PRODUCT TECHNICAL DOSSIER K-PURE CALCIUM BIS-GLYCINATE Product Code: P03084 Raw Material Full Name: K-Pure Calcium Bis-Glycinate Limit/Range/Specification: Ca content 18.0%-22.0% CAS Number: 56960-17-9 Molecular Formula for the raw material: Ca(C2H4NO2)2 Average Molecular weight: 188.22 g/mol Particle Size: 40 Mesh Percentage passed through: Min 90% Tapped Density: NLT 0.7g/mL pH (1% Solution): 10 - 12.5 Loss on Drying: Max 6% Country of Origin: USA Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Country of Origin of the Manufacture: USA Base Source/Start Material: L-Glycine 56% – 76.1% ( Derived from Sodium Gluconate) , Calcium oxide 22.7% - 30.7% (Mined Limestone ), Citric Acid 5.4% – 7.4 % (Tapioca ,Fermentation of Corn Derivatives, Sugar Beets), Silicon Dioxide 0.371% - 0.501% (Mined) Origin of Product – Synthetic, Plant, Mineral, Animal, Fish or Fermented: Synthetic Shelf Life from Date of Manufacture: 3 Years Storage Conditions: Store in a cool and dry location. Appearance: Powder Colour: White to Off White Flavour/Taste: Characteristic Texture: Powder Odour: Characteristic Microbiological Test Total Viable Count: Max 3,000cfu/g Yeast & Moulds: Max 300cfu/g Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 E.Coli: Negative in 10g Salmonella: Negative in 25g Metals Lead (Pb): Max 1ppm Cadmium (Cd): Max 1ppm Mercury (Hg): Max 0.1ppm Arsenic (As): Max 1ppm There are no nuts in this recipe and are no nuts on site, however we cannot guarantee that the raw materials entering the site are nut free. Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 INTOLERANCE DATA If No please give details Free from All Animal Products (Beef, Pork, Poultry or other) Free from Bovine Products or Derivatives by using hormones to increase milk yield in cows Free from Bone Meal Free from Peanuts and Peanut Derivatives (including possible cross contamination) Free from other Nut and Nut Derivatives Free from Nut Derived Oil Free from Sesame Seeds and Sesame Seed Derivatives Free from Poppy Seeds and Poppy Seed Derivatives Free from Sunflower Seeds and Sunflower Seeds Derivatives Free from other Seeds and Seed Derivatives Free from Milk and Milk Derivatives (including lactose) Free from Egg and Egg Derivatives Free from Cereals containing Gluten (wheat / rye / oats / barley/ spelt/ kamut or their hybridised strains) and Derivatives Free from Soya and Soya Derivatives Free from Maize and Maize Derivatives Free from Corn and Corn Derivatives Free from Lupin and Lupin Derivatives Free from Yeast and Yeast Derivatives Free from Cotton Seeds (Flour) and Cotton Seed Derivatives Free from Rice and Rice Derivatives Free from Mustard and Mustard Derivatives Free from Celery or Celery Derivatives Free from Celeriac or Celeriac Derivatives Free from Fruit and Fruit Derivatives Free from Vegetable and Vegetable Derivatives Free from Carrot and Carrot Derivatives Free from Legumes / Pulses Free from Fish and Fish Derivatives Free from Crustaceans / Molluscs and their Derivatives Free from Additives Free from Added Salt Free from Added Sugar Free from Antioxidants Free from Artificial Glutamates Free from Aspartame Free from Azo and Coal Tar Dyes Free from Benzoates (E210 / E219) Free from BHA / BHT (E320 / E321) Free from Caffeine Free from Cinnamon Free from Cocoa Free from Colours (Artificial / Nature Identical / Natural / Smoked) Free from Dextrose Free from Dioxins Free from Ethanol Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 YES YES YES YES YES YES YES YES YES YES YES YES YES YES No No Citric Acid Citric Acid No Citric Acid YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES INTOLERANCE DATA If No please give details Free from Ethylene Oxide Free from Flavourings (Artificial / Nature Identical / Natural / Smoked) Free from Garlic Free from Gelatine Free from Glutamates (E620 to E625) Free from Histamine Free from Hickory Free from Honey Free from Lactose Free from Latex Free from MSG (Added and Naturally Occurring E621) Free from Nucleotides (E627, E630, E631, E635) Free from Polyols Free from Preservatives Free from Starch Products (Including Maltodextrin) Free from Sorbic Acid (E200, E203) 2 Free from Sulphur Dioxide and Sulphites at levels above 10mg/kg or 10mg/litre expressed as SO Free from Sulphites (E220, E228) Free from Sweeteners Free from Vannillin Suitable for Diabetics Suitable for Coeliacs Suitable for Ovo-Lacto Vegetarians Suitable for Vegans Kosher Certified Halal Certified Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES NO NO Not Certified Not Certified CONFIRMATION OF BSE/TSE STATUS This is to certify that this product complies with all relevant current UK and EU Legislative requirements in regard to Transmissible Spongiform Encephalopathies (TSE) and Bovine Spongiform Encephalopathy (BSE) for human