27th International Symposium
on Organic Chemistry of Sulfur
July 24–29, 2016
Jena/Germany
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Table of Contents
Organisation and Imprint................................................................................... 4
Welcome Notes.................................................................................................. 6
General Information........................................................................................... 9
Sponsors and Exhibitors..................................................................................... 15
Social and Cultural Programme.......................................................................... 16
Plenary Speakers................................................................................................ 18
Programme Overview
Sunday/Monday, July 24/25...................................................................... Tuesday/Wednesday, July 26/27............................................................... Thursday/Friday, July 28/29...................................................................... 21
22
23
Scientific Programme
Sunday, July 24.......................................................................................... 24
Monday, July 25......................................................................................... 27
Tuesday, July 26......................................................................................... 31
Wednesday, July 27................................................................................... 35
Thursday, July 28....................................................................................... 36
Friday, July 29............................................................................................ 40
Poster Presentations.......................................................................................... 41
Index of Plenary Speakers, Invited Speakers, Presenting Authors and Chairs.... 48
Abstracts
Table of Contents....................................................................................... 51
Talks........................................................................................................... 52
Posters....................................................................................................... 128
Index of Authors........................................................................................ 191
City Map ............................................................................................................ 195
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Organisation and Imprint
Venue
July 24, 2016
Institute of Inorganic & Analytical Chemistry
Humboldtstraße 8 • 07743 Jena (DE)
July 25–29, 2016
Friedrich-Schiller-University Jena
Carl-Zeiss-Straße 3 • 07743 Jena (DE)
Date
July 24–29, 2016
Conference Website
www.isocs-27.org
Conference Language
English
Conference Chair
Prof. Dr. Wolfgang Weigand
Friedrich-Schiller-University Jena
Department of Inorganic and Analytical Chemistry
Humboldtstraße 8 • 07743 Jena (DE)
Conference Organisation and Industrial Exhibition
Conventus Congressmanagement & Marketing GmbH
Anja Hannawald
Carl-Pulfrich-Straße 1 • 07745 Jena (DE)
Phone +49 3641 31 16-327 • Fax +49 3641 31 16-243
[email protected] • www.conventus.de
Design/Layout
Layout Print Circulation Editorial Deadline 4
krea.tif-studio UG (haftungsbeschränkt)
Junggebauer Medien GmbH
250
July 11, 2016
27th International Symposium on Organic Chemistry of Sulfur
Organisation and Imprint
International Committee
Jósef Drabowicz (Częstochowa/PL)
Jose Luis Garcia Ruano (Madrid/ES)
Richard S. Glass (Tucson, AZ/US) – Chair
Mikhail Krayushkin (Moscow/RU)
Marian Mikolajczyk (Łódź/PL)
Stefano Menichetti (Florence/IT)
Juzo Nakayama (Saitama/JP)
Mogens B. Nielsen (Copenhagen/DK)
Turan Ozturk (Istanbul/TR)
Stephane Perrio (Caen/FR)
Ernst Schaumann (Clausthal/DE)
National Advisory Board
Peter Bäuerle (Ulm/DE)
Carsten Bolm (Aachen/DE)
Egon Fanghänel (Merseburg/DE)
Claus Jacob (Saarbrücken/DE)
Michael Reggelin (Darmstadt/DE)
Ralf Steudel (Berlin/DE)
Local Organizing Committee
Hans-Dieter Arndt (Jena/DE) – Vice-Chairman
Rainer Beckert (Jena/DE)
Jozef Drabowicz (Częstochowa/PL)
Christian Hertweck (Jena/DE)
Olaf Klobes (Greiz/DE)
Grzegorz Mloston (Łódź/PL) – Vice-Chairman
Christian Robl (Jena/DE)
Ulrich S. Schubert (Jena/DE)
Previous „International Symposia on the Organic Chemistry of Sulfur“ have taken place in:
Lódz, Poland 1990
Liblice, CSR 1964
Caen, France 1992
Groningen, The Netherlands 1966
Merseburg, Germany 1994
Caen, France 1968
Tsukuba, Japan 1996
Venice, Italy 1970
Florence, Italy 1998
Lund, Sweden 1972
Sheffield, UK 2000
Bangor, UK 1974
Flagstaff, US 2002
Hamburg, Germany 1976
Madrid, Spain 2004
Portoroz, Yugoslavia 1978
Saitama, Japan 2006
Riga, Latvia 1980
Moscow, Russia 2008
Bangor, UK 1982
Florence, Italy 2010
Lindau, Germany 1984
Częstochowa, Poland 2012
Nijmegen, UK 1986
Istanbul, Turkey 2014
Odense, Denmark 1988
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Welcome Note of the conference chair
Dear Colleagues,
It is my great honor and pleasure to welcome all delegates and guests at ISOCS 27 – the
27th International Symposium on Organic Chemistry of Sulfur, to be held at Jena from
July 24–29, 2016. Chemistry at Jena has a long and successful tradition dating back to
1789, when Friedrich August Göttling was appointed chair of chemistry at the University of Jena. In 2016 our chemistry faculty is celebrating the 200th anniversary of the
chemical institute that was brought to life by Johann Wolfgang Döbereiner (successor
to Göttling) in 1816 with great support of Johann Wolfgang von Goethe, at the time
minister of science to the local Duke of Sachsen-Weimar-Eisenach. In this chemistry
institute (the building is located at Neugasse 23 and still used by the university), Döbereiner discovered the catalytic activity of Platinum, invented “Döbereiner’s lighter”,
and made progress in defining systematic “triad” rules for the chemical reactivity of
the elements, an early form of the periodic table.
As of today about 200 participants from nearly 30 countries have registered. The
meeting will feature 6 plenary lectures, 20 invited lectures, 40 oral presentations and
nearly 70 posters focused on the frontiers of all aspects of Organic Sulfur Chemistry.
Looking at the names of those who have accepted to give talks it is easy to predict a
high scientific level for the meeting. It has been one of our major motivations to enable especially young scientists for giving short oral communications, which have been
selected from the Organisation Committee. On Tuesday afternoon we are organizing
that special session for young scientists for giving them an opportunity to present
their exciting work in the whole auditorium.
Furthermore, there will be two dedicated poster sessions during the conference. We
are deeply grateful to the precious support of the Taylor and Francis Group who have
sponsored three poster awards.
Sincere thanks are due to the speakers, to the International Committee and the National Advisory Board for their important contributions to the scientific contents, the
Local Organizing Committee and the vice-chairs Hans-Dieter Arndt/Jena and Grzegorz
Mloston/Lodz for the invaluable help given in the organization of the symposium.
We sincerely hope that participants will appreciate great benefit from the conference
and will also enjoy their stay in Thuringia, one of the most historic and scenic regions
of Germany.
In closing, let me wish us all a scientifically exciting and stimulating
meeting on all aspects of the Organic Chemistry of Sulfur - and
beyond!
Sincerely,
Wolfgang Weigand
On behalf of the Organizing Committee
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27th International Symposium on Organic Chemistry of Sulfur
Welcome Note of the State Secretary
Ladies and Gentlemen,
Participants in the 27th International Symposium on Organic Chemistry of Sulfur,
On behalf of the Federal Ministry of Education and Research I would like to welcome
you to Jena to exchange the latest ideas and results on the organic chemistry of sulfur.
Unfortunately, sulfur does not enjoy the best reputation among the general public.
It is usually associated with a bad smell and even with the devil himself. But from
a scientific or technical point of view, this is not at all justified. Due to its chemical
properties sulfur occurs as a building block in a huge variety of inorganic and organic compounds. Compounds with sulfur moieties are omnipresent and demonstrate
interesting properties that are used in a great number of applications, ranging from
pharmaceuticals to fertilizers. In fact, the world around us would be quite different
without sulfur and its chemical properties.
Apart from the scientific insights to be gained by investigating the properties of sulfur,
we can also expect valuable contributions to the development of new materials. The
Federal Ministry of Education and Research is addressing this aspect as part of the
German federal government’s new “High-Tech Strategy”. The funding program “From
Materials to Innovations”, for instance, sets out to push the limits of technology and
new materials. Recently, many new materials have been developed with the support
of the Ministry’s funding schemes where sulfur-containing organic compounds have
been essential. One remarkable example is the development of macromolecular and
polymeric active materials for use in organic light-emitting devices (OLEDs) and organic
photovoltaic cells (OPVCs). The electrical and optical features of the materials used
for the active layer of OLEDs and OPVCs can be tuned and optimized for a specific
application by incorporating sulfur-containing heterocyclic aromatics, e.g. thiophene
and thiazole. This technology is just entering the market in the form of highly efficient
displays and lightweight or flexible devices.
I wish all the participants in the 27th International Symposium on Organic Chemistry of
Sulfur fruitful discussions and new insights which will advance our scientific knowledge
as well as our capability for science-based innovation.
Best wishes
State Secretary
Dr. Georg Schütte
Federal Ministry of Education and Research, Germany
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Welcome Note of the INTERNATIONAL COMMITTEE
Dear Colleagues,
On behalf of the International Committee for ISOCS, it is my pleasure to welcome
you to ISOCS-27.
In 1964 Professor Horak and his colleagues invited a small group of chemists to the
first conference on organic sulfur chemistry convened in a castle in Liblice near Prague.
