Safety Data Sheet
Potassium Chlorate Crystal, ACS
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: Potassium Chlorate Crystal, ACS
Synonyms/Generic Names: None
Product Number: 4225
Product Use: Industrial, Manufacturing or Laboratory use
Manufacturer: Columbus Chemical Industries, Inc.
N4335 Temkin Rd.
Columbus, WI. 53925
For More Information Call: 920-623-2140 (Monday-Friday 8:00-4:30)
In Case of Emergency Call: CHEMTREC - 800-424-9300 or 703-527-3887 (24 Hours/Day, 7 Days/Week)
2. HAZARDS IDENTIFICATION
OSHA Hazards: Oxidizer, Toxic by inhalation, Harmful by ingestion.
Target Organs: Blood, Liver, Kidney
Signal Words: Danger
Pictograms:
GHS Classification:
Oxidizing solids
Acute toxicity, Oral
Acute toxicity, Inhalation
Acute aquatic toxicity
Chronic aquatic toxicity
Category 1
Category 4
Category 4
Category 2
Category 2
GHS Label Elements, including precautionary statements:
Hazard Statements:
H271
May cause fire or explosion; strong oxidizer.
H302+H332
Harmful if swallowed or if inhaled.
H411
Toxic to aquatic life with long lasting effects.
Precautionary Statements:
P210
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P220
Keep/Store away from clothing and other combustible materials.
P221
Take any precaution to avoid mixing with combustibles.
Revised on 01/29/2015
Page 1 of 6
P261
P264
P270
P271
P273
P280
P283
P301+P312
P304+P340
P306+P360
P312
P330
P370+P378
P371+P380+P375
P391
P501
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wash hands thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
Wear fire/flame resistant/retardant clothing.
IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON CLOTHING: Rinse immediately contaminated clothing and skin with
plenty of water before removing clothing.
Call a POISON CENTER/doctor/physician if you feel unwell.
Rinse mouth.
In case of fire: Use appropriate media to extinguish.
In case of major fire and large quantities: Evacuate area. Fight fire remotely
due to the risk of explosion.
Collect spillage.
Dispose of contents/container in accordance with local regulations.
Potential Health Effects
Eyes
May cause eye irritation.
Inhalation
Toxic if inhaled. May cause respiratory tract irritation.
Skin
Harmful if absorbed through skin. May cause skin irritation.
Ingestion
Harmful if swallowed.
NFPA Ratings
Health
Flammability
Reactivity
Specific hazard
HMIS Ratings
Health
Fire
Reactivity
Personal
3
0
2
OX
3
0
2
J
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component
Weight %
CAS #
EINECS# /
ELINCS#
Formula
Molecular
Weight
Potassium Chlorate
>98
3811-04-9
223-289-7
KClO3
122.55 g/mol
4. FIRST-AID MEASURES
Eyes
Inhalation
Skin
Ingestion
Rinse with plenty of water for at least 15 minutes and seek medical attention immediately.
Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not
breathing, give artificial respiration. Get medical attention immediately.
Gently brush loose chemical off of skin. Flush with plenty of water for at least 15 minutes while
removing contaminated clothing and wash using soap. Get medical attention immediately.
Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If
conscious, wash out mouth with water. Get medical attention immediately.
Revised on 01/29/2015
Page 2 of 6
5. FIRE-FIGHTING MEASURES
Suitable (and unsuitable)
extinguishing media
Special protective equipment
and precautions for firefighters
Specific hazards arising from
the chemical
Use alcohol-resistant foam, dry chemical, or carbon dioxide. In case of
major fire and large quantities: Evacuate area.
Wear self-contained, approved breathing apparatus and full protective
clothing, including eye protection and boots.
Oxidizer! Fight fire remotely due to the risk of explosion. Emits toxic
fumes (potassium oxides, hydrogen chloride gas) under fire conditions.
(See also Stability and Reactivity section).
6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
Environmental precautions
Methods and materials for
containment and cleaning up
See section 8 for recommendations on the use of personal protective
equipment.
Prevent spillage from entering drains. Any release to the environment
may be subject to federal/national or local reporting requirements.
Pick up and arrange disposal without creating dust. Sweep up and
shovel. Clean surfaces thoroughly with water to remove residual
contamination. Dispose of all waste and cleanup materials in accordance
with regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
See section 8 for recommendations on the use of personal protective equipment. Use with adequate
ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts
and aerosols. Keep away from sources of ignition – No smoking. Strong oxidizer.
Conditions for safe storage, including any incompatibilities
Store in cool, dry well ventilated area. Keep away from incompatible materials (see section 10 for
incompatibilities).
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational exposure controls: Contains no substances with occupational exposure limit values.
Personal Protection
Eyes
Wear chemical safety glasses or goggles.
Inhalation
Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an
approved respirator.
Skin
Wear nitrile or rubber gloves, apron or lab coat.
Other
Not Available
Other Recommendations
Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and
handling.
Revised on 01/29/2015
Page 3 of 6
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance (physical state, color, etc.)
