Priority Pollutant Standard Mixtures Solutions for a Greener World oduction Priority Pollutant Standard Mixtures Chlorobenzene and Chlorophenol Standard Mixtures Owing to the sheer volume of use in commercial products, halogenated benzenes and phenols remain among the largest contributors to environmental contamination. The standards listed here are in routine use in many laboratories around the world. US EPA Method 1653A US EPA Method 1653A is used for the determination of pollutants in pulp and paper industry wastewater. This revision was promulgated in 1997, superseding the earlier method 1653. While still used primarily for the determination of chlorophenolic compounds, Revision A incorporates several changes to the analytical procedure, including the use of specially formulated standard mixtures applicable to this revision. isotope.com Human Exposure Analysis Exposure analysis studies the ultimate effects environmental or food pollutants have on a biological system. Increasingly, public health studies are looking at the relationship between adverse health issues and exposure to environmental and food pollutants, as well as consumption pollutants such as tobacco compounds, bisphenols, etc. CIL has worked for years to develop analytical standards to assist exposure research and now offers some targeted mixtures as well. Our “phenolics” mixes include several ubiquitous exposure biomarkers, including PCB metabolites, BDE metabolites, tetrabromobisphenol A, triclosan, chlorophenols, and bromophenols. The analytes in the calibration solutions are the derivatized analogues of the target compounds, and the unusual concentrations are a result of corrections for molecular weights of the derivatized products. The spiking solution contains underivatized compounds to allow for derivatization during the isotope dilution method. US EPA CLP DMC Standard Mixtures EPA’s Contract Laboratory Program (CLP) has developed methods for the analysis of volatile and semi-volatile compounds which utilize isotopically labeled internal standards. These deuterated monitoring compounds (DMCs) have been added to strengthen the analysis by providing sample-by-sample internal standard addition. CIL’s CLP DMC standard mixtures are designed to match requirements of the OLC and SOM test methods. US EPA Method 1624/1625 CIL maintains a full suite of standards used for the analysis of volatile and semi-volatile organic compounds by US EPA Method 1624/1625. 194 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] Priority Pollutant Standard Mixtures isotope.com Chlorobenzene and Chlorophenol Standard Mixtures Catalog No. |EM-1724-A |EM-1724-B Compound 13 C-Labeled Chlorobenzene Cocktail Solution – Mono, Di, Tri Isomers 13 C-Labeled Chlorobenzene Cocktail Solution – Mono, Di, Tri Isomers Labeled Chlorobenzene (13C6, 99%) 1,4-Dichlorobenzene (13C6, 99%) 1,2,4-Trichlorobenzene (13C6, 99%) |EM-1725-A |EM-1725-B |EM-1726-A |EM-1726-B C-Labeled Chlorobenzene Cocktail Solution – Tetra, Penta, Hexa Isomers C-Labeled Chlorobenzene Cocktail Solution – Tetra, Penta, Hexa Isomers 13 C-Labeled Chlorophenol