ISO9001:2000 Certified Material Safety Data Sheet Iodine Section 1 - Chemical Product and Company Identification MSDS Name: Iodine Catalog Numbers: Q09551 Synonyms: Company Identification: Qorpak 1195 Washington Pike Bridgeville, PA 15017 Company Phone Number: (412) 257-3100 Emergency Phone Number: (800) 424-9300 CHEMTREC Phone Number: (800) 424-9300 Section 2 - Composition, Information on Ingredients CAS# 7553-56-2 Chemical Name: Iodine Percent 100 Section 3 - Hazards Identification Emergency Overview Appearance: Dark purple crystals Caution! May cause respiratory and digestive tract irritation. May cause eye and skin irritation. May cause fetal effects based upon animal studies. Target Organs: central nervous system, respiratory system, cardiovascular system. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause gastric disturbances and electrolytic imbalance. Inhalation: May cause respiratory tract irritation. -1 - Material Safety Data Sheet Iodine Chronic: Chronic exposure can lead to iodism characterized by salivation, nasal discharge, sneezing, conjunctivitis, fever, laryngitis, bronchitis, stomatitis, and skin rashes. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn. Section 4 - First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids until chemical is gone. Get medical aid. Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Give conscious victim 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Move victim to fresh air immediately. Give artificial respiration if necessary. Get medical aid if cough or other symptoms appear. Notes to Physician: Treat symptomatically and supportively. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn. Negligible fire and explosion hazard when exposed to heat or flame. Move container if possible, cool with flooding amounts of water. Absorb with water - do not touch spilled material. Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use extinguishing media most appropriate for the surrounding fire. Autoignition Temperature: No information found. Flash Point: No information found. NFPA Rating: CAS# 7553-56-2: Not published. Explosion Limits: Lower: Upper: Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. -2 - Material Safety Data Sheet Iodine Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Storage: Store in a cool, dry area. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits: Chemical Name: ACGIH NIOSH OSHA None of the components None of the components C 0.1 ppm; C 1 mg/m3; are on this list. are on this list. Iodine OSHA Vacated PELs: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Section 9 - Physical and Chemical Properties Physical State: Crystals. Color: Purple. Odor: Iodine –like. pH: No information found. Vapor Pressure: 1mm Hg @ 38.7 Vapor Density: 9.0 (H2O = 1) Evaporation Rate: Negligible. Viscosity: No information found. -3 - Material Safety Data Sheet Iodine Boiling Point: 184.35°C Freezing/Melting Point: 113.5°C Decomposition Temperature: Sublimes. Solubility in water: Slight. Specific Gravity/Density: 4.93 Molecular Formula: I2 Molecular Weight: 253.81 Section 10 - Stability and Reactivity Chemical Stability: Sublimes, especially when heated. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Ammonia, acetylene, acetaldehyde, aluminum, active metals, bromine pentafluoride, alkali metals, strong oxidizing agents. Hazardous Decomposition Products: Iodine. Hazardous Polymerization: Will not occur. Section 11 - Toxicological Information RTECS: CAS# 7553-56-2: NN1575000. LD50/LC50: CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg Oral, rabbit: LD50 = 10 gm/kg Oral, rat: LD50 = 14 gm/kg. Carcinogenicity: CAS# Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop 65. Epidemiology: Teratogenicity: Reproductive: Mutagenicity: Neurotoxicity: Section 12 - Ecological Information No information found. Section 13 - Disposal Considerations Dispose of in accordance with Federal, State, and local regulations. -4 - Material Safety Data Sheet Iodine Section 14 - Transport Information US DOT Shipping Name: Corrosive solid, n.o.s. (Iodine) Hazard Class: 8 UN Number: UN1759 Packing Group: II Section 15 - Regulatory Information US Federal TSCA: CAS# 7553-56-2 is listed on the TSCA Inventory. SARA Reportable Quantities (RQ): None of the components are on this list. CERCLA/SARA Section 313: None of the components are on this list. OSHA - Highly Hazardous: None of the components are on this list. US State State Right to Know: Iodine can be found on the following state Right-to-Know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. California Regulations: European/International Regulations Canadian DSL/NDSL: CAS# 7553-56-2 is listed on Canada's DSL List. Canada Ingredient Disclosure List: CAS# 7553-56-2 is listed on Canada's Ingredient Disclosure List. Section 16 - Other Information MSDS Creation Date: November 4, 2004 Revision Date: July 17, 2006 Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and Qorpak assumes no liability resulting from the use of this MSDS. The user must determine suitability of this information for his application. -5 -
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