ELSEVIER Earth and Planetary Science Letters 173 (1999) 271–284 www.elsevier.com/locate/epsl Geochemistry of lavas from the Garrett Transform Fault: insights into mantle heterogeneity beneath the eastern Pacific J. Immo Wendt a , Marcel Regelous a,Ł , Yaoling Niu a , Roger Hékinian b , Kenneth D. Collerson a a Department of Earth Science, The University of Queensland, Brisbane 4072, Australia b IFREMER, Centre de Brest, 29287 Plouzané, France Received 23 December 1998; accepted 22 September 1999 Abstract Young intra-transform lavas erupted as a result of extension within the Garrett Transform Fault on the southern East Pacific Rise, are more porphyritic, less evolved, have lower concentrations of incompatible trace elements, and lower ratios of more incompatible to less incompatible elements (e.g. low K=Ti and La=Sm) compared to lavas from the adjacent East Pacific Rise ridge axis. Sr, Nd and Pb isotope compositions overlap with the depleted end of the field for Pacific mid-ocean ridge basalts, but extend to lower 87 Sr=86 Sr (0.702137), 206 Pb=204 Pb (17.462), 207 Pb=204 Pb (15.331), 208 Pb=204 Pb (36.831), and higher 143 Nd=144 Nd (0.513345) than any lavas previously reported from the Pacific. Peridotites from the Garrett Transform have Nd isotope compositions within the range of the intra-transform lavas. The unusual major and trace element compositions of the Garrett lavas appear to be characteristic of other intra-transform lavas from elsewhere in the Pacific. The chemical and isotopic features of the Garrett lavas can be explained by remelting, beneath the transform, a two-component upper mantle which was depleted in incompatible element-enriched heterogeneities during melting beneath the East Pacific Rise ridge axis (within the past 1 Ma). Our data place new constraints on the trace element and isotope composition of the depleted mantle component that contributes to magmatism in the Pacific, and show that this component is heterogeneous, both on the scale of a single transform fault, and on the scale of an ocean basin. 1999 Elsevier Science B.V. All rights reserved. Keywords: East Pacific Rise; transform faults; East Pacific; lava flows; geochemistry 1. Introduction Geochemical studies of mid-ocean ridge basalts (MORB) have shown that the upper mantle beneath the ocean basins is chemically and isotopically heterogeneous [1–3]. In some cases, heterogeneity in MORB can be attributed to the presence of nearŁ Corresponding author. Present address: Max-Planck-Institut für Chemie, Postfach 3060, 55050 Mainz, Germany. Fax: C49 6131 371051; E-mail: [email protected] ridge mantle plumes (e.g. [4–7]). However, chemical and isotopic heterogeneity is found in lavas erupted at all mid-ocean ridges, including those far from known mantle plumes [3,8–10]. The magmas erupted at mid-ocean ridges are derived from relatively high degrees of partial melting of relatively large volumes of mantle, and these melts undergo mixing during melt aggregation and focusing towards the ridge axis, and also within magma chambers in the crust. As a result, it is difficult to infer the chemical and isotopic com- 0012-821X/99/$ – see front matter 1999 Elsevier Science B.V. All rights reserved. PII: S 0 0 1 2 - 8 2 1 X ( 9 9 ) 0 0 2 3 6 - 8 272 J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 positions of mantle heterogeneities from studies of lavas erupted on ridge axes alone. Lavas erupted on seamounts on the ridge flanks are derived from melting of smaller volumes of mantle, and studies of such rocks have given important insights into the composition and scale of heterogeneities in the upper mantle. For example, the trace element and isotope variation within Pacific seamounts is greater than that seen in Pacific MORB [11–15]. This observation has led to the idea that the chemical and isotopic heterogeneity observed in lavas erupted at spreading centers and on seamounts is the result of melting a two-component mantle, consisting of easily melted, incompatible element-enriched veins or ‘plums’ with relatively high K=Ti, high 87 Sr=86 Sr etc., within a more refractory matrix which is relatively depleted in incompatible trace elements, and has lower K=Ti and low 87 Sr=86 Sr [9–11,13–17]. Several different depleted and enriched components appear to be necessary to explain the heterogeneity observed in the lavas erupted on Pacific ridge axes and on Pacific seamounts [9,15,18,19]. However, because all of these lavas are derived from different degrees of melting of variably enriched mantle, the compositions of individual endmember components in the sub-Pacific upper mantle is not well known. In this paper, we present new trace element and Sr, Nd and Pb isotope data for young lavas erupted as a result of intra-transform extension within the Garrett Transform Fault, on the East Pacific Rise (EPR) in the eastern Pacific (Fig. 