BLM 2-50 continued 17. (a) (b) 18. (a) FeCl3 (b) (NH4)3PO4 (c) N2S3 (d) tetraphosphorus decaoxide (e) sodium sulphate 19. (a) 3KI + AlCl3 → 3KCl + AlI3 (b) C3H8 + 5O2 → 3CO2 + 4H2O BLM 2-25, Acids and Bases + 1. (a) H ; less than; lower; blue; red; turns pink; conduct; sour – (b) OH ; greater than; higher; red; blue; remains colourless; conduct; bitter 2. Answers are in boldface. Chemical Formula of Aqueous Solution Name of Acid or Base H2S hydrosulphuric acid hydrogen carbonate H2CO3 carbonic acid hydrogen phosphate H3PO4 phosphoric acid magnesium hydroxide Mg(OH)2 magnesium hydroxide solution ammonium hydroxide NH4OH ammonium hydroxide solution hydrogen chlorate HClO3 chloric acid hydrogen acetate CH3COOH acetic acid or ethanoic acid hydrogen sulphite H2SO3 sulphurous acid Name of Substance hydrogen sulphide BLM 2-26, Working with Acids and Bases 1. The safety glasses, gloves, and lab apron serve the same purpose: to protect against accidental spills and contact with corrosive acids and bases. The eyewash station and safety showers are both used to dilute any acid or base that has contacted living tissues, to the point at which it is not concentrated enough to cause significant damage. 2. Baking soda can act as either an acid or a base. This property means that it can neutralize both acids and bases. Copyright © 2008, McGraw-Hill Ryerson Limited, a subsidiary of the McGraw-Hill Companies. All rights reserved. This page may be reproduced for classroom use by the purchaser of this book without the written permission of the publisher. (b) Applying Knowledge Substance pH Value Acid or Methyl Base Red Phenolphthalein Indigo Carmine tomato 4 acid red colourless blue oven cleaner 13 base yellow pink yellow egg 8 base yellow colourless blue Acids versus bases Page 87 definition 3. Substance pH Value Acid or pH Indicator Base Colour of pH Indicator black coffee 5 acid litmus red milk of magnesia 10 base phenolphthalein pink battery acid 0 acid bromothymol blue yellow sea water 8 base indigo carmine blue orange juice 3 acid methyl orange red liquid drain cleaner 14 base methyl red yellow ACIDS BASES compounds containing hydrogen that produce a solution with a pH of less than 7 when they dissolve in water and that produce a salt and water when they react with ionic compounds containing hydroxide ions chemical compounds containing hydroxide that produce a solution with a pH of more than 7 when they dissolve in water and produce a salt and water when they react with ionic compounds containing positive hydrogen ions <7 >7 what to look for in chemical formula H OH Comprehension production of ions H+ OH– Names of acids Page 86 electrical conductivity conductive conductive 1. ate taste taste sour taste bitter 2. ite touch burn skin feel slippery; burn skin 3. (a) carbonic acid (b) acetic acid pH examples HCl, H2SO4, lemons, NaOH, KOH, drain stomach acid cleaner, soap (c) phosphoric acid (d) chlorous acid 2. (a) acid (e) sulphurous acid (b) base (f) nitric acid (c) base (g) hydrofluoric acid (d) acid (h) hydrochloric acid (e) base 4. (a) HI (f) acid (b) H2SO4 (g) acid (c) HClO4 (h) base (d) HNO2 (i) acid (e) HClO3 (j) base (f) HBr (k) base (g) H3PO3 (l) acid (h) HClO Assessment Acids and bases Page 88 1. D 2. F 3. A 4. E 5. B 6. G 7. C 8. A 9. A 10. C 11. A 12. C 13. B 14. B 12 MHR • Workbook Answers © 2008 McGraw-Hill Ryerson Limited Section 5.2 Salts (b) acetic acid + barium hydroxide → water + barium acetate Comprehension 2 CH3COOH + Ba(OH)2 → 2 H2O + Ba(CH3COO)2 Recognizing acids, bases, and salts Page 91 1. (a) acid (b) acid (c) phosphoric acid + aluminum hydroxide → water + aluminum phosphate H3PO4 + Al(OH)3 → 3 H2O + AlPO4 (c) base (d) nitric acid + lithium