KTN Knowledge Transfer Network MAGAZINE PLASTIC ELECTRONICS INTRODUCTION DEFINITIONS PLASTIC, PRINTED, LARGE AREA, TOLAE... 2 / PLASTIC ELECTRONICS / 2014 P lastic electronics goes by a bewildering variety of names, not all of which adequately describe an emerging field - one of the fastest growing technologies in the world which many experts say will revolutionise the electronics industry. The names most commonly used are plastic, flexible, organic and printable electronics or, most recently, TOLAE (Thin-film, Organic and Large Area Electronics). Essentially, it’s a multi-disciplinary technology which enables circuits to be printed or deposited onto a range of surfaces (both rigid and flexible) and so opens the door to a new generation of innovative products that can be produced more cheaply and in a more environmentally-friendly way than previously viable. The potential for manufacturing is huge. However, as Chris Rider of the Engineering and Physical Sciences Research Council (EPSRC) funded Centre for Innovative Manufacturing in Large Area Electronics (CIMLAE) points out, this is not a new technology: “There’s nothing that we do that can’t be done by another route. It’s about the materials that enable these manufacturing processes. Plastic electronics is a catch-all term for a radical new way of making electronics.” What it does is allow electronics to be used in places it hasn’t been used before, to create new products, as well as improve existing electronics by either replacing some components or films with cheaper, more robust, higher performance alternatives, or completely replacing existing devices, such as organic light emitting diode (OLED) displays supplanting LCD displays in mobile phones. Many aspects of printed electronics promise to eventually be cheaper but can often start off at a high cost base until manufacturing volume becomes significant. The materials and components used in plastic electronics are not always plastic but they are often carbon-based and therefore organic, rather than traditionally silicon-based. Manufacturing costs are reduced by printing these components directly onto a surface and using semi-conductive inks, which brings savings not possible with the use of traditional methods. The products created by these new materials and methods are often flexible (such as bendy screens and clothes with digital displays), thinner and lighter. They can be mass-produced roll to roll (R2R) and are safe for disposal. The technology is also flexible in the sense that it can be integrated into almost anything from intelligent packaging, to protect goods, prevent counterfeiting or detect when products are past their shelf life, to low-cost solar cells in the fabric of buildings and vehicles. It’s the gateway to edible, foldable, rollable, conformal, wearable, biodegradable and other electronics and of vital interest to industries as diverse as consumer goods, healthcare, mobility, electronics, the media and architecture. The market UK-based research company IDTechEx has been reporting on printed electronics since 2002. “The topic is broader than many people realise,” they write. “There is strong interest in printed electronics enabling part of the Internet of Things vision; researchers are working on bringing together 3D printing with electronics; bioelectronics...”. Their research underlines that this is a very exciting market that’s growing by the minute: • The most successful (multi-billion dollar) industries stemming from plastic electronics are currently OLED displays, eReaders and conductive ink, with the latter used for a wide range of applications. • The total market for printed, flexible and organic electronics will grow from $16.04bn in 2013 to $76.79bn in 2023. • Much of this growth will be in OLEDs (organic but not printed) and conductive ink. However, stretchable electronics, logic and memory and thin film sensors are also believed to hold huge growth potential as R&D progresses. • Over $10bn has been invested into plastic electronics in the last 20 years and this is predicted to increase to $25bn by 2020.w • The vast majority (approx. 94%) of current plastic electronics products continue to be fabricated on glass or other rigid substrates, with new materials used mainly for cost and performance improvements. • There is significant opportunity for producers of non-commodity high value chemicals, manufacturing equipment, electronic and electrical components. Companies offering commodities such as substrates, barriers, or electronics-enabled products will also be in demand. • Globally, over 3,000 organisations are currently involved in pursuing opportunities in plastic electronics, including printing, electronics, materials and packaging companies. • In the UK, 134 companies and 33 universities are involved in plastic electronics, providing employment for over 2,500 individuals and revenue of £234m (Plastic Electronics Leadership Group’s sector study). Contact EMAIL: [email protected] PHONE: 01403 251354 ADDRESS: Bailey House, 4-10 Barttelot Road, Horsham, West Sussex, RH12 1DQ, UK 2014 / INTRODUCTION / 3 A VERY BRITISH TECHNOLOGY British scientists were at the heart of the invention of plastic electronics; at the Cavendish Laboratory in Cambridge, Jeremy Burroughes, Donal Bradley and Richard Friend pioneered the technology in the 1990s and span out two leading companies in the field: CDT (Cambridge Display Technologies) and Plastic Logic. Initial breakthroughs and investments were in organic materials development. This has been followed by a focus on developing the necessary printing equipment, and the involvement of new companies and stakeholders. BENEFITS R&D in the new technology has benefited from British expertise in disciplines such as thin film technology, organic chemistry, printing and circuit design. With milestones in materials and equipment having been reached, the current phase sees companies now able to manufacture components beginning to put together complete solutions and create new markets. Plastic electronics produces products which often have one or more of the following benefits: • • • • • • • • Lower cost Use less energy and materials Have improved performance Flexibility Transparency Stretchability Reliability And are better for the environment. 4 / PLASTIC ELECTRONICS / 2014 APPLICATIONS Plastic electronics could lead to clothing which is wired to cool or heat, reading tablets that fold like a newspaper and wallpaper integrated with electronics to provide light; imagine an electronic display as translucent as glass, a curtain that illuminates a room or a smartphone screen that doubles in size, stretching like rubber. Perhaps the most successful use of the technology to date has been the Duracell battery reader, which uses its packaging to estimate remaining charge. The attention grabbing aspect of the technology has meant a great deal of activity in the FMCG (fast moving consumer goods) industry, where attracting consumers’ attention is a priority. But however wide the application base is, there’s presently no one “killer” application for plastic electronics. This has led critics to speculate that the technology is a solution looking for a problem. In the medical field, electronic strip readers for diabetes sufferers have sold billions in the past decade. Countless health and beauty applications exist, yet inertia combined with red tape has held up much of the promise of plastic electronics in medical testing. 2014 / INTRODUCTION / 5 E-READERS E-READERS WHAT’S THE STORY? Electronic paper or, e-paper, has its main application in e-book readers, or e-readers, a market that has flourished recently due to the success of devices such as the Kindle. IDTechEx valued the market at $1.03 bn in 2012, but possibly the last legacy of e-readers is how instrumental they’ve been in sparking an interest in the technology behind them. E-paper displays mimic real paper, which can be described as a reflective surface, non-emissive and viewable from any angle. There’s no need for a backlight to illuminate the pixels as they reflect light, just like paper does, and can hold text and images indefinitely without drawing power. Many versions can also be flexible, thinner and more robust than other display technologies. E Ink E-readers all use the same E Ink Pearl display. E Ink technology was released more than two years ago and E Ink currently holds more than 95% of the e-reader market (excluding LCD tablets). The reasons for this are manifold: it provides decent contrast for reading, has an almost 180 degree viewing angle, is bistable (meaning that the display can hold an image without consuming power) and compatible with roll-to-roll manufacturing using printing technolo6 / PLASTIC ELECTRONICS / 2014 gies. This has allowed the company to rapidly scale up, producing products at high volume and high yield, and thus a highly competitive price. However, there are also negatives: the screen for one. It’s not actually white but a light grey. This is because the “white” state is only about 40% reflective (a white page in a newspaper would be around 60% reflective). The other major problem is the lack of colour. E Ink’s colours are obtained by adding RGB (an additive colour model in which red, green, and blue light are added together) filters on top of a monochrome display, this reduces the reflectance even further. And competitors are starting to appear. Liquavista (recently bought by Amazon) uses a technique called electrowetting which makes it possible to incorporate a larger choice of colour pigments into the fluids, resulting in a perception of rich colour. However a major disadvantage with their displays is that they’re not bistable, which means higher power consumption. Another company, Mirasol (owned by Qualcomm), uses a completely different approach. Their display has an array of microelectromechanical systems (MEMS) which make minute, rapid movements to tiny mirrors. This means that they are able to display video. However, the disadvantages are that the displays have a narrow viewing angle, because of the way each optical cavity reflects light, and are expensive compared to E Ink ones. Qualcomm has now stopped production and is looking to license the technology to other manufacturers. The future For many, e-readers were only a transition technology which peaked in 2011. Once e-readers had been accepted as a substitute for books, the argument is that it’s only a small step to start reading on colour, multi-media LCD tablets. But e-readers are still hugely popular, not least because of their long battery life, readability in sunlight and low price. The expert view is that e-readers will co-exist alongside tablets in the medium term, mainly because they are cheaper and have better battery life. But the appearance of new, hybrid devices, which can also be used as mobiles, indicates that dedicated e-readers are unlikely to survive. COMPANIES TO WATCH HP and Fuji Xerox are working on colour e-paper displays that outperform E Ink Gamma Dynamics: specialists in electrofluidic display technology of e-Paper applications. Opalux: makes the colour of previously static photonic crystals tunable 2014 / E-READERS / 7 Towards a flexible future It’s been around 15 years since CDT embarked on its quest to develop flexible displays. Progress since then has been slower than many expected. But the feeling that this is an industry on a tipping point is returning. A recent report from IHS claims demand for flexible OLEDs is expected to grow by more than 300% in 2014, with sales reaching nearly $100 m, $1.5 bn by 2016 and in excess of $10 bn by 2019. Much of this renewed enthusiasm is down to two companies: LG Display and Samsung Electronics. In October 2013, LG announced mass-production of the world’s first flexible OLED panel for smartphones, which was followed swiftly by Samsung’s launch of the Galaxy Round, a mobile handset with a curved display screen. Chris Rider of EPSRC’s CIMLAE believes the new OLED products could be a game changer: “It proves it’s all for real and shows that organic materials will make it,” he says. “It’s no longer an issue of will it make it? It has. This is the flagship, if you like, of organic electronics.” Although flexible, it’s not clear whether the Samsung display uses glass. But LG have been more forthcoming about their product: it uses unbreakable plastic substrates instead of glass, is vertically concave and is currently the world’s slimmest, lightest and largest smartphone OLED mobile display panel. LG has also expressed its desire to take an early lead in this direction, as it expects the flexible display market to grow quickly and expand further into diverse applications including automotive displays, tablets and wearable devices, as well as rollable and foldable displays in various sizes. 