Policy - Process - Procedure
Document Title:
Specification of Banned
and Restricted Substances
for Use
Document #:
PEC-REG-1-003-00
Organization
Corporate
Revision: L
Document Owner: Ed Decker
Effective Date: February 20, 2008
APPROVALS
NAME
Seb Nardecchia
Bill Ricci
Mario Ochoa
Dongkai Shangguan
TITLE
DEPT NAME
Sr. Director
Director
Director
VP
CSER
GPO
EHS
TLG
DATE
2/20/2008
2/20/2008
2/20/2008
2/20/2008
REVISION HISTORY
REV.
DESCRIPTION OF CHANGE
ORIGINATOR
RELEASE DATE
FBP-RHS500
Rev A
FBPRHS500
Rev B
FBP-RHS500
Rev C
FBP-RHS500
Rev D
FBP-RHS500
Rev E
FBP-RHS500
Rev F
FBP-RHS500
Rev G
Internal Draft
C Graat
01-14-2004
Mod. Version_01
C Graat
07-12-2004
Mod. Version_02
Regulation sub team
07-27-2004
Updated version
J Jurisits
08-09-2004
Final version
P Saavalainen;
J Jurisits; C Graat
08-10-2004
Change to Flex fact doc. Numbering
C Graat
08-20-2004
Add level B substances (JIG Sep 03) and level A
substance (JIG Sep 2004) updates according to
requirements of major customers
P Saavalainen, C Graat
02-03-2005
FBP-RHS500
Rev H
Added homogeneous mat. definition as well as
added column with reference to the related law
and deleted the non intentionally added
P Saavalainen, C Graat
06-07-2005
FBP-RHS500
Battery requirements separated to other table,
P Saavalainen
10-17-2005
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed. Go to the FMS Document Management Portal at
www.fms.flextronics.com to find the latest and controlled copy of this document.
1 of 22
Rev I
FBP-RHS500
Rev J
FBP-RHS500
Rev K
PEC-REG1-002-00
Rev L
reportable substances deleted
New substances and exemptions added
P Saavalainen,
M Ochoa
05-06-2006
Proposal for new Substances, and new
exemptions
P Saavalainen
24-10-2006
New substances (PFOS, PFOs, PFAs, PFOA,
PFC, Se, Bi, Perchlorate , HFC and PFC)
change 0ppm to prohibit
Acceptable testing methods (Chap 5), bans and
restrictions apply per doc date
Ed Decker
Feb 13, 2008
This document is proprietary property of Flextronics. It may be uploaded and
utilized by Flextronics supply partners but may not be shared external to that
relationship.
1.0
BACKGROUND/INTRODUCTION
This specification lists all Flextronics banned and restricted substances based on industry
standards and customer requirements.
2.0 PURPOSE
This specification provides general requirements to suppliers and procurement teams as well as
design teams regarding Flextronics’ standard of banned substances used in components as
recorded in the BoM, materials used in production processes not being part of BoM,
subassemblies, packaging materials and finished products, which are supplied to Flextronics, in
order to fulfill the following targets:



To comply with legal and regulatory requirements
To prevent the banned substances from being used and supplied to Flextronics
To reduce the impact of hazardous substances to the environment and preserve the nature..
3.0 SCOPE
The scope of this document is to specify prohibitions and restrictions on certain substances and
materials used in products and manufacturing, and is applicable to the followings, which are
supplied to or purchased by Flextronics for incorporation into products:

Semi or Fully assembled parts (e.g. module, functional units, board assemblies, and other
assembled parts and accessories)

Parts (e.g. electrical parts, mechanical parts, semiconductor devices, PWB-s)

Indirect Materials (e.g. adhesives, adhesive tapes, labels and soldering materials) used in
production or for products

Packaging materials (e.g. trays, reels, sticks, bags, cushions, staples, sheets, wraps, tapes,
labels, corrugated cardboard, wooden frames, pallet, vinyl ties, and inks or paints for printing)
For some specific applications (e.g. medical, military applications, monitoring and control
instruments), this document may not be applicable and can be exempted as long as a written
approval is provided by customer.
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
2 of 22
When regional or country laws and ordinances exist that set prohibitions or restrictions on
certain substances, the laws and ordinances must be observed, even though the
substances are not clearly regulated in this specification. And the measurement should be
based on the methodology set forth in those laws.
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
3 of 22
4.0 DEFINITIONS and ABBREVIATIONS
Product
The item that the respondent is supplying (e.g., assembly, subassembly,
component, raw material).
Subpart
A sub-unit of a product.
Material
A material is made up of one or more substances (e.g., copper alloy is a
material, which in turn is made up of a number of defined substances,
copper, nickel, silver, etc.).
Substances
Substances are chemical elements and their compounds. CAS numbers
are provided for these substances where known.
Homogeneous
material
Homogeneous material means a material that can not be mechanically
disjointed into different materials. Types of homogeneous material are :
plastics; ceramics; alloys; paper ; resins and coatings.
Mechanically disjointed Means that the materials can be separated by mechanical actions such
as unscrewing ;cutting; crushing; grinding and abrasive processes.
Threshold level
Concentration level, which defines the limit, above which the presence of a
substance defined in Table 1 in homogeneous materials in a product or
subpart is not allowed.
PPM
parts per million, unit of measurement for weight percentage. 1 PPM = 1
mg/kg = 0.0001 % by weight. The parts per million thresholds listed in this
specification refer to the weight of the homogeneous material in a specific
part, not the weight of the material in an entire system.
End-of-life
management
Recycling processes such as precious metals, plastic or other material
recovery etc.
