Proc. Radiochim. Acta 1, 349–355 (2011) / DOI 10.1524/rcpr.2011.0062 © by Oldenbourg Wissenschaftsverlag, München Planetary gamma ray spectrometry: remote sensing of elemental abundances By P. A. J. Englert∗ Hawai’i Institute for Geophysics and Planetology, University of Hawai’i at Mânoa, 1680 East West Road, Honolulu, HI 96822, USA (Received January 3, 2010; accepted in revised form November 11, 2010) Summary. Planetary gamma ray spectrometry is a form of nuclear spectroscopy applied remotely to provide geochemical maps of planetary bodies. From early developments it has by now become a standard modality of planetary exploration. Basic and applied nuclear science has made significant contributions to the advancement of planetary gamma ray spectrometry, as outlined in this methodological and historical assessment. spectrometry and to demonstrate its developments from genuinely nuclear chemical and physical domains to the integration of the modality into the new knowledge compact of remote geochemical analysis. 1. Introduction Of the key elements of planetary gamma ray spectrometry only a few will be discussed here in form of an overview. These include the origin of gamma rays from planetary surfaces, their transport to a detector above the surface, their measurement and interpretation. Gamma ray spectroscopy, since its inception has been widely used as a tool to determine elemental abundances of geological samples in the laboratory and in the field. Diagnostic gamma rays of naturally radioactive elements and those of isotopes excited or activated by neutrons are predominantly used in terrestrial laboratory and field settings, including all forms of neutron activation analysis. The power of gamma ray spectroscopy for the determination of elemental abundances of distant planetary surfaces has been recognized very early in the history of planetary exploration. While at that time the focus of planetary gamma ray spectrometry was on determining the overall abundances of naturally radioactive elements K, Th, and U, it was soon recognized that a wider range of elements, including major rock-forming ones such as O, Si, and Fe were accessible through gamma rays produced by interaction of planetary surfaces with galactic cosmic radiation. Advancements in instrument and space vehicle development soon supported the concept of orbital mapping of elemental abundances of terrestrial planets. Major targets for planetary gamma ray spectroscopy were the Moon, Mars, Venus and one Asteroid with missions to further asteroids and Mercury underway. Compared to terrestrial applications of e.g. prompt gamma activation analysis with neutron beams, planetary gamma ray spectroscopy is comparatively complex and resource intensive. Therefore nations with major space exploration programs dominated the development of the modality in its early development phases. To date five nations have successfully completed such experiments, beginning with the United States and USSR/Russia, and recently Japan, China, and India. The scope of this paper is to provide a brief methodological and historical overview over planetary gamma ray *E-mail: [email protected]. 2. Principles of planetary gamma ray spectrometry 2.1 Cosmic radiation and planetary gamma rays While planetary surface gamma rays are produced by decay of naturally radioactive elements, the majority of gamma rays in planetary surfaces are produced by the interaction of galactic cosmic radiation. Galactic cosmic radiation consists of charged particles, predominantly protons and alpha particles of energies between several hundred MeV to several GeV per nucleon. Their flux is about 4 particles per cm2 and s, with protons being by far the most abundant. Galactic cosmic ray fluxes are modulated by solar activity but do not originate from the Sun. These high-energy particles are stopped in the planetary surface through multiple interactions with atomic nuclei, transferring their energy, among other mechanisms, through an intranuclear cascade to nucleons of the surface producing directly (knock-on) or through subsequent evaporation secondary particles. These include neutrons which through further interactions including scattering, moderation, and capture produce gamma rays diagnostic for the elements/isotopes they interact with [1, 2]. Conceptually, therefore, planetary gamma ray spectroscopy can also be considered a special form of prompt gamma activation analysis with neutron beams. Both natural and galactic cosmic ray produced gamma rays are formed at depths that include or exceed those where galactic cosmic ray particles are completely stopped. Their production and attenuation are dependent on factors such as gamma ray energy, density and average atomic number Z of the surface, and the presence ofUnauthenticated neutron moderators and absorbers. The effective depths from which Download Date | 6/17/17 5:51measurable AM 350 gamma rays are emitted covers only a few decimeters. And it is important that as many factors that influence the behavior of neutrons and gamma ray absorption are known or obtainable from other measurements [2]. The advantage over optical and X-ray spectroscopic methods in depth coverage of chemical information makes planetary gamma ray spectrometry a valuable complement. 