The Maharaja Sayajirao University of Baroda
Polytechnic
Department of Petrochemical Technology
Polytechnic, Near Shastri Bridge, Fatehgunj,Vadodara-2
0265-2781983, , www.msubaroda.ac.in
ACADEMIC
YEAR
2012-2013
Diploma : Full Time (Regular)
YEAR
II
Semester
II
CHL3404: Physical and analytical chemistry
IA
UA
HOURS
20
80
56
COURSE CONTENT / SYLLABUS
State of matter
Solid Liquid & Gas their properties – Physical properties of liquids types of
physical properties & characteristics of each properly. Definition of surface
UNIT-I
tension, refractive Index, Molar refraction ,specific refraction viscosity
,Molecular viscosity ,surface tension & Viscosity measurement methods,
Ostwald Viscosity, stalagmometer
General Gas Laws & Atomic Theory
UNIT-II Kinetic theory of gases. Deviation from gas Law, Reduced Vander waal's
equation of state, Critical properties, Phenomenon of liquefaction of gases
Ionic equilibria
UNIT-III Introduction sparingly soluble salts, Acids & Bases Hydrolysis, Hydrolysis
constant, Buffer Solution, Acid base titrations
Colloids & Emulsion
Colloids & its various aspects, characteristics of true solutions, suspension &
colloidal solution. Classification of colloids difference between Lyophobic,
Lyophillic solutions methods, preparation of colloidal solutions, condensation &
UNIT-IV dispersion methods, purification of colloidal solution, Dialysis ultra filtration,
properties of colloidal solution, scattering of light colour charge, Electro osmosis
protection, Brownian movement, electrophoresis co-agitation. Phenomenon of
emulsion. Definition of Emulsion, types of cleansing action of soap, Advantages
of synthetic detergent over alkali Soap, properties & utility of gels
Adsorption
UNIT-V Langmuir's adsorption theorem Gibbs adsorption equation, solid liquid, Liquid –
liquid interfaces
Chemical Thermodynamics
Systems, State & state functions, work & heat, First law of thermodynamics,
UNIT-VI Thermo chemistry, Entropy & free energy, Gibbs-Helmholtz, Clapeyron
Equation, Isotherm & Isochore, standard free Energy & its utility Free energy,
Temp. Dependence of equilibria
Chemical Kinetics
UNIT-VII Classification of reactions. Reaction mechanisms Concentration effect temp.
effect, reaction Velocity order of reaction, expression & Determination
Electrometric– methods of analysis
Electrode types of electrode distinguish between Inert electrode working
UNIT-IX electrode reference electrode various electrometric methods. pH metry definition
of pH, POH & their relationship, std oxidation potential functions of hydrogen
electrode calomel electrode, glass Electrode Ag/AgCl/KCl electrode
4 hrs
3 hrs
6hrs
9 hrs
4 hrs
10 hrs
7 hrs
9 hrs
quinhydrone, Electrode. Problems of pH & POH calculation, Methods of
determining pH by pH meter, by pH indicator, By potentiometer methods.
Conductometery; definition of conductivity, Galvanic cell, concentration cell,
specific, Conductance, cell constant, equivalent Conductance, molecular
conductance, Conductivity of water. Conductometry titrations, acid base
titration, Precipitation titration replacement titrations. Chromatography– Thin –
layer Chromatography, Ion exchange, column chromatography, Paper
chromatography.
Qualitative & quantitative analysis:
4 hrs
UNIT-X Common ion effect, Ionic product, solubility, solubility product, use of H2 &
NH4Cl in qualitative inorganic analysis.
REFERENCES
1. Unit Operation Vol.I By K.A.Gavhane
2. Mass transfer Operations – Robert E Treybal