This remote venue proved conducive to vigorous and insightful discussions which have
been the hallmark of these conferences. The innovative meeting in Liblice and the
expanding impact of sulfur chemistry resulted in prestigious biennial ISOCS conferences all over the world, eagerly awaited by the scientific community, for over fifty
years. In addition to formal and informal presentations these meetings feature vigorous discussions in a congenial atmosphere in the lecture halls, at poster sessions and
at informal social gatherings.
Professor Weigand, his local Organizing Committee, National Advisory Board and
Conventus have organized an outstanding ISOCS-27 meeting both scientifically and
socially. This is a wonderful opportunity to make new friends, initiate new contacts, be
inspired scientifically, have your ideas critically discussed, receive recognition for your
insights, attend the industrial exposition and enjoy the cuisine, culture and ambience
of Jena and Thuringia.
The members of the International Committee wish that you personally benefit from
these outstanding opportunities!
Best wishes,
Professor Richard S. Glass
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27th International Symposium on Organic Chemistry of Sulfur
General Information
Registration
Registration is required. Please register online at www.isocs-27.org.
Registration Fees
Scientific Programme
Regular participants
Students*
Accompanying person
Day ticket
*
650 EUR
350 EUR
260 EUR
150 EUR
Please send a confirmation of your status either to [email protected], Fax +49 3641 31 16-244
or by mail to Conventus GmbH • Carl-Pulfrich-Straße 1 • 07745 Jena (DE) indicating the keyword: ISOCS.
The registration fee for all days includes
• Admission to all scientific sessions and industrial exhibition
• Welcome Reception
• Evening Reception in the historic town hall
• Catering during coffee and lunch breaks
• Conference materials (conference bag, programme and abstract booklet)
Social Programme
Welcome Reception with beer and „Bratwurst“
Guided City Tour Jena
Evening reception in the historic townhall
Conference trip to Weimar
Organ concert
Banquet
0 EUR
30 EUR
0 EUR
0 EUR
0 EUR
60 EUR
Payment and Confirmation of Payment
An invoice or confirmation of registration will be sent to you via postal or electronic
mail within 14 days. This is a valid invoice which may be submitted to the local tax
and revenue office. All fees are due upon receipt of invoice/registration confirmation.
Payment transfers must include participant’s name and invoice number. Payment is
also accepted by credit card (Master-/Eurocard, American Express, VISA). Should you
transfer your invoice amount within 10 days of the start of the event, please present
your transfer remittance slip onsite.
Accommodation
A contingent of rooms at special rates is reserved in different hotels in Jena. Please
refer to www.isocs-27.org for further information.
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General Information
Opening hours
July 24
July 25
July 26
July 27
July 28
July 29
Check–In
16.30–18.00
08.00–18.00
08.00–18.30
08.00–13.00
08.00–17.00
08.00–12.00
Media Check–In
–
08.00–18.00
08.00–18.30
08.00–12.00
08.00–17.00
08.00–11.00
Industrial Exhibition
–
10.30–19.00
08.00–19.30
08.00–13.00
08.00–17.30
08.00–13.00
Internet
Free WIFI is available in the entire conference area. Please ask at the check-in desk
for the login data.
Submitting your Presentation/Technical Information
Please prepare your presentation in 4:3 aspect ratio. A presentation note-book with
a PDF reader and MS Office PowerPoint 2007 will be provided. The use of personal
notebooks is possible upon agreement. Please provide an adapter for VGA if necessary. A notebook, presenter and laser pointer are available at the speaker’s podium
in the Lecture Hall. A technical supervisor will help you.
Speakers Preparation
Please submit your presentation at the media check-in in the Lecture Hall no later than
90 minutes before the presentation begins. You may view and/or edit your presentation. For submission, please use a USB flash drive.
Please prepare your presentation for the allotted amount of time (incl. discussion).
Chairs and moderators may interrupt should you overrun your time limit.
• Plenary speakers 50 minutes
• Invited speakers 30 minutes
• Abstract speakers 20 minutes
Poster Session
All posters will be shown during the poster sessions on Monday and Tuesday. Posters
should be prepared in size DIN A0 (width 84.1 cm x height 118.9 cm) and not laminated. Mounting materials will be provided. Poster authors are asked to be present
at their poster during the poster sessions. The posters should be removed by Friday,
July 29, 2016, 11.00 hrs. Poster prizes will be awarded on Thursday evening during
the Conference Dinner.
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27th International Symposium on Organic Chemistry of Sulfur
General Information
Cooperation with German Railways
Conventus has partnered up with Deutsche Bahn to create an exclusive
deal that allows you to travel conveniently to the 27th International
Symposium on Organic Chemistry of Sulfur to Jena.
Take advantage and make the journey time yours. Use your outward and return journeys to work, read or relax. Whatever you decide to do, your long-distance travel with
the Event Ticket will be powered by 100% renewable energy.
Your Event Ticket for a return journey* to and from all
train stations in Germany is priced as follows:
Ticket for booked trains
2nd class EUR 99
1st class EUR 159
Fully flexible ticket
2nd class EUR 139
1st class EUR 199
We would be happy to inform you about ticket prices for international journeys on
request. Click to book your ticket quickly and easily online:
http://www.isocs-27.org/travel-hotels/
This special offer is valid for all events and congresses of Conventus Congressmanagement & Marketing GmbH in 2016. To book please follow the online link above or call
+49 1806 – 31 11 53** and state “Conventus” as reference. Please have your credit
card ready when booking.*** Your booking will be binding after Deutsche Bahn’s
confirmation.
We wish you a pleasant journey!
*
**
***
An advance booking of at least three days is required. Changes and reimbursement before the first
day of validity are possible. Changes and reimbursement conditions at the time of the ticket booking
according to Conditions of Carriage of the DB of Sparpreis fares. Changes and reimbursement are
excluded from the first day of validity onwards. Passengers restrict themselves to a particular train
and travel times. For a supplement of Euro 40 full flexible tickets are also available for domestic travels
within Germany.
The booking line is available from Monday to Saturday 07.00–22.00 hrs. Calls will be charged
at Euro 0.20 per call, from mobiles Euro 0.60 per call at maximum.
Please note that Deutsche Bahn AG introduced a surcharge for all credit card payments in accordance
with the conditions of carriage for persons travelling with Deutsche Bahn AG companies (“BB Personenverkehr”)
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General Information
Travel
By train
There are two train stations in Jena. Station “West” is currently under construction
and closed for all trains. Trains will be redirected to station Jena “Paradies”.
From station “Paradies” to the conference venue – 10 minutes by foot:
• After leaving the train station, cross the main road in front of the station and walk
straight ahead into the street “Am Volksbad”
• Pass the bus station and turn left into “Grietgasse”, follow the street for 150 m
• At the crossroads turn right and walk on “Schillerstraße” for about 120 m
• Then turn left, follow the same route as the tram runs, into Ernst-Abbe-Platz
By plane
Jena is located in the middle of Germany. You can reach Jena from the following
airports by car or train very fast:
Leipzig
1 hour
Berlin
2,5 hours
Frankfurt a. M. 3 hours
Dresden 2,5 hours
By car
Address for navigation devices:
Campus der Friedrich-Schiller-Universität Jena
Carl-Zeiss-Straße 3/Ernst-Abbe-Platz • 07743 Jena (DE)
Parking
The following chargeable parking possibilities near to the campus are available:
• Parking garage of the „Neue Mitte“ (distance to the venue: 160 m)
• Parking „Eichplatz“ (distance to the venue: 250 m)
• Parking garage of the “Goethe Galerie” (distance to the venue: 400 m)
The costs are on average 0.50 EUR/30 minutes.
Limited parking places without costs may be available in the nearby residential areas,
however free parking in the city of Jena is very limited.
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27th International Symposium on Organic Chemistry of Sulfur
General Information
Useful Country Information
Citizens of the EU
EU nationals do not require a visa to enter the Federal Republic of Germany.
Non-EU citizens
All Non-EU citizens require a visa. However, a visa is not required for visits of up to
90 days in an 180 day period for nationals of those countries for which the European
Community has abolished the visa requirement.
You may apply for short stay visas (Schengen Visas) at missions of the German Federal
Foreign Office, such as embassies and consulates.
Please also visit the homepage of “Auswärtiges Amt” www.auswaertiges-amt.de to
find a detailed table of all countries requiring a visa and more information on visa
regulations, as well as a list of German missions around the world.
Invitation Letter
An invitation letter for the purpose of obtaining a travel visa or permission to attend the
meeting will be handed out on request after successful registration for the conference.
Weather
The average temperature in July in Jena is around 25°C.
Please also check www.weather.com for up-to-date weather forecasts.
Currency
As in most countries of the European Union, the official German currency is the Euro
(€). Please note that there are no general bank hours in Germany. Most banks are
open in the morning hours and just a few hours in the afternoon or early evening.
Major credit cards are accepted at most cashpoints, stores, restaurants and hotels.
Language
English is spoken by the staff of most hotels, restaurants and shops.
Telephone and internet
Germany’s international pre-dial is +49 (0049).
Public places like airports, universities, libraries, restaurants and cafés may offer “free”WiFi Hotspots.
