Influence of town on PDC temperature 1 Influences of urban fabric on pyroclastic density currents at Pompeii (Italy), part II: 2 temperature of the deposits and hazard implications 3 E. Zanella 4 Dipartimento di Scienze della Terra, Università di Torino, Via Valperga Caluso 35, 10125, Torino, Italy 5 ALP – Alpine Laboratory of Paleomagnetism, Peveragno, Italy 6 L. Gurioli 7 Istituto Nazionale di Geofisica e Vulcanologia, Via della Faggiola 32, 56126, Pisa, Italy 8 Present address: Geology & Geophysics, University of Hawaii, 1680 East-west Rd, Honolulu HI 96822, USA 9 M.T. Pareschi 10 Istituto Nazionale di Geofisica e Vulcanologia, Via della Faggiola 32, 56126, Pisa, Italy 11 R. Lanza 12 Dipartimento di Scienze della Terra, Università di Torino, Via Valperga Caluso 35, 10125, Torino, Italy 13 ALP – Alpine Laboratory of Paleomagnetism, Peveragno, Italy 14 15 During the AD 79 eruption of Vesuvius, Italy, the Roman town of Pompeii, was covered by 16 2.5 m fallout pumice and then partially destroyed by pyroclastic density currents (PDCs). Thermal 17 remanent magnetization (TRM) measurements performed on the lithic and roof tile fragments 18 embedded in the PDC deposits allow us to quantify the variations in the temperature (Tdep) of the 19 deposits within and around Pompeii. These results reveal that the presence of buildings strongly 20 influenced the deposition temperature of the erupted products. The first two currents which entered 21 Pompeii at a temperature around 300-360 ºC, show drastic decreases in the Tdep, with minima of 22 100-140 ºC found in the deposits within the town. We interpret these decreases in temperature as 23 being the result of localized interactions between the PDCs and the city structures, which were only 24 able to affect the lower part of the currents. Down flow of Pompeii, the lowermost portion of the 25 PDCs regained its original physical characteristics, emplacing hot deposits once more. The final, 26 dilute PDCs entered a town that was already partially destroyed by the previous currents. These 27 PDCs left thin ash deposits which mantled the previous ones. The lack of interaction with the urban 1 Influence of town on PDC temperature 28 fabric is indicated by their uniform temperature everywhere. However, the relatively high 29 temperature of the deposits, between 140 and 300 ºC, indicates that even these distal, thin ash 30 layers, capped by their accretionary lapilli bed, were associated with PDCs that were still hot 31 enough to cause problems for unsheltered people. 32 KEYWORDS: Pompeii, temperature, magnetic fabric, pyroclastic density currents. 33 34 1. Introduction 35 Pyroclastic density currents (PDCs) are the primary cause of death during explosive eruptions 36 [Tanguy et al., 1998]. These currents are hot mixtures of gas, pumice and lithic fragments, ranging 37 in size from fine ash up to metric blocks and bombs [e.g. Freundt and Bursik, 1998; Druitt, 1998]. 38 In the proximal locations their destructive effect is mainly due to their high momentum and 39 temperature [e.g. Baxter et al., 2005]. In distal locations, where the currents have already lost a 40 large portion of their solid load, their hazard is associated with their high concentration in fine ash 41 [e.g. Horwell and Baxter, 2006], coupled with their high velocity and temperature [e.g. Todesco et 42 al., 2002]. Thus, in order to assess the hazard posed by PDCs to human populations, it is extremely 43 important to understand PDC dynamics and their physical characteristics. In addition, educational 44 efforts, based on scientific analyses of PDC emplacement and their effects, will likely improve the 45 chances of survival of, or correct response to, future eruptions. 46 Observations made in villages and areas devastated by PDCs report evidence of sudden death 47 and survival among groups of people sheltering in the same house and even in the same room, as 48 during the eruption of Mt. Pelée, Martinique, in 1902 [Anderson and Flett, 1903,]. There is also 49 evidence for survival of certain individuals, when the majority of people in area impacted by PDC 50 were killed, as for example during the 1980 eruption of Mt St Helens (USA) [Bernstein et al., 1986] 51 or during the dome-collapse-fed pyroclastic flows of 1991 at Mount Unzen [Baxter et al., 1998]. In 52 addition, during the 1902 eruption of Mt. Pelée un-burnt material was found in close proximity to 53 incinerated objects [Lacroix, 1904]. The variable impact PDCs on human populations has been 2 Influence of town on PDC temperature 54 explained at Montserrat in terms of survivors being located in areas marginal to the PDCs [Baxter et 55 al., 2005]. However, this explanation cannot be applied for unconfined, diluted PDCs, as shown by 56 Gurioli et al. [2005]. Further investigations are thus required if we are to understand these local 57 variations in PDC dynamics, and how a PDC interacts with a town and its human population. 58 We attempt to resolve this issue through analysis of the PDC deposits of the AD 79 eruption 59 of Vesuvius (Italy) which crop out within and around the Roman town of Pompeii. All PDCs that 60 entered the town, even the most dilute ones, were density stratified currents whose lower part 61 interacted with the urban fabric [Gurioli et al., submitted]. We use a combination of thermal 62 remanent magnetization (TRM) and anisotropy of the magnetic susceptibility (AMS) analyses to 63 obtain information regarding flow direction of these parent currents and deposit temperatures. 64 These data, when integrated with volcanological field investigations, reveal that the presence of 65 buildings strongly affected the distribution and accumulation of the erupted products; where the 66 results of our analyses from the single, most destructive unit in the sequence have been presented in 67 Gurioli et al. [2005]. Here, we build on these previous findings by now considered the TRM results 68 from the entire eruptive sequence cropping out within and around Pompeii to infer the temperature 69 of all of the deposits. This allows us to assess the cooling effect of the urban fabric on these currents 70 and the effect of these currents on the inhabitants. 