The Lages Pintadas aquamarine deposits, ENE Brasil: a new gem province a new model Estudosand Geológicos v. 14: 54-61 THE LAGES PINTADAS AQUAMARINE DEPOSITS, ENE BRASIL: A NEW GEM PROVINCE AND A NEW MODEL A. Bhaskara Rao 1 Claudio de Castro 2 Maria S. Adusumilli 3 Sandra de B. Barreto 4 1 In memorium GRM, Institute of Geosciences, University of Brasília, Brasília, Brasil 2 Dept of Mining Engineering, UFPE,Recife, Brasil. 3 GMP, Institute of Geosciences, University of Brasília, Brasília, Brasil 4 Dept of Geology, Federal University of Pernambuco, Recife, Brasil, [email protected] RESUMO O domínio pegmatitico granítico da Provincia Borborema é um dos mais ricos em mineralização das províncias pegmatíticas brasileiras. Uma província com gemas de água marinha e outra com gemas de turmalina foram definidas por Baskara Rao et al, (1998), ao sul da cidade de Parelhas no ENE do Brazil. Estas províncias são caracterizadas pelos seus condicionamentos geológicos, litológicos e estruturais, respectivamente, em um sinforme desenvolvido por biotita xistos e um antiforme desenvolvido em quartzitos micaceous bandados. Os pegmatitos mineralizados foram abandonados e somente agora estão retomando sua exploração, ainda de forma esporádica, com a localização de bolsões de gemas, o que resulta em oscilação na produção de gemas de água marinha e turmalina na região. A região de Lages Pintadas, NW de Santa Cruz, possui pegmatitos encaixados em migmatitos-ganissicos de idade Arqueana, complexo migmatitico-gneissico (TTG ?) com cristais excelentes e grandes fragmentos de água marinha com coloração azul. Elas são excelentes para fins de lapidação e propiciam bom retorno financeiro. As condições geológicas, posicionamento estrutural e controle litológico e a mineralização associada a veios de pegmatito/quartzo favorecem a definição de um novo modelo e de uma nova província. Palavras-chave: Província Borborema, pegmatitos, Lages Pintadas, água marinha, turmalina. ABSTRACT Granitic pegmatite domain of the Borborema Structural Province is one of the most mineralized of the Brazilian pegmatite provinces. One aquamarine gem province and one tourmaline gem province have been defined by Baskara Rao et al, (1998), south of the town of Parelhas in ENE Brazil. They are characterized their geological, lithological, and structural conditioning, respectively in the biotite schist dominated synform, and banded micaceous quartzite antiform. The mineralized pegmatites where abandoned and now are beginning to be reworked, sporadically, with the occurrence of gem pockets which result in an osci1lating gem production of aquamarines and tourmalines in the region. The Lages Pintadas area, NW of Santa Cruz, has pegmatites hosted in Archean migmatitic-gneissic complex (TTG ?) with excellent crystals and large fragments of aquamarines with pleasant water blue color and hue. They are excellent for lapidary purposes and fetch good to high returns. The geological conditioning, structural positioning, lithological controls and pegmatite/quartz vein type mineralization permit the denomination of a new model and also a new province. Keywords: Borborema Province, pegmatites, Lages Pintadas, aquamarine, tourmaline. Estudos Geológicos v. 14, 2004 54 IniciaisEstudosGeologicosOk.p65 54 29/6/2005, 09:00 Bagaço dez A. Bhaskara Rao et al INTRODUCTION The first Aquamarine Gem Pegmatite (AGP) province in ENE Brazil is defined from Acari, in the State of Rio Grande do Norte to São José do Sabugi in the State of Paraíba, including seven recognized aquamarine gem deposits. They are conditioned to a regional synform constituted of Neoproterozoic biotite schists with intense structural deformation due to squeezing. Small granitic stocks and granitic pegmatite fi1lings intrude them. The pegmatites are K- feldspar and quartz rich, poorly zoned and poorly mineralized, often with two generations of beryl. The first generation is opaque with occasional nucleus of aquamarine, the other is characterized by gem crystals embedded in quartz veins (Baskara Rao et al, 1998). Samples of aquamarine from gem pockets of the Lages Pintadas area, State of Rio Grande do Norte, were obtained where large quantities of opaque beryl continues to be recovered. Besides being geographica1ly disconnected from the first AGP province, the geological conditioning is also different. In this study we present and discuss this new mode of occurrence and propose the denomination of a new province. LOCATION Santa Cruz is located