IMPORTANT POLYATOMIC IONS 1– Ions 2 – Ions nitrate NO3 chromate CrO42– nitrite bicarbonate (hydrogen carbonate) perchlorate NO2– dichromate Cr2O72– HCO3– sulfate SO42– ClO4– sulfite SO32– chlorate ClO3– carbonate CO32– chlorite ClO2– oxalate C2O42– – hypochlorite ClO peroxide O22– cyanide CN– hydrogen phosphite HPO32– hydroxide OH– – 3 – Ions – acetate CH3CO2 – permanganate MnO4 hydrogen sulfate HSO4– PO43– borate BO33– 1+ Ion – dihydrogen phosphate phosphate H2PO4 NH4+ ammonium FLOWCHART FOR NAMING COMPOUNDS Does the compound contain a metal (or ammonium ion, NH4+)? Yes Ionic compound (If binary, contains a metal cation with a nonmetal anion) Molecular compound or acid (If binary, contains two nonmetals) Can the metal form more than one type of cation? Does the compound contain hydrogen and is it dissolved in water where it behaves as an acid? Yes The name of the metal ion is written first, followed by a Roman numeral in parentheses to show the charge on the metal. Then write the name of the nonmetal (with an –ide ending) or the name of the polyatomic ion. For example, Cr2(SO4)3 is chromium(III) sulfate. bau02672_endsheetsback.indd ii No No The name of the metal (or ammonium) ion is written first, followed by the name of the nonmetal (with an –ide ending) or the name of the polyatomic ion. For example, MgCl2 is magnesium chloride. Yes In water, name the compound as an acid. For example, H2S(aq) is hydrosulfuric acid. No Use prefixes to indicate the number of atoms for each element. For example, H2S is dihydrogen sulfide. 10/27/11 3:51 PM FUNDAMENTAL PHYSICAL CONSTANTS (FOUR SIGNIFICANT FIGURES) Avogadro’s number = 6.022 × 1023 particles/mol atomic mass unit, amu = 1.661 × 10–24 g Planck’s constant, h speed of light in a vacuum, c = 6.626 × 10–34 J • s = 2.998 × 108 m/s universal gas constant, R = 8.206 × 10–2 (L• atm)/(mol• K) CONVERSIONS AND RELATIONSHIPS Length 1 km Volume Mass 1 liter (L) = 1.057 quarts (qt) 1 cm3 = 1 mL = 1000 m = 0.62 mile (mi) 1 inch (in) = 2.54 cm 1 m3 = 35.3 ft3 1m 1 fluid oz = 29.57 mL 1 gal = 3.785 L = 1.094 yards (yd) Energy 1 kg = 2.205 lb 1 metric ton (t) = 103 kg 1 lb (16 oz) = 453.6 g Temperature Pressure 1 cal = 4.184 J 0K 1 atm 1 Cal = 1000 cal mp of H2O = 0°C (273.15 K) = –273.15°C bp of H2O = 100°C (373.15 K) TK T°C T°F = 1.013 × 105 Pa = 760 torr 1 torr = 1 mm Hg = T°C + 273.15 = (T°F – 32) 59 = 1.8T°C + 32 SI UNIT PREFIXES pico- nano- micro- milli- centi- deci- kilo- mega- giga- p n μ m c d k M G –12 10 bau02672_endsheetsback.indd iii 10 –9 –6 10 10 –3 10 –2 10 –1 10 3 10 6 109 10/27/11 3:51 PM
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