GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 1 of 14
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
Ready America Lighstick: Item #: 27017,27019,25013,27260,27217
STATEMENT OF HAZARDOUS NATURE
CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200
NFPA
1
FLAMMABILITY
1
0
INSTABILITY
HEALTH HAZARD
SUPPLIER
Company:Ready America, Inc.
Address:
1150 Simpson Way
Escondido, CA 92029
760-466-1060
PRODUCT USE
Festival, Party, Camping
SYNONYMS
"Glow Sticks, Lightsticks, Glow Bracelets, Glow Necklaces, Glow Cups in Green, Blue, Yellow, PInk, Red, Purple,
White, Aqua, Orange"
Section 2 - HAZARDS IDENTIFICATION
CANADIAN WHMIS SYMBOLS
None
EMERGENCY OVERVIEW
RISK
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
■ The material has NOT been classified by EC Directives or other classification systems as "harmful by
ingestion". This is because of the lack of corroborating animal or human evidence. The material may still be
damaging to the health of the individual, following ingestion, especially where pre-existing organ (eg. liver,
kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 2 of 14
Section 2 - HAZARDS IDENTIFICATION
producing mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal tract
discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant
quantities is not thought to be cause for concern.
■ The toxicity of phthalates is not excessive due to slow oral absorption and metabolism. Absorption is
affected by fat in the diet. Repeated doses can cause cumulative toxic effects, and symptoms include an
enlarged liver which often reverses if exposure is maintained. Carbohydrate metabolism is disrupted, and
cholesterol and triglyceride levels in the blood falls. There can also be withering of the testicles. Some
phthalates can increase the effects of antibiotics, thiamine (vitamin B1) and sulfonamides.
EYE
■ Evidence exists, or practical experience predicts, that the material may cause eye irritation in a
substantial number of individuals. Prolonged eye contact may cause inflammation characterised by a temporary
redness of the conjunctiva (similar to windburn).
SKIN
■ Skin contact is not thought to have harmful health effects (as classified under EC Directives); the
material may still produce health damage following entry through wounds, lesions or abrasions.
■ Open cuts, abraded or irritated skin should not be exposed to this material.
■ The material may cause severe inflammation of the skin either following direct contact or after a delay of
some time. Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and
blistering.
INHALED
■ Inhalation hazard is increased at higher temperatures.
■ The material has NOT been classified by EC Directives or other classification systems as "harmful by
inhalation". This is because of the lack of corroborating animal or human evidence. In the absence of such
evidence, care should be taken nevertheless to ensure exposure is kept to a minimum and that suitable control
measures be used, in an occupational setting to control vapours, fumes and aerosols.
■ Not normally a hazard due to non-volatile nature of product.
■ The material can cause respiratory irritation in some persons. The body's response to such irritation can
cause further lung damage.
CHRONIC HEALTH EFFECTS
■ Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as
classified by EC Directives using animal models); nevertheless exposure by all routes should be minimised as
a matter of course.
There has been some concern that this material can cause cancer or mutations but there is not enough data to
make an assessment.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or longterm occupational exposure.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME
dimethyl phthalate
hydrogen peroxide
CAS RN
131-11-3
7722-84-1
%
50-60
1-3
Section 4 - FIRST AID MEASURES
SWALLOWED
• Immediately give a glass of water.
• First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
continued...
GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 3 of 14
Section 4 - FIRST AID MEASURES
EYE
■ If this product comes in contact with the eyes:
• Wash out immediately with fresh running water.
• Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by
occasionally lifting the upper and lower lids.
• Seek medical attention without delay; if pain persists or recurs seek medical attention.
• Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
■ If skin contact occurs:
• Immediately remove all contaminated clothing, including footwear.
• Flush skin and hair with running water (and soap if available).
• Seek medical attention in event of irritation.
INHALED
• If fumes or combustion products are inhaled remove from contaminated area.
• Other measures are usually unnecessary.
