Chemistry 1403 CRN: 10022 General Chemistry II Spring 2014 SECTION: 40 Instructor: Dr. Robert E. Belford Office: SCLB 277 Email: [email protected] WEB PAGE: www.ualr.edu/rebelford Office Phone: 569-8824 Lecture: M,W 6:00-7:15 PM, FH 102 Text: Chemistry& Chemical Reactivity, 7th ed., Kotz, Treichel & Townsend, Thomson Books Brooks/Cole, 2009. Handouts in Class Office Hours: M,W,F: 9:00-9:50 AM and by appointment I will try and hold open office hours and you are welcome to drop by anytime. My office is around the corner from the SCLB 263 departmental computing lab, and if I am busy you can let me know you need help and then go study in the computing lab. I'll drop by as soon as I am free. Chemistry Computer Laboratory: SCLB 263 This is an open computer lab where you can access any of the WEB based assignments and tutorials. Tutoring: To be announced Class Bulletin Board: Outside SCLB 277 keys to exams and quizzes will be posted. Attendance: Attendance is required. There will be announced and unannounced quizzes. Absence during a quiz equates to a zero score. If you miss three labs periods, you get an F for this course (see lab syllabus). Lecture: Read the text assignments before the class period. The lecture will be used to cover expected competencies with respect to the subject material and should provide an efficient study guide. Coming to lecture is necessary, but not sufficient with respect to getting a passing grade. You must study outside of lecture. 1 Grade Calculation: Attendance 4 Exams & Quizzes Comprehensive Final Lab Total Final grade Distributions: 05 pts 50 pts 20 pts 25 pts 100 pts 90-100 pts 80-89 pts 70-79 pts 60-69 pts 0 - 59 pts A B C D F There will be NO MAKEUP EXAMS or QUIZZES. If your final exam score (on a 100% basis) is higher than your lowest exam, its grade will be substituted for that grade. In the event that you miss an exam, that exam will be considered your lowest exam score and your final will be substituted for that grade. All quizzes and exams will be closed book and closed notes. You will not be allowed to use programmable calculators and students may not share calculators during quizzes or exams. Cell Phones must be turned off and out-of-sight during exams. Cheating is strictly forbidden. The last day to withdraw from this course is April 16. Final Exam is 8:00-10:00 AM Wednesday, May 9 Your success in this class is important to me, and it is the policy and practice of the University of Arkansas at Little Rock to create inclusive learning environments consistent with federal and state law. If you have a documented disability (or need to have a disability documented), and need an accommodation, please contact me privately as soon as possible, so that we can discuss with the Disability Resource Center (DRC) how to meet your specific needs and the requirements of the course. The DRC offers resources and coordinates reasonable accommodations for students with disabilities. Reasonable accommodations are established through an interactive process among you, your instructor(s) and the DRC. Thus, if you have a disability, please contact me and/or the DRC, at 501-569-3143 (V/TTY) or 501-683-7629 (VP). For more information, please visit the DRC website at www.ualr.edu/disability. 