ES 10 Resources Nonrenewable Energy Resources Oil and Natural Gas continued… Nonrenewable Perpetual http://www.poodwaddle.com/worldclock.swf Past to Present (1 31 slides) What are fossil fuels Where doe the oil come from? Oil Traps; Source, Reservoir & Cap Rocks Why use Oil / Natural Gas Drawbacks Abiotic Oil? How much is there and who has the oil? How long will it last? Where does US get it’s oil? Unconventional sources of oil and gas: Oil Shale, Tar Sands, Methane Clathrates, aka Gas Hydrates st “Potentially” Renewable Fig. 1.11, p. 11 Resources 16 15 ? Renewable Nonrenewable or “Nonrenewable Mineral Resources” 14 13 12 Direct solar energy Winds, tides, flowing water Fossil Fuels (iron, gold, copper, aluminum) Potentially Renewable Fresh air Fresh water NonMetallic minerals & rocks Metallic minerals Fertile soil (clay, sand, marble, slate) These two are sometimes Called: “Solid Nonfuel Mineral Resources” 10 9 8 ? 7 6 Cultural Revolutions 5 •http://www.poodwaddle.com/worldclock.swf 4 Billions of people 11 ? 3 What’s Environmental Degradation? Plants and animals (biodiversity) http://www.worldometers.info/world-population/ 2-5 million 8000 years Fig. 1.11, p. 11 2 Black Death–the Plague Hunting and Gathering 6000 4000 2000 Time Agricultural Revolution Last 14 sec on 24hr Big Bang clock 1 2000 B.C. A.D. 0 2100 Age of Discovery ~last 2 sec on 24hr Big Bang clock Industrial ~Last 1 sec on 24hr revolution Big Bang clock 1 Agricultural Revolution Trade-Offs? Good vs Bad news? Bad News Good News More food, store it year round. Supports a larger population. Longer life expectancies. Formation of villages, towns, cities. Cultural growth; art, religion, music, science, communication, trade goods and information. Irrigation systems developed. Higher standard of living. Destruction of wildlife habits from clearing forests/grasslands. Soil erosion from over tilling and plowing, buildup of salts New Conflicts over water resources, ownership of land, possessions, spread of slavery. Livestock overgrazing / soil compaction, buildup of salts. Cities concentrate waste/pollution Increase in global greenhouse gases from clearing forests/grasslands and livestock husbandry Industrial Revolution Trade-Offs? Good News Mass Production of useful, affordable products Distribution of goods, services Increased Agricultural production, more food Longer life expectancies, better health, lower infant mortality. Better Transportation, communication Higher standard of living. Bad News Increased waste production Burning fossil fuels: increase in global greenhouse gases Increase of air and water pollution Habitat destruction Biodiversity depletion Groundwater depletion Soil depletion, degradation “Industrialization isolates people from nature; reduces understanding of important ecological and economical services nature provides.” Information and Globalization Revolution Some Important Inventions: 1775 - 1903 : 1775 James Watt first reliable Steam Engine 1793 Eli Whitney: Cotton Gin, Interchangeable parts for muskets 1798 Robert Fullerton: Regular Steamboat service on the Hudson River 1807 Samuel F. B. Morse: Telegraph 1836 Elias Howe: Sewing Machine 1851 Cyrus Field: Transatlantic Cable 1866 Alexander Graham Bell: Telephone 1876 Thomas Edison: Phonograph, Light Bulb 1877 Nikola Telsa: Induction Electric Motor 1888 Rudolph Diesel: Diesel Engine 1903 Orville and Wilbur Wright: First Airplane 1908 Henry Ford: Model T Ford & Assembly Line (by 1927, 15 million made) • • • • • • • • • • • • Radio Telephone TV Air travel, freight Computers Space travel Satellites Remote sensing Internet, wireless technology Cellular phones, Smart Phones & TVs, Tablets GPS, GIS ROV’s & AUVs 2 Energy Consumption by Source 1635 - 2009 A change from potentially renewable wood, to nonrenewable fossil fuels Source: Energy Information Administration Whale Oil, Kerosene and the “Oil Industry” In early 1800’s, whale oil was popular for lamps and candles, but expensive. ~15,000 right Whales killed/yr in early 1800’s US whaling fleet: 392 in 1833 to 735 in 1846 “The Pennsylvania Oil Rush” in 1860’s Starts in Titusville in north western Pennsylvania in 1859 Producing 8,000 barrels/day in the 1860’s, 21 meters down, 8 refineries built Cleveland Ohio had 30 refineries by 1865, J.D. Rockefeller 250 whales killed at Point Lobos between 1862 – late 1870’s In 1857, clean burning kerosene (originally called “coal oil”) put on market. Rapid expansion by 1860 in US, eventually leads to the end of whale oil lamps/candles. Titusville from 1 oil well to 75 oil Wells in less than a year What state led the “Oil Rush” in