at 80 km from the city of Natal, following the highway to Currais Novos. Lages Pintadas (36° 7' W, 6° 9' S) is a small town located 16 km NW of Santa Cruz with good access. Within a radius of 10 km, numerous pegmatite fillings occur as dykes, veins or smal1 pods. Four have been catalogued as having produced or produ- cing aquamarines. All pegmatites have been worked in the past and are now reworked. The following pegmatites were visited by the authors: § Tapera: Small scale mining activity stil1 contributing to the recovery of some gems. § Bom Destino: Abandoned, and occasionally reworked. Reports show that it produced good quality colored gems. § Ramal: Abandoned, and occasionally reworked. GEOLOGICAL CONDITIONING The geological setting and the structural aspects of the locality are summarized in figure 01, from the geological map of the State of Rio Grande do Norte in the scale of 1:500.000. (DNPM & UFRN 1998). Geologically the area is situated in the Archean migmatitic-gneissic complex, dominated by a variety of porphyritic (Ab-K feldspar) and banded migmatites with dark bands and/or stringers of mafics constituted of homblende and biotite. They are sutured by a foliation with variation between N-S and NNE-SSW due to the elongated monzonite-granodiorite intrusion showing also an NE-SW trend. Intense folding is observed, characterized by anticlines, isoclines, local ruptures and overturned folds, and evidenced by the horizontal foliation of the gneisses. The region has suffered intense weathering resulting in altered gneisses and regolith soils showing scanty vegetation with small elevations, with the exception of intrusive bodies. 55 Estudos Geológicos v. 14, 2004 IniciaisEstudosGeologicosOk.p65 55 29/6/2005, 09:00 Bagaço dez The Lages Pintadas aquamarine deposits, ENE Brasil: a new gem province and a new model Figure 1 - Geologic context of the Aquamarine deposits of Lages Pintadas - Rio Grande do Norte LOCAL GEOLOGY The local geological aspects are presented in table 1. Table 1- Local Geological Sequence. Estudos Geológicos v. 14, 2004 56 IniciaisEstudosGeologicosOk.p65 56 29/6/2005, 09:00 Bagaço dez A. Bhaskara Rao et al The general structural pattern is restricted to the foliation in NNE-SSW trend, varying to N-S due to the intrusions, during a deformational event characterized by recumbent, isoclinal folds and thrusts faults imprinting schistosity and banding in granitoids and in gneissic-migmatitic complex. Some transcurrent shear zones were also mapped. Four aquamarine occurrences in the Archean and one in the porphyritic granitoid suite are represented in the geological map of the State of Rio Grand do Norte. They are controlled by the NNE-SSW foliation. Previously considered as flebitic migmatite by Adusumilli & Bhaskara Rao, (1968) these bodies are now classified as granodioritic-monzonitic banded and porphyritic gneisses (or TfG gneissic complex), of Archean age. They show the following characteristics: § porphyritic gneiss, with porphyroblasts of white albite, and occasionally red K-feldspar, with bands and/ or stringers of biotite and hornblende, with medium to fine grained matrix of extremely compact and hard nature, submitted to intense deformations, resulting in the fracturing of feldspar porphyroblasts. Sizes: Length 30, breadth 10m, and depth to 15 m. Host rock: Granodiorite- monzonite gneiss. Topographically the terrain is denuded, not similar to the biotite schist degradation, but with some small and accessible elevations, as a resultant of resistant regional gneiss. MINERALOGY Similar to the other aquamarine gem pegmatites (AGP), the ones studied in this region are also poor in their mineralogical content and variation. They commonly present the following mineralogy: Quartz occurrs as independent veins, or as part of pegmatites. These crystals are characterized by its colorless, smoky and rose varieties. The association of rose quartz in the pegmatites or in the quartz veins, seems to characterize them as mineral guide for aquamarine deposits. The smoky variety hosts independent crystals of aquamarine gems. K-feldspar occur as coarse to fine bands or veins of light-red microcline dominating OCCURRENCE The aquamarine occurs associated with veins and dykes of granitic pegmatites and quartz veins. They are usually thin with few centimeters to metric dimensions, outcropping in a terrain degraded showing low relief of the resistant litho- types. The mined areas are both old, and always targets for