8 / PLASTIC ELECTRONICS / 2014 PLASTIC LOGIC: POSITIVELY FLEXIBLE Plastic Logic’s modest HQ in Cambridge Science Park belies the powerhouse of activity inside. There’s a large office space with 15 or so computers and a series of research labs populated with sophisticated mixers, an ink jet printer, ovens to bake and cool the plastic displays and all manner of machines fundamental for understanding the critical performance of transistors. The labs are housed in corridors on either side of the office space, together with the company’s clean room where prototypes of the display technology are produced. Cambridge, as is fitting, focuses on the research side of the business: the diagnostics, measuring the distortion of the various new materials used and changing their dimensions, for example. The company’s manufacturing facility however, is in Dresden, Germany. It’s able to mass produce their ultra lightweight 10.7” displays, with yields comparable to those in the LCD industry. As well as monochrome, the company can now produce colour displays and provide video animation. Displays boast a lifetime of over five years and more than 10 million page updates. As the Plastic Logic’s Research Manager, Dr. Mike Banach has been there almost from the beginning. 2014 / E-READERS / 9 Having completed his first degree in the States, he came to Cambridge University in the late 90’s, and it was there that he first met Plastic Logic’s founders. “It’s just been a fantastic ride,” he says of the past ten years,“to go from university, where we were making individual devices, to making demonstrators compelling enough to inspire investment and build the manufacturing side. Now, with the technology right, you’re more on the sales side, figuring out what the key applications are.” Pivotal year It was largely the technology which let the company down in the pivotal year of 2010. Perhaps it would have been too much of a Cinderella style tale if in that year, the Cambridge University spin-out had pulled the rug out from under Amazon and Apple, and become the go-to purveyor of the e-reader. Instead, the company ended up abandoning their Que proReader, having spent years, not to mention millions, on its development, without having shipped a single unit. “We recognise the market has changed dramatically, and with the product delays we have experienced, it no longer makes sense for us to move forward with our first generation electronic reading product,” said Richard Archuleta, who was then chief executive of Plastic Logic. “This was a hard decision, but is the best one for our company, our investors and our customers.” 10 / PLASTIC ELECTRONICS / 2014 Having missed one boat, the company is now embarking on another but will they get it right this time? Hundreds of millions Plastic Logic was founded over a decade ago by two Cambridge scientists, Prof. Sir Richard Friend and Prof. Henning Sirringhaus. They raised hundreds of millions of pounds to develop their new technology, based on semiconducting polymers deposited onto a plastic surface, with the promise that plastic electronics would ultimately be cheaper than silicon-based circuits. “I think they were too ambitious with what they were trying to do,” says Raghu Das, CEO of IDTechEx, providers of business intelligence on printed electronics. “As a result, it didn’t work out.” It’s not just Plastic Logic who were caught out though, according to EPSRC CIMLAE Director Chris Rider. At the time, expectations of what was possible and how long it would take to achieve, were running high. “When it all started out, it looked like a revolution was about to happen,” says Rider. “It was very exciting, with the possibility of doing things which couldn’t be done in other ways but what we’ve found out in the last ten years is that it wasn’t quite that simple. The problem was the materials only lasted for about a minute and it’s taken a long time to get them to the point when they’ve lasted longer. Meanwhile, the incumbent technology has come along.” Powerhouse In May 2012, Plastic Logic’s new CEO Indro Mukerjee announced that the company would follow a novel strategy: leveraging its R&D and manufacturing resources to accelerate applications, developing partnerships and entering multiple new markets selling its unique flexible plastic display technology. And unique it is, because, in all the furore surrounding the Kindle and the iPad, it’s easy to forget that Plastic Logic are the first business to fully industrialise the mass production of plastic electronics, having, in 2008, opened the world’s first organic electronics manufacturing facility. Not wanting to make the same mistake of focusing on one product again, Plastic Logic are now pursuing not one but three different strategy streams in order to exploit their technology across the widest range of applications and markets. “We’re a display company that’s trying to come back to some of the fundamental things that we were doing when we were younger, with a more stable foundation,” explains Banach. “Our long term agenda is to establish a foothold in the EPD (electrophoretic display) market, but we also want to start a flexible display market. There aren’t really any flexible displays being sold yet. In Cambridge, our research focus is to integrate our flexible electronics with OLEDs. Adding OLED capability opens up a whole new set of opportunities for us and will mean much greater demand.” Then there are all the possibilities which currently lie outside the display space, smart packaging and shelf edge labels for instance. In the future, the company sees applications for their technology not only in their traditional consumer electronics market, but also in diverse fields such as signage, automotive and aerospace. Banach estimates that demonstrators featuring the new OLED based flexible displays should be ready by the end of 2014. However, manufacturing capability is partner dependent, so it could be another year before the first products are rolled out. Seeding the market Having being pipped to the post with their Que proReader, it would be understandable if Plastic Logic were impatient to get their product to market, but that’s not what the company believes will ultimately win out; it’s more about making connections, collaboration and painstaking research. “Seeding the market is what we want to do, as opposed to conquering it,” says Banach. “Also, the entire industry is based on glass at the moment. We’re making it possible to replace heavy and fragile glass backplanes with a plastic alternative. But it’ll be 10-15 years before all displays are on plastic. That’s the technical challenge. Success in the near term will require plastic electronics firms to partner to create integrated solutions. “We work with companies that can do things like put the batteries and electronics in, and we’re in a lot of conversations right now.” With flexible displays an area that the broader technology industry is increasingly interested in, Plastic Logic is in discussion with several third-parties, including device manufacturers, about licensing its technology. The company’s secondary display for smartphones (a collaboration with Pocketbook) is one example. Because it’s built on plastic, not glass, their device will be shatterproof and will function as a protective cover for the LCD or OLED display on the phone. So, for the first time ever, a display will be protecting another display - a good example of how flexible electronics can be integrated into everyday objects to enable new functions. This device, and so-called secondary displays in general, are attracting a lot of interest, according to Banach. The key attractions are that the displays are flexible and solar powered. The idea is that people continue to use their primary, colour, mobile display to watch videos and for the Internet, but can easily access a secondary display for saving information, such as plane tickets, or perhaps as a watch. Because it doesn’t require battery power, it can always be on and can be integrated into the plastic casing on the phone. With wearables and small displays becoming more popular, sparked off by Google Glass and Samsung’s recent launch of its smart watch, the Galaxy Gear, it’s a logical step for the company to take. Another possible application is a smart bracelet displaying your hospital details and which can be updated externally with test results, says Banach. What’s also emerging on the back of the 3D printing revolution, according to Banach, is a swing towards lower volume, more bespoke products. And the company’s Dresden-based manufacturing facility is perfectly suited to cater for this. Obviously, high volume manufacturing is the way to drive down 2014 / E-READERS / 11 cost but, says Banach, much of the process is digital, which means that you can iterate. The company is exploring the potential of catering for personalised production through further digitisation of the manufacturing process in partnership with the UK’s National Printable Electronics Centre at the Centre for Process Innovation. However, currently, it’s still very much a volume versus price negotiation. Second time around So there’s a lot going on at Plastic Logic HQ and a sense of little time to be wasted. But just how far off is success? Is this an industry at the turning point, or is there still a way to go? And what’s the prognosis for the future of a company which some believe is already on borrowed time? “While the market’s moved, there’s still nobody who is doing what we are,” says