2.2 Measurement and interpretation Gamma rays meeting a detector interact with that detector through different mechanisms. The most important effect in a detector able to record the full energy of a gamma ray is the photoelectric effect in which the gamma photon transfers its entire energy to an electron of the detector material. This energetic electron is stopped in the detector material by ionization or other processes, providing an electrical signal in a solid-state detector and a light yield in a scintillation detector directly proportional to the gamma energy deposited. These signals can be recorded in event/energy multi-channel analyzers as so-called pulse height spectra recording the number events/gamma rays over a defined energy range and time interval for the target observed [4]. Gamma ray spectra obtained can be used for elemental abundance determination. For space based gamma ray experiments the choice of detector is a question of detection technology available at the time of mission and experimental boundary conditions provided by spacecraft and flight parameters. The earliest detectors used were scintillation detectors such as NaI(Tl), Sodium Iodide, scintillation detectors, and CsI(Tl), Cesium Iodide, scintillation detectors, and later also BGO, Bismuth Germanate, scintillation detectors. When high volume solid state detectors became available, especially HPGe, High Purity Germanium, they were used in space based gamma ray measurements, including planetary gamma ray spectrometry. These detectors need to be cooled to 80–100 K for operation. While the ultimate choice of detector types depends on the scientific goals to be achieved, practical considerations determine the choice of flight instrumentation. The key weighing has to occur between the following parameters: Overall gamma ray detection efficiency is higher in scintillation detectors, a choice when measurement time is short. Overall energy resolution is better in solid-state detectors, a choice when improving detection opportunity for more major and some minor elements. Scintillation detectors do not show degradation of resolution under radiation exposure, but solid state detectors do. Hence for longer flights solid-state detector radiation damage needs to be repeatedly annealed in flight. Cooling of solid-state detectors can be active through mechanical coolers, which caused in the past some technical, but mostly energy use issues. Passive space based cooling places constraints on orbit and pointing accuracy of solid-state detector passive coolers into dark space [5]. Gamma ray spectrometers on landers, on spacecraft in fly-by mode or highly elliptical orbits tend to integrate all gamma rays measured during active counting. Spacecraft in circular equatorial and especially those in circular polar orbits have the opportunity to obtain data in a mode that allows establishing partial or complete geochemical maps P. A. J. Englert of the target planet, respectively. The spatial resolution for such maps depends predominantly on the angular response of the spectrometer and the altitude of the spacecraft orbit. Unless collimated by anti-coincidence techniques, the angular response of most detector arrangements used is omnidirectional. For gamma rays from the target surface the effective geometric counting efficiency for an area on the surface is in first order dependent on the spacecraft altitude. This means that the footprint for spatial resolution can be large [2]. For the Apollo Missions to the Moon at an orbital altitude of 100 km the spatial resolution was about 150 km and for Mars Odyssey at 400 km it was 600 km, respectively. An additional concern of omnidirectional detector response is gamma radiation induced in spacecraft materials by cosmic radiation. Reduction of this background can be achieved by positioning the detector away from the spacecraft on a boom and measurement of this background before reaching the planetary target. If for technical reasons the detector is integrated into the spacecraft, gamma ray anticoincidence shielding towards the spacecraft source can be effective; this can also be used to reduce background resulting from gamma ray–detector interactions. For gamma radiation produced in the detector assembly itself careful selection of the construction materials can be helpful. Signals produced by charged particle interaction with the detector itself need to be rejected electronically. For orbital planetary gamma ray experiments statistically sufficient spectra for elemental abundance determination over a point or region of interest, spectra need to be accumulated from “snapshots” (about 20 s) of repeated passes of the spacecraft over that point or region. Depending on gamma ray yields for a given element accumulation times of several ten to a few thousand hours are needed for elemental abundance uncertainties below 10% for e.g. the Mars Odyssey mission. As in neutron activation analysis comparator methods are best suited to provide reliable elemental abundance data. In the case of Moon and Mars “ground truth” standards are available through sample return missions and or in-situ elemental analysis through robotic missions. Complexities arising from the presence of neutron moderators and minor and trace elements with high neutron capture cross sections can be addressed through intrinsic properties of the gamma ray spectra, through concurrent and complementary measurement of neutron leakage spectra, and model calculations. 