reworking. They are small and could be generalized as follows: MINERALIZED ROCKS The mineralized rocks are granitic pegmatites and quartz veins. Pegmatites: composed dominantly by K-feldspar and quartz. Commonly they are not zoned, but show bands of K-feldspar and quartz veins, intercalated, giving the aspect of a pegmatite vein. Their grain size is very variable, depending on the thickness of the bands and veins, and occasiona1 aplitic nature. Quartz veins: Thin to medium sized, colorless, milky, smoky and rose quartz veins, are recorded. The smoky quartz vein is coarse-grained, fractured and has light grey to shady smoky in color. A1ong the fractures, excellent hexagonal prisms of aquamarine crystals wit sizes up to 2 cm are obtained. Their transparency, color and hue are of good quality. They show basal partings, occasionally causing horizontal color zoning. Some crystals also show simple vertical color zoning, with the nucleus lighter in hue probably due to depletion in Fe. 57 Estudos Geológicos v. 14, 2004 IniciaisEstudosGeologicosOk.p65 57 29/6/2005, 09:00 Bagaço dez The Lages Pintadas aquamarine deposits, ENE Brasil: a new gem province and a new model the pegmatites. These bands host thick to giant prismatic crysta1s of opaque, grassy green beryl. Beryl crystals are opaque green and represent an economic product from these pegmatites. It can grow up to100 x 30 cm, but also occurs as smal1 prismatic crystals in the feldspar zone of the pegmatites, and normal1y have a coating of Mn-oxides and hydroxides. Some small opaque crystals show a substitution resulting in the gem variety, along the nucleus. This is usually restricted to the Si-rich part of the pegmatite, or exclusively to quartz veins. The main accessory minerals are tourmalines, mainly elbaites, well developed crystals up to centimetric in size, biotite flakes, and muscovite are also recorded. The tourmaline crystals are fractured, and are found more frequently in the feldspar zone. GENETIC ASPECTS Earlier studies of the on aquamarine deposits in the region are summarized below, and they are basically in consonance with genetic considerations for these occurrences. The works of Barton (1986), Ricca & Berger (1996), and Evensen et al. (1999) were used to formulate the following ideas to explain the evolution of the gem beryl in ENE Brazil. 1 – The opaque beryl has crystallized at high temperature magmatic-pegmatitic phase. Evensen et al. (1999) show that beryl bearing pegmatites are commonly peraluminous in composition. This mineral assemblage beryl + chrysoberyl + quartz may be relevant to the magmatic portion of their crystallization. But, in natural systems, the back reaction may occur: AQUAMARINES The gems obtained in this region find market easily principal1y due to their color and sizes. The characteristics of the aquamarines are shown in Table 2. 3BeAl2O4 + 2 KAlSi3O8 + 6 SiO2 = Chrysoberyl Potash feldpar Quartz Be2Al2Si6OI8 + 2 KAl3Si3O10(OH)2 (1) Beryl Muscovite Table 2 – Characteristics of the Aquamarines. Estudos Geológicos v. 14, 2004 58 IniciaisEstudosGeologicosOk.p65 58 29/6/2005, 09:00 Bagaço dez A. Bhaskara Rao et al This leaves beryl as a predominant mineral. The assemblage chrysoberyl + beryl + phenakite is not expected in quartz saturated systems, viz. granitic pegmatites, which contain all important “magmatic” Be-phases. 2 – Baskara Rao et al. (1999) consider the evolution of the second phase, resulting in the aquamarines, in the following manner. § § § Active hydrothermal fluids, under high pressure traversed the first phase opaque beryls. Along the channel structure, some chemical elements were destabilized, mobilized and ionic alkaline elements were left (Baskara Rao et al., 1997); Fluid inclusions, as “bottles” (Barton, 1986) were also left as trails; Magneto-hydrodynamic motivated complex physical mechanisms, such as the formation of knotted and linked structure for the fluid flow, must have resulted in the interaction and linking of two elliptical ring movements (Ric- § § ca & Berger ,1996); This movement of the fluids resulting in the mobility of the ions and their migration along the nucleus might have contributed to the generation of the clear gem variety; The isolated presence of gem beryl in quartz vein is probably conditioned to the enrichment of silica in the fluid system, intensifying (?) the process of flow mechanisms that permit the growth of gem variety in the SiO2 rich environment. (Baskara Rao et al., 1999) promoting ideal physical