Page:1of9
1676
SDS#:
SAFETYDATASHEET
Revision Date: 01/13/16
Sec*on1-Iden*fica*onofthesubstance/mixtureandofthesupplier
TradeName:
ProductCode:
ChemicalName:
Applica*on/Uses:
Restric*ons:
DistributorInforma*on:
EmergencyPhoneNumber:
PrudentGreen
PrudGreen
9-0-0
FerUlizingCompound
None
PERFORMANCENUTRITION-ADivisionofLidoChem,Inc.20VillageCourt,Hazlet,NJ07730
Phone:(732)8888000•Fax:(732)2642751•email:[email protected]
CHEMTREC-DayorNight-at8004249300
Sec*on2-HazardIden*fica*on
Classifica*onofthesubstanceormixture(GHS-US)
Precau*onaryStatements:
Precau*onaryStatements-Preven*on,Response,Storage,Disposal
Carcinogenicity2
AcuteinhalaUontoxicity4
Acuteoraltoxicity4,Acutedermaltoxicity4
SkinCorrosion/IrritaUon2
Seriouseyedamage/irritaUon2B
STOTSE3(irritaUngtorespiratorysystem)
P201:ObtainspecialinstrucUonsbeforeuse.
P202:DonothandleunUlallsafetyprecauUonshavebeenreadand
understood.
P261:Avoidbreathingfume/mist/vapours/spray.
P264:Washskinthoroughlya^erhandling.
PhysicalHazards
P270:Donoteat,drinkorsmokewhenusingthisproduct.
None
P271:Useonlyoutdoorsorinawell-venUlatedarea.
HazardStatements
H302:Harmfulifswallowed
P280:WearprotecUvegloves/protecUveclothing/eyeprotecUon/face
protecUon.
H312:Harmfulincontactwithskin
P301+P312+P330:IFSWALLOWED:Callapoisoncontrolcenteror
doctor/physicianifyoufeelunwell.Rinsemouth.
H315:CausesskinirritaUon
P302+P352:IFONSKIN:Washwithplentyofsoapandwater.
H320:CauseseyeirritaUon
P332+P313:IfskinirritaUonoccurs:Getmedicaladvice/adenUon.
H332:Harmfulifinhaled
P304+P340+P312:IFINHALED:RemovevicUmtofreshairandkeep
atrestinaposiUoncomfortableforbreathing.Callapoisoncenteror
doctor/physicianifyoufeelunwell.
P305+P351+P338:IFINEYES:RinsecauUouslywithwaterforseveral
minutes.Removecontactlenses,ifpresentandeasytodo.ConUnue
rinsing.
P337+P313:IfeyeirritaUonpersists:Getmedicaladvice/adenUon.
H335:MaycauserespiratoryirritaUon
H336:Maycausedrowsinessordizziness
H351:Suspectedofcausingcancer
P308+P313:IFexposedorconcerned:Getmedicaladvice/adenUon.
GHSLabelelements
P362+P364:Takeoffcontaminatedclothingandwashitbeforereuse.
HazardPictograms
SignalWord
Warning
P403+P233:Storeinawell-venUlatedplace.KeepcontainerUghtly
closed.
P405:Storelockedup.
HNOC-HazardsNotOtherwiseClassified
None
P501:Disposeofcontents/containertoanapprovedwastedisposal
plantinaccordancewithlocal/regional/naUonalregulaUons.
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01/13/16
Page:2of9
SAFETYDATASHEET
Sec$on3-Composi$on/Informa$ononIngredients
ChemicalIden$ty: 9%N
CAS#:
13598-36-2
141-43-5
51503-61-8
1317-80-2
1314-13-2
CommonName/Synonyms:
Phosphorusacidcrystal
Monoethanolamine
Ammoniumphosphite
Titanium(IV)oxide
Zincoxide
%byWt.
20-22%
18-20%
4.5-5.0%
14-14.5%
4-4.5%
CAS#:
CommonName/Synonyms:
%byWt.