food, and so is free of TSE/BSE. This is also to certify that, during the course of their manufacture, the above-mentioned product did not come into contact with any materials, which could be derived from TSE/BSE risk materials. CONFIRMATION OF GM STATUS This is to certify that this product is not manufactured from GM raw materials and is therefore not subject to labelling under regulations 1829/2003/EC and 1830/2003/EC. CONFIRMATION OF NON IRRADIATION STATUS This is to certify that this product, whole or in part, has not been subjected to Ionising Radiation as per European Directives 1999/2/EC and 1000/3/EC. CONFIRMATION OF NANDROLONE STATUS This is to certify that this product, whole or in part, has not come into contact with Nandrolone or any of its precursors in any way. CONFIRMATION OF IOC PRODUCT STATUS This is to certify that this product, whole or in part, has not come into contact with any product/s, which is banned by the IOC (International Olympics Committee). CONFIRMATION OF ANIMAL TESTING STATUS This is to certify that all the products sold by Cambridge Commodities have not been tested on animals in any part of its manufacture in accordance with regulation 86/609/EEC. CONFIRMATION OF PESTICIDES STATUS This is to certify that the above-mentioned product complies with the regulation (EC) No.396/2005 of 23rd February 2005 and commission Regulation (EU) No. 559/2011 of 7th June 2011 amending annexes II and III of the above Regulation. Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 PRODUCT PROCESS FLOW DIAGRAM Raw Materials are inspected and weighed Raw materials are mixed to a liquid state and allowed to react. The Product is spray dried The product is sampled tested and packaged Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 MATERIAL SAFETY DATA SHEET Section 1 Description 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY UNDERTAKING Identification of the substance or preparation Product Name: Product Code: Molecular Formula Supplier: Calcium Bis-Glycinate P03084 Ca2(C2H4NO2)2 Cambridge Commodities Limited 78 Lancaster Way, Ely, Cambridgeshire, CB6 3NW. Tel: 01353 667258. Email: [email protected] 2 Composition/information on ingredients Components Calcium Oxide L-Glycine Citric Acid Silicon Dioxide 3 Hazards identification Calcium Oxide Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 % N/A CAS Number 1305-78-8 56-40-6 77-92-9 112945-52-5 EINECS/ EC Number Calcium oxide is not listed on the NTP ,IARC or OSHA lists of carcinogens. Crystalline silica a component of this product is listed by IARC, NTP, but not OSHA, IARC has determined that “Crystalline silica” inhaled in the form of quartz or crystobalite from occupational sources is a carcinogenic to humans (Group1). OSHA requires that have >0.1% of a known carcinogen must be labelled. NTP states that “Silica , Crystalline(respirable)” may reasonably be anticipated as a carcinogen. Personal Protection equipment is recommended when handing this product. 3 Hazards identification Continued L-Glycine Emergency Overview Eyes Skin Inhalation Ingestion Citric Acid Emergency overview Inhalation Eye contact Ingestion Chronic Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 May be harmful by inhalation, contact with the skin and if swallowed. Product dust may be irritating to eyes, skin and respiratory system. It is white crystalline solid and odourless. Contact with eyes may cause irritation, stinging, tearing, redness and swelling. Avoid contact May be harmful by skin contact. Substances may cause slight skin irritation . Avoid contact with skin May be harmful by inhalation. May cause irritation of the mucous membrane. May cause irritation of the respiratory tract. May be harmful if swallowed. Ingestion of large Products may cause Gastrointestinal irritation. White translucent crystals or granular powder having no characteristic odour. This material can cause severe irritation to the eyes , to the skin , and to the respiratory tract. This material may cause allergic reaction in some sensitive individuals. It will react vigorously with strong acid and alkali and strong oxidizers. Inhalation of dust may cause irritation, Possibly severe , to the nose, mouth, throat, mucous membranes, and lungs. Symptoms of exposure may include sneezing , coughing, sore throat, chest discomfort or pain and shortness of breath. Inhalation of high dust concentrations may cause Permanent lung damage. Exposure to powder, crystals and dust can cause severe eye irritation. Symptoms of exposure may include redness, swelling and discomfort . No Published reports indicate this material is absorbed through the skin, May cause severe irritation to the gastrointestinal tract including stomach and intestines characterized by nausea, vomiting, abdominal pain, possible hypocalcaemia and/or diarrhoea. Prolonged skin exposure to this material may lead to dermatitis. Repeated or long term exposure to teeth may cause damage to the tooth enamel. 