Redox Half Reactions and Reactions WS 1. State the Oxidation Number of each of the elements that is underlined. a) NH3 b) H2SO4 c) ZnSO3 d) Al(OH)3 e) Na f) Cl2 g) AgNO3 h) ClO4- j) K2Cr2O4 k) Ca(ClO3)2 l) K2Cr2O7 n) HClO o) MnO2 p) KClO3 q) PbO2 r) PbSO4 s) K2SO4 t) NH4+ u) Na2O2 v) FeO w) Fe2O3 x) SiO44- y) NaIO3 z) ClO3- aa) NO3- i) SO2 m) HPO3 2- cc) CaH2 dd) Pt(H20)5(0H) 2+ bb) Cr(OH)4 ee) Fe(H2O)6 3+ ff) CH3COOH 2. What is the oxidation number of carbon in each of the following substances? a) CO d) CO3 2- 3. Define each b) C c) CO2 e) C2H6 f) CH3OH Oxidation Oxidizing agent Reduction Reducing agent 4. For each of the following reactions, identify: the oxidizing agent, the reducing agent, the substance oxidized and the substance reduced. a) Cu2+ (aq) Zn (s) --------> Cu (s) + Substance reduced Oxidizing agent Reducing agent + 2 Na (s) --------> 2 Na+ (aq) + Substance reduced Oxidizing agent Reducing agent Determine the oxidation number for the element underlined. PbSO4 ClO3- HPO32- Na2O2 CaH2 Al2(SO4)3 NaIO3 C4H12 Al3+ + Zn → Substance oxidized 7. Cr2O72- 2 Cl- (aq) Substance oxidized What is Oxidized & what is the oxidizing agent 6. Zn2+ (aq) Substance oxidized b) Cl2 (g) 5. + + Substance reduced Al + Zn2+ Oxidizing agent ClO2- → Cr3+ + ClO4- Oxidizing agent 8. Cr3+ + ClO4- → Cr2O72- + ClO2- Substance reduced 9. 3As2O3 + Oxidizing agent 4NO3- + 7H2O + 4 H+ → 6H3AsO4 Substance reduced + 4NO Reducing agent Write half reactions for each of the following atoms or ions. Label each as oxidation or reduction. 10. Al ---------> Al3+ 11. S ---------> S2- 12. O2- ---------> O2 13. Ba2+ ---------> Ba 14. N3- ---------> N2 15. Br2 ---------> Br- 16. P ---------> P3- 17. Ca ---------> Ca2+ 18 Ga3+ ---------> Ga 19. S ---------> S2- 20. H2 ---------> H+ 21. H+ ---------> H2 22. F- ----------> F2 23. P3- ----------> P Balance each spontaneous redox equation. Identify the entities reduced and oxidized. State the reducing agent and the oxidizing agent. 24. Al + Zn2+ → Al3+ + Zn 25. F2 + O2- → F- + O2 26. Ca → Ca2+ + O2- 27. Al3+ → Al 3Li+ + + O2 Li +
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