Sec$on4-FirstAidMeasures
Descrip$onoffirstaidmeasures
GeneralAdvice:
Removecontaminatedclothingandshoes.Seekmedicaladviceimmediatelyandshowsafetydatasheetorlabeltothedoctor,ifpossible.
IfInhaled:
Remove person from contaminated area to fresh air. If not breathing, give ar>ficial respira>on. Seek medical aEen>on if irrita>on or dizziness
occurs.
InCaseOfSkinContact:
Remove contaminated clothing and wash before re-using. Flush skin with water and then wash with soap and water. Seek medical aEen>on if
irrita>onpersists.
InCaseOfEyeContact:
Flush eyes with clean water for at least 15 minutes. Li< eyelids to facilitate irriga>on. If present, remove contact lenses a<er 5 minutes and con>nue
rinsing.SeekmedicalaEen>onimmediately.
IfSwallowed:
Seek medical aEen>on or call a poison control center immediately. Do not induce vomi>ng unless instructed to do so by a poison control center or
doctor.Donotgiveanythingbymouthtoanunconsciousperson.
Mostimportantsymptomsandeffects,bothacuteanddelayed:
Themostimportantknownsymptomsandeffectsaredescribedinsec>on2.Furthersymptomsarepossible.
Indica$onofanyimmediatemedicalaRen$onandspecialtreatmentneeded:
Noaddi>onalinforma>onavailable.
Sec$on5-Fire-figh$ngMeasures
Ex$nguishingmedia:
Suitableex>nguishingmedia:water,drypowder,carbondioxide,foam.
SpecificHazardsarisingfromthesubstanceormixture:
Oxidesofphosphorus,>taniumoxides
Adviceforfirefighters:
Fire fighters should wear appropriate protec>ve equipment and self-contained breathing apparatus (SCBA) with a full face piece operated in posi>ve
pressuremode.
Furtherinforma$on:
Disposeoffiredebrisandcontaminatedex>nguishingwaterinaccordancewithofficialregula>ons.
ForChemicalEmergenciesCallCHEMTREC-DayorNight-at8004249300.
01/13/16
Page:3of9
SAFETYDATASHEET
Sec$on6-Accidentalreleasemeasures
Personalprecau$ons,protec$veequipmentandemergencyprocedures:
As outlined in secBon 8, wear appropriate respiratory protecBon. Avoid breathing fume, vapours, spray, mist or gas. Use personal protecBve
clothing.EnsureadequatevenBlaBon.Evacuatepersonneltosafeareas.
Environmentalprecau$ons:
Donotallowspilledproducttoenterwatersupplies.
Methodsandmaterialsforcontainmentandcleaningup:
Spills should be contained by diking area with sand or soil. Cover contained spill with an inert absorbent material such as sand, vermiculite or other
appropriate material. Vacuum, scoop or sweep up material and place in a container for disposal. Do not place spilled material back into the original
container.
Sec$on7-HandlingandStorage
Precau$onsforsafehandling:
Do not eat, drink or smoke when using this product. Wash hands and other exposed areas thoroughly a?er handling. Provide adequate venBlaBon.
Protectpackagesagainstphysicaldamage.Resealcontainersimmediatelya?eruse.Immediatelyremoveanddisposeofanyspilledmaterial.
Condi$onsforsafestorage,includinganyincompa$bili$es:
KeepcontainerBghtlyclosedinadryandwellvenBlatedarea.AVOIDFREEZING.
Sec$on8-ExposureControl/PersonalProtec$on
Controlparameters:
ChemicalIden$ty:
CAS#:
Phosphorusacidcrystal
13598-36-2
Monoethanolamine
141-43-5
Ammoniumphosphite
Titanium(IV)oxide
Zincoxide
ACGIHThresholdLimitValues
OSHAPEL
NIOSHREL
TWA
STEL
TWA
STEL
TWA
STEL
NDA
NDA
NDA
NDA
NDA
NDA
2mg/m3
6mg/m3
6mg/m3
15mg/m3
8mg/m3
15mg/m3
51503-61-8
1317-80-2
NDA
NDA
NDA
NDA
NDA
NDA
NDA
NDA
NDA
NDA
NDA
NDA
1314-13-2
2mg/m3
10mg/m3
5-15mg/m3
10mg/m3
5mg/m3
10mg/m3
Appropriateengineeringcontrols:
Provide sufficient venBlaBon to maintain airborne concentraBons below the recommended exposure limits. Handle in accordance with good
industrialhygieneandsafetypracBce.Washhandsbeforebreaksandattheendoftheworkday.
