Minnesota Minerals Education Workshop Eveleth, MN June 21-23, 2011 FIELD GUIDEBOOK ON THE GEOLOGY AND MINERAL DEPOSITS OF THE EASTERN MESABI IRON RANGE Richard Patelke, PolyMet Mining Company Mark Severson, Natural Resources Research Institute at UMD Jim Miller, University of Minnesota Duluth MMEW FIELD TRIP (June 22-23, 2011) GEOLOGY AND MINERAL DEPOSITS OF THE EASTERN MESABI IRON RANGE Richard Patelke, PolyMet Mining Company Mark Severson, Natural Resources Research Institute at UMD Jim Miller, University of Minnesota Duluth Geologic Overview of the Eastern Mesabi Iron Range The bedrock geology of the Eastern Mesabi Iron Range contains a broad range of rock types that formed in diverse geologic settings over a wide span of earth history (1.5 billion years). These same rocks are also host to several types of mineral deposits. On this field trip we will examine some the main rock types of the eastern Mesabi Iron Range and visit mineral deposits of ironformation, copper+nickel±platinum group metals, and sand and gravel. Three geologic terranes are exposed along the Eastern Mesabi Iron Range (four counting the glacial cover). Each represents a unique stage in the formation of the North American continent during the Precambrian (Fig. 1). Terrane Age* Formational Stage Superior Province ~2.6 (Granite-Greenstone) forms the core of the North American continent (Kenoraland); created by the tectonic merging of volcanic (greenstone) terranes and the emplacement of granite intrusions. Penokean represents sediments deposited on the margin of the new continent; to the south, these sedimentary rock were deformed and metamorphosed during the formation of the Penokean Mtns Midcontinent Rift * in billions of years(Ga) ~1.85 1.1 represents igneous activity related to a failed attempt by the North American continent (Laurentia) to split apart, thus forming the Midcontinent Rift Figure 1. Generalized geology of northeastern Minnesota 1 The Archean-aged granite-greenstone terrane (formally known as the Superior Province) is exposed north of the Mesabi Iron Range. It is composed of a variety of volcanic and sedimentary rocks that have been deformed, moderately metamorphosed, and intruded by magma that crystallized to form large bodies of granite. This assemblage of rocks is interpreted to represent the tectonic collision of volcanic island arcs (like those that ring the western Pacific Ocean today) and small protocontinents (represented in Minnesota by the ancient gneiss terrane of the Minnesota River Valley). The merging of these volcanic terranes and the related intrusion of granite occurred about 2.6 billion years ago and came to create the core of the North American continent – a landmass we call Kenoraland. About 2 billion years ago, a part of Kenoraland separated (rifted) from the main landmass and the area now occupied by the Mesabi Iron Range became the approximate continental edge of the Animikie Sea. Along this continental margin, not only were fine sediments (sand, silt and mud) being deposited from the erosion of Kenoraland, but a unique type of "chemical" sediment was being deposited as well – iron-formation (Fig. 2). During this time in earth history, simple photosynthesizing organisms (cyanobacteria, or algae) had just evolved and this biological event had a dramatic effect on the local chemistry of the oceans and the atmosphere. Prior to this evolutionary stage, the oceans and the atmosphere were deficient in free oxygen. Under these conditions, reduced iron could be easily dissolved and built up in seawater. With the arrival of oxygen-producing organisms, which formed algal "reefs" along the shorelines of the world's continents, this iron was quickly (geologically-speaking) precipitated as iron minerals and collected on the shorelines. By this biologically-mediated process (referred to as the Great Oxidation Event or GOE) most of the major iron-formations of the world were created. The present position of the Mesabi Iron Range roughly approximates the northern edge of the Animikie Sea – the body of water into which iron-formation and other sediments were deposited. A Offshore (mud, turbidites) ANIMIKIE SEA Si,Fe B glacial till S Algal Reef Nearshore (iron oxide, chert) Sediment (sand, silt, mud) O Archean Crust Natural Ore Natural Ore N Virginia Fm. Biwabik Fe-Fm. Pokegama Qtzt. ~ 1 km Figure 2. A. Depositional environment of the Biwabik Iron Formation and related sedimentary rocks of the Mesabi Iron Range. B. Idealized cross section across the Mesabi Iron Range showing the relationship of faulting to the occurrence of natural ores. 2 The nearly flat-lying sedimentary rocks of the Eastern Mesabi Range we see today indicate that these roughly 1.85 billion year old rocks have been only mildly deformed since their deposition at the margin of the Animikie Sea. Following these same rocks to the south, however, we find that they become strongly folded, faulted, metamorphosed (to slates and schists), and intruded by granite. This transformation resulted from the tectonic collision of Kenoraland with a volcanic island arc (now exposed in central Wisconsin) about 1.8 billion years ago (Fig. 3). This collision formed the Penokean Mountains – an impressive mountain belt that stretched northeasterly across central Minnesota and northern Wisconsin (Fig. 4). The addition