5.0
REFERENCES
5.1 EU Directive 2002/95/EC Restriction of Hazardous Substances (RoHS).
5.2
China SJ/T 11363-2006: Requirements for Concentration Limits for Certain
Hazardous Substances in Electronic Information Products
5.3
China SJ/T 11364-2006: Marking for Control of Pollution Caused by Electronic
Information Products
5.4
China SJ/T 11365-2006: Testing Methods for Hazardous Substances in Electronic
Information Products
5.5
EU Directive 2005/32/EU EcoDesign Requirements for Energy Using Products (EuP)
5.6
EU Directive 1907/2006 Registration, Evaluation, Authorization and Restriction of
Chemicals
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
4 of 22
5.7
Flextronics Specification for Procurement of Lead(Pb) Free Electronic and
Electromechanical Components and Assemblies” (Flextronics Document FBPRHS002)
5.8
Flextronics Declaration Only Form (Flextronics Document FBP-RHS007)
5.9
Flextronics 100% Material Content Declaration Form (Flextronics Document FBPRHS005)
5.10 Flextronics Supplier Environmental Manual (Flextronics Document FBP-RHS012)
5.11 IPC Standard: IPC-1066 - Marking, Symbols, and Labels for Identification of Lead
Free and other Reportable Materials in Lead-Free Assemblies, Components, and
Devices.
5.12 JEDEC Standard: JESD46C - Customer Notification of Product/Process Changes by
Semiconductor Suppliers.
5.13 JEDEC Standard: JESD48B – Product Discontinuance
6.0
PROCEDURE
Banned / Restricted Substance Requirements Table 1, 2 and 3
All bans and restrictions are effective as of the document date.
Table 1 shows substances which are banned / restricted for the use in products and
production. The threshold levels are based on legal requirements in EU. If international law
establishes a new threshold for ban / restriction purpose or there is an update from customer’s
requirements, the threshold levels will be revised accordingly.
Table 2 shows substances which are banned /restricted in product packaging.
Packaging materials (e.g. cartons to package products, cartons for returnable boxes, and
packaging for part transportation which includes handles, reels, sticks, magazines, bags,
staples, sheets, wraps, paints, inks, tapes, labels, cushions, wooden frames, corrugated
cardboard, vinyl ties, cushioning materials, foil and trays) must not contain any amount of lead,
mercury, cadmium, or hexavalent chromium as an intentionally added element. The total
concentration of the four heavy metals (lead, mercury, cadmium and hexavalent chromium)
must not exceed 0.01% (100 PPM) by weight.
Table 3 shows substances which are banned /restricted batteries
Based on EU directive, there are substance bans in different type of batteries. These
substances are Cadmium, Lead and Mercury.
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
5 of 22
7.0
RESPONSIBILITY
7.1
Flextronic’s – It is the responsibility of Flextronics to incorporate restrictions
resulting from current document in all applicable drawings and specifications. Drawings and
specifications have to be updated in case international standards are modified.
7.2
Suppliers – It is the responsibility of all suppliers to comply with the reporting
requirements for all parts and substances sold to Flextronics. An initial declaration on meeting
requirements is needed before starting deliveries of products or materials.
8.0
DOCUMENT REVIEW AND APPROVAL REQUIREMENTS
8.0 This document shall be reviewed for approval by the Environmental Compliance
Procurement Sub-team and approved by key members of the Environmental
Compliance Steering Committee.
9.0
ATTACHMENT/APPENDICES
9.0 Tables 1,2 and 3. Appendix A.
Table 1 - Banned substances
These substances are banned /restricted to the PPM threshold level in all applications. All
homogeneous material in purchased articles (i.e. materials, components, subassemblies, or
products must be free from following substances): cannot contain higher concentrations as
defined in the ppm threshold levels.
Substance Name
Asbestos
CAS – no (Table A)
Azo-based dyes and
colorants
CAS – no (Table B)
in textiles and leathers only
Cadmium and –compounds
PPM
Threshold
banned
Comment
Legal
Regulations
Plastics (mineral filler)
83/ 478/EEC
85/610/EEC
91/659/EEC
1999/77/EEC
USA:CAprop
65
30
75
CAS – no (Table C)
Chromium VI (Cr6+) and –
compounds
Examples of
Applications
1000
Paints, dyes, pigments
used for products
contacting human skin
continuously
Accumulators, batteries,
Relays (contact materials)
Hard and soft solders
Pigments in plastics
Stabilized vinyl chloride
polymers and copolymers
(e.g. PVC) Metallic surface
coating Motors (contact
material) Switches
(contact material) Zinc
layers Pigments, in
enamels and plastics.
Coatings, pigments in
plastics, industrial tubes
Carcinogenic
2002/61/EC
76/769/EEC
Toxic, some
compounds
(cadmium
chloride,
cadmium
oxide and
cadmium
sulfate) are
carcinogenic
EU RoHS
Directive
(2002/96/EC)
91/338/EEC
91/157/EEC
94/62/EC
1999/51/EC
2000/53/EC
76/769/EEC
Carcinogenic
in exhalable
EU RoHS
Directive
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
6 of 22
CAS – no (Table D)
(Flextronics banns without
exemption2006/692/EC)
Formaldehyde
CAS – no 50-00-0
Lead and -compounds
For Pb-free electrical /
electronic components and
interconnect materials, please
refer to the document “
Procurement Guidelines for
Lead (Pb)-Free Electronic
Components and Assemblies “.