Banach. “There’s no doubt that our competitors have flexible electronics programmes, but they’re doing it in different ways. It’s just a matter of which technology wins and how long it takes. As with all technology, it takes longer to develop than you’d expect. Samsung and LG have certainly been at each other throats to get their products out to market, but that certainly doesn’t mean they have it all sussed out. And it’s also fuelled the interest in flexible displays so, in that sense, it’s good to have competition.” The world’s leading electronic manufacturer is certainly a formidable competitor to have, but Plastic Logic’s reputation is also something to be reckoned with, according to Chris Rider: “Plastic Logic are absolutely world class,” he says, “they just haven’t got a big market at the moment, they’re trying to find it.” 12 / PLASTIC ELECTRONICS / 2014 And there’s more at stake here than Plastic Logic alone. Rider believes the industry as a whole was also somewhat to blame for raising hopes regarding what was possible, and that may also have contributed to Plastic Logic’s initial failure. “We completely sold this the wrong way, we over hyped it, and I think it’s very important that we now present this in a way that is realistic,” he says. “Now people are excited but have the right expectations.” And that’s how it should be because, although it’s a hugely exciting field, it’s also a fledgling industry and it needs successes. It can’t afford to take any more risks with investor confidence. With the technology almost there, many, including Mike Banach, believe the future is flexible: “If you look at the benefits of flexible displays: robust, thin, lighter weight... In the future I think all displays will be flexible. Why keep it on glass if you can do it on plastic? But there are certain performance attributes needed and until companies can do it without our technology, we still have a very valuable role to play.” PLASTIC LOGIC COLLABORATIONS An integrated, plastic digital timetable: dresden elektronik with Plastic Logic Large-area (40”) flexible digital signage: TOPPAN Printing Co. Ltd. and Plastic Logic “Papertab” - a flexible paper computer: Queen’s University, Intel Labs and Plastic Logic Developing graphene as a transparent, highly conductive layer for plastic backplanes and transistors: Cambridge University’s Graphene Centre and Plastic Logic, June 2013 A secondary display for smartphones: Pocketbook and Plastic Logic, September 2013 A plastic image sensor: ISORG and Plastic Logic, November 2013 THE PLASTIC ELECTRONICS PLATFORM P lastic electronic devices can vary significantly in design and complexity. In the simplest design case, a few circuit elements are attached to a substrate. Sensors, resistors, capacitors, inductors and switch elements are printed onto the substrate material along with conductive traces to create the circuit layout. Active elements, such as LEDs, transistors and integrated circuits are directly attached using conductive adhesives. Alternatively, where limited low-power active circuitry is required, a fully plastic electronic design is possible, with the active circuit elements fabricated as thin film (diodes or transistors) by depositing additional layers of organic solution-processed materials directly onto the conductive traces printed on the substrate. In the more complex cases, such as large area active matrix backplanes fabricated on plastic, the final device may contain millions of micron-sized switching transistors that are themselves part of an additional device such as a sensor array or flat panel display. 2014 / INTERACTIVE APPLICATIONS / 13 INTERACTIIVE APPLICATIONS NOVALIA: Everything is intera E ven after nine years, there’s still very much an air of excitement and determined enthusiasm surrounding a small Cambridge based company called Novalia. At demos, their products invariably elicit gasps of amazement and delight. They’re testaments to what’s possible with a little technology, a large dose of creativity and a heap of integration. Now there’s also a belief that the world may have finally caught up with their way of thinking, that it’s possible to create a lot with very little. It’s a philosophy propagated by the company’s founder, Dr. Kate Stone: “My Gran told me: “You cut your coat from the cloth at hand,” which sort of makes sense,” she muses. “It’s not about looking at a polymer transistor and thinking what is the ideal way that I could make this? If I had an infinite amount of money, what machines would I build and what materials would I develop? If the material your coat is made out of is from the environment you’re in, it’s more likely to fit in with it. So using the processes that are already used means its much more likely that there’s a fit with the industry.” 14 / PLASTIC ELECTRONICS / 2014 Stone is talking about the printing industry. She cut her teeth (along with her coat) in plastic electronics, while working on circuit design at Plastic Logic, and it was there that she became inspired by printing. She set out to visit manufacturers and learn about print processes and ways of depositing material, converting, laminating at high speed, how to dye cut and all manner of other high volume manufacturing processes. Not put off by printers telling her it was impossible to print electronics on a conventional press, she bought her own, installed it in her garage and taught herself how to print. She called the company she started, with backing from Solon Ventures, Novalia. They use traditional print processes including flexography, offset lithography, gravure and screen, and work closely with a number of UK print & packaging companies; they recommend, for instance, which components, inks and substrates should be used, and specify the design and software. A chip on a circuit board The electronics they add to the process essentially comprise little more than small electronics modules attached to everyday materials such as paper, card, sounds simple but it’s actually been really challenging and we’ve had to solve a lot of problems.” In the process, the company has accumulated 30 patent applications half of which have been granted. Everything is interactive active and plastic, for a very low cost at high volume. “It’s just a chip on a circuit board that we stick on a piece of paper, and then we print conductive inks on that paper that connect to the circuit board,” explains Stone. The Novalia concept may be simple, but its not pure printed electronics, it’s a hybrid: the platform integrates conventional electronics, low-cost slender, silicon chips, with printed electronics. With a circuit in the corner, these can be distributed even over a large area. It’s an effective way of manufacturing electronics, on a press, without the need for glass. But the resourceful Stone doesn’t think the hybrid nature of their products is a problem, in her view it’s an advantage: “There’s a mindset, a holy grail of everything being printed,” she explains, “and I think that’s the wrong goal. The right goal is to create interactive products that can change people’s lives, because people don’t care if it’s all printed, they don’t worry about the technology. The majority only think about the experience and about it being affordable. That’s their goal and that’s our goal.” “We’re looking at how traditional print and traditional electronics can come together in a way that creates a good experience, and is easy to manufacture. It Novalia see a world where any printed item can be enabled with interactivity; bringing it to life with traditional printing techniques, using processes and manufacturing capabilities that are available right now. Commissioned product designs can involve writing interaction, software, circuit layout or creating graphics. By proving a wall-to-wall service, Novalia are able to collect a design or royalty fee on their products, which goes to fund future research and development, creating IP in printed electronic devices, methods of manufacture and applications. “The innovation is in the integration,” says Stone. And the integration is key because, in this multidisciplinary field, distinctly different skills are needed throughout the process - from graphic design to print production and, naturally, electronics. Stone leads a small, tightly knit, team. Rather than a scientist, the first person hired was a designer, a creative - rather telling in an industry dominated by technologists. “In everything that we’ve done, we put art, design and creativity before technology,” says Stone. “You can create more value, use less technology and have something that costs less if you get the concept right. Understanding people and the market is the most difficult thing. It’s not about showing off high tech. Because our tech isn’t visible, people have said: ‘it can’t do that!’ People expect it to look high tech. The future won’t be like that.” Being ahead of their time has been something of a challenge for Novalia. It’s why Stone believes that it’s taken nine long years to get to this stage. But, in a world where the Internet of Things lies just around the corner, where technology is ubiquitous and everything is interactive, Novalia’s moment may finally have arrived. Keyboards, drum kits and card Having already developed a range of product demonstrators, many in collaboration with customers, Novalia are currently engaged in innumerable exciting projects and one that’s even in production, although Stone is reticent about revealing the details. There’s a book project with a musician and a paper-thin DJ deck demoed on TEDx by Stone. But it’s not all been plain sailing. In July 2013, Novalia invited small investors to be a part of their story by backing their work through crowdfunding site Kickstarter, with a project to manufacture an A2-sized capacitive touch poster of a drum kit. With the integration of innovative sound technology, the whole surface becomes a speaker. Not only does the user hear the beats, but they also feel them when they touch the drums or cymbals. 