1). These intra-transform lavas include samples with lower 87 Sr=86 Sr, 206 Pb=204 Pb, 207 Pb=204 Pb and 208 Pb=204 Pb and higher 143 Nd=144 Nd than any other lavas previously reported from the Pacific. Compared to lavas from the adjacent EPR ridge axis, the Garrett lavas are more porphyritic and less evolved, have lower concentrations of incompatible trace elements, and lower ratios of more incompatible to less incompatible trace elements (e.g. low K=Ti, La=Sm). We argue that the unusual trace element and isotope compositions of these lavas are the consequence of melting a twocomponent mantle beneath a transform fault. That is, the Garrett intra-transform lavas are derived from a mantle source which was depleted in the easily melted, incompatible element-enriched components, as a result of partial melting beneath the EPR axis, within the last 1 Ma. Our data give new insights into the composition of the depleted upper mantle beneath the eastern Pacific. 2. Geological setting The Garrett Transform Fault offsets the fastspreading (14.5 cm=y) southern EPR axis at 13º280 S by 130 km (Fig. 1a), and is one of the few transform faults in which active volcanism is known to occur. In the Pacific, systematic sampling of intra-transform volcanism has only been carried out in the Siqueiros and Garrett transform faults [20–25]. Detailed descriptions of the structure and geology of the Garrett Transform have been published elsewhere [22–25]. The transform fault zone is around 24 km in width, and the deepest parts of the transform valley are over 5000 m in depth. Within the transform valley, three NE–SW-trending ridges (named the Alpha, Beta and Gamma Ridges, Fig. 1) lie at a depth of <3500 m. Submersible observations have shown that recent volcanism within the transform is largely restricted to these ridges, but has also built small cones on the floors of the eastern and western transform troughs [22,23]. Young flows also occur on the south wall of the Eastern Trough, in the East Valley, and on the southern wall of Garrett Deep, in which upper mantle and lower crustal rocks are exposed [22,23]. The intra-transform lavas were erupted as pillow lavas and as sheet flows, many of which consist of fresh glass [22,23]. Of the samples analysed in this study, sample GN13-1 was collected from a young intra-transform lava flow on the floor of the Eastern Trough (Fig. 1b). Samples GN12-1 and GN12-10 are from the Alpha Ridge, and samples GN2-2 and GN2-5 were collected from young flows on the flank of the Gamma Ridge. The other samples were collected from older flows, or from talus piles, and may therefore be from intra-transform lavas, or from older crust formed at the EPR ridge axis. Details of the sample locations are given in Tables 1 and 2. 3. Petrology and major element chemistry The Garrett intra-transform lavas are dominantly olivine and=or plagioclase phyric basalts and picritic basalts [22,23]. On the EPR, porphyritic lavas such J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 273 Fig. 1. Simplified tectonic maps adapted from [25] showing (a) the location of the Garrett Transform in the eastern Pacific, and (b) the major structural features of the transform and locations of the samples studied. as these are rare, and are generally only found close to large transform faults. Petrographic descriptions and major element analyses of the Garrett intra-transform lavas have been reported previously [22–25]. Major element data for the samples analysed in this study are given in Table 2. Compared to lavas erupted on the adjacent segments of the southern East Pacific Rise ridge axis, the Garrett lavas are generally less evolved, and contain lower concentrations of incompatible minor and trace elements. For example, the intra-transform lavas have Mg# in the range 58–71, and average K2 O contents of 0.04% [22,25], compared with values of 40–65 and 0.14% for lavas from ridge segments of the southern EPR axis adjacent to the Garrett Transform [9]. The Garrett lavas also have lower TiO2 , FeO, Na2 O and P2 O5 , and higher CaO and Al2 O3 compared to lavas from the adjacent EPR. The range in major element composition within the Garrett lavas can be explained by fractionation of olivine š plagioclase š clinopyroxene from a range of primary melt compositions; however, the intra-transform lavas do not represent parental magmas to the more evolved lavas erupted at the EPR ridge axis [22,25]. Compared to MORB erupted at adjacent segments of the southern EPR ridge axis, the Garrett lavas were derived from smaller degrees of melting (¾15%), of a mantle source which was relatively depleted in incompatible minor and trace elements [9,22,25,26]. The peridotites recovered from the Garrett Transform are variably serpentinised harzburgites, some of which have been locally refertilised, probably as a result of intra-transform magmatism [25]. Spinel, orthopyroxene and rare clinopyroxene in these peri- 274 J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 Table 1 Isotope data for peridotites and lavas from the Garrett Transform Sample Latitude (ºS) Longitude (ºW) Depth (m) Peridotites GN 3-9 GN 14-1 GN 14-2 GN 14-9 GN 14-14 GN 15-2 GN 15-5 13º28.3 13º28.0 13º28.0 13º28.4 13º28.7 13º27.8 13º27.8 111º32.1 111º30.4 111º30.4 111º30.8 111º31.1 111º32.8 111º32.8 4324 5050 5046 4660 4244 4647 4688 Lavas GN 2-2 GN 2-5 GN 4-1 GN 4-11 GN 10-3 GN 11-4 GN 12-1 GN 12-10 GN 13-1 GN 13-6 GN 13-8 GN 15-1 13º28.1 13º28.1 13º28.2 13º26.9 13º25.9 13º27.5 13º24.2 13º24.2 13º26.7 13º28.1 13º28.3 13º27.3 111º22.2 111º22.2 111º30.1 111º29.5 111º49.9 111º49.9 111º56.5 111º56.5 111º35.4 111º35.3 111º34.7 111º32.9 3451 3257 5062 3720 4434 3806 3740 3478 4528 3657 3764 4801 87 Sr=86 Sr 0:702319 š 10 0:702298 š 10 0:702268 š 10 0:702459 š 10 0:702211 š 10 0:702219 š 11 0:702354 š 13 0:702207 š 13 0:702156 š 8 0:702392 š 10 0:702417 š 11 0:702137 š 6 dotites are extremely depleted in Al2 O3 compared to those in peridotites from slow-spreading ridges, suggesting that the Garrett peridotites are residues of very high degrees of melting [25,27]. 4. Analytical methods Trace element and isotope analyses of intra-transform lavas were carried out on hand-picked chips of fresh glass and crystalline basalt which were leached in 5% HCl–10% H2 O2 in an ultrasonic bath for 10 min, and washed thoroughly with water before digestion. Sr and Nd isotope analyses were also carried out on aliquots of the same peridotite samples for which major and trace element data have been published previously [25]. These samples were taken from the freshest peridotite, away from gabbro veinlets [25]. 1–5 g of unleached sample powder was dissolved for the analyses. All isotope measurements were carried out on a VG 54-30 Sector multicollector mass spectrometer in static mode. For Sr and Nd, exponential fractionation 143 Nd=144 Nd eNd 0:513222 š 31 0:513271 š 12 0:513276 š 17 0:513256 š 42 0:513250 š 34 0:513253 š 8 0:513311 š 9 11.4 12.4 12.5 12.1 11.9 12.0 13.1 0:513345 š 17 0:513247 š 8 0:513269 š 8 0:513270 š 9 0:513272 š 28 0:513259 š 18 0:513286 š 8 0:513289 š 9 0:513295 š 7 0:513225 š 7 0:513257 š 9 0:513292 š 7 13.8 11.9 12.3 12.3 12.4 12.1 12.5 12.7 12.8 11.5 12.1 12.8 206 Pb=204 Pb 207 Pb=204 Pb 208 Pb=204 Pb 17.830 17.817 17.462 17.903 17.469 17.545 17.621 17.655 17.697 18.023 18.075 17.768 15.363 15.374 15.341 15.444 15.379 15.346 15.418 15.363 15.353 15.416 15.425 15.331 37.121 37.121 37.025 37.327 36.831 36.895 37.079 37.004 36.980 37.413 37.468 37.028 corrections were applied using 86 Sr=88 Sr 0.1194 and 146 Nd=144 Nd 0.7219. The NBS-987 Sr standard and an in-house Nd standard prepared from Ames Nd metal gave 87 Sr=86 Sr 0:710261 š 14 (n D 3, 2¦ ) and 143 Nd=144 Nd 0:511973 š 12 (n D 10, 2¦ ), respectively, over the period of analysis. Data in Table 1 are normalised to values of 0.710248 and 0.511972 (the value of the in-house Nd standard relative to a value of 0.511855 for the La Jolla standard). Pb was analysed at 1350ºC, and the data corrected for instrumental mass fractionation using the values of Todt et al. [28] for the NBS-981 Pb standard. The total Pb procedure blank for whole-rock analyses is between 60 and 100 pg per analysis. Based on repeated analysis of standards, the 2¦ external precision on the Pb isotope analyses is approximately 0.014, 0.018 and 0.040 for 206 Pb=204 Pb, 207 Pb=204 Pb and 208 Pb=204 Pb, respectively. Trace element analyses were carried out on a Fisons Plasmaquad II inductively coupled plasma mass spectrometer at The University of Queensland; details of sample preparation and analytical conditions are given elsewhere [13]. 39.1 256 361 47.6 68.9 92.9 67.7 15.2 0.207 77.0 23.4 52.8 0.824 2.04 1.53 5.57 1.08 6.15 2.40 0.945 3.36 0.628 4.33 0.938 2.72 0.403 2.59 0.392 1.63 0.0655 0.562 0.0430 0.0206 36.4 255 372 48.2 67.0 89.2 70.7 15.7 0.285 62.2 22.6 49.1 0.930 2.34 1.42 5.01 0.982 5.36 2.05 0.821 2.94 0.546 3.82 0.808 2.40 0.364 2.30 0.344 1.43 0.0773 0.241 0.0444 0.0974 26.4 193 317 39.8 92.0 74.7 64.1 15.4 0.200 59.0 18.3 36.0 0.570 1.63 0.982 3.55 0.719 4.10 1.64 0.664 2.39 0.443 3.12 0.659 1.95 0.298 1.86 0.278 1.11 0.0585 0.271 0.0303 0.0160 50.13 1.11 15.40 9.07 0.19 8.95 12.24 2.18 0.03 0.05 GN 4-11 33.4 203 441 43.2 130 65.6 53.8 13.8 0.432 62.3 15.8 28.0 0.447 1.25 0.775 2.84 0.571 3.36 1.43 0.605 2.08 0.410 2.89 0.637 1.85 0.278 1.80 0.280 0.949 0.0345 0.136 0.0218 0.0221 GN 10-3 West Trough 32.5 216 362 46.6 194 67.9 66.0 14.9 0.145 103 23.2 62.2 0.597 1.16 1.63 6.40 1.24 6.89 2.58 0.996 3.42 0.638 4.36 0.937 2.67 0.398 2.56 0.391 1.82 0.0507 0.275 0.0334 0.0173 49.59 1.28 15.97 8.70 0.17 8.90 11.83 2.60 0.03 0.00 GN 11-4 38.4 217 258 49.1 148 95.4 71.2 15.5 0.213 138 24.8 67.8 0.863 2.06 2.04 7.41 1.38 7.50 2.76 1.07 3.63 0.683 4.62 1.01 