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General Information
Electricity
The electrical power supply in Germany is 220v, 50 Hz, AC.
Official plugs in Germany are:
“Schukostecker” (round) Type F/ CEE 7/4
“Eurostecker” (flat) Type C/ CEE 7/16
Time
Germany’s standard time zone is UTC/GMT +1 hour.
Health
All visitors are advised to have valid international insurance before coming to Germany.
Citizens of the EU are insured with their EHIC (European Health Insurance Card).
© JenaKultur l Andreas Hub
14
27th International Symposium on Organic Chemistry of Sulfur
Sponsors and Exhibitors
Main Sponsors
Chevron Phillips Chemicals International N. V. (Overijse/BE) Sponsors
Akzo Nobel Functional Chemicals GmbH (Greiz/DE)
DSM (Basel/CH)
Bayer Pharma AG (Berlin/DE)
Bruno Bock Chemische Fabrik GmbH & Co. KG (Marschacht/DE)
The Journal of Organic Chemistry/
ACS Publications (Washington, WA/US) Deutsche Forschungsgemeinschaft
(Bonn/DE)
Fonds der chemischen Industrie im Verband der chemischen Industrie
(Frankfurt am Main/DE)
Gesellschaft Deutscher Chemiker
(Frankfurt am Main/DE)
Exhibitors
Chevron Phillips Chemicals International N. V. (Overijse/BE)
Taylor and Francis Group (Abington/GB)
NORMAG Labor- und Prozesstechnik GmbH (Ilmenau/DE)
TCI Europe NV (Eschborn/DE)
J & K Scientific bvba (Overpelt/BE)
Magritek GmbH (Aachen/DE)
Poster Prizes are kindly sponsored by
Taylor and Francis Group (Abington/GB)
Wiley-VCH Verlag GmbH & Co. KGaA
State at printing
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Social and Cultural Programme
Welcome Reception with beer and “Bratwurst”
Come together for drinks and snacks to enjoy the evening before the forthcoming conference. Allow yourself
interesting conversations with colleagues, old friends
and meet new acquaintances.
Date
Time
Venue
Fee
Sunday, July 24, 2016
© photocrew l fotolia.com
19.00–21.00
Institute of Inorganic and Analytical Chemistry
Humboldtstraße 8 • 07743 Jena
free, registration required
Guided City Tour Jena
Enjoy a comprehensive sightseeing tour in Jena. The
tour will show you around the lively student city that
became famous both for its university and the worldwide
known company of Carl Zeiss. You will visit the historical
old town with town gate, the church St. Michael, the
historical market and the town hall as well as the historical premises of Carl Zeiss company and the historic
buildings of Friedrich-Schiller University.
Date
Time
Meeting point
Fee
© Marcus Olbrich l wikimedia.org
Monday, July 25, 2016 10.00–13.00
Congress Venue – Check-In
30 EUR
Evening Reception in the Historic Town Hall
During the evening reception in the historic town hall all
participants will be welcomed in Jena by the representatives of the town. Food and beverages will be served.
Date
Time
Venue
Fee
16
Monday, July 25, 2016
19.30–21.00
Rathausdiele in the historic town hall
Markt 1 • 07743 Jena
free, registration required
© Juergen l fotolia.com
27th International Symposium on Organic Chemistry of Sulfur
Social and Cultural Programme
Conference Trip to Weimar
During this tour you will follow the Goethe traces to the Goethe
house, the National Museum with the permanent exhibition, then
pass the unique historical library of Anna Amalia, the GoetheSchiller-Archive (with Goethe’s hand-written estate) to the famous
Goethe Garden house in the wide Ilmpark. Most of the sights
related to Goethe are part of the UNESCO World Heritage “Classical Weimar”. Before going back to Jena you will have a little snack
at the Villa Haar.
Date
Time
Meeting point
Fee
Wednesday, July 27, 2016
© l-pics l fotolia.com
13.00–20.00
Bus shuttle: 12.45 corner of Carl-Zeiss-Straße/Carl-Zeiss-Platz
free, registration required
Organ Concert
Date
Time
Venue
Fee
Wednesday, July 27, 2016
20.00–21.00
St. Michael town church
Kirchplatz 1 • 07743 Jena
free, registration required
Banquet
On top of the mountain “Hausberg“ you will have a
comfortable evening at the restaurant “Fuchsturm“. Experience a unique look over the whole city of Jena and
its vicinity. Have a relaxed dinner of typical thuringian
specialities in a rustical, homely surrounding – in good
weather willingly served in the picturesque garden.
Enjoy this last evening of the conference with your colleagues in this beautiful landscape.
Date
Time
Venue
Fee
© Daniel Schlesinger l wikimedia.org
Thursday, July 28, 2016
19.30–23.30
Restaurant Fuchsturm Jena
Turmgasse 26 • 07749 Jena
60 EUR
Shuttle to the restaurant:
Departure 19.00 on the corner of Carl-Zeiss-Straße/Carl-Zeiss-Platz
Shuttle back to the city:
Departure 23.30 Fuchsturm
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Plenary Speakers
Prof. Paul Alewood
Paul Alewood is Professor at the Division of Chemistry and Structural Biology in the Institute for Molecular Bioscience (IMB) at the
University of Queensland. He has an international reputation in the
field of bioactive peptides and synthetic proteins and is the author of
over 300 publications in high quality journals. He is also an inventor
on 14 licensed patents that underpin peptide drug candidates with
two candidates going into man. He was a prime mover in establishing the IMB, the Melbourne-based peptide company Auspep, and
Xenome, a spin-off biopharmaceutical company from the University
of Queensland focusing on pain drugs.
Professor Alewood’s research group comprises approximately 10 research students,
assistants and postdoctoral fellows in the broad fields of peptide, protein and medicinal
chemistry. Research projects include the development of the chemical synthesis of
cysteine-rich bioactive peptides, the design and synthesis of new peptide drugs, peptidomimetics and proteomics. Current research targets involve the discovery of novel
toxins from Australia’s venomous creatures, the design of mediators of neuropathic
pain, and ion channel therapeutics.
Prof. Eric Block
Eric Block, Carla Rizzo Delray Distinguished Professor of Chemistry
at the State University of New York at Albany, was born in New York
City, and received a Ph.D. in chemistry from Harvard University, with
E. J. Corey. Block, a Fellow of the ACS and the AAAS, has authored
more than 240 scientific papers and four books, including “Garlic and
Other Alliums: The Lore and the Science,” currently being translated
into Chinese, and trained more than 70 coworkers during his 49 years
in academia. Block is the 2016 recipient of the American Chemical
Society’s Ernest Guenther Award in the Chemistry of Natural Products,
and recipient of a John Simon Guggenheim Fellowship, the ACS Award for Advancement of Application of Agricultural and Food Chemistry, the International Council on
Main Group Chemistry Award for Excellence in Main Group Chemistry Research, the
Kenneth C. Spencer Award and a Sterling B. Hendricks Memorial Lecturer Award.
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27th International Symposium on Organic Chemistry of Sulfur
Plenary Speakers
Prof. Carsten Bolm
Carsten Bolm was born in Braunschweig in 1960. He studied chemistry at the TU Braunschweig (Germany) and at the University of
Wisconsin, Madison (USA). In 1987 he obtained his doctorate with
Professor Reetz in Marburg (Germany). After postdoctoral training
with Professor Sharpless at MIT, Cambridge (USA), Carsten Bolm
worked in Basel (Switzerland) with Professor Giese to obtain his
habilitation. In 1993 he became Professor of Organic Chemistry at
the University of Marburg (Germany), and since 1996 he has a chair
of Organic Chemistry at RWTH Aachen University (Germany). In 2012
he became an adjunct professor at WIT (Wuhan Institute of Technology), China, and
in 2014 he was awarded a Distinguished Professorship RWTH Aachen University. He
is Board Member of several journals and Associate Editor of the Journal of Organic
Chemistry. His publication list has over 430 entries, and in 2014 and 2015 he was
selected “Thomson Reuters Highly Cited Researcher”. (Author profile: Angew. Chem.
Int. Ed. 2014, 53, 6596 - 6597.)
Prof. Grzegorz Mloston
Education
1991 – Habilitation in Chemical Sciences, University of Łódź
1981 – Ph.D, Organic Chemistry with Prof. Romuald Bartnik, University of Łódź
1974 – Dipl. Chem., University of Łódź
Academic Career
October 1998 …. data – Full Professor at the University of Łódź
March 1981–September 1998 – University Professor at the University of Łódź
Awards and Honors
Liebig Prize – Gesellschaft Deutscher Chemiker (2012)
Polish Chemical Society – Stanisław Kostanecki Medal (2012)
Eureka Statue – for the best research and technological achievements in the City of
Łódź (2011)
Medal of the Polish Educational Commission – Ministry of Science and Higher Education, 2006
Polish Ministry of Science and Higher Education – for outstanding research achievements (Team leader: 1999, 2003, 2007, 2012)
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Plenary Speakers
Prof. Turan Ozturk
Turan Ozturk received his PhD degree from the University of East
Anglia, England, then, moved to the University of Kent at Canterbury, England, as a postdoctoral fellow, where he developed a
new method for the synthesis of fused 1,4-dithiin and thiophene
rings from 1,8-diketones using Lawesseon’s reagent and P4S10.
