Sophomore AP Name: ______________________________________________________ Chemistry Sophomore Student Golder College Prep Class of 2018 Dear AP Chemistry Student, First, congratulations on successfully completing your freshman year at Golder. You should be proud of all that you have accomplished! Next year, you are enrolled to be part of Golder’s first ever Sophomore AP Chemistry course. Its going to be an amazing year and below you will find the information you need to get you started with the course. AP Chemistry will be a very challenging course. You will read pages and pages of your science textbook, take hundreds of pages of notes, study for quizzes, prepare for exams, perform laboratory experiments, write papers/lab reports, keep an organized portfolio, explore the world around you, listen to and question current scientists, and more. We have confidence that the class of 2018 is ready for the challenge and will have historic growth on the science section of the PLAN. In addition, we are confident that you are ready to raise the bar for AP Chemistry here at Golder College Prep. Due to the large amount of material that we will need to cover next year, you will be responsible for learning the material in this packet by the first day of school. Pace yourself and spread it out throughout the summer. Memorization takes a while and should be done every day for 10-15. Stay organized and on track. There is a checklist on the last page of this packet to help you keep track of your responsibilities. Please be aware, that as an AP student, you will need to hold yourself to a high standard. The first part of this will be doing your ABSOLUTE best work on your summer homework. Not doing the assignment, is not an option. It will leave you far behind and you will have so much to make up in the first few days off school. We are confident, no student will choose to put themselves in that situation! Get ready for a great year in AP Chemistry! Have a great (and productive) summer! J 1 Sophomore AP Name: ______________________________________________________ Chemistry AP Chemistry Summer Assignment 1. MEMORIZE the symbols and names for the following elements. If you are given the symbol, you should be able to write the name. If you are given the name, you should be able to write the symbol. (*Notice the symbols are one capital letter or one capital with one lower case letter) On the AP test, you are given a periodic table with NO element names so this is very important for your success in the course/on the test. YOU SHOULD MAKE FLASHCARDS WITH THE NAME ON ONE SIDE AND SYMBOL ON THE OTHER TO HELP YOU MEMORIZE! DO THESE 10-15 MINUTES EVERY DAY! Name Symbol Name Symbol Name Symbol Hydrogen H Titanium Ti Molybdenum Mo Helium He Vanadium V Technetium Tc Lithium Li Chromium Cr Ruthenium Ru Beryllium Be Manganese Mn Rhodium Rh Boron B Iron Fe Palladium Pd Carbon C Cobalt Co Silver Ag Nitrogen N Nickel Ni Cadmium Cd Oxygen O Copper Cu Indium In Fluorine F Zinc Zn Tin Sn Neon Ne Gallium Ga Antimony Sb Sodium Na Germanium Ge Tellurium Te Magnesium Mg Arsenic As Iodine I Aluminum Al Selenium Se Xenon Xe Silicon Si Bromine Br Cesium Cs Phosphorus P Krypton Kr Barium Ba Sulfur S Rubidium Rb Platinum Pt Chlorine Cl Strontium Sr Gold Au Argon Ar Yttrium Y Mercury Hg Potassium K Zirconium Zr Lead Pb Calcium Ca Niobium Nb Uranium U Scandium Sc 2 Sophomore AP Name: ______________________________________________________ Chemistry 2. MEMORIZE the symbols, charges and names of the ions on the ion list. If you are given the ion formula, you should be able to write the name. If you are given the name, you should be able to write the formula with charge. YOU SHOULD MAKE FLASHCARDS WITH THE NAME ON ONE SIDE AND FORMULA WITH CHARGE ON THE OTHER TO HELP YOU MEMORIZE! DO THESE 10-15 MINUTES EVERY DAY! a. Example: NO3- is nitrate. NO3- is the formula containing a -1 charge. The ion is called nitrate. b. Helpful Hint #1- Any positively charged ions are called cations and any negatively charged ions are called anions. c. Helpful Hint #2- Trends in charge on the periodic table. i. Any element in the