Contents Eligible Texas Essential Knowledge and Skills Correlation Chart . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 TEKS Chapter 1 Properties of Matter . . . . . . . . . . . . . . . . . . . . . . . . . 13 Lesson 1 States of Matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 C.4C Lesson 2 Physical and Chemical Properties . . . . . . . . . . . . . . . . 20 C.4A, C.4B Lesson 3 Pure Substances and Mixtures . . . . . . . . . . . . . . . . . . 28 C.2E, C.2H, C.4D Chapter 1 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Chapter 2 The Atom . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Lesson 4 The Development of Atomic Theory . . . . . . . . . . . . . . 40 C.2A, C.3F, C.6A Lesson 5 Electromagnetic Radiation and the Bohr Model . . . . . 48 C.2G, C.3C, C.6A, C6.B, C.6C Lesson 6 Atomic Structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 C.2G, C.6A, C.6D Lesson 7 Electron Configurations . . . . . . . . . . . . . . . . . . . . . . . . 62 C.6E Chapter 2 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 Chapter 3 The Periodic Table . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 Lesson 8 The Organization of the Periodic Table . . . . . . . . . . . 78 C.5A, C.5B Lesson 9 C.5C Periodic Trends . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Chapter 4 Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99 Lesson 10 Chemical Bonding . . . . . . . . . . . . . . . . . . . . . . . . . . 100 C.2G, C.7C, C.7D Lesson 11 Ions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112 C.7B Lesson 12 Chemical Formulas and Compound Names . . . . . . 117 C.7A, C.7B Lesson 13 VSEPR Theory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123 C.7E Chapter 4 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Chapter 5 Chemical Calculations . . . . . . . . . . . . . . . . . . . . . . . 137 Lesson 14 Calculations Involving Chemical Composition . . . . . 138 C.2G, C.8A, C.8B, C.8C Lesson 15 Balancing Chemical Equations . . . . . . . . . . . . . . . . . 144 C.2G, C8.D Lesson 16 Calculations Involving Chemical Reactions . . . . . . . . 149 C.2G, C.3D, C.3E, C.8E Chapter 5 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157 Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC Chapter 3 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94 4 592TX_Sci_Chem_SE_PDF Round.indd 4 06/08/13 4:28 PM TEKS Chapter 6 Gases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163 Lesson 17 Gas Laws . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 C.1A, C.1B, C.2E, C.2F, C.2G, C.2H, C.2I, C.3E, C.3F, C.9A, C.9B Lesson 18 Kinetic Molecular Theory of Gases . . . . . . . . . . . . . 176 C.2B, C.2C, C.2D, C.9C Chapter 6 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 Chapter 7 Solutions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 185 Lesson 19 Properties of Water . . . . . . . . . . . . . . . . . . . . . . . . . . 186 C.10A Lesson 20 C.10B, C.10C, C.10D, Properties of Solutions . . . . . . . . . . . . . . . . . . . . . . . 192 C.10E, C.10F Lesson 21 Acids and Bases . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 C.1A, C.1B, C.1C, C.2E, C.2F, C.2G, C.2H, C.7B, C.10G, C.10I, C.10J Lesson 22 Reactions in Aqueous Solutions . . . . . . . . . . . . . . . . 213 C.10H Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC Chapter 7 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224 Chapter 8 Energy Changes . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 Lesson 23 Energy and Its Forms . . . . . . . . . . . . . . . . . . . . . . . . 234 C.11A. C.11B Lesson 24 Heat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240 C.3C, C.11D Lesson 25 Endothermic and Exothermic Reactions . . . . . . . . . . 251 C.11C, C.11E Chapter 8 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259 Chapter 9 Nuclear Chemistry . . . . . . . . . . . . . . . . . . . . . . . . . . 265 Lesson 26 Radioactivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266 C.3D, C.12A, C.12B Lesson 27 C.3A, C.3B, C.3D, C.12C Fission and Fusion . . . . . . . . . . . . . . . . . . . . . . . . . . 274 Chapter 9 Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 281 Investigations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 285 Investigation 1 Identifying Unknown Solutions . . . . . . . . . . . . . . 285 C.1A, C.1B, C.1C, C.2B, C.2C, C.2E, C.2F, C.7A, C.7B, C.10B, C.10H Investigation 2 Determining the Oxidation Number of Copper . . . . . . . . . . . . . . . . . . . . . . . 299 C.1A, C.1B, C.1C, C.2E, C.2F, C.2G, C.7A, C.7B, C.8A, C.8B, C.8D, C.8E 5 592TX_Sci_Chem_SE_PDF Round.indd 5 06/08/13 4:28 PM Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 311 Pretest . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321 Posttest . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349 Chemistry Reference Materials . . . . . . . . . . . . . . . . . . . . . . . . . . 377 Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC Safety Guidelines for Investigations . . . . . . . . . . . . . . . . . . . . . . 