71 72 2. Volcanological setting and sampling 73 Pompeii is located 9 km southeast of Vesuvius (Figure 1) and the following 74 reconstruction of events during the AD 79 eruption at that location is based on the analysis of 75 Sigurdsson et al. [1985], Carey and Sigurdsson, [1997] and Cioni et al. [2000]. The town first 76 experienced 7 hours of air fall comprising white pumice, lapilli and bombs (up to 3 cm in 77 diameter), with scarce lithic blocks of up to 3 cm in diameter. This emplaced unit EU2 (Figure 78 2). The town then underwent 18 hours of grey pumice, lapilli and bombs (up to 10 cm in 79 diameter) fallout to emplace EU3 (Figure 2); a deposit that is rich in lithic blocks of up to 7 cm 3 Influence of town on PDC temperature 80 in diameter. During this Plinian phase, some PDCs were generated by the discontinuous collapse 81 of marginal portions of the convective column. Only the last of these events (EU3pf1, Figure 2) 82 was able to reach the north-western edge of Pompeii, but did not enter the town itself. This PDC 83 left only a 2-3 cm thick ash layer interbedded with the fallout deposit. The town was then 84 completely covered by a 5-30 cm thick ash layer (EU3pf, Figure 2) emplaced by very dilute 85 PDCs, derived from the total collapse of the Plinian column. Locally EU3pf was able to interact 86 with obstacles of a few decimetres in height, suggesting that its denser, thin lower part was 87 capable of only filling minor negative depressions [Gurioli et al., submitted]. 88 EU3pf was next mantled by a 3-6 cm thick, lithic rich (blocks up to 3 cm in diameter), 89 grey pumice, lapilli and bomb (up to 3 cm in diameter) fall deposit (EU4, Figure 2), emplaced 90 from a second, short-lived, lithic-rich column. The collapse of this second column generated the 91 most powerful, turbulent, PDC of the eruption. This was able to partially destroy the town and 92 left relatively coarse-grained, cross stratified, meter-thick deposits (EU4pf, Figure 2). EU4pf was 93 able to interact with obstacles of a few meters in height, showing significant interaction with the 94 town [Gurioli et al., 2005]. 95 Finally, the settlement was buried by a 1 m thickness of very dilute PDC and air-fall 96 deposits (EU7 and EU8, Figure 2) consisting of ash and accretionary lapilli emplaced during the 97 last, phreatomagmatic phase of the eruption. The EU7 sequence (Figure 2) comprises two 98 centimetre-thick grain supported, lithic-rich lapilli beds, separated by a 1-to-3-cm thick cohesive 99 ash layer, and capped by a coarse ash layer, which is in turn covered by a massive pisolite 100 bearing fine ash bed. EU8 then comprises an alternation of normally graded, ashy bedsets, each 101 up to 10 cm thick (Figure 2). Each bedset is characterised at its base by a massive-to-crudely 102 stratified facies followed by accretionary lapilli facies. In general, the EU7 and EU8 deposits 103 mantled a town that had already been severely damaged by the preceding currents (mainly 104 EU4pf) [Gurioli et al., submitted]. 4 Influence of town on PDC temperature 105 Within this sequence we sampled undisturbed sites in open country around the city, as 106 well as sites along the city walls and within the town, both along the roads and inside the rooms 107 (Figure 1). As described in Gurioli et al. [2005] we collected lithics and stripped roof tiles on 108 which we could perform TRM analyses. At least 5 lithic or tile fragments were collected from 109 each unit at each site giving a total of more than 200 samples. The tile fragments and the larger 110 lithic clasts (Figure 3) were first oriented using clinometer, magnetic compass and, whenever 111 possible, sun compass, before being removed from the outcrop. Usually two specimens were cut 112 from individual fragments to improve accuracy in the estimate of the deposition temperature 113 interval. The great majority of lithic clasts in the AD 79 deposits, and thus around 70% of our 114 samples, are fragments of a few mm in dimension (Figure 3). They were considered as un- 115 oriented samples, because their small size prevents accurate orientation. The presence of 116 fragments of plaster and roof tiles picked up and heated by the PDCs makes the Pompeii deposits 117 particularly suitable for such a study. As already discussed in Evans and Mareschal [1986], 118 Marton et al. [1993], Zanella et al. [2000] and Cioni et al. [2004], building fragments within the 119 deposits are reliable magnetic thermometers, because they were cold when they were picked up 120 by the PDC. 121 122 3. Measurement of deposition temperature using TRM 123 The thermal remanent magnetization (TRM) acquired during the cooling of a magmatic rock 124 records the polarity, direction and intensity of the Earth’s magnetic field at the time of cooling. 125 Such paleomagnetic information is widely used in geodynamics and stratigraphy. However, 126 thorough investigation of the TRM features may yield information on the physical processes 127 which led the remanence acquisition and help in understanding the emplacement mechanisms of 128 magmatic rocks. This applies to pyroclastic deposits, whose formation results from combination 129 of thermal and sedimentological processes. Paleotemperature investigation of pyroclastic rocks, 130 emplaced by PDCs, was pioneered by Aramaki and Akimoto [1957] and Chadwick [1971]. Their 5 Influence of town on PDC temperature 131 assumption was straightforward. If a deposit was emplaced hot (where hot means at higher 132 temperature than the Curie point of magnetite), then the primary remanence of the embedded 133 lithic fragments would have been erased. A secondary remanence was then re-acquired during 134 the subsequent cooling. All fragments were magnetized at the same time and their TRM 135 directions are therefore well clustered. In contrast, if the emplacement temperature was cold each 136 fragment would have retained its own primary TRM acquired when the parent rocks formed. In 137 this case, the TRM directions are randomly distributed because of the chaotic movements during 138 emplacement. 