2.91 0.431 2.78 0.425 1.88 0.0706 0.309 0.0493 0.0228 48.68 1.35 16.20 10.23 0.15 8.16 11.15 2.78 0.04 0.00 GN 12-1 Alpha Ridge 39.7 281 214 44.4 73.6 68.3 78.3 16.5 0.238 94.5 29.3 74.5 1.10 2.30 2.17 7.87 1.50 8.32 3.14 1.19 4.26 0.807 5.46 1.19 3.42 0.505 3.26 0.498 2.24 0.0876 0.294 0.0588 0.0288 GN 12-10 33.3 235 394 46.6 129 74.9 68.8 15.8 0.290 63.1 22.6 46.3 0.767 1.92 1.24 4.63 0.956 5.39 2.15 0.868 3.09 0.565 3.96 0.825 2.42 0.365 2.31 0.344 1.47 0.0654 0.247 0.0367 0.0455 50.58 1.16 15.59 8.95 0.16 8.79 12.34 2.37 0.04 0.10 GN 13-1 Outcrop of sheeted lavas 36.4 302 330 45.8 102 74.3 243 17.5 2.45 80.2 34.2 98.1 2.44 6.99 3.18 10.6 1.97 10.1 3.54 1.26 4.81 0.853 5.95 1.23 3.66 0.559 3.51 0.531 2.73 0.194 0.454 0.148 0.0722 50.47 1.73 14.73 10.15 0.14 7.57 11.27 2.67 0.11 0.15 GN 13-6 Pillow fragment from outcrop Major element concentrations in weight %, trace element concentrations in ppm. Major element analyses by electron microprobe from Hekinian et al. [19]. 0.0483 0.0229 40.8 262 383 46.9 67.8 95.0 69.6 15.6 0.233 79.7 24.3 55.9 0.892 2.25 1.63 5.90 1.15 6.47 2.48 0.972 3.49 0.653 4.48 0.982 2.81 0.418 2.68 0.407 1.70 0.0679 Sc V Cr Co Ni Cu Zn Ga Rb Sr Y Zr Nb Ba La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Th U 50.78 1.25 14.17 9.81 0.19 8.05 12.29 2.23 0.04 0.06 GN 4-1 50.57 1.18 15.07 9.32 0.18 8.45 12.23 2.41 0.04 0.08 GN 2-5 GN 2-2 50.95 1.21 14.62 9.30 0.25 8.33 12.41 2.32 0.03 0.09 Pillow fragment, talus, East Trough Gamma Ridge SiO2 TiO2 Al2 O3 FeOt MnO MgO CaO Na2 O K2 O P2 O5 Sample description, geological setting: Table 2 Major and trace element analyses of lavas from the Garrett Transform 39.2 335 232 46.4 89.1 70.9 101 17.8 2.29 84.6 40.1 117 3.13 8.60 3.99 13.0 2.40 12.2 4.24 1.47 5.72 1.02 7.12 1.48 4.40 0.658 4.16 0.626 3.30 0.247 0.532 0.189 0.290 50.78 2.05 13.48 11.76 0.20 6.87 11.31 2.74 0.20 0.18 GN 13-8 Pillow fragment, talus 35.9 331 307 50.8 153 73.1 349 18.9 0.921 95.1 45.6 131 2.05 3.84 3.61 12.9 2.48 13.1 4.68 1.55 6.39 1.15 8.01 1.67 4.91 0.745 4.69 0.701 3.70 0.177 0.724 0.111 0.662 50.50 2.45 14.96 10.07 0.15 6.83 10.26 3.71 0.19 0.06 GN 15-1 Talus, Central Basin J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 275 276 J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 5. Results 5.1. Garrett intra-transform lavas Sr, Nd and Pb isotope data for the intra-transform lavas, and Nd isotope data for the associated peridotites are given in Table 1. The Garrett lavas have isotope compositions which overlap with the depleted end of the field defined by Pacific MORB, but extend to considerably lower 87 Sr=86 Sr, 206 Pb=204 Pb, 207 Pb=204 Pb, 208 Pb=204 Pb, and higher 143 Nd=144 Nd than any lavas previously reported from the Pacific, including lavas from the EPR axis immediately to the north and to the south of the Garrett Transform [18] (Fig. 2). Two previous isotope analyses of Garrett intra-transform lavas [2,18] lie within the range of our new data and are shown for comparison in Fig. 2. Previously, the lavas with the most depleted isotope signatures known from the Pacific (excluding the two previous analyses of Garrett lavas [2,18]) were samples from the western rift of the Easter Microplate [6,29], and from the Lamont seamounts near the EPR axis at 10ºN [15]. To our knowledge, sample GN2-2 from the Garrett Transform has higher 143 Nd=144 Nd (0.513345) than any other lava yet reported from the ocean basins. 87 Sr=86 Sr ratios of samples GN13-1, GN15-1, GN10-3 and Fig. 2. Isotope compositions of Sr, Nd and Pb of the Garrett intra-transform lavas (ITL) analysed in this study (filled squares). 2¦ external precision on the isotope analyses is shown as a cross in bottom left corner of each figure. The bar in (a) represents range in 143 Nd=144 Nd of the Garrett peridotites (see Table 1). Open circles are data for lavas from segments of the EPR axis immediately to the north and south of the Garrett Transform [18]. Two previous analyses of Garrett lavas (open square, [18] and open triangle [2]) are also shown, together with fields for Pacific, Indian and Atlantic MORB. J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 GN12-10 of between 0.702137 and 0.702211 are lower than the lowest value previously reported for a lava from the Pacific Ocean (sample 1558-2014 from the Lamont Seamounts; 0.702218 [15]) and similar to the lowest values observed in lavas from the MidAtlantic Ridge at 2–7ºS (0.702125 to 0.702270 [30]). 