Acid Base Practice Problems: Today: Next Week: REVIEW FOR FINAL EXAM: ◦ Logarithms & pH Calculations ◦ Acid-Base Titrations ◦ Bring your questions ◦ Indicators for monitoring ◦ Pizza Party NEXT THURSDAY reactions with Jeopardy Style Review COMPREHENSIVE FINAL EXAM: Thursday, December 19th: 1:00-3:50 pm in 615 Grade Replacement OPTION: If you opt in, you can replace your lowest exam grade for your final exam grade: • • If you improve, this will help your overall grade by bringing up your lowest exam grade If you do poorly, this will hurt your overall grade 1 Concept Check pH and Acid Strength Which solution would have the lowest pH? A. 0.001 M HNO3 B. 0.001 M HCl(aq) C. 0.001 M HClO4(aq) D. 0.001 M HBr(aq) E. They would all have the same pH Acid-Base Practice Problems Write the reaction that occurs when 5.3 grams of solid Acetic Acid (monoprotic, weak acid: CH3CO2H) dissolves in 100. mL of water. What is the concentration of this acid in moles/L? Would this solution be a strong electrolyte, weak electrolyte or NONelectrolyte? 2 iClicker Participation Question pH and Acid Strength Which solution would have the lowest pH? A. 0.01 M CH3CO2H(aq) (Acetic Acid) B. 0.01 M HCl(aq) C. 0.01 M NH3(aq) D. 0.1 M NaOH(aq) E. They would all have the same pH Acid-Base Practice Problems What is the pH of a solution prepared by dissolving 5.86 grams of barium hydroxide in water to reach a total volume of 150 mL of aqueous solution? Would this solution be conductive? Write the balanced equation for the reaction of aqueous barium hydroxide with aqueous sulfuric acid. What volume of 0.5 M sulfuric acid (H2SO4) would be needed to fully react with the 150. mL of aqueous barium hydroxide from above? 3 Logarithmic pH scale: pH = -log[H+] TITRATION: A substance in solution with a known concentration is reacted with another substance in a solution with an unknown concentration. • An indicator is used to signal when the reaction is complete. • The concentration and volume of the known is then used to calculate the moles and concentration of the unknown. Acid Base Indicators: a dye whose color changes depending on the pH (acidity) of the solution. 4 iClicker Participation Question Acid-Base Titrations and Electrical Conductivity For the titration of barium hydroxide with sulfuric acid, which plot would best represent the change in conductivity versus volume of sulfuric acid added? H2SO4(aq) + Ba(OH)2(aq) → 2 H2O(l) + BaSO4(s) A. B. C. D. The conductivity would NOT change 5
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