Lecture 2 : Propagation in anisotropic media • Linear anisotropic media • Characteristic surfaces: – Index ellipsoïd – Index surface – Radial velocity surface or Ray surface NW wave optics (polarization) For more details about the calculations in these lectures: Optical waves in crystals, Yariv & Yeh (more details about some of the calculations done in this chapter, but does not mention the radial velocity surface) Optics, Born&Wolf (details of the calculation of the ray surface/ radial velocity surface from page 792 of the 7th edition) 2 2. Propagation in anisotropic media NW wave optics (polarization) 3 Review about isotropic media • Maxwell’s Equations (in a medium without sources) • Polarization : when it travels through a medium, the EM wave induces a polarization that adds up in phase to the one in vacuum: (the medium is non-magnetic: ) • We try to find a solution to Maxwell’s equations as a plane wave : (other fields: same type of expression) • We get : • E and D are parallel and transverse • B and H are perpend to them, also transverse • The Poynting vector is parallel to NW optique physique II 2. Propagation in anisotropic media Review about isotropic media Which EM waves can propagate in the medium ? • From Maxwell’s equations because • On the other hand, • So : - All transverse polarizations are possible - Dispersion relationship: • In general, we define the index of refraction: • We get : • Phase velocity : 4 2. Propagation in anisotropic media NW optique physique II Linear anisotropic media • In an anisotropic medium, the susceptibility, and thus the permittivity, are no longer scalar, but tensors (3x3 matrices): -> the medium is still linear, but no longer isotropic. • If there is no absorption, it can be shown that the permittivity tensor is symmetric • It thus has three real eigenvalues, corresponding to orthogonal eigenvectors. In the basis of these eigenvectors, the matrix can be written as : • By analogy with the isotropic medium, we define indices: The indices ni are called the principal indices of refraction. In an anisotropic medium, the index « seen » by an EM wave depends on its polarization state. 5 2. Propagation in anisotropic media NW optique physique II Linear anisotropic media Classification of materials depending on their permittivity tensor Isotropic medium with index n Uniaxial anisotropic medium, with optic axis Oz Biaxial anisotropic medium 6 NW optique physique II 2. Propagation in anisotropic media 7 Linear anisotropic media What is the structure of an EM wave propagating in an anisotropic medium ? -> D is no longer parallel to E -> D and B are still orthogonal to k -> D and H are orthogonal -> E and B are orthogonal D, E and k are in the same plane, orthogonal to B k2 1 = D=− 2 E − u .E u 2 k × k × E µ0ω µ0ω ( ) [ ( ) ] • D is the projection of E in the plane orthogonal to u (to within a mult. factor) € € vector (direction of « light ray») • The Poynting is no longer parallel to the wave vector (direction of propagation of the phase) NW optique physique II 2. Propagation in anisotropic media 8 Linear anisotropic media Which waves can propagate in a given direction? • Definitions: k0 = ω ε 0 µ 0 = ω c n is the index «seen» by the wave with direction u and 2 2 u u • From Maxwell: D = ε 0 n E − P ( E ) = ε 0 n P⊥ E [ € ] u ⊥ is P the projector on the plane perpendicular to u • Also: € : Permeability tensor. In the€ eigenvectors basis, • Condition on D: D u 2 = P⊥ [η] D = [ Au ] D n The solutions for D are eigenvectors of matrix Au 2. Propagation in anisotropic media NW optique physique II Linear anisotropic media D u 2 = P⊥ [η] D = [ Au ] D n • Eigenvectors : polarization states (vector D) that can propagate in the medium without changing their shape € Different from the isotropic case: not all polarization states can propagate • Eigenvalues : corresponding indices of refraction 1/n2 ( and phase velocities c/n) The polarization states and the corresponding indices of refraction depend on the direction of propagation u 9 NW optique physique II 2. Propagation in anisotropic media 10 Linear anisotropic media Can we show some specific properties of these eigenstates? D u 2 = P⊥ [η] D = [ Au ] D n u ⊥ is P the