3. Planetary gamma ray spectrometry: from concept to success Planetary gamma ray spectrometry as tool for comparative planetology has been proposed by J. R. Arnold, University of California, San Diego in 1958 [6]. Beginning with the Ranger missions of the United States in 1962 many missions with the goal of obtaining planetary gamma ray spectra have been completed to date. At present, two missions are on trajectory to their targets. A frequency diagram of all successful planetary gamma ray missions to date is provided in Fig. 1. Success for the purpose of this study is defined in terms of a successful Unauthenticated launch of the spacecraftDownload and theDate measurement | 6/17/17 5:51ofAMspectra Planetary gamma ray spectrometry: remote sensing of elemental abundances Fig. 1. Frequency diagram of successful planetary gamma ray experiments. The development of planetary gamma ray spectroscopy has progressed from a trial, proof of concept, and investigation phase into a standard modality for geological exploration of planets. with the gamma ray instrument on board. For some experiments it does not include the measurement of planetary gamma ray spectra as for example in the case of the Mars Observer mission, where multiple cruise phase data were obtained but where the spacecraft did not reach its planetary mapping orbit. Parameters of importance for discussion are given in Table 1 for each of the missions represented in Fig. 1. Based on the frequency diagram in Fig. 1 the following phases of planetary gamma ray development and application can be derived. The early phase including United States Ranger and Russian Luna missions can be termed the trial phase from 1962 to 1966, followed by the proof of concept phase that consists in principle of the first successful orbiter experiments on Apollo 15 and 16 in 1971 and 1972. With the exception of the Russian Venera 8 mission to Venus in 1974 and the Phobos mission to Mars in 1988 there were no other planetary gamma ray experiments until the successful launch of the Mars Observer Mission in 1992. This phase of almost two decades could be called the investigation phase as many experiments including detector development and underpinning nuclear science were undertaken to improve the planetary gamma ray spectrometry modality. It was in the transition from this phase to the next that planetary gamma ray spectroscopy became an integral part of the area of remote geochemical analysis [7]. The geological exploration phase, that is the phase where geological exploration goals dominated mission design and expectations begins in 1992, with to date nine missions completed or in progress by five nations. 3.1 Trial The trial phase can be associated with the Ranger 3 and 5 missions and the Luna 10 and 12 missions to the Moon, and under the definition above, Kosmos 60. Several tasks were accomplished by these missions. All of these missions provided measurements of space background gamma rays, and all but one, Kosmos 60, provided lunar surface gamma ray spectra using scintillation detectors. Rangers 3 and 5 can be 351 classified as fly-bys while Luna 10 and 12 were successfully inserted into elliptical lunar orbits. Gamma ray accumulation times of the missions ranging from several hours to more than 30 days were too short to provide fine scale geochemical mapping. Gamma energies measured ranged from about 0.2 MeV to 2.0 and 3.0 MeV, respectively, and were useful to record natural radioactivity and some inelastic neutron scattering gamma ray lines. Neutron capture gamma ray lines at higher energies could not be measured. Arnold et al. (1962) [8], van Dilla et al. (1962) [9], and Metzger et al. (1964) [10] reported first results of the Ranger missions. Vinogradov et al. (1966 & 1968) [11, 12] reported on the Luna missions. Key results, as exemplarily expressed in Vinogradov et al. (1966), are that the ratio of gamma radiation between lunar maria and lunar highlands is approximately 1.15 to 1.2, that natural radioactivity of the lunar surface indicates its correspondence to terrestrial basalts, and that only about 10% of the total gamma ray intensity measured on the lunar surface comes from natural radioactivity. These findings provided valuable information for future lunar gamma ray missions. Accomodations had to be made to measure cosmic ray induced inelastic neutron scattering and neutron capture gamma ray lines. To some degree the Russian Venera 8, 1972, and Mars 5, 1974, missions also belong into the trial period [13, 14]. 