Cocktail Solution – Mono, Di, Tri Isomers C-Labeled Chlorophenol Cocktail Solution – Mono, Di, Tri Isomers 13 |ES-5401 C-Labeled Chlorophenol Cocktail Solution – Tri, Tetra, Penta Isomers C-Labeled Chlorophenol Cocktail Solution – Tri, Tetra, Penta Isomers 13 |ES-5406 C-Labeled Mono-Hexa Chlorobenzene Solution 1.2 mL in toluene (µg/mL) 500 500 500 500 500 500 Native Mono-Hexa Chlorobenzene Solution Unlabeled Chlorobenzene (unlabeled) 1,4-Dichlorobenzene (unlabeled) 1,2,3-Trichlorobenzene (unlabeled) 1,2,3,4-Tetrachlorobenzene (unlabeled) Pentachlorobenzene (unlabeled) Hexachlorobenzene (unlabeled) 1.2 mL in isooctane 1.2 mL in methanol (µg/mL) 100 100 100 13 Labeled Chlorobenzene (13C6, 99%) 1,4-Dichlorobenzene (13C6, 99%) 1,2,3-Trichlorobenzene (13C6, 99%) 1,2,3,4-Tetrachlorobenzene (13C6, 99%) Pentachlorobenzene (13C6, 99%) Hexachlorobenzene (13C6, 99%) 1.2 mL in isooctane 1.2 mL in methanol (µg/mL) 100 100 100 13 Labeled 2,4,5-Trichlorophenol (13C6, 99%) 2,3,4,5-Tetrachlorophenol (13C6, 99%) Pentachlorophenol (13C6, 99%) 1.2 mL in isooctane 1.2 mL in methanol (µg/mL) 100 100 100 13 Labeled 4-Chlorophenol (13C6, 99%) 2,4-Dichlorophenol (13C6, 99%) 2,4,6-Trichlorophenol (13C6, 99%) |EM-1727-A |EM-1727-B (µg/mL) 100 100 100 13 Labeled 1,2,4,5-Tetrachlorobenzene (13C6, 99%) Pentachlorobenzene (13C6, 99%) Hexachlorobenzene (13C6, 99%) Amount 1.2 mL in isooctane 1.2 mL in methanol 1.2 mL in toluene (µg/mL) 500 500 500 500 500 500 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] 195 Priority Pollutant Standard Mixtures isotope.com US EPA Method 1653A Standard Mixtures Catalog No. Compound Amount |EM-4173 Method 1653A Labeled Chlorophenolic Derivatives Mixture – 1 Each: EM-4173-1 and EM-4173-2 2 × 1 mL (Note: unlabeled internal standard, 3,4,5-trichlorophenol already formulated into the standard) |EM-4173-1 |EM-4173-2 Method 1653A Labeled Chlorophenolic Derivatives Mixture Method 1653A Labeled Chlorophenolic Derivatives Mixture Labeled 2,4-Dichlorophenol (13C6, 99%) 4-Chloroguaiacol (13C6, 99%) 4,5-Dichlorocatechol (ring-13C6, 99%) 4,5,6-Trichloroguaiacol (13C6, 99%) Pentachlorophenol (13C6, 99%) 3,4,5,6-Tetrachloroguaiacol (13C6, 99%) 3,4,5,6-Tetrachlorocatechol (ring-13C6, 99%) 3,4,5-Trichlorophenol (unlabeled) (IS) 5-Chlorovanillin (ring-13C6, 99%) |EM-4181 1 mL in acetone (µg/mL) 500 Method 1653A Other Chlorophenolics Mixture-1 Unlabeled 4-Chlorocatechol (unlabeled) 4-Chlorophenol (unlabeled) 3,6-Dichlorocatechol (unlabeled) 3,4-Dichloroguaiacol (unlabeled) 4,6-Dichloroguaiacol (unlabeled) 2,6-Dichlorophenol (unlabeled) 4-Chloroguaiacol (unlabeled) 3,4-Dichlorocatechol (unlabeled) 4,5-Dichlorocatechol (unlabeled) 4,5-Dichloroguaiacol (unlabeled) 2,4-Dichlorophenol (unlabeled) 1 mL in methanol (µg/mL) 1000 1000 1000 500 500 500 1000 500 1000 500 500 Method 1653A Regulated Chlorophenolics Mixture-2 Unlabeled Trichlorosyringol (unlabeled) |EM-4183 EM-4173-2 (µg/mL) – – – – – – – – 250 Method 1653A Regulated Chlorophenolics Mixture-1 Unlabeled Pentachlorophenol (unlabeled) 3,4,5,6-Tetrachloroguaiacol (unlabeled) 3,4,5-Trichlorocatechol (unlabeled) 