He took up a position at TUBITAK MRC, Turkey, then Middle East
Technical University, Turkey, and joined Istanbul Technical University as a full professor. He has previously been British Council
Research Fellow, NATO Research Fellow and Honorary Lecturer
at the University of Kent at Canterbury and Senior Research Fellow at University of
Waterloo, Canada. His research interests concentrate on the development of new
organic materials having electronic and optical properties.
Prof. Norihiro Tokitoh
Born in 1957; Ph.D., The University of Tokyo (1985); Assist. Prof. of
Tsukuba Univ. (1987); Assist. Prof. (1989) and then Assoc. Prof. (1994)
of The University of Tokyo; Professor of Institute of Fundamental
Organic Chemistry, Kyushu Univ. (1998-2000); Professor of Institute
for Chemical Research, Kyoto Univ. (2000-present).
Guest Professor, Institute for Molecular Science, Japan (2001-2003);
Visiting Professor, TU Braunschweig (2004-2007) and Universität Bonn,
Germany (2013-2015); Director of ICR (2008-2012, 2014-present);
Editor-in-chief, Bulletin of the Chemical Society of Japan (2013-present); President, The Society of Silicon Chemistry, Japan (2016-present).
Progress Award in Synthetic Organic Chemistry, Japan (1992); Progress Award in Silicon
Chemistry, Japan (1996); Japan IBM Science Award (1998); Chemical Society of Japan
Award for Creative Work (2003); Alexander von Humboldt Research Award (2003);
Lectureship Award of National Science Council, Republic of China (2007); Kim Yong
Hae Lectureship Award of KAIST, Korea (2010); BCSJ Awards (2002, 2005, 2007, 2009,
2010 and 2013); Alexander von Humboldt Research Award (Re-invitation, 2013).
20
27th International Symposium on Organic Chemistry of Sulfur
Programme Overview • Sunday/Monday, July 24/25
Monday, July 25
Sunday, July 24
Institut of Inorganic and Analytical Chemistry
09:00–11:00
Lecture Hall 3
Lecture Hall 4
09:00–09:25
Opening Ceremony p. 27
Polish‐German Workshop Part 1
09:30–10:20
p. 24
Plenary Session
Eric Block p. 27
10:20–10:50
11:30–12:45
Invited Speakers Session
S. Matile p. 27
Polish‐German Workshop Part 2
p. 24
11:15–11:45
Invited Speakers Session
M. Pietrusiewicz p. 27
14:00–15:15
11:45–12:15
Invited Speakers Session
P. M. Bonaccorsi p. 28
Polish‐German Workshop Part 3
p. 25
12:15–13:15
12:15–13:15
Session 1 p. 28
Session 2 p. 28
15:45–17:00
Polish‐German Workshop Part 4
14:45–15:15
p. 26
Invited Speakers Session
T. Müller p. 29
15:15–16:15
15:15–16:15
Session 3 p. 29
Registration Desk
16:45–17:45
18:00–18:45
Session 4 p. 29
16:45–17:45
Session 5 p. 30
Session 6 p. 30
17:45–19:00
Historic Plenary Session
Dietmar Linke
Poster Session 1 p. 30
p. 26
19:30–21:00
18:45–21:30
Welcome Reception p. 16
Evening Reception Rathausdiele p. 16
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
21
Programme Overview • Tuesday/Wednesday, July 26/27
Tuesday, July 26
Lecture Hall 3
Wednesday, July 27
Lecture Hall 4
08:40–09:30
Lecture Hall 3
08:30–09:00
Plenary Session
Norihiro Tokitoh p. 31
Invited Speakers Session
P. Bäuerle p. 35
09:30–10:00
09:00–09:50
Invited Speakers Session
U. Lücking p. 31
Plenary Session
Paul Alewood p. 35
10:00–10:30
09:50–10:20
Invited Speakers Session
X. Jiang p. 31
Invited Speakers Session
V. Burkhardt p. 35
11:00–11:30
10:50–11:20
Invited Speakers Session
M. Gingras p. 31
Invited Speakers Session
H. Ila p. 35
11:30–12:00
11:20–11:50
Invited Speakers Session
A. Ishii p. 31
Invited Speakers Session
M. D'Ischia p. 35
12:00–13:00
12:00–13:00
Session 7 p. 32
Session 8 p. 32
Meeting Intern. Committee
Room: 120 (First Floor)
12:45–19:30
15:15–15:45
Invited Speakers Session
R. Glass p. 32
15:45–16:45
Workshop Young
Scientists Part 1 p. 33
Conference Trip
to Weimar
17:15–18:15
Workshop Young Scientists Part 2 p. 34
18:15–19:30
Postersession 2 p. 34
p. 17
20:00–21:00
Organ Concert p. 17
22
27th International Symposium on Organic Chemistry of Sulfur
Programme Overview • Thursday/Friday, July 28/29
Thursday, July 28
Lecture Hall 3
Friday, July 29
Lecture Hall 4
Lecture Hall 3
09:00–09:50
09:00–09:50
Plenary Session
Carsten Bolm p. 36
Plenary Session
Turan Ozturk p. 40
09:50–10:20
09:50–10:20
Invited Speakers Session
V. Ananikov p. 36
Invited Speakers Session
V. G. Anand p. 40
10:20–10:50
Invited Speakers Session
N. Maulide p. 36
10:50–11:20
Invited Speakers Session
M. El‐khateeb p. 40
11:20–11:50
11:20–12:10
Invited Speakers Session
H. Fujihara p. 36
11:50–12:50
Plenary Session
Grzegorz Mloston p. 40
11:50–12:50
Session 9 p. 37
12:10–12:45
Session 10 p. 37
Closing p. 40
14:15–14:45
Invited Speakers Session
R. Laitinen p. 37
14:45–15:45
14:45–15:45
Session 11 p. 38
Session 12 p. 38
16:15–17:15
Session 13 p. 39
19:30–23:30
Banquet p. 17
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
23
Scientific Programme • Sunday, July 24
09.00–11.00
Room
Chair
Polish-German Workshop Part 1
Lecture Hall E017 – Institute of Inorganic and Analytical Chemistry
Wolfgang Weigand (Jena/DE)
09.00
Opening of the Workshop
Grzegorz Mlostoń (Łódź/PL)
09.05
PGW-01
Stereochemistry of organic sulfur compounds – more than 100
years of history, current state and further challenges
Jósef Drabowicz (Łódź/PL)
09.30
PGW-02
Alkoxyallene-based approach to polyhydroxylated cycloheptane
Greta Utrecht (Łódź/PL)
09.45
PGW-03
Polysulfanes – a natural remedy with considerable flavour
Jawad Nasim (Saarbrücken/DE)
10.00
PGW-04
Silver nanowires – from synthesis to application
Ewelina Mackiewicz (Łódź/PL)
10.15
PGW-05
Total Synthesis of Nosiheptide
K. Philip Wojtas (Jena/DE)
10.30
PGW-06
Synthesis of new macrocyclic systems with free hydroxyl groups
Monika Stefaniak (Łódź/PL)
10.45
PGW-07
One-Pot Regioselective Syntheses of 1,2-Thiazines
Rebekka Bohmann (Aachen/DE)
11.30–12.45
Room
Chair
Polish-German Workshop Part 2
Lecture Hall E017 – Institute of Inorganic and Analytical Chemistry
Wolfgang Weigand (Jena/DE)
11.30
PGW-08
Short and efficient preparation of alkynyl sulfides from terminal
alkynes
Mateusz Musiejuk (Łódź/PL)
24
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Sunday, July 24
11.45
PGW-09
FeNi Sulfides as Highly Efficient, Sustainable and Stable
Electrocatalysts for H2 Generation
Ulf-Peter Apfel (Bochum/DE)
12.00
PGW-10
Luminescent derivatives of Nucleobases – synthesis, properties,
and applications
Artur Jabłoński (Łódź/PL)
12.15
PGW-11
Tuning the Effect of the Dithiolate Linker “[µ-(S(CH2)nS] (n = 6-8)”
on the Stabilization or Destabilization of the Rotated Structure in
[Fe-Fe]-Hydrogenase Models
Hassan Abul-Futouh (Jena/DE)
12.30
PGW-12
Novel ruthenium complexes containing ligands with a stereogenic
heteroatom(s) for organometallic catalysis
Jacek Chrzanowski (Łódź/PL)
14.00–15.15
Room
Chair
Polish-German Workshop Part 3
Lecture Hall E017 – Institute of Inorganic and Analytical Chemistry
Grzegorz Mlostoń (Łódź/PL)
14.00
PGW-13
The Huisgen Reaction – 1,3-Dipolar Cycloaddition – Click Reaction
Hans-Ulrich Reissig (Berlin/DE)
14.30
PGW-14
Cytotoxic Platinum(II) Complexes with Sulfur and
Selenium-Containing Natural Products as Ligands
Jana Hildebrandt (Jena/DE)
14.45
PGW-15
Synthesis of Fluorinated and Phosphonylated β-Lactams via
Kinugasa Reaction