139 Following Chadwick [1971], Hoblitt and Kellog [1979] applied a more quantitative 140 procedure, based on thermal demagnetization of the fragments. This technique allows derivation 141 of the TRM blocking temperature (Tb) spectrum and thus identification of the distinct TRM 142 components acquired in different temperature ranges, usually referred to as high-Tb and low-Tb 143 components. Such an analysis yields an estimate of the actual temperature reached by the 144 fragment upon re-heating within the pyroclastic material, this being the maximum unblocking 145 temperature (Tbmax) of the low-Tb component. 146 Further work has improved this methodology [e.g. McClelland and Druitt, 1989; Bardot, 147 2000] and have revealed some complications to the initial assumptions. According to the 148 simplest model, paleomagnetic estimates of the deposition temperature relies on two basic 149 assumptions: 150 1) During PDC transport and deposition heat is transferred from the hot gas and fine-grained 151 material to the cold clasts. For clasts larger than 2-5 cm, thermal equilibrium is mainly reached 152 during residence in the deposit rather than the emplacing current. In fact, the time required to 153 reach thermal equilibrium within the current is longer than the time of residence in the flow 154 [Cioni et al., 2004]. For this reason, rock magnetic investigations give an estimate of the deposit 155 (Tdep) rather than the emplacement (Temp) temperature. 156 2) The clasts’ remanence is a pure thermal remanent magnetization (TRM). 6 Influence of town on PDC temperature 157 In cases where these assumptions are fulfilled, the natural remanent magnetization (NRM) of a 158 clast consists of two TRM components characterized by different blocking temperatures (Tb). 159 The high-Tb component pre-dates the PDC emplacement. This was acquired when the lithic clast 160 was originally formed. A part of this remanence is erased when the clast is re-heated within the 161 PDC and then acquired as low-Tb component when the PDC comes to rest and cools down. 162 Considering the full Tb spectrum of the clast, Tbmax is the temperature value which separates the 163 two components. It can be identified by stepwise thermal demagnetization because the directions 164 of the two components are different (Figure 4). The low-Tb direction is close to that of the 165 geomagnetic field at the time of the PDC emplacement, and it is the same in all clasts. The high- 166 Tb direction is fully random. According to the first assumption above, Tdep may thus be derived 167 from the mean Tbmax value derived from a number of clasts. 168 Estimation of Tdep, however, is not always as straightforward as in the above case 169 [Grubensky et al., 1998]. The first problem is that we do not know the thermal history of the 170 clast. It might have been either picked up cold along the slopes of the volcano, or ejected hot 171 from the conduct, possibly being even hotter than the PDC within which it became entrained. In 172 the second case, when the current stops the lithic fragment is still hotter than the surrounding 173 fine-grained matrix and the Tbmax value found from rock-magnetism will be higher than Tdep. 174 The second problem concerns NRM which, in addition to the thermal (TRM) components, 175 may also comprise chemical (CRM) and viscous (VRM) components. It has been shown by 176 McClelland [1996] that a chemical remanence (CRM) may develop due to mineralogical 177 changes during reheating. This will hinder the identification of the low-Tb and high-Tb 178 components (Figure 4b). VRM is typical of ferromagnetic grains with low relaxation time, and 179 thus low blocking temperature. According to theory [Pullaiah et al., 1975, Bardot and 180 McClelland, 2000] a VRM component acquired at 20 °C in the course of the ~1930 years 181 elapsed since the AD 79 eruption, is erased by heating at 125 °C in a time of 25 to 30 minutes, 182 typical of a thermal demagnetization step in the laboratory. It may thus be indistinguishable from 7 Influence of town on PDC temperature 183 very low Tb secondary components. Moreover, a small VRM overprint often occurs in most 184 rocks. The presence of a VRM overprint could partially affect identification of the true, low-Tb 185 TRM component and hamper the determination of its direction by principal component analysis 186 [Kirschvink, 1980]. 187 The problems outlined above do not always occur and when they do they can often be 188 overcome. In the case of the Vesuvius AD 79 eruption, archaeological remains are of great help. 189 Bricks and tiles, which have their own TRM typical of baked-clay artefacts, were picked up by 190 PDCs at the ambient temperature and could not be heated at values higher than Tdep. The 191 problems with CRM are also reduced sampling clasts of as different lithologies as possible, 192 because different lithology means different magnetic properties. 193 In conclusion, the various clasts collected at an individual site may have had different 194 thermal histories and have recorded more or less faithfully the Tdep. Following the approach of 195 Cioni et al. [2004], the thermal overprint of a group of clasts by a PDC is better represented by 196 what they have in common. The Tbmax values derived from each individual clast may differ from 197 each other because of the reasons summarized above, whereas the re-heating was a single event. 