3.2 Proof of concept The opportunity to provide proof of concept for orbital geochemical mapping through planetary gamma ray spectrometry came with the United States manned Apollo missions to the Moon. Apollo 11 and Apollo 12, both flown in 1969, landed the first human beings on the Moon and returned 22 kg and 34 kg, respectively, of lunar material from their lunar equatorial landing sites. This was followed by the Russian robotic return missions Luna 16, 1970, Luna 20, 1974, and Luna 24, 1976, with 101 g, 30 g, and 170.1 g, respectively. These samples, in particular the Apollo landing site ones, provided an important standard or „ground truth“ for absolute elemental abundance determinations with orbital gamma ray spectrometers or other measurement devices. Based on missions during the trial phase and knowledge about celestial body compositions, a fundamental understanding of characteristic gamma ray production became available [15–17]. Apollo 15, 1971, and Apollo 16, 1972, carried a NaI(Tl) scintillation detector each attached to the Command Service Module (CSM) on a 7.6 m long boom. These detectors could measure lunar surface gamma rays along the 100 km altitude circular nearly-equatorial orbit of the CSM during lunar surface operations for a combined time of about 10.5 d. Data, covering energies from 0.2 to 10.0 MeV, the new standard for planetary gamma ray spectrometry, were stored on the board computer of the return vehicle so that telemetry was not needed. The orbits of the CSMs on Apollos 15 and 16 covered about 20% of the lunar surface. The experiment provided geochemical maps of the areas covered by the CSM orbit of the naturally radioactive element Th, as well of the elements Fe and Ti with relatively Unauthenticated high spatial resolution,Download as well Date as information | 6/17/17 5:51on AMK. Sig- 352 P. A. J. Englert Table 1. Successfull planetary gamma ray spectrometry experiments. Year Mission name Object studied Country Mode, orbit Data acquisition time (planet) Detector Shielding anti-coincidence 1962 Ranger 3 Moon USA Fly-by 4h CsI(Tl) Plastic scintillator 1962 Ranger 5 Moon USA Fly-bay 4h CsI(Tl) 1965 Kosmos 60 Moon USSR Lander none Na(Tl) 1966 Luna 10 Moon USSR Elliptical 1966 Luna 12 Moon USSR 1971 Apollo 15 Moon 1972 Apollo 16 1972 Boom length Gamma energies Boom 1.8 m 0.2–2.0 MeV Plastic scintillator Boom 1.8 m 0.2–2.0 MeV Plastic scintillator Integrated 0.2–3.0 MeV 57 d NaI(Tl) Plastic scintillator Integrated 0.2–3.0 MeV Elliptical 85 d NaI(Tl) Plastic scintillator Integrated 0.2–3.0 MeV USA Equatorial at 100 km 10.5 d combined NaI(Tl) Plastic scintillator Boom 7.6 m 0.2–10.0 MeV Moon USA Equatorial at 100 km 10.5 d combined NaI(Tl) Plastic scintillator Boom 7.6 m 0.2–10.0 MeV Venera 8 Venus USSR Lander 50 m CsI(Tl) None Integrated 0.2–3.0 MeV 1974 Mars 5 Mars USSR Orbiter 23 d (22 elliptical orbits) CsI(Tl) None Integrated 0.2–3.0 MeV 1988 Phobos 2 Mars Elliptical equatorial 120 m (2 elliptical orbits) CsI(Tl) None Integrated 0.2–4.0 MeV 1992 Mars Observer Mars USA Circular polar, at 400 km none HPGe Boron-loaded plastic scintillator 1996 Near Earth Eros Asteroid Rendezvous (NEAR) USA Orbiter 7 weeks at 35 km, 7d NaI (Tl) BGO Integrated 1998 Lunar Prospector Moon USA Circular polar, at 100 km & 30 km 300 d & 220 d BGO Boron-loaded plastic scintillator Boom 2.5 m 0.2–10.0 MeV 2001 2001 Mars Odyssey Mars USA Circular polar, at 400 km > 6 years (> 3 Martian years) HPGe Boron-loaded plastic scintillator Passive Boom 6.2 m 0.2–10.0 MeV 2004 Messenger Mercury USA 3 fly-bys Elliptical polar Few hours planned: 1 year HPGe Boron-loaded plastic scintillator Active Integrated 0.2–10.0 MeV 2007 Selene (Kaguya) Moon JPN Circular polar, at 100 km & 50 km 1.5 years HPGe BGO. plastic scintillator Active Integrated 0.2–12.0 MeV 2007 Dawn Vesta Ceres USA High and low altitude circular Planned: BGO 6 months at CZT each asteroid array Boron-loaded plastic scintillator Integrated 0.2–10.0 MeV 2007 Chang’e-1 Moon CHN Circular polar, at 200 km 1 year CsI(Tl) CsI(Tl) Integrated 0.2–9.0 MeV 2008 Chandrayaan-1 Moon IND Circular polar, 312 d at 100 and 200 km CZT array CsI(Tl) Integrated < 250 KeV Lander Cooling Location Passive Boom 4.3 m cruise 0.2–10.0 MeV 6.0 m orbit 0.2–10.0 MeV In coulmun 4 the following abbreviations were used to identify countries: USA – United States of America, USSR – Soviet Union; JPN – Japan, CHN – China, and IND – India. In column 7 the following conventions were used to describe gamma ray sensors: NaI – Sodium Iodide, CsI – Cesium Iodide, BGO – Bismuth Germanate, CZT – Cadmium Zink Telluride, HPGe – High Purity Germanium, Tl - Thallium. nificant differences of elemental abundances between the far side and near side of the Moon were reported [18, 19]. The Apollo 15 and 16 lunar gamma ray experiment provided proof that planetary gamma ray spectrometry is a valuable and by now proven method of elemental abundance measurements for planetary surfaces. The principle of ground truth or comparator methodology for absolute Unauthenticated abundance