Marcin Kowalski (Łódź/PL)
15.00
PGW-16
The ’Sulfur approach’ for the synthesis of ferrocifen Analogues
Róża Hamera-Fałdyga (Łódź/PL)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
25
Scientific Programme • Sunday, July 24
15.45–17.00
Room
Chair
Polish-German Workshop Part 4
Lecture Hall E017 – Institute of Inorganic and Analytical Chemistry
Grzegorz Mlostoń (Łódź/PL)
15.45
PGW-17
Green batteries based on carbon nanotubes
Damian Kulawik (Łódź/PL)
16.00
PGW-18
Reactions between hetero-/aromatic thioketones and trieisendo
decacarbonyl
Mario Grosch (Jena/DE)
16.15
PGW-19
Application of green chromatography for determination of
endogenic aminothiols
Justyna Stachniuk (Łódź/PL)
16.30
Summary and Closing
Grzegorz Mlostoń (Łódź/PL)
18.00–18.45
Room
Chair
Historic Plenary Session
Lecture Hall E017 – Institute of Inorganic and Analytical Chemistry
Wolfgang Weigand (Jena/DE)
18.00
PL01
History of chemistry in Jena
Dietmar Linke (Berlin/DE)
18.45–21.30
Welcome Reception
Foyer – Institute of Inorganic and Analytical Chemistry
(see page 18)
26
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Monday, July 25
09.00–09.25
Room
Opening Ceremony
Lecture Hall 3
09.00
Opening Remarks
Walter Rosenthal (Jena/DE)
09.05
Opening Remarks
Christian Robl (Jena/DE)
09.10
Opening Remarks
Henning Hopf (Braunschweig/DE)
09.15
Opening Remarks
Richard S. Glass (Tucson, AZ/US)
09.20
Opening Remarks
Wolfgang Weigand (Jena/DE)
09.30–10.20
Room
Chair
Plenary Session
Lecture Hall 3
Richard S. Glass (Tucson, AZ/US)
09.30
PL02
Fifty years of smelling sulphur – from the chemistry of garlic to the
molecular basis for olfaction
Eric Block (Albany, NY/US)
10.20–10.50
Room
Chair
Invited Speakers Session
Lecture Hall 3
Richard S. Glass (Tucson, AZ/US)
10.20
IVS01
Supramolecular functional systems – sulfur in action
Stefan Matile (Geneva/CH)
11.15–11.45
Room
Chair
Invited Speakers Session
Lecture Hall 3
Marian Mikolajczyk (Łódź/PL)
11.15
IVS02
Sulfur and Phosphorus – mutually inspiring neighbors
Michał Pietrusiewicz (Lublin/PL)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
27
Scientific Programme • Monday, July 25
11.45–12.15
Room
Chair
Invited Speakers Session
Lecture Hall 3
Marian Mikolajczyk (Łódź/PL)
11.45
IVS03
From transient sulfenic acids towards peculiar sulfurated
molecules
Paola Maria Bonaccorsi (Messina/IT)
12.15–13.15
Room
Chair
Session 1
Lecture Hall 3
Antonella Capperucci (Messina/IT)
12.15
S01-01
Reaction of thiofenchone with Acid Chloride – Wagner-Meerwein
rearrangement
Kentaro Okuma (Fukuoka/JP)
12.35
S01-02
Horner-type reactivity of sulfonyl fluorides and esters:
experimental studies of the Hawkins-Kagabu olefination
Michał Barbasiewicz (Warsaw/PL)
12.55
S01-03
Extraodinary behavior of β-hydroxy sulfoxides and sulfones of
pinane series
Liliya Nikitina (Kazan/RU)
12.15–13.15
Room
Chair
Session 2
Lecture Hall 4
Kei Goto (Tokyo/JP)
12.15
S02-01
A Study on the Stereoselective Cyclization of 1-Alkenyl
β-Aminoalkyl Sulfoxides and Sulfones
Monika Kulak (Guelph/CA)
12.35
S02-02
Carbene-CS2 Adducts – Versatile Compounds for Catalysis
Rene Wilhelm (Paderborn/DE)
12.55
S02-03
Sulfide Quenching of Viologens
Edward Clennan (Laramie, WY/US)
28
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Monday, July 25
13.30–14.30
Room
Lunch Symposium Chevron Phillips Chemicals International N. V.
Lecture Hall 3
14.45–15.15
Room
Chair
Invited Speakers Session
Lecture Hall 3
Rainer Beckert (Jena/DE)
14.45
IVS04
Multicomponent Syntheses of Functional Sulfur-Heterocycles
Thomas Müller (Düsseldorf/DE)
15.15–16.15
Room
Chair
Session 3
Lecture Hall 3
Hans-Dieter Arndt (Jena/DE)
15.15
S03-01
Synthesis and reactivity of novel sulfur pentafluorides
Petr Beier (Prague/CZ)
15.35
S03-02
Phenylsilane as an effective and stereoselective desulfinylation
reagent
Wanda Midura (Łódź/PL)
15.55
S03-03
Stabilization of phenoxyl radicals by adjacent benzofused
heterocylcles – Sulfur makes the difference (again)
Stefano Menichetti (Sesto Fiorentino/IT)
15.15–16.15
Room
Chair
Session 4
Lecture Hall 4
Kentaro Okuma (Fukuoka/JP)
15.15
S04-01
Novel sulfur and selenium containing antioxidants – synthesis and
evaluation of their gpx-like activity
Damiano Tanini (Sesto Fiorentino/IT)
15.35
S04-02
Sulfur bonding as a mechanism to impact drug-receptor
interactions
Mahesh Narayan (El Paso, TX/US)
15.55
S04-03
Sulfur molecules in catalysis: substrates – catalysts – modifiers
Werner Bonrath (Basel/CH)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
29
Scientific Programme • Monday, July 25
16.45–17.45
Room
Chair
Session 5
Lecture Hall 3
Akihiko Ishii (Saitama/JP)
16.45
S05-01
tba
N.N.
17.05
S05-02
THIOCURE Polythiols – Multi-talents in Industrial Application
Tom Beyersdorff (Marschacht/DE)
17.25
S05-03
Dynamic Molecular Architectures Based on Tetrathiafulvalene
Building Blocks
Vladimir Azov (Bremen/DE)
16.45–17.45
Room
Chair
Session 6
Lecture Hall 4
Richard Grainger (Birmingham/GB)
16.45
S06-01
Thiotetronic Acids from North American Ground Water
Adrian Schwan (Guelph/CA)
17.05
S06-02
Unusual oxidative Smiles-Truce reaction of quinine
1,10-phenanthro-2-yl-thioether with SO2 extrusion
Przemysław Boratyński (Wrocław/PL)
17.25
S06-03
Chiral alkynyl products by a sulfinate-mediated approach with
allenyl sulfones – a modified padwa reaction
Thomas Martzel (Caen/FR)
17.45–19.00
Room
Poster Session 1
Foyer (see page 41)
19.30–21.00
Evening Reception
Rathausdiele in the Historic Townhall (see page 16)
30
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Tuesday, July 26
08.40–09.30
Room
Chair
Plenary Session
Lecture Hall 3
Juzo Nakayama (Saitama/JP)
08.40
PL03
Sulfurization of Low-coordinated Heavier Main Group Element
Compounds and Comparison with That of Lighter Congeners
Norihiro Tokitoh (Kyoto/JP)
09.30–10.00
Room
Chair
Invited Speakers Session
Lecture Hall 3
Juzo Nakayama (Saitama/JP)
09.30
IVS05
Sulfoximines – a neglected opportunity in Medicinal Chemistry
Ulrich Lücking (Berlin/DE)
10.00–10.30
Room
Chair
Invited Speakers Session
Lecture Hall 3
Juzo Nakayama (Saitama/JP)
10.00
IVS06
Sulfur Atom Transfer (SAT) Reaction
Xuefeng Jiang (Shanghai/CN)
11.00–11.30
Room
Chair
Invited Speakers Session
Lecture Hall 3
Mogens Brøndsted Nielsen (Kopenhagen/DK)
11.00
IVS07
Sulfur-Rich Polyaromatic Architectures – Asterisks, Dendrimers, Polymers, and Their Metal Interactions
Marc Gingras (Marseille/FR)
11.30–12.00
Room
Chair
Invited Speakers Session
Lecture Hall 3
Mogens Brøndsted Nielsen (Kopenhagen/DK)
11.30
IVS08
Sulfur-based organic photoluminescent compounds incorporated
in a dibenzobarrelene skeleton
Akihiko Ishii (Saitama/JP)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
31
Scientific Programme • Tuesday, July 26
12.00–13.00
Room
Chair
Session 7
Lecture Hall 3
Adrian Schwan (Guelph/CA)
12.00
S07-01
Synthesis and properties of novel polymers based on 3-mercapto
propanol derivatives
Jan Fleischhauer (Koblenz/DE)
12.20
S07-02
Porous inverse vulcanised polymers for mercury capture
Tom Hasell (Liverpool/GB)
12.40
S07-03
Selective access to sulfurated and selenated heterocycles by
intramolecular cyclization of β-substituted sulfides and selenides
Antonella Capperucci (Royston Herts/GB)