3 Hazards identification Continued Silicon Dioxide Emergency overview Eye Contact Skin contact Inhalation Ingestion General HMIS Rating NFPA Rating Dust may be irritating to the respiratory tract. Possibly irritating. May cause drying of skin. Temporary discomfort to the upper respiratory tract may occur due to mechanical irritation when exposures are above the occupational exposure limits. No hazards expected under normal use Medical conditions which may be aggravated by exposure to this product include Conjunctivitis of the eye, Dermatitis of the skin asthma and respiratory disease Health-1, Flammability-0, Reactivity-0 Health-1, Flammability -0, Reactivity - 0 Section 4 Emergency and First Aid Procedures Potential General adviceShow this safety sheet to the doctor in attendance. Eye Contact Skin Contact Inhalation Ingestion Not Physician Protection of first aiders Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Rinse thoroughly with plenty of water, also under the eyelids. Consult a physician. Wash of immediately with soap and water removing all contaminated clothes and shoes. Wash contaminated clothing before re-use. Consult a physician Move to the fresh air. If not breathing give artificial respiration . If breathing is difficult give oxygen. Consult a physician Rinse mouth. Never give anything by mouth to an unconscious Person. Consult a physician. Treat symptomatically Use personal protective equipment Avoid contact with skin eyes and clothing. Section 5 Fire and Hazard Data Calcium Oxide Special Fire fighting Procedures Unusual Hazards L-Glycine Flammable properties Suitable extinguishing media Hazardous and combustion products Specific Hazards Rising from the Chemical Protective equipment and Precautions For fire fighters NFPA Rating Caution! Water application may produce exothermic reaction and release a sufficient beat to ignite combustible material Wet or unused products stored for lengthy periods will absorb moisture and potentially rupture bags causing a spillage. Dust may form explosive mixture in the air Water spray, Carbon dioxide, dry Powder and foam. Thermal decomposition or combustion products may produce Hazardous gases and/or materials. Keep product and empty containers away from heat and sources of ignition. As in any fire wear a self-contained Breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) And full protective equipment. Health-1, Flammability – 0, Instability-0 Section 5 Fire and Hazard Data Continued Citric Acid Flashpoint and method: This material does not flash. Auto ignition temperature Powder: 1,010°C General hazard This material is a granular or crystalline, organic solid. The uniform fire code health hazard classification for this material is irritant- Avoid airborne dispersion of dust and powder enclosed area, to reduce the potential for a dust explosion, in the presence of an ignition source. This material may produce hazardous dusts or hazardous decomposition Products. Extinguishing Media Water fog, CO2, Foam or dry chemicals. Use the extinguishing media that is appropriate to the surrounding fire. Do not use water as this could cause dispersal of dust/ Powder. Fire Fighting equipment Fire Fighter should wear full protective equipment, including self-contained breathing apparatus. Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Silicon Dioxide Extinguishing media Fire Fighting Procedures Use water spray or fog, Foam, Dry chemical or CO2 Fire fighters must wear positive pressure self-contained breathing apparatus and full protective clothing. Section 6 Accidental release measures Calcium oxide Steps to be taken in case material Is released or spilled Normal clean up procedures. Care should be taken to avoid Causing dust to become airborne. Vacuum cleaning systems recommended., L-Glycine Methods for Cleaning up Personal Precautions Environmental precautions Citric Acid Water spill Land Spill Silicon Dioxide Steps to be taken in case the Material is released or spilled: Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Evacuate personnel to safe areas. Sweep and Shovel into suitable containers for disposal. Avoid dust formation. Clean contaminated surface thoroughly. Evacuate personnel to a safe area. Ensure adequate ventilation. Use Personal Protective equipment. Avoid contact with the skin and eyes and clothing. In insufficient ventilation wear suitable Respiratory equipment. Local authorities should be advised is spillages cannot be contained. Wear recommended Protective equipment and clothing if contact with hazardous material can occur. Stop or divert water flow. Dike Contaminated water