198 The traces it left, Tdep, must be consistent at the site scale. 199 200 4. Standard measurements and peculiar cases 201 A total of 379 specimens were measured at the ALP laboratory (Peveragno, Italy) using a 202 JR-5 spinner magnetometer, and Schonstedt and ASC TD-48 thermal demagnetizers. Small bits 203 were measured using the plastic box + Plasticine technique of Cioni et al. [2004]. Thermal 204 demagnetization was carried out in steps of 40 °C between a starting temperature of 100 °C and 205 a maximum of ~520 °C. Whenever sister specimens from individual clasts were available, a 206 second demagnetization was carried out using the same 40 °C steps but starting at 80 °C. The 207 data were then interpreted using the principal component analysis available as part of the 208 Paleomac program [Cogné, 2003]. 8 Influence of town on PDC temperature 209 On the basis of the demagnetization patterns, Cioni et al. [2004] distinguished four kinds of 210 thermal behaviour in clasts embedded within the AD 79 PDC deposits. Type A is characterized 211 by blocking temperatures higher than Tdep and its primary TRM is therefore not affected by the 212 re-heating. Type B has blocking temperatures lower than Tdep and its primary TRM is completely 213 erased during the re-heating. Type C is the archetype of lithic clasts with a TRM comprising two 214 components with distinct Tb spectra, which are well evident in the Zijderveld diagrams (Figure 215 4a). In Type D the two components are not very clear because the spectra more or less overlap, 216 show a zigzag pattern, or have points that are too close to each other to be well distinguished 217 (Figure 4b). Identification of Tbmax is thus straightforward in Type C, more complicated in Type 218 D. A similar classification was adopted by McClelland et al. [2004] whose Types 1a, 1b, 2 and 3 219 respectively correspond to the Types C, D, A, B types of Cioni et al. [2004]. In the present 220 paper, we add Type E, which comprises a few tile fragments which show no evidence of re- 221 heating. The normalized intensity decay curve (Figure 4c) shows that a fraction of their 222 ferromagnetic grains have low blocking temperatures. The clasts NRM directions, however, do 223 not change throughout demagnetization up to the highest values close to the Curie point and are 224 different from that of the ambient field in AD 79. In the example, the direction of the 225 characteristic remanent magnetization (ChRM), calculated using all steps and with maximum 226 angular deviation MAD = 1° (Figure 4c), is D = 356.5°, I = 2.3°, where D is declination and I 227 inclination. We have no explanation for the occurrence of these clasts and can only consider 228 them as outliers, but which bear witness to the fact that the temperature distribution within thin 229 pyroclastic deposits is far from uniform and can in fact be highly variable. 230 The pie diagram in Figure 5 summarizes the per cent occurrence of the five types in all 231 clasts investigated in the present paper. Type C accounts for about 50 % of the clasts, Type D for 232 about 45%, with the remainder are either being Type A or E. No Type B clasts were found in the 233 present investigation. 9 Influence of town on PDC temperature 234 An uncommon case is given by the plaster fragment sampled at site 18 (Figure 1). Hueda- 235 Tanabe et al. [2004] have shown that plaster may be used as archaeomagnetic material. Small 236 ferromagnetic grains are free to move when plaster is applied to a wall or floor, orienting their 237 magnetic moment parallel to the Earth’s magnetic field and then being blocked when the plaster 238 dries. The vector sum of the NRM of a plaster specimen is thus given by the NRM of its 239 individual grains. The process is similar to the orientation of the grains of ferromagnetic 240 pigments in red coloured murals, which also have been shown to record the ambient field 241 direction at the time of painting [Zanella et al., 2000]. The plaster sampled at Pompeii is a kind 242 of pozzolana, one of the most outstanding results of Roman civil engineering. It was made from 243 lime and grains of volcanic rocks from the sandy deposits of neighbouring rivers. A large 244 fraction of grains are 1-2 mm in size (Figure 6a), too large to be effectively oriented by the 245 Earth’s field. Thus, it can reasonably be assumed that the remanence direction varies from grain 246 to grain. At a first glance the thermal demagnetization diagram looks quite odd (Figure 6b). 247 Because each grain has its own Tb spectrum, thermal demagnetization erases different fractions 248 of remanence in grains with different TRM directions, so that the direction of the resultant vector 249 varies randomly from one step to another, without any coherence. However, the low-temperature 250 demagnetization steps show a linear trend in the initial part of the Zijderveld diagrams (up to 251 180-200 °C in Figure 6b). This suggests that, in each individual grain, the fraction of remanence 252 with Tb < Tdep was erased when the plaster was re-heated to the Tdep of the pyroclastic material 253 filling the room and burying the walls. During cooling, all grains re-acquired a low-Tb 254 component showing the same direction, i.e. that of the Earth’s field, which is therefore coherent 255 throughout the specimen. 256 Another peculiar case is that of the lithics embedded in the fall deposits. The 16 lithics we 257 sampled were characterized by three TRM components: these being the expected high- and low- 258 Tb components, as well as an intermediate-Tb component with a distinct direction around 10 Influence of town on PDC temperature 259 temperatures of 340 to 480 °C (Figure 7). No evidence for an intermediate-Tb component was 260 found in the tile fragments embedded in these deposits. 