Petroleum Ether 80-1000C
CAS No 8032-32-4
MATERIAL SAFETY DATA SHEET
SDS/MSDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1
1.2
Product identifiers
Product name
:
Petroleum Ether 80-100 C
CAS-No.
:
8032-32-4
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
1.3
:
Laboratory chemicals, Industrial & for professional use only.
Details of the supplier of the safety data sheet
Company
: Central Drug House (P) Ltd
7/28 Vardaan House
New Delhi-10002
INDIA
Telephone
Email
1.4
0
:
:
+91 11 49404040
[email protected]
Emergency telephone number
Emergency Phone #
:
+91 11 49404040 (9:00am - 6:00 pm) [Office hours]
SECTION 2: Hazards identification
2.1
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Germ cell mutagenicity (Category 1B), H340
Carcinogenicity (Category 1B), H350
Aspiration hazard (Category 1), H304
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
F, T
Highly flammable, Toxic
R45, R46, R11, R65
For the full text of the R-phrases mentioned in this Section, see Section 16.
2.2
Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word
Hazard statement(s)
H225
H304
Danger
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
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H340
H350
May cause genetic defects.
May cause cancer.
Precautionary statement(s)
P201
P210
P301 + P310
Obtain special instructions before use.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
IF exposed or concerned: Get medical advice/ attention.
Do NOT induce vomiting.
P308 + P313
P331
Supplemental Hazard
Statements
none
Restricted to professional users.
2.3
Other hazards - none
SECTION 3: Composition/information on ingredients
3.1
Substances
CAS-No.
EC-No.
Index-No.
:
:
:
8032-32-4
232-453-7
649-263-00-9
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component
Classification
Ligroine
CAS-No.
EC-No.
Index-No.
8032-32-4
232-453-7
649-263-00-9
Flam. Liq. 2; Muta. 1B; Carc.
1B; Asp. Tox. 1; H225, H304,
H340, H350
Hazardous ingredients according to Directive 1999/45/EC
Component
Classification
Ligroine
CAS-No.
EC-No.
Index-No.
8032-32-4
232-453-7
649-263-00-9
F, T, R45 - R46 - R11 - R65
Concentration
<= 100 %
Concentration
<= 100 %
For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16
SECTION 4: First aid measures
4.1
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
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4.3
Indication of any immediate medical attention and special treatment needed
no data available
SECTION 5: Firefighting measures
5.1
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
Special hazards arising from the substance or mixture
Carbon oxides
5.3
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4
Further information
Use water spray to cool unopened containers.
SECTION 6: Accidental release measures
6.1
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13).
6.4
Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1
Precautions for safe handling
Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation of
vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
For precautions see section 2.2.
7.2
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
7.3
Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
8.1
Control parameters
Components with workplace control parameters
8.2
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
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Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of
protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to
engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1
Information on basic physical and chemical properties
a)
Appearance
Form: liquid
Colour: colourless
b)
Odour
no data available
c)
Odour Threshold
no data available
d)
pH
no data available
e)
Melting point/freezing
point
no data available
f)
Initial boiling point and
boiling range
36 - 60 °C at 1.013 hPa
g)
Flash point
-49 °C - closed cup
h)
Evapouration rate
no data available
i)
Flammability (solid, gas)
no data available
j)
Upper/lower
flammability or
explosive limits
Upper explosion limit: 8 %(V)
Lower explosion limit: 1,1 %(V)
k)
Vapour pressure
724,66 hPa at 20 °C
1.778,33 hPa at 55 °C
l)
Vapour density
no data available
m) Relative density
0,640 g/cm3
n)
Water solubility
no data available
o)
Partition coefficient: noctanol/water
no data available
p)
Auto-ignition
temperature
no data available
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9.2
q) Decomposition
temperature
no data available
r)
no data available
Viscosity
s) Explosive properties
no data available
t)
no data available
Oxidizing properties
Other safety information
no data available
SECTION 10: Stability and reactivity
10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1
Information on toxicological effects
Acute toxicity
LC50 Inhalation - rat - 4 h - 3400 ppm
Remarks: Behavioral:Convulsions or effect on seizure threshold. Behavioral:Muscle weakness.
LD50 Intravenous - mouse - 40 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
In vivo tests showed mutagenic effects
Carcinogenicity
Possible human carcinogen
IARC:
2B - Group 2B: Possibly carcinogenic to humans (Ligroine)
3 - Group 3: Not classifiable as to its carcinogenicity to humans (Ligroine)
IARC: 2B - Group 2B: Possibly carcinogenic to humans (Ligroine)
3 - Group 3: Not classifiable as to its carcinogenicity to humans (Ligroine)
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
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Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
May be fatal if swallowed and enters airways.
Additional Information
RTECS: Not available
burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting
Liver - Irregularities - Based on Human Evidence
SECTION 12: Ecological information
12.1 Toxicity
no data available
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.
SECTION 14: Transport information
14.1 UN number
ADR/RID: 1268
IMDG: 1268
IATA: 1268
14.2 UN proper shipping name
ADR/RID: PETROLEUM DISTILLATES, N.O.S.
IMDG:
PETROLEUM DISTILLATES, N.O.S.
IATA:
Petroleum distillates, n.o.s.
14.3 Transport hazard class(es)
ADR/RID: 3
IMDG: 3
IATA: 3
14.4 Packaging group
ADR/RID: II
IMDG: II
IATA: II
14.5 Environmental hazards
ADR/RID: no
IMDG Marine pollutant: no
IATA: no
14.6 Special precautions for user
no data available
SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
SECTION 16: Other information
Full text of H-Statements referred to under sections 2 and 3.
Asp. Tox.
Carc.
Flam. Liq.
H225
H304
H340
H350
Muta.
Aspiration hazard
Carcinogenicity
Flammable liquids
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
May cause genetic defects.
May cause cancer.
Germ cell mutagenicity
Full text of R-phrases referred to under sections 2 and 3
F
T
R11
R45
R46
R65
Highly flammable
Toxic
Highly flammable.
May cause cancer.
May cause heritable genetic damage.
Harmful: may cause lung damage if swallowed.
Further information
The above information is believed to be correct but does not purport to be all inclusive and shall
be used only as a guide. The information in this document is based on the present state of our
knowledge and is applicable to the product with regard to appropriate safety precautions. It does
not represent any guarantee of the properties of the product. Central Drug House (P) Ltd and its
Affiliates shall not be held liable for any damage resulting from handling or from contact with the
above product. See www.cdhfinechemical.com for additional terms and conditions of sale.
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