conditions, as detailed above. EXPLORATION PARAMETERS A comparative study of both the AGP’s of the region is shown with similarities and differences (Table 3), including exploration guides. A follow-up with ground penetration radar (GPR) should be very useful in detecting gem pockets, leading to the exploration work economically feasible for exploitation. Table 3: Comparison of the Two Aquamarine Gem Provinces in ENE Brazil 59 Estudos Geológicos v. 14, 2004 IniciaisEstudosGeologicosOk.p65 59 29/6/2005, 09:00 Bagaço dez The Lages Pintadas aquamarine deposits, ENE Brasil: a new gem province and a new model NEW AQUAMARINE GEM PEGMATITE MODEL The present study reveals new aspects charactering different geological condition and thus confirms the Lages Pintadas as a new model. This is another aquamarine gem pegmatite province, totally distinct in, geographic placement and structural positioning that, characterize it as another AGP Province. Thus, the Lages Pintadas is a new AGP in ENE Brazil, and the established genetic and exploration parameters could be useful for the location of other occurrences in the region. CONCLUSION The important conclusions of this study are: § The aquamarines obtained from this Archean migmatite-gneissic ambient hosted pegmatites are more colored than those located in the Neoproterozoic biotite schists. They also have better sizes, § § ACKNOWLEDGEMENTS Thanks are due to Rao’s Ideas Bank, who arranged a sponsor for our field travels towards R & D works; and to Mr. José Oliveira de Nóbrega, whose information on the localities proved valuable and who also provided some gem samples. Estudos Geológicos v. 14, 2004 60 IniciaisEstudosGeologicosOk.p65 § and together with their transparency and uniform hue, become more attractive. The host rock is highly weathered favoring a better and an easy recovery of the gem stones without much damage during mining. These conditions associated with good quality imply in higher prices for the gems, and assured market and economic returns. Thus, the program of the government of the State of Rio Grande do Norte (REN, 1998), and the Ministry of National integration should give more attention to the gem projects in order to stimulate the gem industry. 60 29/6/2005, 09:00 Bagaço dez A. Bhaskara Rao et al REFERENCES Adusumilli, M.S. & Bhaskara Rao, A., 1968. Considerações sobre os migmatitos do Nordeste. I. Classificação, Nomenclature e exemplos – Jor. De Mineral, Vol.VI, p.61-81. Adusumilli, M.S.& Bhaskara Rao. A, 1991. Small Scale Mining in Brazilian Pegmatites: Mineralogy and Economic Importance. In: Small Scale Mining- An Overview. Arem, J.E., 1987. Color Encyclopaedia ofGemstones. Van Nostrand Reinhold, New York. A.K. Ghose-Editor. Oxford Publ. Co. New Delhi. 1994. p. 301-324. Barton, M.D., 1986. Phase equilibria and thermodynamic properties of mineraIs in the BeO-Al2O3-SiO2-H2O (BASH) system, with petrologic applications. Amer. Mineral, Vol. 71, p.277-300. Bhaskara Rao, A, Adusumilli, M.S., & Castro, C., 1996. Diagnostic Characteristics of the Aquamarine deposit of Canoas, Acari, RN State, Brazil. 39 Congr. Brasil. Geol., Salvador. ResumosErpandidos, p.197-200. Bhaskara Rao, A., Adusumilli, M.S., & Castro, C., 1997. Evolution and exploration parameters of gem beryls from Varzea do Serrote Pegmatite, RN State, Brazil. XVII Simp. Geol. Nordeste, Soc. Brasil. Geol., Fortaleza. ResumosExpandidos, Bol.15, p.414-418. Bhaskara Rao, A., Adusumilli, M.S., & Castro, C., 1998. Geological and Exploration Chracteristics of an Aquamarine Gem Pegmatite Sub-Province in ENE Brazil. IMA 98, Toronto, Abstracts, p. AI7. Poster 18pp. Bhaskara Rao, A., Adusumilli, M.S. & Castro, C., 1999. Genetic and exploration aspects of Serrote do Meio Aquamarine Pegmatites near Parelhas, ENE Brazil. (Communicated). Brisbin, W. C., 1986. Mechanics of pegmatite intrusion. Amer.Mineral, Vol.71, p.644-651. DNPM & UFRN., 1998. Mapa Geologico do Estado do Rio Grande do Norte.DNPM, Recife. Evensen, J.M., London, D. & Wendlandt, R.F., 1999. Solubility and stability of beryl in granitic melts. Amer. Mineral, Vol.84, p.733-745. REN., 1998. Programas do Desenvolvimento do Estado do Rio Grande do Norte na Area de Geologia e Mineração. Governo do Estado, Natal. Ricca, R.L., & Berger, M.A., 1996. Topological Ideas and Fluid Mechanics. Physics Today, Vol.49 (12), p. 28-34. 61 Estudos Geológicos v. 14, 2004 IniciaisEstudosGeologicosOk.p65 61 29/6/2005, 09:00 Bagaço dez
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