1 CHAPTER 1 INTRODUCTION Iron and Steel rank amongst the most important materials of our times. The iron and steel industry remains a viable and dynamic industry; thanks to creative engineers and enterprising investors. Competition, the driving force of invention and innovation, has forced steel makers to adopt new technologies that reduce costs without sacrificing quality. 1.1 HISTORICAL BACKGROUNDS OF STEEL MAKING TECHNOLOGY Production of hot metal in the Blast Furnaces (BF) followed by steel making through Bessemer Converters or Open Hearth Furnaces (OHF) was the main steel making process for mass production from 1850 to 1960. From the early 1960s, while blast furnaces continued to be the source of supply of hot metal to steel melting shops, the OHF started getting replaced by LD converters where pure oxygen blowing in a specially designed vessel was carried out in order to shorten the blowing period. Typically, the processing time in the OHF was 12 to 14 hours while the LD cut short the processing time to less than one hour. Hence, from 1960 onwards all new facilities for steel melting came up with LD converters for large capacity integrated steels plants. For lower capacity new installations, normally Electric Arc Furnace (EAF) was installed, especially in the areas where scrap/sponge iron and power at economic price was available. The OHF were normally having ingot casting arrangement for converting liquid steel to solid product suitable for rolling. However, in high speed LD converter and EAF 2 shops, continuous casting machines were installed to handle large quantities of liquid steel for casting into solid products at the matching speed. During the period mid 1960s up to the end of 1970s, a lot of work was done to reduce the cycle time of the OHF in order to compete with the new installations having LD converters and EAF. This was mainly achieved through oxygen blowing in the OHF through the roof and also through submerged tuyeres. Through various efforts, the cycle time of OHF was reduced from 12 hours to as low as 4 to 5 hours. Due to the basic construction of the OHF, it was difficult to reduce the cycle time below 4 hours and therefore OHF was not able to compete with the LD converters or EAF with regard to productivity as well as cost of production. Hence, a number of OHF in the existing steel plants either closed down or were replaced by more efficient steel making equipments. The steel manufacturing companies were faced with the situation to replace the less efficient OHF by LD Converters, EAF or by a new process in order to remain competitive. New capacities for steel production, which were emerging primarily in the developing countries, also had to make a choice between one of the three options specified above. Each option has its own merit and it is suitable in a given local condition. The raw material and the major inputs in iron and steel making are location specific depending on the cost of material and transportation cost. Therefore, a steel maker has to select the most economical process in order to convert the local raw materials into the finished steel. Such decisions are based on the capital investments as well as operational costs. 3 1.2 DEVELOPMENT OF ENERGY OPTIMIZING FURNACE IN BRAZIL At CS Pains, Divinopolis, Brazil, KORF Group had a 200,000 MT per annum steel plant, having three numbers working and one stand-by OHF. During late 1970s to meet the competition of LD converters and EAF, the KORF group developed the Energy Optimizing Furnace (EOF) which was designed to have the advantages of both the LD converter and EAF. The (EOF) is a combined blowing, basic oxygen steel making furnace where a combination of hot metal and solid scrap is converted to liquid steel suitable for secondary refining and continuous casting. The schematic view of the first EOF developed at C.S.Pains is shown in Figure 1.1 - Weber et al (1984). 1. Furnace Vessel 6. Combustion Air (cold) 2. Scrap Preheating 7. Combustion Air (preheated) 3. Recuperator 8. Additional Oxygen 4. Oxygen Nozzles Beneath Bath 9. Scrap (cold) 5. Oil-Oxygen Burner 10. Scrap (preheated) Figure 1.1 Energy optimizing furnace overview 4 The quality of steel produced through EOF was comparable with OHF- Weber et al (1984). The shape of the EOF is like EAF, which facilitates continuous slag removal, and efficient slag free tapping. The top and side oxygen blowing in EOF is like LD converters where it facilitates very high turbulence of the bath in order to achieve short blowing time of about thirty minutes. C S Pains, not only wanted to increase the steel production in their works, but also to market EOF technology all over the world with flexibility of hot metal to scrap ratio in order to produce steel economically. The first EOF installed at CS Pains in 1982 and then replaced by the tilting type modern EOF in 1988, presently having capacity of 35 / 40 MT, is still in operation and presently producing 0.5 million MT steel per annum. Thereafter, a number of EOF’s were installed worldwide but most of them were not commercially successful for one reason or the other as shown in Table 1.1. By the mid 1990s, when 80 MT EOF at TATA Iron & Steel Company Ltd (TISCO) was shut down, this technology almost appeared to be technically not sound for mass production. This is the reason why in the book “Making, Shaping and Treating of Steel” in Chapter 13, ‘Alternative Oxygen Steel Making Process’, page 746, EOF is also appearing as One of the processes under development along with other new processes such as IRSID (France), WORCA (Australia), COSMOS (U.S) etc. 5 Table 1.1 EOF Installations EOF PLANTS Capacity Heat size (MT per (MT) annum) S.No. Location 1 CS.PAINS, Brazil 30 220,000 in operation from 12/1/1982 to 1998. 