10/26/2014 What Does Periodic Mean? The properties of the elements are periodic functions of their atomic numbers. Huh? As atomic number increases, certain properties of atoms repeat periodically PeriodicallyAt regular intervals Unit 5: The Periodic Table Lesson 5.1: The Development of the Periodic Table. 1 2 The History of the Modern Periodic Table During the nineteenth century, chemists began to categorize the elements according to similarities in their physical and chemical properties. The end result of these studies was our modern periodic table. Antoine Lavoisier Johann Dobereiner • Early classification of elements – First person to attempt to sort elements into groups – First periodic table, which contained 33 elements – Periodic table based on chemical properties – Some of these were later found to be compounds – The table did show a distinction between metals and non-metals In 1829, he classified some elements into groups of three, which he called triads. The elements in a triad had similar chemical properties and orderly physical properties. (ex. Cl, Br, I and Ca, Sr, Ba) Model of triads 1780 - 1849 1 10/26/2014 William Odling John Newlands • 1864 - Classification of elements into two dimensions – Found a horizontal connection between the elements fluorine, oxygen, nitrogen and carbon (first element in groups 1 – 4) – Overcame problems that mandeleev has on 1st attempt – Did not get credit for all his work In 1863, he suggested that elements be arranged in “octaves” because he noticed (after arranging the elements in order of increasing atomic mass) that certain properties repeated every 8th element. – Not true past Ca Law of Octaves 1838 - 1898 (1829-1921) Dmitri Mendeleev Lothar Meyer A German chemist, Worked on classification of the elements. His periodic law, stated that the properties of the elements are periodic functions of their atomic weights. Was late to publish – did not get 1830 - 1895 credit • In 1869 he published a table of the elements organized by increasing atomic mass. • Received more credit than Mayer He left spaces in his table for as yet undiscovered elements, and predicted properties of those elements. 1834 - 1907 Henry Moseley – Though a good model, Mendeleev could not explain inconsistencies, for instance, all elements were not in order according to atomic mass – 1913 - Henry Moseley explained the discrepancy – Discovered correlation between number of protons (atomic number) and frequency of X rays generated – Today, elements are arranged in order of increasing ATOMIC NUMBER The Modern Periodic Law Henry Moseley (1887 – 1915) 11 • This is the basis for the modern Periodic Table 12 2 10/26/2014 Periodic Table by Dates of Discovery 13 3
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