2014 / INTERACTIVE APPLICATIONS / 15 The demo led US magazine Adweek to ask: “Is this musical poster with interactive paper the future of print and outdoor ads?” As often with their products, there are two different versions: the first connects via Bluetooth to an app running on an iPhone or iPad and plays through the device; the second is a standalone version that plays straight out of the poster. But the project hasn’t been as successful as the company hoped: “I think we created something that people just didn’t understand,” Stone explains. “When you tell someone you can play drums on a poster, they just don’t get it. But it was unbelievable to see the shock and delight on their faces every time I showed someone. They wanted to buy it straightaway! People love it but they have to experience it.” Another project on the go is a fully-functional QWERTY keyboard printed with conductive ink on a regular sheet of A4. It employs a single embedded Nordic Semiconductor System-on-Chip (SoC), with interactivity provided via a smartphone or tablet app, and it requires very little manual assembly or wiring. Because of its powerful processor, it can run Bluetooth and capacitive touch at the same time. The control module which houses the battery and electronics is just 2mm deep, while the keyboard area can be as thin as 0.005mm, ten times thinner than any other keyboard ever produced. And all this can be printed at 100 metres-per-minute on a standard print press. A simpler version called ‘Switchboard,’ which comprises only eight touch buttons, can be configured to control (or be controlled by) any Bluetooth enabled device and can conduct an eight-piece Jazz band (audio being replayed through a smartphone or tablet), control iTunes and even send Tweets. “We printed what’s known as an xy matrix, which means the chip knows where you’ve touched,” explains Stone. “Software works out what key it is and the chip, running bluetooth software, scans the matrix very quickly and communicates back. So you have a very responsive bluetooth keyboard based on one chip and a piece of print - that has to be the lowest cost way of making a keyboard. It’s caught a lot of people’s attention and we’re collaborating with a company about taking this to market.” Throwing it in the bin Because it’s produced so cheaply and is so thin, Novalia’s keyboard is also totally disposable. When I meet him, Chris Jones, the companies ink and print specialist, dramatically demonstrates the point by taking the keyboard he’s been showing me and scrunching up the plastic sheet, as you would do with a piece of paper before throwing it in the bin. Jones is enthusiastic in describing how plastic electronics can open up a whole new world of possibilities: 16 / PLASTIC ELECTRONICS / 2014 “You’ll see traditional touch interfaces disappearing into actual physical items,” he says. “Books and keyboards which are flexible, foldable, can sit in your pocket and are disposable. Even things like “liking” something in Facebook, could be done electronically; you can go into a cafe, for instance, and physically like it.” “The future potential for this technology is enormous and unlimited,” echoes Stone. “Imagine being able to touch a shop display and the product information is instantly downloaded to your smartphone; a magazine you simply touch to personalise the cover; a printed advert with a built-in social media sharing button.” Advertising and media are areas Novalia are increasingly interested in, believing there’s a big opportunity at point of sale. Getting consumers engrossed in an experience, believes Stone, has huge value. There’s also the potential for interactive direct mail and for the advertiser to be made aware of who is touching what, why, how and when. One outdoor project they have in mind is making bus shelter advertising interactive, possibly even with their drumkit poster. With so many major brands headquartered there, there’s also been a lot of US interest in Novalia recently with Stone making frequent trips across the pond. Undoubtedly, a major attraction is the low cost associated with their products. Conductive ink requires only a small press and the electronics used are also inexpensive. Also key is the fact that the products don’t require a built in display or speaker to function; lights, music, etc can come either from the point of interaction or via a mobile. Using an external device also keeps costs low as display technologies and good quality speakers are expensive and need an independent power supply. “If we can put the bare minimum of technology on the print,” says Jones, “things can be produced at the lowest cost. People already have a smartphone available they can use. But also, rather than pulling your phone out all the time, you can use it to interact with the world around you, as we can embed the touch technology on screens, displays, in books and services.” It also allows their products to be device agnostic; able to communicate with a computer, a mobile phone or the point of sale technology in a store. Jones is convinced that this method, rather than producing a stand-alone device, is the way forward: “The problem is that, once you’ve developed a really cool display, you’ve got to go out and persuade people to use it,” he explains. “Whereas If you produce a printed matrix you can buy that mass produced in China for less than 10 cents. From a marketing perspective it’s all about making these things as low cost as possible.” But instead of China, says Jones, Novalia’s strategy also focuses on localised manufacturing: “Companies producing their own things have to set up their own production line, our production line is the entire printing industry right round the world. It democratises manufacturing. We’re not paying over the odds for a special dedicated manufacturing line, we’re producing these,” he says, holding up an electronic keyboard, “on a machine that’s running ordinary print jobs too.” Just to underscore the point. Jones tells me there’s a very good reason behind his bleary eyed appearance on the morning we meet. The night before he was celebrating, after a ceremony where Novalia was the recipient of the Flexotech International Print and Innovation Award for 2013. “This is quite special to me personally,” he says, “because it’s an award about printing and underlines that we’re doing this using standard printing processes.” Britain has a long history of innovation in printing, beginning with the first press, set up at Westminster by William Caxton; there’s a vibrant, modern print & packaging industry that’s the fifth largest producer in the world. But technology is encroaching fast and many, up to now, have considered print a dying industry. So, it’s ironic that a technology which sprung up with e-Readers should also potentially become print’s saviour. For Kate Sone, it’s special for another reason too: “In particular I would love to see this technology being used to make everyday physical objects we all know and love, such as books and traditional music packaging, that have recently been in terminal commercial decline, perhaps being updated and possibly even made relevant again. And low cost keyboards made of paper could also form part of charitable and NGO initiatives to enable even the poorest people in the developing world to access modern technology for the first time. The possibilities are endless.” With Novalia, there is a tangible air of a business at the brink of success and, after nine years hard slog, it will be well deserved, but Kate Stone is wary of cracking open the champagne just yet: “A real business is a business that makes more money than it spends and we’re not yet a real business,” she explains. “We still rely on grants and investment to keep us going, we’re almost breaking even but not quite. If you’re a musician or an artist, overnight success often takes about ten years! So, if I make it this year, I’m slightly ahead of schedule. The moment of success is when everyone else would have given up and you didn’t. But the moment of perceived success, when you’re cracking open the champagne, that could be five years later.” 2014 / INTERACTIVE APPLICATIONS / 17 INTERACTIVE ELECTRONIC APPLICATIONS Wearable electronics Woven materials and fibres can also perform electrical functions such as low-power generation and storage, as well as providing lighting and display. Award winning UK company, Peratech, is working to commercialise a material called QTC (Quantum Tunnelling Composite) which can used to create new forms of switches and sensors. It’s washable and can be applied to textiles. This will not only create new market opportunities in fashion design, but also improve safety in products such as illuminated jackets for emergency workers. The military are also exploring ‘electronic camouflage’ which can cover people and equipment and is capable of dynamically changing to reflect its current environment. In the last decade, fifty percent of jobs in the European textile industry have been lost, mostly as a result of manufacturing shifting to South Asia. Technical textiles and smart textiles hold out one big hope and the market within the EU, currently valued of €45bn, is growing by 3.2% per annum, as opposed to a declining trend in the conventional textile industry of 4%. Cigarette packaging Tighter regulations mean that tobacco companies may soon be forced to introduce plain packaging. Reluctant to lose shelf visibility, they’re mooting alternatives and at least one manufacturer is looking at printed electronics. Incorporating electrical circuits into the packaging will cost manufacturers just a few pence per unit, and it’s already possible for individual cigarette packs to appear blank while on the shelf, but magically reveal their branding once in the consumer’s hand. Difficult to copy, printed electronics could also act as a security feature and counterfeiting deterrent. The Internet of Things Norway-based Thin Film Electronics has now raised $24m which it plans to use embedding sensors, displays and other devices into the Internet of Things, which sees everyday objects take on network connectivity, allowing them to send and receive data. The company’s key product is a printed, integrated, electronic tag, which can potentially replace product bar codes and costs a fraction of the price of competing products to manufacture. The company has taken three printed components — memory, logic, and a temperature sensor — and integrated them. The circuitry is sprayed onto surfaces, such as thin films, in a process which resembles inkjet printing. The device senses temperature and writes the results to memory. The data can then be output to a display and can enable tracking for goods such as pharmaceuticals and perishable foods. However it will be a few years before the system is in mass production. 18 / PLASTIC ELECTRONICS / 2014 APPLICATIONS Batteries with integral battery tester... made by Duracell Musical rum bottles which light up when you pick them up... from Coyopa Optiks - an anti-counterfeiting technology... from banknote printers DeLaRue Talking pizza boxes... from the US National Football League with Mangia Media Various anti-theft devices... in development by Wal-Mart and Tyco ADT Compliance monitoring blisterpacks and bottles... from Fisher Scientific, Vitaly Inc., Animated board games... from Hasbro and Character Vision Place mats at McDonalds RFID for tracking... being developed by Tesco & Metro and Alien Technology An interactive tablecloth... from Hallmark Magazine covers and greeting cards... from a variety of manufacturers including Tigerprint and PragmatIC A fake interactive boarding pass... Sata Airlines and Ynvisible Time temperature label to monitor Findus meatballs... designed by Bioett Posters and keyboards... from Novalia A cookie heater pack... by T Ink A fly seeking spray... by Reckitt Benkiser Theft detection devices... being tested by Swedish Postal Service and Deutsche Post Aardex and Medicom among others Real time locating systems... (source: IDTechEx) Jackson Healthcare Hospitals and Awarepoint 2014 / INTERACTIVE APPLICATIONS / 19 SMART PACKAGING F rom winking rum bottles and talking pizza boxes to electrically charged insecticide that chases the bug, electronics are already used in packaging and developers have long seen highvalue consumer goods, such as tobacco, alcohol and cosmetics, as possible springboards for electronic printing. 