of this new Penokean terrane to Kenoraland gave rise to a larger continental mass called Laurentia. The Penokean Mountains did not last long, however. By 1.7 billion years ago they were eroded flat. Figure 3. Tectonic model for deposition and deformation of sediments deposited in the Animkie Sea about 1.85 billion years ago. With the formation of Laurentia, roughly two-thirds of present-day North America had been created. The remainder would come with the addition other mountain belt terranes along the margins (e.g. the Grenville Mtns, the Acadian Mtns, the Appalachians, the Rocky Mtns). However, continents do not always just grow, but at various times may rift off part of themselves (as Kenoraland did to form the Animikie Sea). About 1.1 billion years ago, Laurentia was attempting to separate off a part of itself along a continental rupture called the Midcontinent Rift. This rift arched from lower Michigan, through the Lake Superior region, and southwest into eastern Kansas (Fig. 4). As the land mass inside the arching rupture migrated southward, basaltic magma welled up from deep in the earth's mantle to erupt layer upon layer of lava flow into the breach. 3 Midcontinent Rift Granite-Greenstone Terrane Animikie Sedimentary Rocks Volcanic Arc Figure 4. Trace of the Midcontinent Rift arcing across Penokean terrane. Although the figure shows the extent of the Penokean Mountains which formed at 1.85 Ga, the mountain belt was eroded to a flat plain by the time the Midcontinent Rift developed at 1.1 Ga. Arrows show the general direction of separation of the Laurentian continent. At its greatest separation in the Lake Superior region, the lava piled up to over 20 kilometers in thickness – more than half the thickness of the crust. After a time, some of the magma began to stage in sheet-like magma chambers at the base of the lava pile. Being insulated by the overlying volcanic rocks, these magmas cooled slowly to form a coarse-grained igneous rock called gabbro. More or less continuous bodies of gabbro can be traced from Duluth to the Canadian border in northeastern Minnesota (Fig. 1). We call this mass of intrusive igneous rock the Duluth Complex. In the eastern Mesabi Range, the intrusions of the Duluth Complex invaded below the lowest volcanic rocks of the rift and therefore we now find gabbro in direct intrusive contact with older rocks of the Mesabi Range and the Granite-Greenstone terrane (Fig. 1). Most continental rifts progress to complete continental separation but the Midcontinent Rift did not. The reason for this probably has to do with the fact that at this same time what is now South America was colliding with the eastern margin of Laurentia (proto-North America) to create the Grenville Mountains (the remnants of which stretch across upstate New York and southern Quebec). That collision probably closed the Midcontinent Rift. With the cessation of crustal separation and volcanic activity, the heavy basalts and gabbros filling the Midcontinent Rift caused the crust to sag and the Rift to become infilled with sand from the surrounding highlands. These sands are now the sandstones of east central Minnesota and the Bayfield Peninsula. The sagging also tilted the rocks on the margins of the rift, whereupon erosion has 4 now exposed the once deeply buried base of the volcanic pile and its collection of gabbro intrusions. Although the area of the Eastern Mesabi has been tectonically quiet for over a billion years, the "recent" invasion of continental glaciers over the past 2 million years has sculpted a new landscape. With glaciers being one of the most powerful erosive agents on earth, these mighty bulldozers of nature wore down the weak rocks in the area and left the more resistant rocks standing as higher ground. It is no coincidence that the great watershed divides between Hudson's Bay, Lake Superior, and Mississippi River drainage run along the granite highlands of the Giants Range batholith just to the north of the Mesabi Range. Granite is a very erosion resistant rock. The glaciers in their last retreat about 12,000 years ago left behind a blanket of sediment that covers most of the crystalline bedrock. Some of this sediment is molded into glacial landforms such as moraines, eskers, and drumlins. Mineral Deposits of the Eastern Mesabi Range The formation of economical mineral deposits depends on a unique combination of factors coming together at the right time and at the right place in the earth's crust. The creation of iron formation coincided with a singular irreversible oxygen producing evolutionary event occurring at a time when the shoreline of the Kenoraland continent coincided with what became northern Minnesota. The positioning of copper-nickel sulfide deposits along the base of the Duluth Complex coincided with mixing of the right ingredients of metal-rich magma and sulfur-rich wall rocks and with just the right amount of erosion to expose these deeply formed deposits at the present day land surface. Indeed, one of the most important ingredients for making an economic ore deposit is luck. And at least in terms of iron ore and perhaps copper, nickel and platinum ore, Minnesota has been particularly lucky. Iron Ore – The Mesabi Iron Range (Fig. 5) is one of the most important mining districts in the world. The Biwabik Iron Formation, the name