first group/column on the periodic table (H, Li, Na, K, Rb, Cs, Fr) have a +1 charge. ii. Any element in the second group/column on the periodic table (Be, Mg, Ca, Sr, Ba, Ra) have a +2 charge. iii. This elements in the third group/column on the periodic table (Al) has a +3 charge. th iv. These elements in the 15 group/column on the periodic table (N, P) have a -3 charge. th v. These elements in the 16 group/column on the periodic table (O, S) have a -2 charge. th vi. Any element in the 17 group/column on the periodic table (F, Cl, Br, I) have a -1 charge. th vii. Any elements in the 18 group/column on the periodic table (He, Ne, Ar, Kr, Xe, Rn) have NO charge or a charge of zero. d. Helpful Hint #3- Any ion with ONE element (monoatomic anions/cations) containing a charge (Li+, N3-, etc) are named just like the elements are named. Li is lithium and Li+ is also lithium. N is nitrogen and N3- is also nitrogen. e. Helpful Hint #4- Memorize the –ate ions first (sulfate, nitrate, chlorate, etc). i. Once you memorize the –ate ions, the –ite ions have ONE LESS OXYGEN. Example sulfate is SO42- and sulfite is SO32-. ii. Once you memorize the –ate ions, the per- ions have ONE MORE OXYGEN. Example chlorate is ClO3- and perchlorate is ClO4-. iii. Once you memorize the –ate ions, the hydrogen _____ ions have ONE HYDROGEN and +1 charge added. Example sulfate is SO42- and hydrogen sulfate is HSO4-. f. Helpful Hint #5- “Metals with more than one ion” charges just need to be memorized. No shortcuts on these guys J Please note the charge corresponds to the written name (stock system). Example: Fe3+ is Iron (III) and Fe2+ is Iron (II). 3 Sophomore AP Name: ______________________________________________________ Chemistry 3. SKILL of figuring out what formulas/compounds are created between different ions. Positively charged ions are attracted to negatively charged ions (think of a magnet! J). Due to different numbers of charges (+1, -3, +2, -1, etc), different formulas will be created. The key is that all compounds formed have an overall charge of ZERO. Using the ion puzzle, attached. Complete the follow up questions a. For example, Li+ and N3- forming a compound (puzzle) would involve the following thought process… i. Each Li+ puzzle piece has one “key” and each N3- has 3 “locks”. If you have an unlimited amount of each puzzle piece, 3 Li+ “keys” would be needed to fill the N3- “locks”. Your formula becomes Li3N meaning you used 3 Li and 1 N. • • Notice in your final answer, Li3N, there are no longer + or – signs. You would write Li3N on the line for the formula and move on to the next chemical combination. Notice if you have one of something (like one N in the previous example), you do not write Li3N1, but rather Li3N. Directions: Cut out each of the puzzle pieces. Use the “puzzle pieces” to show how the various compounds bond together. 1. Use your puzzle pieces to combine the following ions to show how they make a compound. Write down the chemical formula for the final compound. Remember: Positive ion is written first, negative ion is second! Include subscripts (small numbers written below the symbol) to show the number of atoms! For example H + O would use 2 H+ ions and 1 O2- ion, so you would write H2O. H + F____________ Be + O ___________ Be + I _____________ Al + N ___________ Al + P ____________ Li + P _____________ Li + F ___________ Li + Br ___________ Ca + O ____________ Ca + S ___________ H + O ____________ Al + N _____________ Al + Br __________ K + Cl ____________ K + I ______________ Mg + S __________ K + S ____________ Rb + I _____________ Rb + Br __________ H + Cl ___________ Be + N _____________ 4 Sophomore AP Name: ______________________________________________________ Chemistry 2. What happens to the total charge of the compound after the ions bond together? (Hint: add together the charges of the ions in the compound). 