20 / PLASTIC ELECTRONICS / 2014 Now, even in fast moving consumer goods (FMCG), at least one major manufacturer is talking about adding printed electronics to their top range, reportedly for a nine figure sum and, according IDTechEx, the global demand for electronic smart packaging devices is currently at a tipping point and will grow rapidly to $1.45 bn within 10 years. The technology is attractive to packaging manufacturers as the products have the potential to touch consumers at many points: when a consumer first gets to know about the product or during an advertisement, when they first come across it and when it’s used for the first time. Plastic electronics can play a critical role at each of these junctions. It’s also a solution to the ageing population’s need for disposable medical testers and drug delivery devices. It can address the fact that, even in middle age, onethird of us have difficulty reading ever smaller instructions. Living in a technological age, consumers can be more demanding, and have more disposable income. As a bonus, interactive packaging presents a convenient way to get around tougher legislation (with cigarette packaging, for instance), deal with counterfeiting and even terrorism. An answer without a question? But while developers are printing batteries on pieces of paper or producing posters that act as loudspeakers, their prototypes have sometimes been labelled as answers in search of questions. Only occasionally, argue critics, have technologies been scaled up. “One of the best examples of printed electronics is the Duracell battery tester which has been in use for about ten years,” says Raghu Das, of IDTechEx. “It’s boring to most people, but its probably one of the few sustainable applications of printed electronics in packaging. It’s very crude and very simple. Quite often companies are trying to do something that’s too complex. And there’s a lot of technology, but very few actual products. Users don’t know what to do with a printed battery, for example.” The main issue seems to be that developers, up to now, have been focusing on individual components, a battery or a display rather than an integrated or complete device - the solution which end users require. A complete product But, according to Das, a few companies, having not had much revenue over the last few years, are now collaborating to build devices. One example is the Norwegian printed memory company, Thin Film Electronics. Collaboration has enabled them to create an integrated electronic label, which takes temperature readings and has a display. The first products are expected in 2014. “It’s only beginning to work now because they’re not relying on someone else to integrate it for them,” says Das. “They’re working with other suppliers to make a complete product.” But it’s still early days: in order to gain very high volume, and therefore the lowest costs by selling across all industries, basic hardware platforms such as a very low cost talking label must be developed. Getting companies often involved in different disciplines to collaborate is key. “Most SME’s don’t have resources or the capability to put a complete system together”, says Chris Rider, Director of the EPSRC’s new £5.6m Centre for Innovative Manufacturing in Large Area Electronics (CIMLAE). “We’re trying to grow a brand new industry but customers who are not part of the manufacturing supply chain just want the thing to work, they don’t want to have to organise different companies to do that.” And that’s exactly what CIMLAE seeks to address: “It’s the power, it’s an input sensor to start, the start button, timer, output, there are at least four components in every system,” says Rider. “So, if Proctor & Gamble say we want a smart label to go on a hair dye bottle with a built in timer, it’s doable but you have to speak to about three or four different companies. And how you power it? The problem the centre is going to try and solve is how to put it all together.” Prior to EPSRC’s CIMLAE, Rider headed up the Cambridge Integrated Knowledge Centre (CIKC), just one of five Centres of Excellence around the UK which have helped many new companies in the printed electronics field. He believes that smart packaging holds good early opportunities for the technology: “Companies are starting to know how to put the bits together, Novalia is one of them and PragmatIC Printing too. Some technologies will be in volume production within 5 years, but not necessarily mass market.” Technology companies are also starting to involve creative design agencies earlier in the process; they’ve seen that getting the tech right is really only half the job and that developers may not be the right people to design the creative products that really excite people and make them want to buy. “The way we’re seeing companies approach it now is that they’re building lots of different prototypes for different people and they’re seeing which one snares their client’s interest,” says Raghu Das. “Some end users fund projects, but at the moment, most of them have only been used for a promotional period because of the higher cost; they’re only doing orders of a few million.” But when these problems are finally resolved, smart packaging is on course to provide a host of consumer benefits that will make the competition look very tired indeed. With modern merchandising, a new disruptive trend will emerge and we’ll progress beyond the static of current modes of packaging. We’ll also be seeing dramatically better consumer propositions. 2014 / INTERACTIVE APPLICATIONS / 21 HEALTHCARE & MEDICAL HEALTHCARE AND MEDICAL TESTING 22 / PLASTIC ELECTRONICS / 2014 In the not-too-distant future, it’s completely feasible that chronic and even acute medical conditions might be monitored and treated in the home in a smoothly unobtrusive way: technology that reads vital signs can already easily be built into T-shirts, belts and shoes; bed sheets can check your vital signs; biosensors can live in the body, communicating directly with medical professionals. There’s even therapeutically-enabled smart furniture - these are all conceivable advances in the medium term. Cost savings riding on the back of these advances mean that they’ve attracted considerable interest from governments and insurers, particularly in the US, fueling R&D. Market Trends Raghu Das, CEO, IDTechEx: “At present, the most successful medical testing device is the glucose strip. About 20 billion are printed annually, so it’s a big industry. There’s a lot of interest in doing printing around sensing but on the other hand, there’s also been a lot of inertia - largely due to the huge potential liabilities and low rates of adoption. The medical industry can be very slow to move unless it’s legislated to. Things like smart blister packs have real potential, the idea being that each time you push a pill through, it breaks a circuit, so doctors can monitor whether a patient’s taking their pills on time. This can also be immensely helpful in clinical trials for new drugs. At the moment, drug companies have to pay people to call up and ask if participants have been taking drugs at the right time, which is expensive. However, even through smart blister packs have been on the market for nearly five years, they haven’t been widely adopted. Again, this is down to the inertia of many drug companies. So, while plastic electronics has the potential to improve healthcare in many different ways, adoption rates vary hugely. A lot of it could be helped by the government, which may need to mandate the technology in some cases.” Market Statistics • • The printed and flexible sensor market was worth $6.3bn in 2013 and IDTechEx forecasts that, by 2020, this figure will have increased by more than $1bn. Smartphones and other electronic gadgets with digital camera functionality will be able to use conventional silicon-based image sensors in combination with organic electronics. Complementary metal-oxide-semiconductor (CMOS) • • • image sensors - for increased range and sensitivity - are expected to quickly become the second largest market. Piezoresistive sensing is already an established market, and is expected to triple by 2018, with a compound annual growth rate (CAGR) of 23%. The global breath analysers market was valued at $402.1m in 2012 and is estimated to reach $4,518.4m in 2019, a CAGR of 41.3% from 2013 to 2019 (source: Transparency Market Research) Integrated circuits - with System-on-Chip in combination with printed electronics - are ideal for use in the medical device market. This sector is showing growth of 8% p.a. and will be worth £74bn by 2018. Areas such as bladder control, nerve stimulation for people with epilepsy and paraplegia, as well as temperature sensors, all are key for commercial expansion (IDTechEx). A brilliant future for blister packs? It’s estimated that globally, only half of all medication is taken as prescribed. This doesn’t just affect patient health, it hampers research and can compromise drug trials. The economic burden of non compliance has been put at $100bn a year. IDTechEx has found that the demand for electronic smart packaging devices is currently at a tipping point and will grow rapidly to $1.45bn within 10 years; it’s the obvious way to tackle compliance issues. In the US particularly, there are a large number of companies currently working on smart blister packs, They typically function by means of a tiny, hidden microprocessor and printed, conductive inks which record the date, time and location of each pill removed from the package. The outer packaging helps patients remember to take their medication, through customised “prompt technologies” including light, sound or vibration. Glowpack, made by Vitaly Inc., is just one example. It can measure liquid medicines as well as oral solids, injectables and topical ointments and provides both visual and audible reminders at dosage time. It fits on most prescription bottles, via a cap containing a wireless chip that communicates with a light plug—akin to a night light—which pulses orange and chirps, when you’ve forgotten to take a pill. Due to go on sale in the US in early 2014, it’s priced at $79.99 plus a monthly service fee. For other products, additional features may also be integrated, such as questionnaires to record patient feedback, to record any pain, for instance. As well as compliance, blisterpacks are also thought to boost sales. Research by the Swiss drugmaker 2014 / HEALTHCARE AND MEDICAL TESTING / 23 Novartis and consulting firm Xcenda found that patients who received medicines in blister packs with calendars bought refills five days sooner than those getting them in traditional amber bottles. They also stayed on their medication 22 days longer over the course of a year. American pharmacies like Wal-Mart and Kroger already use smart blister packs for some drugs to set themselves apart from competitors and Wal-Mart intends to expand their use in 2014. In the short term, it’s easy to see how smart packaging can deliver clear healthcare improvements and it could also be a