9/27/2015 Types of Compounds • Biology 102 Organic molecules • Primary structure from carboncarbon-carbon bonds • Most biological molecules • Examples: carbohydrates, lipids, proteins Lecture 2: Water Types of Compounds • Inorganic molecules • Primary structure from anything except carbon--carbon bonds carbon • Examples: NH3, O2, NaCl, NaCl, CO2 • Most important for life is water Properties of Water • We are mostly water! • All chemical processes for life occur in water • Metabolism stops if cell’s water content drops below 50% Properties of Water • Keys to water’s unique properties • Shape • Polarity and hydrogen bonds Properties of Water • Cohesion: the ability of molecules of a single compound to stick together • Water likes to stick to itself • Due to hydrogen bonds 1 9/27/2015 Properties of Water • Properties of Water Adhesion: the ability of molecules of one compound to stick to molecules of another compound • Water likes to stick to other molecules • Due to hydrogen bonds Water sticking to itself Water sticking to Something else • Properties of Water • The balance between these forces leads to all kinds of phenomena Properties of Water • Properties of Water • Surface tension • Hydrogen bonds at the surface of water are especially strong • Reduces evaporation • Acts as barrier (example: eyes) The balance between these forces leads to all kinds of phenomena The balance between these forces leads to all kinds of phenomena Properties of Water • Surface tension 2 9/27/2015 Properties of Water • Surfactants are substances that disrupt surface tension • Properties of Water • Lung surfactant Examples: soap, egg yolk, EDTA, fabric softeners, laxatives, insecticides Properties of Water • Specific heat • Measure of how much thermal energy a substance can absorb without changing temperature • How much heat it can store Properties of Water • Properties of Water • Specific heat • Specific heat • Water has a VERY high specific heat – the second highest found in nature • Remarkable because of small mass • Due to hydrogen bonds Properties of Water • Due to its high specific heat, water is excellent for evaporative cooling • ALL hydrogen bonds must be broken for water to escape and become a gas • Takes a tremendous amount of energy Makes water a very efficient insulator 3 9/27/2015 Properties of Water • Energy is supplied by the molecules underneath • Leaves the substance cooler Properties of Water • Lubrication • Water is virtually incompressible • Molecules pass over each other easily • Reduces friction Properties of Water • Nearly universal solvent • This is quite unusual Solutions • A solution is a homogenous mixture of one or more solutes dissolved into a solvent • Solute: what is dissolved • Solvent: what is doing the dissolving • Aqueous solution: one in which the solvent is water Solubility • Not all solutes will dissolve in all solvents • Solubility rule of thumb: Like dissolves like • Polar and ionic solutes dissolve in polar solvents • Non--polar solutes dissolve in nonNon non-polar solvents Solvents and Solutes Like dissolves like Sugar (polar) + Water (polar) Sugar (polar) + CCl4 (non (non--polar) Iodine (non(non-polar) + Water (polar) Iodine (non(non-polar) + CCl4 (non (non--polar) 4 9/27/2015 Solvents and Solutes • Substances that associate with water = hydrophilic (water (water--loving) Solvents and Solutes • Substances that do not associate with water = hydrophobic (water (water--fearing) • Polar or nonnon-polar? • Polar or nonnon-polar? • Examples? • Examples? Solvents and Solutes Solvents and Solutes • Substances that do not associate with water = hydrophobic (water (water--fearing) • Some are both hydrophilic and hydrophobic at the same time • Non--polar Non • Surfactants • Examples: oil, iodine, hydrophobic sand 5
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