*
487 317.985 共0.048兲*
487 318.343 共0.048兲*
487 318.354 共0.048兲*
487 319.796 共0.048兲*
487 319.796 共0.048兲*
487 372.919 共0.039兲*
487 375.246 共0.039兲*
487 379.173 共0.038兲*
487 379.173 共0.038兲*
487 381.405 共0.039兲*
487 381.578 共0.039兲*
487 381.663 共0.038兲*
487 381.663 共0.038兲*
487 432.177 共0.031兲*
487 436.080 共0.030兲*
487 437.220 共0.031兲*
487 437.220 共0.031兲*
487 441.126 共0.031兲*
487 441.126 共0.031兲*
487 441.387 共0.031兲*
487 441.400 共0.031兲*
487 494.375 共0.025兲*
487 494.388 共0.025兲*
487 494.391 共0.025兲*
487 499.453 共0.024兲*
487 500.449 共0.024兲*
487 502.307 共0.025兲*
487 503.301 共0.025兲*
487 503.304 共0.025兲*
487 528.833 共0.276兲*
487 532.974 共0.123兲*
487 565.972 共0.020兲*
487 566.516 共0.020兲*
487 568.698 共0.020兲*
487 569.189 共0.019兲*
487 571.853 共0.020兲*
487 576.327 共0.020兲*
487 576.334 共0.020兲*
487 576.889 共0.020兲*
487 659.267 共0.016兲*
487 666.937 共0.016兲*
487 686.412 共0.016兲*
487 687.008 共0.017兲*
487 691.904 共0.016兲*
487 696.988 共0.013兲*
487 700.797 共0.017兲*
487 705.303 共0.016兲*
487 713.966 共0.016兲*
488 340.920 共0.254兲*
488 348.462 共0.122兲*
488 348.462 共0.122兲*
92.516
300.285
92.309
254.298
254.444
254.444
254.505
254.465
254.115
254.301
254.301
213.879
213.893
214.060
214.060
213.740
213.697
214.031
214.031
178.739
178.958
178.902
178.902
178.799
178.799
178.863
178.541
149.185
149.061
149.061
149.271
149.232
149.034
148.872
148.872
477.477
483.409
124.797
124.797
124.840
124.992
124.960
124.684
124.609
124.609
106.066
105.966
106.038
105.856
105.934
92.201
105.654
106.068
105.968
477.541
483.244
483.244
1.002
0.344
0.998
0.485
0.486
0.486
0.488
0.489
0.492
0.491
0.491
0.614
0.615
0.616
0.616
0.619
0.620
0.617
0.617
0.726
0.727
0.727
0.727
0.729
0.729
0.729
0.730
0.822
0.821
0.821
0.822
0.823
0.824
0.824
0.824
3.630
2.592
0.899
0.899
0.900
0.899
0.900
0.900
0.900
0.900
0.960
0.959
0.960
0.960
0.959
0.996
0.959
0.960
0.959
4.055
2.593
2.593
1
1
1
1
3
3
3
1
3
1
1
3
1
1
1
3
1
3
3
3
1
1
1
3
3
3
1
1
3
3
1
3
3
1
1
1
1
1
1
3
3
1
1
3
3
3
1
3
1
1
3
3
3
1
1
1
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
MICROWAVE SPECTRA OF METHYLAMINE
1275
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
11
14
24
11
11
11
19
8
8
8
8
19
14
8
8
8
8
8
8
8
8
11
11
11
11
30
8
8
8
8
8
8
8
8
24
24
14
6
6
6
6
30
26
25
26
10
10
10
10
9
9
9
9
30
30
15
15
2
0
3
2
2
2
9
6
6
6
6
9
0
6
6
6
6
6
6
6
6
1
1
1
1
3
6
6
6
6
6
6
6
6
3
3
0
2
2
2
2
3
11
2
11
1
1
1
1
1
1
1
1
3
3
8
8
E1 + 1
E1 + 1
E1 + 1
A2
B2
E2 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E1 + 1
A2
B2
A1
B2
B2
B2
B2
B1
B1
B1
B1
E1 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
B1
E2 − 1
B2
E1 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 − 1
E1 − 1
E1 + 1
A2
F⬘
8
9
7
8
9
7
8
9
7
8
9
7
8
9
7
5
7
6
9
11
10
9
10
8
J⬙
K⬙a
⌫⬙
10
13
23
10
10
10
20
9
9
9
9
20
13
9
9
9
9
9
9
9