3,4,5-Trichloroguaiacol (unlabeled) 4,5,6-Trichloroguaiacol (unlabeled) 2,4,6-Trichlorophenol (unlabeled) 3,4,5,6-Tetrachlorocatechol (unlabeled) 2,3,4,6-Tetrachlorophenol (unlabeled) 3,4,6-Trichlorocatechol (unlabeled) 3,4,6-Trichloroguaiacol (unlabeled) 2,4,5-Trichlorophenol (unlabeled) |EM-4182 EM-4173-1 (µg/mL) 250 250 250 250 250 250 250 250 – 1 mL in methanol 1 mL in acetone 1 mL in methanol (µg/mL) 250 250 500 500 500 500 250 500 500 500 500 196 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] Priority Pollutant Standard Mixtures isotope.com US EPA Method 1653A Standard Mixtures Catalog No. |EM-4184 Compound Method 1653A Other Chlorophenolics Mixture-2 Unlabeled 2-Chlorosyringealdehyde (unlabeled) 5-Chlorovanillin (unlabeled) 6-Chlorovanillin (unlabeled) 2,6-Dichlorosyringealdehyde (unlabeled) 5,6-Dichlorovanillin (unlabeled) |EM-4185 |EM-4186 |EM-4180 Amount 1 mL in acetone (µg/mL) 500 500 500 1000 1000 Set of Regulated Chlorophenolics Mixtures 1 Each: EM-4181 and EM-4182 Set of Other Chlorophenolics Mixtures 1 Each: EM-4183 and EM-4184 Set of Chlorophenolics Mixtures 1 Each: EM-4181, EM-4182, EM-4183 and EM-4184 2 × 1 mL 2 × 1 mL 4 × 1 mL US EPA Method 1653 Standard Mixtures |EM-4018 Method 1653 Unlabeled Chloroguaiacol Cocktail Unlabeled 4-Chloroguaiacol (unlabeled) 3,4-Dichloroguaiacol (unlabeled) 4,5-Dichloroguaiacol (unlabeled) 4,6-Dichloroguaiacol (unlabeled) 3,4,5-Trichloroguaiacol (unlabeled) 3,4,6-Trichloroguaiacol (unlabeled) 4,5,6-Trichloroguaiacol (unlabeled) 3,4,5,6-Tetrachloroguaiacol (unlabeled) |EM-4028 1 mL in acetone (µg/mL) 250 500 500 500 500 500 500 1000 Instrument Performance Standard Unlabeled 2,2’-Difluorobiphenyl (unlabeled) 1 mL in acetone (µg/mL) 5000 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] 197 Priority Pollutant Standard Mixtures isotope.com US EPA CLP DMC Standard Mixtures Catalog No. |ES-5037 Compound CLP Semi-Volatiles DMC Stock Solution Labeled Phenol (ring-D5, 98%) Bis(2-chloroethyl) ether (D8, 98%) 2-Chlorophenol (ring-D4, 98%) 4-Methylphenol (p-Cresol) (D8, 98%) Nitrobenzene (D5, 99%) 2-Nitrophenol (ring-D4, 98%) 2,4-Dichlorophenol (ring-D3, 98%) 4-Chloroaniline (D4, 98%) Dimethyl phthalate (dimethyl-D6, 98%) Acenaphthylene (D8, 98%) 4-Nitrophenol (ring-D4, 98%) Fluorene (D10, 98%) 4,6-Dinitro-2-methylphenol (ring-D2, 98%) Anthracene (D10, 98%) Pyrene (D10, 98%) Benzo[a]pyrene (D12, 98%) |ES-5038 |ES-5038-1 |ES-5038-2 Amount 1.2 mL in MeCl-D2 (µg/mL) 2000 2000 2000 2000 2000 2000 2000 2000 2000 2000 2000 2000 2000 2000 2000 2000 CLP OLC Volatiles DMC Stock Solutions 1 Each: ES-5038-1 and ES-5038-2 CLP OLC Volatiles Non-Ketone DMC Stock Solution CLP OLC Volatiles Ketone DMC Stock Solution Labeled Vinyl chloride (D3, 98%) Chloroethane (D5, 98%) 1,1-Dichloroethene (D2, 98%) 2-Butanone (1,1,1,3,3-D5, 98%) Chloroform (D, 98%) 1,2-Dichloroethane (D4, 99%) Benzene (D6, 99.5%) 1,2-Dichloropropane (D6, 98%) Toluene (D8, 99.5%) 1,3-Dichloropropene (D4, 98%) (cis/trans mixture) 2-Hexanone (1,1,1,3,3-D5, 98%) Bromoform (D, 99.5%) 1,1,2,2-Tetrachloroethane (D2, 99.6%) 1,2-Dichlorobenzene (D4, 99%) 1 set 1 mL in methanol-OD 