4.1 INTRODUCTION TO CHEMICAL REACTIONS CHEMICAL REACTIONS Chemical Reactions are the result of one or more substances undergoing a chemical change to produce new substances. How can you tell that new substances have been formed? Indicators of a Chemical Change: The problem with these indicators is that they don’t 100% verify that you have undergone a chemical change. Think about two examples where this may be true: Elements and compounds often interact together in a chemical reaction. are a way of communicating what is occurring in a chemical reaction. The are the substances that undergo the chemical reaction (on the left) and the are the substances formed in a chemical reaction (on the right). Figure 1: According to the following chemical reaction, two molecules of hydrogen peroxide decompose to form two molecules of water and one molecule of oxygen gas. The bonds in hydrogen peroxide break and rearrange to form new bonds. A catalyst (MnO2) can be used in this reaction to speed up a reaction, without being used up itself. DESCRIBING CHEMICAL REACTIONS A. WORD EQUATIONS: hydrogen peroxide MnO2 catalyst water + oxygen + energy* The disadvantage of a word equation is that you do not have information about the chemicals themselves, including the number of atoms being reacted and produced. B. SKELETON EQUATIONS: H2O2(aq) solid MnO2 catalyst H2O(l) + O2(g) + energy* liquid gas aqueous The disadvantage of a skeleton equation is that it does not show how the numbers of atoms have balanced each other on the reactant side and the product side. *Even though energy is not considered a chemical, it is still absorbed or released in a reaction, and therefore we include this in a reaction. You will see more of this in Grade 12. C. THE LAW OF CONSERVATION OF MASS AND BALANCING CHEMICAL EQUATIONS This is also true for the number of atoms. We know from atomic theory that matter cannot be created or destroyed, only changed. The number of atoms is always the same. This law has been proven using experimental evidence. 2 H2O2(aq) MnO2 catalyst 2 H2O(l) + O2(g) + energy Balancing equations is possible, because of the Law of Conservation of Mass. Occasionally, you will have a skeleton equation that is already balanced. C(s) + O2(g) → CO2(g) Not all chemical equations work out this way. In the equation below, there is one magnesium on both sides of the equation. There are 2 O on the reactant side, but only 1 O on the product side. Mg(s) + O2(g) → MgO(s) To balance the equation, you can add numbers called in front of the chemical formulas. This will tell us how many molecules or formula units are present. You cannot change the formulas, only the coefficient in front of it. 2 Mg(s) + O2(g) → 2 MgO(s) RULES TO BALANCING CHEMICAL EQUATIONS (Using Trial and Error) Here is a diagram showing the balancing of an equation with molecular structures: Example Problems: 1. ___ As4S6(s) + ___ O2 → ___ As4O6(s) + ___ SO2(g) 2. ___ Sc2O3(s) + ___ H2O(l) → ___ Sc(OH)3(s) 3. ___ C2H5OH(l) + ___ O2(g) → ___ CO2(g) + ___ H2O(l) 4. ___ C4H10(g) + ___ O2(g) → ___ CO2(g) + ___ H2O(g) 5. ___ Fe2(SO4)3(aq) + ___ KSCN(aq) → ___ K3Fe(SCN)6(aq) + ___ K2SO4(aq) * You can use an alternate way of balancing equations by making a table for each element on the reactant side and the product side. You may have learned this format last year.
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