NOTES TO PHYSICIAN
■ Treat symptomatically.
for poisons (where specific treatment regime is absent):
-------------------------------------------------------------BASIC TREATMENT
-------------------------------------------------------------• Establish a patent airway with suction where necessary.
• Watch for signs of respiratory insufficiency and assist ventilation as necessary.
• Administer oxygen by non-rebreather mask at 10 to 15 L/min.
• Monitor and treat, where necessary, for pulmonary oedema .
• Monitor and treat, where necessary, for shock.
• Anticipate seizures .
• DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg
recommended) for dilution where patient is able to swallow, has a strong gag reflex and does not drool.
-------------------------------------------------------------ADVANCED TREATMENT
-------------------------------------------------------------• Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where
respiratory arrest has occurred.
• Positive-pressure ventilation using a bag-valve mask might be of use.
• Monitor and treat, where necessary, for arrhythmias.
• Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload
might create complications.
• Drug therapy should be considered for pulmonary oedema.
• Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might
create complications.
• Treat seizures with diazepam.
• Proparacaine hydrochloride should be used to assist eye irrigation.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994.
Section 5 - FIRE FIGHTING MEASURES
Vapour Pressure (mmHG): Not Available
Upper Explosive Limit (%): Not Available
Specific Gravity (water=1): Not Available
Lower Explosive Limit (%): Not Available
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 4 of 14
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
• Foam.
• Dry chemical powder.
• BCF (where regulations permit).
• Carbon dioxide.
• Water spray or fog - Large fires only.
FIRE FIGHTING
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear full body protective clothing with breathing apparatus.
• Prevent, by any means available, spillage from entering drains or water course.
• Use water delivered as a fine spray to control fire and cool adjacent area.
• Avoid spraying water onto liquid pools.
• DO NOT approach containers suspected to be hot.
• Cool fire exposed containers with water spray from a protected location.
• If safe to do so, remove containers from path of fire.
GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS
• Combustible.
• Slight fire hazard when exposed to heat or flame.
• Heating may cause expansion or decomposition leading to violent rupture of containers.
• On combustion, may emit toxic fumes of carbon monoxide (CO).
• May emit acrid smoke.
• Mists containing combustible materials may be explosive.
Combustion products include: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of
burning organic material.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
• Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine
etc. as ignition may result.
Personal Protective Equipment
Gloves, boots (chemical resistant).
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
• Remove all ignition sources.
• Clean up all spills immediately.
• Avoid breathing vapours and contact with skin and eyes.
• Control personal contact by using protective equipment.
• Contain and absorb spill with sand, earth, inert material or vermiculite.
• Wipe up.
• Place in a suitable, labelled container for waste disposal.
MAJOR SPILLS
■ Moderate hazard.
• Clear area of personnel and move upwind.
• Alert Fire Brigade and tell them location and nature of hazard.
• Wear breathing apparatus plus protective gloves.
• Prevent, by any means available, spillage from entering drains or water course.
• No smoking, naked lights or ignition sources.
• Increase ventilation.
• Stop leak if safe to do so.
• Contain spill with sand, earth or vermiculite.
• Collect recoverable product into labelled containers for recycling.
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 5 of 14
Section 6 - ACCIDENTAL RELEASE MEASURES
• Absorb remaining product with sand, earth or vermiculite.
• Collect solid residues and seal in labelled drums for disposal.
• Wash area and prevent runoff into drains.
• If contamination of drains or waterways occurs, advise emergency services.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
• DO NOT allow clothing wet with material to stay in contact with skin.
• Avoid all personal contact, including inhalation.
• Wear protective clothing when risk of exposure occurs.
• Use in a well-ventilated area.
• Prevent concentration in hollows and sumps.
• DO NOT enter confined spaces until atmosphere has been checked.
• Avoid smoking, naked lights or ignition sources.
• Avoid contact with incompatible materials.
• When handling, DO NOT eat, drink or smoke.
• Keep containers securely sealed when not in use.
• Avoid physical damage to containers.
• Always wash hands with soap and water after handling.