projector on the plane perpendicular to u, i.e. on the phase plane. • In a basis consisting of 2 vectors in the phase plane plus the vector u, the matrix can be written as: € € € [ ]= A u u P⊥ ⎡1 0 0⎤ ⎡η11 η12 η13 ⎤ ⎡η11 η12 η13 ⎤ ⎢ ⎥ ⎢ ⎥ ⎢ ⎥ [η] = ⎢ 0 1 0⎥ ⎢η12 η22 η23 ⎥ = ⎢η12 η22 η23 ⎥ ⎢⎣ 0 0 0⎥⎦ ⎢⎣η13 η23 η33 ⎥⎦ ⎢⎣ 0 0 0 ⎥⎦ [η] is not diagonal in this basis but it remains symmetric (like [ε]) Only the restriction of [Au] in the phase plane plays a role. We thus have to find the two eigenvectors and eigenvalues of a 2x2 symmetric matrix ⇒ 2 real eigenvalues 1/n’² and 1/n’’²(we will show later that they must be positive) ⇒ orthogonal eigenvectors D’⊥D’’ Since the matrix is also real, D’ and D’’ are real (linear polarizations) 2. Propagation in anisotropic media NW optique physique II Linear anisotropic media Can we calculate more precisely the eigenvalues? • The two eigenvalues 1/n2 depend on the direction of u (direction of propagation) : • To calculate them, we need to solve the equation: • We have to calculate the determinant of a 3x3 matrix. We do this calculation in the (x,y,z) frame where [ε] and [η] are diagonal. After some tedious calculations, we get Fresnel’s equation for the indices of refraction: This equation can turn into an equation of the type n4-Sn²+P=0: ⇒ we get two solutions n’² and n’’² (we showed before that they must be real) ⇒ we can show now that they are positive (S>0 and P>0): ⇒ n’ and n’’ are real numbers (propagation without absorption) 11 2. Propagation in anisotropic media NW optique physique II Linear anisotropic media We will now show an easier, graphical way to represent the solutions to Fresnel’s equation and the corresponding eigen polarizations Several characteristic surfaces • Index ellipsoïd • Index surface • Radial velocity surface or Ray surface 12 2. Propagation in anisotropic media NW optique physique II Characteristic surface 1: Index ellipsoïd Definition Let us recall the wave equation in terms of D and E: Scalar-multiplying it by D we obtain : For a given D vector, there is only one index n of propagation, given by the above equation. The surface we obtain when we report the value of the index n in the corresponding direction of D is called the index ellipsoïd and its equation is: 13 NW optique physique II 2. Propagation in anisotropic media Index Ellipsoïd – directions of E and B For a given direction of D corresponding to a point M on the ellipsoïd: 1) E is normal to the ellipsoïd at point M Proof: ⎡ X 0 n x2 ⎤ ⎢ 2 ⎥ Y n Vector normal to the index ellipsoïd at point (X0,Y0,Z0): ⎢ 0 y ⎥ ⎢⎣ Z 0 n z2 ⎥⎦ ⎡ Dx n x2 ⎤ ⎡ X 0 n x2 ⎤ 1 ⎢ D ⎢ 2 ⎥ 2 ⎥ Y n € ⎢Dy n y ⎥ = ε0 ε 0 n ⎢ 0 y2 ⎥ 2 ⎢⎣ Dz n z ⎥⎦ ⎢⎣ Z 0 n z ⎥⎦ Vector E corresponding to this direction of D (X0,Y0,Z0): € 2) B, orthogonal to E, is thus tangent to the ellipsoïd at point M 14 NW optique physique II 2. Propagation in anisotropic media Index Ellipsoïd – graphical determination of eigenpolarizations For a given direction of the wave vector k: • D is in the phase plane (orthogonal to k) thus on the intersection of the index ellipsoïd with the plane orthogonal to k which is an ellipse • D is orthogonal to B, which is tangent to the ellipsoïd, thus the only possibilities for D’ and D’’ are the two principal axes of the ellipse Intersection of the ellipsoïd by the phase plane Π E B k D’ B D’’ Π 15 NW optique physique II 2. Propagation in anisotropic media 16 Index Ellipsoïd in the case of a uniaxial medium Uniaxial medium: nx= ny = no Positive uniaxial ne > no nz=ne optic axis z Ellipsoïd invariant under rotation about the z axis: Do ⊥ k & optic axis De ⊥ k & Do or De projection of the optic axis on the phase plane Π Eo // Do Ee normal to the ellipsoïd 2. Propagation in anisotropic media NW optique physique II Characteristic surface 2: Index surface Definition We have shown that for a fixed direction of propagation k, there are two possible values for index of refraction n’ and n’’ The index surface represents the two values of the index in the direction of k (locus of points N satisfying ON=n(u)u). It thus has two shells. Writing ON=(X=nα,Y=nβ,Z=nγ) where X²+Y²+Z²=n², we can write Fresnel’s equation relative to the wave normals as a function of X, Y and Z. We get a complicated equation from which we can imagine the shape of the normal surface by choosing nx<ny<nz and studying its intersection with each of the coordinate planes x, y or z=0. We obtain for example in the xz plane: a circle with radius ny an ellipse of equation x²/nz²+z²/nx²=1 Using circular permutations we can obtain the three intersections. 