SAFETY DATA SHEET SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Kit Part Number: HCK1004-01-006 Kit name: Pd Amination weak base kit, EvoluChem™ Identified Uses: For laboratory use only, not for drug, household or other use Manufacturer Name: HepatoChem, Inc. Address: 100 Cummings Center Suite 424J Beverly, MA 01915 USA Telephone: +1 617 500 5285 Fax: +1 617 274 0827 Emergency Phone: +1 857 998 0454 SDS Date Creation: November 1, 2015 SDS Revision Date January 26,2016 1 SECTION 2: HAZARD(S) IDENTIFICATION Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K0096-01-001 Chemical Name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 GHS Pictograms: Hazard Statements: H318 Causes serious eye damage. H335 May cause respiratory irritation. GHS Class: Health Hazard Category: Flammability Category: Physical Hazard: Precautionary Statements: Eye Emergency Overview: Danger 2 0 0 P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/ face protection. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Skin Inhalation P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. Ingestion Target Organs Part Number: K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K0094-01-001 Chemical Name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 GHS Pictograms: Hazard Statements: GHS Class: H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Health Hazard Category: Flammability Category: Physical Hazard: Emergency Overview: Warning 2 0 0 Precautionary Statements: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. Eye P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin P302 + P352 IF ON SKIN: Wash with plenty of soap and water. Inhalation P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. Ingestion Target Organs 2 Part Number: K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K0095-01-001 Chemical Name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 GHS Pictograms: Hazard Statements: H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. GHS Class: Health Hazard Category: Flammability Category: Physical Hazard: Precautionary Statements: Eye Emergency Overview: Warning 2 0 0 P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ eye protection/ face protection. Skin P302 + P352 IF ON SKIN: Wash with plenty of soap and water. Inhalation P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Ingestion P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell Target Organs 3 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Part Number Part Name Chemical name CAS# K-0025-01-001 XphosPdG2/K2CO3 XphosPdG2 K2CO3 1310584-14-5 584-08-7 21% 79% K-0026-01-001 XphosPdG2/K3PO4 XphosPdG2 K3PO4 1310584-14-5 7778-53-2 16% 84% K-0039-01-001 BrettPhosG2/Cs2CO3 BrettPhosG2 Cs2CO3 1451002-39-3 534-17-8 11% 89% K-0040-01-001 BrettPhosG2/K2CO3 BrettPhosG2 K2CO3 1451002-39-3 584-08-7 22% 78% K-0041-01-001 BrettPhosG2/K3PO4 BrettPhosG2 K3PO4 1451002-39-3 7778-53-2 11% 89% K-0042-01-001 RuPhosG2/Cs2CO3 RuPhosG2 Cs2CO3 1375325-68-0 534-17-8 11% 89% K-0043-01-001 RuPhosG2/K2CO3 RuPhosG2 K2CO3 1375325-68-0 584-08-7 21% 79% K-0044-01-001 RuPhosG2/K3PO4 RuPhosG2 K3PO4 1375325-68-0 7778-53-2 16% 84% K-0045-01-001 tBuBrettPhosG3/Cs2C tBuBrettPhosG3 O3 Cs2CO3 1536473-72-9 534-17-8 12% 88% K-0046-01-001 tBuBrettPhosG3/K2C O3 tBuBrettPhosG3 K2CO3 1536473-72-9 584-08-7 23% 77% K-0047-01-001 tBuBrettPhosG3/K3P O4 tBuBrettPhosG3 K3PO4 1536473-72-9 7778-53-2 17% 83% K-0048-01-001 tBuXPhosG3/Cs2CO3 tBuXPhosG3 Cs2CO3 1447963-75-8 534-17-8 11% 89% K-0049-01-001 tBuXPhosG3/K2CO3 tBuXPhosG3 K2CO3 1447963-75-8 584-08-7 21% 79% K-0050-01-001 tBuXPhosG3/K3PO4 tBuXPhosG3 K3PO4 1447963-75-8 7778-53-2 16% 84% K-0051-01-001 XphosPdG2/Cs2CO3 XphosPdG2 Cs2CO3 1310584-14-5 534-17-8 11% 89% K-0086-01-001 AmphosG3/Cs2CO3 AmphosG3 Cs2CO3 No CAS 534-17-8 9% 91% 4 EC Num Ingredient Percent Part Number Part Name Chemical name CAS# K-0087-01-001 AmphosG3/K2CO3 AmphosG3 K2CO3 No CAS 584-08-7 19% 81% K-0088-01-001 AmphosG3/K3PO4 AmphosG3 K3PO4 No CAS 7778-53-2 13% 87% K-0090-01-001 AdBrettPhosG3/Cs2C O3 AdBrettPhosG3 Cs2CO3 1445972-29-1 534-17-8 13% 87% K-0091-01-001 AdBrettPhosG3/K2CO AdBrettPhosG3 3 K2CO3 1445972-29-1 584-08-7 27% 73% K-0092-01-001 AdBrettPhosG3/K3PO AdBrettPhosG3 4 K3PO4 1445972-29-1 7778-53-2 19% 81% K-0094-01-001 CataCXium® A G3/Cs2CO3 CataCXium® A G3 Cs2CO3 No CAS 534-17-8 10% 90% K-0095-01-001 CataCXium® A G3/K2CO3 CataCXium® A G3 K2CO3 No CAS 584-08-7 21% 79% K-0096-01-001 CataCXium® A G3/K3PO4 CataCXium® A G3 K3PO4 No CAS 7778-53-2 15% 85% 5 EC Num Ingredient Percent SECTION 4: FIRST AID MEASURES Part Number: Eye Contact K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K0096-01-001 BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin Contact Wash off with soap and plenty of water. Consult a physician. Inhalation If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. Ingestion Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Part Number: Eye Contact K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K0094-01-001 BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin Contact Wash off with soap and plenty of water. Consult a physician. Inhalation If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. Ingestion Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Part Number: Eye Contact K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K0095-01-001 BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin Contact Wash off with soap and plenty of water. Consult a physician. Inhalation If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. Ingestion Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Chemical name: Chemical name: Chemical name: 6 SECTION 5: FIRE FIGHTING MEASURES Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K-009601-001 Chemical name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Flash Point Not determined Flash Point Method Not determined Auto Ignition Temperature Data not available. Lower Flammable/Explosive Limit Data not available. Extinguishing Media Upper Flammable/Explosive Limit Data not available. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Protective Equipment Wear self-contained breathing apparatus for firefighting if necessary. Hazardous Combustion Byproducts Oxides of phosphorus, Potassium oxides Part Number: K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K-009401-001 Chemical name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Flash Point Not determined Flash Point Method Not determined Auto Ignition Temperature Data not available. Lower Flammable/Explosive Limit Data not available. Extinguishing Media Upper Flammable/Explosive Limit Data not available. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Protective Equipment Wear self-contained breathing apparatus for firefighting if necessary. Hazardous Combustion Byproducts Cesium/cesium oxide Part Number: K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K-009501-001 Chemical name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Flash Point Not determined Flash Point Method Not determined Auto Ignition Temperature Data not available. Lower Flammable/Explosive Limit Data not available. Extinguishing Media Upper Flammable/Explosive Limit Data not available. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Protective Equipment Wear self-contained breathing apparatus for firefighting if necessary. Hazardous Combustion Byproducts Carbon oxides, Potassium oxides 7 SECTION 6: ACCIDENTAL RELEASE MEASURES Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K-009601-001 Chemical name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Personnel Precautions Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental Precautions Do not let product enter drains. Methods for containment Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Methods for cleanup Part Number: K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K-009401-001 Chemical name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Personnel Precautions Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental Precautions Do not let product enter drains Methods for containment Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Methods for cleanup Part Number: K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K-009501-001 Chemical name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Personnel Precautions Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental Precautions Do not let product enter drains. Methods for containment Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Methods for cleanup 8 SECTION 7: HANDLING AND STORAGE Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K-009601-001 Chemical Name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Handling Storage Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Further processing of solid materials may result in the formation of combustible dusts. Keep container tightly closed in a dry and well-ventilated place Special Handling Procedures hygroscopic Hygiene Practices Part Number: K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K-009401-001 Chemical Name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Handling Storage Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Further processing of solid materials may result in the formation of combustible dusts. Store under argon. Keep container tightly closed in a dry and well-ventilated place. Special Handling Procedures hygroscopic Keep in a dry place. Hygiene Practices Part Number: K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K-009501-001 Chemical Name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Handling Storage Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Keep container tightly closed in a dry and well-ventilated place. Special Handling Procedures Hygiene Practices 9 SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K-009601-001 Chemical name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Engineering Controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/Face Protection Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. Hand Protection Description