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or explosive limit
Vapor pressure
Vapor density
Density
Solubility (ies)
Partition coefficient: n-octanol/water
Auto-ignition temperature
Decomposition temperature
Colorless to white crystalline solid.
Not Available
Not Available
5.0 - 6.5 at 61.3 g/L at 25°C (77°F)
356°C (673°F)
Not Available
Not Flammable
Not Available
Not Flammable
Not Flammable
Not Available
Not Available
3
2.320 g/cm
Completely soluble in water.
Not Available
Not Available
Not Available
10. STABILITY AND REACTIVITY
Chemical Stability
Possibility of Hazardous Reactions
Conditions to Avoid
Incompatible Materials
Hazardous Decomposition Products
Stable
Will not occur.
Flammable materials, sources of ignition.
Strong reducing agents, powdered metals, strong acids, alcohols,
organic materials.
Hydrogen chloride gas, potassium oxides.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Potassium Chlorate
Skin
LD50 Dermal - rat - male and female - > 2,000 mg/kg
Eyes
Eyes – rabbit – Mild eye irritation.
Respiratory
LC50 Inhalation - rat - male and female - 4 h - > 5.1 mg/l
Ingestion
LD50 Oral - rat - 1,870 mg/kg
Carcinogenicity
IARC
No components of this product present at levels greater than or equal to 0.1% is identified
as probable, possible or confirmed human carcinogen by IARC.
ACGIH
No components of this product present at levels greater than or equal to 0.1% is identified
as a carcinogen or potential carcinogen by ACGIH.
NTP
No components of this product present at levels greater than or equal to 0.1% is identified
as a known or anticipated carcinogen by NTP.
OSHA
No components of this product present at levels greater than or equal to 0.1% is identified
as a carcinogen or potential carcinogen by OSHA.
Signs & Symptoms of Exposure
Skin
Irritation, itching, redness, burning
Eyes
Irritation, itching, redness, burning.
Respiratory
Burning, coughing, wheezing, laryngitis, shortness of breath, headache.
Ingestion
Burning, nausea, vomiting, diarrhea, anemia, hemorrhage, convulsions.
Revised on 01/29/2015
Page 4 of 6
Chronic Toxicity
Teratogenicity
Mutagenicity
Embryotoxicity
Specific Target Organ Toxicity
Reproductive Toxicity
Respiratory/Skin Sensitization
Not Available
Not Available
Not Available
Not Available
Absorption into the body leads to the formation of methemoglobin which
in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4
hours or longer.
Not Available
Not Available
12. ECOLOGICAL INFORMATION
Ecotoxicity
Aquatic Vertebrate
Aquatic Invertebrate
Terrestrial
Other
LC50 – Oncorhynchus mykiss (rainbow trout) – 1.750 mg/l – 96.0 hours.
EC50 – Daphnia magna (water flea) – 1,093 mg/l – 24 hours
Not Available
static test EC50 - Nitzschia closterium - 2.8 mg/l - 72 h
Persistence and Degradability
Bioaccumulative Potential
Mobility in Soil
PBT and vPvB Assessment
Other Adverse Effects
Not Available
Not Available
Not Available
Not Available
Toxic to aquatic life with long lasting effects.
13. DISPOSAL CONSIDERATIONS
Waste Residues
Product
Containers
Users should review their operations in terms of the applicable federal/national or
local regulations and consult with appropriate regulatory agencies if necessary before
disposing of waste product container or residue.
Users should review their operations in terms of the applicable federal/national or
local regulations and consult with appropriate regulatory agencies if necessary
before disposing of waste product container.
The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may
significantly change the characteristics of the material and alter the waste classification and proper disposal
methods.
14. TRANSPORTATION INFORMATION
US DOT
TDG
IMDG
Marine Pollutant
IATA/ICAO
Revised on 01/29/2015
UN1485, Potassium chlorate, 5.1, pg II
UN1485, POTASSIUM CHLORATE, 5.1, PG II
UN1485, POTASSIUM CHLORATE, 5.1, PG II
No
UN1485, Potassium chlorate, 5.1, pg II
Page 5 of 6
15. REGULATORY INFORMATION
TSCA Inventory Status
DSCL (EEC)
California Proposition 65
SARA 302
SARA 304
SARA 311
SARA 312
SARA 313
WHMIS Canada
All ingredients are listed on the TSCA inventory.
All ingredients are listed on the DSCL inventory.
Not Listed
Not Listed
Not Listed
Reactivity Hazard, Acute Health Hazard, Chronic Health Hazard
Reactivity Hazard, Acute Health Hazard, Chronic Health Hazard
Not Listed
Class C: Oxidizing material.
16. OTHER INFORMATION
Revision
Date
Revision 1
01-10-2013
Revision 2
01/29/2015
Disclaimer: Columbus Chemical Industries, Inc. (“Columbus”) believes that the information herein is factual but is not intended to be all
inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other
materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus
has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current
information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal,
state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION)
WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED
HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE.
Revised on 01/29/2015
Page 6 of 6