and remove for disposal and/or treatment. As appropriate remove all downstream users of possible contamination. Wearing recommended protective equipment and clothing, Pick up the spilled material and place in approved containers for recovery or disposal. Neutralize the acidity, of the remaining solid, using dilute solution of soda ash, lime, other agents appropriate for neutralizing acidic solids. Flush the spill area with water, Collect the reinstates for disposal or sewers appropriate Obey relevant local, state, provincial and federal laws and regulations. Do not contaminate any lakes, streams, ponds, groundwater, or soil. Use personal protective equipment Section 7 Storage Calcium Oxide Handling Storage: L-Glycine Handling Product should never be discarded with wet combustible material or comingled in containers exposed to rainfall. Store away from water and acids Use only in an area equipped with safety shower. Ensure that eyewash Stations and safety showers are close to the workstation location. Ensure Adequate ventilation. DO not breathe in vapours/dusts. Citric Acid Storage Pressure and temperature Store in a cool, dry area away from incompatible material and product. Protect eyes, skin, and clothing from contact with product. Wear recommended personal protective equipment. Avoid breathing in dust. Use good housekeeping practices to prevent accumulation of dust. Keep in Container tightly closed when not in use. Wash thoroughly after handling. Silicon dioxide Handling Storage Wash thoroughly after handling. Use adequate ventilation. Follow MSDS/ label precautions even after the container is emptied as it may retain product Residues. Take precautionary measures against static discharges. Store in a cool dry Place. Keep container tightly closed when not in use. Section 8 Control Methods/Personal Protection Calcium Oxide Specific Chemical Identity Common names. Calcium Oxide Lime; Quick Lime Crystalline silica (Quarts) Respiratory Protection Ventilation: Local Exhaust Mechanical Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 OSHAPEL 5mg/m3 0.1mg/m3 ACGIH TLV 2mg/m3 0.05mg/m3 Other Limits Recommended % Respirable 0.1 – 0.3% Dust filter mask are recommended personal comfort and/or protection. To maintain TLV’s PEL’s Special-None To maintain TLV’s PEL’s Other-None Protective Equipment Cloth or leather gloves. Reduce wrist burns from sweat by using protective area. Eye: always were side shielded glasses and or goggles around product to reduce Eye injury. Flush eyes immediately and seek medical attention. Contact Lenses may impede first aid. Section 8 Control Methods/Personal Protection Continued. L-Glycine. Exposure guidelines Engineering controls Eye/face protection Skin Protection Respiratory Protection This product does not contain any hazardous materials with occupational exposure limits established by region specific regulatory bodies. Ensure adequate ventilation, especially in confined areas. Tightly fitting safety goggles. Wear protective gloves/clothing. in the case of insufficient ventilation wear suitable respiratory equipment. Citric Acid Control measures Respiratory Eyes Gloves Clothing Equipment Footwear Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Use local or general, mechanical exhaust ventilation system capable of maintaining dust levels in the work area, below the OSHA-PEL for particulates not otherwise regulated. If use causes dust levels to exceed the OSHA-PEL wear a NIOSH approved respirator equipped with a good dust/Particulate cartridge or supplied air. Wear chemical goggles, unless a full face piece respirator is worn. Wear Plastic or rubber gloves. Wear a plastic or rubber apron when handling this material. An eye wash station and safety shower should be available in the work area. If contact is likely, wear rubber boots. Silicon Dioxide Exposure Limits Silicon dioxide amorphous Crystalline free Engineering controls Respiratory protection Eye Protection Skin Protection Other protective equipment Value Limit Reference 6mg/m3 10mg/m3 N.E TWA TWA STEL OSHA ACGIH OSHA/ACGIH Use adequate ventilation A respiratory protection Programme that meets OSHA 1910.134 and ANSI Z88.2 or applicable federal/ provincial requirements must be followed whenever workplace conditions warrant respirator use. NIOSHS “Respirator Decision Logic” may be useful determining the suitability of various types of respirator. Wear safety glasses with side shields Use impermeable gloves. A safety shower and eye wash fountain should be readily available. To identify additional personal protective equipment requirements, it is recommended that a hazard assessment be conducted before using this product. Section 9 Physical and Chemical Properties Physical state Colour Odour Powder White to Off white Typical Section 10 