Chemistry Final Review - Fall Semester KEY 1. Which of the following is a mixture? a. Carbon b. Air c. Water d. Ice 2. Classify the following as a heterogeneous, a homogenous mixture, or compound. a. Milk Homogenous mixture b. Brass ( copper and zinc) Homogeneous mixture c. Water Compound d. Air Homogeneous mixture e. Ocean water Heterogeneous mixture f. Chocolate milk with marshmallows Heterogeneous mixture g. CO2 Compound 3. What element has 23 protons, 23 electrons and 28 neutrons? Vanadium 4. Consider the following elements ,Carbon -14, Carbon-13, Carbon-12 a. How many protons, neutrons, and electrons does each carbon contain? Carbon-14: 6 protons, 8 neutrons, 6 electrons Carbon-13: 6 protons, 7 neutrons, 6 electrons Carbon-12: 6 protons, 6 neutrons, 6 electrons b. What subatomic particle is different in each of these forms of carbon? Neutrons c. Why is the atomic mass on the periodic table 12.01, when none of these carbon atoms have 12.01 as its mass? 12.01 is a weighted average of the different isotopes of carbon, C-12 being the most abundant because the atomic mass is closest to 12. d. What are the same elements, with differing atomic masses called? Isotopes 5. Give an example of an element that has a larger atomic radius when it becomes an ion. Any anion (negative charge) will have a larger atomic radius because they gain electrons. 6. Give an example of an element that has a smaller atomic radius when it becomes an ion. Any cation (positive charge) which are metals 7. Write a formula and name two elements that form a type III compound. Transition metals will form type II compounds when combined with a nonmetal. 8. Write a formula and name two elements that form a type I compound. A metal in the s block or in the “island” will for type I compounds when combined with a nonmetal. 9. How can you recognize the formula of an acid? Acids always start with H in their formula (although not all formulas that start with H are an acid, such as H2O) 10. Explain when you need to use parenthesis around a polyatomic ion that is in a binary compound. If the charge of the cation is greater than one and/or different from the charge on the polyatomic ion, then you need parentheses around it to indicate how many of those polyatomic ions need to be in the formula. 11. Give 4 examples of compounds that are formed with polyatomic ions, each compound must require a parenthesis around the polyatomic. Here are a few, but there are many more • Ca(NO3)2 • Mg(OH)2 • Cu3(PO4)2 • (NH4)2O 12. Name the following: a. Ba(OH)2 Barium hydroxide b. MgCl2 Magnesium chloride c. FeSO4 Iron (II) sulfate d. HCl Hydrochloric acid e. H3PO4 Phosphoric acid f. H2SO3 Sulfurous acid g. Cu3N Copper (I) nitride h. Cu(NO3)2 Copper (II) nitrate i. O3S5 Trioxygen pentasulfide j. H2S Hydrosulfuric acid k. P6Br7 Hexaphosphorus heptabromide 13. Which atomic sub particle is responsible for giving an element its chemical properties? Electrons 14. Which atomic sub particle determines the identity of the element? Protons 15. Calculate the atomic mass of silicon. The three silicon isotopes have atomic masses and relative abundances of 27.9769 amu (92.2297%), 28.9765 amu (4.6832%) and 29.9738 amu (3.0872%). � 92.2297 100 × 27.9769� + � 4.9832 100 × 28.9765� + � 3.0876 100 × 29.9738� = 28.1724 amu 16. Bromine has two naturally occurring isotopes. Bromine-79 has a mass of 78.918 amu and is 50.69% abundant. Using the atomic mass reported on the periodic table, determine the mass of bromine-81, the other isotope of bromine. 100 – 50.69 = 49.31% � 50.69 100 × 78.918� + � 49.31 100 × 𝐵𝐵𝐵𝐵� = 79.904 40.00 + .4931Br = 79.904 .4931Br = 39.90 Br-81 = 80.918 amu 17. Gallium has two naturally occurring isotopes. The mass of gallium-69 is 68.9256 amu and it is 60.108% abundant. The mass of gallium-71 is 70.9247 amu and it is 39.892% abundant. Find the atomic mass of gallium. � 60.108 100 × 68.9256� + � 39.892 100 × 70.9247� = 69.723 amu 18. a. Where are the metals and nonmetals located on the periodic table? Metals To the left of the line of separation Nonmetals To the right of the line of separation b. Give two examples of metals and the ions they form. Metals form cations (positive charge) c. Give two examples of nonmetals and the ions they form. Nonmetals form anions (negative charge) e. Where are the transitional metals located on the periodic table? The d block (middle of periodic table) f. Name two compounds that contain a transitional metal. Type II compounds 19. The atomic number of an element is used to find the number of which subatomic particle? a. Neutron b. Electron c. Proton d. Isotope 20. Which statement correctly describes the change of a neutral atom to its ion? a. Oxygen loses two electrons b. Aluminum gains three electrons c. Calcium loses one electron d. Barium loses two electrons 21. Which of the following statements is not true? a. The current model of an atom is a nucleus that contains protons and neutrons. b. The electrons surround the nucleus, but are not part of it. c. The nucleus has a positive charge that attracts the electrons d. The electrons orbit the nucleus in specific paths e. The electrons orbit the nucleus in areas of high probability, but with no specific path. 22. How many protons, neutrons and electrons are in the following: Protons – 17, Neutrons – 18, Electrons – 17 23. How many protons and electrons are in the following: Protons – 8, Neutrons – 8, Electrons – 10 24. Chris is driving his new car, which gets 25 mi/ gal. What is the gas mileage in km/L? ( 1km = .62mi and 1 gal = 3.79L) 25 mi 1 gal 1 km .62 mi 1 gal 3.79 L = 10.64 km/L 25. The Webers are going on a vacation to Mexico to go scuba diving. The plane travels at an average speed of 920 km/ hr . The distance between Colorado Springs and Cozumel, Mexico is 1,658 miles. How ,many hours will it take to get to Cozumel? 