WATER IN THE SOIL Soil is a porous media composed by solid, water, and air SPATIAL CHARACTERIZATION Vadose Zone ≈ 10 cm – 100 m Capillary fringe ≈ 1 cm in Sand 10 m in Clay Vadose Zone Root Zone Unsaturated Zone Capillary Fringe Saturated Zone “Groundwater hydrology”, is historically separated by surface hydrology Unsaturated zone (≈ Vadose zone) It represents the source of moisture for vegetation. In this zone evaporation, transpiration and recharge to deeper saturated aquifers occur. It controls the separation of precipitation between infiltration into soil and surface runoff, therefore it is a “hub” for all of the hydrological processes. It is a highly non-linear system with many components (water, vapor, air) Saturated Zone Aquifer is an underground layer of water-bearing permeable rock or unconsolidated materials from which groundwater can be extracted relatively easily. Aquiclude (aquifuge) An impermeable body of rock or stratum of sediment that acts as a barrier to the flow Aquitard A rather impermeable body of rock or stratum of sediment with very low permeability. Water is mainly stored in unconsolidated porous material: Alluvial, colluvial deposits (Typical aquifers) Sandstone, Limestone, Karst formation (Fractured aquifers) Volcanic rock, shale clay (Basically impermeable) TYPICAL VALLEY SECTION Spring Perched aquifer 30-50 m Valley aquifer Soil - Porous material Fractured rock Near surface Soil ≈ 5 cm – 30 m; mainly composed of sand-silt-clay and a fraction of organic material. Greater depths Aquifers; saturated soil defined as a “body” from where water can be relatively fast and easily withdrawn. A typical aquifer is in unconsolidated material (gravel, sand, fine-sand) of alluvial or glacial origins. Fractured-rock and karst aquifers also exist and depend on the degree of fracturing. PROPERTIES OF POROUS MATERIALS s: solids v: voids w: water a: air V Va Vw Vs V SOIL POROSITY Vv V Vs Va Vw Representative Elementary Volume: A sufficiently large volume of soil containing a large number of pores, such that the concept of mean global properties is applicable but it is still small enough to be homogenous Vv n lim V 0 V Porosity Porosity is a function of particle size and rearrangement of the particles (for specific soil, such as clay or organic soil also of electrical charges) Porosity can be artificially increased and decreased (raking, ploughing, compaction, stock treading) Water content WATER CONTENT (Volumetric) Vw lim V 0 V sat Saturated Water Content ≈ n, water content at full saturation r Residual Water Content, water content that cannot be extracted through mechanical forces (e.g., from evapotranspiration or gravity); θ(dθ/dψ= 0) Water in the upper soil is generally in contact with air: θ < θsat i.e., unsaturated soil ψ : SOIL WATER POTENTIAL or SOIL WATER SUCTION or SOIL WATER TENSION [kPa] or [MPa] or [m] or [mm] Water potential is the potential energy of water per unit volume relative to pure water in reference conditions. Water potential quantifies the tendency of water to move from one area to another due to osmosis, mechanical pressure, or matric effects such as surface tension. Mechanisms for Water Retention directly related to surface tension (typically the most important), called Matric or Tension or Capillary potential. related to particle charges, particles repelling each other, called Osmotic potential chemical effect on clay particles that trap water particles (adsorption) • We consider only the matric potential (capillarity) sat 0 Soil water potential at saturation is equal or very close to zero ψ(θ): SOIL WATER RETENTION CURVE sat r Water Potential [MPa] -10 0 -10 -5 sat r Silt Sandy-Loam Clay Sand FUNCTION OF THE SOIL TYPE 0 0.1 0.2 0.3 [-] 0.4 0.5 Soil water content profile at equilibrium with water depth: S e ,i Effective saturation 1 Se DEGREE OF SATURATION S sat Depth EFFECTIVE SATURATION r Se sat r S e [0 1] Gravitational ψ = 0 kPa -/- -33 kPa Water in the soil 100 [kPa] Capillary ψ = -33 kPa -/- -3 Mpa Hygroscopic (unavailable) ψ < -3 Mpa; -10 Mpa Free aspiration, possible because the water potential is higher than absolute pressure. 1500 / 4000 33 [kPa] [kPa] Wilting point of plants. Usually plants are not able to extract water below these potentials. Wilting point is a plant dependent property. Field capacity is the the water potential that holds water in the soil. Below field capacity gravity processes (free drainage) become of minor importance. However, it is a problematic definition. At large water contents, water flows in the soil are controlled by gravity; at lower water contents capillary is the dominating process with strong negative water potentials. SOIL HYDRAULIC HYSTERISIS drying drying wetting r wetting r Wetting and drying boundary curves (main scanning curves) sat Saturation sat Satiation sat sat In experimental results and in common discussion, no distinction is made between Saturation and Satiation. While hysteresis may be important and influence hydrological behavior, it is difficult to model numerically and it is typically not accounted for. FUNCTION FOR SOIL WATER RETENTION CURVES b S e 1 0 Brooks and Corey, 