9
10
10
10
10
30
9
9
9
9
9
9
9
9
23
23
13
5
5
5
5
30
27
25
27
9
9
9
9
8
8
8
8
30
30
16
16
2
1
4
2
2
2
8
5
5
5
5
8
1
5
5
5
5
5
5
5
5
1
1
1
1
2
5
5
5
5
5
5
5
5
4
4
1
1
1
1
1
2
10
1
10
0
0
0
0
0
0
0
0
2
2
7
7
E1 + 1
E1 + 1
E1 − 1
A1
B1
E2 − 1
E1 − 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
E2 + 1
B2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 − 1
E1 − 1
E1 − 1
E2 + 1
E1 + 1
A1
B1
A2
B1
B1
B1
B1
B2
B2
B2
B2
E1 + 1
E2 − 1
E2 + 1
E1 + 1
E1 + 1
E1 + 1
E1 + 1
B2
E2 − 1
B1
E1 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 − 1
E1 + 1
A1
F⬙
9
10
8
9
10
8
9
10
8
9
10
8
9
10
8
4
6
5
8
10
9
8
9
7
Obs. Freq. 共unc.兲
共MHz兲
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
488 360.081 共0.015兲*
488 466.447 共0.030兲*
488 668.227 共0.062兲*
488 741.694 共0.015兲*
488 755.966 共0.015兲*
488 758.144 共0.016兲*
488 963.857 共0.108兲*
489 491.729 共0.052兲*
489 491.332 共0.052兲
489 491.897 共0.052兲
489 491.967 共0.052兲
489 849.838 共0.122兲*
490 911.504 共0.048兲*
491 188.143 共0.047兲*
491 187.746 共0.047兲
491 188.311 共0.047兲
491 188.381 共0.047兲
491 741.093 共0.052兲*
491 740.696 共0.052兲
491 741.262 共0.052兲
491 741.331 共0.052兲
491 809.030 共0.013兲*
491 894.586 共0.013兲*
491 928.007 共0.013兲*
491 947.764 共0.013兲*
492 554.770 共1.041兲*
492 702.174 共0.048兲*
492 701.777 共0.048兲
492 702.342 共0.048兲
492 702.412 共0.048兲
492 702.174 共0.048兲*
492 701.776 共0.048兲
492 702.342 共0.048兲
492 702.411 共0.048兲
493 043.048 共0.057兲*
493 087.276 共0.060兲*
493 396.313 共0.030兲*
493 487.663 共0.014兲*
493 487.306 共0.014兲
493 487.444 共0.014兲
493 488.216 共0.014兲
493 850.437 共1.055兲*
494 367.757 共0.207兲*
494 581.735 共0.258兲*
495 321.727 共0.261兲*
496 209.779 共0.016兲*
496 209.445 共0.016兲
496 209.518 共0.016兲
496 210.366 共0.016兲
496 790.379 共0.013兲*
496 789.532 共0.013兲
496 790.736 共0.013兲
496 790.886 共0.013兲
497 123.149 共0.692兲*
497 145.400 共0.683兲*
497 316.739 共0.094兲*
497 390.391 共0.099兲*
92.513
138.818
451.609
92.630
92.668
92.442
483.448
134.448
134.448
134.448
134.448
483.238
138.652
134.487
134.487
134.487
134.487
134.250
134.250
134.250
134.250
85.076
85.135
85.119
84.963
696.384
134.277
134.277
134.277
134.277
134.277
134.277
134.277
134.277
451.463
451.579
138.754
25.444
25.444
25.444
25.444
696.409
828.110
477.388
828.282
66.868
66.868
66.868
66.868
53.590
53.590
53.590
53.590
696.181
696.168
333.564
333.746
0.998
7.089
0.811
1.002
1.003
0.999
2.590
0.524
0.173
0.193
0.154
2.594
7.188
0.524
0.173
0.193
0.154
0.524
0.173
0.193
0.154
1.026
1.029
1.031
1.025
13.209
0.524
0.173
0.193
0.154
0.524
0.173
0.193
0.154
6.359
2.692
7.035
1.193
0.325
0.459
0.387
13.459
3.951
3.916
3.947
0.113
0.034
0.041
0.037
7.145
2.352
2.632
2.101
13.130
12.885
1.770
1.768
3
3
3
1
3
1
3
3
3
3
3
1
3
1
1
1
1
3
3
3
3
1
3
1
3
1
3
3
3
3
3
3
3
3
3
1
1
3
3
3
3
3
1
3
3
1
1
1
1
1
1
1
1
1
3
3
1
Ref.