0.5 mL in methanol-OD ES-5038-1 (µg/mL) 100 100 100 – 100 100 100 100 100 100 – 100 100 100 ES-5038-2 (µg/mL) – – – 200 – – – – – – 200 – – – 198 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] Priority Pollutant Standard Mixtures isotope.com US EPA CLP DMC Standard Mixtures Catalog No. |ES-5286 |ES-5286-10X Compound CLP SOM Volatiles Non-Ketone DMC Stock Solution CLP SOM Volatiles Non-Ketone DMC 10X Stock Solution Labeled Vinyl chloride (D3, 98%) Chloroethane (D5, 98%) 1,1-Dichloroethylene (2,2-D2, 98%) Chloroform (D, 99.8%) 1,2-Dichloroethane (D4, 99%) Benzene (D6, 99.5%) 1,2-Dichloropropane (D6, 98%) Toluene (D8, 99.5%) 1,3-Dichloropropene (D4, 98%) (cis/trans mixture) 1,1,2,2-Tetrachloroethane (D2, 99.6%) 1,2-Dichlorobenzene (D4, 99%) |ES-5287 |ES-5287-10X ES-5286 (µg/mL) 100 100 100 100 100 100 100 100 100 100 100 ES-5286-10X (µg/mL) 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 1000 CLP SOM Volatiles Ketone DMC Stock Solution CLP SOM Volatiles Ketone DMC 10X Stock Solution 0.5 mL in methanol-OD 0.5 mL in methanol-OD ES-5287 (µg/mL) 500 500 Labeled 2-Butanone (1,1,1,3,3-D5, 98%) 2-Hexanone (1,1,1,3,3-D5, 98%) |ES-5288 |ES-5288-10X Amount 1 mL in methanol-OD 1 mL in methanol-OD ES-5287-10X (µg/mL) 5000 5000 CLP SOM Volatiles 1,4-Dioxane DMC Stock Solution CLP SOM Volatiles 1,4-Dioxane 10X DMC Stock Solution Labeled 1,4-Dioxane (p-dioxane) (D8, 99%) 1 mL in methanol-OD 1 mL in methanol-OD ES-5288 (µg/mL) 1250 ES-5288-10X (µg/mL) 12,500 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] 199 Priority Pollutant Standard Mixtures isotope.com US EPA Methods 1624/1625 Standard Mixtures Catalog No. |ES-2036 Compound Acid Extractables Mixture-3 Labeled (EPA 222A) (EPA 224A) (EPA 231A) (EPA 234A) (EPA 260A) (EPA 259A) (EPA 257A) (EPA 258A) (EPA 264A) (EPA 265A) (EPA 631A) (EPA 221A) |ES-2002 4-Bromophenyl phenyl ether (phenyl-D5, 98%) 2-Chloronaphthalene (D7, 98%) 4-Chlorophenyl phenyl ether (phenyl-D5, 98%) Di-n-butyl phthalate (ring-D4, 98%) Diethyl phthalate (ring-D4, 98%) Di-n-octyl phthalate (ring-D4, 98%) Hexachlorobenzene (13C6, 99%) Hexachloroethane (1-13C, 99%) Isophorone (3-methyl-D3 ; 2,4,4,6,6-D5, 98%) 1,2,4-Trichlorobenzene (D3, 98%) 1 mL in benzene-D6 (µg/mL) 5000 5000 5000 5000 5000 5000 5000 5000 5000 5000 Base Neutrals Dilution Mixture-5.2 Labeled (EPA 628B) (EPA 261B) (EPA 263B) |ES-2003 (µg/mL) 5000 5000 5000 5000 5000 5000 5000 5000 5000 5000 5000 5000 Base Neutrals Mixture-4.3 Labeled (EPA 241B) (EPA 220B) (EPA 240B) (EPA 268B) (EPA 270B) (EPA 269B) (EPA 209B) (EPA 212B) (EPA 254B) (EPA 208B) |ES-2026 4-Chloro-3-methylphenol (ring-2,6-D2, 98%) 2-Chlorophenol (ring-D4, 98%) 2,4-Dichlorophenol (ring-D3, 98%) 2,4-Dimethylphenol (ring-D3, 98%) 4,6-Dinitro-2-methylphenol (ring-D2, 98%) 2,4-Dinitrophenol (ring-D3, 98%) 2-Nitrophenol (ring-D4, 98%) 4-Nitrophenol (ring-D4, 98%) Pentachlorophenol (13C6, 99%) Phenol (ring-D5, 98%) 2,4,5-Trichlorophenol (ring-D2, 98%) 2,4,6-Trichlorophenol (ring-D2, 98%) Amount 1 mL in benzene-D6 Carbazole (ring-D8, 98%) N-Nitrosodimethylamine (D6, 98%) N-Nitrosodi-n-propylamine (D14, 98%) 1 mL in