CAS – no (Table E)
Lead in PVC
CAS – no (Table E)
Lead in Plastic
CAS – no (Table E)
Mercury and –compounds
CAS - no ( Table F )
Chromium pigments,
chromate surfaces,
corrosion inhibitors
Formaldehyde must not be
used in wooden materials,
furniture, detergents,
cleaning agents and
polishes
Solder, hybrid circuits,
stabilizers in plastics Lead
as component in metals
and alloys, cable
insulation, production of
pigments, corrosion
inhibitors (fuel additive or
in paints)
form
300
PVC, cables
100
Pigments
Same as
above
Same as
above
Mercury and
its
compounds.
Acutely and
chronically
(very) toxic,
accumulate in
organisms
Contribute to
global
warming,
ozone
depleting
Aquatic
pollutants,
nondegradable,
accumulate in
organisms
Skin allergy
banned
1000
1000
Fluorescent light tubes,
Barometers, Discharge
lamps, Relays, Switches,
High intensity discharge
lamps
Ozone depleting substances
CFCs /Isomers CAS - no
(Table G)
BFCs/Isomers CAS - no
(Table G)
HCFCs/Isomers CAS - no
(Table H)
HFCs/Isomers common
names & codes (Table O)
banned
Coolants and cleaning
agents Blowing agent for
plastics HCFCs
replacement for CFCs
Solvents and degreasing
agents. Foaming agent.
Nickel and –compounds in
applications where nickel
compounds are likely to
result
in prolonged skin exposure
Phthalates
in toys and childcare articles
See table N
1000
Polybrominated biphenyls
(PBB)and derivatives
including diphenyl ethers
(PBDE) or biphenyl oxides
(PBDO) Including DecaBDE
CAS – no (Table I)
Polychlorinated Biphenyls
(PCBs), Terphenyls (PCTs)
and Pentachlorophenol
(PCPs)
CAS – no (Table J)
Metal alloys
1000 by mass
of the
plasticized
material
900
50
Plasticizer, particularly in
PVC
Germany:
ChemverbotsV
USA:CA prop65
Teratogenic
Bioaccumulati
ve
Toxic to
reproduction,
aquatic
pollutant
Plastics (flame retardant)
Flame retardants in circuit
boards and plastic parts
Capacitors (liquid) PCP
wood (durability
treatment)
94/62/EEC
2000/53/EC
EU RoHS
Directive
89/677/EEC
91/157/EEC
94/62/EEC
2000/53/EC
See above
See above
EU RoHS
Directive
89/667/EEC
94/62/EEC
98/101/EC
2000/53/EC
2001-H6161A
Montreal
ProtocolClass1
EU:2037/2000
Japan/USA law.
Requirement
of some
major
customers
2005/84/EC
EU RoHS
Directive
2003/11/EC
76/769/EEC
Easily form
very toxic
polybrominate
d dioxins,
thereby
EU:850/2004
85/567/EEC
89/677/EEC
76/769/EEC
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
7 of 22
Polychlorinated
Naphthalenes (more than 3
chlorine atoms)
Radioactive Substances
CAS – no (Table K)
Shortchain Chlorinated
paraffins
CAS – no (Table L)
Tributyl Tin, Triphenyl Tin
and oxides
CAS – no (Table M)
Halogenated (Brominated
and Chlorinated) Flame
Retardants (other than PBB
or PBDE)
CAS – no (Table N)
banned
-
banned
Radioactive substances
cannot be used in any
materials except for usage
in measuring systems or
detectors
Softener or plasticizer in
plastics, paints, coatings,
flame retardants in
plastics, rubbers
Lubricants, paints
Stabilizers Paints, inks,
dyes, colorant,
preservatives, fungicides,
Printed circuit boards,
Plastics (plastic part and
enclosures)
1000
100
900 ppm Br or
Cl
1500 ppm
combined
Vinyl Chloride Polymer
(PVC)
CAS – no 9002-86-2
1000
Packaging, electronic and
mechanical equipment
Antimony trioxide
CAS – no 1309-64-4
1000
Flame retardants in
plastics
Arsenic
CAS – no 7440-38-2
1000
Beryllium oxide
CAS – no 1304-56-9
1000
Paints and fusion coatings,
wood preservatives,
leather
and textile finishers, water
treatment agents, flat
glass,
metal adhesives,
pyrotechnic objects, metal
refinement, glass, metal
bonding agents, coatings,
LED's, semiconductors
(dopant, Gallium arsenide
as substrate),
photocouplers, fiberglass,
insulating tapes, printed
circuit boards, optical
lenses
Component heat sink
Perfluorooctane Sulfonates
(PFOS), and it's derivatives
PFOs, PFAs, PFOA and
max 0.005%
by mass
Scotchguard and stain
repellants and
semiconductor
rendering
plastics nonrecyclable
waste
-
Japanese
law
Carcinogenic
Eu
2000/60/EC
2002/45/EC
Toxic,
Bioaccumulati
ve
Bioaccumulati
ve
EU:89/677/EEC
99/51/EC
76/769/EEC
None
Corrosion
and/or risk of
formation of
chlorinated
dibenzodioxins
and -furans at
uncontrolled
fire
Toxic,
negative for
recycling
Toxic
None
None
Carcinogenic
None
Persistant
Bioaccumlativ
e
76/769/EEC
None
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
8 of 22
Perfluorocarbons (PFC)
Selenium / Selenium
Compounds
CAS – no (Table M)
1000
Bismuth / Bismuth
Compounds
CAS 7440-69-9
1000
Semiconductor,pigment,pa
int,catalyst,sensitizer,anal
ytical reagent,oxidizing
agent
Semiconductor,
solder, catalyst
Remark: The Legal regulations are provided for reference only, and are not intended to be a
comprehensive list of all possible regulations .They should not be considered the sole
reference for material requirements or threshold limits.
