2 3 4 5 6 7 Supplement Fig. S1. Simulated zonal mean vertical profiles of N2O mixing ratio (ppb) for DJF (upper panel) and JJA (lower panel) shown for each model as indicated in the top-left corner. Superimposed are contours of annual mean potential temperature (K) (white lines) and annual mean tropopause height (dotted black line). 43 1 Fig. S2. Map showing the observations used in this inter-comparison study. ALT ZEP MHD PFA BRW SHM THD NWR HAAKUM MLO CHR ULB IZO RPB ASC SMO SEY RTA EIC CGO TDF HBA NOAA CCGG AGAGE NOAA aircraft SPO 2 3 44 Fig. S3. Comparison of the zonal annual mean meridional gradients of N2O (ppb) at the surface with the modelled/observed global mean mixing ratio subtracted. Shown are the gradients calculated using the flux scenarios: OCNPIC (top left), OCNN04 (top right), OCNN95 (bottom left), and BWMN04 (bottom right) with the integrated flux in 10° latitudinal bands (TgN y-1) from each scenario shown in the bar-plot below. Legend: Mozart4: yellow, ACTMt42l32: blue, ACTMt42l67: green, TM5: grey-blue, TM3-NCEP: purple, TM3-ERA: red, LMDZ4: magenta, TOMCAT: dark green, observed: black. 2 2 1 1 N2O [ppb] N2O [ppb] 1 2 3 4 5 6 7 8 9 0 −1 −2 −90 −60 −30 0 30 60 90 N2O [TgN y−1] N2O [TgN y−1] 2.0 1.5 1.0 −60 −30 0 30 60 N2O [ppb] N2O [ppb] 0 −60 −30 0 30 60 90 30 60 90 −60 −30 0 30 60 90 1.5 1.0 Latitude 0 −1 −2 −90 −60 −30 0 30 60 90 −60 −30 0 30 60 90 2.5 N2O [TgN y−1] 2.0 N2O [TgN y−1] 0 1 −1 1.5 1.0 0.5 2.0 1.5 1.0 0.5 −60 −30 0 Latitude −30 2 1 10 11 12 13 −60 2.0 0.0 −90 90 Latitude 2 0.0 −90 −2 −90 0.5 0.5 −2 −90 −1 2.5 2.5 0.0 −90 0 30 60 90 0.0 −90 Latitude 45 1 2 3 4 Fig. S4. Hovmöller plots of N2O fluxes from the terrestrial biosphere in OCN (BWM had no seasonal cycle) and from the ocean in PIC, N95 and N04 (from top to bottom). Fluxes are shown in gN m-2 y-1. OCN 0.10 0.08 0 Latitude 50 0.12 0.06 −50 0.04 0.02 0.00 2 4 6 8 10 12 PIC 0.10 0.06 0.04 0 Latitude 50 0.08 0.02 0.00 −50 −0.02 −0.04 2 4 6 8 10 12 N95 0.10 0.06 0.04 0 Latitude 50 0.08 0.02 0.00 −50 −0.02 −0.04 2 4 6 8 10 12 N04 0.10 0.06 0.04 0 Latitude 50 0.08 0.02 0.00 −50 −0.02 −0.04 2 5 6 4 6 8 10 12 46
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