2 Chem 1403 Date Jan Feb _ _ _ April Tentative Lecture Schedule Spring 2012 Text & Topics Introduction and Review 8.2-8.8, 9.2: Lewis Dot Structures, Molecular Shapes and Molecular Polarity 15 Review: 12.1-12.4 Intermolecular Forces and Properties of Liquids 20 MLK Holiday 22 12.4: Finish chapter 12 13.1-13.2: Crystal Lattices Plagiarism Assignment Due for Extra Credit due in class for credit Chapter 13 1st Draft Extra Credit Definition Due by midnight Jan 22 27 13.3-13.6: Solids and Phase Diagrams 29 14.2: Solvation Processes and Henry’s Law Chapter 14 1st Draft Definition Extra Credit Due by midnight Jan. 29 Note: 14.1 is not covered in lecture but Lab Experiment 2A 14.3-14.5: Colligative Properties and Collids 03 Review/Catchup 05 Exam 1 (Chapters 8,9,12 & 14) Chapter 13 & 14 Final Draft Extra Credit Due by Midnight Feb 06 10 15.1-15.4: Introduction to Kinetics & Differential Rate Laws Chapter 15 1st Draft Extra Credit Definition Due by midnight Feb. 11 12 15.4-15.5, 23.4: Integrated Rate Laws, Arrhenius Eq. & Half Lifes 17 15.5 Arrhenius Eq & Catalysts and Reaction Mechanisms 19 16.1-16.3: Equilibria, Equilibrium Constants and Reaction Quotients Chapter 16 1st Draft Extra Credit Definition Due by midnight Feb. 19 24 16.3-16.4 Equilibrium Calculations: LeChatlier's Principle 26 16.4-16.5 More Equilibrium Calculations & Le Chatlier’s Principle 03 Exam 2(Chapters 15 & 16) Chapter 15 & 16 Final Draft Extra Credit Due by Midnight March 4 05 17.1-17.4 Acid & Bases, pH Scale, Bronstead Lowry Acids & Bases Chapter 17 1st Draft Definition Due by midnight Mar. 5 17.4-17-6 Acid/Base Properties of Salts, Product/Reactant Favored Systems and _ Types of Acid/Base Reactions 10 17.7 Acid Base Calculations 12 17.8-17.9 PolyProtic Acid/Base Reactions and Lewis Acid/Bases 17.10 Acid Bases and Molecular Structure 17 18.1-2 Common Ion Effect & Buffers Chapter 18 1st Draft Definition Due by midnight Mar. 25 19 LAST DAY TO WITHDRAW 18.3: Acid Base Titrations 24/26 Spring Break 31 18.4: Solubility of Salts 02 18.5 Precipitation Reactions 18.6 Solubility and Complex Ions 07 Exam 3 (Chapters 17 & 18) Chapter 17 & 18 Final Draft Extra Credit Due by Midnight April 9 09 19.1-19.3 Entropy, Spontaneity and Second Law of Thermodynamics Chapter 19 1st Draft Definition Due by midnight April 10 19.4-19.5 More Entropy, Spontaneity and Third Law of Thermodynamics 14 19.6-19.7 Gibbs Free Energy & K 16 20.1 Balancing Oxidation-Reduction Reactions 13 3 21 23 28 30 06 May 07 13 Chapter 20 1st Draft Definition Due by midnight April 17 20.2-3 Galvanic Cells 20.4 Standard Reduction Potentials 20.5-6: Electrochemistry, Thermodynamics and Nernst Eq. 20.7-20.8 Electrolysis and Stoichiometry 22.3-4: Coordination Compounds 22.4: Coordination Compounds and Isomers Exam 4: Chapter 17 & 18 Final Draft Extra Credit Due by Midnight May 4 23.1-23.2, 23.5 Review of Nuclear Chemistry from Gen. Chem I FINAL EXAM (6:00-8:00 PM) Suggested Problems from Text (These will not be graded or collected) Be Sure to do the Interactive Quizzes http://www.ualr.edu/rebelford/chem1403/q1403/chem1403QP.htm Exam 1 Chp. 8: Chp. 9: Chp .12: Chp. 13: Chp. 14: 5,7,11,17,19,21,23,27,37,39 1,3,5,7 1,5,7,11,13,15,17,19,23,25,29,39,41,43,47,49, 7,21,23,27,29, 1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,35,37,39,41,43,45,47,51,53,55,57, 59,61,63,65,67,73,75,79 Exam 2 Chp. 15: 1,3,5,7,9,11,,13,15,17,19,21,25,,27,29,31,33,35,37,39,41,43,45,49,51,53,55, 57,59,61,63,65,75,77,79,83, Chp. 23: 29,31,33,37, Chp. 16: 1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,33,37,39,41,43,45,47,49,53,55,57 Exam 3 Chp. 17: 1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,33,35,37,39,41,43,45,47,49,51,53, 55,57,59,61,63,65,67,69,71,73,75,77,79,83,85,87,89,91,93,95,113 Chp. 18: 1,3,5,7,9,11,13,15,17,19,21,23,25,27,29,31,33,35,37,39,41,43,45,47,49,51,53, 55,59,61,63,67,69,71,73,77,79,83,85 Exam 4 Chp. 19: 1,3,5,7,15,17,19,21,25,27,27,29,31,33,35,37,,39,41,43,45,47,49,51,53,57, 61,67,69,75,79 Chp. 20: 1,3,5,7,9,13,15,17,19,21,23,25,27,29,31,33,35,37,43,45,47,49,51,53,57,59, 63,87,89 Chp. 22: 7,9,11,19,21,41 Chp. 23: 11,13,35 4
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