determination was established, mapping Download Date | 6/17/17 5:51 AM along Planetary gamma ray spectrometry: remote sensing of elemental abundances the flight path completed, and the results provided valuable source data addressing the origin and geological history of the Moon. 3.3 Investigation Despite the success of the Apollo gamma ray experiment planetary exploration proceeded over almost two decades with many space and planetary exploration missions not carrying planetary gamma ray spectrometers. Despite of the spectacular success of Apollo, many fundamental nuclear science and radiation detection, measurement and evaluation questions needed to be answered. Of the many scientific and technical developments that aided planetary gamma ray spectrometry in becoming a standard modality in geochemical space exploration, some were specifically undertaken for its development. Other advances came from developments in other areas of science and technology, the closest being from gamma ray astrophysics and otherwise from general nuclear science and space technology. These include general advancements in solid state detector development, such as the HPGe detectors with gamma ray energy resolutions superior to those of scintillation detectors, and associated gamma ray spectra deconvolution techniques. Of the several streams of developments during this time frame specifically targeted on planetary gamma ray spectrometry, a few examples will illustrate important areas of fundamental and applied nuclear science to further its advancement. Understanding gamma ray yields, especially for inelastic neutron scattering reactions, knowledge of production cross sections is necessary. Cross sections for major rock-forming elements are useful in model calculations, especially for geochemical environments for which no ground truth standards exist. This was at the time the case for all planetary bodies but the Moon. A limited set of inelastic cross section measurements were conducted [20]. Interactions of cosmic radiation with planetary objects are complex and show variations with major elements, such as Fe and/or Ti, and minor and trace element composition, such as Gd, of the location of interest. Model calculations can reflect this complexity and were, in general, verified in their applicability through comparisons with complex but controlled terrestrial simulation experiments. Such experiments were completed in preparation of the Mars Observer mission. So-called “Thick Targets”, simulating a planetary surface were exposed to beams of accelerator produced high-energy protons of known flux and energy while gamma rays emitted from its surfaces were measured with highresolution HPGe detectors [21]. Variations in Thick Target composition simulated expected variations in Martian surface composition. Gamma ray spectra for two proton energies and several variations of expected Martian composition were produced and analyzed. These experiments are useful as their gamma ray spectra are very similar to actual HPGe spectra from Mars and Moon. They are diagnostic in that over 270 gamma ray lines comprising more that 95% of all present were identified (target and background), and many diagnostic gamma ray lines of elements of interest were available for quantitative evaluation. Comparisons with model calculations were also undertaken [22]. 353 Solid-state detectors, and especially high volume HPGe detectors, lose resolution due to radiation damage caused by exposure to cosmic radiation. This becomes an issue when planetary exploration experiments are designed for extended durations, e.g. of several years, of cruise to the target and measurement times to obtain gamma ray spectra providing reasonable uncertainties for the elements of interest. Therefore a set of radiation damage experiments with high volume p- and n-type HPGe detectors was conducted with highenergy protons. The experiments showed the superiority of n-type HPGe detectors for planetary gamma ray spectrometry and provided the experimental basis for the design and optimization of in-space annealing procedures. Annealing design and procedures maintained the Mars Odyssey gamma ray spectrometer operational at acceptable resolution for over six years [23]. Many other experiments contributing to the performance and of planetary gamma ray spectrometers in space continuing beyond the time frame called investigation phase were completed. Among others, the problem of mechanical cooling has been solved recently, extending operational capabilities of HPGe detector use [24]. However, the few examples presented demonstrate that basic and applied nuclear science investigations were a key element in preparing the modality of planetary gamma ray spectrometry for its application-oriented expansion. 