given to the geological formation exposed along the Mesabi Iron Range, has produced around 4 billion metric tons since the first shipment in 1892. There are six operating iron mines employing about 3,500 people in the region. They all produce taconite pellets from low grade magnetic ore. Four are captive to steel companies, two produce pellets for market, generally through long term contracts. Product shipping is largely by rail to one of four ports on Lake Superior (Superior, Duluth, Two Harbors, and Silver Bay), then by boat to mills on the lower lakes. About thirty eight million tons of pellets were produced in 2007. Total material movement (ore and stripping) was on the order of two hundred million tons. The one-hundred plus year history of this world class mining district means that there is an extensive developed infrastructure and service industry for these mines. Mesabi Nugget in Hoyt Lakes is producing iron nuggets for use in electric arc furnaces by a so-called direct reduction process. Essar Steel in Nashwauk is re-opening the closed Butler Taconite mine with an aim to eventually making slab steel on site from direct reduced iron pellets, as well as taconite pellets for Algoma Steel in Sault St. Marie Ontario. The Biwabik Iron Formation was produced by the biologically-mediated precipitation of iron-rich and silica-rich gels from seawater some 1.9 to 1.85 billion years ago. When these sediments became lithified through the process of diagenesis (by burial, compaction, and 5 Figure 5. (A) Map of Mesabi Iron Range with aerial distribution of taconite pits (magenta) and cities (blue). Trend of Biwabik Iron Formation is outlined in red (modified from Jirsa et al., 2005). (B) Longitudinal section (looking north) of the Biwabik Iron Formation showing: variation in thickness of the iron-formation members at each taconite operation; mined taconite intervals at each operation represented by black bars. dewatering) to form rock, some of the original iron minerals were transformed into the mineral magnetite (Fe3O4), and the silica gel hardened to a microcystalline form of quartz (SiO2) called chert. Sediments deposited in deeper water hardened to clay. Because the relative rates, and relative sites, of sedimentation of these three materials varied, iron-formation is typically banded between "slatey" layers (deeper water) and chert-rich layers (shallow water) that contain variable amounts of magnetite. In fact, these rocks are often referred to as banded iron-formations, or BIFs. Where this BIF is particularly rich in magnetite (30% or more magnetite, about 22% iron), the rock is referred to as taconite ore. This is the type of iron-formation being mined today. The processing takes advantage of the fact that magnetite is, well, magnetic. As will be explained in greater detail during our visit to the taconite plants, the taconite ore is crushed, mixed with water and ground to a very fine powder, and then passed over magnetic drums that separate the magnetite from the clay and chert. During the first half of the 20th century, however, a different type of iron ore was mined one called natural ore or direct-shipping ore. The natural ore formed by the oxidation of the iron-formation along fault zones by either descending meteoric fluids or ascending hydrothermal fluids – two entirely different origin processes that have been debated by geologists over the last 100 years. Whatever the origin, this alteration caused the magnetite to be oxidized to other types of iron oxides (hematite, goethite, limonite) and caused the dissolution of chert leaving behind a rock strongly enriched in iron (>65% Fe). As can be seen in Figure 2B, the locations of these natural ore bodies usually occurred along fault zones cutting the iron formation, suggesting that faults provided pathways for the altering fluids. 6 Cu-Ni-PGE Ore – The magmatic intrusion of the Duluth Complex into older rocks of the Mesabi Range and the granite-greenstone terrane has resulted in the creation of one of the largest concentrations of copper (Cu), nickel (Ni), and platinum group element (PGE) ore in the world. For the past 50 years, at least 22 mineral exploration companies have explored along the base of the Duluth Complex and by drilling into the bedrock (over 2,000 holes totaling over 2.0 million feet of drill core) they have identified 10 areas sufficiently enriched in Cu-Ni±PGE sulfide ore to be potentially mineable (Fig. 6). Although the total tonnage of ore is larger than any other deposit of its type, the concentration of copper, nickel, and PGE in the ore is low. With more efficient processing techniques and demand for PGE for auto catalysts, however, these deposits once evaluated for copper and nickel are currently being reevaluated as sources for copper, nickel, cobalt, platinum, palladium, gold, and silver. Figure 6. Cu-Ni-PGE and Fe-Ti deposits of the Duluth Complex (from Severson & Hauck, 2008) These deposits formed when hot gabbroic magmas of the Duluth Complex, rich in metals, came into contact with older rocks, locally rich in sulfur. So much sulfur was assimilated by the gabbroic magma that it caused the sulfide to unmix from the magma as separate liquid. Given a choice between residing in a sulfide liquid or a silicate magma, metals will strongly choose the sulfide melt. So as the dense droplets of sulfide liquid would form, they would settle through the magma and settle on the floor of the chamber, scavenging metals along the way. With the cooling and crystallization of the sulfide melt and magma, the resulting rock became a gabbro typically containing several percent sulfide minerals of iron, copper, nickel, and trace amounts of PGE. Again, were it not for erosion which removed about 2 kilometers of lava flows overlying the Duluth Complex these deposits would not be accessible. 