the US in the 1800’s? 3 California led the world in oil production in 1910 McKittrick Tar Pit in west San Joaquin Valley, 1st mined in 1864 The Lakeview #1 Gusher in San Joaquin Valley in 1910, 18,000 barrels/day flowed uncapped for 18 months The “Texas Oil Boom” Spindletop Gusher, E Texas, Jan 10, 1901 A period of dramatic change and economic growth in Texas & US between 1901 - 1940’s Expansion in the Panhandle, North and Central Texas. The largest is the East Texas Oil Field aka “Black Giant” “Big Inch Pipeline”, built in 1942, for WWII effort, 1,200 miles from Houston to NJ 2 ft diameter, cost 7 million, takes oil 3.5 days, 300,000 bpd By the end of the WWII, over 350 million barrels transported. Line is still in use. 4 For more on Oil History, check out this http://www.sjgs.com/index.html In early 1900’s car are getting very popular. In 1900 ~8,000 autos registered in US In 1910 ~ 900,000 autos resisted in US In 2007 ~254 million passenger vehicles register in US (most in any country in world) Elk Hills California, (west of Bakersfield) Hay No.7 Well blew out natural gas and caught fire on July 26th, 1919. It burned for 26 days. The well was extinguished with torpedoes of dynamite. By the 1950’s, the US can no longer supply its oil needs. Somewhere in China ~1/3 of all oil comes from the sea. Big Gulf of Mexico Petroleum Discovery September 2006 Chevron estimated the 300-square-mile region, could hold between 3 - 15 billion barrels of oil and natural gas There are 42 US gallons in a barrel, or 159 liters. Gulf of Mexico: 1st offshore wells in 1947. In 1960’s 30 miles offshore, by 1970’s 100 miles offshore. Platform in >7,000 ft of water (2,134m) Drill hole depth ~20,000 ft (6.1km) Total depth >28,120ft (>8 km or 5 miles) 1950’s tankers ~ 500 ft, 25,000 tons 1970’s tankers 1,400ft (5 football fields) 500,000 tons Known recoverable US reserves is ~21 billion barrels and US consumes ~22 million barrels/day. 5 “Reserves” = known amounts that can be profitably developed at current prices and costs, using current technologies and under current rules (institutional resources) Total World Oil Reserves Conventional vs Unconventional Reserves increase in response to: • • • • higher prices lower costs of development technological improvements new discoveries without any change in the quantity in the ground The size of reserves depends on economic factors, not on the physical amount in the ground. What are fossil fuels? • Oil, Natural Gas, and Coal • Derived from remains of organisms which decompose and are exposed to heat and pressure beneath the Earth’s surface over millions of years. • Consist primarily of hydrocarbons: organic compounds of H and C atoms with smaller amounts of O, S and N. The approximate length range for “oil” is C5H12 to C18H38. Any shorter hydrocarbons are considered natural gas, the simplest form is methane CH4. • Petroleum (Petra-rock / Oleum-oil) /Crude Oil: complex mixture of liquid hydrocarbons of various lengths. Termed 1st used and published in 1546 by German geologist/mineralogist Georg Bauer aka Georgis Agricola Origin of Oil? Most commercial oil is probably “organic oil” How can this happen? • Forms in marine basins with rich diversity of microscopic algae, protozoa and animals (plankton) living on the surface • Organisms die, settle onto ocean floor --> some decomposition occurs -->depletion of O2 in bottom waters -->decay slows or ceases. • Pressure and heat build up as organic material is buried under many layers of sediment. This converts the organic molecules to kerogen (solid, waxy organic matter in sedimentary rock, too thick to flow out of rock). Geothermal Gradient: 20 degrees C/km, 68 degrees F/km or 109 degrees F/mi 6 Kerogen / Oil Formation Figure 5.7 • Kerogen, highly viscous, complex molecules (“Tar”) forms first, at temperatures <30º- ~100ºC @ ~ <1-3km depth. Kerogen can then convert to various liquid hydrocarbons at temperatures ~80ºC - 120ºC (sometimes wider) @ ~ 3-8km depth. is The process of breaking a long-chain of hydrocarbons into short ones = “Cracking”. • At temperatures > 100ºC (212ºF), liquid petroleum can be converted into a variety of natural gases such as methane, ethane, propane and butane each type more complex and heavier molecules. • • Geothermal Gradient: 20 – 30 deg C/Km At temperatures of ~200ºC (400ºF) and/or depths of > 10km, methane can break down completely and the rocks no longer contain hydrocarbons. Limited window of opportunity for the conversion of organic remains to hydrocarbon fuels ~1,6Km ~3Km Or 77 deg F/Mi ~6Km 7
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