benzene-D6 (µg/mL) 5000 5000 5000 Base Neutrals Mixture-6.2 Labeled (EPA 201B) (EPA 278B) (EPA 275B) (EPA 218B) (EPA 276B) (EPA 280B) (EPA 255B) (EPA 284B) Acenaphthene (D10, 99%) Anthracene (D10, 98%) Benzo[k]fluoranthene (D12, 98%) Bis(2-chloroethyl) ether (D8, 98%) Chrysene (D12, 98%) Fluorene (D10, 98%) Naphthalene (D8, 99%) Pyrene (D10, 98%) 2 × 1 mL in 50% benzene-D6 and 50% MeCl-D2 (µg/mL) 2500 2500 2500 2500 2500 2500 2500 2500 200 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] Priority Pollutant Standard Mixtures isotope.com US EPA Methods 1624/1625 Standard Mixtures Catalog No. |ES-2004 Compound Base Neutrals Mixture-6.3 Labeled (EPA 272B) (EPA 267B) (EPA 243B) (EPA 266B) (EPA 282B) (EPA 225B) (EPA 227B) (EPA 271B) (EPA 236B) (EPA 256B) (EPA 629B) |ES-2032 (µg/mL) 5000 5000 5000 5000 5000 5000 5000 5000 5000 5000 5000 1 mL in methanol-D4 Carbon tetrachloride (13C, 99%) Chlorobenzene (D5, 99%) Chloroform (13C, 99%) 1,1-Dichloroethane (2,2,2-D3, 98%) 1,1-Dichloroethylene (2,2-D2, 98%) Methylene chloride (D2, 99.9%) 1,2-Dichloropropane (D6, 98%) 1,1,2-Trichloroethane (13C2, 99%) (µg/mL) 50 50 50 50 50 50 50 50 Purgeables / Volatiles Mixture-F Labeled (EPA 204V) (EPA 247V) (EPA 210V) (EPA 238V) (EPA 215V) (EPA 286V) (EPA 211V) |ES-2008 Benz[a]anthracene (D12, 98%) Butyl benzyl phthalate (ring-D4, 99%) Bis(2-chloroethoxy) methane (chloroethoxy-D8, 98%) Bis(2-ethylhexyl) phthalate (ring-D4, 99%) Dibenz[a,h]anthracene (D14, 98%) 1,2-Dichlorobenzene (D4, 99%) 1,4-Dichlorobenzene (D4, 98%) Dimethyl phthalate (ring-D4, 99%) 2,6-Dinitrotoluene (methyl-D3, 98%) Nitrobenzene (D5, 99%) 1,2,3-Trichlorobenzene (D3, 98%) Purgeables / Volatiles Mixture-E.1 Labeled (EPA 206V) (EPA 207V) (EPA 223V) (EPA 213V) (EPA 229V) (EPA 244V) (EPA 232V) (EPA 214V) |ES-2006 Amount 1 mL in benzene-D6 1 mL in methanol-D4 Benzene (D6, 99.5%) Bromoform (13C, 99%) 1,2-Dichloroethane (D4, 99%) Ethylbenzene (D10, 98%) 1,1,2,2-Tetrachloroethane (D2, 99.6%) Toluene (D8, 99.5%) 1,1,1-Trichloroethane (D3, 98%) (µg/mL) 50 50 50 50 50 50 50 Purgeables / Volatiles Mixture-H Labeled (EPA 248V) (EPA 251V) (EPA 30V) (EPA 33V) (EPA 627V) (EPA 285V) (EPA 287V) 1 mL in methanol-D4 Bromodichloromethane (13C, 99%) Chlorodibromomethane (13C, 99%) 1,2-Dichloroethylene (1,2-D2, 98%) 1,3-Dichloropropene (D4, 98%) (cis/trans mixture) 1,4-Dioxane (D8, 99%) Tetrachloroethylene (13C2, 99%) Trichloroethylene (13C2, 99%) (µg/mL) 50 50 50 50 50 50 50 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] 201 Priority Pollutant Standard Mixtures isotope.com Human Exposure Analysis Standard Mixtures NEW NEW NEW NEW NEW NEW NEW Catalog No. |ES-5510 |ES-5510-CS1 |ES-5510-CS2 |ES-5510-CS3 |ES-5510-CS4 |ES-5510-CS5 |ES-5510-CS6 Compound Extended Phenolic Calibration Solutions [CS1-CS6] Extended Phenolic Calibration Solution [CS1] Extended Phenolic Calibration Solution [CS2] Extended Phenolic Calibration Solution [CS3] Extended Phenolic Calibration Solution [CS4] Extended Phenolic Calibration Solution [CS5] Extended Phenolic Calibration Solution [CS6] Amount 6 × 0.5 mL in 80% nonane/20% dodecane, hexane and toluene 