7 Sand and Gravel – Many people are surprised to learn that the mining and processing of sand and gravel (aggregate) resources is the largest mining industry in the State of Minnesota. And while thanks to the glaciers, we have a fair abundance of unconsolidated sediment spread over the surface of the state, much of this sediment contains too much clay to be used. Indeed, just like other mineral deposits, some special factors had to come together to produce a "washed" sand and gravel deposit. Usually washing required the sorting and winnowing action of glacial meltwaters as it carried away the glacial sediment. Consequently, well-washed sediment can be found in meltwater channels, on outwash plains that spread out from the margins of the receding glaciers, and in eskers, which represent sediments deposited in subglacial meltwater valleys. Figure 7. Major glacial ice lobes that advanced over Minnesota around 14,000 years ago. In their retreat around 12,000 years ago, the glaciers left behind deposits of glacial till and outwash . 8 Field Trip Stops DAY 1 POLYMET PLANT SITE AND BIWABIK IRON FORMATION AT THE INACTIVE LTV MINE, AND WETLEGS CU-NI DEPOSIT At the inactive workings of the LTV mine are eleven separate open pits from which the Biwabik Iron Formation was mined. Initially operated by the Erie Mining Company, this was the second taconite mine to be established on the Mesabi Iron Range with production starting in 1957. Most of the original LTV facilities have been purchased by PolyMet Mining Company and will be used to process Cu-Ni-PGE ore from their NorthMet deposit in the nearby Duluth Complex (Figs. 8 and 9). The Erie plant was the largest project ever built when done in the 1950’s at a cost of $330 million. Construction included the plants, mines, 70 mile railroad, enough shops to be selfsufficient, the Town of Hoyt Lakes, a power station, and docks on Lake Superior. PolyMet has a resource of about 1 billion tons. Within that resource there is a reserve of about 275 million tons of ore. The current plan (June 2011) is to mine about 225 million tons over twenty years at a grade of 0.28% copper, 0.08% nickel, 70 ppm cobalt, plus platinum, palladium, and gold. The Process Plant design is based on key parameters determined by the characteristics of the deposit to be mined and the beneficiation and hydrometallurgical processes that will extract the metals from the ore. On average, 32,000 short tons of ore will be processed each day. This results in annual production of ________tons of copper concentrate, ______tons of nickel and cobalt concentrates, about 22,000 ounces of platinum, 87,000 ounces of palladium and 13,000 ounces of gold. The process plant is located at the LTVSMC plant site. The entire Process Plant is in an area that was previously disturbed by mining operations. The Beneficiation Plant will use the Coarse Crusher Building, Fine Crusher Building and Concentrator Building that were part of the LTVSMC taconite plant. The flotation process has been designed to recover virtually all of the sulfide minerals to the concentrate and minimize the amount of sulfide minerals remaining with the tailings. This process has been tested with ore samples representing the NorthMet ore in a pilot plant set up to represent the proposed grinding and flotation process. The flotation tailings generated by this work has been subjected to rigorous waste characterization. Collectively this has demonstrated that the flotation tailings can be placed in the LTVSMC Tailings Basin. The result is that there is no surface discharge of process water at the Plant Site and that the requirement for make-up water via water appropriation from Colby Lake is minimized. 9 Figure 8. PolyMet’s NorthMet project site. 10 Figure 9. Detail of Erie Plant site showing existing facility and proposed construction. 11 Stop 1-1: PolyMet offices – bathroom stops and introduction to PolyMet staff. Stop 1-2: Coarse Crusher Stop 1-3: Rod and Ball Mill Stop 1-4: Tailings Basin Stop 1-5: Lower Cherty and Lower Slaty members of the Biwabik Iron Formation Location: Pit 5E, Cliffs-Erie site, T. 60 N., R. 13 W., sec. 31, SW, SW Allen quadrangle; UTM: 571,040E/5,275,876N (NAD-83) Description: At this inactive mine pit the entire stratigraphic section of the Lower Cherty and Lower Slaty members can be viewed. Also present at this site are localized exposures of the underlying Pokegama Formation (quartzite) and granitic rocks of the Archean Giants Range Batholith. Both are exposed in the floor of the mine where they are present as several small domal features The Lower Cherty member at this site is about 80 feet thick. Most of the Lower Cherty constitutes taconite ore. At the bottom of the iron-formation are several thin units that were each formed in different energy environments due to deposition at variable