• Work clothes should be laundered separately.
• Use good occupational work practice.
• Observe manufacturer's storing and handling recommendations.
• Atmosphere should be regularly checked against established exposure standards to ensure safe working
conditions.
RECOMMENDED STORAGE METHODS
• Metal can or drum
• Packaging as recommended by manufacturer.
• Check all containers are clearly labelled and free from leaks.
STORAGE REQUIREMENTS
• Store in original containers.
• Keep containers securely sealed.
• No smoking, naked lights or ignition sources.
• Store in a cool, dry, well-ventilated area.
• Store away from incompatible materials and foodstuff containers.
• Protect containers against physical damage and check regularly for leaks.
• Observe manufacturer's storing and handling recommendations.
_____________________________________________________
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
+
+
+
+
X
+
_____________________________________________________
+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 6 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
US OSHA Permissible Exposure Levels ( PELs)
Z
Material
__
_______
Z1
Dimethylphthalate
Z1
Hydrogen peroxide
Source
___________
US OSHA Permissible
Exposure Levels (PELs) Table Z1
US ACGIH Threshold Limit
Values (TLV)
Material
___________
dimethyl phthalate
(Dimethylphthalate)
US - California Permissible
Exposure Limits for
Chemical Contaminants
Canada - Prince Edward
Island Occupational
Exposure Limits
TWA ppm
____
1
TWA mg/m³
_______
5
Notes
_______
dimethyl phthalate
(Dimethyl phthalate)
5
TLV Basis:
eye & upper
respiratory
tract
irritation
dimethyl phthalate
(Dimethyl phthalate)
5
dimethyl phthalate
(Dimethyl phthalate)
5
US - Oregon Permissible
Exposure Limits (Z- 1)
US OSHA Permissible
Exposure Levels (PELs) Table Z1
US ACGIH Threshold Limit
Values (TLV)
dimethyl phthalate
(Dimethylphthalate)
hydrogen peroxide (Hydrogen
peroxide)
5
hydrogen peroxide (Hydrogen
peroxide)
1
US - California Permissible
Exposure Limits for
Chemical Contaminants
Canada - Prince Edward
Island Occupational
Exposure Limits
hydrogen peroxide (Hydrogen
peroxide, as H2O2)
1
hydrogen peroxide (Hydrogen
peroxide)
1
hydrogen peroxide (Hydrogen
peroxide)
1
US - Oregon Permissible
Exposure Limits (Z- 1)
EMERGENCY EXPOSURE LIMITS
Material
dimethyl phthalate|10082
hydrogen peroxide
Revised
2, 000
5
TWA ppm
_______
TWA mg/m³
____
5
1.4
1
TLV Basis:
eye & upper
respiratory
tract
irritation
1.4
TLV Basis:
eye, upper
respiratory
tract & skin
irritation
1.4
TLV Basis:
eye, upper
respiratory
tract & skin
irritation
1.4
IDLH
75 [Unch]
MATERIAL DATA
GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS:
■ Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
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CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 7 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
throat. Historically occupational exposure standards for these irritants have been based on observation of
workers' responses to various airborne concentrations. Present day expectations require that nearly every
individual should be protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-observable-effectlevels (NOEL) are used to determine these limits where human results are unavailable. An additional approach,
typically used by the TLV committee (USA) in determining respiratory standards for this group of chemicals,
has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure
limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine
to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-category system based on
intensive odour, local irritation, and elimination half-life. However this system is being replaced to be
consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this
is more closely allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
• cause inflammation
• cause increased susceptibility to other irritants and infectious agents
• lead to permanent injury or dysfunction
• permit greater absorption of hazardous substances and
• acclimate the worker to the irritant warning properties of these substances thus increasing the risk of
overexposure.
DIMETHYL PHTHALATE:
■ For dimethyl phthalate:
The TLV has been recommended to control the excess mist rather than to protect against toxic effects.
HYDROGEN PEROXIDE:
■ for hydrogen peroxide
NOTE: Detector tubes for hydrogen peroxide, measuring in excess of 0.1 ppm, are available commercially.