Stability and Reactivity Chemical Stability Hazardous Decomposition Products Conditions to avoid Incompatibility Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Stable under normal conditions. Bases, strong acids, neutralizing pH, Strong heated resins, polymers, carbon monoxide, carbon dioxide, Nitrogen oxides and Ammonia. Moisture, heat, flames, sparks operations that create dust Oxidizing agents, acids, chlorine triffluoride, fluorine, nitrogen dioxide, phosphorus, strong bases. Section 11 Toxicological Information Calcium oxide Product is listed on toxic substance control act, Canada DSL and other international inventories. L-Glycine Acute Toxicity LD50 oral= 7930mg/kg oral LD50 rat. Carcinogenicity: There are no known carcinogenic chemicals in this product. Eye contact Rabbit:750 µ g/24hour Severe Skin contact Rabbit: 500mg/24 hour Moderate Oral Rat LD50: 3mg/kg Intravenous mouse LD50: 42mg/kg Target organs: eyes, skin, mucous membranes and lungs. Medical conditions aggravated by over exposure: Skin or respiratory disorders. Product toxicological information: Oral LD50 (rat) : >1000mg/kg Dermal LD50 (rabbit) :>5000 mg/kg Citric Acid Silicon Dioxide Section 12 Ecological Information Calcium Oxide Product contains alkaline material potentially toxic to acquatic life if concentration is elevated or extended periods of time. Minimize contact with storm water run off. L-Glycine Contains no substances known to be hazardous to the environment or not degradable in in waste water treatment plants. Citric Acid Environmental Fate: The environmental fate of this material is expected to be: Land: biodegradation with some leaching into the ground water. Water: Biodegradation. Air: Not expected to volatize due to low vapour pressure, this material is not expected to bioaccumulation. Environmental considerations: Aquatic Toxicity Goldfish LD0:635mg/liter, long time exposure in hard water. Goldfish LD100: 894 ma/liter. Long-time exposure in hard water Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Section 13 Disposal Considerations Waste from residues Waste must be disposed of in accordance with federal, state, and local environmental control regulations. Section 14 Transport Information Calcium Oxide L-Glycine Citric Acid Silicon Dioxide Product is not regulated by the U.S department of transportation Not Regulated DOT Proper Shipping Name: Not Restricted Primary Label: Non Required Subsidiary Label: Non Required DOT Reportable Quantity (RQ): Not Listed Marine Pollutant: No TDG Schedule XII: Not Listed Regulated Limit: Not Listed US DOT Transport Information: Not Regulated Section 15 Regulatory Information Calcium Oxide Not available. L-Glycine USA (TSCA): Complies Canada (DSL): Complies EU (ELINCS): Does not comply Japan (ENCS): Complies China: Complies Korea (KECL): Complies Philippines (PICCS): Complies Australia (AICS): Complies USA Federal Regulations SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1987 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization: Acute Health:= No, Chronic Health= No, Fire Hazard= No, Reactive Hazard= No, Sudden Release of Pressure Hazard= No Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see40 CFR 61) This product does not contain any HAPs. Chemical Name: Glycine CAS Number:56-40-6 VOCs: Present State Regulations California Proposition 65: This product does not contain any Proposition 65 chemicals. Sate Right-to-Know Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all information required by the CPR. Citric Acid WHMIS Hazard Class: Not Determined. OSHA Target Organs: Eyes, skin, mucous, membranes and lungs Carcinogenic Potential: No Listed on NTP Report: No Listed by IARC: No ACGIH Appendix A: Not Listed SARA Title III Hazard Categories (product) Fire=N, Sudden Release of Pressure= N, Reactivity=N, Acute Health=Y, Chronic Health=N Planning Threshold= 10,000 lbs U.S TSCA Status: Listed (40 CFR 710) Yes State Regulations: No Silicon Dioxide Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1 Canadian Regulations: Controlled Product=Yes WHMIS Hazard Symbol= Corrosive Material WMIS Class & Division= E IDL Substance= Yes DLS or NDSLK List=DSL Not Regulated Section 16 Other Information This advice is given by Cambridge Commodities Ltd who accept no legal liability for it. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties. Individuals working with chemicals should consider all chemicals to be potentially hazardous even if their individual hazards may be uncharacterised or unknown. We confirm that the information above is sourced from the original manufacturers/suppliers Specification To be used as per local legislation Version No: 0 Compiled and Authorised By: S. Frankish Issue Date: 14.02.12. Version No: 1
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