Ocean Acidification Process GCSE Science Why study ocean acidification? – The oceans contain 50 times more carbon dioxide than the atmosphere – The ocean pH has decreased by 0.1 of a unit, representing a 29% increase in hydrogen ions since the Industrial Revolution – The oceans absorb roughly 30% of humangenerated carbon dioxide GCSE Science – pH is the unit used to measure acidity – The lower the pH value, the greater the acidity Increasing acidity Why is pH? 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 Drain cleaner Ammonia Soap Baking soda Water Milk Banana Tomato Vinegar Lemon Hydrochloric acid GCSE Science Atmospheric CO2 Ocean acidification process CO2 dissolves in water CO2 (aq) Carbon dioxide in the atmosphere dissolves in the oceans. Atmospheric CO2 CO2 dissolves in water CO2 (aq) Ocean acidification process Forms Carbonic Acid H 2CO3 This aqueous carbon dioxide reacts with the water to form carbonic acid. Atmospheric CO2 CO2 dissolves in water CO2 (aq) Ocean acidification process Forms Carbonic Acid Breaks down to form bicarbonate and hydrogen ions H 2CO3 H+ HCO3- The carbonic acid breaks down to form bicarbonate and hydrogen ions. The increase in hydrogen ions makes the oceans more acidic. So the more carbon dioxide that is absorbed by the oceans, the more acidic they become. Atmospheric CO2 CO2 dissolves in water CO2 (aq) Ocean acidification process Forms Carbonic Acid Breaks down to form bicarbonate and hydrogen ions H 2CO3 Carbonate ions react with these ‘extra’ hydrogen ions H+ + HCO3- CO32- Carbonate ions ‘buffer’ this increased number of hydrogen ions by forming more bicarbonate ions. Carbonate ions enter the oceans through processes such as the weathering of limestone (CaCO3). This buffering decreases the amount of carbonate and hydrogen ions in the oceans. Atmospheric CO2 CO2 dissolves in water CO2 (aq) Ocean acidification process Forms Carbonic Acid Breaks down to form bicarbonate and hydrogen ions H 2CO3 Carbonate ions react with these ‘extra’ hydrogen ions H+ + HCO3- CO32- Organisms that form their shells or skeletons from carbonate will be affected because there are fewer carbonate ions in the oceans. The levels of ocean acidification may also reach a ‘corrosive’ level where these shells or skeletons start to dissolve to ‘buffer’ the ocean pH.
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