Protective gloves Other Protective PPE Pictograms Part Number: K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K-009401-001 Chemical name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Engineering Controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/Face Protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin Protection Description Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Hand Protection Description Protective gloves Other Protective PPE Pictograms 10 Part Number: K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K-009501-001 Chemical name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Engineering Controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/Face Protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin Protection Description Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Hand Protection Description Protective gloves Other Protective PPE Pictograms 11 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Part Number: Chemical Name: Appearance Form Odour K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K0096-01-001 BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 solid No data available Odour Threshold No data available pH No data available Melting point/freezing point No data available Initial boiling point and boiling range No data available Flash point No data available Evaporation rate No data available Flammability (solid, gas) No data available Upper/lower flammability or explosive limits No data available Vapour pressure No data available Vapour density No data available Relative density No data available Solubility No data available Partition coefficient No data available Auto-ignition temperature No data available Decomposition temperature No data available Viscosity No data available Explosive properties No data available Oxidizing properties No data available 12 Part Number: Chemical Name: Appearance Form Odour K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K0094-01-001 BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 solid No data available Odour Threshold No data available pH No data available Melting point/freezing point No data available Initial boiling point and boiling range No data available Flash point No data available Evaporation rate No data available Flammability (solid, gas) No data available Upper/lower flammability or explosive limits No data available Vapour pressure No data available Vapour density No data available Relative density No data available Solubility No data available Partition coefficient No data available Auto-ignition temperature No data available Decomposition temperature No data available Viscosity No data available Explosive properties No data available Oxidizing properties No data available 13 Part Number: Chemical Name: Appearance Form Odour K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K0095-01-001 BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 solid No data available Odour Threshold No data available pH No data available Melting point/freezing point No data available Initial boiling point and boiling range No data available Flash point No data available Evaporation rate No data available Flammability (solid, gas) No data available Upper/lower flammability or explosive limits No data available Vapour pressure No data available Vapour density No data available Relative density No data available Solubility No data available Partition coefficient No data available Auto-ignition temperature No data available Decomposition temperature No data available Viscosity No data available Explosive properties No data available Oxidizing properties No data available 14 SECTION 10: STABILITY AND REACTIVITY Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K0096-01-001 Chemical name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Chemical Stability Stable under recommended storage conditions Hazardous Polymerization No data available Conditions to Avoid Exposure to moisture Incompatible Materials Strong oxidizing agents Special Decomposition Products No data available Part Number: K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K0094-01-001 Chemical name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Chemical Stability Stable under recommended storage conditions Hazardous Polymerization No data available Conditions to Avoid Exposure to moisture. Incompatible Materials Strong oxidizing agents, Strong acids Special Decomposition Products No data available Part Number: K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K0095-01-001 Chemical name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Chemical Stability Stable under recommended storage conditions Hazardous Polymerization No data available Conditions to Avoid Exposure to moisture. Incompatible Materials Strong oxidizing agents, Strong acids Special Decomposition Products No data available 15 SECTION 11: TOXICOLOGICAL INFORMATION Part Number: RTECS Number K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K0096-01-001 BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Not