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
9 of 22
Exemptions
Here is the list of exemptions for certain applications of lead, mercury, cadmium, hexavalent
chromium, polybrominated biphenyls (PBB) or polybrominated diphenyl ethers (PBDE) which are
exempted from the requirements of RoHS directive 2002/95/EC (amended with commission
decisions 2005/618/EC, 2005/717/EC, 2005/747/EC and 2006/310/EC, 2006/691/EC,
2006/692/EC, 2006/690/EC)
1. Mercury in compact fluorescent lamps not exceeding 5 mg per lamp.
2. Mercury in straight fluorescent lamps for general purposes not exceeding:
— halophosphate 10 mg
— triphosphate with normal lifetime 5 mg
— triphosphate with long lifetime 8 mg.
3. Mercury in straight fluorescent lamps for special purposes.
4. Mercury in other lamps not specifically mentioned in this Annex.
5. Lead in glass of cathode ray tubes, electronic components and fluorescent tubes.
6. Lead as an alloying element in steel containing up to 0,35 % lead by weight, aluminium
containing up to 0,4 % lead by weight and as a copper alloy containing up to 4 % lead by weight.
7. — Lead in high melting temperature type solders (i.e. lead-based alloys containing 85 % by
weight or more lead),
— lead in solders for servers, storage and storage array systems, network infrastructure equipment
for switching, signalling, transmission as well as network management for telecommunications,
— lead in electronic ceramic parts (e.g. piezoelectronic devices)
8. Cadmium and its compounds in electrical contacts and cadmium plating except for applications
banned under Directive 91/338/EEC (*) amending Directive 76/769/EEC (**) relating to restrictions
on the marketing and use of certain dangerous substances and preparations.
9. Hexavalent chromium as an anti-corrosion of the carbon steel cooling system in absorption
refrigerators.
9a. DecaBDE in polymeric applications. (Flextronics bans without exemption)
9b. Lead in lead-bronze bearing shells and bushes.
11. Lead used in compliant pin connector systems.
12. Lead as a coating material for the thermal conduction module c-ring.
13. Lead and cadmium in optical and filter glass.
14. Lead in solders consisting of more than two elements for the connection between the pins and
the package of microprocessors with a lead content of more than 80 % and less than 85 % by
weight.
15. Lead in solders to complete a viable electrical connection between semiconductor die and
carrier within integrated circuit Flip Chip packages.
16. Lead in linear incandescent lamps with silicate coated tubes.
17. Lead halide as radiant agent in High Intensity Discharge (HID) lamps used for professional
reprography applications.
18. Lead as activator in the fluorescent powder (1 % lead by weight or less) of discharge lamps
when used as sun tanning lamps containing phosphors such as BSP (BaSi2O5:Pb) as well as
when used as specialty lamps for diazo-printing reprography, lithography, insect traps,
photochemical and curing processes containing phosphors such as SMS ((Sr,Ba)2MgSi2O7:Pb).
19. Lead with PbBiSn-Hg and PbInSn-Hg in specific compositions as main amalgam and with
PbSn-Hg as auxiliary amalgam in very compact Energy Saving Lamps (ESL).
20. Lead oxide in glass used for bonding front and rear substrates of flat fluorescent lamps used for
Liquid Crystal Displays (LCD).
21. Lead and cadmium in printing inks for the application of enamels on borosilicate glass.
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
10 of 22
22. Lead as impurity in RIG (rare earth iron garnet) Faraday rotators used for fibre optic
communications systems.
23. Lead in finishes of fine pitch components other than connectors with a pitch of 0.65 mm or less
with NiFe lead frames and lead in finishes of fine pitch components other than connectors with a
pitch of 0.65 mm or less with copper lead frames.
24. Lead in solders for the soldering to machined through hole discoidal and planar array ceramic
multilayer capacitors.
25. Lead oxide in plasma display panels (PDP) and surface conduction electron emitter displays
(SED) used in structural elements; notably in the front and rear glass dielectric layer, the bus
electrode, the black stripe, the address electrode, the barrier ribs, the seal frit and frit ring as well as
in print pastes.
26. Lead oxide in the glass envelope of Black Light Blue (BLB) lamps.
27. Lead alloys as solder for transducers used in high-powered (designated to operate for several
hours at acoustic powerlevels of 125 dB SPL and above) loudspeakers.
28. Hexavalent chromium in corrosion preventive coatings of unpainted metal sheetings and
fasteners used for corrosion protection and Electromagnetic Interference Shielding in equipment
falling under category three of Directive 2002/96/EC (IT and telecommunications equipment).
Exemption granted until 1 July 2007. (Flextronics bans without exemption)
29. Lead bound in crystal glass as defined in Annex I (Categories 1, 2, 3 and 4) of Council Directive
69/493/EEC
Reportable substances
Flextronics may require additional reporting on certain substances, when ever level 2 data is
required.