12.00–13.00
Room
Chair
Session 8
Lecture Hall 4
Marc Gingras (Marseille/FR)
12.00
S08-01
Palladium-Catalyzed Carbonylative Four-Component Synthesis of
Thiochromenones with the Assistant of Reagent Capsule
Xiao-Feng Wu (Rostock/DE)
12.20
S08-02
Electrocatalytical properties of heteroaromatic ferroceny
thioketones in oxidation processes of hydroquinone drivatives
Slawomir Domagała (Łódź/PL)
12.40
S08-03
Synthesis of Nitrogen- and Sulfur-Containing Heterocycles by
Palladium-Catalyzed C−S and Oxidative Dehydro C−H Couplings
Jan Paradies (Paderborn/DE)
15.15–15.45
Room
Chair
Invited Speakers Session
Lecture Hall 3
Edward Clennan (Laramie, WY/US)
15.15
IVS09
From Waste to Valuable Plastics – Discovery of New Paradigms
from Well-Studied Systems
Richard S. Glass (Tucson, AZ/US)
32
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Tuesday, July 26
15.45–16.45
Room
Chair
Workshop Young Scientists Part 1
Lecture Hall 3
Edward Clennan (Laramie, WY/US)
15:45
P22 15:53
P20
Helical shaped bis-1,4-benzoxathiines
Lorenzo Tofani (Sesto Fiorentino/IT)
16:01
P18
16:09
P17 16:17
P12
16:25
P15 Reaction of 2-alkylidene-3,1-benzoxathiin-4-ones with nitrones
Koujiro Kurita (Noda/JP)
16:33
P14 Reaction of ferrocenyl substituted thioketones with
trimethylsilyldiazomethane (TMS-CHN2)
Róża Hamera-Fałdyga (Łódź/PL)
Sulfenylation of Aromatic Compounds with N-Sulfenylbenzimidazoles
Shin-ya Suzuki (Noda/JP)
Synthesis of thienoacenes utilizing palladium-catalyzed C-S
coupling reactions
Peter Oechsle (Paderborn/DE)
Synthesis and application of thiocarboxylic acid derivatives
employing the mild thiolation concept
Hendryk Würfel (Jena/DE)
A New Preparation of Highly Substituted 1,4-Oxathiin Dioxides
Adrian Schwan (Guelph/CN)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
33
Scientific Programme • Tuesday, July 26
17.15–18.15
Room
Chair
17:15
P55
Workshop Young Scientists Part 2
Lecture Hall 3
Xuefeng Jiang (Shanghai/JP)
17:23
P51
Encapsulation of Thiocarbonyl Compound into Carbon
Nanotube
Hideaki Miyake (Ube/Japan)
17:31
P64 Coinage Metal(I)-dithiocarboxylate Complexes
Johanna Glatthor (Bielefeld/DE)
17:39
P21
Synthesis of Rotaxanes by Using Thiol-Exchange Reaction of
Selenenyl Sulfides
Satoshi Noda (Tokyo/JP)
17:48
Cytotoxic Platinum(II) Complexes with Sulfur and
Selenium-Containing Natural Products as Ligands
Jana Hildebrandt (Jena/DE)
17:55
P48 From Sulfur Redox Switches for Anion- π Catalysis to Chalcogen
Bonds
Sebastian Benz (Geneva/CH)
18:03
P05
Boron and Tetraphenylethene Substituted Thienothiophene
Possessing Molecules for OLED Applications
Pelin Ulukan (Istanbul/TR)
18.15–19.30
Room
Poster Session 2
Foyer (see page 41)
34
Synthesis and Structural Analysis of Fulvalene-based Materials
Michael Bauer (Ulm/DE)
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Wednesday, July 27
08:30-09:00 Room Chair Invited Speakers Session
Lecture Hall 3
Mikhail Krayushkin (Moscow/RU)
08.30 IVS10 Thiophene-based Nanomaterials for Organic Electronics
Peter Bäuerle (Ulm/DE)
09.00–09.50
Room
Chair
Plenary Session
Lecture Hall 3
Mikhail Krayushkin (Moscow/RU)
09.00
PL04
Venoms to drugs
Paul Alewood (Brisbane/AU)
09.50–10.20
Room
Chair
Invited Speakers Session
Lecture Hall 3
Mikhail Krayushkin (Moscow/RU)
09.50
IVS11
Polysulfides – chemistry and applications
Volker Burkhardt (Greiz/DE)
10.50–11.20
Room
Chair
Invited Speakers Session
Lecture Hall 3
Józef Drabowicz (Łódź/PL)
10.50
IVS12
Design and Developement of Novel Organosulfur Synthons as
Versatile Intermediates for Heterocycle Synthesis
Hiriyakkanavar Ila (Oulu/IN)
11.20–11.50
Room
Chair
Invited Speakers Session
Lecture Hall 3
Józef Drabowicz (Łódź/PL)
11.20
IVS13
The Cysteine-Quinone Coupling Reaction – Mutation-Inspired
Sulfur Chemistry in the Quest for Functionality
Marco D’Ischia (Irbid/JO)
12.45–19.30
Conference Trip to Weimar
Weimar (see page 17)
20.00–21.00
Organ Concert
Stadtkirche Jena (see page 17)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
35
Scientific Programme • Thursday, July 28
09.00–09.50
Room
Chair
Plenary Session
Lecture Hall 3
Stefano Menichetti (Sesto Fiorentino/IT)
09.00
PL05
Sulfoximines – Ligands for Asymmetric Catalysis, Syntheses, and
Bioactivities
Carsten Bolm (Aachen/DE)
09.50–10.20
Room
Chair
Invited Speakers Session
Lecture Hall 3
Stefano Menichetti (Sesto Fiorentino/IT)
09.50
IVS14
Adaptive Transition Metal Complexes and Nanoparticles Catalysis
in Organic Synthesis – С-С, C-S and C-Se Bonds
Valentine Ananikov (Moscow/RU)
10.20–10.50
Room
Chair
Invited Speakers Session
Lecture Hall 3
Stefano Menichetti (Sesto Fiorentino/IT)
10.20
IVS15
Sulfur (IV) mediated Synthesis – from ylides to sigmatropic
rearrangements
Nuno Maulide (Vienna/AT)
11.20–11.50
Room
Chair
Invited Speakers Session
Lecture Hall 3
Turan Ozturk (Istanbul/TR)
11.20
IVS16
Transportation and Encapsulation – Chiral Inorganic
Nanoparticle-Polythiophene Hybrid Nanotubes
Hisashi Fujihara (Osaka/JP)
36
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Thursday, July 28
11.50–12.50
Room
Chair
Session 9
Lecture Hall 3
Ernst Schaumann (Clausthal-Zellerfeld/DE)
11.50
S09-01
Syntheses of Cysteine-Derived Reactive Intermediates by Taking
Advantage of Cradled Cysteines
Kei Goto (Tokyo/JP)
12.10
S09-02
Role of Electron Transfer Processes in the Oxidation of Aromatic Sulfides Promoted by the Nonheme Iron Complex [FeII(N4Py)](OTf)2
Osvaldo Lanzalunga (Rome/IT)
12.30
S09-03
Synthesis, Structure and Reaction of a Stable Enethiol and Its
Derivatives Bearing 9-Triptycyl Group
Mariko Yukimoto (Tokyo/JP)
11.50–12.50
Room
Chair
Session 10
Lecture Hall 4
Risto Laitinen (Oulu/FI)
11.50
S10-01
Alkynyl sulfoxides as alpha-sulfinyl carbene equivalents
Richard S. Grainger (Birmingham/GB)
12.10
S10-02
Sulfur Dioxide-Based One-Pot-Reactions for the Rapid and Highly
Modular Synthesis of Sulfones
Georg Manolikakes (Frankfurt a. M./DE)
12.30
S10-03
Copper-catalyzed aerobic coupling of thiols – Synthesis of
N-sulfenylimines, sulfenamides, and sulfinate esters
Hye-Young Jang (Suwon/HR)
14.15–14.45
Room
Chair
Invited Speakers Session
Lecture Hall 3
N.N.
14.15
IVS17
Similarities and Differences in Imidosulfur and Imidoselenium
Chemistry
Risto Laitinen (Oulu/FI)
J uly 24–29, 2016 l J ena /G ermany l
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37
Scientific Programme • Thursday, July 28
14.45–15.45
Room
Chair
Session 11
Lecture Hall 3
Michał Pietrusiewicz (Lublin/PL)
14.45
S11-01
New sulfur derivatives of carboranes and metallacarboranes
Igor Sivaev (Moscow/RU)
15.05
S11-02
Size Selective Synthesis of Sulfur Nanoparticles and their Anti
cancer Activity
Anas Al Ali (Nablus/PS)
15.25
S11-03
Preparation, Reactivity, and Electrochemical Property of
Benzodichalcogenate Derivatives
Takeshi Kimura (Morioka/JP)
14.45–15.45
Room
Chair
Session 12
Lecture Hall 4
Valentine Ananikov (Moscow/RU) 14.45
S12-01
Derivatization of 2-sulfanylhydroquinone dimers – development
of water solubility and other new functionalization
Akio Kamimura (Ube/JP)
15.05
S12-02
Synthesis of Sulfur Heterocycles via Domino Metal-mediated
Reactions
Mihaela Gulea (Strasbourg/FR)
15.25
S12-03
Trithiomethaphosphate Anion – A Heavy Nitrate?
Konstantin Karagiosoff (Munich/DE)
38
27th International Symposium on Organic Chemistry of Sulfur
Scientific Programme • Thursday, July 28
16.15–17.15
Room
Chair
Session 13
Lecture Hall 3
Risto Laitinen (Oulu/FI)
16.15
S13-01
Manipulation of the H-Cluster from the [FeFe]-Hydrogenase with
Synthetic Cofactors
Ulf-Peter Apfel (Bochum/DE)
16.35
S13-02
Sulfur migration through the molecule – the case of hydroxy
alkylphosphine sulfides
Marek Stankevič (Lublin/PL)
16.55 S13-03
New Aspects of the Detection and Analysis of
Organothiophosphates related to the Chemical Weapons
Convention
Marc André Althoff (Munich/DE)
19.30–23.30
Banquet
Restaurant Fuchsturm Jena (see page 17)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
39
Scientific Programme • Friday, July 29
09.00–09.50
Room
Chair
Plenary Session
Lecture Hall 3
Mao Minoura (Tokyo/JP)
09.00
PL06
Thienothiophenes (TT) and Dithienothiophenes (DTT) for Organic
Materials
Turan Ozturk (Istanbul/TR)
09.50–10.20
Room
Chair
Invited Speakers Session
Lecture Hall 3
Mao Minoura (Tokyo/JP)
09.50
IVS18
Radical and Diradical Isophlorinoids
Venkataramanarao G. Anand (Pashan/IN)
10.50–11.20
Room
Chair
Invited Speakers Session
Lecture Hall 3
Stéphane Perrio (Caen/FR)
10.50
IVS19
Cyclopentadienyl Iron Complexes containing Sulfur Ligands
Mohammad El-khateeb (Irbid/JO)
11.20–12.10
Room
Chair
Plenary Session
Lecture Hall 3
Stéphane Perrio (Caen/FR)
11.20
PL07
Aryl, Hefaryl and Ferrocenyl Thioketones as Versatile Building
Blocks for the Organic Chemistry of Sulfur
Grzegorz Mlostoń (Łódź/PL)
12.10–12.45
Room
Closing
Lecture Hall 3
40
27th International Symposium on Organic Chemistry of Sulfur
Poster Presentations
Organic Chemistry of Sulfur
P01
Design and eco-friendly synthesis of benzothiazepines using silzic as a
heterogeneous catalyst
Tamer K. Khatab (Cairo/EG)
P02
Synthesis of Aminooxazole, Aminothiazol, and Aminothieno Derivatives of
Diosgenine
Khaled Shawakfeh (Irbid/JO)
P03
Reaction of Lawesson reagent and phosphacumulenes with
dichlorovinylsilane
Marwa El-Hussieny (Giza/EG)
P04
New Functionalized Organophosphorus Derivatives of Methane- and
Ethanesulfonic Acids with P-C-N Moieties
Andrey Prishchenko (Moscow/RU)
P05
Boron and Tetraphenylethene Substituted Thienothiophene Possessing
Molecules for OLED Applications
Pelin Ulukan (Istanbul/TR)
P06
1,1′-Biferrocenylene Based D−A−D Oligomers
Okan Demirel (Istanbul/TR)
P07
Synthesis and Optoelectronic Properties of Mono-Alkylated
Thieno[3,2-b]Thiophenes and Their Polymers
Koray Tansu Ilhan (Istanbul/TR)
P08
Donor-Acceptor Systems Possessing Tetraphenylethylene Substituted
Dithienothiophene-S, S-dioxides for OLED Applications
Rengin Büşra Özek (Istanbul/TR)
P09
Synthesis of S-benzhydrylthiocarbamates from acylisothiocyanates and
benzhydrols via Newman-Kwart rearrangement
Florea Dumitrascu (Bucharest/RO)
P10
Synthesis of Five-Membered Heterocycles through Oxidative Ring Closure
of Isolable 1,3-Thiaza-1,3-butadienes
Kazuaki Shimada (Morioka/JP)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
41
Poster Presentations
P11
Application of HPLC for the Screening of Separation of new macrocyclic
Systems
Monika Stefaniak (Łódź/PL)
P12
Synthesis and application of thiocarboxylic acid derivatives employing the
mild thiolation concept
Hendryk Würfel (Jena/DE)
P13
Synthesis and Properties of Thienothiophene-Boron for Solar Cell
Application
Recep İŞÇİ (Istanbul/TR)
P14
Reaction of ferrocenyl substituted thioketones with
trimethylsilyldiazomethane (TMS-CHN2)
Róża Hamera-Fałdyga (Łódź/PL)
P15
A New Preparation of Highly Substituted 1,4-Oxathiin Dioxides
Adrian Schwan (Guelph/CA)
P16
Development of thia-isosteric analogs of imidazo[1.2-a]pyridine drugs
Yulia Volkova (Moscow/RU)
P17
Synthesis of thienoacenes utilizing palladium-catalyzed C-S coupling
reactions
Peter Oechsle (Paderborn/DE)
P18
Reaction of 2-alkylidene-3,1-benzoxathiin-4-ones with nitrones
Koujiro Kurita (Noda/JP)
P19
Cyclization of 2-(N-pyrrolylsulfenyl)benzoic acids for the synthesis of
pyrrolo[1,2-b][1,2]benzothiazin-10-ones
Kotaro Masuda (Noda/JP)
P20
Sulfenylation of Aromatic Compounds with N-Sulfenylbenzimidazoles
Shin-ya Suzuki (Noda/JP)
P21
Synthesis of Rotaxanes by Using Thiol-Exchange Reaction of Selenenyl
Sulfides
Satoshi Noda (Tokyo/JP)
42
27th International Symposium on Organic Chemistry of Sulfur
Poster Presentations
P22
Helical shaped bis-1,4-benzoxathiines
Lorenzo Tofani (Sesto Fiorentino/IT)
P23
Hetero-Diels-Alder Reactions of Hetaryl Substituted Thiochalcones with
Electron Deficient Alkenes
Paulina Grzelak (Łódź/PL)
P24
Stabilization of a Primary-alkyl-substituted Sulfenic Acid and Its Anion by
Utilizing a Cavity-shaped Molecular Framework
Shohei Sase (Tokyo/JP)
P25
Microwave Assisted Synthesis of Ferrocenyl and Hetaryl Functionalized
Thioketones
Grzegorz Mlostoń (Łódź/PL)
P26
The Attempted Generation and Selected Reactions of Chlorinated
Thiocarbonyl S-Imides
Paulina Pipiak (Łódź/PL)
P27
Thionation of Some Mono- and Dicarbonyl Compounds with Japanese
Reagent
Naglaa El-Sayed (Giza/EG)
P28
Synthesis of the Novel Crown and Lariat Ethers with Integrated
1,2,3-Triazole Ring
Jarosław Romański (Łódź/PL)
P29
One-Pot Regioselective Syntheses of 1,2-Thiazines
Rebekka Bohmann (Aachen/DE)
P30
Microwave assisted polysulfide thiourethane acrylate synthesis
Zohreh Khoshnevisan (Tehran/IR)
P31
Synthesis and chirality of 4-oxo, 2-arylthiazolidines
Fatima Zohra Kouidri (Mascara/DZ)
P65 Access to Pyridazines via Modified Thiohydrazides
Mikhail Krayushkin (Moscow/RU)
J uly 24–29, 2016 l J ena /G ermany l
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43
Poster Presentations
Stereoselective synthesis
P32
Synthesis of 2-(p-toluenesulphonyl) tropane-2-ene – anhydroecgonine
analogue
Abdulmajeed Salih. Hamad Alsamarrai (Samarra/IR)
P33
Synthesis, Characterization, and Reactions of
1,3,5-Cycloheptatrien-2-yldiphenylphosphine Oxide with N-Nucleophiles
Eman A. Othman (Samarra/IR)
P34
Stereoselective [3+2]-cycloadditions of cycloaliphatic thioketones with
carbohydrate-derived nitrones
Artur Michalak (Łódź/PL)
Bio-organic, bioorganometallic (coordination chemistry)
P35
Synthesis and Properties of Sulfur-substituted Chlorophyll Derivatives
Kifa Kim (Kusatsu/JP)
P36
Novel plant macromolecule from bugloss (Anchusa italica Retz.)