3.4 Geological exploration Missions that, with some exceptions, completed or intended to complete orbital geochemical mapping of celestial bodies characterize the geological exploration phase of planetary gamma ray spectrometry. Two experiments that led into exploration are the 1997/98 Lunar Prospector Mission [25], and the Mars Observer Mission of 1992, although the latter did not produce planetary data [26]. Both had functioning gamma ray spectrometers on board. Mars Observer, for the first time in planetary exploration was carrying a passively cooled HPGe crystal as gamma ray sensor. The contemporary1988 Phobos 2 mission had a few close passes of the Martian surface where gamma ray spectra could be taken by its scintillation detector before the spacecraft failed [27]. Subsequent exploration missions to asteroid Eros, Moon and Mars were all completed successfully or are in progress. Two missions in progress are the United States MESSENGER, 2004, and Dawn, 2007, missions to Mercury, and the asteroids Vesta and Ceres [28, 29]. Of the completed missions, NEAR (Near Earth Asteroid Rendezvous) functioned as a Lander operating a spacecraft integrated NaI(Tl) spectrometer with a BGO shield for 7 days after having completed orbital measurements far from the asteroid Eros [30]. Most important, following Lunar Prospector, was the completion of the Mars Odyssey Mission in 2009 providing elemental maps for more than ten major and minor elements [31]. Of later missions, three had circular polar orbits around their lunar target, capable of complete geochemical mapping. Two US missions underway, MESSENGER and Dawn, will arrive at their main or first targets Mercury and Vesta in 2011,to assume elliptical and Unauthenticated circular orbits respectively. Both carry advanced gamma ray instrumentation, an Download Date | 6/17/17 5:51 AM 354 actively cooled BGO shielded HPGe and BGO and Cadmium Zink Telluride (CZT) detectors shielded with borated plastic scintillators, respectively. The first ever complete geochemical mapping of the Moon by gamma ray and neutron spectrometry, or any planet for that matter, was achieved by the Lunar Prospector, 1998, which operated instruments on 2.5 m booms at an altitude of 100 km for 300 d, and at an altitude of 30 km for 220 d [32]. The experiment marks the transition from proof of concept to the first full application of the capabilities of gamma ray spectrometry for planetary exploration [33]. 2001 Mars Odyssey followed immediately with a complete coverage of Mars using a passively cooled HPGe detector on a 6.2 m boom and neutron detectors at an altitude of 400 km. The experiment took data for over six terrestrial years (three Martian years) until operation of the ceased to conduct other experiments with the spacecraft. Complete elemental maps K, Th, Si, H, Cl, Ca, Al, O, S, and U were obtained [3, 31, 34]. Together, these missions verify the full capability and scientific value of planetary gamma ray spectrometry. In a different way, the lunar polar orbiters launched by Japan, China, and India in 2007 and 2008, establish planetary gamma-ray spectrometry as a routine method of remote geochemical analysis. Each one of these experiments has additional and interesting features that make them unique. The SELENE (Kaguya) mission, 2007, used for the first time an actively cooled HPGe to measure lunar gamma rays at orbits of 100 km and 50 km altitude, respectively, for combined accumulation time of 1.5 years [35]. The Chang’e-1 mission, 2007, used a CsI(Tl) detector with a CsI(Tl) anticoincidence operating at an altitude of 200 km for more than one year [36]. Objectives of both missions are similar to that of the Lunar Prospector. The Chandrayaan-1 mission, 2008, operated at an altitude of 100 km and 200 km respectively. In contrast to all most of the other gamma ray experiments which covered gamma ray energies between 0.2 and 10.0 MeV, the Chadrayaan-1 team used a CdZnTe detector array capable of measuring x rays and gamma rays below 250 KeV, an interesting complement to other recent lunar gamma ray experiments, focused on naturally radioactive elements Th and U [37]. With five orbital planetary gamma ray experiments to Moon and Mars completed in the last decade and two more complex experiments to asteroids and Mercury under way planetary gamma ray spectrometry is now established as a standard modality of remote geochemical analysis. 4. Discussion and conclusions Five decades after the first proposal in 1958 for the development of planetary gamma ray spectrometry as a unique nuclear analytical technique for planetary exploration the experiments launched in the past decade have firmly embedded it as a standard modality of space exploration. Many technical and scientific problems had to be resolved through supporting work in basic and applied nuclear sciences. However, the field itself with increasing success is not any more directly dependent on underpinning nuclear science research. Its major drivers are now planetary geoscience objectives that can be addressed with the current inventory of P. A. J. Englert nuclear science knowledge. This does not mean that all basic and applied nuclear science issues are resolved. It only means that the driving force for additional nuclear science investigations has become a function of planetary exploration objectives and will be employed only when these objectives