Examples of these are:
1. Substances and compounds containing Halogens:
Chlorine and Bromine compounds
Halogenated Dioxins and Furans and Other Halogenated Hydrocarbon compounds, including
HFCs, and PFCs
2. Precious materials/substances that provide economic value for end-of-life management purposes
Copper, Gold, Magnesium, Palladium, Selenium, Silver, Nickel, Aluminum, Manganese, Iron and
other Ferous compounds, Tin, Zinc, Barium, Chromium (III), Cobalt, Molybdenum, Tantalum,
Tellurium, Thallium, Zirconium, Vanadium, Niobium, Tungsten, Platinum, Gallium, Indium
3. Materials/substances that are of significant environmental, health, or safety interest or could have
a negative impact on end-of-life management
Antimony, Arsenic, Beryllium, Amines, Bismuth, Boron Naphthalene and Naphthalene compounds,
including Creosotes, Aromatic compounds and Monomers, Sulfur/Sulfide, Phosphorous, Small
Fibers (5 micron or less diameter; length diameter ratio greater than 3:1)
4. Compounds and materials that affects to products recyclability:
Glass, Plastic (Thermopolymer/Thermoset materials), Polymers, Ceramics, Silicon Compounds
(including Ferrosilicon compounds), Organic/Inorganic Oils, other Organic and Inorganic
Compounds Titanium, Paper, Cyanide,
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
11 of 22
Table 2 - Banned substances in Product Packaging
Product packaging must be free from the above-mentioned substances including:
PPM
Threshold
Total
amount
100
Substance
Cadmium,
Mercury,
Lead,
Chromium VI
Chlorofluorocarbons (CFCs)
Hydrochlorofluorocarbons (HCFCs)
Hydrofluorocarbons (HFCs)
banned
banned
banned
Application
Inks
Reason
Reference
For packaging, the
sum of the
concentrations of the
listed substances on
component level may
not exceed 100 ppm.
94/62/EEC
EPS
EPS
EPS
Table 3 - Banned substances in Batteries
Batteries must be free from the above-mentioned substances including:
Substance
Threshold
Application
Mercury and –
compounds
CAS - no ( Table F )
5 ppm
Batteries and
accumulators
Mercury and –
compounds
CAS - no ( Table F )
2%
Button cells
and batteries
composed of
button
cells
0.025%
Batteries and
accumulators
Lead and –compounds
CAS – no (Table E)
0.4%
Batteries and
accumulators
Perchlorate
CAS – no 14797-73-0
PFC (Phosphine,
(fluoromethylidyne)
CAS – no 65756-42-5
6ppb
CR Batteries
Cadmium and –
compounds
CAS – no (Table C)
Comment
Mercury and its
compounds. Acutely and
chronically (very) toxic,
accumulate in organisms
Mercury and its
compounds. Acutely and
chronically (very) toxic,
accumulate in organisms
Toxic, some compounds
(cadmium chloride,
cadmium oxide and
cadmium sulfate) are
carcinogenic
Teratogenic
Bioaccumulative
, It is not restricted but
only needs to be labeled.
Legal
Regulations
98/101/EC
91/157/EEC
98/101/EC
91/157/EEC
98/101/EC
91/157/EEC
98/101/EC
91/157/EEC
California
Code
of
Regulations,
title
22,
division 4.5:
Chapter 33 –
Best
Management
Practices for
Perchlorate
Materials.
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
12 of 22
Appendix A
These lists are not comprehensive; they represent examples of chemicals with
known CAS numbers.
Where a product or sub-part contains related substance and meet reporting
criteria, this information should be reported.
Table A – Asbestos and Asbestos Materials
Substance
CAS #
Asbestos and Asbestos Materials
1332-21-4
Actinolite
77536-66-4
Amosite (Grunerite)
12172-73-5
Anthophyllite
77536-67-5
Chrysotile
12001-29-5
Crocidolite
12001-28-4
Tremolite
77536-68-6
Table B – Azo-based dyes and colorants
Substance
4-Aminobiphenyl
Benzidine
4-Chloro-o-toluidine
2-Naphthylamine
o-Aminoazotoluene
5-Nitro-o-toluidine
4-Chloroaniline
4-methoxy-m-phenylenediamine
4,4.-Diaminodipheylmethane
3,3.-Dichlorobenzidine
3,3.-Dimethoxybenzidine
3,3.-Dimethylbenzidine
4,4.-methylenedi-o-toluididne
p-Cresidine
4,4.-Methylene-bis-(2-chloro-anilene)
4,4.-Oxydianilene
4,4.-Thiodianiline