Found Eye Tox No data available Skin Tox No data available Inhalation Tox No data available Ingestion Tox No data available Part Number: RTECS Number K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K0094-01-001 BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Not Found Eye Tox No data available Skin Tox No data available Inhalation Tox No data available Ingestion Tox No data available Part Number: RTECS Number K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K0095-01-001 BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Not Found Eye Tox No data available Skin Tox No data available Inhalation Tox No data available Ingestion Tox No data available Chemical name Chemical name Chemical name 16 SECTION 12: ECOLOGICAL INFORMATION Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-009 Chemical name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K Ecotoxicity: No ecotoxicity data was found for the product Environmental Fate: No environmental information found for this product Effect of Material On Aquatic Life: No data available Biodegradation: No data available Part Number: K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-009 Chemical name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG Ecotoxicity: No ecotoxicity data was found for the product Environmental Fate: No environmental information found for this product Effect of Material On Aquatic Life: No data available Biodegradation: No data available Part Number: K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-009 Chemical name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K Ecotoxicity: No ecotoxicity data was found for the product Environmental Fate: No environmental information found for this product Effect of Material On Aquatic Life: No data available Biodegradation: No data available 17 SECTION 13: DISPOSAL INFORMATION Part Number: K-0041-01-001; K-0043-01-001; K-0025-01-001; K-0047-01-001; K-0050-01-001; K-0088-01-001; K-0092-01-001; K0096-01-001 Chemical name: BrettPhosG2/K3PO4; RuPhosG2/K3PO4; XphosPdG2/K3PO4; tBuBrettPhosG3/K3PO4; tBuXPhosG3/K3PO4; AmphosG3/K3PO4; AdBrettPhosG3/K3PO4; CataCXium® A G3/K3PO4 Waste Disposal: Part Number: Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combust K-0039-01-001; K-0044-01-001; K-0026-01-001; K-0045-01-001; K-0048-01-001; K-0086-01-001; K-0090-01-001; K0094-01-001 Chemical name: BrettPhosG2/Cs2CO3; RuPhosG2/Cs2CO3; XphosPdG2/Cs2CO3; tBuBrettPhosG3/Cs2CO3; tBuXPhosG3/Cs2CO3; AmphosG3/Cs2CO3; AdBrettPhosG3/Cs2CO3; CataCXium® A G3/Cs2CO3 Waste Disposal: Part Number: Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combust K-0040-01-001; K-0042-01-001; K-0051-01-001; K-0046-01-001; K-0049-01-001; K-0087-01-001; K-0091-01-001; K0095-01-001 Chemical name: BrettPhosG2/K2CO3; RuPhosG2/K2CO3; XphosPdG2/K2CO3; tBuBrettPhosG3/K2CO3; tBuXPhosG3/K2CO3; AmphosG3/K2CO3; AdBrettPhosG3/K2CO3; CataCXium® A G3/K2CO3 Waste Disposal: Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combust 18 SECTION 14: TRANSPORT INFORMATION Kit Part Number: HCK1004-01-006 Kit name: Pd Amination weak base kit, EvoluChem™ DOT Shipping Name: Not dangerous goods DOT UN Number: Not dangerous goods DOT Hazard Class: Not dangerous goods DOT Packing Group: Not dangerous goods 19 SECTION 15: REGULATORY INFORMATION Part Number: K-0039-01-001; K-0040-01-001; K-0041-01-001; K-0042-01-001; K-0043-01-001; K-0044-01-001; K-0051-01001;K-0025-01-001; K-0026-01-001; K-0045-01-001; K-0046-01-001; K-0047-01-001 Chemical name: BrettPhosG2/Cs2CO3; BrettPhosG2/K2CO3; BrettPhosG2/K3PO4; RuPhosG2/Cs2CO3; RuPhosG2/K2CO3; RuPhosG2/K3PO4; XphosPdG2/Cs2CO3; XphosPdG2/K2CO3; XphosPdG2/K3PO4; tBuBrettPhosG3/Cs2CO3; tBuBrettPhosG3/K2CO3; tBuBrettPhosG3/K3PO4 DSL Status: SARA 302 Components: SARA 313 Components: Not Listed SARA 311/312 Hazards: Acute Health Hazard Massachusetts: Not Listed Pennsylvania: Potassium carbonate, Caesium carbonate New Jersey: Potassium carbonate, Caesium carbonate California Prop 65: Not Listed TSCA: Not Listed Part Number: K-0048-01-001; K-0049-01-001; K-0050-01-001; K-0086-01-001; K-0087-01-001; K-0088-01-001; K-0090-01001; K-0091-01-001; K-0092-01-001; K-0094-01-001; K-0095-01-001; K-0096-01-001 Chemical name: tBuXPhosG3/Cs2CO3; tBuXPhosG3/K2CO3; tBuXPhosG3/K3PO4; AmphosG3/Cs2CO3; AmphosG3/K2CO3; AmphosG3/K3PO4; AdBrettPhosG3/Cs2CO3; AdBrettPhosG3/K2CO3; AdBrettPhosG3/K3PO4; CataCXium® A G3/Cs2CO3; CataCXium® A G3/K2CO3; CataCXium® A G3/K3PO4 DSL Status: SARA 302 Components: SARA 313 Components: Not Listed SARA 311/312 Hazards: Acute Health Hazard Massachusetts: Not Listed Pennsylvania: Potassium carbonate, Caesium carbonate New Jersey: Potassium carbonate, Caesium carbonate California Prop 65: Not Listed TSCA: Not Listed 20 SECTION 16: OTHER INFORMATION Kit Part Number HCK1004-01-006 Kit name Pd Amination weak base kit, EvoluChem™ Date creation November 1, 2015 SDS Revision Date January 26,2016 This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. 21
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