9G Environmental Chemistry Level by Level (1996 to 2006) Commentary Acid rain is the main event when you are planning delivery of this unit. A lesson on global warming might not go amiss (but has not yet been tested explicitly as far as I can tell). A good chance to revisit 7E Acids and Alkalis, and 9I Energy and Electricity. This is the distribution of questions/Levels (omitting questions which fit more naturally elsewhere : Level no. of qu.s 3 4 5 6 7 0 0 1 0 3 What are the implications for your planning? Level 5 1. Burning fossil fuels causes air pollution. (a) (i) Give the names of two fossil fuels. ....................................... and .............................................. 1 mark (ii) Some fossil fuels contain sulphur. Complete the word equation for the reaction between sulphur and oxygen in the air. sulphur + oxygen → ..........................................................1 mark (b) Burning fossil fuels leads to the formation of acid rain. Acid rain has collected in this lake. A helicopter is dropping calcium hydroxide into the lake. 1 Calcium hydroxide dissolves in water to form an alkaline solution. (i) What effect does an alkali have on the pH of an acidic lake? ..................................................................................................1 mark (ii) When calcium hydroxide reacts with sulphuric acid in the lake a calcium salt is formed. What is the name of this salt? Tick the correct box. calcium carbonate calcium chloride calcium nitrate calcium sulphate 1 mark (c) The photograph below shows trees damaged by acid rain. (i) The trees have lost their leaves and have died. Explain why leaves are needed for a tree to grow. ..............................................................................1 mark (ii)What effect does acid rain have on buildings made from limestone? ............................................................................1 mark maximum 6 marks 2 Level 7 2. The chemical name for pure limestone is calcium carbonate. When calcium carbonate is heated to a temperature above 825°C it produces calcium oxide and carbon dioxide. (a) Complete the symbol equation for this reaction. CaCO3 → .............................. + .............................. 2 marks (b) The photograph shows a limestone statue that has been changed by acid rain. Some gases which pollute the air dissolve in rainwater to form acids. (i) Give the name of a gas which dissolves in rainwater, leading to the formation of sulphuric acid. ....................................................................................................... ...... 1 mark (ii) Complete the word equation for the reaction between calcium carbonate and sulphuric acid. calcium + sulphuric → ........................... + ...........................+ water carbonate acid 2 marks maximum 5 marks 3 3. (a) Complete the word equation below for the reaction between calcium carbonate and hydrochloric acid. carbon calcium hydrochloric + → ................................... + + water dioxide carbonate acid 1 mark Limestone is mainly calcium carbonate. It is weathered by acids in the air or in soil. (b) In June 1990, a Year 9 class planned a long-term investigation into the chemical weathering of limestone by acids in soil. They put limestone chippings of similar size in three nylon mesh bags. They buried the bags outside in soils of different pH. (i) Chemical weathering took place in sample A, and the mass of the sample decreased. Give the reason for the decrease in mass. Use the word equation above to help you. .........................................................................................1 mark (ii) The pupils predicted that chemical weathering would not take place in samples B and C. Give the reason for their prediction. ........................................................................................1 mark (iii) Some chemical weathering did take place in samples B and C. What could have changed the conditions in these soils to cause weathering to take place? ........................................................................................1 mark 4 (c) The table shows how the mass of each sample changed between the years 1990 and 2000. year sample A, at pH 5 mass, in g sample B, at pH 7 1990 1000 1000 1000 1995 980 992 997 2000 960 984 995 sample C, at pH 8 In 2000, a year 9 class buried another identical 1000 g sample of limestone chippings in soil of pH 6. (i) Use the results in the table to predict an approximate value for the mass of this sample in 2010. ................. g 1 mark (ii) Why is it not possible to be certain what the mass of this sample will be in 2010? ............................................................................................1 mark Maximum 6 marks 4. This table shows where different pollutants in the air come from. source of pollutants percentage from power stations percentage from road traffic percentage from other sources sulphur dioxide 72 2 26 nitrogen oxides 28 51 21 smoke 6 46 48 carbon monoxide 1 90 9 pollutants 5 (a) Which two pollutants in the table above cause acid rain? 1. .......................................................................................................... 2. ......................................................................................................... 2 marks (b) Lichens are organisms which grow on buildings and trees. They are affected by some pollutants. Use the information in the table to suggest why few lichens survive close to power stations but many survive alongside roads. ................................................................................................1 mark (c) The two products of complete combustion of petrol are not shown in the table. Give the names of the two products of complete combustion of a fuel such as petrol. 1. ................................................................................................. 2. ................................................................................................ 2 marks (d) Smoke contains particles of carbon. These can burn when there is enough oxygen present. Write a word equation for the reaction of carbon with excess oxygen. ................................................................................................1 mark (e) Which term best describes the combustion process? Tick one box. decomposition oxidation pollution respiration 1 mark Maximum 7 marks 6
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