o-Toluidine
4-Methyl-m-phenylenediamine
2,4,5-Trimethylaniline
o-Anisidine
4-amino azobenzene
CAS #
92-67-1
92-87-5
95-69-2
91-59-8
97-56-3
99-55-8
106-47-8
615-05-4
101-77-9
91-94-1
119-90-4
119-93-7
838-88-0
120-71-8
101-14-4
101-80-4
139-65-1
95-53-4
95-80-7
137-17-7
90-04-0
60-09-03
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
13 of 22
Table C – Cadmium and Cadmium compounds
Substance
Cadmium
Cadmium oxide
Cadmium sulfide
Cadmium chloride
Cadmium sulfate
Other cadmium compounds
CAS #
7440-43-9
1306-19-0
1306-23-6
10108-64-2
10124-36-4
--
Table D – Chromium VI and Chromium Compounds
Substance
Chromium
Chromium (VI) oxide
Barium chromate
Calcium chromate
Chromic acetate
Chromium trioxide
Lead (II) chromate
Sodium chromate
Sodium dichromate
Strontium chromate
Potassium dichromate
Potassium chromate
Zinc chromate
Chromium dichloride dioxide
Chromium VI ion
CAS #
7440-47-3
1333-82-0
10294-40-3
13765-19-0
1066-30-4
1333-82-0
7758-97-6
7775-11-3
10588-01-9
7789-06-2
7778-50-9
7789-00-6
13530-65-9
14977-61-8
18540-29-9
Table E – Lead and Lead Compounds
Substance
Lead
Lead (II) sulfate
Lead (II) carbonate
Lead hydrocarbonate
Lead acetate
Lead (II) acetate, trihydrate
Lead phosphate
Lead selenide
Lead (IV) oxide
Lead (II,IV) oxide
Lead (II) sulfide
Lead (II) oxide
CAS #
7439-92-1
7446-14-2
598-63-0
1319-46-6
301-04-2
6080-56-4
7446-27-7
12069-00-0
1309-60-0
1314-41-6
1314-87-0
1317-36-8
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
14 of 22
Lead (II) carbonate basic
Lead hydroxidcarbonate
Lead (II) phosphate
Lead (II) chromate
Lead (II) titanate
Lead sulfate, sulphuric acid, lead salt
Lead sulphate, tribasic
Lead stearate
1319-46-6
1344-36-1
7446-27-2
7758-97-6
12060-00-3
15739-80-7
12202-17-4
1072-35-1
Reference : Specification for Procurement of Lead(Pb) Free Electronic and
Electromechanical Components and Assemblies “.FBP-RHS002
Table F – Mercury and Mercury compounds
Substance
Mercury
Mercuric chloride
Mercury (II) chloride
Mercuric sulfate
Mercuric nitrate
Mercuric (II) oxide
Mercuric sulfide
Table G – Ozone Depleting Substances
Substance
Trichlorofluoromethane (CFC 11)
Dichlorodifluoromethane (CFC12)
Chlorotrifluoromethane (CFC 13)
Pentachlorofluoroethane (CFC 111)
Tetrachlorodifluoroethane (CFC 112)
Trichlorotrifluoroethane (CFC 113)
1,1,2 Trichlorotrifluoroethane
Dichlorotetrafluoroethane (CFC 114)
Monochloropentafluoroethane (CFC 115)
Heptachlorofluoropropane (CFC 211)
Hexachlorodifluoropropane (CFC 212)
Pentachlorotrifluoropropane (CFC 213)
Tetrachlorotetrafluoropropane (CFC 214)
1,1,1,3-Tetrachlorotetrafluoropropane
Trichloropentafluoropropane (CFC 215)
CAS #
7439-97-6
33631-63-9
7487-94-7
7783-35-9
10045-94-0
21908-53-2
1344-48-5
CAS #
75-69-4
75-71-8
75-72-9
354-56-3
76-12-0
354-58-5
76-13-1
76-14-2
76-15-3
422-78-6
135401-87-5
3182-26-1
2354-06-5
134237-31-3
29255-31-0
2268-46-4
1599-41-3
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
15 of 22
1,1,1-Trichloropentafluoropropane
1,2,3-Trichloropentafluoropropane
Dichlorohexafluoropropane (CFC 216)
Monochloroheptafluoropropane (CFC 217)
Bromochlorodifluoromethane (Halon 1211)
Bromotrifluoromethane (Halon 1301)
Dibromotetrafluoroethane (Halon 2402)
Carbon Tetrachloride (Tetrachloromethane)
1,1,1, - Trichloroethane (methyl chloroform) and its
isomers except 1,1,2-trichloroethane
Bromomethane (Methyl Bromide)
Bromodifluoromethane and isomers (HBFC.s)
Dichloroethane
1.1.1.2 Tetrachloroethane
Pentachloroethane
Methylene chloride
1.1.2 Trichloroethane
Trichloromethane (Chloroform)
Trichloroethylene
1.1.2.2 Tetrachloroethane
4259-43-2
76-17-5
661-97-2
422-86-6
353-59-3
75-63-8
124-73-2
56-23-5
71-55-6
74-83-9
1511-62-2
107-06-2
630-20-6
76-01-7
75-09-2
79-00-5
67-66-3
79-01-6
79-34-5
Note
These materials may contain isomers that are not listed here.
Table H - Ozone Depleting Substances - Hydrochlorofluorocarbons(HCFCs) / Isomers
Substance