17 2. Propagation in anisotropic media NW optique physique II 18 Shape of the index surface when nx<ny<nz There are two directions ON and ON’ for k that satisfy n’=n’’: this is why the medium is called BIAXIAL. NW optique physique II 2. Propagation in anisotropic media Shape of the index surface when nx= ny = no nz=ne z z Sphere with radius no no no ne y ne no x ne ellipse circle x Ellipsoïd with axial symmetry around the z axis 19 Uniaxial medium with optic axis z NW optique physique II 2. Propagation in anisotropic media Positive and negative uniaxial crystals Negative uniaxial ne < no Positive uniaxial ne > no calcite no= 1,658 ne=1,486 Quartz no= 1,544 (λ=589nm) ne=1,553 20 NW optique physique II 2. Propagation in anisotropic media Characteristic surface 3: Radial velocity surface 21 or Ray surface For each EM wave defined by (k,D) propagating with index n, there is a similar description where: (k,D) is replaced by (R, E) Index n is replaced by the « apparent » radial velocity defined by: D θ E k,n θ R,vr Σ0 Σ1 2. Propagation in anisotropic media NW optique physique II Radial velocity surface Definition In a very similar way as we defined the indices surface, we define a radial velocity surface by reporting in the direction of the ray (Poynting vector R) the value of the radial velocity vr=v/cosθ (where θ is the angle between k and S). The shape of this surface is determined from Fresnel’s equation relative to the radial velocities which has a similar expression as the one relative to the wave normals: We get a surface with two shells very similar to the normal surface, but with its characteristic length along the directions of the axes x,y,z equal to c/ni or rather 1/ni. 22 2. Propagation in anisotropic media NW optique physique II Radial velocity surface for a uniaxial medium 23 NW optique physique II 2. Propagation in anisotropic media Property of the radial velocity surface The radial velocity surface gives access, for a given direction of the Poynting vector R (light ray), to the corresponding directions of Do , Eo , De , Ee : For the ordinary wave: Eo ⊥ z & R Do // Eo For the extraordinary wave: Ee ⊥ Eo & R, De tangent to the extraordinary shell of the radial velocity surface (see demonstration in the next slide) 24 2. Propagation in anisotropic media NW optique physique II Finding the direction of De from the velocity surface Relationship between De and Ee : Coordinates of the Poynting vector in the (x,y,z) reference frame: Extraordinary shell of the velocity surface: Vector normal to that shell in the direction of R: Finally: De is tangent to the extraordinary shell of the radial velocity surface 25 2. Propagation in anisotropic media NW optique physique II 26 Summary about the characteristic surfaces • Index ellipsoïd: We plot in the direction of D (linear polarisation state that can propagate in the medium) the corresponding value of the index. It is the simplest surface (only one shell) to represent the dielectric properties of the medium • Radial velocity surface: We plot in the direction of the ray R (direction of propagation of energy, direction of the Poynting vector) the two possible values of the radial velocities corresponding to the two eigen polarization states that can propagate with this direction of ray. It is a more complex surface, with two shells, useful to construct the refracted or reflected rays in an anisotropic medium • Index surface: We plot in the direction of the wave vector k (perpendicular to the wave surface) the two possible values of the index of refraction corresponding to the two eigen polarization states that can propagate in that direction of k. It also has two shells, it will be useful later to calculate more easily the path or phase differences when propagating through an anisotropic medium
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