261 As discussed in the previous section, most of our samples were fragments too small to be 262 oriented in the outcrop. Out of a total of 379 specimens, 145 were oriented and 75 gave two 263 clearly isolated components whose directions could be transformed to the geographical reference 264 system. The directions of the high-Tb component were widely scattered, as expected (Figure 8); 265 those of the low-Tb were more clustered. The site mean ChRM direction (D = 350.4°, I = 61.8°, 266 Fisher’s semi-angle of confidence α95 = 7.4°) is close to the AD 79 Earth’s magnetic field 267 direction as given by archaeomagnetism [Tema et al., in press], even if its statistical definition is 268 lower than usual in paleomagnetic investigations. This is often the case in paleotemperature 269 investigations [McClelland et al., 2004; Tanaka et al., 2004]. In our case, this is mainly due to 270 the fact that the analysis of the low-Tb component relies on few clustered points due to the low 271 rate of decrease in the intensity of magnetization. Furthermore it may also be biased by a VRM. 272 Even if the low-Tb directions of individual clasts show some dispersion, their overall mean (D = 273 352.0°, I = 53.7°, number of specimens N = 75, length of the resultant vector R = 69; α95 = 4.9°) 274 passes the Watson [1956] randomness test and is consistent with the archaeomagnetic direction 275 (D = 354.3°; I = 58.0°; α95 = 1.7°) derived from various materials studied at Pompeii 276 (archaeological remains, fine-grained pyroclastics, lithic clasts) [Evans and Hoye, 2005; Tema et 277 al., in press and references therein]. 278 Final estimation of paleotemperature was completed following the technique of Cioni et al. 279 [2004]. For each site and each eruptive unit, first the temperature interval which contains the 280 maximum unblocking temperature (Tbmax) of the low-Tb component of each individual clast was 281 derived from the demagnetization path. This was done by analysis of the normalized intensity 282 decay curve, the Zijderveld diagrams and the equal-area plot of directions. As a conservative 283 approach, directions separated by less than 15° were not considered as significantly different 284 [Porreca, 2004], because a small angular deviation might be due to post-depositional settling of 11 Influence of town on PDC temperature 285 the fragment within the still unconsolidated rock. Tdep of each site and eruptive unit was then 286 estimated from the overlap range of the temperature intervals of the individual fragments 287 (Figures 9a, 9b, 9c1, 9c2, 9c3 and 9d). 288 289 5. The temperature of the AD 79 deposits around and within Pompeii 290 In the following discussion we present our data for the whole eruptive sequence present 291 in Pompeii, unit by unit (Figures 9a, 9b, 9c1, 9c2, 9c3 and 9d). Where ever possible, we compare 292 these results with the data obtained for the same units cropping out around Vesuvius by Cioni et 293 al. [2004]. 294 5.1 The fallout sequence (EU2-EU3 and EU4) 295 We collected just a few samples from the three main fallout deposits (EU2-EU3 and 296 EU4), mostly to check whether they were emplaced hot and whether they were able to maintain a 297 temperature high enough to heat artefacts. As already shown by several authors [e.g. Thomas and 298 Sparks, 1992; Tait et al., 1998; Hort and Gardner, 2000] pumice clasts larger than 6 cm in 299 diameter suffer little heat loss during their fall and can be emplaced at temperatures within 10-20 300 % of their magmatic temperature [Thomas and Sparks, 1992]. Thus Plinian deposits, depending 301 on their grain size, thickness and distance from the vent, can remain sufficiently hot to pose 302 hazards to life and property [Thomas and Sparks, 1992]. For the fallout deposits in Pompeii, we 303 found that the white fallout deposit had a temperature high enough to warm the tiles up to 120- 304 140 °C (Figure 9a). Unfortunately, we could not collect any artefacts in the grey fallout, EU3, 305 but we can assume that this deposit was even hotter than the white one, because of its coarser 306 grained texture. 307 Within both the EU3 and EU4 fall deposits we also sampled lithic blocks. As previously 308 discussed, all these lithics are characterized by three components (Figure 7). We assume that, 309 while the high-Tb component was acquired during clast formation, the low-Tb component 310 represents the temperature of the lithic at the point at which it fell to the ground. If this 12 Influence of town on PDC temperature 311 hypothesis is correct the lithic fragments reached Pompeii at a minimum temperature of 180-220 312 °C during the EU3 fallout and 220-260 °C during the EU4 fallout (Figure 9a). We do not fully 313 understand the meaning of the intermediate temperature component. It may represent heating 314 during passage as part of the gas-thrust section of the plume and/or cooling experienced in the 315 umbrella portion of the plume. 316 5.2 The first PDC entering Pompeii (EU3pf) 317 EU3pf deposits were sampled around and within Pompeii (Figure 10a). They show a 318 large variation in their Tdep, ranging from 140 to 300 °C (Figures 9b and 10a). Nowhere else 319 around Vesuvius do we find such high variability in EU3pf deposit temperatures [Cioni et al., 320 2004] (Figure 10b). Even the coldest outcrops located north of Vesuvius are relatively warm in 321 comparison to those within Pompeii (Figure 10). 322 EU3pf in Pompeii shows the highest Tdep (240-300 °C) in the northern sector (Figures 9b 323 and 10a), outside the town. However, these values are lower than the 300 to 360 °C values 324 obtained for the EU3pf deposits emplaced upstream of Pompeii, in the proximal sector (Figure 325 10b). We explain these results as the consequence of uniform cooling experienced by the current 326 at this distance from the vent, due to the reduction of its total load which will decrease its 327 thermal energy. 