Q1. Read the information in the box and then answer the questions. Sun Creams Sun creams contain titanium oxide. This compound absorbs harmful radiation. Traditional sun creams contain normal-sized particles of titanium oxide. Normal-sized particles of titanium oxide are known to be safe to put on the skin. Many new sun creams contain nano-sized particles of titanium oxide. Experiments suggest that nano-sized particles might pass through the pores of the skin more easily than normal-sized particles. (a) Explain why nano-sized particles might pass more easily through the pores of the skin than normal sized particles. ........................................................................................................................ ........................................................................................................................ (1) (b) Using these sun creams is beneficial because they absorb harmful radiation. Suggest one possible risk of using these sun creams. ........................................................................................................................ ........................................................................................................................ (1) (Total 2 marks) Q2. This drill contains an electric motor. Page 1 The diagram below shows the main parts of an electric motor. The carbon contacts are made of graphite. Springs push the contacts against the copper ring. The carbon contacts conduct electricity to the copper ring. The copper ring rotates rapidly but does not stick or become worn because the graphite is soft and slippery. (a) Using this information give two properties that make graphite suitable for making the carbon contacts. 1 .......................................................................................................... ......................... ............................................................................................................................. ........ 2 .............................................................................................. ..................................... ............................................................................................................................. ........ (2) (b) (i) Draw a ring around the correct word in each box to complete the sentence. Each carbon atom in graphite is joined to two three covalent other carbon atoms by ionic Page 2 bonds. four metallic (2) (ii) Tick ( ) the statement which explains why graphite is soft and slippery. Statement Tick ( ) It is made of layers of atoms. It is made of small molecules. It is an ionic compound. (1) (Total 5 marks) Q3. Bricks made from silica (silicon dioxide) are used to line furnaces that operate at high temperatures. Part of the structure of silica is shown in the diagram. Page 3 Use words from the box to complete the sentences. covalent giant four high low six small weak One reason for using silica to make bricks for high-temperature furnaces is that silica has a .......................................... melting point. Silica has this property because it is a .......................................... structure in which each silicon atom is joined to .......................................... oxygen atoms by .......................................... bonds. (Total 4 marks) Q4. This label was on a container of graphite lubricant. Super G Graphite Lubricant Super G forms a thin anti-friction film on metal surfaces. It provides good lubrication when metal parts rub against each other. (a) Give one reason why a lubricant is used when metal parts rub against each other. ..................................................................................................................................... ............................................................................................................................. ........ (1) (b) The diagram shows the arrangement of atoms in graphite. Page 4 (i) Draw a ring around the type of atoms in graphite. aluminium carbon silicon (1) (ii) Graphite is a good lubricant because it is slippery. Use the diagram to explain why graphite is slippery. ........................................................................................................................... ........................................................................................................................... ........................................................................................................................... ........................................................................................................................... ........................................................................................................................... (2) (Total 4 marks) Q5. Read the article and then answer the questions. Nanotennis! Tennis balls contain air under pressure, which gives them their bounce. Normal tennis balls are changed at regular intervals during tennis matches because they slowly lose some of the air. Page 5 ‘Nanocoated’ tennis balls have a ‘nanosize’ layer of butyl rubber. This layer slows down the escape of air so that the ball does not lose its pressure as quickly. (a) What is the meaning of nanosize? ............................................................................................................................. ........ ................................................................................................................ ..................... (1) (b) Suggest why using ‘nanocoated’ tennis balls would be good for the environment. ............................................................................................................................. ........ ................................................................................................................................... .. ............................................................................................................................. ........ .......................................................................................................................... ........... (2) (Total 3 marks) Q6. Magnesium oxide is a compound, made up of magnesium ions and oxide ions. Page 6 (a) What is the charge on each magnesium ion? ............................................................. (1) (b) Explain how the magnesium ions get this charge. ............................................................................................................................. ........ ..................................................................................................................................... ............................................................................................................................. ........ (2) (Total 3 marks) Q7. Read this passage about metals. Metals are crystalline materials. The metal crystals are normally about 20 000 nm (nanometres) in diameter. The atoms inside these crystals are arranged in layers. A new nanoscience process produces nanocrystalline metals. Nanocrystalline metals are stronger and harder than normal metals. It is hoped that nanocrystalline metals can be used in hip replacements. Page 7 The use of nanocrystalline metals should give people better hip replacements which last longer. (a) State why metals can be bent and hammered into different shapes. ............................................................................................................................. ........ ............................................................................................................................. ........ (1) (b) How is the size of the crystals in nanocrystalline metals different from the size of the crystals in normal metals? ............................................................................................................................. ........ ................................................................................................................. .................... (1) (c) Hip joints are constantly moving when people walk. Suggest and explain why the hip replacement made of nanocrystalline metal should last longer than one made of normal metals. ..................................................................................................................................... Page 8 ............................................................................................................................. ........ ..................................................................................................................................... ............................................................................................................................. ........ (2) (Total 4 marks) Page 9 M1. (a) because nano-sized particles are smaller than normal sized particles 1 (b) may cause harm when they are inside the body 1 [2] M2. (a) any two from: • conducts electricity • soft • slippery • high melting point ignore hardwearing / does not stick apply list principle 2 (b) (i) three 1 covalent 1 (ii) it is made of layers of atoms 1 [5] M3. high Page 10 1 giant allow covalent 1 four 1 covalent 1 [4] M4. (a) reduce wear of metal ie don’t get damaged or other sensible answer or stop / reduce friction accept stop metal heating up accept move more smoothly ignore make it slippery / rub more smoothly or prevent seizing accept can move freely 1 (b) (i) carbon 1 (ii) layers (of atoms) 1 can slide / slip over each other allow slip off or weak forces of attraction / weak bonds (between layers) allow no bonds accept there are weak forces of attraction for 1 mark even when there is no reference to layers accept atoms slide over each other (for 1 mark) an answer which only states there are weak bonds would gain 0 mark when there is no reference to layers Page 11 weak covalent bonds = 0 marks 1 [4] M5. (a) 1-100 nm in size or a few (hundred) atoms in size accept very / really small / tiny or 10–9 accept billionth of a metre or any number that implies very small accept measured in nanometers if answer ‘very small’ ignore incorrect numerical values 1 (b) any two from: • less tennis balls need to be made • tennis balls last longer or don’t have to replace as often • less materials / resources / fuel used up / saves resources accept saving materials • less energy used or making tennis balls uses energy accept saving energy • less pollution caused accept named pollutant accept global warming / greenhouse effect • less waste eg fewer tennis balls going to landfill 2 [3] ## (a) positive for 1 mark 1 Page 12 (b) any reference to loss of electrons for 1 mark reference to charge being +2 (in (a)) or to loss of 2 electrons (in (b)) for 1 mark 2 [3] M7. (a) any one from: • they are made of layers do not accept line / rows / lattice • atoms / ions / particles / layers (of atoms) can slide over each other 1 (b) any one from: • smaller / tiny or very small do not allow small alone • correct size range 1 to 100 nanometres • a few hundred atoms in size if they state smaller and give a size outside range ignore size if it is less than 20,000 1 (c) harder 1 plus one from: • so does not wear as quickly / erode as quickly ignore corrode • less vulnerable to damage owtte harder to wear down = 1 mark • because they have a high surface area to volume ratio or stronger (1) Page 13 plus one from: (1) • less likely to break / do not break accept withstand pressure • not as vulnerable to damage owtte harder and stronger alone gains 1 mark • do not bend out of shape • because they have a high surface area to volume ratio 1 [4] Page 14
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