require it. The development of planetary gamma ray spectrometry is only one of many examples of the contributions nuclear science has made to many other fields of research. The development history of planetary gamma ray spectrometry also falls into a larger framework of knowledge growth and the establishment of new areas of research and knowledge at the intersection between originally separate scientific domains. Under this framework basic nuclear science has made many contributions over time to knowledge growth in many different areas, a fact that underlines the importance of basic nuclear sciences. Acknowledgment. This work was possible through long-term support from NASA to the Mars Observer and 2001 Mars Odyssey missions, and through continued collaboration with the Max Planck Institute for Chemistry, Mainz, Germany. References 1. Reedy, R. C.: Planetary Gamma Ray Spectrometry. 9th Proc. Lunar Planet. Sci. Conf. (1978), p. 2961. 2. Prettyman, T. H.: Remote chemical sensing using nuclear spectroscopy. In: Encyclopedia od the Solar System, Academic Press (2007), p. 765. 3. Boynton, W. V., Feldman, W. C., Mitrofanov, I. G., Evans, L. G., Reedy, R. C., Squyres, S. W., Starr, R., Trombka, J. I., d’Uston, C., Arnold, J. R., Englert, P. A. J., Metzger, A. E., Wänke, H., Brückner, J., Drake, D. M., Shinohara, C., Fellows, C., Hamara, D. K., Harshman, K., Kerry, K., Turner, C., Ward, M., Barthe, H., Fuller, K. R., Storms, S. A., Thornton, G. W., Longmire, J. L., Litvak, M. L., Ton’Chev, A. K.: The Mars Odyssey Gamma-Ray Instrument Suite. Space Science Rev. 110, 37 (2004). 4. Knoll, G. F.: Radiation Detection and Measuerement. Wiley, New York (1989), 754 pp. 5. Arnold, J. R., Boynton, W. V., Englert, P. A. J., Feldman, W. C., Metzger, A. E., Reedy, R. C., Squyres, S. W., Trombka, J. I., Wänke, H.: Scientific considerations in the design of the MarsObserver Gamma-Ray Spectrometer. In: High-Energy Radiation Backgrounds in Space. (Rester, A. C., Trombka, J. I., eds.) AIP Conference Proceedings 186, 453 (1989). 6. Arnold, J. R.: The Gamma Spectrum of the Moon’s Surface. Proceedings of the Lunar and Planetary Exploration Colloquium, 1, Space and Information Systems Division, Noirth American Aviation Inc., Downey, CA (1958), p. 28. 7. Pieters, C., Englert, P. A. J. (eds.): Remote Geochemical Analysis: Elemental and Mineralogical Composition. Cambridge University Press, New York (1993), 585 pp. 8. Arnold, J. R., Metzger, A. E., Anderson, E. C., van Dilla, M. A.: Gamma rays in space, Ranger 3. J. Geophys. Res. 67, 4878 (1962). 9. van Dilla, M. A., Anderson, E. C., Metzger, A. E., Shuch, A. L.: Lunar composition by scintillation spectroscopy. Inst. Rad. Eng. Trans. Nucl. Sci. NS-9, 405 (1962). 10. Metzger, A. E., Anderson, E. C., van Dilla, M. A., Arnold, J. R.: Detection of an interstellar flux of gamma rays. Nature 204, 766 (1964). 11. Vinogradov, A. P., Surkov, Yu. A., Chernov, G. M., Krinozov, F. F., Nazakrina, G. B.: Preliminary results of measuring gamma radiation of the lunar surface from Luna 10. Kosmich. Issled. IV, 871 (1966), translated in Cosm. Res. 4, 751 (1966) 12. Vinogradov, A. P. , Surkov, Yu.A. , Chernov, G. M., Krinozov, F. F., Nazakrina, G. B.: In: Gamma Investigations of the Moon and Composition of Lunar Rocks. Moon and Planets II. NorthUnauthenticated Holland Publishing Co.,Download Amsterdam (1968), p. 77.5:51 AM Date | 6/17/17 355 Planetary gamma ray spectrometry: remote sensing of elemental abundances 13. Vinogradov, A. P., Surkov, Yu. A., Krinozov, F. F.: The Content of Uranium, Thorium and Potassium in Venusian Rock as Measuerd by Venera 8. Transl. into English from: Soderzhaniye Urana, Totiya I Kaliva V Veneranskoy Porode, Izmerenoye Veneroy 9, Academy of Sciences USSR (Moscow) (1973), p. 22. 14. Vinogradov, A. P. , Surkov, Yu.A. , Moskaleva, L. P., Krinozov, F. F.: Mars-5 intensity and spectral composition measurements of martian gamma radiation. Transl. into English from Dokl. Akad. Nauk. SSSR (Moscow) 223-6, 1336 (1975). 15. Gorenetein, P., Gursky, H.: Charactersitic γ - and X-radiation in the planetary system. Space Sci. Rev. 10, 770 (1970). 16. Armstrong, T. W.: Calculation of the lunar photon albedo from galactic and solar proton bombardment. J. Geophys. Res. 77, 524 (1972). 17. Reedy, R. C., Arnold, J. R., Trombka, J. I.: Expected γ -ray emission from the lunar surface as a function of chemical composition. Annu. Rev. Nucl. Part. Sci. 33, 505 (1973). 18. Metzger, A. E., Trombka, J. I., Peterson, L. E., Reedy, R. C., Arnold, J. R.: Lunar surface radioactivity: preliminary results of the Apollo 15 and Apollo 16 gamma-ray spectrometer experiments. Science 281, 1484 (1973). 19. Metzger, A. E.: Composition of the Moon as determined from orbit by gamma ray spectroscopy. In: Remote Geochemical Analysis: Elemental and Mineralogical Composition. (Pieters, C., Englert, P. A. J., eds.) Cambridge University Press, New York (1993), p. 341. 20. Castaneda, C. M., Gearhart, D. G., Gearhart, R. M., Sanii, B., Englert, P. A. J., Dempsey, J. F., Young, J. C., Drake, D. M., Reedy, R. C.: Gamma ray production cross sections from the bombardment of Mg, Al, Si, Ca, and Fe with medium energy neutrons. Nucl. Instr. Methods Phys. Res. B 260, 508 (2007). 