328 Lowest temperatures were recorded within the town and in the western sector, where Tdep 329 drops to 140-220 °C. Slightly higher values have been found in rural areas south of Pompeii, 330 where the Tdep is 220-260 °C [Cioni et al., 2004] (Figure 9b and 10a). These temperatures show 331 that the EU3pf current, even if diluted and capable of only emplacing thin deposits, entered 332 Pompeii with a minimum temperature of 260-300 °C. The decrease in temperature within 333 Pompeii, indicates that the local interaction with the city structures had a cooling effect on the 334 lower part of the current. South of Pompeii, the EU3pf current was unable to restore the same 335 temperature it had before entering Pompeii, but it was still able to emplace hotter deposits than 336 found within Pompeii with temperatures of up to 220-260 °C. 13 Influence of town on PDC temperature 337 5.3 The most powerful PDC (EU4pf) 338 Temperature data obtained from the thick deposits of EU4pf display the largest 339 variability in temperature at the scale of individual sampling sites, ranging from 100 to 320 °C 340 (Figures 9c1, 9c2, 9c3 and 11a). These values differ from those obtained from the same deposits 341 in non-urban areas around the volcano, (Figure 11b). In such non-urban locations, all sites yield 342 temperatures of around 300°C (260-340 °C), irrespective of their distance from the vent [Cioni et 343 al., 2004]. This relatively uniform temperature suggests a substantial homogeneity of the 344 transport system of the EU4pf deposits in the Vesuvius area [Cioni et al., 2004]. 345 In contrast, a large decrease in temperature occurs within Pompeii. In sites examined 346 orientated along the axis of the flow direction (from the northwest edge of the city towards its 347 southern edge), temperatures generally decline. As found for EU3pf, EU4pf also has highest Tdep 348 values in the northern sector of Pompeii, where the Tdep range from 240 to 320 °C, with an 349 average value of around 280 °C. A low value of 200-240 °C was found up flow the Villa dei 350 Misteri, at site 2a (Figure 11a). We speculate that this anomalous value may be due to the 351 presence of some structure up flow of this area, or some morphological high, not now visible 352 because is covered by the deposits and the modern soil and vegetation. 353 Inside the town Tdep ranges from 100 to 220 °C, with an average value of 160 °C. Here 354 the lowest values are found in three rooms with collapsed roofs, aligned parallel with the main 355 flow direction. The lowest value that we found is located in the third of these three rooms, i.e. 356 the furthest down flow [Gurioli et al., 2005]. These low values are consistent with cooling due to 357 strong disturbances caused by the town and morphological features, such as the 3-meter-deep 358 cavities presented by rooms with collapsed roofs (Figure 11a, sites 10, 12a and 12b), the 10-m- 359 high cliff on the southern edge of the town (Figure 11a, sites 22c and 25), or collapsed walls 360 (Figure 11a, sites 11 and 16). Down flow of the city walls, where there are no morphological or 361 urban disturbances, the deposit temperatures are high once more (Figure 11a, sites 22a, 22b, 19a 362 and 19b). 14 Influence of town on PDC temperature 363 These results show that the presence of the settlement resulted in substantial cooling of 364 the current over short distances. Roughness of the topographic/depositional surface increases the 365 ability of the basal portion of the flow to decouple from the main flow and to form local 366 vortexes, ingesting ambient air. Increases in turbulence, due to the surface irregularities caused 367 by the presence of the town, are evident from upstream particle orientations which develop 368 down-flow of obstacles or inside cavities [Gurioli et al., 2005] and from characteristic 369 sedimentary structures such as fines-poor, undulatory, lenticular bedded facies on the lee side of 370 the obstacles [Gurioli et al., submitted]. This would also cause air ingestion. Air ingestion into 371 the lower system of the EU4pf current during passage over the urban canopy is the most 372 reasonable cause of the observed strong temperature decreases. As shown in Cioni et al. [2004], 373 the very high thermal diffusivity of air with respect to magma, and the intimate mixing between 374 the air and gas-ash mixture, results in instantaneous thermal equilibrium during this process. 375 Furthermore, the EU4pf current lasted for 8-10 minutes [Gurioli, 1999]; because we witness 376 cooling this interval of time must be sufficient for the lower part of the current to entrain air and 377 undergo cooling. 378 The amount of building material entrained by the current seems not to play an important 379 role in cooling of the deposits, where we found no correlation between low temperatures and 380 amount of building material. Furthermore, tile-fragment-rich zones within EU4pf deposits are 381 present as small lenses (around 1-2 m long, 1 m high and less than 1 m wide) which probably did 382 not have sufficient volume or extent to cool the deposits. 383 The roof tiles have very high thermal conductivity, as a result they will heat up very 384 quickly. We estimate the characteristic time it takes to heat a cool object (roof tile) buried in a 385 hot medium (the deposit) from τ = D2/α, in which D is the object dimension and α is the thermal 386 diffusivity of the object. Thermal diffusivity is calculated using the density and specific heat 387 capacity for common brick [obtained from Holman, 1992], as well as the temperature dependent 388 thermal conductivity which we calculate for clay following Vosteen and Schellschmidt [2003]. 