Individualprotec$onmeasures,suchaspersonalprotec$veequipment:
Eyeprotec$on:
TightlyfiPngsafetygogglesorfaceshieldifasplashinghazardexists.UseequipmentforeyeprotecBontestedandapprovedunderappropriate
governmentstandardssuchasNIOSH.
Skinprotec$on:
HandlewithchemicalresistantprotecBvegloves.Usepropergloveremovaltechnique(withouttouchingglove’soutersurface)toavoidskincontact
withthisproduct.Washanddryhands.
ForChemicalEmergenciesCallCHEMTREC-DayorNight-at8004249300.
01/13/16
Page:4of9
SAFETYDATASHEET
Sec-on8-ExposureControl/PersonalProtec-on(cont.)
Bodyprotec-on:
Bodyprotec3onmustbechosendependingonac3vityandpossibleexposure,i.e.apron,chemicalresistantfootwearplussocks,longsleevedshirt,
longpants,chemicalprotec3onsuit.
Respiratoryprotec-on:
Respiratoryprotec3onisnottypicallyrequiredifairborneconcentra3onsaremaintainedbelowtheestablishedexposurelimits.WearaNIOSHcer3fied(orequivalent)organicvapour/par3culaterespirator.Donotexceedthemaximumuseconcentra3onfortherespiratorfacepiece/cartridge
combina3on.Foremergencyornon-rou3ne,highexposuresitua3ons,useaNIOSH-cer3fiedfullfacepiecepressuredemandself-contained
breathingapparatus(SCBA)orafullfacepiecepressuredemandsupplied-airrespirator(SAR)withescapeprovisions.ObserveOSHAregula3onsfor
respiratoruse(29CFR1910.134)
Generalsafetyandhygienemeasures:
Eyewashfountainsandsafetyshowersmustbeeasilyaccessible.Employeesshouldwashtheirhandsandfacebeforeea3ng,drinkingorusing
tobaccoproducts.
Sec-on9-PhysicalandChemicalProper-es
Appearance(physicalstate,color,etc):
GreenLiquid
Odor:
None
Odorthreshold:
None
pH:
7.0+/-0.3
Mel-ngpoint:
Nodataavailable
Freezingpoint:
Nodataavailable
Ini-alboilingpoint:
Nodataavailable
Boilingrange:
Nodataavailable
Flashpoint:
Nodataavailable
Evapora-onrate:
Nodataavailable
Flammability(solid,gas):
Nodataavailable
Upper/lowerflammabilityorexplosivelimits:
Nodataavailable
Vaporpressure:
Nodataavailable
Vapordensity:
Nodataavailable
Rela-vedensity:
Nodataavailable
Solubility:
infiniteinwaterandalcohol
Par--oncoefficient:n-octanol/water:
Nodataavailable
Auto-igni-ontemperature:
Nodataavailable
Decomposi-ontemperature:
Nodataavailable
Viscosity:
Nodataavailable
Specificgravity:
1.47
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01/13/16
Page:5of9
SAFETYDATASHEET
Sec$on10-StabilityandReac$vity
Reac$vity:
Nodataavailable.
Chemicalstability:
Productisstableatambienttemperatureandpressure,undernormalstorageandhandlingcondi@ons.
Possibilityofhazardousreac$ons:
Nodataavailable.
Condi$onstoavoid(i.e.sta$cdischarge,shockorvibra$on):
Nodataavailable.
Incompa$blematerials:
Bases,oxidizingandreducingagents,metals.