Dichlorofluoromethane (HCFC 21)
Chlorodifluoromethane (HCFC 22)
Chlorofluoromethane (HCFC 31)
Tetrachlorofluoroethane (HCFC 121)
1,1,1,2-tetrachloro-2-fluoroethane (HCFC 121a)
1,1,2,2-tetracloro-1-fluoroethane
Trichlorodifluoroethane (HCFC 122)
1,2,2-trichloro-1,1-difluoroethane
Dichlorotrifluoroethane(HCFC 123)
Dichloro-1,1,2-trifluoroethane
2,2-dichloro-1,1,1-trifluroethane
1,2-dichloro-1,1,2-trifluroethane (HCFC-123a)
1,1-dichloro-1,2,2-trifluroethane (HCFC-123b)
2,2-dichloro-1,1,2-trifluroethane (HCFC-123b)
Chlorotetrafluoroethane (HCFC 124)
2-chloro-1,1,1,2-tetrafluoroethane
CAS #
75-43-4
75-45-6
593-70-4
134237-32-4
354-11-0
354-14-3
41834-16-6
354-21-2
34077-87-7
90454-18-5
306-83-2
354-23-4
812-04-4
812-04-4
63938-10-3
2837-89-0
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
16 of 22
1-chloro-1,1,2,2-tetrafluoroethane (HCFC 124a)
Trichlorofluoroethane (HCFC 131)
1-Fluoro-1,2,2-trichloroethane
1,1,1-trichloro-2-fluoroethane (HCFC131b)
Dichlorodifluoroethane (HCFC 132)
1,2-dichloro-1,1-difluoroethane (HCFC 132b)
1,1-dichloro-1,2-difluoroethane (HFCF 132c)
1,1-dichloro-2,2-difluoroethane
1,2-dichloro-1,2-difluoroethane
Chlorotrifluoroethane (HCFC 133)
1-chloro-1,2,2-trifluoroethane
2-chloro-1,1,1-trifluoroethane (HCFC-133a)
Dichlorofluoroethane(HCFC 141)
1,1-dichloro-1-fluoroethane (HCFC-141b)
1,2-dichloro-1-fluoroethane
Chlorodifluoroethane (HCFC 142)
1-chloro-1,1-difluoroethane (HCFC142b)
1-chloro-1,2-difluoroethane (HCFC142a)
Hexachlorofluoropropane (HCFC 221)
Pentachlorodifluoropropane (HCFC 222)
Tetrachlorotrifluropropane (HCFC 223)
Trichlorotetrafluoropropane (HCFC 224)
Dichloropentafluoropropane, (Ethyne, fluoro-)
(HCFC 225)
2,2-Dichloro-1,1,1,3,3-pentafluoropropane(HCFC
225aa)
2,3-Dichloro-1,1,1,2,3-pentafluoropropane (HCFC
225ba)
1,2-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC
225bb)
3,3-Dichloro-1,1,1,2,2-pentafluoropropane (HCFC
225ca)
1,3-Dichloro-1,1,2,2,3-pentafluoropropane (HCFC
225cb)
1,1-Dichloro-1,2,2,3,3-pentafluoropropane(HCFC
225cc)
1,2-Dichloro-1,1,3,3,3-pentafluoropropane (HCFC
225da)
1,3-Dichloro-1,1,2,3,3-pentafluoropropane (HCFC
225ea)
1,1-Dichloro-1,2,3,3,3-pentafluoropropane(HCFC
225eb)
354-25-6
27154-33-2;(134237-34-6)
359-28-4
811-95-0
25915-78-0
1649-08-7
1842-05-3
471-43-2
431-06-1
1330-45-6
1330-45-6
75-88-7
1717-00-6; (25167-88-8)
1717-00-6
430-57-9
25497-29-4
75-68-3
25497-29-4
134237-35-7
134237-36-8
134237-37-9
134237-38-0
127564-92-5; (2713-09-9)
128903-21-9
422-48-0
422-44-6
422-56-0
507-55-1
13474-88-9
431-86-7
136013-79-1
111512-56-2
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
17 of 22
Chlorohexafluoropropane (HCFC 226)
Pentachlorofluoropropane (HCFC 231)
Tetrachlorodifluoropropane (HCFC 232)
Trichlorotrifluoropropane (HCFC 233)
1,1,1-Trichloro-3,3,3-trifluoropropane
Dichlorotetrafluoropropane (HCFC 234)
Chloropentafluoropropane (HCFC 235)
1-Chloro-1,1,3,3,3-pentafluoropropane
Tetrachlorofluoropropane (HCFC 241)
Trichlorodifluoropropane (HCFC 242)
Dichlorotrifluoropropane (HCFC 243)
1,1-dichloro-1,2,2-trifluoropropane
2,3-dichloro-1,1,1-trifluoropropane
3,3-Dichloro-1,1,1-trifluoropropane
Chlorotetrafluoropropane (HCFC 244)
3-chloro-1,1,2,2-tetrafluoropropane
Trichlorofluoropropane (HCFC 251)
1,1,3-trichloro-1-fluoropropane
Dichlorodifluoropropane (HCFC 252)
Chlorotrifluoropropane (HCFC 253)
3-chloro-1,1,1-trifluoropropane (HCFC 253fb)
Dichlorofluoropropane (HCFC 261)
1,1-dichloro-1-fluoropropane
Chlorodifluoropropane (HCFC 262)
2-chloro-1,3-difluoropropane
Chlorofluoropropane (HCFC 271)
2-chloro-2-fluoropropane
Note
134308-72-8
134190-48-0
134237-39-1
134237-40-4
7125-83-9
127564-83-4
134237-41-5
460-92-4
134190-49-1
134237-42-6
134237-43-7
7125-99-7
338-75-0
460-69-5
134190-50-4
679-85-6
134190-51-5
818-99-5
134190-52-6
134237-44-8
460-35-5
134237-45-9
7799-56-6
134190-53-7
102738-79-4
134190-54-8
420-44-0
These materials may contain isomers that are not listed here.