15 Influence of town on PDC temperature 389 This gives τ of ~1 minute for our smallest (1 cm) objects, increasing to ~1.5 hours for our largest 390 (10 cm) objects for heating from ambient to 200-400 °C. This means that all of our objects 391 should have equilibrated with the temperature of the deposit within 1.5 hours, with the smallest 392 objects reaching equilibrium in just a few minutes. Thus, although individual tile fragments 393 entrained within the deposit were heated quickly, they robbed insufficient thermal energy from 394 the surrounding hot body to cause significant cooling. 395 As shown in Gurioli et al [submitted], the urban canopy encouraged deposition and the 396 upper portion of the current was not able to fully restore the sediment supply to the lower 397 current. Our temperature results also show that the increase in surface roughness caused by the 398 presence of the town caused strong variations in temperature. However, these variations where 399 short-lived and confined to the lower part of the current. South and south east of Pompeii, at 400 distances of up to 8 km from the town, EU4pf was able to emplace hot deposits once more 401 [Cioni et al., 2004] (Figure 11b). 402 5.4 The final PDCs (EU7 and EU8) 403 Temperature data obtained from the thin deposits of EU7 and EU8 display the lowest 404 variability in temperature at the scale of individual sampling sites. In EU7 we sampled the ash 405 interlaid between the two lapilli beds (Figure 2d). This gives a temperature of between 210 and 406 260 °C, in agreement with the temperature range (180-240 °C) found by Cioni et al. [2004] 407 between the vent area and Pompeii for this deposit. The second ash layer shows a highest 408 temperature of 260-300 °C at Site 1 (Figure 12) but around and within Pompeii Tdep ranges from 409 180-260 °C, without showing strong variations within the city. This behaviour agrees with a 410 scenario within which there was interaction between this current and a town that was already 411 partially covered by the previous deposits [Gurioli et al., submitted]. 412 EU8 was sampled at just one site because we had difficulties in finding lithic fragments 413 large enough to be suitable for measurement. It displays a Tdep of 180-220 °C. A fragment of tile 414 was also collected at site 16 (Figures 9d and 12) within the coarse grained ash layer of this 16 Influence of town on PDC temperature 415 deposit. Even if the top of the deposit shows evidence of water condensation, the deposit at the 416 base had a temperature able to heat the tile up to 130-180 °C. 417 418 6. Implications for volcanic hazard 419 In the early afternoon of August 24 AD 79 a pumice fall began which lasted until early in 420 the morning of the following day. During this period Pompeii was covered by 3 meters of pumice. 421 Within 6 hours the roofs and parts of the walls of the buildings had collapsed under the pumice load 422 [Sigurdsson et al.,1985; Luongo et al., 2003a]. Luongo et al. [2003a, b] identify a significant 423 number of victims within this deposit (38 % of the total number of victims, estimated to be about 424 1150). They probably died as a consequence of building collapse. Our new data reinforce this 425 reconstruction, where we find that these deposits were emplaced with sufficient heat to be able to 426 heat cold materials to 140 °C. We can therefore speculate that in some sites they could have been 427 capable of causing damage by carbonisation of wood, such as roof beams, and skin burn upon direct 428 contact. This hazard scenario was made even more dangerous by the scattered rain of large, very 429 hot, lithic blocks. 430 In the early morning of August 25, the PDCs started to enter and devastate Pompeii 431 [Cioni et al., 2000]. In Pompeii, features of both EU3pf and EU4pf show that the two currents 432 were able to interact with the urban structures even in the first, very dilute case, suggesting that 433 the currents were stratified, and capable of interacting with objects of the same height as the 434 thickness of their depositional systems [Gurioli et al., submitted]. EU3pf interacted little with the 435 fabric of the town, due to its very thin depositional system. However, its content of fine ash and 436 relatively high temperatures would have made it hazardous to the human population, causing 437 asphyxia and lung damage. Recent studies [Luongo et al., 2003a, b] suggest that the first diluted 438 PDC (EU3pf) caused minimal damage in Pompeii. This is true for the building structures, but 439 our evidence indicates that even this current was extremely dangerous for the inhabitants [Cioni 440 et al., 2000]. Here we have been able to quantify this hazard, where the hazard results from the 17 Influence of town on PDC temperature 441 temperature of this current and its composition of fine ash. Although the current left only a thin 442 deposit, the current itself had a thickness of more than 10 m (the height of the ridge on which 443 Pompeii was built). Furthermore, the current was hot, with a temperature of 140-300 °C. This 444 temperature would have been very close to the average temperature within the current at 445 Pompeii, an assumption made plausible by the abundance of fine-grained fragments that 446 comprised the PDC at this distance from the vent [Cioni et al., 2004]. Finally, the grain-size of 447 the EU3pf deposits indicates that 40-50 % of its mass was accounted for by particles of less than 448 0.1 mm in diameter [Gurioli et al., submitted]. Such a size represents dust that can be inhaled by 449 humans. Assuming a minimum fractional particle volume concentration of about 1-5 x10-4 for 450 this current and a minimum bulk density of 1000 kg/m3 for the particles [Freundt and Bursik; 451 1998], the concentration of fine materials is between 0.03 and 0.15 kg/m3. These values fall 452 within the concentration range for inhalable dust capable of causing asphyxia [0.1 kg/m3, Baxter 453 et al., 1998] at ordinary temperatures. A temperature of 200 °C and ash concentration of 0.1 454 kg/m3 are considered threshold values above which human survival is likely to be impossible 455 [Baxter et al., 1998]. Furthermore this atmosphere would have persisted for several minutes, as 456 suggested by the low terminal velocity of the fine particles and the aggradational model 457 proposed for this current [Gurioli, 2000; Gurioli et al., submitted]. Thus, this PDC was 458 extremely hazardous and, following Baxter et al. [1998], would have led to asphyxia and severe 459 lung damage. 