SAFETY DATA SHEET BUD1208, BUDENE 1208 SDS No. G0063B EU / EN Effective Date 05/15/2006 Revision: 05/17/2012 1. IDENTIFICATION of the SUBSTANCE and COMPANY Trade Name BUD1208, BUDENE 1208 Chemical Name Polybutadiene Synonym(s): PBD Miscellaneous Information: Company Identification The Goodyear Tire & Rubber Company Akron, Ohio 44316-0001 U.S.A. Goodyear Canada, Inc. Etobicoke, Ontario M8Z 5E1 Canada Emergency Phone Numbers Chemical Transportation Emergency Assistance, CHEMTREC (USA) 800-424-9300 (Canada) 613-996-6666 MSDS Information ISSUED BY - Global Chemical Material Management - Akron, Ohio 44316-0001 Technical Assistance 330-796-1906 2. HAZARDS IDENTIFICATION EC Classification Designation This substance is classified as dangerous according to Council Directive 67/548/EEC. Emergency Overview If ignited by excessive heat or open flame, this product will burn. During fire conditions fumes are irritating to eyes and respiratory tract. APPEARANCE: Amber solid ODOR: Rubber Potential Health Effects --- PRIMARY ROUTES OF ENTRY --Dermal Contact - Inhalation --- SHORT-TERM EXPOSURE --Vapors generated during processing may be irritating to the eyes, skin or respiratory system. --- LONG-TERM EXPOSURE --None known for product as produced. _____________________________________________________________________________________________ Page 1 of 5 G0063B - BUD1208, BUDENE 1208 Revision: 05/17/2012 3. COMPOSITION / INFORMATION on the COMPONENTS Chemical Name Polybutadiene. Synonym(s): PBD Product Description: Polymer Non-hazardous information Chemical name 1,3-Butadiene, homopolymer Percentage by wt. 50-100 Regulatory CAS Notes: REACH Registration Number(s): 01-2119471988-16 (1,3 butadiene) CAS-No 9003-17-2 EC Number EU Classification NE 4. FIRST AID MEASURES Eye Contact For fumes generated during high heat procedures: For irritation, flush eyes with copious amounts of water. If irritation persists, seek medical attention. Skin Contact Wash with soap and water. Inhalation For fumes generated during high heat procedures: If overcome by exposure, remove victim to fresh air. Ingestion Seek immediate medical attention. 5. FIRE-FIGHTING MEASURES --- EXTINGUISHING MEDIA --Water, all purpose (ABC) dry chemical, CO2, foam --- SPECIAL INTERVENTION METHODS --During emergency conditions, overexposure to thermal decomposition products may cause a health hazard. An approved, self-contained breathing apparatus should be worn. --- SPECIAL EXPOSURE HAZARDS --Not easily ignited. However, when ignited, and particularly in bulk storage, a hot and difficult to control fire may develop. This material emits acrid smoke and fumes when burning. 6. ACCIDENTAL RELEASE MEASURES ---AFTER SPILLAGE/LEAKAGE --- (methods for cleaning up) Wear personal protective equipment. Prevent spill from entering sanitary sewers and waterways. Place in closed container for recycle or disposal. 7. HANDLING and STORAGE --- PRECAUTIONS --Keep away from excessive heat and open flame. --- HANDLING --Avoid eye contact. Avoid skin contact. Avoid inhalation. --- STORAGE --Store in a cool dry place away from excessive heat or open flame. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION _____________________________________________________________________________________________ Page 2 of 5 G0063B - BUD1208, BUDENE 1208 Revision: 05/17/2012 8. EXPOSURE CONTROLS / PERSONAL PROTECTION --- VENTILATION PROTECTION --When this material is heated, provide enough fresh air and/or exhaust to remove the hot processing vapors from the work area. Observe the Occupational Exposure Limit of 3 mg/m3 (Threshold Limit Value - 8 hour time weighted average) for insoluble respirable particulates, not otherwise classified. --- RESPIRATION PROTECTION --Under normal conditions of use, respiratory protection should not be required. --- SKIN PROTECTION --Employees who have prolonged contact with this material should practice good personal hygiene by frequent washing of hands and arms with soap and water. --- EYE PROTECTION --Safety glasses --- PROTECTIVE GLOVES --Heavy cotton or impervious if practical. --- OTHER PROTECTION --Practice good personal hygiene. 9. PHYSICAL and CHEMICAL PROPERTIES APPEARANCE: Amber solid ODOR: Rubber pH Not determined. FLASH POINT and METHOD Not determined. FLAMMABLE LIMITS LEL Not established for product UEL Not established for product THERMAL DECOMPOSITION Not determined. AUTO-IGNITION TEMP Not determined. INITIAL BOILING POINT Not determined. MELT POINT Not determined. SPECIFIC GRAVITY 0.91 SOLUBILITY IN WATER Insoluble 10. STABILITY and REACTIVITY --- CONDITIONS TO AVOID --Material is stable. --- MATERIALS TO AVOID --If nitrosating agents (i.e. NOx) are present during processing nitrosamines may be formed. Nitrosamines are animal carcinogens. --- HAZARDOUS DECOMPOSITION PRODUCTS --Carbon monoxide, Carbon dioxide. 11. TOXICOLOGY INFORMATION ORAL LD50 DERMAL LD50 INHALATION LC50 Not established for product Not established for product Not established for product 12. ECOLOGICAL INFORMATION _____________________________________________________________________________________________ Page 3 of 5 G0063B - BUD1208, BUDENE 1208 Revision: 05/17/2012 12. ECOLOGICAL INFORMATION Component Information: Data for components given below. --- OTHER --This product has not been tested for ecological (physical and/or biological) hazards or the data is not available or not known. 13. DISPOSAL CONSIDERATIONS --- DISPOSAL --Incinerate or landfill in accordance with applicable environmental control regulations. Recycle if possible. 14. TRANSPORTATION INFORMATION Hazard Class - Not classified. No labelling required according to current transport legislation. 15. REGULATORY INFORMATION EC Classification Designation This substance is classified as dangerous according to Council Directive 67/548/EEC. ---EC LABELLING--No labelling required according to criteria of European Directive 67/548/EEC and its subsequent amendments. --- INTERNATIONAL --EINECS TSCA CANADIAN (DSL) AICS ENCS KECL PICCS CHINA New Zealand One or more ingredients are not on EINECS Listed or Exempt Listed or Exempt Listed or Exempt Listed or Exempt Listed or Exempt Listed or Exempt Listed or Exempt Listed or Exempt _____________________________________________________________________________________________ Page 4 of 5 G0063B - BUD1208, BUDENE 1208 Revision: 05/17/2012 16. OTHER INFORMATION / ADDITIONAL COMMENTS Revision: Revision summary 05/17/2012 The SDS has been updated to meet the requirements stipulated in commission regulation (EU) 453/2010. Goodyear believes that the information herein is correct at the date that this Material Safety Data Sheet was prepared. The data may not be exhaustive and should only be used as a guide to determine the best conditions for the safe use of the product. Goodyear is not responsible for any injury or liability resulting from misuse of this product. --- END of DOCUMENT --- _____________________________________________________________________________________________ Page 5 of 5
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