1964 The parameters are dependent on the soil type b [kPa] Air entry soil water potential 1 1 S e m 1 Parameters: 1 n 0 [-] Pore-size distribution parameter van Genuchten, 1980 1 m 1 n n [-] [kPa-1] INSTRUMENTS The are several geophysical methods to measure soil water content in the field, The most common soil moisture probes are using the Time-domain reflectometry, TDR, principle. The instrument to measure water potential is called “tensiometer” but typically works at relatively high water potentials (> -200/-400 kPa) WATER TRANSPORT IN THE SUBSURFACE The flow generally depends on water-vapor interactions, gravity and capillarity forces, temperature gradients, but typically many of these complications are not accounted for. Darcy’s law is derived for saturated, homogenous, isothermal, isotropic media in a steady-state DARCY’s LAW [1856] K sat Ah3 h4 t Vol L Hydraulic Head h z Gravity + Soil water potential Darcy’s Law is generally expressed for unit area and in differential infinitesimal terms in the vertical direction: q K sat h z [m/s] or [mm/h]; Discharge per unit area v q z Real average velocity of the flow Ksat = saturated hydraulic conductivity [m/s] or [mm/h] More general when the system is tri-dimensional and anisotropic: q K h q [q x , q y , q z ] h: scalar [ , , ] x y z K x,x K sat K y , x K z , x K x, y K y, y K z, y K x,z K y ,z K z , z Principal axes: h q x K xx x h q y K yy y h q z K zz z Darcy Law is an empirical generalization of the flow equation for laminar flow on regular surfaces (e.g., Hagen–Poiseuille law); where viscous forces are comparable with inertial forces, small Reynolds numbers (Re). gd 2 h q 32 x q K sat h z Linear dependence of “flow” on gradients of hydraulic head. Ksat = saturated hydraulic conductivity = function of fluid and pore size distribution (porous media) Isotropic: KH = Kv Anisotropic: KH ≠ Kv Equal or different properties in different directions aR KH KV Anisotropy ratio Homogenous: K 0 z Heterogeneous: K 0 z Spatial variability of the properties Averaging of hydraulic conductivity it depends on the geometrical composition of the soil block and direction of flow (serial or parallel) z1 z2 K1 K2 K1 z1 K 2 z2 KH z1 z 2 Simple Mean z1 z 2 KV z1 z2 K1 K 2 Harmonic Mean Hydraulic conductivity depends on domain size (it typically increases for larger areas) this is due to: •Macropores •Preferential paths •Spatial variability of properties •Regions of low K can be by passed Extension of Darcy’s Law to unsaturated flow (Buckingham, 1907) K K Unsaturated hydraulic conductivity – Partially saturated hydraulic conductivity As soil dries the connections between pores become irregular and discontinuous θ ↓ K↓; Less connections, less water in the pores, more tortuous paths. At higher water contents, K decreases more rapidly because larger pores are the first to get empty. Almost all the water flow is transferred through big-pores. This relationship is not hysteretic. K K sat Unsaturated Conductivity K [mm h -1] FUNCTION OF THE SOIL TYPE 10 0 10 -5 10 -10 Silt Sandy-Loam Clay Sand 0 0.1 0.2 0.3 [-] 0.4 0.5 SOIL HYDRAULIC CONDUCTIVITY CURVES K K sat S 2 3 e 0 K K sat S e 1 1 S 0.5 Brooks and Corey, 1964 2 1/ m m e Parameters are soil type dependent van Genuchten, 1980 VALUES OF HYDRAULIC CONDUCTIVITY K sat In Soil: 0.1 -500 [mm/h] Gravel: 1 [m/s] Rocks: 10-8 – 10-9 [m/s] 10-7 10-6 10-5 10-4 10-3 10-2 10-1 100 101 102 103 [mm/h] 104 105 DARCY-BUCKINGHAM LAW (Unsaturated soil) q K h Principal axes: h z x q y K yy y q z K zz K zz z q x K xx Diffusion Formulation of Darcy Law q K h D K d d q K K z Soil Diffusivity q D K z Conservation of Mass (Continuity Equation) + Conservation of Momentum (Flow law = Darcy Law) = RICHARDS EQUATION dV dxdydz q z qz dz z qy qx q y y dy q x qx dx x qy qz Mass Conservation in the dV M w dV t t RICHARDS EQUATION (1931) Conservation of mass: q x w q x dydy w q x dx dydz ... w dV x t q x q y q z x y z t Flow equation: q K h q t K h t RICHARDS EQUATION (1931) K h t K K z t For isotropic, homogenous media in the vertical direction K 1 t z z Equation that governs variably saturated subsurface flow No general analytical solution is available Solutions of Richards equation are demanding from a computational point of view (it is a non-linear partial differential equation) Numerical models are used to solve Richards equation (e.g., Hydrus-1D) EXAMPLES 1 2 1 2 After some time Horizontal 1 1 1 2 dz 2 1 2 dz 1 2 After some time 2 1 1 2 dz 1 2 2 Vertical PREFERENTIAL FLOW Dual porosity – dual permeability model (Gerke and van Genuchten, 1993, 1996) 1-wf Km Vf/Vt = wf ≈ 0.01-0.05 Kf Γw Exchange term: w aw f m f f w K f 1 t z z wf m w m K m 1 t z z 1 wf Mass transfer coefficient: [1 / h] aw aw K as , m , f K m , K f , sat , f , sat ,m , r ,m , f , m , n f , nm , w f , K as Increasingly difficult to parameterize and to resolve numerically [1 / mm h] EXAMPLE: PREFERENTIAL FLOW Ponded surface for 12 hours – clay-loam soil 0 -50 Time evolution: every 2 hours Depth Depth[mm] (mm) -100 -150 -200 No Preferential flow -250 Preferential flow -300 0.25 0.3 0.35 0.4 [-] θ [-] 0.45 0.5
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