Exposure at or below the TLV-TWA is thought to minimise irritation and bleaching of hair.
PERSONAL PROTECTION
EYE
• Safety glasses with side shields.
• Chemical goggles.
• Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A
written policy document, describing the wearing of lens or restrictions on use, should be created for each
workplace or task. This should include a review of lens absorption and adsorption for the class of
chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in
their removal and suitable equipment should be readily available. In the event of chemical exposure, begin
eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the
first signs of eye redness or irritation - lens should be removed in a clean environment only after workers
have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
• Wear chemical protective gloves, eg. PVC.
• Wear safety footwear or safety gumboots, eg. Rubber.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves
include: such as:
• frequency and duration of contact,
• chemical resistance of glove material,
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 8 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
• glove thickness and
• dexterity
Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739).
• When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher
(breakthrough time greater than 240 minutes according to EN 374) is recommended.
• When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time
greater than 60 minutes according to EN 374) is recommended.
• Contaminated gloves should be replaced.
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturiser is recommended.
OTHER
• Overalls.
• P.V.C. apron.
• Barrier cream.
• Skin cleansing cream.
• Eye wash unit.
ENGINEERING CONTROLS
■ General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in
special circumstances. If risk of overexposure exists, wear approved respirator. Supplied-air type respirator
may be required in special circumstances. Correct fit is essential to ensure adequate protection. Provide
adequate ventilation in warehouses and enclosed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Liquid.
State
Melting Range (°
F)
Boiling Range (°
F)
Flash Point (°
F)
Decomposition Temp (°
F)
Autoignition Temp (°
F)
Upper Explosive Limit (%)
Lower Explosive Limit (%)
Volatile Component (%vol)
Liquid
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Molecular Weight
Viscosity
Solubility in water (g/L)
pH (1% solution)
pH (as supplied)
Vapour Pressure (mmHG )
Specific Gravity (water=1)
Relative Vapour Density
(air=1)
Evaporation Rate
Not Available
Not Available
P artly Miscible
Not Availabl e
Not A vailable
Not Available
Not Available
Not Available
Not Available
APPEARANCE
green, blue, yellow, pink, red, purple, white, aqua, orange
Material
DIMETHYL PHTHALATE:
log Kow
HYDROGEN PEROXIDE:
log Kow
Value
1.56- 2.12
- 1.36
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 9 of 14
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
• Presence of incompatible materials.
• Product is considered stable.
• Hazardous polymerisation will not occur.
STORAGE INCOMPATIBILITY
• Avoid strong bases.
• Avoid reaction with oxidising agents.
For incompatible materials - refer to Section 7 - Handling and Storage.
Section 11 - TOXICOLOGICAL INFORMATION
Glow Sticks, Glow Bracelets, Glow Necklaces, Glow Cups
TOXICITY AND IRRITATION
■ Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may
be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur
following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS
include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A
reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity
on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia,
have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating
inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to
the irritating substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of
exposure due to high concentrations of irritating substance (often particulate in nature) and is completely
reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production.
Section 12 - ECOLOGICAL INFORMATION
HYDROGEN PEROXIDE:
DIMETHYL PHTHALATE:
■ DO NOT discharge into sewer or waterways.
DIMETHYL PHTHALATE:
■ On the basis of available evidence concerning either toxicity, persistence, potential to accumulate and or
observed environmental fate and behaviour, the material may present a danger, immediate or long-term and /or
delayed, to the structure and/ or functioning of natural ecosystems.
for phthalate esters:
Environmental fate;
Under aerobic and anaerobic conditions, studies reveal that many phthalate esters are degraded by a wide
range of bacteria and actinomycetes. Standardized aerobic biodegradation tests with sewage sludge inocula
show that within 28 days approximately 50% ultimate degradation occurs. Biodegradation is, therefore,
expected to be the dominant pathway in surface soils and sediments. In the atmosphere, photodegradation via
free radical attack is the anticipated dominant pathway. The half-life of many phthalate esters is ca. 1 day
in the air, from < 1 day to 2 weeks in surface and marine waters, and from < 1 week to several months in
soils.
