Common Ions Note that there are patterns. Flash cards help. Please know formulas, names, charges. In formulas, the cation is listed first, followed by the anion. In names, the cation precedes the anion. 1 1A 1 H All monatomic ions formed by main group elements in columns 1A, 2A, and 7A Nonmetals in groups 5A and 6A; Al3+ in group 3A Cations: “metal name ion” charge = A column number “nonmetal root – ide” ion charge = 8 – A column number Anions: NH4+ ammonium ion OH- hydroxide C2H3O2- acetate NO3NO2- nitrate nitrite SO42SO32- sulfate sulfite HSO4HSO3- hydrogen sulfate hydrogen sulfite Cu+ Cu2+ Hg22+ Hg2+ Fe2+ Fe3+ copper (I) copper (II) mercury (I) mercury (II) iron (II) iron (III) Sn2+ tin (II) Sn4+ tin (IV) Pb2+ lead (II) Pb4+ lead (IV) CO32HCO3PO43PO33- carbonate hydrogen carbonate phosphate phosphite HPO42HPO32H2PO4H2PO3- hydrogen phosphate hydrogen phosphite dihydrogen phosphate dihydrogen phosphite 18 8A 2 He 2 2A 13 3A 14 4A 15 5A 16 6A 17 7A +1, -1 3 Li 4 Be 5 B 6 C 7 N 8 O 9 F 10 Ne +1 11 Na +2 12 Mg 13 Al 14 Si -3 15 P -2 16 S -1 17 Cl 18 Ar +1 19 K +2 20 Ca +3 31 Ga 32 Ge -3 33 As -2 34 Se -1 35 Br 36 Kr +1 37 Rb +2 38 Sr 49 In 50 Sn 51 Sb -2 52 Te -1 53 I 54 Xe +1 55 Cs +2 56 Ba +1, +3 81 Tl +2, +4 82 Pb 83 Bi 84 Po -1 85 At 86 Rn +1 87 Fr +2 88 Ra +1, +3 113 Uut +2, +4 114 Uuq 115 Uup 116 Uuh -1 117 Uus 118 Uuo +1 +2 3 3B 4 4B 5 5B 6 6B 7 7B 8 8B 9 8B 10 8B 11 1B 12 2B 21 Sc 22 Ti 23 V 24 Cr 25 Mn 26 Fe 27 Co 28 Ni 29 Cu 30 Zn 39 Y 40 Zr >1 41 Nb >1 42 Mo >1 43 Tc +2, +3 44 Ru >1 45 Rh +2 46 Pd +1, +2 47 Ag +2 48 Cd 71 Lu 72 Hf 73 Ta 74 W 75 Re 76 Os 77 Ir 78 Pt +1 79 Au 80 Hg 103 Lr 104 Rf 105 Db 106 Sg 107 Bh 108 Hs 109 Mt 110 Ds +1, +3 111 Rg +1, +2 112 Uub Cobalt, chromium, manganese, and vanadium also require Roman numerals. Look at the anion to determine the charge. Ag+ H3O+ silver hydronium Cd2+ Ni2+ Zn2+ cadmium nickel zinc CNSCNMnO4- cyanide thiocyanate permanganate ClO4perchlorate ClO3chlorate ClO2chlorite ClOhypochlorite (similarly for bromine and iodine) CONGRATULATIONS! You’ve memorized the whole table. CrO42Cr2O72C2O42O22- chromate dichromate oxalate peroxide Common Ions (learn these) Positive ions (cations) +1 Charge ammonium (NH4+) copper (I) or cuprous (Cu+) hydrogen (H+) “proton” silver (Ag+) hydronium ion (H3O+) Group 1A cations (Li+, Na+, K+, Rb+, Cs+, Fr+) Negative ions (anions) -1 Charge acetate (C2H3O2-) cyanide CNdihydrogen phosphate (H2PO4-) hydrogen carbonate or bicarbonate (HCO3-) hydrogen sulfate of bisulfate (HSO4-) hydroxide (OH-) nitrate (NO3-), nitrite (NO2-) perchlorate (ClO4-),chlorate (ClO3-),chlorite (ClO2-), hypochlorite (ClO-) permangante (MnO4-) thiocyanate (SCN-) Group 7A anions (F-, Cl-, Br-, I-) – ide ending +2 Charge -2 Charge cadmium (Cd2+) carbonate (CO32-) chromium (II) or chromous (Cr2+) chromate (CrO42-), dichromate(Cr2O72-) cobalt(II) or cobaltous (Co2+) hydrogen phosphate (HPO42-) 2+ copper(II) or cupric (Cu ) oxalate (C2O42-) 2+ iron(II) or ferrous (Fe ) oxide (O2-), peroxide (O22-) 2+ lead(II) or plumbous (Pb ) sulfate (SO42-), sulfite (SO32-) 2+ manganese(II) or manganous (Mn ) sulfide (S2-) 2+ mercury(I) or mercurous (Hg2 ) Group 6A anions (O2-, S2-, Se2-, Te2-) – ide ending mercury(II) or mercuric (Hg2+) nickel (Ni2+) tin(II) or stannous (Sn2+) zinc (Zn2+) Group 2A cations (Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Ra2+) +3 Charge -3 Charge aluminum (Al3+) phosphate (PO43-); phosphite (PO33-) chromium(III) or chromic (Cr3+) Group 7A anions - nitride (N3-), phosphide (P3-) 3+ iron(III) or ferric (Fe ) Group 3A cations - aluminum (Al3+) +4 Charge lead(IV) or plumbic (Pb4+) tin(IV) or stannic (Sn4+) Summary of metal cations with more than one possible charge: Cu+, Cu2+; Hg22+, Hg2+; Fe2+, Fe3+; Pb2+, Pb4+; Sn2+, Sn4+ There are other metals that form more than two stable ions. These include manganese, chromium, cobalt, vanadium, and others. You should know these four require Roman numerals. Covalent compounds follow a different naming system Binary covalent compounds use prefixes to indicate number of each atom. Mono is not used if there is only one of the first atom; -ide is used as a suffix on the root of the second atom. Number Prefix Number Prefix 1 mono 6 hexa 2 di 7 hepta 3 tri 8 octa 4 tetra 9 nona 5 penta 10 deca Binary acid (HnX) solutions form when certain gaseous compounds dissolve in water. Ex. HCl gas dissolves in water to form hydrochloric acid. hydro- + anion nonmetal root + -ic acid - hydrochloric acid Ex. HF HBr HI H2S - hydrofluoric acid hydrobromic acid hydroiodic acid hydrosulfuric acid
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