Lela Amiranashvili (Tbilisi/GE)
P37
New Coordination Compounds of Copper, Nickel and Cobalt with Schiff
Bases Derived from Nicotinic Hydrazide and Benzaldehydes – the
Preparation, Characterization, Theoretical Study
Tareq Alshboul (Tafila/JO)
Medicinal chemistry
P38
Cytotoxic Platinum(II) Complexes with Sulfur and Selenium-Containing
Natural Products as Ligands
Jana Hildebrandt (Jena/DE)
P39
Palladium-Catalyzed Direct α-Arylation of Protected S, S-Dimethysulfoximine
Juan Alberto Sirvent Perez (Berlin/DE)
P40
Investigation of antioxidant activity of thienyl hydrazide boron
hydrazone derivatives
Antigoni Kotali (Thessaloniki/GR)
P41
A new class of metallocene-nucleobase derivatives – synthesis and
biological activity
Joanna Skiba (Łódź/PL)
44
27th International Symposium on Organic Chemistry of Sulfur
Poster Presentations
Catalysis
P42
Synthesis of Plavix using ZnO nanocatalysts
Ali Gharib (Mashhad/IR)
P43
One-Pot Synthesis of β-acetamido Ketones Using Silica-Supported
Preyssler Nanoparticles (SPNPs) as Green and Reusable Catalyst
Ali Gharib (Mashhad/IR)
P44
Enantioenriched 3-pyrroline derivatives by sulfinate-mediated formal
[3+2] cycloaddition of allenyl sulfones with activated imines
Stephane Perrio (Caen/FR)
P45
Copper-catalyzed aerobic cross-coupling of thiols and amines for synthesis
of N-sulfenylimines
Chan Lee (Suwon/HR)
P46
Chiral Sulfer Redox Switch for Asymmetric Anion – Π Catalysis
Masaaki Akamatsu (Geneva/CH)
P47
Synthesis of α-sulfenylated carbonyl compounds via enamine catalysis
Hyeong Wan Noh (Suwon/HR)
P48
From Sulfur Redox Switches for Anion π Catalysis to Chalcogen Bonds
Sebastian Benz (Geneva/CH)
P49
Stable primary diamondoid phosphines – Preparation and applications in
catalysis
Oana Moncea (Giessen/DE)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
45
Poster Presentations
Advanced materials
P50
Liquid Crystals Alignment in Photo-materials with Chalcone Group for 3D
Display
GyoJic Shin (Cheonan-si/HR)
P51
Encapsulation of Thiocarbonyl Compound into Carbon Nanotube
Hideaki Miyake (Ube/JP)
P52
Synthesis and Characterization of A-D-A Oligomers for Halogen-free
Solution-processed Organic Solar Cells
Dusko Popovic (Ulm/DE)
P53
Synthesis and Characterization of Thienylene- and Phenylene-containing
Macrocycles as Precursor for S-doped Nanographene
Stephanie Untch (Ulm/DE)
P54
Synthesis and Characterization of S,N-Heterotetracenes for Application in
Vacuum-processed Organic Solar Cells
Florian Henne (Ulm/DE)
P55
Synthesis and Structural Analysis of Fulvalene-based Materials
Michael Bauer (Ulm/DE)
P56
Turn-on Phosphorescence by Metal Coordination to a Multivalent
Terpyridine Ligand – a New Paradigm for Luminescent Sensors
Marc Gingras (Marseille/FR)
P57
A Multichromophoric Highly Luminescent Polysulfurated Pyrene as an
Efficient Light-Harvesting Antenna and Its Metal Coordination
Marc Gingras (Marseille/FR)
P58
Molecular Asterisks with a Persulfurated Benzene1 Core Are Among the Strongest Organic Phosphorescent Emitters in the Solid State
Marc Gingras (Marseille/FR)
46
27th International Symposium on Organic Chemistry of Sulfur
Poster Presentations
Nanotechnology
P59
The use of organosulfur compounds in nanomaterials
Ewelina Mackiewicz (Łódź/PL)
P60
Sonochemical synthesis of UV curable polysulfide thiourethane acrylate
nanocomposite
Behzad Shirkavand Hadavand (Tehran/IR)
P61
Preparation of nanoclay/epoxy/polysulfide nanocomposite and study on
its properties
Behzad Shirkavand Hadavand (Tehran/IR)
Primordial chemistry
P62
Synthesis of New Molecules of Benzimidazolothione Structure
Mohamed Amari (Algiers/DZ)
Varia
P63
Treatment of ethynyl n-hetarenes with selenium and tellurium halides:
a key step to a novel organoselenium and -tellurium compounds
Jelena Vasiljeva (Riga/LV)
P64
Coinage Metal(I)-dithiocarboxylate Complexes
Johanna Glatthor (Bielefeld/DE)
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
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Index of Plenary Speakers, Invited Speakers, Presenting Authors
and Chairs
A
Akamatsu, Masaaki
Al Ali, Anas Alewood, Paul Alshboul ,Tareq Althoff, Marc André Amari, Mohamed Amiranashvili, Lela Anand, Venkataramanarao G. Ananikov, Valentine Apfel, Ulf-Peter Arndt, Hans-Dieter Azov, Vladimir B
Barbasiewicz, Michał Bauer, Michael Bäuerle, Peter Beckert, Rainer
Beier, Petr Benz, Sebastian Beyersdorff, Tom Block, Eric Bolm, Carsten Bonrath, Werner Boratyński, Przemysław Burkhardt, Volker C
Capperucci, Antonella Chrzanowski, Jacek Clennan, Edward D
Demirel, Okan Domagala, Slawomir Dumitrascu, Florea Drabowicz, Jósef
48
45
38
18, 35
44
39
47
44
40
36, 38
25, 39
5, 6, 29
30
28
46
5, 35
29
29
34, 45
30
18, 27
5, 19, 36
29
30
35
28, 32
25
28, 32, 33
41
32
41
24,35
E
El-Hussieny, Marwa El-khateeb, Mohammad El-Sayed, Naglaa 41
40
43
F
Fleischhauer, Jan Fujihara, Hisashi 32
36
G
Gharib, Ali Gingras, Marc Glass, Richard Glatthor, Johanna Goto, Kei Grainger, Richard S. Grzelak, Paulina Gulea, Mihaela 45
30, 32, 34, 46
27, 32
34, 47
28, 37
37
43
38
H
Hamera, Róża Hasell, Tom Henne, Florian Hildebrandt, Jana 25, 33, 42
32
46
25, 44
I
Ilhan, Koray Tansu İŞÇİ, Recep Ishii, Akihiko 41
42
30, 31
J
Jabłoński, Artur Jacob, Claus Jang, Hye-Young Jiang, Xuefeng 25
5
37
31, 34
27th International Symposium on Organic Chemistry of Sulfur
General
Information
Index of Plenary Speakers, Invited Speakers,
Presenting
Authors
and Chairs
K
Kamimura, Akio Karagiosoff, Konstantin
Khoshnevisan, Zohreh Kim, Kifa Kimura, Takeshi Klobes, Olaf Kotali, Antigoni Kouidri, Fatima Zohra Krayushkin, Mikhail Kulak, Monika Kulawik, Damian Kurita, Koujiro L
Laitinen, Risto Lanzalunga, Osvaldo Lee, Chan Linke, Dietmar Lücking, Ulrich 38
38
43
44
38
5
44
43
5, 35, 43
28
26
33, 42
37, 39
37
45
26
31
M
Mackiewicz, Ewelina 24, 47
Manolikakes, Georg 37
Martzel, Thomas 30
Masuda, Kotaro 42
Matile, Stefan 27
Maulide, Nuno 36
Menichetti, Stefano 5, 29, 36
Michalak, Artur 44
Midura, Wanda 29
Mikolajczyk, Marian
27, 28
Minoura Mao 37
Miyake, Hideaki 34, 46
Mlostoń, Grzegorz 24, 25, 26, 40, 43
Moncea, Oana 45
Müller, Thomas
29
Musiejuk, Mateusz 24
N
Nakayama, Juzo
Narayan, Mahesh Nasim, Jawad Niesen, Mogens Brøndsted
Nikitina, Liliya Noda, Satoshi Noh, Hyeong Wan O
Oechsle, Peter Okuma, Kentaro Othman, Eman A. Özek, Rengin Büşra Ozturk, Turan P
Paradies, Jan Perrio, Stéphane Pietrusiewicz, Michal
Pipiak, Paulina Popovic, Dusko Prishchenko, Andrey 31
29
24
31
28
34, 42
45
33, 42
28, 29
44
41
5, 20, 36, 40
32
40
27, 38
43
46
41
R
Reissig, Hans-Ulrich Romański, Jarosław 25
43
S
Sase, Shohei 43
Schaumann, Ernst
37
Schwan, Adrian 30, 32, 33, 42
Shawakfeh, Khaled 41
Shimada, Kazuaki 41
Shin, GyoJic 46
Shirkavand Hadavand, Behzad
47
Sirvent Perez, Juan Alberto 44
Sivaev, Igor 38
J uly 24–29, 2016 l J ena /G ermany l
www . isocs -27. org
49
Index of Information
General
Plenary Speakers, Invited Speakers, Presenting Authors
and Chairs
Skiba, Joanna Stachniuk, Justyna Stankevič, Marek Stefaniak, Monika Strauß, Marcel Suzuki, Shin-ya 44
26
39
24, 42
26
33, 42
T
Tanini, Damiano Tofani, Lorenzo Tokitoh, Norihiro 29
33, 43
20, 31
U
Ulukan, Pelin Untch, Stephanie Utrecht, Greta 34, 41
46
24
V
Vasiljeva, Jelena Volkova, Yulia W
Weigand, Wolfgang
Wilhelm, Rene Wojtas, K. Philip Wu, Xiao-Feng Würfel, Hendryk 47
42
4, 6, 24, 26, 27
28
24
32
33, 42
Y
Yukimoto, Mariko 37
DiD
you
Know?
Conventus is the Professional Congress Organiser
of the ISOCS-27*
* 27th international Symposium on organic Chemistry of Sulfur
50
27th International Symposium on Organic Chemistry of Sulfur