Phthalates are high molecular weight chemicals, and are not expected to partition significantly to air.
However for the minor amount that may partition to air, modelled predictions indicate that they would be
rapidly oxidised: with a
predicted atmospheric oxidation half-life of around 0.52 days . They are expected
to react appreciably with other photo oxidative species in the atmosphere, such as O3. Therefore, it is
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Version No:2.0
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Section 12 - ECOLOGICAL INFORMATION
expected that reactions with hydroxyl radicals will be the most important fate process in the atmosphere for
phthalates.
Bioaccumulation of phthalate esters in the aquatic and terrestrial food chain is limited by biotransformation.
Most phthalates have experimental bioaccumulation factor (BCFs) and bioconcentration factor (BAFs) below 5000
L/kg, as they are readily metabolised by fish
A study of 18 commercial phthalate esters with alkyl chains ranging from one to 13 carbons found an eight
order of magnitude increase in octanol-water coefficients (Kow) and a four order of magnitude decrease in
vapor pressure with increasing length. This increase in Kow and decrease in vapor pressure results in
increased partitioning of the phthalate esters to suspended solids, soils, sediments, and aerosols
The phthalate esters are distributed throughout the environment ubiquitously. They are found complexed with
fulvic acid components of the humic substances in soil and marine and estuarine waters. Fulvic acid appears
to act as a solubiliser for the otherwise insoluble ester and serves to mediate its transport and
mobilisation in water or immobilisation in soil. Phthalate esters have been found in open ocean environments,
in deep sea jelly fish, Atlantic herring and in mackerel. Phthalic ester plasticisers are clearly recognised
as general contaminants of almost every soil and water ecosystem. In general they have low acute toxicity but
the weight of evidence supporting their carcinogenicity is substantial. Other subtle chronic effects have
also been reported. As little as 4 ug/ml in culture medium is lethal to chick embryo heart cells. This
concentration is similar to that reached in human blood stored in vinyl plastic bags for as little as one
day. As phthalates are present in drinking water and food, concerns have been raised about their long term
effects on humans.
Ecotoxicity:
Some phthalates (notably di-2-ethylhexyl phthalate and dibutyl phthalate) may be detrimental to the
reproduction of the water flea (Daphnia magna), zebra fish and guppies
While phthalates may have very low true water solubilities, they possess the ability to form suspensions
which may cause adverse effects through physical contact with Daphnia at very low concentrations.
Available toxicity and water solubility information suggest that the high molecular weight phthalates, form
these suspensions and are able to elicit chronic toxic effects at concentrations of approximately 0.05 mg/L .
Therefore, these substances are considered to have the potential to harm aquatic organisms at relatively low
concentrations.
log Kow: 1.56-2.12
Koc: 44-160
Half-life (hr) air: 23.8
Half-life (hr) H2O surface water: 6-260
Henry's atm m³ /mol: 1.10E-07
BCF: 4.7-5.4
Fish LC50 (96 h): 17 mg/L
HYDROGEN PEROXIDE:
■ For hydrogen peroxide:
log Kow: -1.36
Environmental fate:
Hydrogen peroxide is a naturally occurring substance (typical background concentrations < 1 - 30 g/l). Almost
all cells with the exception of anaerobic bacteria produce it in their metabolism. Hydrogen peroxide is a
reactive substance in the presence of other substances, elements, radiation, materials and can be degraded by
micro-organisms or higher organisms.
Air: Hydrogen peroxide may be removed from the atmosphere by photolysis giving rise to hydroxyl radicals, by
reaction with hydroxyl radicals, or by heterogenous loss processes such as rain-out. Significantly higher
hydrogen peroxide concentrations are found in polluted atmospheres as compared with clean air. These
concentrations are believed to arise from photochemically-initiated oxidation of reactive hydrocarbons. Under
severe smog conditions, daytime levels of hydrogen peroxide as high as 0.18 ppm have been reported, but
atmospheric night-time levels of 2-5 ppb did not correlate to smog intensity.