hydroxide → water + lithium nitrate (d) acid HNO3 + LiOH → H2O + LiNO3 (e) base (f) acid (e) sulphuric acid + calcium hydroxide → water + calcium sulphate (g) acid H2SO4 + Ca(OH)2 → 2 H2O + CaSO4 (h) acid (i) salt (f) hydrochloric acid + magnesium hydroxide → water + magnesium chloride (j) base 2 HCl + Mg(OH)2 → 2 H2O + MgCl2 (k) base (l) salt (m) acid (n) salt (o) salt (p) salt (q) acid (r) acid (s) base (t) acid (u) acid (v) salt 2. acetic acid, CH3COOH 3. sodium chloride, NaCl 4. sulphuric acid, H2SO4 5. sodium hydroxide, NaOH 6. magnesium hydroxide, Mg(OH)2 7. hydrochloric acid, HCl Applying Knowledge Acid-base neutralization reactions Page 92 1. (a) H2SO4 + 2 NaOH → 2 H2O + Na2SO4 (b) HNO3 + KOH → H2O + KNO3 (c) 2 HCl + Ca(OH)2 → 2 H2O + CaCl2 (d) 2 H3PO4 + 3 Ba(OH)2 → 6 H2O + Ba3(PO4)2 (e) CH3COOH + NaOH → H2O + NaCH3COO (f) 2 HNO3 + Sr(OH)2 → 2 H2O + Sr(NO3)2 (g) 3 HF + Fe(OH)3 → 3 H2O + FeF3 Applying Knowledge Metal oxides and non-metal oxides Page 93 1. oxygen 2. metal oxide 3. non-metal oxide 4. it becomes basic 5. it becomes acidic 6. a base 7. an acid 8. (a) metal oxide (b) non-metal oxide (c) non-metal oxide (d) metal oxide (e) non-metal oxide (f) metal oxide (g) non-metal oxide (h) metal oxide 9. (a) a base (b) an acid (c) a base (d) an acid Assessment Salts Page 94 1. A 2. C 3. F 4. E 5. D 6. B 7. C 8. B 9. D 10. B 11. B 12. D 13. B (h) 4 HBr + Sn(OH)4 → 4 H2O + SnBr4 2. (a) sulphuric acid + potassium hydroxide → water + potassium sulphate H2SO4 + 2 KOH → 2 H2O + K2SO4 © 2008 McGraw-Hill Ryerson Limited Workbook Answers • MHR 13 BLM 2-50 continued 3. (a) Using a base to neutralize an acid spill to skin tissue is not a good idea because it is difficult to judge the correct amount to use. Too little base and the acid will still be corrosive. Too much base and the corrosive base will damage the tissue. Also, the heat generated by the reaction can further damage skin. (b) The student should immediately dilute the acid on the affected area by flushing with lots of cold water for several minutes. BLM 2-27, Salts and Metal and Non-Metal Oxides 1. (a) (b) (c) (d) (e) 2. (a) (b) (c) (d) (e) 3. (a) (b) (c) (d) HBr + NaOH → NaBr + H2O; sodium bromide H2SO4 + Mg(OH)2 → MgSO4 + H2O; magnesium sulphate 2H3PO4 + 3Sr(OH)2 → Sr3(PO4)2 + 6H2O; strontium phosphate 3HNO3 + Al(OH)3 → Al(NO3)3 + 3H2O; aluminum nitrate 2CH3COOH + Ca(OH)2 → Ca(CH3COO)2 + 2H2O; calcium acetate 2HF + Mg → MgF2 + H2; magnesium fluoride 6HClO3 + 2Al → 2Al(ClO3)3 + 3H2; aluminum chlorate 2H3PO3 + 6K → 2K3PO3 + 3H2; potassium phosphite 2HNO3 + Ca → Ca(NO3)2 + H2; calcium nitrate 2CH3COOH + Zn → Zn(CH3COO)2 + H2; zinc acetate basic acidic acidic basic BLM 2-28, Classifying Substances 1. Substance A is a base because it turns red litmus blue and conducts electricity. Substance B is an ionic compound because it conducts electricity when dissolved in water. Substance C is a covalent compound because it is a liquid at room temperature and does not conduct electricity or change the colour of litmus. Substance D is an acid because it turns blue litmus red when dissolved in water and also conducts electricity when dissolved in water. 2. Answers are in boldface. Chemical Formula Substance Letter (A, B, C, or D) CH3OH C hydrogen sulphide H2S D sodium hydroxide (aqueous solution) NaOH A ammonium sulphide (aqueous solution) (NH4)2S B Substance methanol BLM 2-29, Acids and Bases Review 1. 2. 3. 4. 5. A A D C 100 times Copyright © 2008, McGraw-Hill Ryerson Limited, a subsidiary of the McGraw-Hill Companies. All rights reserved. This page may be reproduced for classroom use by the purchaser of this book without the written permission of the publisher.
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