CHEMICAL IMPACT HUMANS HAVE ALWAYS been fascinated by the heavens, by the behavior of the sun by day and the stars by night. Although more accurately measured now because of precise instruments, the basic observations of these events have remained the same over the past 4000 years. However, our interpretations of the events have changed dramatically. For example, about 2000 B.C. the Egyptians postulated that the sun was a boat inhabited by the god Ra, who daily sailed across the sky. Over the years, patterns in the changes in the heavens were recognized and, through marvelous devices such as Stonehenge in England, were connected to the seasons of the year. People also noted that seven objects seemed to move against the background of “fixed stars.” These objects, actually the sun, the moon, and the planets Mercury, Venus, Mars, Jupiter, and Saturn, were called the “wanderers.” The planets appeared to move from west to east, except Mars, which seemed to slow down and even move backwards for a few weeks. One of the first explanations for these observations came from Eudoxus, born in 400 B.C. He imagined the earth as fixed, with the planets attached to a nested set of transparent spheres that moved at different rates around the earth. The stars were attached to the outermost sphere. This model, although clever, still did not account for the strange behavior of Mars. Five hundred years later, Ptolemy, a Greek scholar, worked out a plan more complex than that of Eudoxus, in which the planets were attached to the edges of spheres that “rolled around” the spheres of Eudoxus (see time line). This model accounted for the behavior of all the planets, including the apparent reversals in the motion of Mars. Because of human prejudice that the earth should be the center of the universe, Ptolemy’s model was assumed to be cor- Observations, Theories, and the Planets rect for more than a thousand years, and its wide acceptance actually inhibited the advancement of astronomy. Finally, in 1543, a Polish cleric, Nicholas Copernicus, postulated that the earth was only one of the planets, all of which revolved around the sun. This “demotion” of the earth’s status produced violent opposition to the new model, and in fact, Copernicus’s writings were “corrected” by religious officials before scholars were allowed to use them. The Copernican theory persisted and was finally given a solid mathematical base by Johannes Kepler. Kepler postulated elliptical rather than circular orbits for the planets in order to account more completely for their observed motions. Kepler’s hypotheses were in turn further refined 36 years after his death by Isaac Newton, who recognized that the concept of gravitation could account for the positions and motions of the planets. However, even the brilliant models of Newton were found incomplete by Albert Einstein, who showed that Newton’s mechanics was a special case of a much more general model. Thus the same basic observations were made for several thousand years, but the explanations—the models—have changed remarkably from the Egyptians’ boat of Ra to Einstein’s relativity. Our models will inevitably change, and we should expect them to do so. They can help us make scientific progress, or they can inhibit progress if we become too attached to them. Although the fundamental facts of chemistry will remain the same, the models in a chemistry text written a century from now will certainly be quite different from the ones presented here. A time line showing how models of the solar system changed over 4000 years. 2000 B.C.: Egyptians: sun is a boat sailed by a god 1600 B.C. 1200 B.C. 800 B.C. 400 B.C.: Eudoxus: earth fixed; planets roll on spheres 100 A.D.: Ptolemy: modified Eudoxus’s model to account for apparent direction reversals 400 A.D. 800 A.D. 1200 A.D. Copernicus: sun-centered solar system Kepler: elliptical planetary orbits Galileo: confirmed Kepler’s laws Newton: universal law of gravitation Einstein: general relativity 2000 A.D.
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