3. How many lithium ions are required to bond with one nitrogen ion? Why? 4. How many chlorine ions are required to bond with one aluminum ion? Why? b. Follow Up Questions when you are finished completing your puzzle activity… i. What do you notice about the formula created when a positive ion and negative ion join together and have the same, but opposite charge? For example, Be2+ and O2- or Li+ and Br-. ii. What do you notice about the formula created when a positive ion and negative ion join together and have different, but opposite charge? For example, Be2+ and N3- or K+ and S2-. 4. KNOWLEDGE of comparing and contrasting ionic and covalent bonding. You MUST complete this section before moving onto nomenclature. a. Watch and take outline notes on the following ionic/covalent bonding videos. i. https://www.youtube.com/watch?v=CGA8sRwqIFg ii. https://www.youtube.com/watch?v=QqjcCvzWwww b. IONIC BONDING i. Between a metal and a nonmetal OR a metal with a polyatomic ion • Ex: NaCl (metal + nonmetal) or Mg3(PO4)2 (metal + polyatomic ion) ii. Transfer of electrons • Metals lose electrons and have positive charges • Nonmetals gain electrons and have negative charges • Positive and negative charges attract causing a compound to form c. COVALENT/MOLECULAR BONDING i. Between 2 or more nonmetals • Ex: HCl (nonmetal + nonmetal) or CO2 (nonmetal + nonmetal) ii. Sharing of electrons • No charges, just sharing of electrons 5 Sophomore AP Name: ______________________________________________________ Chemistry iii. Follow Up Question Are the following compounds ionic or covalent? • CaSO4 _______________________________________ • FeCl3 _______________________________________ • P2 O5 _______________________________________ • N2 O _______________________________________ • NH4Cl _______________________________________ • MgCl2 _______________________________________ • HNO3 _______________________________________ • SiO2 _______________________________________ • H2 O _______________________________________ • Al(NO3)3 _______________________________________ 6 Sophomore AP Name: ______________________________________________________ Chemistry 5. SKILL of naming ionic and covalent compounds. This process is called Nomenclature. There are different rules for naming ionic and covalent compounds. Ionic is much more challenging and diverse so we will start with those. a. Naming Monoatomic Ionic Compounds (Example: CaBr2) i. The first element is a metal and will just be called by its element name. Example: In CaBr2, Ca is pronounced “Calcium” ii. The second element is a nonmetal and will be called by its element name ending in –ide (also found on ION LIST in googledocs). Example: In CaBr2, Br2 is Bromine pronounced à “Bromide” iii. Try the following compounds • NaF ______________________________________ • CaCl2 ______________________________________ • AlF3 ______________________________________ • BaI2 ______________________________________ • KCl ______________________________________ b. Naming Polyatomic Ionic Compounds (Example: Al(NO3)3) i. The first element is a metal and will just be called by its element name. Example: In Al(NO3)3, Al is pronounced “Aluminum” ii. The second element is a nonmetal and will be called by its ion name (found on ION LIST in googledocs that you should have memorized). Example: In Al(NO3)3, (NO3)3 is “Nitrate” iii. Try the following compounds • NaNO2 ______________________________________ • CaSO4 ______________________________________ • Al(OH)3 ______________________________________ • Ba3(PO4)2 ______________________________________ • KNO3 ______________________________________ 7 Sophomore AP Name: ______________________________________________________ Chemistry c. Naming Covalent Compounds (Example: N2O3) i. Covalent compounds use prefixes to tell us how many atoms of each element are present in the compound. In N2O3 there are 2 nitrogen atoms and 3 oxygen atoms. Using the prefix list below, the compound would be named “dinitrogen trioxide” to represent 2N and 3O. • Note that the first word is simply the element name with the prefix added on and the second is the element ending in –ide (similar to ionic naming) with the prefix added on. • HELPFUL HINT- Do NOT add mono- to the first element’s name. For example CO2 is NOT monocarbon dioxide. It is carbon dioxide. ii. 1- mono 2- di 3- tri 