depths below wave and storm action. These units consist of: conglomerate (high energy), algal stromatolite horizons (moderate energy), thin-bedded iron-formation (low energy) and pale gray chalcedonic chert/flint bands with quartz-filled syneresis cracks (indicating that the chert was deposited as a silica gel). The stromatolites are recognized by bright red jasper columns. The conglomerate contains a variety of iron-formation clasts with a sprinkling of detrital quartz grains from the underlying Pokegama Formation. Most of the rock in the pit wall at this stop exhibits what is called wavy-bedding in that the dark-colored magnetite-rich bands show pinching, swelling, terminations, and splitting in a semirandom fashion. Cross-bedded features are also present in the wavy-bedded iron-formation indicating that they were deposited in a relatively high-energy environment (shallow water on the edge of a shoreline). Also present within the wavy-bedded iron-formation are pink-colored spheres, or mottles less than 1 cm across, that are composed of ankerite (iron-carbonate). The Lower Slaty member of the Biwabik Iron Formation is exposed along the southern edge of this pit. It is a weakly-magnetic rock and is not taconite ore. The rock is characterized by thinbedded rock indicative of deep water deposition (low energy environment). At the very base of the Lower Slaty member is the "Intermediate Slate" which is a thin-bedded, black, organic-rich mudstone that may contain volcanic tuffaceous materials. The "Intermediate Slate" is extremely fissile (readily breaks into small chips) and locally exhibits bright, shiny graphitic surfaces with bedding-parallel slickensides (grooved surfaces that indicate one rock face moved past another rock face). 12 Stop 1-6: Biwabik Iron formation at the Cliffs-Erie site Location: Pit 3, Cliffs-Erie site, T. 59 N., R. 14 W., secs. 14 and 15, Allen quadrangle Description: While continuing to stop 7 the bus will go through Pit 3 where ore was mined from the Lower Cherty member. Note that the undulating floor of this pit was exposed during striping by following the bedding trends of one or two bed forms. Use your imagination and peer back through time (1.9 by) to reconstruct a scene where these roll-and-swell bedding planes represent iron-rich sediments that are accumulating along a continental shelf on gently rolling surfaces. Stop 1-7: Archean/Paleoproterozoic unconformity at the Cliffs-Erie site Location: Cliffs-Erie site, T. 59 N., R. 14 W., sec. 14, NE, NW, NE Allen quadrangle Description: After a short walk from the bus, this stop is an excellent exposure of a 700 million year break in the geological record. Such breaks are called unconformities. At this location, steeply-dipping Archean (2.6 by) sedimentary rocks are unconformably overlain by the Pokegama Formation (1.9 by). Again, imagine yourself to have traveled back in time (1.85 by) to a sandy beach on the northern shore of an inland sea. As you look to the south all you see is a vast sea, but if you could look underwater you would notice that iron-rich sediments of the Biwabik Iron-Formation are accumulating on the continental shelf, and further out, deep water sediments of the Virginia Formation are accumulating. As you turn and look to the north you would see a low range of hills, consisting of the ancient Archean rocks, from which streams would meander down to the inland sea. Now, back in the present, it is possible to actually put your finger on the unconformity line that separates rocks that are 2.6 by old from rocks that are 1.8 by old. This gap in time represents approximately a 700 million year time span - a span that is 13 times greater than the span of time that has passed since the dinosaurs last roamed this planet. Try to imagine the immense passage of time represented by the sharp contact between these two different-aged rocks and think about what could have taken place in that time span. Stop 1-8: Algal submember near the top of the Upper Cherty member, Biwabik Iron Formation Location: Pit 2E, Cliffs-Erie site, T. 59 N., R. 14 W., sec. 14, N 1/2, NW Access to this site is via Dunka Road, which is a private mining company road. Allen quadrangle; UTM: 568,202E/5,270,625N (NAD 83) Description: Algal structures were first described by Leith (1903) as "contorted bedding." Grout and Broderick (1919) were the first who assigned an organic origin to them. This locality is an excellent place to view a nearly horizontal portion of the iron-formation that contains abundant individual mounds of algal stromatolites. Internally, the mounds are characterized by many individual, columnar, finger-like structures that are convex upward. Recent studies have shown that the bacteria that produced these algal mounds were able to directly precipitate iron (an intermediary oxygen-producing stage was not necessary to precipitate the iron). Between the 13 mounds are conglomeratic units that were deposited as storm debris. Again, use your imagination to peer back through time to reconstruct a scene where shallow waters along the shoreline of the Animikie sea are covered with close-spaced algal mounds that are responsible for the deposition of the iron-formation. A remarkably similar scene of algal mounds could be viewed today at Shark Bay in Australia. Stop 1-9: Virginia Formation near