powerful weapon against drug counterfeiting. Furthermore, in the US, the tracking of patient compliance will become increasingly important with upcoming changes to healthcare funding in the Affordable Care Act. Under the new Act, which comes into effect next year, reimbursements to health plans for Medicare patients can be docked if patients don’t keep up prescriptions for their cholesterol, blood pressure and diabetes drugs, meaning insurers may be looking for packaging ploys that boost adherence. As well as fundamentally changing the way the package interacts with the consumer, this upcoming wave of technological innovation will have other implications and is expected to come to fruition over the next fifteen years. Packaging may feature inexpensive displays as conductive inks will allow “screens”, that could be updated interactively, with video clips to prompt or educate. But there’s also cause for concern. As the market for smart medical packaging grows and moves increasingly online, it will be vital to keep an eye on how well private medical data is protected. After all, the inappropriate disclosure of personal medical information could set smart packaging back a long way, before it’s even got started. A big issue is also that smart blister packs are still expensive to produce - one study estimates that costs are up to three times more than typical pill bottles - and more research is necessary to judge whether their potential to increase drug adherence outweighs their higher cost. But sensing a shift, some in the market are already responding. Having gained US Food and Drug Administration approval for its smart blister packs, Northern Ireland-based contract manufacturer Almac has invested about $10m in a Pennsylvania packing plant. Richard Shannon, head of business development in Europe for the company, said it has seen a move by the industry toward blister packs and wallet cards to improve patient adherence to dosing regimens. “We have invested heavily in blistering packs and wallet card automation based on where we see the market moving in the U.S. and Europe,” he told online publication, Fierce Pharma Manufacturing. 24 / PLASTIC ELECTRONICS / 2014 COMPANY WATCH PolyPhotonix, a poly-capable startup Richard Kirk, CEO of Durham-based PolyPhotonix, doesn’t claim to have all the answers for tech-based startups. But when it comes to bringing innovation to the marketplace, his argument is sound. PolyPhotonix is pioneering the early adoption of organic light. They work with designers and potential end-users, to create new products and to support the design process right through to largescale manufacture. “We started as many companies do, as one person with an idea. We managed to get that funded through an early Technology Strategy Board (TSB) project, that offered significant investment of £3.5m, over 3 years. We were very fortunate in that we were then able to work with the Centre for Process Innovation (CPI), which was a good place to incubate the company and work with their scientists and management. Fairly quickly, we were able to work as a larger company might because we had the back-up and we had the systems.” But what differentiates PolyPhotonix from other science-led start-ups is their keen sense of the commercial imperative. When their first brainwave proved more costly than they’d thought to develop, they diversified. “Our great strength is that we’re driven by the market, not by our technology and we’ve been very good at talking to one potential funding body and linking them with another. The TSB, the Department for Business Innovation and Skills (BIS) and the NHS have all been supremely helpful to PolyPhotonix. We’ve managed to migrate between these big, powerful organisations with a clear message and to pull a little bit of support from here and from there - joining all those dots to get the right outcome.” Their clear message has managed to raise £12m in four years. Which sounds like a lot for joining some dots - and it is. A lot of that has gone through PolyPhotonix to the seven universities that are currently running long-term clinical trials for its new treatment for macular eye disease. They’re feeling confident, but are cautious about attracting premature publicity for the treatment: “We’re three years away from finishing trials. People who are losing their sight are understandably desperate for any therapy, immediately. It’s just not fair to make big statements until we’re ready to go to market.” In the meantime, Kirk and his colleagues are constantly looking for the next brainwave. “We talk continuously to other scientific sectors. It’s great to get physicists, medics and biologists - people who are all at the top of their game - together in one room to spark ideas off each other. I love to engineer those meetings - and I make sure we do it frequently.” WE’RE BUSINESS DRIVEN. AND WE’RE GOOD AT JOINING THE DOTS. 2014 / HEALTHCARE AND MEDICAL TESTING / 25 EPIDERMAL ELECTRONICS 26 / PLASTIC ELECTRONICS / 2014 BODY AREA NETWORKS The body area network (BAN) field is an interdisciplinary area exploring the possibility of inexpensive and continuous health monitoring with real-time updates of medical records through the Internet. BANs rely on the feasibility of implanting very small biosensors inside the human body that are comfortable enough for the wearer to go about their business normally. The implanted sensors would collect various physiological data in order to monitor the patient’s health status, whatever their location. The information would be transmitted wirelessly to an external processing unit. This unit would then transmit information in real time to doctors throughout the world. If an emergency is detected, the patient would be informed through the system by the sending of appropriate messages or alarms. At present, the quality of information provided and energy resources capable of powering the sensors are limited. While the technology is still in early stages, it is being widely researched. Initial applications of BANs are expected to appear primarily for patients suffering from chronic problems such as diabetes, asthma and heart disease. The benefits are clear. A BAN might call the hospital even before the patient has a heart attack, alerted by changes in their vital signs. On a diabetic patient it could auto inject insulin through a pump, when levels decline to a risky point. However, the potential drawbacks of BANs need to be addressed - e.g. the risk of data interference, data consistency and information security. THE BARE FACTS ABOUT E-SKIN Advances in materials, fabrication strategies and device designs for flexible and stretchable electronics and sensors make it possible to envision a not-toodistant future where ultra-thin, flexible circuits based on inorganic semiconductors can be wrapped and attached to any imaginable surface, including body parts and even internal organs. Robotic technologies could also benefit as e-skin allows surgical robots to interact in a soft contacting mode with their surroundings through touch. Human skin is a sensitive detector of both pressure and temperature and efforts to develop electronic sensors with comparable capabilities are widespread. In the past decade, with the increased availability of new materials and processes, the pace of e-skin development has raced ahead. Perhaps the most obvious characteristic of human skin is its ability to stretch and flex. But it has other crucial sensing capabilities including tensile strain monitoring and grasp control. Fabricating the large-area flexible arrays needed for the batch production of e-skin is a challenge. Many groups have turned to polymer micromachining, which is more cost effective and typically involves using photolithography or moulding to pattern device structures, such as air gaps for capacitive sensors or resistive strain gauges. Large-area solution processing and printing technologies have gained popularity as low-cost, high-throughput techniques. As tactile sensing requires a multitude of sensors distributed over a large area, effective ways of collecting and processing a large amount of information are essential. Modular approaches involve creating arrays that can be combined to order. By implementing computing capabilities into each module, signal processing or data analysis can occur within the sensor network itself. Modularity also provides the ability to expand a sensor network to meet the needs of any application. E-skin might even be augmented beyond the capabilities of human skin through the integration of chemical and biological sensors to monitor of a whole range of compounds - from environmental pollutants and chemical and biological warfare agents to medically relevant biomarkers. SKIN TATTOOS THAT CAN CHAT WITH MOBILE DEVICES Someday soon, a picture of a hospital patient hooked up by wires and monitors will seem as out-dated as one of an iron lung. The era is fast approaching when electronic patches will be temporarily tattooed onto patients’ bodies - enabling them freedom of movement and allowing medics to monitor their vital signs without poking and prodding. Patients wearing neck patches will even be able to communicate with robots, who will translate throat muscle movements into simple speech. In May 2012 the company Motorola Mobility, owned by Google, lodged a patent application for a device described as a “tattoo that could be applied to the throat....and would include an embedded microphone, a transceiver for enabling wireless communications, and a power supply to receive energising signals from a personal area network associated with your mobile devices.” A similar idea was published in 2011 by research teams at the University of Illinois. Described as a patch that mounts onto the skin like a temporary tattoo, it combines electronics for sensing, medical diagnostics, communications and human-to-machine interfaces. The healthcare potential is compelling. By “reading” the movement of facial muscles, this could aid technologies that help people who cannot speak; smart skin patches could make it easier to monitor newborn babies, or people with sleep disorders. The devices might even laminate onto a portion of muscle that is atrophied, or onto a wound site, and could electrically stimulate muscle contraction, to aid healing. 