4- tetra 5- penta 6- hexa 7- hepta 8- octa 9- nona 10- deca iii. Try the following compounds • P2O5 ______________________________________ • SiO2 ______________________________________ • PCl5 ______________________________________ • CO ______________________________________ • S2Cl4 ______________________________________ 6. Balancing Chemical Equations (Note: This may be tricky at first. KEEP TRYING! It is really fun once you get the hang of it. ) a. Watch and take outline notes on the following balancing chemical equations videos. i. https://www.youtube.com/watch?v=RnGu3xO2h74 ii. https://www.youtube.com/watch?v=UGf60kq_ZDI b. Practice balancing on this website (start with beginner and move to intermediate and advanced. The more practice the better!!! J) http://education.jlab.org/elementbalancing/ 8 Sophomore AP Name: ______________________________________________________ Chemistry c. Balance the following equations • ____S8 + ____O2 → ____SO3 • ____N2 + ____O2 → ____N2O • ____Zn + ____HCl → ____ZnCl2 + ____H2 • ____CO2 + ____H2O → ____C6H12O6 + ____O2 • ____Al + ____FeO → ____Al2O3 + ____Fe 7. Dimensional Analysis (You should have learned the basics of unit conversions Freshman year in math. You may use the factor-label method [road maps, etc] or you may solve these with whatever method you choose) If you need extra help, use resources such as youtube to find videos to help you J DIMENSIONAL ANALYSIS PROBLEMS Conversions Factors 1 hr = 60 min 1 min = 60 sec 1 ton = 2000 lbs 7 days = 1 week 24 hrs = 1 day 1 kg = 2.2 lbs 1 gal = 3.79 L 264.2 gal = 1 cubic meter 1 mi = 5,280 ft 1 kg = 1000 g 1 lb = 16 oz 20 drops = 1 mL 365 days = 1 yr 52 weeks = 1 yr 2.54 cm = 1 in 1 L = 1000 mL 0.621 mi = 1.00 km 1 yd = 36 inches 3 1 cc is 1 cm 1 mL = 1 cm3 DIRECTIONS: Solve each problem using dimensional analysis. Every number must have a unit. Work must be shown. Conversion factors are given below 1.) How many miles will a person run during a 10 kilometer race? 2.) The moon is 250,000 miles away. How many feet is it from earth? 9 Sophomore AP Name: ______________________________________________________ Chemistry 3.) A family pool holds 10,000 gallons of water. How many cubic meters is this? 4.) The average American student is in class 330 minutes/day. How many hours/day is this? How many seconds is this? 5) How many seconds are there in 1 year? 6) Lake Michigan holds 1.3 x 1015 gallons of water. How many liters is this? 7) Pepsi puts 355 ml of pop in a can. How many drops is this? How many cubic meters is this? 8) Chicago uses 1.2 x 109 gallons of water /day. How many gallons per second must be pumped from the lake every second to supply the city? 9) Sixty miles/ hour is how many ft/sec? 10) Lake Michigan holds 1.3 x 1015 gallons of water. If just Chicago removed water from the lake and it never rained again, how many days would the water last? Chicago uses 1.2 x 109 gallons of water /day 10 Sophomore AP Name: ______________________________________________________ Chemistry 11 Sophomore AP Name: ______________________________________________________ Chemistry 12 Sophomore AP Name: ______________________________________________________ Chemistry 13 Sophomore AP Name: ______________________________________________________ Chemistry 14 Sophomore AP Name: ______________________________________________________ Chemistry 15 Sophomore AP Name: ______________________________________________________ Chemistry Checklist for Summer Assignment You should have memorized: o Elements o Ion list You should have completed: o This packet and all questions o Ion Puzzle o Balancing Practice Online o Watching all videos on this packet You should bring with you on the first day of AP Chemistry: o This packet o Flashcards of elements and ions o Puzzle pieces o Notes that you took on videos o Your brain and lots of excitement!!!!! 