206 Pb=204 Pb ratios of samples GN4-1, GN10-3 and GN11-4 (17.462 to 17.545) are lower than those of any other lavas from the Pacific and Atlantic Oceans, including sample EN113 26D from the West Rift of the Easter Microplate which has a 206 Pb=204 Pb ratio of 17.594 [6]. These 206 Pb=204 Pb values are not as low as some MORB and ocean island basalts from the Indian Ocean (e.g. [31,32]), but the Indian Ocean basalts differ as their low 206 Pb=204 Pb is often associated with high 87 Sr=86 Sr. Two of the Garrett lavas (GN13-6, GN13-8) have 87 Sr=86 Sr and 206 Pb=204 Pb values that overlap with the field defined by lavas from adjacent segments of the southern EPR, but have higher 143 Nd=144 Nd (Fig. 2a). The Garrett lavas have a large range in 207 Pb=204 Pb for a given 206 Pb=204 Pb, compared to lavas from the adjacent spreading segments on the southern EPR (see Fig. 2b). The two previous Pb isotope analyses of Garrett lavas [2,18] have a similar range in 207 Pb=204 Pb. In Pb isotope evolution diagrams (Fig. 3), the lavas scatter about the evolution curves estimated for the depleted upper mantle [33], or have lower 207 Pb=204 Pb than the depleted mantle model evolution curves. There is a positive correlation between 87 Sr=86 Sr and 206 Pb=204 Pb (Fig. 2). The Garrett lava analysed by Mahoney et al. [18] has a 3 He=4 He ratio of 9.7 R=RA , which is significantly higher than the typical range for Pacific MORB (¾8.5 R=RA ). 277 Fig. 3. Pb isotope diagrams showing model evolution curve for the depleted upper mantle [33], and data for the Garrett intra-transform lavas. Data are from this study (filled squares), Mahoney et al. [18] (open square) and Hamelin et al. [2] (open triangle). Also shown are data for lavas from segments of the EPR axis immediately to the north and south of the Garrett Transform [18] (circles). dotites in the Indian Ocean which have values in the range 0.51296–0.51320 [34]. 6. Combined trace element and isotope variations 5.2. Garrett peridotites The peridotites from the Garrett Transform have been extensively serpentinised, which has modified the primary Sr isotope compositions of these rocks (87 Sr=86 Sr values of the peridotites are 0.7076– 0.7093); however, Nd appears to have remained immobile during this process [25]. Nd isotope compositions of the peridotites (0.51322–0.51331, see Table 1) lie within the range of the intra-transform lavas (vertical bar in Fig. 2a). The whole-rock analyses of the Garrett peridotites have significantly higher 143 Nd=144 Nd than clinopyroxenes from abyssal peri- Trace element data for the samples we have analysed for isotopes are listed in Table 2. Additional trace element analyses of Garrett intra-transform lavas are given in [25]. Compared to normal Pacific MORB, the Garrett intra-transform lavas have relatively low concentrations of incompatible minor and trace elements [24,25]. For example, the Garrett lavas have Zr concentrations of 28–130 ppm, compared to 80–350 ppm for lavas from adjacent segments of the EPR axis [18]. The Garrett lavas also have low ratios of more incompatible to less incompatible elements 278 J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 Rb=Sr, 206 Pb=204 Pb, and 143 Nd=144 Nd. 87 Sr=86 Sr, and higher Sm=Nd 7. Discussion 7.1. Comparison with other intra-transform lavas Fig. 4. K=Ti, Rb=Sr, Nb=Zr and Nd=Sm for Garrett intra-transform lavas (data from [2,18] and this study), and MORB from the adjacent segments of the EPR axis [18]. Symbols as in Fig. 2. The Garrett lavas have low ratios of more incompatible to less incompatible trace elements, compared to Pacific MORB. (for example low K=Ti, Nb=Zr, Nd=Sm, and Rb=Sr) compared to lavas from adjacent ridge segments of the southern EPR (Figs. 4 and 5). In addition, trace element ratios such as Nb=Ta (9.74–13.1) and Zr=Hf (29.5–36.1), which are generally little fractionated due to the similar chemical behaviour of these element pairs, are low compared to MORB from the EPR and chondrites (Nb=Ta ¾17; Zr=Hf ¾38), and are similar to the lowest values observed in some lavas from Pacific seamounts [13]. In incompatible trace element ratio-isotope diagrams (Fig. 5a–i), the Garrett lavas overlap the field defined by lavas from the adjacent ridge segments of the southern EPR (Fig. 5), but extend to lower K=Ti, Intra-transform volcanism is known to occur at only a few locations in the Pacific, and geochemical analyses have been carried out only on intra-transform lavas from the Siqueiros, Raitt and Garrett Transforms. Lavas erupted at small spreading centers within the Siqueiros Transform are more primitive (9.5– 10.6% MgO) and more porphyritic, than lavas from the nearby EPR ridge axis [20,21,35]. Siqueiros intra-transform lavas also have lower K=Ti and La=Sm than MORB erupted at the nearby ridge axes (Fig. 6), and have 87 Sr=86 Sr compositions (0.70235 to 0.70260 [21,35]) which extend to values that are lower than those observed in lavas from the EPR at 9º300 N and 10º300 N (0.70248 to 0.70259 [36–38]). However, picritic basalts from the Siqueiros Transform, which have the lowest incompatible trace element abundances, have 87 Sr=86 Sr values similar to those of lavas from adjacent segments of the EPR [35]. Two intra-transform lavas recovered from the Raitt Transform on the Pacific–Antarctic Ridge at 54º260 