DATE ___________________ NOTES-031 CHEM 110 (BEAMER) xNOTES-31:x Lewis Dot Structures-02 Lewis Dot Structures of Covalent Compounds I. Covalent Compounds (review) Note: Take out your Periodic Tables. You will need them throughout the lecture. Covalent compounds are composed only from PRACTICE PROBLEMS: Circle only the covalent compounds below. Assume metalloids (semi-metals) in the following problems behave like non-metals. CCl4 HBr Na2SO4 FeO C12H22O11 SO3 AsF3 H2O N2O5 in share to attain a . Period 1: Full Valence Shell = All other elements: Full Valence Shell = , often called the . _________________ atoms EXAMPLE: CH4 _________________ atoms EXAMPLE: SeBr2 Page 1 of 6 DATE ___________________ II. NOTES-031 CHEM 110 (BEAMER) Rules for Drawing Lewis Structures: Note: There are LOTS of rules. These need to be memorized. And you must be able to apply them at a moment’s notice. Note: Work Horses (you know who you are): I would re-type these rules so that they all fit on one page. Note: Always keep these rules at your side while drawing Lewis Structures until Friday. 1) Count the total number of electrons. Your final structure should have the same number of electrons. 2)* is always a atom. 3)* is NEVER a atom. 4)* Carbon 5)* ABSOLUTELY NO has a total of until CHEM 120. They tend to Examples * 6) Except for the is usually the . 7) , they are usually If there is . Example: C2F2H4 Total # of e–: vs Page 2 of 6 DATE ___________________ 8) NOTES-031 Carbon CHEM 110 (BEAMER) has . Total # of e–: Example: CNH5 vs PRACTICE PROBLEMS: NH3 EXAMPLE: Total # e–: C2H6 EXAMPLE: Total # e–: C2H6O EXAMPLE: Total # e–: C3H7Br EXAMPLE: Total # e–: N2H4 EXAMPLE: Total # e–: Page 3 of 6 DATE ___________________ NOTES-031 CHEM 110 (BEAMER) . III. Rules for Drawing Lewis Structures: 9) If single bonds “don’t work,”: double, triple up, or two doubles. O2 EXAMPLE: Total # e–: N2 EXAMPLE: Total # e–: CH2O AYD1: Total # e–: HCN AYD1: Total # e–: 10)* 11) EXAMPLES OF NO-NO’S: When given a choice of where to put , the element gets the most lone pair, and gets the most lone pairs. Example: CH3NO vs Page 4 of 6 DATE ___________________ 12) NOTES-031 CHEM 110 (BEAMER) Get over “American Sharing.” CO EXAMPLE: Total # e–: O3 AYD1: Total # e–: IV. Rules for Drawing Lewis Structures: An is a particle where Ions have 13) If an ion is indicated by remove any anywhere in the structure that will make the structure “work.” OH1– EXAMPLE: or OH– # of e–: 14) If an ion is add any anywhere in the structure that will make the structure “work.” NH41+ EXAMPLE: or NH4+ # of e–: Page 5 of 6 DATE ___________________ A NOTES-031 is a in which a total of between A . is a in which a total of between A CHEM 110 (BEAMER) . is a in which a total of between . Again: Bond Length: Bond Strength: Page 6 of 6
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