Siphon fault Location: Cliffs-Erie site, T. 59 N., R. 14 W., sec. 14, SE, SE, NE, Allen quadrangle Description: This area contains the only natural exposures of the Virginia Formation on the Mesabi Iron Range. Unfortunately, the formation is only a few 10s of feet thick at this site. The Virginia Formation overlies the Biwabik Iron Formation and a total of 1,443 feet of the formation is present in drill cores from holes drilled south of the Mesabi Iron Range. At this stop, note the sedimentary features such as: graded beds, mud chips, concretions, thin cross-bedded lenses, and loading at the base of some beds. These sedimentary features are indicative of deposition by turbidity currents which are generated when loose sediment near the shoreline is jostled by storm activity (or seismic activity) and the resultant muddy slurry flows downward along the bottom of ocean. Note that the bedding is near vertical in this location due to proximity to the north-trending Siphon fault. The sedimentary features indicate which way the beds top – which is to the east. Also present at this site is a large glacial erratic of marble derived from a horizon at the top of the Biwabik Iron Formation. This marble horizon is unique in that it records evidence of a major catastrophic event that occurred over 500 miles to the east when a meteorite struck the earth near the present town of Sudbury, Ontario. This Sudbury Impact Event, produced by a meteorite over 10 miles in diameter, is the second largest such impact on the planet and took place 1.85 b.y. ago. The table below shows the effects that might have been expected in this area (calculated for the Gunflint Lake area of Minnesota by Mark Jirsa). Some scientists have suggested that the impact drastically changed the environment, wiped out the bacteria in the Animikie Sea, and subsequently stopped deposition of the iron-formation. Arrival Time ~13 seconds ~2-3 minutes Effect Fireball Earthquakes ~5-10 minutes Airborne ejecta arrives ~40 minutes Air Blast ~1-2 hours Tsunami 14 Modern Analog 3rd degree burns, trees ignite Richter scale 10.2 at Sudbury, seismic shaking at Siphon Fault site Layer at base of marble contains airborne microtektites and shocked quartz Maximum wind speeds ~1,400 mph Tokyo 2011? Stop 1-10: Wetlegs Copper-Nickel deposit (railroad cut off Dunka Road) Location: Rail tracks just south of Dunka Road T. 59 N., R. 13 W., sec. 17, NE, SE, SE Allen quadrangle; UTM: 572,72E/5,271,178N (NAD 83) Description: This stop is a chance to see and sample gabbroic material from the Duluth Complex with copper-nickel (Cu-Ni) mineralization. Drilling in this area by three exploration companies (International Nickel Co., Bear Creek Mining, and Exxon Minerals) during the late1950s through the 1970s outlined a small Cu-Ni deposit of about 38,000,000 tons of material grading 0.57% Cu+Ni. Sulfide-bearing rocks exposed in the railroad cut consist of heterogeneous ophitic augite troctolite to olivine gabbro with patches and lenses of augite-rich pegmatite. Note the rusty ironstaining that is characteristic of the rock. This type of staining is normally looked for when exploring for Cu-Ni deposits and is due to weathering and oxidation of the sulfides in the rock. The sulfides that are present include pyrrhotite (iron sulfide), pentlandite (nickel sulfide), and chalcopyrite (copper sulfide). One of the gabbroic exposures on the tracks exhibits variably-sized anorthosite inclusions that range from 2 inches across to 10x15 foot blocks. The anorthosite crystallized earlier from a plagioclase-rich magma only to be broken-up, surrounded and carried upward by later gabbroic magmas. Two other major base metal deposits occur further to the northeast in the Duluth Complex: the NorthMet (Dunka Road) Cu-Ni deposit and the Mesaba (Babbitt) Cu-Ni deposit. The NorthMet deposit, initially drilled by United States Steel Corp. (1969-1974) is currently undergoing environmental review to be permitted as a possible mine by PolyMet Mining Corp. PolyMet estimates that the deposit contains about 1 billion tons of material grading 0.43% Cu and 0.11% Ni with localized concentrations of 1-2 ppm Pd (around 0.03 oz/ton). Probably the largest of the known Cu-Ni deposits is the Mesaba deposit which was drilled and defined by Bear Creek Mining (1959-1971) and by AMAX (1974-1978). The deposit is currently controlled by Teck American., Vancouver, B.C., who are also trying to establish a non-ferrous mine in the state of Minnesota. Teck estimates that the Mesaba deposit, contains about 1 billion tons of material that grades about 0.46% Cu and 0.12% Ni. DAY 2 UNITED TACONITE MINE AND FAIRLANE PLANT, IDEA DRILLING, AND MINE VIEW IN THE SKY Stop 2-1: United Taconite Mine/Thunderbird North Mine (Eveleth, MN) Description – At this locality, magnetic taconite is mined from the Lower Cherty, Lower Slaty, and Upper Cherty members of the Biwabik Iron Formation. Direct-shipping ore, also referred to a natural ore, was originally mined in the immediate vicinity. Exploration for taconite at this site began in earnest in 1960, after the opening of pioneering taconite operations at the Reserve Mining Company (now Northshore) and Erie Mining Company (now Cliffs-Erie site) in the mid1950s. Drilling by Oglebay Norton Company identified several magnetite deposits in the area 15 and the