Soil: No information was found in the secondary sources searched regarding the transformation or persistence
of hydrogen peroxide in soil, however, solutions of hydrogen peroxide gradually deteriorate.
Water: Hydrogen peroxide is a naturally occurring substance. Surface water concentrations of hydrogen
peroxide have been found to vary between 51-231 mg/L, increasing both with exposure to sunlight and the
presence of dissolved organic matter.
Hydrogen peroxide degrades by various mechanisms, including chemical reduction and enzymatic (catalase and
peroxidase) decomposition by algae, zooplankton, and bacteria. Microorganisms, especially bacteria, account
for the majority of degradation, significantly more than all other chemical and biological mechanisms. The
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GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
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Section 12 - ECOLOGICAL INFORMATION
rate at which hydrogen peroxide decomposes in natural water can vary from a few minutes to more than a week,
depending on numerous chemical, biological, and physical factors.
Hydrogen peroxide is rapidly degraded in a biological waste water treatment plant. Hydrogen peroxide adsorbs
poorly to sediment particles and is rapidly degraded, thus accumulation in the sediment is also not expected
Hydrogen peroxide (log Kow < -1) is an inorganic substance and therefore shows little potential to
bioaccumulate.
Ecotoxicity:
Fish LC50 (96 h): catfish 37.4 mg/l
Fish LC50 (24 h): mackerel 89 mg/l; chameleon gobi 155 mg/l
Zebra mussel LC50 (28 h) 30 mg/l; (228 h): 12 mg/l
Ecotoxicity data show that microorganisms (i.e., bacteria, algae) and zooplankton present in aquatic
ecosystems are generally less tolerant of hydrogen peroxide exposure than are fish or other vertebrates.
Effects of short-term exposures on sensitive bacteria and invertebrates (e.g., Daphnia pulex) have been
observed at concentrations in the low mg/L (ppm) range, while effects on sensitive algae have been reported
at levels less than 1.0 mg/L. Algae are the most sensitive species for hydrogen peroxide. The algal EC50 of
hydrogen peroxide was 1.6-5 mg/l, while the NOEC was 0.1 mg/l. In a 21-d continuous exposure study on Daphnia
magna, the chronic no observable effect concentration (NOEC) for reproduction was 0.63 mg/L and the NOEC for
mortality was 1.25 mg/L.
In chronic toxicity studies with invertebrates (zebra mussels) and hydrogen peroxide shows an NOEC of 2 mg/l.
The PNEC of hydrogen peroxide is equal to 10 ug/l.
Risk mitigation is needed to ensure that use of hydrogen peroxide will not adversely impact aquatic life. An
acute water quality criterion or "benchmark" has been determined. For hydrogen peroxide, the acute benchmark
is 0.7 mg/L. This value was calculated using the extensive toxicity database for hydrogen peroxide and
procedures in U.S. Environmental Protection Agency guidance for deriving numerical national water quality
criteria. The use of hydrogen peroxide in intensive aquaculture in finfish (at up to 100 mg/L for 60 minutes)
and finfish eggs (at up to 1,000 mg/L for 15 minutes) is not expected to have a significant impact on the
environment.
Ecotoxicity
Ingredient
dimethyl phthalate
hydrogen peroxide
Persistence:
Water/Soil
LOW
LOW
Persistence: Air
Bioaccumulation
Mobility
HIGH
LOW
LOW
HIGH
HIGH
Section 13 - DISPOSAL CONSIDERATIONS
US EPA Waste Number & Descriptions
B. Component Waste Numbers
When dimethyl phthalate is present as a solid waste as a discarded commercial
chemical product, off-specification species, as a container residue, or a spill
residue, use EPA waste number U102 (waste code I).
Disposal Instructions
All waste must be handled in accordance with local, state and federal regulations.