Hazardousdecomposi$onproducts:
Phosphorusoxides,nitrogenoxides.
Sec$on11-ToxicologicalInforma$on
Likelyroutesofexposure:
Inhala@on,inges@on,skinandeyecontact.
Symptomsrelatedtophysical,chemicalandtoxicologicalcharacteris$csanddelayedandimmediateeffectsandchroniceffectsfromshortandlongtermexposure:
AcuteToxicity:
Acute oral - Ethanolamine: Es@mated LD50 = 1,515 mg/kg. Phosphorus acid: Es@mated LD50 = 1,560 mg/kg. Acute Oral - Zinc oxide: Es@mated
LD50=7,950mg/kgAcuteinhala$on-Ethanolamine:Es@matedLC50=>1.3mg/l.Acutedermal-Ethanolamine:Es@matedLD50=2,504mg/kg.
Skincorrosion/irrita$on:
[email protected],rash,derma@@sorotherreac@on.
Seriouseyedamage/eyeirrita$on:
Maycauseeyeirrita@on,includingrednessandinflamma@onbasedoncomponentdata.
Respiratoryorskinsensi$za$on:
Nodataavailable.
Carcinogenicity:
ThisproductisorcontainsacomponentthatisnotclassifiableastoitscarcinogenicitybasedonitsIARC,ACGIH,NTPorEPAclassifica@on.
ForChemicalEmergenciesCallCHEMTREC-DayorNight-at8004249300.
01/13/16
Page:6of9
SAFETYDATASHEET
IARC:Group2B:Possiblycarcinogenictohumans(Titanium(IV)oxide).
Sec$on11-ToxicologicalInforma$on(cont.)
Germcellmutagenicity
Nodataavailableonthemixture.
Zincoxide:Hamsterembryo-unscheduledDNAsynthesis,morphologicaltransforma@on,sisterchroma@dexchange.
Reproduc$vetoxicity:
Nodataavailable.
Specifictargetorgantoxicity-singleorrepeatedexposure:
Nodataavailableonthemixture.
Ethanolamine:A:errepeatedexposure,theprominenteffectislocalirrita@on.Thesubstancemaycausedamagetotheupperrespiratorytract
a:errepeatedinhala@on,asshowninanimalstudies.
Aspira$onhazard:
Nodataavailable.
SymptomsaCerinhala$on:
Harmfulifinhaled.Cancauseirrita@onoftheupperrespiratorytractwithpoten@aleffectsonthecentralnervoussystem.
SymptomsaCerskincontact:
Maycauseskinirrita@on.
SymptomsaCereyecontact:
Maycauseeyeirrita@onincludingrednessandinflamma@on.
SymptomsaCeringes$on:
Harmfulifswallowed.Inges@oncouldhavenega@veeffectsonthekidneysandliver.
Sec$on12-EcologicalInforma$on
Ecotoxicity(aqua$candterrestrial,whereavailable):
Toxicitytofish(acuteandchronic):
Nodataavailableforthemixture.Individualcomponentdatareported.
Ethanolamine:
LC50:349mg/l,exposure@me:96h,species:Cyprinuscarpio(Carp),testtype:[email protected].
Chronic:NOEC:1.2mg/l,exposure@me:30d,species:Oryziasla0pes(orange-redkillifish),method:OECDtestguideline210.Literaturedata.
Zincoxide:LC50:1.1mg/lmexposure@me:96h,species:Oncorhynchusmykiss(rainbowtrout)
Toxicitytodaphniaandotheraqua$cinvertebrates(acuteandchronic):
Nodataavailableforthemixture.Individualcomponentdatareported.
Ethanolamine:
EC50:65mg/l,exposure@me:48h,species:Daphniamagna(waterflea),testtype:sta@ctest,method:84/449/EECC.2,Literaturedata.
Chronic:NOEC:0.85mg/l,exposure@me:21d,species:Daphniamagna(waterflea),method:OECDtestguideline211.Literaturedata.
