safety data sheet - Goodyear Chemical

SAFETY DATA SHEET
BUD1208, BUDENE 1208
SDS No. G0063B
EU / EN
Effective Date 05/15/2006
Revision: 05/17/2012
1. IDENTIFICATION of the SUBSTANCE and COMPANY
Trade Name
BUD1208, BUDENE 1208
Chemical Name
Polybutadiene
Synonym(s):
PBD
Miscellaneous Information:
Company Identification
The Goodyear Tire & Rubber Company Akron, Ohio 44316-0001 U.S.A.
Goodyear Canada, Inc. Etobicoke, Ontario M8Z 5E1
Canada
Emergency Phone Numbers
Chemical Transportation Emergency Assistance, CHEMTREC (USA) 800-424-9300
(Canada) 613-996-6666
MSDS Information
ISSUED BY - Global Chemical Material Management - Akron, Ohio 44316-0001
Technical Assistance
330-796-1906
2. HAZARDS IDENTIFICATION
EC Classification Designation
This substance is classified as dangerous according to Council Directive 67/548/EEC.
Emergency Overview
If ignited by excessive heat or open flame, this product will burn. During fire conditions fumes are irritating to eyes and
respiratory tract.
APPEARANCE: Amber solid
ODOR: Rubber
Potential Health Effects
--- PRIMARY ROUTES OF ENTRY --Dermal Contact - Inhalation
--- SHORT-TERM EXPOSURE --Vapors generated during processing may be irritating to the eyes, skin or respiratory system.
--- LONG-TERM EXPOSURE --None known for product as produced.
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3. COMPOSITION / INFORMATION on the COMPONENTS
Chemical Name Polybutadiene.
Synonym(s): PBD
Product Description: Polymer
Non-hazardous information
Chemical name
1,3-Butadiene, homopolymer
Percentage by wt.
50-100
Regulatory CAS Notes:
REACH Registration Number(s): 01-2119471988-16 (1,3 butadiene)
CAS-No
9003-17-2
EC Number
EU Classification
NE
4. FIRST AID MEASURES
Eye Contact
For fumes generated during high heat procedures: For irritation, flush eyes with copious amounts of water. If irritation
persists, seek medical attention.
Skin Contact
Wash with soap and water.
Inhalation
For fumes generated during high heat procedures: If overcome by exposure, remove victim to fresh air.
Ingestion
Seek immediate medical attention.
5. FIRE-FIGHTING MEASURES
--- EXTINGUISHING MEDIA --Water, all purpose (ABC) dry chemical, CO2, foam
--- SPECIAL INTERVENTION METHODS --During emergency conditions, overexposure to thermal decomposition products may cause a health hazard. An approved,
self-contained breathing apparatus should be worn.
--- SPECIAL EXPOSURE HAZARDS --Not easily ignited. However, when ignited, and particularly in bulk storage, a hot and difficult to control fire may develop. This
material emits acrid smoke and fumes when burning.
6. ACCIDENTAL RELEASE MEASURES
---AFTER SPILLAGE/LEAKAGE --- (methods for cleaning up)
Wear personal protective equipment. Prevent spill from entering sanitary sewers and waterways. Place in closed container
for recycle or disposal.
7. HANDLING and STORAGE
--- PRECAUTIONS --Keep away from excessive heat and open flame.
--- HANDLING --Avoid eye contact. Avoid skin contact. Avoid inhalation.
--- STORAGE --Store in a cool dry place away from excessive heat or open flame.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
--- VENTILATION PROTECTION --When this material is heated, provide enough fresh air and/or exhaust to remove the hot processing vapors from the work
area. Observe the Occupational Exposure Limit of 3 mg/m3 (Threshold Limit Value - 8 hour time weighted average) for
insoluble respirable particulates, not otherwise classified.
--- RESPIRATION PROTECTION --Under normal conditions of use, respiratory protection should not be required.
--- SKIN PROTECTION --Employees who have prolonged contact with this material should practice good personal hygiene by frequent washing of
hands and arms with soap and water.
--- EYE PROTECTION --Safety glasses
--- PROTECTIVE GLOVES --Heavy cotton or impervious if practical.
--- OTHER PROTECTION --Practice good personal hygiene.
9. PHYSICAL and CHEMICAL PROPERTIES
APPEARANCE:
Amber solid
ODOR:
Rubber
pH
Not determined.
FLASH POINT and METHOD
Not determined.
FLAMMABLE LIMITS
LEL Not established for product
UEL Not established for product
THERMAL DECOMPOSITION
Not determined.
AUTO-IGNITION TEMP
Not determined.
INITIAL BOILING POINT
Not determined.
MELT POINT
Not determined.
SPECIFIC GRAVITY
0.91
SOLUBILITY IN WATER
Insoluble
10. STABILITY and REACTIVITY
--- CONDITIONS TO AVOID --Material is stable.
--- MATERIALS TO AVOID --If nitrosating agents (i.e. NOx) are present during processing nitrosamines may be formed. Nitrosamines are animal
carcinogens.
--- HAZARDOUS DECOMPOSITION PRODUCTS --Carbon monoxide, Carbon dioxide.
11. TOXICOLOGY INFORMATION
ORAL LD50
DERMAL LD50
INHALATION LC50
Not established for product
Not established for product
Not established for product
12. ECOLOGICAL INFORMATION
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12. ECOLOGICAL INFORMATION
Component Information: Data for components given below.
--- OTHER --This product has not been tested for ecological (physical and/or biological) hazards or the data is not available or not known.
13. DISPOSAL CONSIDERATIONS
--- DISPOSAL --Incinerate or landfill in accordance with applicable environmental control regulations. Recycle if possible.
14. TRANSPORTATION INFORMATION
Hazard Class - Not classified. No labelling required according to current transport legislation.
15. REGULATORY INFORMATION
EC Classification Designation
This substance is classified as dangerous according to Council Directive 67/548/EEC.
---EC LABELLING--No labelling required according to criteria of European Directive 67/548/EEC and its subsequent amendments.
--- INTERNATIONAL --EINECS
TSCA
CANADIAN (DSL)
AICS
ENCS
KECL
PICCS
CHINA
New Zealand
One or more ingredients are not on EINECS
Listed or Exempt
Listed or Exempt
Listed or Exempt
Listed or Exempt
Listed or Exempt
Listed or Exempt
Listed or Exempt
Listed or Exempt
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16. OTHER INFORMATION / ADDITIONAL COMMENTS
Revision:
Revision summary
05/17/2012
The SDS has been updated to meet the requirements stipulated in commission regulation (EU) 453/2010.
Goodyear believes that the information herein is correct at the date that this Material Safety Data Sheet was
prepared. The data may not be exhaustive and should only be used as a guide to determine the best conditions
for the safe use of the product. Goodyear is not responsible for any injury or liability resulting from misuse of this
product.
--- END of DOCUMENT ---
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