property was jointly developed by the Ford Motor Company – groundbreaking occurred in June, 1964. The Thunderbird North mine and Fairlane plant began producing in November, 1965, with an initial rated capacity of 1.6 million tons of iron ore pellets per year. In 1977, addition of a second concentrating and pelletizing line, and the opening of the adjacent Thunderbird South mine, increased rated capacity to 6.0 million tons of pellets. The Thunderbird South mine closed in 1992, and in 1996, ownership of the operation was transferred to Eveleth Mines LLC. Eveleth Mines closed the concentrating and pelletizing Line 1 in May, 1999, reducing capacity to 4.2 million tons of pellets. The remaining operation was idled in May, 2003. The idled facility was purchased and re-opened by United Taconite LLC in December, 2003 (now owned 100% by Cliffs Natural Resources). They subsequently refurbished and reactivated Line 1 in December, 2004, which increased the annual rated capacity to 5.2 million tons of pellets. Field trip stops at this site will include a general view of the mine operations and other geologic sites to be announced on the day of the field trip. Stop 2-2: Fairlane Processing Plant (Forbes, MN) Description – Taconite is an economic term for iron-formation from which iron can be profitably extracted after fine-grinding the rock followed by magnetic separation and pelletizing. Because taconite is incredibly hard there are several steps that are needed to grind it to a face powder consistency. Figure 10 is a generalized flow sheet that illustrates the basic steps to produce taconite pellets. This chart should be taken with you while taking the tour through the plant to help you understand what you will be viewing (the plant is noisy and it is difficult to hear what the guides are saying all of the time). A few items that are not displayed in this figure are: It takes 3 tons of mined iron-formation to produce 1 ton of pellets; Most of the cost of producing pellets is in the first crushing phase – it takes a lot of energy to crush the extremely hard rock to a consistency of face powder; Water is added to the process in the rod and ball mills – at least 20 rods (out of over 100 rods) are replaced in the rod mill every other day due to intense wear-and-tear in crushing the hard rock; Magnetite is separated from the rock. Bentonite clay (or an organic binder) is added to this magnetite powder in the balling drum to hold the material together as spherical pellets that are made by a rolling action; and Several temperatures are needed in the furnace as follows: o Pre-oxidation temperature of 800º F is initially needed to convert the magnetite pellet to a hematite pellet through oxidation (90% oxidized); o A maximum of 2200-2400º F is reached to indurate the pellet (a temperature of >2500º F starts to melt the furnace); and o A final heating stage of 600º F converts any remaining magnetite to hematite – this final oxidation step is recognized when all of the free oxygen in the furnace is consumed by burning. 16 Figure 10: Simple flow sheet of steps to produce taconite pellets from magnetic iron-formation (from 1959 USS training manual). Stop 2-3: Idea Drilling Office (Virginia, MN) Here we will see how the exploration core drilling process works. IDEA is one of the main service companies to the local exploration community. Weather permitting they will set up a drill rig in the parking lot and help us explain the components of the process. Mechanically, the drill rig consists of a power unit that is capable of rotating a series of interconnected steel rods (called a core barrel). A tubular steel bit, in which industrial-grade 17 diamonds are set, is screwed onto the bottom of the core barrel. This bit, and core barrel above it, are rotated at speed under controlled pressure. Water is pumped down through the core barrel to cool the bit and to remove rock cuttings that are generated as the diamonds in the bit abrade the rock. With advance of the bit, a cylindrical core of rock (called drill core) passes up into the core barrel. Retrieval of the drill core used to be by withdrawing all of the steel rods to get at the bottom-most rod. This tactic has since changed with the invention of a wire line which is a “grabbing” tool that is sent down within the string of rods, slips over the drill core, and the entire assembly (along with the drill core) can then be pulled back to the surface. Ask the drillers to show you how the wire line assembly works. Other questions should become obvious as you are shown the basics of how drilling rigs operate. Stop 2-4: Giant’s Range Granite at the Laurentian Divide wayside rest, Hwy. 53. Location: T.58N., R.17W., sec. 19, SE, SE; wayside off Highway 53: Virginia Quadrangle; UTM: 534,337E/5,269,458N. Description: At this stop, we see outcrops of the Giant’s Range batholith, the “granitic” portion of the Archean “granite-greenstone” terrane. The Giant’s Range granite crops out from Babbitt, on the east Range, to west of Hibbing, a distance of about 60 miles. Rising 200 to 400 feet above the surrounding countryside, it forms the hills that we see in the distance to the north of the Rouchleau mine overlook (Stop 2) and at various points along the trip. These hills form the Laurentian Drainage Divide in this area – water on the northern side