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
1276
V. ILYUSHIN AND F. J. LOVAS
TABLE 2. Microwave transitions of CH3NH2 in order of frequency—Continued
J⬘
K⬘a
⌫⬘
15
6
6
6
6
19
16
9
9
9
9
26
6
6
6
6
8
2
2
2
2
9
1
1
1
1
1
11
2
2
2
2
A1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B1
B2
B2
B2
B2
E2 + 1
E2 − 1
E2 − 1
E2 − 1
E2 − 1
F⬘
5
7
6
9
10
8
5
7
6
J⬙
K⬙a
⌫⬙
16
5
5
5
5
20
15
8
8
8
8
27
5
5
5
5
7
1
1
1
1
8
2
0
0
0
0
10
1
1
1
1
A2
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E1 + 1
B2
B1
B1
B1
B1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
E2 + 1
F⬙
Obs. Freq. 共unc.兲
共MHz兲
4
6
5
8
9
7
4
6
5
6. References
Calc. Freq. 共unc.兲
共MHz兲
El
共cm−1兲
␮ 2S
共D2兲
Wst
497 390.391 共0.099兲*
498 062.504 共0.014兲*
498 062.238 共0.014兲
498 062.337 共0.014兲
498 062.922 共0.014兲
498 165.864 共0.134兲*
498 177.050 共0.060兲*
499 120.603 共0.022兲*
499 119.729 共0.022兲
499 120.972 共0.022兲
499 121.126 共0.022兲
499 846.068 共0.200兲*
499 867.612 共0.015兲*
499 867.360 共0.015兲
499 867.454 共0.015兲
499 868.007 共0.015兲
333.746
25.426
25.426
25.426
25.426
483.060
189.083
53.393
53.393
53.393
53.393
828.259
25.426
25.426
25.426
25.426
1.768
2.765
0.754
1.064
0.896
2.595
7.366
7.323
2.411
2.698
2.154
3.944
1.163
0.317
0.447
0.377
1
1
1
1
1
3
3
3
3
3
3
1
1
1
1
1
Ref.
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14
N. Ohashi, S. Tsunekawa, K. Takagi, and J. T. Hougen, J. Mol. Spectrosc.
137, 33 共1989兲.
15
D. R. Lide, Jr., J. Chem. Phys. 27, 343 共1957兲.
16
B. N. Taylor and C. E. Kuyatt, NIST Technical Note No. 1297, 1994. The
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17
W. H. Kirchhoff, J. Mol. Spectrosc. 41, 333 共1972兲.
18
N. Kaifu, M. Morimoto, K. Nagane, K. Akabane, T. Iguchi, and K.
Takagi, Astrophys. J., Lett. Ed. 191, L135 共1974兲.
19
N. Fourikis, K. Takagi, and M. Morimoto, Astrophys. J., Lett. Ed. 191,
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20
C. H. Townes and A. L. Schawlow, Microwave Spectroscopy 共McGrawHill, New York, NY, 1955兲.
11
12
13
1
V. V. Ilyushin, E. A. Alekseev, S. F. Dyubko, R. A. Motiyenko, and J. T.
Hougen, J. Mol. Spectrosc. 229, 170 共2005兲.
N. Ohashi and J. T. Hougen, J. Mol. Spectrosc. 121, 474 共1987兲.
3
K. Shimoda, T. Nishikawa, and T. Itoh, J. Phys. Soc. Jpn. 9, 974 共1954兲.
4
D. R. Lide, Jr., J. Chem. Phys. 22, 1613 共1954兲.
5
H. Hirakawa, A. Miyahara, and K. Shimoda, J. Phys. Soc. Jpn. 11, 334
共1956兲.
6
T. Nishikawa, J. Phys. Soc. Jpn. 12, 668 共1957兲.
7
K. Takagi and T. Kojima, J. Phys. Soc. Jpn. 30, 1145 共1971兲.
8
K. Takagi and T. Kojima, Astrophys. J. 181, L91 共1973兲.
9
N. Ohashi, K. Takagi, J. T. Hougen, W. B. Olson, and W. J. Lafferty, J.
Mol. Spectrosc. 126, 443 共1987兲.
10
M. Kreglewski, W. Stahl, J.-U. Grabow, and G. Wlodarczak, Chem.
Phys. Lett. 196, 155 共1992兲.
2
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 29 Jul 2011 to 129.6.105.191. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions