Page: 1 of 9
Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
Conforms to EU Directive 1907/2006/EC - MSDS_NL
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Ashland
P.O. Box 8619
NL3009 AP, Rotterdam
Netherlands
Emergency telephone number
+1-800-ASHLAND (+1-800-274-5263/+1-606-3295701) , or contact your local emergency telephone
number at 112
[email protected]
Product Information
+31 10 497 5000 (in the Netherlands), or contact your
local CSR contact person
Product name
Product code
Product Use Description
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries, registered in various countries
340655
No data
2. HAZARDS IDENTIFICATION
Hazard Summary
Dangerous for the environment
Risks
Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
3. COMPOSITION/INFORMATION ON INGREDIENTS
H azardous C om ponents C A S-N o.
E IN ECS-N o.
C oncentration
Sym bol(s)
R -p h rase(s)
Sodium
dimethyldithiocarbamate
204-876-7
>=40 - <50%
N
R50/53
128-04-1
For the full text of the R-phrases mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
General Information
no data available
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
Page: 2 of 9
Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
Eyes
Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists.
Remove contact lenses.
Skin
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water.
Ingestion
Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious
person. Consult a physician if necessary.
Inhalation
Move to fresh air. In case of shortness of breath, give oxygen. If symptoms persist, call a
physician.Move to fresh air. If symptoms persist, call a physician. In case of shortness of breath, give
oxygen.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
ABC powder, Carbon dioxide (CO2), Dry chemical, Water mist
Unsuitable extinguishing media
DO NOT USE: Halons
Hazardous combustion products
carbon dioxide and carbon monoxide, carbon disulfide, sulfur oxides, Amines, Hydrocarbons,
nitrogen oxides (NOx)
Thermal decomposition
no data available
Precautions for fire-fighting
Do not allow run-off from fire fighting to enter drains or water courses. Keep containers and
surroundings cool with water spray. Prevent fire extinguishing water from contaminating surface water or
the ground water system. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
Personal protective equipment
In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
6. ACCIDENTAL RELEASE MEASURES
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
Page: 3 of 9
Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
Personal precautions
Persons not wearing protective equipment should be excluded from area of spill until clean-up has
been completed.
Environmental precautions
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Large spills should be collected mechanically (remove by pumping) for disposal. Keep in suitable,
closed containers for disposal.Neutralise with acid. Large spills should be collected mechanically (remove
by pumping) for disposal. Keep in suitable, closed containers for disposal.
Other information
Comply with all applicable federal, state, and local regulations.
7. HANDLING AND STORAGE
Handling
Do not breathe vapours or spray mist. For personal protection see section 8. Provide sufficient air
exchange and/or exhaust in work rooms. Avoid exceeding of the given occupational exposure limits (see
section 8). Smoking, eating and drinking should be prohibited in the application area. Normal measures for
preventive fire protection.
Storage
Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Stable under
recommended storage conditions. Protect from frost.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
General advice
These recommendations provide general guidance for handling this product. Personal protective
equipment should be selected for individual applications and should consider factors which affect exposure
potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the
responsibility of the employer to follow regulatory guidelines established by local authorities. Keep away
from food, drink and animal feedingstuffs. When using do not eat, drink or smoke. Ensure that eyewash
stations and safety showers are close to the workstation location.
Exposure controls
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Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
level of overexposure (from known, suspected or apparent adverse effects).
Eye protection
Safety glasses with side-shields
Skin and body protection
Wear as appropriate:
Safety shoes
Wear resistant gloves such as:
Nitrile rubber
Respiratory protection
No personal respiratory protective equipment normally required.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Form
Colour
Odour
Boiling point/boiling range
Melting point/range
liquid
no data available
yellow
no data available
> 100,00 °C
< -5 °C
Sublimation point
pH
Flash point
no data available
(ca.)10
Ignition temperature
Evaporation rate
Lower explosion limit / Upper explosion
limit
Dust explosion class
Dust explosion constant
Burning number
Particle size
Vapour pressure
Vapour density
Density
Bulk density
Solubility
Partition coefficient: n-octanol/water
log Pow
not applicable
no data available
no data available
no data available
no data available
no data available
no data available
no data available
23,30 hPa
no data available
1,18 g/cm3
no data available
Water completely soluble
no data available
-2,41
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Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
Autoignition temperature
Viscosity, dynamic
Viscosity, kinematic
Hydrolysis
Physico-chemical removability
no data available
not applicable
no data available
no data available
no data available
10. STABILITY AND REACTIVITY
Stability
Stable under recommended storage conditions.
Conditions to avoid
None known.
Incompatible products
N-nitrosamines, strong mineral acids, Strong oxidizing agents
Hazardous decomposition products
carbon dioxide and carbon monoxide, carbon disulfide, Sulphur oxides, Hydrocarbons, Amines,
nitrogen oxides (NOx)
Hazardous reactions
Hazardous polymerisation does not occur.