S [39] are also relatively primitive and have low concentrations of incompatible trace elements, low K=Ti (0.052–0.054), and La=Sm (0.51–0.54) relative to MORB from adjacent ridge axis segments (Fig. 6). Pb isotope compositions of the intra-transform lavas are within the range of MORB from elsewhere on the Pacific–Antarctic Ridge, whereas 87 Sr=86 Sr is higher, and 143 Nd=144 Nd lower, than other Pacific–Antarctic Ridge lavas [39]. Thus on the basis of the available data, intra-transform lavas are in general more porphyritic, more primitive, contain lower concentrations of incompatible trace elements, and have lower ratios of more incompatible to less incompatible trace elements, compared to normal MORB (Fig. 6). However, the relatively low 87 Sr=86 Sr and 206 Pb=204 Pb, and high 143 Nd=144 Nd ratios of the Garrett lavas are not a characteristic of all intra-transform lavas. In the following section, we discuss a petrogenetic model J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 279 Fig. 5. Variation in Sr, Nd and Pb isotope composition with Rb=Sr, Sm=Nd and K=Ti, for the Garrett intra-transform lavas, and MORB from adjacent segments of the southern EPR. Symbols as in Fig. 2. for intra-transform magmatism that can account for these observations. 7.2. Petrogenesis of Garrett intra-transform lavas The petrological differences between the intratransform lavas and those erupted at the ridge axis may reflect the different physical conditions beneath the transform [20,22]. Thus, the relatively primitive and porphyritic nature of the Garrett lavas may be the result of rapid transport of magmas to the surface, without extensive cooling and fractionation in crustal magma chambers [22]. Hékinian et al. [22] argued that the relatively low concentrations of incompatible trace elements, and the low ratios of more incompatible to less incompatible trace elements, could also be explained in terms of processes operating within the crust. In this model, although more enriched lavas are produced during mantle melting beneath the transform, these are not erupted at the surface, but instead freeze within the lithosphere. This model thus requires a unique process, restricted to transform faults, whereby enriched and depleted melts from the same source remain separate, with the more enriched melts freezing before they are erupted [22]. 280 J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 Fig. 6. K=Ti and La=Sm for intra-transform lavas (ITL) from the Siqueiros and Raitt Transform Faults in the Pacific, compared with MORB from the adjacent segments of the northern EPR and Pacific–Antarctic Ridge (PAR). Data are from [21,37,39]. Alternatively, the depleted incompatible trace element signatures of the Garrett and other intra-transform lavas may have been derived directly from their mantle source. We suggest that the unusual isotope and trace element compositions of the Garrett lavas may simply be a consequence of melting a twocomponent mantle beneath a transform fault [24]. As discussed in Section 1, geochemical studies of lavas from Pacific ridge axes and Pacific seamounts have shown that the upper mantle beneath the region consists of incompatible element-enriched, easily melted heterogeneities which occur as veins or ‘plums’ within a depleted matrix [10,11,13,16]. Mahoney et al. [18] and Sinton et al. [9] speculated that the Garrett sample they analysed was derived from mantle that had been depleted in incompatible element-enriched heterogeneities as a result of melting beneath the adjacent ridge axis. The upper mantle material currently melting beneath the Garrett Transform has previously undergone partial melting beneath the EPR axis within the last 900 ka (the age offset at the transform). During upwelling and melting of mantle beneath the ridge axis, the enriched, most fertile components would have been the first to melt. Asthenospheric mantle that underwent only limited upwelling and melting will therefore have lost the enriched, easily melted component, but will have remained sufficiently fertile to undergo decompression melting during lithospheric extension within the Garrett Transform [24] (Fig. 7). Peridotites from the Garrett Transform are highly depleted harzburgites with clinopyroxene being essentially absent (<1 vol.