Center for Academic Services & Advising September 9, 2016 Chemistry I β Chap 3 1. Complete the chart below: Formula Name CSI Worksheet 1 Molecular Weight HCl Hydrochloric Acid 36.46 g/mol CO Carbon Monoxide 28.01 g/mol Fe2O3 Iron(III) oxide 159.7 g/mol MgCl2 Magnesium Chloride 95.21 g/mol SiO2 Silicon Dioxide 60.09 g/mol NH4NO3 Ammonium Nitrate 80.05 g/mol NaHCO3 Sodium Bicarbonate 84.01 g/mol 2. The elemental mass percent composition of ascorbic acid (vitamin C) is 40.92% C, 4.58% H, and 54.50% O. Determine the empirical formula for ascorbic acid. Assume a basis of 100g of ascorbic acid, therefore: C = 40.92 g, H = 4.58 g, O = 54.50 g Convert all masses to moles: 1 mol C = 3.41 mol C 12.01 g C 1 mol H 4.58 g H = = 4.54 mol H 1.008 g H 1 mol O 54.50 g O = = 3.41 mol O 16.00 g O 40.92 g C = Write in the form of a chemical equation: C3.41 H4.54 O3.41 Divide all subscripts by the lowest number (in this case, 3.41) C1 H1.33 O1 Scale the formula to reach whole numbers in the subscripts π π π π ππ COLORADO SCHOOL OF MINES Catherine I Core Supplemental Instruction Facilitator | Chemistry I Center for Academic Services & Advising 3. Write a balanced chemical equation for the following reaction: Solid iron(III) oxide reacts with hydrogen gas to form solid iron and liquid water. Determine the unbalanced formula first: Fe2 O3 (s) + H2 (g) β Fe(s) + H2 O(l) Next, balance the equation: ο· There are 2 iron atoms in the Fe2O3 (iron(III) oxide), so there must be 2 iron atoms on the products side of the equation. ο· There are 3 oxygen atoms in the Fe2O3 (iron(III) oxide), so there must be 3 oxygen atoms on the products side of the equation. ο· There are 2 hydrogen atoms on the reactants side, and since liquid water is already scaled up by 3 to account for the oxygen, there must be 3 hydrogen molecules on the reactants side. Fe2 O3 (s) + π H2 (g) β π Fe(s) + π H2 O(l) 4. Fructose is a common sugar found in fruit. Elemental analysis of fructose gives the following mass percent composition: 40.00% C, 6.72% H, and 53.28% O. The molar mass of fructose is 180.16 g/mol. Find the molecular formula for fructose. Assume a basis of 100g of fructose: C = 40.00 g, H = 6.72 g, O = 53.28 g Convert all masses to moles: 1 mol C = 3.33 mol C 12.01 g C 1 mol H 6.72 g H = = 6.67 mol H 1.008 g H 1 mol O 53.28 g O = = 3.33 mol O 16.00 g O Write in the form of a chemical equation: C3.33 H6.67 O3.33 Divide all subscripts by the lowest number (in this case, 3.33) C1 H2 O1 Determine the βmolecular weightβ of this empirical formula: π π π 1 πΆ β 12.01 + 2 π» β 1.008 + 1 π β 16.00 = 30.03 π/πππ πππ πππ πππ Take the molar mass of fructose and divide by the calculated molar mass: π 180.16 πππ = 6.00 π 30.03 πππ Therefore, the molecular formula for fructose is: 6 β (C1 H2 O1 ) = ππ πππ ππ 40.00 g C = COLORADO SCHOOL OF MINES Catherine I Core Supplemental Instruction Facilitator | Chemistry I
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