Using Scientific Measurements We have talked about measured quantities: Quantities that can be measured directly. Examples – Length, Mass, Volume… What about quantities that can not be measured directly, or, derived quantities: Quantities found by the mathematical manipulation of one or more measured quantities. Examples – Area, Volume, Density… How can Volume be both measured and derived? Density: • Derived quantity from mass and volume • Physical property of a substance • Is temperature dependent m d= V Use the picture below to calculate the density of a piece of chewing gum that has a mass of 25.3 grams. Sample Problem: What is the density of aluminum if a 3.0 cm by 3.0 cm by 2.5 cm block has a mass of 58.7 grams? Notice, the volume can be calculated from a geometric formula and the mass can be measured directly. But what about a wad of chewing gum. How do we finds its volume to find its density? Accuracy vs. Precision The goal of all measurements is to be both accurate and precise! • Accuracy refers to the proximity of a measurement to the true value of a quantity. • Precision refers to the proximity of several measurements to each other. 1 Remember, each measured quantity must have an uncertain digit. The uncertain digit relays the accuracy of a measurement. How then does the accuracy of a set of measurements become relayed in a calcualted, or derived, quantity? A derived quantity can not be more accurate than the least accurate measurement! Determining Significant Figures 1. All nonzero digits are significant. 2. Zeroes between two significant figures are themselves significant. 3. Zeroes at the beginning of a number are never significant. 4. Zeroes at the end of a number are significant if a decimal point is written in the number. 5. Exact numbers are infinitely significant. Significant Figures • When addition or subtraction is performed, answers are rounded to the least significant decimal place. • When multiplication or division is performed, answers are rounded to the number of digits that corresponds to the least number of significant figures in any of the numbers used in the calculation. Significant Figures • The term significant figures refers to digits in a number that were measured. • When rounding calculated numbers, we pay attention to significant figures so we do not overstate the accuracy of our answers. 1. How many significant figures are in each of the following measurements? 24 mL 2 significant figures 3001 g 4 significant figures 0.0320 m3 3 significant figures 6.4 x 104 molecules 2 significant figures 560 kg 2 significant figures Significant Figures Addition or Subtraction The answer cannot have more digits to the right of the decimal point than any of the original numbers. 89.332 +1.1 90.432 3.70 -2.9133 0.7867 one significant figure after decimal point round off to 90.4 two significant figures after decimal point round off to 0.79 2 Significant Figures Multiplication or Division The number of significant figures in the result is set by the original number that has the smallest number of significant figures 4.51 x 3.6666 = 16.536366 = 16.5 3 sig figs round to 3 sig figs 6.8 ÷ 112.04 = 0.0606926 = 0.061 2 sig figs round to 2 sig figs Rules for Rounding • If the number to be retained is followed by a number larger than 5, round up. • If the number to be retained is followed by a number less than 5, drop. • If the number following the number to be retained is 5 followed by any non-zero number, round up. • If the last number to be retained is a 5 and is followed by a zero, then always make it even. Perform each of the following, rounding the answer to the correct number of sig. fig’s.: 1. 298 g – 43.7 g 2. 4.218 cm x 6.6 cm 3. 4.23 m2 ÷ 18.941 m 4. 0.0653 g + 0.08538 g + 0.07654 g + 0.0432 g 5. 50 L x 5.23 L 6. 85.621 s – 5.5 s 3
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