2014 / HEALTHCARE AND MEDICAL TESTING / 27 Wearable electronics for healthcare T he development of electronics that can be bent, stretched or moulded without loss of function, or can store energy, has attracted a great deal of research. Companies such as UK’s Peratech, which focuses on the innovative material QTC, and PowerWeave (funded through the EU’s FP7 programme) which is developing textiles for energy generation and storage, have made great progress in harnessing the potential of printed electronics in this area. Commercialisation hasn’t quite kept pace with the technical breakthroughs, but exciting possibilities are continuing to emerge. Temperature monitoring insoles to keep diabetics on their feet In partnership with Reebok, Massachusetts-based MC10 have launched a wearable device designed to take the on-the-pitch guesswork out of head trauma. Called Checklight, it uses a core technology called BioStamp, with a stretchable, sensor-laden surface to measure the speed and impact of blows to the head, providing information to athletes and medics. MC10 also intends to launch a sticking-plaster-sized BioStamp vital-sign monitor in the next five years it will be smartphone-compatible and priced at less than $10 per unit. Diabetes is associated with numbness in the extremities and an increased risk of foot ulcers. Any untreated wound can, in the worst case, lead to gangrene. However, foot inflammation can be readily monitored via temperature and a new pressure monitoring system, named SurroSense, has now been developed by Orpyx Medical Technologies Inc. of Canada to help prevent diabetic foot ulcers. A spring 2014 launch is anticipated in the UK. Thin, sensor-embedded inserts, which monitor the pressure exerted on various areas of the feet, are worn in the patients’ shoes and the information sent wirelessly to either a smartwatch or a mobile app. Philips Bilirubin blanket Smart Diapers MC10 & Reebok: brain-impact sensor The Philips Bilirubin Blanket is the antidote to the intrusive photo therapies used, up to now, for the treatment of jaundiced newborns. The blanket incorporates LEDs in its textile technology which - because it emits little infrared and ultraviolet radiation - is safe to use. 28 / PLASTIC ELECTRONICS / 2014 Babies of the future may be wearing Pixie Scientific’s Smart Diapers which have in-built sensors and a QR patch on the front that changes colour when wet. When scanned with a phone, the data can be analysed for urinary infections, dehydration and kidney problems. FROM HEART DISEASE AND DEEP VEIN THROMBOSIS TO GASTRIC CANCER Heart disease is the UK’s biggest killer — one in five men and one in seven women can expect to die from it. Its cost to the UK Healthcare System was estimated at £625m in 2011. In the US Healthcare system, the bill is a mighty $34.4bn. Currently, Chronic Heart Failure (CHF) is tackled via a combination of drug therapies and surgical intervention. In all, up to 40 percent of sufferers of CHF die within the first year of diagnosis. However, researchers at Nottingham Trent University may have a new solution. They’ve developed a “smart pump” that can be grafted on to the aorta. Made from a smart material, it responds to a voltage by expanding and collapsing, to create a pumping mechanism and is powered by a remote and self-contained, implanted battery. Not a publicity stent For blocked arteries, the main method of treatment is currently coronary angioplasty, where a short wiremesh tube is inserted via the wrist into the artery, effectively, propping it open. English hospitals perform over 61,000 angioplasty procedures a year and a significant number lead to complications. It’s estimated maybe 20% of angioplasties may not even be the best therapeutic option and an angiogram doesn’t always help. A new option is to insert a tiny wire with an extremely accurate sensor in its tip that precisely measures blood flow and pressure in the artery. The disposable pressure wire costs £330, which is about the same as a stent and studies have shown positive results. DIY test for DVT Long-haul air travelers may soon be able to check if their blood is clotting with a simple test during flights. With just one drop of blood needed for analysis by a biochip for clotting markers, a disposable single-use device could be carried by anyone at high risk of clotting disorders. The deep vein thrombosis (DVT) diagnostic test could also be available for hospitals and GPs’ surgeries. This means patients would no longer have to wait days for a lab result. Ten leading European research institutes and high tech firms are currently working on the “Do-It-Yourself” DVT diagnostic. They’re also developing a sensor wristband which could provide long-term monitoring of various vital stats for older patients and athletes, such as hydration levels and “electric smog,” to warn pacemaker wearers of strong electric or electromagnetic fields in close proximity. A digestable test for early-stage gastric cancer Researchers at Chongqing University in China have developed a capsule which can detect tiny quantities of “occult” blood for screening of early-stage gastric cancer. The capsule, which is swallowed, carries inside a detector, power supply, and wireless transmitter, encased in non-toxic, acid-safe polycarbonate. It transmits data to an external monitoring device in real time for diagnosis by a physician. Laboratory tests have demonstrated its simplicity and reliability, the researchers say. Optical sensing research for faster cancer detection Laser-printed paper-based sensors that can be used to detect biomarkers in cancer patients and see how they are responding to their chemotherapy treatment are being developed by the UK’s Optoelectronics Research Centre (ORC), with the aid of an EPSRC research grant. The technology could transform the care of cancer patients, or people with infections, in their own homes. The sensors would also be telemedicine-enabled allowing transfer of valuable clinical diagnostic information between patients and their care team through a mobile. Biomarkers for breast cancer have already been identified, validated and are now being used to study the response of patients receiving chemotherapy. If successful, these paper-based sensors would prove invaluable in rapidly testing for detection and diagnosis of conditions including cancer and infectious diseases such as influenza, HIV and tuberculosis. They would allow the rapid testing for these conditions in a safe, inexpensive and flexible way that would have enormous benefits in time, cost and improvement of patient care. 2014 / HEALTHCARE AND MEDICAL TESTING / 29 MATERIALS Materials Electronic components such as chips, displays and wires are generally made from metals and inorganic semiconductors — materials with physical properties that make them fairly stiff and brittle. So, in the quest for flexibility, many researchers have been experimenting with semiconductors made from plastics (polymers), which bend and stretch readily. Over the last two decades of the 20th century, a huge number of new organic and inorganic materials were invented in the UK’s universities. These include highperformance organic and inorganic transparent and opaque conductive materials, organic semiconductor materials and both organic and inorganic dielectric materials, light emitting materials, protective materials, materials that are flexible and/or transparent, barrier materials and substrates. How does plastic electronics differ from conventional electronics manufacturing? Conventional Electronics Plastic Electronics Needs high-temperature processes. No need for high-temperature processes. Relies on subtractive ‘coat, pattern and etch back’ processes resulting in excessive waste materials with environmental implications. Individual circuit devices are fabricated at the point of manufacture using new solution-processed materials and delivery methods. Active circuit elements can be printed using carbon-based semiconductive inks. High-investment manufacturing cost which means a limited number of global manufacturers dominate production. Processes can be used by non-electronic printing and packaging companies in existing production lines. 30 / PLASTIC ELECTRONICS / 2014 Organic vs. inorganic and composite materials Many people don’t realise that plastic is classified as an organic material because it’s carbon-based. Organic materials are the preferred choice for use as substrates for flexible electronics because they’re light weight, low cost and have a wide range of mechanical flexibility. Polymer films are most often used today, but paper, cardboard, thin glass and stainless steel are also prominent candidates. Plastics are higher priced because of special advantages like increased heat or chemical stability. Inorganics include various metals and metal oxides, used as transparent conductors (such as fluorine tin oxide or indium tin oxide) or as transistor materials and inks (nano-silicon, copper or silver). Then there are tiny inorganic nano particles, known as quantum dots, carbon structures such as graphene, nanotubes, buckyball magnets and the amazing new metamaterials that can even render things invisible and lead to previously impossible forms of electronics. IDTechEx forecasts a market of $45bn for printed electronics by 2022, expected to be more or less evenly divided between organic and inorganic materials. Over the next ten years, inorganics are likely to win out as a choice for the majority of conductors (electrodes, antennas, touch buttons, interconnects) as improvements are made possible with the use of nanotechnology. As opposed to organic alternatives, which will remain poorly conductive and expensive. 2014 / MATERIALS / 31 CHALLENGES Finding a replacement for ITO Today, more than 50% of the cost of a capacitive touch screen module comes from its indium tin oxide (ITO) sensor. The replacement of this widely used ITO sensor electrode material will not only change the game entirely in terms of costs, but also open the door to bendable, rollable and stretchable electronics with touch functionality. Replacement possibilities include metal meshes, graphene, organic materials and carbon nanotubes. But despite significant efforts to develop alternatives, ITO coating remains the favoured technique for producing clear conductive substrates suitable for OLED displays. How to seal materials that are otherwise sensitive to air Many of the materials used in printed or organic electronic displays are chemically sensitive and will react with environmental components such as oxygen and moisture. Using substrates and barriers such as glass and metal to protect them results in a rigid device unsatisfactory for many applications. Whereas a big problem with plastic substrates and transparent flexible encapsulation barriers is that they are semipermeable, which could allow air and water to leak into the device. To avoid this, there are a range of approaches to encapsulation where the plastic is coated and barrier layers applied. Progress has recently been made with hybrid barrier and encapsulation layers, in which organic interlayers decouple small defects in inorganic barrier layers, reducing the number of layers needed for an acceptable barrier. This challenge highlights that beyond flexibility, printability and functionality, encapsulation is an important requirement for plastic electronics. Because to be commercially successful, they must be robust enough to survive for the necessary time and conditions required of the device. According to IDTechex, by 2023, flexible barrier manufacturing will be a market of more than $240m. 32 / PLASTIC ELECTRONICS / 2014 Plastic isn’t the answer to everything Plastic has different properties to glass, so manufacturers have to find ways to use it without compromising a screen’s image quality or responsiveness. Researchers are also experimenting with glass/plastic hybrids and “crystallisation,” an industrial process for making plastics. A team at London’s Imperial College has now found