• DO NOT allow wash water from cleaning or process equipment to enter drains.
• It may be necessary to collect all wash water for treatment before disposal.
• In all cases disposal to sewer may be subject to local laws and regulations and these should be considered
first.
• Where in doubt contact the responsible authority.
• Recycle wherever possible or consult manufacturer for recycling options.
• Consult State Land Waste Authority for disposal.
• Bury or incinerate residue at an approved site.
• Recycle containers if possible, or dispose of in an authorised landfill.
continued...
GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 12 of 14
Section 14 - TRANSPORTATION INFORMATION
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: DOT, IATA, IMDG
Section 15 - REGULATORY INFORMATION
REGULATIONS
ND
Ingredient
CAS
dimethyl phthalate
131- 11- 3
% de minimus
concentration
1.0
ND
Ingredient
dimethyl phthalate
CAS
131- 11- 3
RQ
5000 lb (2270 kg)
Regulations for ingredients
dimethyl phthalate (CAS: 131-11-3) is found on the following regulatory lists;
"Canada - Prince Edward Island Occupational Exposure Limits","Canada National Pollutant Release Inventory (NPRI)","GESAMP/EHS Composite List - GESAMP Hazard
Profiles","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","International Fragrance Association (IFRA) Survey: Transparency
List","US - California Permissible Exposure Limits for Chemical Contaminants","US - Oregon Permissible Exposure Limits (Z-1)","US ACGIH Threshold Limit Values
(TLV)","US Clean Air Act - Hazardous Air Pollutants","US CWA (Clean Water Act) - Priority Pollutants","US EPCRA Section 313 Chemical List","US FDA Indirect
Food Additives: Adhesives and Components of Coatings - Substances for Use Only as Components of Adhesives - Adhesives","US List of Lists - Consolidated List of
Chemicals Subject to EPCRA, CERCLA and Section 112(r) of the Clean Air Act","US OSHA Permissible Exposure Levels (PELs) - Table Z1","US Toxic Substances
Control Act (TSCA) - Inventory","US TSCA Section 4 - Chemicals Subject to Testing Consent Orders","US TSCA Section 4/12 (b) - Sunset Date/Status","US TSCA
Section 8 (d) - Health and Safety Data Reporting"
hydrogen peroxide (CAS: 7722-84-1) is found on the following regulatory lists;
"Canada - Prince Edward Island Occupational Exposure Limits","Canada - Prince Edward Island Occupational Exposure Limits - Carcinogens","GESAMP/EHS Composite
List - GESAMP Hazard Profiles","IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk","International Agency for Research on Cancer
(IARC) - Agents Reviewed by the IARC Monographs","International Air Transport Association (IATA) Dangerous Goods Regulations","US - California Permissible
Exposure Limits for Chemical Contaminants","US - Oregon Permissible Exposure Limits (Z-1)","US ACGIH Threshold Limit Values (TLV)","US ACGIH Threshold Limit
Values (TLV) - Carcinogens","US FDA Indirect Food Additives: Adhesives and Components of Coatings - Substances for Use Only as Components of Adhesives Adhesives","US List of Lists - Consolidated List of Chemicals Subject to EPCRA, CERCLA and Section 112(r) of the Clean Air Act","US OSHA Permissible Exposure
Levels (PELs) - Table Z1","US SARA Section 302 Extremely Hazardous Substances","US Toxic Substances Control Act (TSCA) - Inventory","USA: Chemical Facility
Anti-Terrorism Standards - List Appendix A - 6CFR 27"
No data for Glow Sticks, Glow Bracelets, Glow Necklaces, Glow Cups (CW: 1230432)
Section 16 - OTHER INFORMATION
LIMITED EVIDENCE
#Regulations for ingredients
continued...
GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 13 of 14
Section 16 - OTHER INFORMATION
#dimethyl phthalate (CAS: 131- 11- 3) is found on the following regulatory
lists;
" Canada - Prince Edward Island Occupational Exposure Limits" , " Canada
National Pollutant Release Inventory (NPRI)" , " GESAMP/EHS Composite List GESAMP Hazard Profiles" , " IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid
Substances Carried in Bulk" , " International Fragrance Association (IFRA)
Survey: Transparency List" , " US - California Permissible Exposure Limits for
Chemical Contaminants" , " US - Oregon Permissible Exposure Limits (Z- 1)" , "
US ACGIH Threshold Limit Values (TLV)" , " US Clean Air Act - Hazardous Air
Pollutants" , " US CWA (Clean Water Act) - Priority Pollutants" , " US EPCRA
Section 313 Chemical List" , " US FDA Indirect Food Additives: Adhesives and
Components of Coatings - Substances for Use Only as Components of Adhesives Adhesives" , " US List of Lists - Consolidated List of Chemicals Subject to
EPCRA, CERCLA and Section 112(r) of the Clean Air Act" , " US OSHA Permissible
Exposure Levels (PELs) - Table Z1" , " US Toxic Substances Control Act (TSCA) Inventory" , " US TSCA Section 4 - Chemicals Subject to Testing Consent Orders"
, " US TSCA Section 4/12 (b) - Sunset Date/Status" , " US TSCA Section 8 (d) Health and Safety Data Reporting"
#hydrogen peroxide (CAS: 7722- 84- 1) is found on the following regulatory
lists;
" Canada - Prince Edward Island Occupational Exposure Limits" , " Canada Prince Edward Island Occupational Exposure Limits - Carcinogens" , " GESAMP/EHS
Composite List - GESAMP Hazard Profiles" , " IMO MARPOL 73/78 (Annex II) - List
of Noxious Liquid Substances Carried in Bulk" , " International Agency for
Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs" , "
International Air Transport Association (IATA) Dangerous Goods Regulations" , "
US - California Permissible Exposure Limits for Chemical Contaminants" , " US Oregon Permissible Exposure Limits (Z- 1)" , " US ACGIH Threshold Limit Values
(TLV)" , " US ACGIH Threshold Limit Values (TLV) - Carcinogens" , " US FDA
Indirect Food Additives: Adhesives and Components of Coatings - Substances for
Use Only as Components of Adhesives - Adhesives" , " US List of Lists Consolidated List of Chemicals Subject to EPCRA, CERCLA and Section 112(r) of
the Clean Air Act" , " US OSHA Permissible Exposure Levels (PELs) - Table Z1" ,
" US SARA Section 302 Extremely Hazardous Substances" , " US Toxic Substances
Control Act (TSCA) - Inventory" , " USA: Chemical Facility Anti- Terrorism
Standards - List Appendix A - 6CFR 27"
EXPOSURE STANDARD FOR MIXTURES
■ "Worst Case" computer-aided prediction of spray/ mist or fume/ dust components and concentration:
■ Composite Exposure Standard for Mixture (TWA) :100 mg/m³.
continued...
GLOW STICKS, GLOW BRACELETS, GLOW NECKLACES, GLOW CUPS
Chemwatch Material Safety Data Sheet (REVIEW)
Oct-26-2011
NC293SCP(cs)
CHEMWATCH 1230432
Version No:2.0
CD 2011/1 Page 14 of 14
Section 16 - OTHER INFORMATION
■ Classification of the preparation and its individual components has drawn on official and authoritative
sources as well as independent review by the Chemwatch Classification committee using available literature
references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors
determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined
by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering
controls must be considered.
■ For detailed advice on Personal Protective Equipment, refer to the following U.S. Regulations and Standards:
OSHA Standards - 29 CFR:
1910.132 - Personal Protective Equipment - General requirements
1910.133 - Eye and face protection
1910.134 - Respiratory Protection
1910.136 - Occupational foot protection
1910.138 - Hand Protection
Eye and face protection - ANSI Z87.1
Foot protection - ANSI Z41
Respirators must be NIOSH approved.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Oct-26-2011
Print Date: Oct-26-2011