11. TOXICOLOGICAL INFORMATION
Exposure routes
Skin contact, Eye Contact, Ingestion, Inhalation
Eye contact
Mild eye irritation
Skin contact
Causes mild skin irritation.
Ingestion
Not known to be harmful if swallowed.
Inhalation
Not known to be harmful if inhaled.
Aggravated Medical Condition
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Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to
this material: lung (for example, asthma-like conditions)
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of
the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea), irritation
(nose, throat, airways)
Target Organs
no data available
Acute or al toxicity
:
rat: > 5.000 mg/kg
Sodium dimethyldithiocarbamate (128-04-1 )
:
LC 50
Rat: > 3,93 mg/l, 4 h
Acute der mal toxicity
:
rat:
> 5.000 mg/kg
Acute inhalation toxicity
12. ECOLOGICAL INFORMATION
Elimination infor mation (per sistence and degr adability)
Biodegr adability
Sodium dimethyldithiocarbamate (128-04-1 )
:
no data available
Physico-chemical r emovability
Sodium dimethyldithiocarbamate (128-04-1 )
:
no data available
:
The bioaccumulation potential cannot be determined.
:
no data available
Bioaccumulation
Ecotoxicity effects
Toxicity to fish
Sodium dimethyldithiocarbamate (128-04-1 )
Toxicity to daphnia and other aquatic inver tebr ates.
Sodium dimethyldithiocarbamate (128-04-1 )
:
no data available
:
no data available
Toxicity to algae
Sodium dimethyldithiocarbamate (128-04-1 )
Toxicity to bacter ia
Page: 7 of 9
Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
Sodium dimethyldithiocarbamate (128-04-1 )
:
no data available
13. DISPOSAL CONSIDERATIONS
Waste disposal methods
Dispose of in accordance with the European Directives on waste and hazardous waste. Do not
contaminate ponds, waterways or ditches with chemical or used container. Container hazardous when
empty. Dispose of in accordance with local regulations.
Empty packaging
Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an
approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use
a cutting torch on, the empty drum.
European Waste Catalogue
The Waste code should be assigned in discussion between the user and the waste disposal
company.
14. TRANSPORT INFORMATION
REGULATION
ID
PROPER SHIPPING
NUMBER
NAME
ADR
UN
3082
ADNR
UN
3082
*HAZARD
CLASS
SUBSIDIARY
HAZARDS
PACKING
GROUP
ENVIRONMENTALLY
9
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (SODIUM
DIMETHYLDITHIOCARBA
MATE)
III
ENVIRONMENTALLY
9
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (SODIUM
DIMETHYLDITHIOCARBA
MATE)
III
MARINE
POLLUTANT /
LTD. QTY.
Page: 8 of 9
Revision Date: 14.09.2010
Print Date: 02.06.2011
MSDS Number: R0525489
Version: 2.0
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
RID
UN
3082
ENVIRONMENTALLY
9
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (SODIUM
DIMETHYLDITHIOCARBA
MATE)
INTERNATIONAL MARITIME DANGEROUS GOODS
UN
3082 ENVIRONMENTALLY
9
HAZARDOUS
SUBSTANCE, LIQUID,
N.O.S. (SODIUM
DIMETHYLDITHIOCARBA
MATE)
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
UN
3082 Environmentally hazardous
9
substance, liquid, n.o.s.
(SODIUM
DIMETHYLDITHIOCARBA
MATE)
III
III
III
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
UN
3082 Environmentally hazardous
9
III
substance, liquid, n.o.s.
(SODIUM
DIMETHYLDITHIOCARBA
MATE)
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
15. REGULATORY INFORMATION
Hazard symbols
Dangerous for the environment
R-phrase(s)
R50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
SAFETY DATA SHEET
Amersep™ MP3 NEUTRALIZING AGENT
™ Trademark, Ashland or its subsidiaries,
registered in various countries
340655
S-phrase(s)
S57
S60
Use appropriate container to avoid environmental contamination.
This material and its container must be disposed of as hazardous waste.
Notification status
US. Toxic Substances Control Act
Australia. Industrial Chemical (Notification and Assessment) Act
Canada. Canadian Environmental Protection Act (CEPA).
Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)
Japan. Kashin-Hou Law List
Korea. Toxic Chemical Control Law (TCCL) List
Philippines. The Toxic Substances and Hazardous and Nuclear
Waste Control Act
China. Inventory of Existing Chemical Substances
ABM Class
ABM 4A
ABM Class
ABM 4A
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Revision Date: 14.09.2010
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MSDS Number: R0525489
Version: 2.0
y (positive listing)
y (positive listing)
y (positive listing)
y (positive listing)
y (positive listing)
y (positive listing)
y (positive listing)
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
16. OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
The information accumulated herein is believed to be accurate but is not warranted to be whether originating
with the company or not. Recipients are advised to confirm in advance of need that the information is
current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's
Environmental Health and Safety Department (+31 10 497 5000).