Carbohydrates Douglas Wilkin, Ph.D. Jean Brainard, Ph.D. Say Thanks to the Authors Click http://www.ck12.org/saythanks (No sign in required) To access a customizable version of this book, as well as other interactive content, visit www.ck12.org CK-12 Foundation is a non-profit organization with a mission to reduce the cost of textbook materials for the K-12 market both in the U.S. and worldwide. Using an open-source, collaborative, and web-based compilation model, CK-12 pioneers and promotes the creation and distribution of high-quality, adaptive online textbooks that can be mixed, modified and printed (i.e., the FlexBook® textbooks). Copyright © 2016 CK-12 Foundation, www.ck12.org The names “CK-12” and “CK12” and associated logos and the terms “FlexBook®” and “FlexBook Platform®” (collectively “CK-12 Marks”) are trademarks and service marks of CK-12 Foundation and are protected by federal, state, and international laws. Any form of reproduction of this book in any format or medium, in whole or in sections must include the referral attribution link http://www.ck12.org/saythanks (placed in a visible location) in addition to the following terms. Except as otherwise noted, all CK-12 Content (including CK-12 Curriculum Material) is made available to Users in accordance with the Creative Commons Attribution-Non-Commercial 3.0 Unported (CC BY-NC 3.0) License (http://creativecommons.org/ licenses/by-nc/3.0/), as amended and updated by Creative Commons from time to time (the “CC License”), which is incorporated herein by this reference. Complete terms can be found at http://www.ck12.org/about/ terms-of-use. Printed: September 24, 2016 AUTHORS Douglas Wilkin, Ph.D. Jean Brainard, Ph.D. www.ck12.org C HAPTER • • • • Chapter 1. Carbohydrates 1 Carbohydrates Identify the chemical formula of glucose. Describe the structure and function of monosaccharides. List significant polysaccharides. Identify the role of significant polysaccharides. Sugar. Does this look like biological energy? As a child, you may have been told that sugar is bad for you. Well, that’s not exactly true. Essentially, carbohydrates are made of sugar, from a single sugar molecule to thousands of sugar molecules attached together. Why? One reason is to store energy. But that does not mean you should eat it by the spoonful. Carbohydrates Carbohydrates are the most common type of organic compound. A carbohydrate is an organic compound such as sugar or starch, and is used to store energy. Like most organic compounds, carbohydrates are built of small, repeating units that form bonds with each other to make a larger molecule. In the case of carbohydrates, the small repeating units are called monosaccharides. Carbohydrates contain only carbon, hydrogen, and oxygen. Monosaccharides and Disaccharides A monosaccharide is a simple sugar such as fructose or glucose. Fructose is found in fruits, whereas glucose generally results from the digestion of other carbohydrates. Glucose (C6 H12 O6 ) is used for energy by the cells of most organisms, and is a product of photosynthesis. The general formula for a monosaccharide is: (CH2 O)n , 1 www.ck12.org where n can be any number greater than two. For example, in glucose n is 6, and the formula is: C6 H12 O6 . Another monosaccharide, fructose, has the same chemical formula as glucose, but the atoms are arranged differently. Molecules with the same chemical formula but with atoms in a different arrangement are called isomers. Compare the glucose and fructose molecules in Figure 1.1. Can you identify their differences? The only differences are the positions of some of the atoms. These differences affect the properties of the two monosaccharides. FIGURE 1.1 Sucrose Molecule. This sucrose molecule is a disaccharide. It is made up of two monosaccharides: glucose on the left and fructose on the right. If two monosaccharides bond together, they form a carbohydrate called a disaccharide. An example of a disaccharide is sucrose (table sugar), which consists of the monosaccharides glucose and fructose (Figure 1.1). Monosaccharides and disaccharides are also called simple sugars. They provide the major source of energy to living cells Polysaccharides A polysaccharide is a complex carbohydrate that forms when simple sugars bind together in a chain. Polysaccharides may contain just a few simple sugars or thousands of them. Complex carbohydrates have two main functions: storing energy and forming structures of living things. Some examples of complex carbohydrates and their functions are shown in Table 1.1. Which type of complex carbohydrate does your own body use to store energy? TABLE 1.1: Complex Carbohydrates Name Starch Function Used by plants to store energy. Example A potato stores starch in underground tubers. 2 www.ck12.org Chapter 1. Carbohydrates TABLE 1.1: (continued) Name Glycogen Function Used by animals to store energy. Example A human stores glycogen in liver cells. Cellulose Used by plants to form rigid walls around cells. Plants use cellulose for their cell walls. Chitin Used by some animals to form an external skeleton. A housefly uses chitin for its exoskeleton. MEDIA Click image to the left or use the URL below. URL: https://www.ck12.org/flx/render/embeddedobject/165460 Biofuels: From Sugar to Energy For years there’s been buzz, both positive and negative, about generating ethanol fuel from corn. Is this a good idea? Is it necessary? These questions need to be discussed. However, the Bay Area of California is rapidly becoming a world center for the next generation of green fuel alternatives. The Joint BioEnergy Institute is developing methods to isolate biofuels from the sugars in cellulose. 3 www.ck12.org MEDIA Click image to the left or use the URL below. URL: https://www.ck12.org/flx/render/embeddedobject/466 As you view Biofuels: Beyond Ethanol, focus on these concepts: 1. the use of "cellulosic biomass," 2. what is meant by "directed evolution." Summary • Carbohydrates are organic compounds used to store energy. • A monosaccharide is a simple sugar, such as fructose or glucose. • Complex carbohydrates have two main functions: storing energy and forming structures of living things. Review 1. What is a carbohydrate? 2. List three facts about glucose. 3. Assume that you are trying to identify an unknown organic molecule. It contains only carbon, hydrogen, and oxygen and is found in the cell walls of a newly discovered plant species. What type of organic compound is it? Why? 4. Compare and contrast the structures and functions of simple sugars and complex carbohydrates. References 1. User:Booyabazooka/Wikimedia Commons. Structure of a sucrose molecule . Public Domain 4
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