0.5 mL in 80% nonane/20% dodecane, hexane and toluene 0.5 mL in 80% nonane/20% dodecane, hexane and toluene 0.5 mL in 80% nonane/20% dodecane, hexane and toluene 0.5 mL in 80% nonane/20% dodecane, hexane and toluene 0.5 mL in 80% nonane/20% dodecane, hexane and toluene 0.5 mL in 80% nonane/20% dodecane, hexane and toluene All concentrations are in ng/mL (ppb)* Unlabeled 4-Methoxy-2,3,3’,4’,5-pentachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’,5,5’-hexachlorobiphenyl 4-Methoxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl 5-Chloro-2-(2,4-dichlorophenoxy)-anisole (methyl triclosan) (unlabeled) 4-Methoxy-2,2’,3,4’-tetrabromodiphenyl ether 3-Methoxy-2,2’,4,4’-tetrabromodiphenyl ether 5-Methoxy-2,2’,4,4’-tetrabromodiphenyl ether 6-Methoxy-2,2’,4,4’-tetrabromodiphenyl ether 4’-Methoxy-2,2’,4,5’-tetrabromodiphenyl ether 5’-Methoxy-2,2’,4,4’,5-pentabromodiphenyl ether 6-Methoxy-2,2’,4,4’,5-pentabromodiphenyl ether 2,4-Dibromoanisole (unlabeled) 2,4,5-Tribromoanisole (unlabeled) 2,4,6-Tribromoanisole (unlabeled) Pentabromoanisole (unlabeled) Pentachloroanisole (unlabeled) Dimethyl tetrabromobisphenol A (unlabeled) Labeled 4-Methoxy-2,3,3’,4’,5-pentachlorobiphenyl (13C12, 99%) 4-Methoxy-2,2’,3,4’,5,5’-hexachlorobiphenyl (13C12, 99%) 4-Methoxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl (13C12, 99%) 6-Methoxy-2,2’,4,4’-tetrabromodiphenyl ether (ring-13C12, 99%) 6’-Methoxy-2,2’,4,4’,6-pentabromodiphenyl ether (13C12, 99%) 2,4-Dibromoanisole (ring-13C6, 99%) 2,4,5-Tribromoanisole (ring-13C6, 99%) 2,4,6-Tribromoanisole (ring-13C6, 99%) Pentabromoanisole (13C6, 99%) Pentachloroanisole (13C6, 99%) Dimethyl tetrabromobisphenol A (ring-13C12, 99%) 5-Chloro-2-(2,4-dichlorophenoxy)-anisole (methyl triclosan) (ring-13C12, 99%) 1,2,3,4-Tetrachlorodibenzo-p-dioxin (13C6, 99%) 2,2’,3,3’,4,5,5’,6,6’-Nonachlorobiphenyl (13C12, 99%) 3,3’,4,4’-Tetrabromodiphenyl ether (13C12, 99%) 2,2’,3,4,4’,6-Hexabromodiphenyl ether (13C12, 99%) IUPAC 208 77 139 CS1 0.21 0.21 0.21 CS2 0.52 0.52 0.52 CS3 2.60 2.59 2.59 CS4 21 21 26.2 CS5 104 104 103 CS6 520 519 517 2.10 5.24 26.2 210 1048 5242 0.21 0.21 0.21 0.21 0.21 0.20 0.20 0.21 0.21 0.21 0.21 2.11 0.11 0.51 0.51 0.51 0.51 0.51 0.51 0.51 0.53 0.52 0.52 0.51 5.26 0.26 2.57 2.57 2.57 2.57 2.57 2.56 2.56 2.64 2.61 2.61 2.57 26.3 1.31 21 21 21 21 21 21 21 21 21 21 21 210 11 103 103 103 103 102 102 102 106 104 104 103 1053 53 514 514 514 514 514 512 512 528 521 521 514 5263 263 104 104 104 104 104 104 104 104 104 104 104 104 103 103 103 103 103 103 103 103 103 103 103 103 102 102 102 102 102 102 105 104 104 103 1052 53 105 104 104 103 1052 53 105 104 104 103 1052 53 105 104 104 103 1052 53 105 104 104 103 1052 53 105 104 104 103 1052 53 1047 1047 1047 1047 1047 1047 25 100 75 75 25 100 75 75 25 100 75 75 25 100 75 75 25 100 75 75 25 100 75 75 *Concentrations are determined for listed derivatized compounds. 