%), and residual mineral modes and chemistry indicate that they represent the residues of very high degrees of melting (¾25%) beneath the EPR axis. The Garrett harzburgites are melting residues of mantle that ascended to shallow depths and melted most beneath the EPR [25,27] (see Fig. 7b). In contrast, the intra-transform lavas are inferred to result from decompression melting, beneath the Garrett Transform, of mantle that had previously undergone only limited melting and melt extraction beneath the EPR axis, which depleted the source of the Garrett lavas only in the easily melted, incompatible element-enriched components (Fig. 7). The fact that the peridotites and the intra-transform lavas have a similar range in 143 Nd=144 Nd (Fig. 2a) suggests that the mantle currently melting beneath the transform was entirely stripped of the enriched component during partial melting at the EPR axis. Assuming that the Garrett peridotites are residues of ¾25% melting (estimated from the compositions of residual spinel, orthopyroxene and clinopyroxene [25]) indicates that the enriched component comprises significantly less than 25% of fertile mantle (see Fig. 7b). Our model can account for the low concentrations of incompatible elements, the low ratios of more incompatible to less incompatible trace elements (e.g. K=Ti, La=Sm) in lavas from the Garrett, Siqueiros and Raitt Transforms, and the relatively depleted Sr, Nd and Pb isotopic signatures of the Garrett lavas. The model may also explain the differences in isotope compositions of the Garrett, Siqueiros and Raitt intra-transform lavas. For example, whereas Garrett lavas have low Rb=Sr and low 87 Sr=86 Sr compared to MORB from the adjacent ridge segments, Siqueiros intra-transform lavas have low Rb=Sr, but many have 87 Sr=86 Sr values similar to lavas from the nearby ridge axis [21,35], and intra-transform lavas from the Raitt Transform have lower Rb=Sr, but higher 87 Sr=86 Sr than lavas erupted at the Pacific Antarctic Ridge axis [39]. It is possible that these differences reflect variations in the scale of mantle heterogeneity in the upper mantle beneath the Pacific ridges. If J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 mantle heterogeneities are small enough that melts can equilibrate with bulk mantle during the melting process, then after a small degree of melting beneath the EPR axis, the residue will have low K=Ti, Rb=Sr 281 etc, but isotope ratios remain the same [11,40]. In contrast, partial melting of mantle containing larger heterogeneities (>1–10 m) will yield a residue with low K=Ti, Rb=Sr, but also lower 87 Sr=86 Sr and higher 143 Nd=144 Nd. Variations in the age of these heterogeneities may be an important factor in determining the contrast in isotope composition between enriched heterogeneities and depleted matrix, and hence between the lavas erupted at the ridge axis, and within transforms. The low 207 Pb=204 Pb ratios of the Garrett lavas compared to MORB from the EPR (Figs. 2 and 3) suggest that the mantle heterogeneities beneath this part of the southern EPR are probably several Ga old. A third possibility is that the differences in Sr, Nd and Pb isotope composition between intratransform lavas from the Garrett, Siqueiros and Raitt Transforms and MORB from the adjacent ridge axes may be related to variations in spreading rate along the EPR. Spreading rate has an important influence on the mean extent of melting at mid-ocean ridges [27], and thus on the degree of depletion of the melting residues, which determines the nature of the sources for subsequent intra-transform magmatism. The degree of residual mantle depletion is expected to be most extreme beneath the fast-spreading southern EPR (spreading rate 14–16 cm=y), and least beneath the Pacific–Antarctic Ridge (8–9 cm=y). Further studies of other intra-transform lavas from elsewhere in the Pacific are needed to test these possibilities. Our model for intra-transform magmatism may also explain the relatively high 3 He=4 He ratio (9.7 R=RA ) of the Garrett lava analysed by Mahoney et al. [18]. This sample has a He concentration which Fig. 7. Schematic diagrams showing processes by which highly depleted lavas are generated in the Garrett Transform. (a) Map showing location of sections in (b) and (c). (b) Section across the EPR. Mantle upwelling directly beneath the ridge axis (path x) will melt to the greatest extent, leaving a highly depleted residue (abyssal peridotite). In contrast, mantle upwelling away from the ridge axis (path y) will experience only limited decompression melting and melt extraction, leaving a residue (cross-hatched region) which is preferentially depleted in the enriched heterogeneities. (c) Section across the Garrett Transform. Residual mantle that has been stripped of enriched heterogeneities during partial melting beneath the EPR axis, is the source for subsequent intra-transform magmatism. 282 J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 is similar to that of lavas from the nearby ridge axis (J.J. Mahoney, pers. commun., 1999), but the Garrett lavas have generally lower U and Th concentrations. 