Zincoxide:EC50:0.098mg/lmexposure@me:48h,species:Daphniamagna(Waterflea)
Toxicitytoalgae:
Nodataavailableforthemixture.Individualcomponentdatareported.
Ethanolamine:ErC50:2.5mg/l,exposure@me:72h,species:Pseudokirchneriellasubcapitata(greenalgae,testtype:OECDtestguideline201.
Literaturedata.Phosphorusacid:sta@ctestEC50:153mg/l,exposure@me:72h,species:Pseudokirchneriellasubcapitata(greenalgae,test
type:OECDtestguideline201.
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01/13/16
Page:7of9
SAFETYDATASHEET
Sec$on12-EcologicalInforma$on(cont.)
Persistenceanddegradability:
Nodataavailableforthemixture.
Ethanolamine:readilybiodegradable.MethodOECDtestguideline301E
Bioaccumula$vepoten$al:
Nodataavailable.
Mobilityinthesoil:
Nodataavailable.
Otheradverseeffects:
Anenvironmentalhazardcannotbeexcludedintheeventofunprofessionalhandlingordisposal.Zincoxideisverytoxictoaqua?clife.
Sec$on13-DisposalConsidera$ons
Wastetreatmentmethods-product:
Dispose in accordance with all local, state and federal regula?ons. In unused condi?on, this product is not considered to be a RCRA defined
hazardous waste by character/lis?ngs. It is the responsibility of the waster generator to evaluate whether this wastes are hazardous by
characteris?c/lis?ng.
Wastetreatmentmethods-container:
Containers should be cleaned of residual product before disposal. Empty containers should be disposed of in accordance with all applicable laws
and regula?ons. Chemical addi?ons, processing or otherwise altering this material may make the waste management informa?on presented
incomplete,inaccurateorotherwiseinappropriate.
Sec$on14-TransportInforma$on-USDOT,IATA,IMO,ADR:
ProperShippingName:
D.O.T.HazardClass:
Fer?lizingCompound,NOI,Liquid-PrudentGreen
NotregulatedbyD.O.T.
UN#:
LabelRequirement:
None
RQ:
Placard:
None
CAS:
PackingGroup:
EnvironmentHazards:
SpecialPrecau$ons:
N/A
ERGBookInforma$on:
No
N/Ap
N/A
N/Ap
Mixture
154
MarinePollutant:
N/Ap
IATA:
N/Ap
Sec$on15-RegulatoryInforma$on
U.S.Federal-OSHAStatus:
ThisproductishazardousunderthecriteriaoftheFederalOSHAHazardCommunica?onStandard29CFR1910,1200.
TSCAStatus:
NotListed/Non-reportable
SARATitleIIISec$on302-EXTREMELYHAZARDOUSSUBSTANCES:
ForChemicalEmergenciesCallCHEMTREC-DayorNight-at8004249300.
01/13/16
Page:8of9
SAFETYDATASHEET
ThisproductdoesNOTcontainingredientslistedinAppendixAandBasExtremelyHazardoussubstances.
Sec<on15-RegulatoryInforma<on(cont.)
SARATitleIIISec<ons311/312:
Immediate(acute)healthhazard
SARASec<on313ToxicChemicals:
ThisproductcontainsthefollowingtoxicchemicalsubjecttothereporHngrequirementsofSecHon313oftheEmergencyPlanningandCommunity
RighttoKnowAct:
CAS#
ChemicalName:
ThismaterialdoesNOTcontainanychemicalcomponentswithknownCASnumbersthatexceedthethresholdrepor<nglevels.
SARASuperfundSec<on110:
ThisproductdoesNOTcontainingredientslistedashazardoussubstancesonthePriorityListofCERCLAHazardoussubstances.
CERCLA,40CFR117,302:
ThisproductdoesNOTcontainingredientsspecifiedintheListofExtremelyHazardousSubstances.