202 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] Priority Pollutant Standard Mixtures isotope.com Human Exposure Analysis Standard Mixtures NEW Catalog No. |ES-5511 Compound Extended Phenolic Spiking Solution Amount 10 mL in methanol Labeled 4-Hydroxy-2,3,3’,4’,5-pentachlorobiphenyl (13C12, 99%) 4-Hydroxy-2,2’,3,4’,5,5’-hexachlorobiphenyl (13C12, 99%) 4-Hydroxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl (13C12, 99%) 6-Hydroxy-2,2’,4,4’-tetrabromodiphenyl ether (13C12, 99%) 6’-Hydroxy-2,2’,4,4’,6-pentabromodiphenyl ether (13C12, 99%) 2,4-Dibromophenol (13C6, 99%) 2,4,5-Tribromophenol (13C6, 99%) 2,4,6-Tribromophenol (13C6, 99%) Pentabromophenol (13C6, 99%) Pentachlorophenol (13C6, 99%) Tetrabromobisphenol A (ring-13C12, 99%) 5-Chloro-2-(2,4-dichlorophenoxy)-phenol (triclosan) (13C12, 99%) |ES-5321 NEW Multi-Analyte Recovery Spiking Standard 10 mL in 88% hexane/ 2% dodecane/10% nonane 1.2 mL in nonane |ES-5321-200X-1.2 Multi-Analyte Recovery Spiking Standard Labeled 1,2,3,4-TetraCDD (13C6, 99%) 2,2’,3,3’,4,5,5’,6,6’-NonaCB (13C12, 99%) 3,3’,4,4’-TetraBDE (13C12, 99%) 2,2’,3,4,4’,6-HexaBDE (13C12, 99%) NEW (ng/mL) 10 10 10 10 10 10 10 10 10 100 5 100 |ES-9444 IUPAC 208 77 139 ES-5321 (ng/mL) 2.5 10.0 7.5 7.5 ES-5321-200X-1.2 (ng/mL) 500 2000 1500 1500 Extended Phenolic Native PAR Standard Unlabeled 4-Methoxy-2,3,3’,4’,5-pentachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’,5,5’-hexachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’-tetrabromodiphenyl ether (unlabeled) 3-Methoxy-2,2’,4,4’-tetrabromodiphenyl ether (unlabeled) 5-Methoxy-2,2’,4,4’-tetrabromodiphenyl ether (unlabeled) 6-Methoxy-2,2’,4,4’-tetrabromodiphenyl ether (unlabeled) 4’-Methoxy-2,2’,4,5’-tetrabromodiphenyl ether (unlabeled) 5’-Methoxy-2,2’,4,4’,5-pentabromodiphenyl ether (unlabeled) 6-Methoxy-2,2’,4,4’,5-pentabromodiphenyl ether (unlabeled) 2,4-Dibromoanisole (unlabeled) 2,4,5-Tribromoanisole (unlabeled) 2,4,6-Tribromoanisole (unlabeled) Dimethyl tetrabromobisphenol A (unlabeled) Pentabromoanisole (unlabeled) 5-Chloro-2-(2,4-dichlorophenoxy)-anisole (methyl triclosan) (unlabeled) Pentachloroanisole (unlabeled) 1.2 mL in 91% nonane/ 9% toluene (ng/mL)* 520 519 517 514 514 514 514 514 512 512 528 521 521 263 514 5240 5263 *Concentrations are determined for listed derivatized compounds. tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] 203 Priority Pollutant Standard Mixtures isotope.com Human Exposure Analysis Standard Mixtures NEW NEW NEW NEW NEW NEW NEW Catalog No. |ES-5482 |ES-5482-CS1 |ES-5482-CS2 |ES-5482-CS3 |ES-5482-CS4 |ES-5482-CS5 |ES-5482-CS6 Compound Phenolic Calibration Standards [CS1-CS6] Phenolic Calibration Standard [CS1] Phenolic Calibration Standard [CS2] Phenolic Calibration Standard [CS3] Phenolic Calibration Standard [CS4] Phenolic Calibration Standard [CS5] Phenolic Calibration Standard [CS6] Amount 6 × 0.5 mL in nonane 0.5 mL in nonane 0.5 mL in nonane 0.5 mL in nonane 0.5 mL in nonane 0.5 mL in nonane 0.5 mL in nonane All concentrations are in ng/mL (ppb)* Unlabeled 4-Methoxy-2,3,3’,4’,5-pentachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’,5,5’-hexachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl Pentachloroanisole (unlabeled) 5-Chloro-2-(2,4-dichlorophenoxy)-anisole (methyl triclosan) (unlabeled) Pentabromoanisole (unlabeled) Labeled 