1,658 mi 26. 1cm3 = 1 mL 1 km .62 mi 1 hr 920 km = 2.91 hours 27. 1 x 106mm = 1×103 m 28. 60km= 60,000,000 mm 29. An object has a density of 3.6g/mL, will it float, sink or be neutral in water? The density of water is 1g/mL. Sink 30. A graduated cylinder has 26mL of water in it. A piece of aluminum is put into the graduated cylinder. The water level rose to 36mL. The mass of the aluminum is 5.0g a. Why does the water rise 10mL? Because the piece of aluminum was put into the graduated cylinder and displaces the water. b. What does the 10mL represent? The volume of the piece of metal c. What is the density of the aluminum? 5.0 g ÷ 10 mL = 0.5 g/mL 31. A piece of zinc weighs 29.3g. The density of zinc is 33.4g/mL. What is the volume of the zinc? 29.3 g 1 mL 33.4 g = 0.88 g/mL 32. Identify the following bonds as ionic, pure covalent or polar covalent. Define: • Ionic – A bond between two elements that have VERY different electronegativity (metal and nonmetal); electrons are being transferred • Pure covalent – A bond where electrons are shared between two elements with VERY similar electronegativity (usually identical elements) • Polar Covalent – A bond where electrons are shared between two elements with different electronegativity a. HCl Ionic b. Ba(OH)2 Ionic c. F2 Pure Covalent d. H2O Polar Covalent e. CO2 Polar Covalent f. I2 Pure Covalent g. CaCl2 Ionic 33. Circle the letter of all the statements that are true. Correct the false statements. a. Pure covalent bonds share electrons equally True b. Ionic bonds share electrons unequally False – Ionic bonds don’t share electrons, electrons are transferred c. Polar covalent bonds are bonds between metals False – All covalent bonds are always between two or more nonmetals 34. Choose the atomic radius that is larger. a. Ca or As b. Cl or I c. O or P 35. Which of the following are in order of increasing electronegativity (least to greatest)? a. I<Br<F<Cl b. Br<I<Cl<F c. F<Cl<Br<I d. I<Br<Cl<F 36. Write the valence configuration for the following elements: a. Sb 5s25p3 b. Al 3s23p1 c. As 4s24p3 d. Br 4s24p5 37. Write the complete configuration for the following elements: a. N 1s22s22p3 2b. S 1s22s22p63s23p6 (2 electrons are added because of the charge) c. Mg2+ 1s22s22p6 (2 electrons are removed because of the charge) d. F 1s22s22p5 e. Ar 1s22s22p63s23p6 38. The “s” orbital can hold how many electrons? a. 1 b. 2 c. 4 d. 6 39. The “d” orbital can hold how many electrons? a. 3 b. 5 c. 6 d. 10 40. The “p” orbital can hold how many electrons? a. 2 b. 4 c. 6 d. 8 41. Lithium burns red in a flame, copper burns green in a flame. Explain how wavelength and energy are related to color. The more energy there is, the wavelength will be shorter. Green has a shorter wavelength than red, so copper burns with more energy than lithium. 42. We see the visible part of the electromagnetic spectrum. List the colors we see in order from greatest energy to least energy. (Greatest) Violet, Indigo, Blue, Green, Yellow, Orange, Red (Least) 43. Write the configuration for the valence shell of the following: a. Ca 4s2 b. P 3s23p3 c. As 4s24p3 d. Br 4s24p5 e. Te 5s25p4 f. Cl 3s23p5 g. Ge 4s24p2 44. Write the complete configuration for the following; a. Si 1s22s22p63s23p2 b. Be 1s22s2 c. P 1s22s22p63s23p3 d. Ca2+ 1s22s22p63s23p6 (loses two electrons) 3e. N 1s22s22p6 (gains three electrons) 45. Draw the Lewis structure of the following and name the molecular geometry: a. CO2 Molecular Geometry Linear b. N2 Molecular Geometry Linear c. CH4 Molecular Geometry Tetrahedral d. NH3 Molecular Geometry Trigonal Pyramidal 46. The electron pair would be closer to which atom in the following compounds (think about electronegativity). a. H---Cl Chlorine b. C---F Fluorine c. I---Br Bromine d. C—N Nitrogen e. P—Cl Chlorine 47. A chemistry student, Chris, received an awesome review for his chemistry final. For some unknown reason, Chris did not think it was awesome review, in fact he was mad at his sweet Mom due to the length of the review. The review contained 3.5 questions per concept. For every concept it took 0.25 hours to study. Chris covered 13.5 concepts. a. How many questions did he do? 13.5 con 3.5 ques 1 con = 47.25 question b. How many hours did he spend angry at his dear, wonderful mother? 13.5 con .25 hr 1 con = 3.375 hours c. What was Chris’s rate in questions per hour? 47.25 ques 3.375 hr = 14 questions/ hour
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