2 CS.PAINS, Brazil 30 220,000 in operation since 3/1/1988 3 ALIPERTI, Brazil 60 400,000 Start-up, 8/1/1988 CLOSED 4 RIFS, USA 40 250,000 Start-up late 1989 CLOSED 5 TISCO (TATA), Jamshedpur 80 520,000 6 AFS, Italy 60 450,000 start-up early 1991 CLOSED 7 SISCOL, Salem 8 Hospet Steels, Karnataka 1.3 40/45 40 Status start-up early 1990 CLOSED 4,00,000 in operation since 1998 3,50,000 in operation since 1998 INSTALLATION OF ENERGY OPTIMIZING FURNACES IN INDIA In the 1990s two EOF, of 35/40 MT capacity were planned in India in two mini mills. Here the choice was between LD converter, EAF using 60% hot metal and 40% scrap, or to install EOF. The decision was taken in favour of EOF since the capital investment in EOF was less than half of the LD converter and the processing cost was envisaged to be significantly lower than EAF. In 1998 one 40 MT EOF was installed at Hospet Steels Ltd., Hospet, India and another 35 MT capacity EOF was installed at Southern Iron And Steel Co. Ltd, (SISCOL) at Salem, Tamil Nadu, India. The scholar was responsible for putting up 300,000 MT integrated steel plant through EOF 6 route for manufacturing special steels at Hospet Steels Ltd. The EOF operating at CS Pains was studied in detail, which was producing only commercial grade of steel. Through literature survey the reasons for failure of the other EOF in the other parts of the world were also studied in order to take corrective measures. The EOF for manufacturing special steels under Indian conditions at Hospet Steels Ltd was a good success and that gave a new life to the EOF technology. Hospet Steels Ltd operates at the productivity of 400,000 MT per annum for special steels through EOF route. The quality of the product is well accepted by the customers and the cost of production was as per the norms. At SISCOL, EOF was producing 200,000 MT of steel per annum but the over all operation was not profitable. In 2004 the scholar took the responsibility to turn around the SISCOL operation into a successful venture. By increasing the EOF capacity to 45 MT and through technical upgradation of the upstream and downstream facilities, the steel productivity was doubled to 400,000 MT per annum. In addition, one 65 MT EOF, the largest in the world, was put up at SISCOL for the second line of production, having capacity of 600,000 MT per annum. Today SISCOL is a one million ton capacity steel plant where the capacity enhancement has been done at a low investment compared to industry norms. The quality of special steels produced at SISCOL is well accepted by the customers. The cost of production is very similar to the plants making steel through LD converters. In India up to December 2007, 4.42 million ton of steel (Hospet Steels – 2.68 million ton, SISCOL – 1.74 million ton) has been produced as shown in Figures 1.2 and 1.3. This proves that the EOF technology has good potential in India especially for the steel plants of capacity up to one million MT per annum of carbon and special steels. This is also true for other countries where conditions are similar to Indian conditions. Today, SISCOL is the largest integrated steel plant in the world having entire steel production through the EOF route. 7 500000 PRODUCTION (MT) 450000 400000 350000 300000 250000 200000 150000 100000 50000 0 PROD ( MT) 1998-99 1999 2000 9791 64395 2000 - 01 2001- 02 2002- 03 2003 - 04 2004 - 05 2005 - 06 2006 - 07 2007 - 08 67621 46194 213885 171073 161954 YEAR 228104 320402 460878 TOTAL = 1744297 Figure 1.2 Steel productions per annum – SISCOL 450000 PRODUCTION (MT) 400000 350000 300000 250000 200000 150000 100000 50000 0 PROD ( MT) 1998-99 1999 2000 2000 01 2001 2003 2002- 03 02 04 2004 05 2005 06 2006 07 2007 08 27664 127608 195195 250010 279359 273894 347822 351756 408000 417744 YEAR TOTAL = 2679052 Figure 1.3 Steel productions per annum – Hospet Steels 1.4 ORGANIZATION OF THESIS The critical analysis of all the papers published in the field of Energy Optimizing Furnace (EOF) and related steel making processes have been explained in Literature Survey – chapter 2. Literature Survey also gave 8 an insight into the missing links in the technology, which paved the way for further work in the area of EOF based on which the objectives and scope of research for the present work has been defined. Chapter 3 briefly describes the various equipments of EOF. Chapter 4 explains the steel making process through EOF for proper understanding. In Chapter 5, important modifications and design changes carried out in the EOF equipment to suit the Indian conditions have been explained. Chapter 6 deals with improvement in cost of production through the EOF route. Chapter 7 highlights the commissioning of World’s largest 65 MT capacity EOF at SISCOL, Salem, India. Chapter 8 deals with the implementation of catch carbon process in EOF, which has been the most important contribution of the present research work. The results of the present research work and the analysis of the results have been discussed in chapter 9. The main conclusions of this research work are presented in the last chapter 10.
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