that adding small amounts of chemical additives in the formulation of plastic electronic circuitry enables it to be printed more reliably and over larger areas, which would reduce fabrication costs in the industry. The researchers found the additives gave them precise control over where crystals would form, meaning they could also control which parts of the printed material would conduct electricity. Crystallisation also happened more uniformly and faster than normal and without the need for exposure to high temperature (which is used to speed up the process, but can degrade the materials). The team now plan to focus on the industrial exploitation of their process, working with printing companies and aided by EPSRC’s new CIMLAE. Improving materials Materials R&D is, as a whole, one of the strongest areas in UK plastic electronics, but challenges in improving electrical performance, processability and stability of materials still exist. Inks Printing electronics requires inks with electrical properties that can act as conductors, resistors or semiconductors. There are a number of materials which can be used to print flexible electronic circuits directly onto materials like plastic or fabrics. IDTechEx find that the overall conductive ink market size was in decline in 2013 due to less use in photovoltaics. However, they believe that the market will stabilise and grow as applications for conductive inks emerge and predict that sales will increase to $3.36bn in 2018, with $735m captured by new silver and copper nanostructure inks. These values reflect the fact that conductive inks are the most successful segment of printed electronics. This is because of their use in a great variety of end applications, enabling products to be developed using traditional printing methods. Copper conductive ink Although not as good a conductor of electricity as silver and not as stable as gold, copper-based inks have a big advantage in that they’re inexpensive. To take advantage of copper’s reduced costs, efforts are underway to identify solutions, such as novel curing processes including laser or flash sintering, which can improve the material’s shortcomings. One example is Dr David Hutt’s research at Loughborough University. His team has replaced copper oxide with a protective coating, which disappears during thermal curing, leaving a pure copper conductive path. Whilst the conductive material is still wet, components can be put in place and the assembled whole cured. US company Novacentrix are also working in this sphere. Since 2009, they’ve produced nanocopper inks which are reduced in-situ. Silver conductive ink Silver is a better conductor of electricity than copper, but silver is expensive and tricky to print because it melts at 962°C. However, by making silver into particles just five nanometres (billionths of a metre) in size, a US manufacturer, Xerox, has produced a silver ink which melts at less than 140°C. This allows it to be printed using inkjet and other processes relatively cheaply. Gold conductive Inks Gold is valued in the electronics industry due to its stability which promotes high reliability and longevity. Also, unlike silver, when gold is used, there is no crystal growth which leads to tarnishing. These advantages make gold suitable for applications varying from thin film transistors to emerging photovoltaics, photodetectors and other types of sensors. However, gold’s high cost is an important disadvantage, with prices for silver inks already considered too high. Most R&D work in this material is some way from commercialisation, but IDTechEx estimates that the market opportunity for nanoparticle gold inks will reach $10m by 2016. 2014 / MATERIALS / 33 UK companies involved in materials development Merck: this Southampton based company is developing novel materials systems for organic photovoltaics and flexible displays. SmartKem: leading the way with their proprietary polymer organic semi-conductor that is not only air stable, but can also be inkjet printed. Intrinsiq Materials Ltd: currently manufactures the world’s leading copper based inkjet ink with laser curing capabilities making on the fly processing on a reel-to-reel platform possible. CDT: a reputation for making the best-in-class Polymer-OLED materials with over 300 patents filed in the plastic electronics area. 34 / PLASTIC ELECTRONICS / 2014 KEY MATERIALS RESEARCH Graphene The UK’s “miracle material,” graphene, has a key role to play in printed electronics. Said to be hundreds of times stronger than steel and able to conduct electricity at super high-speed, graphene could revolutionise computing and even usurp silicon. There are at least six major potential applications for graphene in plastic electronics, among them: screens and displays; memory chips and electronic processors; biomedical devices and sensors; batteries; coatings, inks, fillers and materials. Display screens are thought to have the most initial potential, as graphene combined with plastic provides strength and will also conduct electricity. Flexible display specialist Plastic Logic has been working with the Cambridge University Research Centre on graphene to create flexible LCD and OLED screens for mobile devices. “It has fantastic potential for flexible electronics, says the company’s Research Manager Mike Banach. “To make a display you need several layers that have different functions, a graphene layer would allow things to be much more flexible.” However, although it has fantastic properties, transitioning that into a practical way of making devices is another thing altogether and graphene has yet to be produced in commercial quantities. But there’s plenty of research going on: Making graphene magnetic would allow for the switchable on/off states that are so integral to electronics. Scientists at the University of Manchester are working on achieving this so that, in the future, graphene can be used in hard disks, memory chips and sensors. Graphene also has application as a solution processable ink, it’s cheap, scalable to match specific application needs and doesn’t require much processing after printing in comparison to other conductive inks. Aided by a CIKC grant, researchers at the University of Cambridge are developing a portfolio of graphenebased inks for printable electronics. By the end of 2014, the goal is to produce three litres per day for R&D work and standardisation to enable compatibility with commercial print processes, such as flexo, gravure and offset litho. The team is working with specialist printed electronics company Novalia to validate the inks on its indus- trial printing machines. An early-stage demonstrator, a flexible piano keyboard, has already been created using the graphene-based ink. In early 2014, the TSB established the Graphene Special Interest Group, accessible at graphenesig.net., to support the exploitation of the UK industry. Carbon Nanotubes Carbon Nanotubes (CNT’s) are tiny but long and hollow tubes, with walls made of carbon sheets covered in electrons, making them extremely conductive. They’re also flexible, transparent and cost efficient and so have a huge potential in electrical and electronic applications. CNTs are used for making transistors and inks, as conductive layers and transparent conductive films (TCFs). They’re also considered a viable replacement for ITO transparent conductors in some applications. Because of their multiple uses, IDTechEx forecasts that the value of devices that partly incorporate these materials will reach over $63bin in 2022. Much research is focussed on this area. One example is the study led by Dr Mark Baxendale, of Queen Mary College, London. His team are experimenting with using carbon nanotubes to create a very disorganised structure, something that looks very much like a plate of spaghetti under a powerful microscope. It’s this disorganisation which enables the network to cope with movement and distortion. Because the super-conductive tubes criss-cross in random patterns, connectivity is maintained even when the material changes shape. It’s expected that carbon nanotubes will be commercially available in volume from 2016 QTC Quantum Tunnelling Composite (QTC) is a unique, patented electronic material which can be used to make completely new forms of switches and sensors capable of carrying large currents and sensitive to various stimuli. A UK company, Peratech, was founded in 1996 to commercialise QTC, which is at the heart of a rapidly-growing number of commercial products and has received many national and international awards, the most recent being the Queen’s Award for Innovation 2012. 2014 / MATERIALS / 35 COMPANY WATCH 3D PRINTED ELECTRONICS Optomec, based in Albuquerque, New Mexico, has developed systems for a variety of industries. It can print electronics directly onto a pair of glasses, for “augmented reality,” it can make a plastic water tank that uses embedded electronics to measure how full it is and turn pumps on or off; it can print sensors on military armour; or an antenna on the case of a mobile phone. In 2012, Optomec collaborated with a US producer of unmanned aerial vehicles and a 3D-printing company to print circuits, sensors and an antenna onto the wing of a small drone, using its Aerosol Jet technology. In the future this would allow lightweight drones that can be customised for specific missions and printed on demand. Aerosol Jet atomises nanoparticle-based print materials into microscopic droplets. The system can print electronic features smaller than a hundredth of a millimetre wide from a variety of materials. Instead of assembling an item from many separate components, 3D-printed electronics make it possible to print an entire product and commercial applications are thought to be less than a year away. But although it’s possible to print transistors, and thus produce logic circuits, it’s not yet possible to print the billions of tiny transistors found in microprocessors and other chips. UK applications With BAE Systems announcement in January 2014 that its engineers had created and flown a 3D printed metal part for the first time on-board a Tornado fighter jet, the way ahead for using 3D printed parts in other military kit is opening up. Aerosol printing has many advantages over silicon versions, including lower set-up costs and increased flexibility of design. The Welsh Centre for Printing and Coating, at Swansea University, is involved in a range of projects involving aerosol jet deposition. One project, supported by 3D semi conductor specialists Interposers GmBh, focuses on the development of aerosol printed so-called interposer layers to interconnect silicon chips. With the ability to tailor treatments and devices to the individual, 3D electronic printing promises a wealth of applications in the medical sphere. Using a smart material which expands when a voltage is applied, researchers at Nottingham Trent University (NTU) and Nottingham University Hospitals NHS Trust have designed a 3D-printed electronic smart pump to increase the efficiency of the human heart. Their design was a focal point of NTU’s September 2013 Expo.
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