460 Invasion of Pompeii by EU4pf was almost instantaneous. If we assume flow velocities of 461 50-60 m/s [Esposti Ongaro et al., 2002], in agreement with the average mean grain size of the 462 deposits [Gurioli et al., submitted], the EU4pf front took less than 10 s to cross the town. This 463 second, more concentrated current had a more profound influence on the town. Its dense 464 depositional system, coupled with its high velocity, was able to tear down some walls orientated 465 at right angles to the main flow direction (i.e. east-west trending structures). This is in agreement 466 with masonry vulnerability of the old Pompeii buildings that fall in the range of 1-5 kPa 18 Influence of town on PDC temperature 467 [Nunziante et al., 2003] and simulated dynamic pressures of 1 kPa calculated for a PDC with a 468 mass effusion rate of 5 x 107 kg/s and at a distance of 7.5 km from the vent [Esposti Ongaro et 469 al., 2002]. The case of EU4pf is more clear-cut, in that it would have been completely lethal for 470 any inhabitants surviving the previous PDC, a consequence of its high velocity, density, mass 471 and temperature. 472 The final, dilute PDCs entered a town that was already partially destroyed by the previous 473 currents. At this stage of the eruption, all the remaining population were dead [Sigurdsson et al., 474 1985; Cioni et al., 2000; Luongo et al., 2003a]. These currents just mantled the ruins left by 475 EU4pf without inflicting further damage upon the buildings. 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Lanza, 605 Archaeomagnetic results from mural paintings and pyroclastic rocks in Pompeii and 606 Herculaneum, Phys. Earth. Planet. Inter., 118, 227-240, 2000. 607 608 Figure captions 609 Figure 1. Ancient Roman town of Pompeii. Dots = sites of studied sections; light areas = portions 610 of ruins still buried by undisturbed AD 79 deposits. Inset upper right, shaded relief map of the of 611 Vesuvius region. 612 613 Figure 2. AD 79 deposits at Pompeii. On the left, the schematic stratigraphy according to the 614 nomenclature of Cioni et al. [1992, 2004]. The numbers in the brackets are the variation 615 thickness of the studied deposits. From a) to d) particulars of the deposits within and around 616 Pompeii (see figure 1 for site location). (1) White pumice lapilli and bombs. (2) Grey pumice 617 lapilli and bombs. (3) Massive to stratified coarse-grained ash and grey pumice lapilli. (4) 618 Accretionary lapilli in in coarse and fine ash matrix. 619 24 Influence of town on PDC temperature 620 Figure 3. Hand sampling of lithic fragments and roman tiles from the PDC deposit matrix. The 621 orientation of the main face of the tile is traced. Inset: standard paleomagnetic specimens and 622 little bits embedded in the plasticine. 623 624 Figure 4. Stepwise thermal demagnetization of lithic clasts from the AD 79 deposits: a) type C 625 clast; b) type D clast; c) type E clast (see text for further explanation). 626 Left: Zijderveld diagrams . Symbols: full dot = declination; open dot = apparent inclination. 627 Right: equal-area projections of the directions of magnetization. Symbols: full/open dot = 628 positive/negative inclination. Directions in the Zijderveld diagrams are represented in the sample 629 reference system; in the equi-areal projections the geographic reference system is used. 630 631 Figure 5. Pie diagram of the percentage occurrence of different types of fragments (see text for 632 further explanation). 633 634 Figure 6. Stepwise thermal demagnetization of a plaster specimen from the AD 79 deposits. 635 a) plaster bit (front and transverse section). 636 b) normalised intensity deacy curve and Zijderveld diagram of specimen T19a. Symbols as in 637 Fig. 4 638 639 Figure 7. Zijderveld diagrams of specimens of ballistic blocks from the fall-out deposit. For 640 symbols see figure 4. 641 642 Figure 8. Equal-area projection of high-Tb (HT) and low-Tb (LT) component directions of the 643 oriented specimens from EU4 pf at site 12a. Symbols: full/open dot = positive/negative 644 inclination; star = site mean direction with α95 confidence ellipse. 645 25 Influence of town on PDC temperature 646 Figure 9. Evaluation of the AD 79 deposits temperature (Tdep), by overlap of individual fragments 647 reheating temperature range (see text for further explanation). Types are shown left of the bar. 648 Color: black = lithic fragment (mainly lavas); grey = tile; black dot = plaster. 649 a) EU2, EU3 and EU4 fall deposits. 650 b) EU3pf deposits 651 c) EU4pf deposits 652 d) EU7pf I ash, EU7pf II ash and EU8 deposits. 653 654 Figure 10. Tdep variation of EU3pf: 655 a) within and around Pompeii. 656 b) around the Vesuvius area [modified from Cioni et al.,2004]. 657 658 Figure 11. Tdep variation of EU4pf: 659 a) within and around Pompeii. 660 b) around the Vesuvius area [modified from Cioni et al.,2004]. 661 662 Figure 12. Tdep variation of EU7pf I ash, EU7 II ash and EU8, within and around Pompeii. 663 664 Figure 13. Destructive effects of the AD 79 deposits in Pompeii: a) collapsed roof tiles in the 665 fall-out deposit (photo courtesy Soprintendenza di Pompeii); b) skeletons in the ash deposits 666 inside a room (photo courtesy Soprintendenza di Pompeii); c) collapsed wall by EU4pf; d) 667 bodies rolled in EU4pf deposits. In c) and d) the arrow indicates the main flow direction. 26
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