CERCLAlistedsubstancesare:
None
OtherFederalRepor<ngRequirements:
CAA:
Thisproductdoesnotcontainanysubstancesregulatedashazardousairpollutants(HAPS)underSecHon112oftheCleanAirAct
CWA:
NochemicalsinproductarelistedaHazardousSubstances,PriorityPollutantsorToxicPollutantsundertheCWA.
RCRA:
Notconsideredahazardouswaste.
StateRepor<ngRequirements:
StateRighttoKnowLaws:
CAS#
141-43-5
13598-36-2
1317-80-2
StateRTK
ChemicalName
CT,MA,MN,NJ, Monoethanolamine
PA,RI
NJ
Phosphorusacidcrystal
NJ,PA
Titanium(IV)oxide
CALIFORNIAPROPOSITION65:
ThisproductdoesNOTcontainachemicalorchemicalssubjecttoCaliforniaProposiHon65.
MichiganCri<calMaterials:
ThisproductdoesNOTcontainingredientslistedontheMichiganCriHcalMaterialsRegister.
GlobalLists/Interna<onalInventories:
CanadaCEPA:
AllintenHonalingredientslistedontheDSL
ForChemicalEmergenciesCallCHEMTREC-DayorNight-at8004249300.
01/13/16
Page:9of9
SAFETYDATASHEET
CanadaWHMIS:
NoInforma0onFound
Sec.on16-OtherInforma.on
NoteSec(on3:Anyconcentra+onshownasarangeistoprotectconfiden+alityorisduetobatch
varia+on.
NoteSec(on10:Shouldfreezingoccur,productwillthinoutifmovedtowarmercondi+onsandcan
beusedasnormal.
1
0
0
N/A
Date of last revision:
1/13/2016
NOTICE: OSHA STANDARD 29 CFR 1910.1200 requires that informa0on be provided to employees regarding the hazards of chemicals by means of a
Hazard Communica0on Program including training, labeling, Safety Data Sheets, and access to wri\en records. We request that you, and it is your legal
duty,makeallinforma0oninthisSafetyDataSheetavailabletoyouremployees.
KeyLegendInforma.on:
N/Ap:
N/R:
ACGI
OSHA:
PEL:
STEL:
IARC:
SARATitleIII:
CAA:
RCRA:
IATA:
NotApplicable
NotRated
ND:
AmericanConferenceofGovr'ntalIndustrialHygienistsNDA:
Occupa0onalSaWeyandHealthAdministra0on
TLV:
PermissableExposureLimit
TWA:
ShortTermExposureLimit
NTP:
Interna0onalAgencyforResearchonCancer
TSCA:
SuperfundAmendmentsandReauthoriza0onActCERCLA:
CleanAirAct
CWA:
ResourceConserva0onRecoveryAct
Interna0onalAirTransportAssocia0onShippingInfo.
IMO:
NotDetermined
NoDataAvailable
ThresholdLimitValue
TimeWeightedAverage
Na0onalToxicologyProgram
ToxicSubstanceControlAct
ComprehensiveResponse,Compensa0onandLiabilityAct
CleanWaterAct
Interna0onalMari0meOrganiza0onShippingInfo.
The informa0on and recommenda0ons contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind expressed or
implied is made with respect to the informa0on contained herein. This Safety Data Sheet was prepared to comply with OSHA Hazard Communica0on standard. (29 CFR
1910.1200 HazCom 2012). This supersedes any previous informa0on. Since the actual use by others is beyond our control, no guarantee, expressed or implied, is made
by LidoChem, Inc. as to the effects of such use or the results to be obtained, nor does LidoChem,Inc. assume any liability arising out of use, by others, of the products
referred to herein. Nor is the informa0on herein to be construed as absolutely complete since addi0onal informa0on may be necessary or desirable when par0cular or
excep0onal condi0ons or circumstances exist because of applicable laws or government regula0ons. All LidoChem Inc. SDS's are reviewed every three years or sooner if
necessary.PleasechecktheReviewDateonPage1formostcurrentversion.PleaserequestanewSDSfromLidoChem,Inc.ifthedateisolderthan3years.
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01/13/16