4-Methoxy-2,3,3’,4’,5-pentachlorobiphenyl (13C12, 99%) 4-Methoxy-2,2’,3,4’,5,5’-hexachlorobiphenyl (13C12, 99%) 4-Methoxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl (13C12, 99%) Pentachloroanisole (13C6, 99%) 5-Chloro-2-(2,4-dichlorophenoxy)-anisole (methyl triclosan) (ring-13C12, 99%) Pentabromoanisole (13C6, 99%) 1,2,3,4-Tetrachlorodibenzo-p-dioxin (13C6, 99%) 2,2’,3,3’,4,5,5’,6,6’-Nonachlorobiphenyl (13C12, 99%) 3,3’,4,4’-Tetrabromodiphenyl ether (13C12, 99%) 2,2’,3,4,4’,6-Hexabromodiphenyl ether (13C12, 99%) IUPAC 208 77 139 CS1 0.52 0.52 0.52 0.53 CS2 1.04 1.04 1.03 1.05 CS3 10.4 10.4 10.3 10.5 CS4 104 104 103 105 CS5 520 519 517 526 CS6 5200 5190 5170 5260 0.52 1.05 10.5 105 524 5240 0.51 1.03 10.3 103 514 5140 104 104 104 104 104 104 104 104 104 104 104 104 103 103 103 103 103 103 263 263 263 263 263 263 262 262 262 262 262 262 103 25 100 75 75 103 25 100 75 75 103 25 100 75 75 103 25 100 75 75 103 25 100 75 75 103 25 100 75 75 *Concentrations are determined for listed derivatized compounds. 204 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] Priority Pollutant Standard Mixtures isotope.com Human Exposure Analysis Standard Mixtures NEW Catalog No. |ES-5483 Compound Phenolic Spiking Standard Amount 10 mL in acetonitrile Labeled 4-Hydroxy-2,3,3’,4’,5-pentachlorobiphenyl (13C12, 99%) 4-Hydroxy-2,2’,3,4’,5,5’-hexachlorobiphenyl (13C12, 99%) 4-Hydroxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl (13C12, 99%) Pentachlorophenol (13C6, 99%) 5-Chloro-2-(2,4-dichlorophenoxy)-phenol (triclosan) (13C12, 99%) Pentabromophenol (13C6, 99%) NEW |ES-5321 Multi-Analyte Recovery Spiking Standard |ES-5321-200X-1.2 Multi-Analyte Recovery Spiking Standard Labeled 1,2,3,4-Tetrachlorodibenzo-p-dioxin (13C6, 99%) 2,2’,3,3’,4,5,5’,6,6’-Nonachlorobiphenyl (13C12, 99%) 3,3’,4,4’-Tetrabromodiphenyl ether (13C12, 99%) 2,2’,3,4,4’,6-Hexabromodiphenyl ether (13C12, 99%) NEW |ES-5496 (ng/mL) 10 10 10 25 25 10 10 mL in 88% hexane/2% dodecane/10% nonane 1.2 mL in nonane IUPAC 208 77 139 ES-5321 (ng/mL) 2.5 10 7.5 7.5 Phenolic Native PAR Standard ES-5321-200X-1.2 (ng/mL) 500 2000 1500 1500 1.2 mL in nonane Unlabeled 4-Methoxy-2,3,3’,4’,5-pentachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’,5,5’-hexachlorobiphenyl (unlabeled) 4-Methoxy-2,2’,3,4’,5,5’,6-heptachlorobiphenyl (unlabeled) Pentachloroanisole (unlabeled) 5-Chloro-2-(2,4-dichlorophenoxy)-anisole (methyl triclosan) (unlabeled) Pentabromoanisole (unlabeled) (ng/mL) 1 1 1 1 1 1 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected] 205 Priority Pollutant Standard Mixtures isotope.com Human Exposure Analysis Standard Mixtures NEW Catalog No. |ES-5535 Compound JECS Labeled Mixture Solution Labeled 8-Hydroxy-2’-deoxyguanosine (15N5, 98%) DL-Cotinine (2’,3’,4’-13C3, 99%) NEW |ES-5536 Amount 1.2 mL in water (ng/mL) 7500 150 JECS Native Mixture Solution Unlabeled 8-Hydroxy-2’-deoxyguanosine (unlabeled) Cotinine (unlabeled) 1.2 mL in water (ng/mL) 500 500 206 tel: +1.978.749.8000 | fax: +1.978.749.2768 | 1.800.322.1174 (North America) | [email protected]
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