21. Brückner, J., Reedy, R. C., Englert, P.A J., Drake, D. M.: Analysis of Complex Gamma-Ray Spectra: Simulations for Planetary Gamma-Ray Spectroscopy of Solar-System Bodies. LPSC 2010 abstract, submitted. 22. Drake, D. M., Drosg, M., Byrd, R. C., Reedy, R. C., Clark, D. A., Englert, P.A J., Dempsey, J. F., Bobias, S. G., Harris, L.: Experimental and numerical simulation of martian neutron distributions. Nucl. Instrum. Methods Phys. Res. B 84, 337 (1994). 23. Brückner, J., Körfer, M., Wänke, H., Schroeder, A. N. F., Filges, D., Englert, P. A. J., Starr, R. D., Trombka, J. I., Taylor, I., Drake, D. M., Shunk, E. R.: Proton induced radiation damage in germanium detectors. IEEE Trans. Nucl. Sci. 38, 209 (1991). 24. Upp, D. L., Keyser, R. M., Twomey, T. R.: New cooling methods for HPGE detectors and associated electronics. J. Radioanal. Nucl. Chem. 264, 121 (2005). 25. Feldman, W. C., Barraclough, B. L., Fuller, K. R., Lawrence, D. J., Maurice, S., Miller, M. C., Prettyman, T. H., Binder, A. B.: TheLunar Prospector gamma-ray and neutron spectrometers. Nucl. Instrum. Methods Phys. Res. A 422, 562 (1999). 26. Boynton, W. V., Evans, L. G., Reedy, R. C., Trombka, J. I.: The composition of Mars and comets by remote and in situ gamma ray spectrometry. In: Remote Geochemical Analysis: Elemental and Mineralogical Composition. (Pieters, C., Englert, P. A. J., eds.) Cambridge University Press, New York (1993), p. 395. 27. Sagdeev, R. Z., Zakharov, A. V.: Brief history of the Phobos mission. Nature 341, 581 (1989). 28. Boynton, W. V., Sprague, A. L., Solomon, S. C., Starr, R. D., Evans, L.G„ Feldman, W. C., Trombka, J. I., Rhodes, E. A.: MESSENGER and the chemistry of Mercury’s surface. Space Sci. Rev. 131, 85 (2007). 29. Prettyman, T. H., Feldman, W. C., Ameduri, F. P., Barraclough, B. L., Cascio, E. W., Fuller, K. R., Funsten, H. O., Lawrence, D. J., McKinney, G. W., Russell, C. T., Soldner, S. A., Storms, S. A., Szeles, C., Tokar, R. L.: Gamma-ray and neutron spectrometer for the Dawn mission to 1 Ceres and 4 Vesta. IEEE Transact. Nucl. Sci. 50, 1190 (2003). 30. Evans, L. G., Starr, R. D., Brückner, J., Reedy, R. C., Boynton, W. V., Trombka, J. I., Goldsten, J. O., Masarik, J., Nittler, L. R., McCoy, T. J.: Elemental composition from gamma-ray spectroscopy of the NEAR-Shoemaker landing site on 433 Eros. Meteorit. Planet. Sci. 36, 1639 (2001). 31. Boynton, W. V., Taylor, G. J., Evans, L. G., Reedy, R. C., Starr, R., Janes, D. M., Kerry, K., Drake, D. M., Kim, K. J., Williams, R. M. S., Crombie, K., Dohm, J. M., Baker, V., Metzger, A. E., Karunatillake, S., Keller, J., Arnold, J. R., Brückner, J., Englert, P. A. J., Gasnault, O., Sprague, A. L., Squyres, S. W., Trombka, J. I., d’Uston, C., Wänke, H.: Concentration of H, Si, Cl, K, Fe, and Th in the Low and Mid Latitude Regions of Mars. J. Geophys. Res. 112, E12S99 (2007), doi:10.1029/2007JE002887. 32. Lawrence, D. J., Feldman, W. C., Barraclough, B. L., Binder, A. B., Elphic, R. C., Maurice, S., Thomson, D. R.: Global elemental maps of the Moon: the Lunar Prospector Gamma-Ray Spectrometer. Science 281, 1484 (1998). 33. Prettyman, T. H., Hagerty, J. J., Elphic, R. C., Feldman, W. C., Lawrence, D. J., McKinney, G. W., Vaniman, D. T.: Elemental composition of the lunar surface: Analysis of gamma ray spectroscopy data from Lunar Prospector. J. Geophys. Res. 111, E12007 (2006), doi:10.1029/2005JE002656. 34. Taylor, G. J., Stopar, J. D., Boynton, W. V., Karunatillake, S., Keller, J. M., Brückner, J., Wänke, H., Dreibus, G., Kerry, K. E., Reedy, R. C., Evans, L. G., Starr, R. D., Martel, L. M. V., Squyres, S. W., Gasnault, O., Maurice, S., d’Uston, C., Englert, P., Dohm, J. M., Baker, V. R., Hamara, D., Janes, D., Sprague, A. L., Kim, K. J., Drake, D. M., McLennan, S. M., Hahn, B. C.: Variations in K/Th on Mars. J. Geophys. Res. Planets 111, E03S06 (2007), doi:10.1029/2005JE002676. 35. Hasebe, N., Shibamaru, E., Miyachil, T., Takashima, T., Kobayashi, M., Okudaira, O., Yamashita, N., Kobayashi, S., Ishizaki, K., Sakurai, K., Miyajima, M., Fujii, M., Narasaki, K., Takai, S., Tsurumi, K., Kanaeko, H., Nakazawa, M., Gasnault, O., Maurice, S., d’Uston, C., Reedy, R. C., Grande, M.: Gamma ray spectrometer (GRS) for lunar polar orbiter SELENE. Earth Planet. Space 60, 299 (2008) 36. Chang, J., Ma, T., Zhang, N., Cai, M. S., Gong, Y. Z., Tang, H. S., Zhang, R. J., Wang, N. S., Y Zhou, Yu, M., Mao, J. P., Zhou, Y. L., Liu, J. Z., Xu, A. A., Liu, L. G.: Gamma ray detector on board lunar mission Chang’e-1. Proc. Int. Workshop Advances in Cosmic Ray Science. J. Phys. Soc. Jpn. 78A, 26 (2009) 37. Goswami, J. N., Banderjee, D., Bhandari, N., Shanmugam, N., Acharya, Y. B., Subhedar, D. V., Sharma, M. R., Umapathy, C. N., Sreekumar, P., Sudhakar, M., Abraham, L., Agrawal, P. C.: High energy X-γ ray spectrometer on the Chandrayaan-1 mission to the Moon. J. Earth Syst. Sci. 114, 733 (2005) Unauthenticated Download Date | 6/17/17 5:51 AM
© Copyright 2026 Paperzz