381 6 • Table of Contents 592TX_Sci_Chem_SE_PDF Round.indd 6 06/08/13 4:28 PM Chapter 1 • Lesson 1 TEKS: C.4C States of Matter Key Words •matter•mass•volume•state of matter•solid•liquid •gas•compressibility •state change•melting•vaporization•boiling•evaporation •sublimation •freezing •condensation•deposition•kinetic molecular theory Getting the Idea When studying objects, it is often helpful to classify them, or group them into categories based on their appearances and behaviors . This process helps us see the basic similarities and differences between objects . One of the most basic characteristics of any object is its form . What Is Matter? The particles that make up matter are constantly in motion . How they move affects the form that matter takes . As the particles move, forces between them tend to pull them toward one another and bind them together, forming objects . When particles move quickly enough, they can overcome these forces . This allows the particles to move around one another and sometimes even fly apart . The motion of the particles determines the form of the object . States of Matter These different physical forms that objects can take are called states of matter . States of matter are also called phases of matter . The most common states of matter on Earth are solid, liquid, and gas . Objects in the same state have similar characteristics in terms of shape, structure, volume, and compressibility . Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC All the objects in the world around us—including ourselves—are composed of matter . Matter is defined as anything that has mass and volume . Mass is the amount of matter in an object . The more mass an object has, the more it resists changes in motion . Volume is the amount of space an object takes up . The different types of matter we encounter consist of basic building blocks called atoms, usually in collections called molecules . For now, though, you can think of these building blocks simply as particles . 14 592TX_Sci_Chem_SE_PDF Round.indd 14 06/08/13 4:29 PM A solid is a substance with a definite shape and volume . The particles in a solid generally stay in one location . They cannot move about freely, but they still move by vibrating in place . This arrangement of the particles gives the solid a definite shape and volume that do not change unless a force acts on the object . A liquid is a substance that has a definite volume but no definite shape . The particles in a liquid stay close together, but they do not keep any pattern or arrangement, unlike in a solid . Instead of being held in place, the particles of a liquid slide past one another . A liquid, therefore, does not have a definite shape and will take the shape of its container . The volume of a liquid stays constant no matter what shape it takes . A gas is a substance that has neither a definite shape nor a definite volume . The particles of a gas move quickly and are far apart, without any regular arrangement . They can spread out and move independently of one another . As such, they have no definite arrangement, shape, or volume . A gas takes on the shape and volume of its container . Compressibility describes the ability of a substance to change volume when the pressure around it changes . Imagine squeezing a small balloon . The balloon becomes smaller as the gas within it is compressed because gases are highly compressible . Squeezing a brick, however, does not much change the volume of the brick because solids are not easily compressible . The compressibility of a substance results from the arrangement of its particles and the forces between them . The table below provides a summary of these characteristics . States of Matter and Their Properties Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC Property Solid Liquid Gas Shape Definite shape No definite shape No definite shape Volume Definite volume Definite volume No definite volume Structure Particles closely packed and fixed in place with a regular arrangement Particles close together, sliding past one another without a regular arrangement Particles far apart, without a regular arrangement Compressibility Not easily compressible Not easily compressible Highly compressible 15 592TX_Sci_Chem_SE_PDF Round.indd 15 06/08/13 4:29 PM Changes of State A state change is a change from one state of matter to another, such as when a solid melts to become a liquid . All state changes require that the substance either absorb or release energy, usually in the form of heat . If a solid absorbs enough energy, it changes from a solid to a liquid, a process called melting . This change occurs at the melting point, a specific temperature that depends on the substance that is melting . Similarly, adding energy to a liquid can change it to a gas . Change from a liquid to a gas is called vaporization . Vaporization can occur in two ways . If it happens rapidly, with bubbles of gas forming throughout a liquid and rising to the surface, the process is called boiling . Each substance has a boiling point . This is the temperature, measured at a standard pressure, at which the substance boils . If a liquid changes to a gas only at the surface of the liquid, the process is called evaporation . This is how a puddle of water dries up on a sunny day . A substance can evaporate even at temperatures below its boiling point . Other state changes result from loss of energy . For example, when warm water is placed in a freezer, energy moves out of the water and into the cold air . This flow of energy due to differences in temperature is called heat . You will learn more about heat transfer in Lessons 23 and 24 . When enough energy is removed from the liquid water, it changes into solid ice . The change from liquid to solid is called freezing . The temperature at which a substance freezes is called its freezing point, and it is almost always equivalent to that substance’s melting point . For example, when the temperature of water falls below 0 degrees Celsius ( °C), the water freezes to form ice . When the temperature of ice rises above 0 °C, the ice melts to form liquid water . Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC Sublimation occurs when a solid absorbs energy and changes directly to a gas, without first becoming a liquid . A substance nicknamed “dry ice,” which is actually solid carbon dioxide, sublimates at room temperature . 16 • Chapter 1: Properties of Matter 592TX_Sci_Chem_SE_PDF Round.indd 16 06/08/13 4:29 PM Lesson 1: States of Matter If enough energy is released or removed from a gas, its particles draw together and change to liquid . This process is called condensation . The drops of water that form on the outside of a cold soda can or glass of iced tea result when water vapor in the air condenses on the can or glass . Under some circumstances, a gas can change directly into a solid through a process called deposition . Particles of water vapor undergo deposition within winter clouds to form solid ice and snow . Notice that the processes of freezing, condensation, and deposition are the reverse of the processes of melting, vaporization, and sublimation . The first three state changes all involve matter losing energy . The latter three state changes involve matter gaining energy . The following diagram summarizes these state changes . Deposition: Energy is released. Freezing: Energy is released. Solid Liquid Melting: Energy is absorbed. Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC Condensation: Energy is released. Gas Vaporization: Energy is absorbed. Sublimation: Energy is absorbed. 17 592TX_Sci_Chem_SE_PDF Round.indd 17 06/08/13 4:29 PM Kinetic Molecular Theory Changes of state are caused by changes in energy . These changes can be described using the kinetic molecular theory . The kinetic molecular theory states that particles of matter are always moving in a random fashion . Even in a solid substance, the particles vibrate in place . The theory’s name comes from kinetic energy, which is the energy due to the motion of objects, such as particles . The diagram below illustrates the arrangements and movements of particles in solids, liquids, and gases . When a substance is in the solid state, its particles have the least kinetic energy . The particles have the most energy when the same substance is in the gas state . Particles in Solids, Liquids, and Gases Liquid The particles are able to slide past one another. Gas The particles move quickly and independently of one another. The kinetic molecular model of matter helps explain the characteristics of each state . Because the particles in solids are bound tightly together, solids keep a specific shape and volume . There is little space between the particles, so compressing the solid does not change its volume much . Although the particles in liquids move too quickly around one another to bind together in a fixed shape, there is little space between the particles . It is difficult to push the particles closer together when compressing a liquid . Thus, a liquid has a fixed volume . The particles in gases move so quickly that they bounce off one another and rocket away, leaving large distances between them . Because gases contain these large empty spaces, they are much more easily compressed into a different volume . This is why gases have neither a fixed volume nor a fixed shape . Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC Solid The particles are held tightly in place and move only by vibrating in place. 18 • Chapter 1: Properties of Matter 592TX_Sci_Chem_SE_PDF Round.indd 18 06/08/13 4:30 PM Lesson 1: States of Matter Discussion Question In a laboratory, a solid substance is heated at a constant rate. As its state changes first to a liquid and then to a gas, how will the behavior of the particles in the substance also change? How do these changes relate to the changes in the characteristics of the different states? Lesson Review 1. A solid and a gas are placed in identical containers. Then, the size of each container is increased. Which of the following will most likely occur? A. The volume of both the solid and the gas will increase. B. The volume of both the solid and the gas will remain the same. C. The volume of the solid will increase, and the volume of the gas will remain the same. D. The volume of the gas will increase, and the volume of the solid will remain the same. 2. In which state of matter do the particles of a certain substance have the least kinetic energy? A. solid B. liquid C. gas Duplicating any part of this book is prohibited by law. © 2014 Triumph Learning, LLC 3. Which state of matter will show the greatest change in volume when pressure is applied to it? A. solid B. liquid C. gas 4. How do particles in a solid substance move? A. Particles in a solid spread far apart and move independently of one another. B. Particles in a solid stay close together but slide around one another. C. Particles in a solid stay bound together and vibrate in place. D. Particles in a solid do not move. 19 592TX_Sci_Chem_SE_PDF Round.indd 19 06/08/13 4:30 PM
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