3 He=4 He ratios higher than those of MORB are often taken as evidence for a contribution from a ‘primitive’, undegassed mantle source. Alternatively, if U and Th are more incompatible than He, as has previously been speculated [41], then the relatively high 3 He=4 He and low (U C Th)=He of the Garrett lava can be explained by our model. The Garrett lavas may have been inherited from a source from which easily melted heterogeneities (enriched in U, Th and 4 He) were removed during melting beneath the EPR axis, leaving a residue with low U and Th, moderate He concentration, and relatively high 3 He=4 He, which became the source for subsequent intra-transform magmatism beneath the Garrett Transform. This suggestion could be tested with He isotope measurements on other intra-transform lavas. 7.3. Implications for mantle heterogeneity The lavas erupted at Pacific ridge axes, on seamounts, and on oceanic islands, all consist of variable mixtures of incompatible trace element depleted matrix and enriched heterogeneities [10– 13,16,17,42]. Earlier studies of oceanic lavas therefore attempted to estimate the isotope composition of the depleted mantle endmember(s), either by inversion of the available isotope data [43], or by arbitrarily placing this endmember beyond the most depleted end of the MORB array (the DMM component [19]). The fact that Garrett peridotites and Garrett intratransform lavas have similar 143 Nd=144 Nd (Fig. 2) suggests that the Sr, Nd and Pb isotope composition of the depleted mantle endmember that contributes to magmatism beneath this region of the southern EPR is similar to that of the most depleted Garrett lavas. However, lavas from the Garrett Transform and from the southern EPR do not lie upon simple two-component mixing lines in trace element-isotope diagrams (Fig. 5), which suggests that the depleted mantle matrix itself is heterogeneous, both on the scale of a few km beneath the Garrett Transform, and on the scale of an ocean basin (the Raitt intra-transform lavas have 87 Sr=86 Sr values that do not overlap with the data for Garrett lavas). Variations in mantle composition on this scale may reflect the complexity of the processes causing mantle heterogeneity, and the fact that these processes have occurred throughout geological time (e.g. [44]). As discussed earlier, mantle heterogeneity beneath the southern EPR may be several Ga old. Insights into the composition of the DMM endmember have also come from studies of abyssal peridotites. Clinopyroxene separates from abyssal peridotites from the Indian Ocean have 143 Nd=144 Nd values that are similar to, or higher than, MORB from the nearby segments of the ridge axes [34]. This was interpreted as the effects of melting a heterogeneous mantle, with the peridotites representing residual mantle from which an enriched component with lower 143 Nd=144 Nd was removed during melting beneath the ridge axis [34]. The Indian Ocean peridotites have lower 143 Nd=144 Nd than the Garrett peridotites. However, the primary Sr and Pb isotope compositions of abyssal peridotites cannot be determined easily, because of the effects of serpentinisation. Intra-transform lavas are therefore an important source of information on the nature and origin of heterogeneity in the upper mantle. 8. Conclusions (1) Lavas erupted within the Garrett Transform Fault are more primitive and more porphyritic, have lower concentrations of incompatible trace elements, and lower ratios of more incompatible to less incompatible elements, compared to lavas from adjacent segments of the southern EPR axis. (2) The unusual petrology and major and trace element compositions of the Garrett lavas appear to be characteristic of intra-transform lavas from the Siqueiros and Raitt Transforms. (3) The relatively primitive and porphyritic nature of these intra-transform lavas may be a result of the different physical conditions that exist beneath the transform. In contrast, the unusual trace element compositions of intra-transform lavas is inherited from the mantle source of these lavas, which has undergone prior melt extraction beneath the EPR axis, depleting an originally heterogeneous mantle in incompatible element-enriched, easily melted heterogeneities. J.I. Wendt et al. / Earth and Planetary Science Letters 173 (1999) 271–284 (4) The Garrett lavas have Sr, Nd and Pb isotope compositions which overlap with the depleted end of the array defined by Pacific MORB, but extend to lower 87 Sr=86 Sr, 206 Pb=204 Pb and 207 Pb=204 Pb, and higher 143 Nd=144 Nd values than any other lavas from the Pacific Ocean. (5) 143 Nd=144 Nd for peridotites from the Garrett Transform are similar to values for the intra-transform lavas, indicating that the source of the Garrett lavas has been entirely stripped of the enriched heterogeneities that exist in the uppermost mantle beneath much of the eastern Pacific. (6) Studies of intra-transform lavas can give important insights into the composition of the upper mantle, and in particular can be used to estimate the Sr and Pb isotope composition of the DMM component, which is difficult to determine from studies of abyssal peridotites. 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