Table I - Polybrominated Biphenyls (PBBs) their Ethers (PBDEs, PBBEs) and
their Oxides (PBBOs)
Substance
CAS #
Bromobiphenyl and its ethers
2052-07-5 (2-Bromobiphenyl)
2113-57-7 (3-Bromobiphenyl
92-66-0 (4-Bromobiphenyl)
101-55-3 (ether)
Decabromobiphenyl and its ethers
13654-09-6
1163-19-5 (ether)
Dibromobiphenyl and its ethers
92-86-4
2050-47-7 (ether)
Heptabromobiphenylether
68928-80-3
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
18 of 22
Hexabromobiphenyl and its ethers
Nonabromobiphenylether
Octabromobiphenyl and its ethers
Pentabromobidphenyl ether (PeBDPO)
Polybrominated Biphenyls
Tetrabromobiphenyl and its ethers
Tribromobiphenyl ether
59080-40-9
36355-01-8 (hexabromo-1,1.biphenyl)
67774-32-7 (Firemaster FF-1)
36483-60-0 (ether)
63936-56-1
61288-13-9
32536-52-0 (ether)
32534-81-9
59536-65-1
40088-45-7
40088-47-9 (ether)
49690-94-0
Table J – Polychlorinated Biphenyls (PCBs) and Terphenyls (PCTs)
Substance
CAS #
Polychlorinated Biphenyls
1336-36-3
Aroclor
12767-79-2
Chlorodiphenyl (Aroclor 1260)
11096-82-5
Kanechlor 500
27323-18-8
Aroclor 1254
11097-69-1
Terphenyls
26140-60-3
61788-33-8
Table K – Radioactive Substances
Substance
Uranium
Plutonium
Radon
Americium
Thorium
Cesium
Strontium
Other radioactive substances
CAS #
-----7440-46-2
7440-24-6
-
Table L – Shortchain Chlorinated paraffin
Substance
CAS #
Chlorinated paraffin (Paraffin wax,
63449-39-8
chlorinated; Paraffin waxes and
8029-39-8
Hydrocarbon waxes, chlorinated;
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
19 of 22
Chlorinated paraffin; Chlorinated wax;
Chlorinated waxes; Chlorowax 40;
Chlorowax 500c;)
alkanes, C10-13, chloro
alkanes, C14-17, chloro
Naphthalene, chloro derives
(Naphthalene, chloro derivs.;
Naphthalene, polychlorinated)
85535-84-8
85535-85-9
70776-03-3
Table M - Tributyl Tin, Triphenyl Tin and oxides
Substance
CAS #
Bis(tri-n-butyltin) oxide
56-35-9
Triphenyltin N,N'1803-12-9
dimethyldithiocarbamate
Triphenyltin fluoride
379-52-2
Triphenyltin acetate
900-95-8
Triphenyltin chloride
639-58-7
Triphenyltin hydroxide
76-87-9
Triphenyltin fatty acid salts (C=9-11)
47672-31-1
Triphenyltin chloroacetate
7094-94-2
Tributyltin methacrylate
2155-70-6
Bis(tributyltin) fumarate
6454-35-9
Tributyltin fluoride
1983-10-4
Bis(tributyltin) 2,3-dibromosuccinate
31732-71-5
Tributyltin acetate
56-36-0
Tributyltin laurate
3090-36-6
Bis(tributyltin) phthalate
4782-29-0
Copolymer of alkyl acrylate, methyl
-N.A.
methacrylate and tributyltin
methacrylate(alkyl; C=8)
Tributyltin sulfamate
6517-25-5
Bis(tributyltin) maleate
14275-57-1
Tributyltin chloride
1461-22-9
Mixture of tributyltin
-N.A.
cyclopentanecarboxylate and its analogs
(Tributyltin naphthenate)
Mixture of tributyltin
-N.A.
1,2,3,4,4a,4b,5,6,10,10a-decahydro-7isopropyl-1,4a-dimethyl-1phenanthlenecarboxylate and its
Analogs (Tributyltin rosin salt)
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
20 of 22
Table N - Halogenated (Brominated and Chlorinated) Flame Retardants (other
than PBB or PBDE)
Substance
CAS #
TBBPA
Tetrabromo bisphenol-A
79-94-7
TBBPA
94334-64-2
TETRABROMOBISPHENOL A CARBONATE-OLIGOMERS
BRPS BROMINATED POLYSTYRENE
57137-10-7
TBPA TETRABROMOPHTHALIC ACID
632-79-1
ANHYDRIDE
TBPI N,N´ETHYLENE32588-76-4
BISTETRABROMOPHTHALIMIDE
Octabromodiphenyl
61288-13-9
Dibromo neopentyl glycol
3296-90-0
HBCD
25637-99-4
HEXABROMOCYCLODODECAN
E
Table M - Selenium and Selenium Compounds
Substance
CAS #
Selenium
7782-49-2
Hydrogen selenide
7783-07-5
Sodium selenide
1313-85-5
Selenium dioxide
7446-08-4
Sodium selenate
10112-94-4
Dimethyl selenide
593-79-3
Selenium oxide
12640-89-0
Table N Phtalates
Substance
CAS #
BUTYLBENZYLPHTHALATE (BBP)
85-68-7
DI(2-ETHYLHEXYL) PHTHALATE (DEHP) 117-81-7
DIBUTYLPHTHALATE (DBP)
84-74-2
DIETHYL PHTHALATE (DEP)
84-66-2
DIISODECYL PHTHALATE
68515-49-1
DIISODECYLPHTHALATE (DIDP)
26761-40-0
DIISONONYL PHTHALATE
68515-48-0
DIISONONYLPHTHALATE (DINP)
28553-12-0
DIMETHYL PHTHALATE (DMP)
131-11-3
N-DIOCTYL PHTHALATE (DNOP)
117-84-0
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
21 of 22
85-68-7
117-81-7
84-74-2
84-66-2
68515-49-1
26761-40-0
68515-48-0
28553-12-0
131-11-3
117-84-0
Table O - Ozone Depleting Substances - Hydrofluorocarbons(HFCs) / Isomers
Systematic name
Trifluoromethane
Difluoromethane
Fluoromethane
2-Chloro-1,1,1,2tetrafluoroethane
1,1,2,2,2pentafluoroethane
1,1,2,2-Tetrafluoroethane
1,1,1,2-Tetrafluoroethane
1,1-Difluoroethane
1,1,1,2,3,3,3Heptafluoropropane
HFC-23
HFC-32
HFC-41
Chemical
formula
CHF3
CH2F2
CH3F
HFC-124
CHFClCF3
HFC-125
HFC-134
HFC-134a, Suva-134a
HFC-152a
HFC-227ea, FE-227,
FM-200
CHF2CF3
F2HC-CHF2
F3C-CH2F
F2HC-CH3
Common Name
Fluoroform
Methyl fluoride
Pentafluoroethane
R-134a
-
Code
F3C-CHF-CF3
All printed copies of this Document are considered ‘Uncontrolled Copies’ and are only
considered valid for the day it is printed.
22 of 22