16 List of Common Ions Monatomic Cations + Polyatomic Cations H Li+ Na+ K+ Rb+ Cs+ Ag+ hydrogen lithium sodium potassium rubidium cesium silver NH4+ H3O+ OHCNO22- hydroxide cyanide peroxide 2+ Mg2+ Ca2+ Sr2+ Ba2+ Zn2+ Cd2+ magnesium calcium strontium barium zinc cadmium 3+ Al3+ Bi3+ aluminum bismuth CO32C2O42NO2NO3PO33PO43SO32SO42S2O32ClOClO2ClO3ClO4CH3COOor C2H3O2AsO43BO33SiO32MnO4CrO42Cr2O72CHO2- carbonate oxalate nitrite nitrate phosphite phosphate sulfite sulfate thiosulfate hypochlorite chlorite chlorate perchlorate 1+ Monatomic Anions HFClBrI- hydride fluoride chloride bromide iodide 2- O2S2- oxide sulfide 3- N3P3- nitride phosphide 4- 4- 1- C (C22-) carbide ammonium hydronium Polyatomic Anions HCO3HSO3HSO4HPO42H2PO4- acetate arsenate borate silicate permanganate chromate dichromate formate hydrogen carbonate or bicarbonate hydrogen sulfite or bisulfite hydrogen sulfate or bisulfate hydrogen phosphate dihydrogen phosphate Metals with more than one ion Element Ion Classical (ous, ic) Stock system System Chromium Cr2+ Cr3+ Co2+ Co3+ Cu+ Cu2+ Fe2+ Fe3+ Pb2+ Pb4+ Mn2+ Mn3+ Mn4+ Hg22+ Hg2+ Sn2+ Sn4+ chromium(II) chromium(III) cobalt(II) cobalt(III) copper(I) copper(II) iron(II) iron(III) lead(II) lead(IV) manganese(II) manganese(III) manganese(IV) mercury(I) mercury(II) tin(II) tin(IV) Cobalt Copper Iron Lead Manganese Mercury Tin chromous chromic cobaltous cobaltic cuprous cupric ferrous ferric plumbous plumbic manganous manganic mercurous mercuric stannous stannic INFORMATION IN THE TABLE BELOW AND ON THE FOLLOWING PAGES MAY BE USEFUL IN ANSWERING THE QUESTIONS IN THIS SECTION OF THE EXAMINATION. Chemistry Practice Exam 11 Chemistry Reference Sheet Periodic Table of the Elements California Standards Test 1 1A 1 1 H Hydrogen 1.01 3 2 3 Li Beryllium 9.01 11 12 Na 6 7 Mg Sodium Magnesium 22.99 24.31 K Key 20 Ca Na Sodium 22.99 3 3B 21 Sc 4 4B 22 5 5B 23 Ti V Potassium Calcium Scandium Titanium Vanadium 39.10 40.08 44.96 47.87 50.94 38 39 Rubidium Strontium Yttrium Zirconium Niobium 85.47 87.62 88.91 91.22 55 56 57 72 Rb Cs Sr Y Hf 41 Nb 7 7B 25 8 26 Mn Fe Iron Cobalt 52.00 54.94 55.85 58.93 42 43 44 Mo Tc Ru 92.91 95.94 (98) 101.07 73 74 75 Co 45 Rh 10 28 Ni 11 1B 29 Nitrogen Oxygen Fluorine Neon 12.01� 14.01 16.00 19.00� 20.18� 14 15 16 Si P S F 17 Cl 10 Ne 18 Ar 12 2B 30 Aluminum Silicon Phosphorus Sulfur Chlorine Argon 26.98 28.09� 30.97 32.07 35.45 39.95 31 Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 65.39 69.72 72.61 74.92 78.96 79.90 83.80 52 53 Palladium Silver 102.91 106.42 107.87 76 77 78 79 49 50 51 Cadmium Indium Tin Antimony Tellurium Iodine Xenon 112.41 114.82 118.71 121.76 127.60 126.90 131.29 80 81 82 83 84 85 86 Rhenium Osmium Iridium Platinum Pt Au Gold Mercury Thallium Tl Pb Lead Bismuth Polonium Astatine Radon 132.91 137.33 138.91 178.49 180.95 183.84 186.21 190.23 192.22 195.08 196.97 200.59 204.38 207.2 208.98 (209) (210) (222) 87 88 89 104 105 106 107 108 109 Bh Hs Radium Actinium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium (223) (226) (227) (261) (262) (266) (264) (269) (268) 58 * If this number is in parentheses, then it refers to the atomic mass of the most stable isotope. Cerium 140.12 90 59 Pr Praseodymium 140.91 60 61 62 Nd Pm Sm 144.24 (145) 150.36 Neodymium Promethium Samarium 68 Er 69 Tm 70 Yb 71 Lu Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium 157.25 158.93 162.50 164.93 167.26 168.93 173.04 174.97 102 103 Neptunium Plutonium Americium Curium 232.04 231.04 238.03 (237) (244) (243) (247) Copyright © 2003 California Department of Education 67 Ho Gadolinium Uranium Pu 66 Dy 151.96 Protactinium Np 65 Tb Europium Thorium U 94 64 Gd 92 Pa 93 63 Eu 91 Th Rn Mt Francium Ce At Xe Tungsten Sg Po I 54 Sn Bi Te Kr In Hg Sb Br 36 63.55 48 Se 35 Copper Cd As 34 Nickel 47 Ge 33 58.69 46 Ga 32 Zn Rhodium Ir Al O Cu Ag Os Carbon N 4.00� Tantalum Db Re Boron 10.81 C Helium Hafnium Rf W 17 7A 9 13 Pd Molybdenum Technetium Ruthenium 16 6A 8 Lanthanum Ac Ta 9 8B 27 Cr Chromium Manganese 15 5A 7 Barium Ra La 40 Zr 6 6B 24 14 4A 6 B Average atomic mass* He 13 3A 5 Cesium Fr Ba Atomic number Element symbol Element name 11 Be 6.94 37 5 2 2A 4 Lithium 19 4 18 8A 2 95 Am 96 Cm 97 Bk 98 Cf 99 Es Berkelium Californium Einsteinium (247) (251) (252) 100 Fm 101 Md Fermium Mendelevium (257) (258) No Lr Nobelium Lawrencium (259) (262)
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