of the divide flows to Hudson Bay; on the southern side, water flows to the Atlantic ocean via the Great Lakes and the St. Lawrence Seaway. These granitic rocks intruded, or forced their way into, the pre-existing volcanic and sedimentary rocks (outcrops ¼ mile to the south), metamorphosing and deforming them about 2.6 billion years ago. Subsequent erosion exposed these deep-seated rocks at the surface by the time the younger Biwabik Iron formation was deposited on top of them (about 1.9 billion years ago), as we now observe just to the south of here. The lighter colored rock is called tonalite while the darker is a diorite; which intruded which? Other dark patches may be inclusions of metamorphosed volcanic or sedimentary rocks which the “granite” intruded. The complex intrusive relationships of one rock into another, and vice versa in other areas, have led to the naming of this exposure as “Confusion Hill.” Stop 2-5 (optional): Gravel pit near Britt, MN If time permits we will make a stop at a gravel pit. The sand, gravel, and boulders in this pit were left behind by glaciers as they retreated from this area around 12,000 years ago (Fig. 7). The materials in this pit are typical of the Rainy Lobe - they were quarried out of the granitegreenstone terraine to the north and then carried southward by the glaciers to their present site. Every boulder in this pit has a story to tell - in what rock did they originate, when did they form, and how did they get here. Find a geologist/guide in your group and test their knowledge by having them “interpret” the stories that the rocks tell, and then see if you too can hear the stories. 18 Stop 2-6: Mineview in the Sky Overlook (Virginia, MN) Location: T.58N., R.17W., sec. 17, NW, SE; north of the junction of highways 53 and 135; Virginia Quadrangle; UTM: 535,710E/5,261,650N. Description: This stop presents an excellent view of a typical “natural ore” mine within the Biwabik Iron-Formation of the Mesabi Range. The term “iron-formation” refers to bedded sedimentary rock that contains 15 percent or more iron. Natural ore, also referred to as direct ore or high-grade ore, was the first type of ore mined from the Mesabi Range at the turn of the 20th century. This ore type was composed mainly of the minerals hematite and goethite and was easily dug out of the ground due to its soft/weathered nature. Natural ores were formed by oxidation and leaching of the Biwabik Iron Formation by circulating water, in the vicinity of faulted and/or fractured zones, to produce a soft iron-enriched material (Fig. 2B). Almost the entire section of the Biwabik Iron Formation (over 700 feet thick) can be viewed on the sides of the pit at this location. The Rouchleau Mine, and a series of adjoining smaller mines, extends for a distance of over 3 miles to the north along a NNW-trending fault (see Mesabi Range map). Note the high hills on the northern horizon, formed by the Giant’s Range granite. Also on the northern horizon, and a little to the west, is United States Steel Corporation’s Minntac taconite mine and plant. At this locality, magnetic taconite is mined from the lower portion of the Biwabik Iron Formation. Taconite is an economic term for iron-formation from which iron can be profitably extracted after fine-grinding the rock followed by magnetic separation and pelletizing. Currently, there are six operating taconite mines on the easternmost 2/3rds of the Mesabi Range. Stop 2-7: Archean pillowed basalt lavas at Gilbert Junior High School Location: T.58N., R.17W., sec. 23, NW, SW, SW; north edge of athletic fields, Gilbert Junior High School; Gilbert Quadrangle, UTM: 539,820E/5,259,750N. Description: At this stop are beautifully preserved pillow structures, formed over 2.6 billion years ago, as lava flowed into a marine sea-floor environment and cooled relatively rapidly. The pillows are defined by the darker grey-green “rinds” forming lobate shapes as the outer portion of the lava quenched on contact with the water. The pillows pile up and drape over one another on the sea floor (Fig. 11). Deformation has tilted these volcanic rocks to a near vertical position and thus giving us a cross sectional view. Can you tell by the draping of the pillows which way was up (toward the water)? Some of this tilting may have been caused by the intrusion of the Giants Range batholith (Stop 1), which is exposed just to the north of here. Note the local occurrence of fractures filled with a reddish glassy material. This is chert, a microcrystalline quartz mineral formed by precipitation from seawater. Red chert is called jasper; black chert is called flint. Chert occurs with iron oxide as the major constituent of banded iron formation. The Biwabik Iron Formation crops out just to the south of this exposure . How would you explain the presence of this chert here? Note also the smooth, glacially scoured nature of the outcrop. Grooves, or striations, some several centimeters across and ½ to 1 cm. deep, are evident and the result of abrasion by the sediment load carried within the glacial ice mass. These smooth, rounded outcrops are often referred to as whalebacks. 19 Cooling against Seawater Pillow Basalts Vesicular Crust Inflation Figure 11. Formation of pillowed structures in submarine basalt flows. 20
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